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The chemistry of organic silicon compounds / / edited by Saul Patai and Zvi Rappoport [[electronic resource]]
| The chemistry of organic silicon compounds / / edited by Saul Patai and Zvi Rappoport [[electronic resource]] |
| Autore | Patai Saul |
| Pubbl/distr/stampa | Chichester [England] ; ; New York, : Wiley, 1989 |
| Descrizione fisica | 1 online resource (2 v. (xvi, 1668 p.) ) : ill. ; |
| Disciplina | 547/.08 |
| Altri autori (Persone) |
RappoportZvi
PataiSaul ApeloigYitzhak |
| Collana |
The Chemistry of functional groups The chemistry of organic silicon compounds
The Chemistry of functional groups |
| Soggetto topico |
Organosilicon compounds
Composés organosiliciés |
| Soggetto genere / forma | Electronic books |
| Soggetto non controllato | Organic silicon compounds |
| ISBN |
1-280-55441-X
9786610554416 0-470-02510-7 |
| Formato | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
v. 1. 1989. [pt. 1.] Historical overview and comparison of silicon with carbon / Joyce Y. Corey -- Theoretical aspects of organosilicon compounds / Yitzhak Apeloig -- Structural chemistry of organic silicon compounds / W.S. Sheldrick -- Dynamic stereochemistry at silicon / Robert J.P. Corriu, Christian Guerin and Joel J.E. Moreau -- Thermochemistry / R. Walsh -- Analysis of organosilicon compounds / T.R. Crompton -- Positive and negative ion chemistry of silicon-containing molecules in the gas phase / Helmut Schwarz -- NMR spectroscopy of organosilicon compounds / Elizabeth A. Williams -- Photoelectron Spectra of Silicon Compounds / H. Bock and B. Solouki -- General synthetic pathways to organosilicon compounds / Leonhard Birkofer and Oskar Stuhl -- Recent synthetic applications of organosilanes / Gerald L. Larson -- Acidity, basicity and complex formation of organosilicon compounds / Alan R. Bassindale and Peter G. Taylor -- Reaction mechanisms of nucleophilic attack at silicon / Alan R. Bassindale and Peter G. Taylor -- [pt. 2.] Activating and directive effects of silicon / Alan R. Bassindale and Peter G. Taylor -- The photochemistry of organosilicon compounds / A.G. Brook -- Trivalent silyl ions / Joseph B. Lambert and W.J. Schulz -- Multiple bonds to silicon / Gerhard Raabe and Josef Michl -- Bioorganosilicon chemistry / Reinhold Tacke and Haryanto Linoh -- Polysilanes / Robert West -- Hypervalent silicon compounds / Robert J.P. Corriu and J. Colin Young -- Siloxane polymers and copolymers / T.C. Kendrick, B. Parbhoo and J.W. White -- Organosilicon derivatives of phosphorus, arsenic, antimony and bismuth / D.A. ("Fred") Armitage -- Chemistry of compounds with silicon-sulphur, silicon-selenium and silicon-tellurium bonds / D.A. ("Fred") Armitage -- Transition-metal silyl derivatives / T. Don Tilley -- The hydrosilylation reaction / Iwao Ojima.
v. 2. 1998. [pt. 1.] Theoretical aspects and quantum mechanical calculations of silaaromatic compounds / Yitzhak Apeloig and Miriam Karni -- A molecular modeling of the bonded interactions of crystalline silica / G.V. Gibbs and M.B. Boisen -- Polyhedral silicon compounds / Akira Sekiguchi and Shigeru Nagase -- Thermochemistry / Rosa Becerra and Robin Walsh -- The structural chemistry of organosilicon compounds / Menