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The organometallic chemistry of the transition metals / / Robert H. Crabtree
| The organometallic chemistry of the transition metals / / Robert H. Crabtree |
| Autore | Crabtree Robert H. <1948-> |
| Edizione | [6th edition.] |
| Pubbl/distr/stampa | Hoboken, New Jersey : , : Wiley, , 2014 |
| Descrizione fisica | 1 online resource (522 p.) |
| Disciplina | 547/.056 |
| Soggetto topico |
Organometallic chemistry
Organotransition metal compounds Compostos organometàl·lics de transició |
| Soggetto genere / forma | Llibres electrònics |
| ISBN |
1-118-78824-9
1-118-78830-3 1-118-78844-3 |
| Formato | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Cover; Title page; Copyright page; Contents; Preface; List of Abbreviations; 1: Introduction; 1.1 Why Study Organometallic Chemistry?; 1.2 Coordination Chemistry; 1.3 Werner Complexes; Stereochemistry; Chelate Effect; Werner's Coordination Theory; 1.4 The Trans Effect; 1.5 Soft versus Hard Ligands; 1.6 The Crystal Field; High Spin versus Low Spin; Inert versus Labile Coordination; Jahn-Teller Distortion; Low- versus High-Field Ligands; Magnetism and Nuclearity; Other Geometries; Isoconfigurational Ions; 1.7 The Ligand Field; 1.8 The sdn Model and Hypervalency; 1.9 Back Bonding
Frontier Orbitalsπ-Donor Ligands; 1.10 Electroneutrality; Oxidation State Trends; Periodic Trends; 1.11 Types of Ligand; Ambidentate Ligands; Actor and Spectator Ligands; Multifunctional Ligands29; Organometallic versus Coordination Compounds; References; Problems; 2: Making Sense of Organometallic Complexes; 2.1 The 18-Electron Rule; Covalent Electron Counting Model; Ionic Electron Counting Model; Electron Counts for Common Ligands and Hapticity; Bridging Ligands; Zero-Electron Ligands; 2.2 Limitations of The 18-Electron Rule; Steric Stabilization of Reactive Species Kinetic Stability from Bulky SubstituentsPreparation of Metal Alkyls; Cyclometalation; Oxidative Addition; Insertion; Bridging Alkyls; Metalacycles; η1 and η2-Acyl and Vinyls; 3.2 Other σ-Bonded Ligands; Group 14 Elements; Groups 15-17; Oxophilicity and Functional Group Tolerance; 3.3 Metal Hydrides; Characterization; Synthesis; Reactions; Hydricity; Bridging Hydrides; 3.4 Sigma Complexes; Dihydrogen Complexes20; Characterization; Reactions; Agostic Species; 3.5 Bond Strengths; Supramolecular Interactions; References; Problems; 4: Carbonyls, Phosphines, and Substitution; 4.1 Metal Carbonyls Preparation of CarbonylsReactions of Carbonyls; Bridging Carbonyls; Isonitriles; Thiocarbonyls; Nitrosyls; Cyanide; Other CO Analogs; 4.2 Phosphines; Structure and Bonding; Tolman Electronic Parameter and Cone Angle; Bite Angle; 4.3 N-Heterocyclic Carbenes (NHCs); 4.4 Dissociative Substitution; Kinetics; Stereochemistry and Trans Effect; Electronic and Steric Factors; 4.5 Associative Substitution; Kinetics; Trans Effect; Solvent Participation; Ligand Rearrangements; 4.6 Redox Effects and Interchange Substitution; 17e and 19e Species; The Interchange Mechanism; 4.7 Photochemical Substitution Carbonyls |
| Record Nr. | UNINA-9910790935003321 |
Crabtree Robert H. <1948->
|
||
| Hoboken, New Jersey : , : Wiley, , 2014 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
The organometallic chemistry of the transition metals / / Robert H. Crabtree
| The organometallic chemistry of the transition metals / / Robert H. Crabtree |
| Autore | Crabtree Robert H. <1948-> |
| Edizione | [6th edition.] |
| Pubbl/distr/stampa | Hoboken, New Jersey : , : Wiley, , 2014 |
| Descrizione fisica | 1 online resource (522 p.) |
| Disciplina | 547/.056 |
| Soggetto topico |
Organometallic chemistry
Organotransition metal compounds Compostos organometàl·lics de transició |
| Soggetto genere / forma | Llibres electrònics |
| ISBN |
1-118-78824-9
1-118-78830-3 1-118-78844-3 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Cover; Title page; Copyright page; Contents; Preface; List of Abbreviations; 1: Introduction; 1.1 Why Study Organometallic Chemistry?; 1.2 Coordination Chemistry; 1.3 Werner Complexes; Stereochemistry; Chelate Effect; Werner's Coordination Theory; 1.4 The Trans Effect; 1.5 Soft versus Hard Ligands; 1.6 The Crystal Field; High Spin versus Low Spin; Inert versus Labile Coordination; Jahn-Teller Distortion; Low- versus High-Field Ligands; Magnetism and Nuclearity; Other Geometries; Isoconfigurational Ions; 1.7 The Ligand Field; 1.8 The sdn Model and Hypervalency; 1.9 Back Bonding
Frontier Orbitalsπ-Donor Ligands; 1.10 Electroneutrality; Oxidation State Trends; Periodic Trends; 1.11 Types of Ligand; Ambidentate Ligands; Actor and Spectator Ligands; Multifunctional Ligands29; Organometallic versus Coordination Compounds; References; Problems; 2: Making Sense of Organometallic Complexes; 2.1 The 18-Electron Rule; Covalent Electron Counting Model; Ionic Electron Counting Model; Electron Counts for Common Ligands and Hapticity; Bridging Ligands; Zero-Electron Ligands; 2.2 Limitations of The 18-Electron Rule; Steric Stabilization of Reactive Species Kinetic Stability from Bulky SubstituentsPreparation of Metal Alkyls; Cyclometalation; Oxidative Addition; Insertion; Bridging Alkyls; Metalacycles; η1 and η2-Acyl and Vinyls; 3.2 Other σ-Bonded Ligands; Group 14 Elements; Groups 15-17; Oxophilicity and Functional Group Tolerance; 3.3 Metal Hydrides; Characterization; Synthesis; Reactions; Hydricity; Bridging Hydrides; 3.4 Sigma Complexes; Dihydrogen Complexes20; Characterization; Reactions; Agostic Species; 3.5 Bond Strengths; Supramolecular Interactions; References; Problems; 4: Carbonyls, Phosphines, and Substitution; 4.1 Metal Carbonyls Preparation of CarbonylsReactions of Carbonyls; Bridging Carbonyls; Isonitriles; Thiocarbonyls; Nitrosyls; Cyanide; Other CO Analogs; 4.2 Phosphines; Structure and Bonding; Tolman Electronic Parameter and Cone Angle; Bite Angle; 4.3 N-Heterocyclic Carbenes (NHCs); 4.4 Dissociative Substitution; Kinetics; Stereochemistry and Trans Effect; Electronic and Steric Factors; 4.5 Associative Substitution; Kinetics; Trans Effect; Solvent Participation; Ligand Rearrangements; 4.6 Redox Effects and Interchange Substitution; 17e and 19e Species; The Interchange Mechanism; 4.7 Photochemical Substitution Carbonyls |
| Record Nr. | UNINA-9910809662703321 |
|
Crabtree Robert H. <1948->
|
||
| Hoboken, New Jersey : , : Wiley, , 2014 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
The organometallic chemistry of the transition metals / Robert H. Crabtree
| The organometallic chemistry of the transition metals / Robert H. Crabtree |
| Autore | Crabtree, Robert H. |
| Edizione | [5th ed.] |
| Pubbl/distr/stampa | Hoboken, N. J. : Wiley, c2009 |
| Descrizione fisica | xiii, 505 p. : ill. ; 25 cm |
| Disciplina | 547.05 |
| Soggetto topico | Organotransition metal compounds |
| ISBN | 9780470257623 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNISALENTO-991000306489707536 |
|
Crabtree, Robert H.
|
||
| Hoboken, N. J. : Wiley, c2009 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. del Salento | ||
| ||
Organotransition metal chemistry [[electronic resource] /] / G.R. Chatwal ; edited by M. Arora
| Organotransition metal chemistry [[electronic resource] /] / G.R. Chatwal ; edited by M. Arora |
| Autore | Chatwal G. R |
| Edizione | [1st ed.] |
| Pubbl/distr/stampa | Mumbai [India], : Himalaya Pub. House, 2010 |
| Descrizione fisica | 1 online resource (333 p.) |
| Disciplina | 547.056 |
| Altri autori (Persone) | AroraM |
| Soggetto topico | Organotransition metal compounds |
| Soggetto genere / forma | Electronic books. |
| ISBN |
1-282-80464-2
9786612804649 1-4416-7456-X 93-5043-169-6 600-00-3989-1 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
COVER; CONTENTS; CHAPTER 1 : INTRODUCTION; CHAPTER 2 : LIGANDS; CHAPTER 3 : CYCLOPENTADIENYL COMPLEX; CHAPTER 4 : ALKYLS AND ARYLS OF TRANSITION METALS; CHAPTER 5 : COMPOUNDS HAVING TRANSITION METAL-CARBON MULTIPLE BONDS; CHAPTER 6 : TRANSITION METAL n-COMPLEXES; CHAPTER 7 : TRANSITION METAL COMPOUNDS WITH BOND TO HYDROGEN; CHAPTER 8 : HOMOGENEOUS CATALYSIS; CHAPTER 9 : FISCHER CARBENE COMPLEXES; CHAPTER 10 : OXIDATIVE COUPLING AND REDUCTIVE ELIMINATION; CHAPTER 11 : OXIDATIVE ADDITION; CHAPTER 12 : MIGRATORY INSERTION REACTIONS; CHAPTER 13 : COUPLING REACTIONS
CHAPTER 14 : REACTIONS OF ORGANOMETALLIC COMPOUNDSCHAPTER 15 : FLUXIONALITY; CHAPTER 16 : FLUXIONAL ORGANOMETALLIC COMPOUNDS; APPENDIX |
| Altri titoli varianti | Metal chemistry |
| Record Nr. | UNINA-9910458773603321 |
|
Chatwal G. R
|
||
| Mumbai [India], : Himalaya Pub. House, 2010 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Organotransition metal chemistry [[electronic resource] /] / G.R. Chatwal ; edited by M. Arora
| Organotransition metal chemistry [[electronic resource] /] / G.R. Chatwal ; edited by M. Arora |
| Autore | Chatwal G. R |
| Edizione | [1st ed.] |
| Pubbl/distr/stampa | Mumbai [India], : Himalaya Pub. House, 2010 |
| Descrizione fisica | 1 online resource (333 p.) |
| Disciplina | 547.056 |
| Altri autori (Persone) | AroraM |
| Soggetto topico | Organotransition metal compounds |
| ISBN |
1-282-80464-2
9786612804649 1-4416-7456-X 93-5043-169-6 600-00-3989-1 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
COVER; CONTENTS; CHAPTER 1 : INTRODUCTION; CHAPTER 2 : LIGANDS; CHAPTER 3 : CYCLOPENTADIENYL COMPLEX; CHAPTER 4 : ALKYLS AND ARYLS OF TRANSITION METALS; CHAPTER 5 : COMPOUNDS HAVING TRANSITION METAL-CARBON MULTIPLE BONDS; CHAPTER 6 : TRANSITION METAL n-COMPLEXES; CHAPTER 7 : TRANSITION METAL COMPOUNDS WITH BOND TO HYDROGEN; CHAPTER 8 : HOMOGENEOUS CATALYSIS; CHAPTER 9 : FISCHER CARBENE COMPLEXES; CHAPTER 10 : OXIDATIVE COUPLING AND REDUCTIVE ELIMINATION; CHAPTER 11 : OXIDATIVE ADDITION; CHAPTER 12 : MIGRATORY INSERTION REACTIONS; CHAPTER 13 : COUPLING REACTIONS
CHAPTER 14 : REACTIONS OF ORGANOMETALLIC COMPOUNDSCHAPTER 15 : FLUXIONALITY; CHAPTER 16 : FLUXIONAL ORGANOMETALLIC COMPOUNDS; APPENDIX |
| Altri titoli varianti | Metal chemistry |
| Record Nr. | UNINA-9910785119003321 |
|
Chatwal G. R
|
||
| Mumbai [India], : Himalaya Pub. House, 2010 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Organotransition metal chemistry [[electronic resource] /] / G.R. Chatwal ; edited by M. Arora
| Organotransition metal chemistry [[electronic resource] /] / G.R. Chatwal ; edited by M. Arora |
| Autore | Chatwal G. R |
| Edizione | [1st ed.] |
| Pubbl/distr/stampa | Mumbai [India], : Himalaya Pub. House, 2010 |
| Descrizione fisica | 1 online resource (333 p.) |
| Disciplina | 547.056 |
| Altri autori (Persone) | AroraM |
| Soggetto topico | Organotransition metal compounds |
| ISBN |
1-282-80464-2
9786612804649 1-4416-7456-X 93-5043-169-6 600-00-3989-1 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
COVER; CONTENTS; CHAPTER 1 : INTRODUCTION; CHAPTER 2 : LIGANDS; CHAPTER 3 : CYCLOPENTADIENYL COMPLEX; CHAPTER 4 : ALKYLS AND ARYLS OF TRANSITION METALS; CHAPTER 5 : COMPOUNDS HAVING TRANSITION METAL-CARBON MULTIPLE BONDS; CHAPTER 6 : TRANSITION METAL n-COMPLEXES; CHAPTER 7 : TRANSITION METAL COMPOUNDS WITH BOND TO HYDROGEN; CHAPTER 8 : HOMOGENEOUS CATALYSIS; CHAPTER 9 : FISCHER CARBENE COMPLEXES; CHAPTER 10 : OXIDATIVE COUPLING AND REDUCTIVE ELIMINATION; CHAPTER 11 : OXIDATIVE ADDITION; CHAPTER 12 : MIGRATORY INSERTION REACTIONS; CHAPTER 13 : COUPLING REACTIONS
CHAPTER 14 : REACTIONS OF ORGANOMETALLIC COMPOUNDSCHAPTER 15 : FLUXIONALITY; CHAPTER 16 : FLUXIONAL ORGANOMETALLIC COMPOUNDS; APPENDIX |
| Altri titoli varianti | Metal chemistry |
| Record Nr. | UNINA-9910828248903321 |
|
Chatwal G. R
|
||
| Mumbai [India], : Himalaya Pub. House, 2010 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Organotransition metal chemistry : applications to organic synthesis / Stephen G. Davies
| Organotransition metal chemistry : applications to organic synthesis / Stephen G. Davies |
| Autore | Davies, Stephen G. |
| Pubbl/distr/stampa | Oxford : Pergamon Press, c1982 |
| Descrizione fisica | xv, 411 p. : ill. ; 24 cm |
| Disciplina | 547.2 |
| Collana | Organic chemistry series ; 2 |
| Soggetto topico |
Chemistry, Organic - Synthesis
Organic compounds - Synthesis Organometallic compounds Organotransition metal compounds Transition metal compounds |
| ISBN | 0080307140 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNISALENTO-991003534399707536 |
|
Davies, Stephen G.
|
||
| Oxford : Pergamon Press, c1982 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. del Salento | ||
| ||
Transition metal reagents and catalysts : innovations in organic synthesis / / Jiro Tsuji
| Transition metal reagents and catalysts : innovations in organic synthesis / / Jiro Tsuji |
| Autore | Tsuji Jiro <1927-> |
| Pubbl/distr/stampa | Chichester, West Sussex, England : , : John Wiley & Sons, Ltd, , [2000] |
| Descrizione fisica | 1 online resource (xv, 477 pages) : illustrations |
| Disciplina | 547.2 |
| Soggetto topico |
Transition metal catalysts
Chemical tests and reagents Organotransition metal compounds |
| ISBN |
9786610555659
0-470-85476-6 1-280-55565-3 0-470-85475-8 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNINA-9910143509203321 |
|
Tsuji Jiro <1927->
|
||
| Chichester, West Sussex, England : , : John Wiley & Sons, Ltd, , [2000] | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Transition metal reagents and catalysts : innovations in organic synthesis / / Jiro Tsuji
| Transition metal reagents and catalysts : innovations in organic synthesis / / Jiro Tsuji |
| Autore | Tsuji Jiro <1927-> |
| Pubbl/distr/stampa | Chichester, West Sussex, England : , : John Wiley & Sons, Ltd, , [2000] |
| Descrizione fisica | 1 online resource (xv, 477 pages) : illustrations |
| Disciplina | 547.2 |
| Soggetto topico |
Transition metal catalysts
Chemical tests and reagents Organotransition metal compounds |
| ISBN |
9786610555659
0-470-85476-6 1-280-55565-3 0-470-85475-8 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNINA-9910830215603321 |
|
Tsuji Jiro <1927->
|
||
| Chichester, West Sussex, England : , : John Wiley & Sons, Ltd, , [2000] | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
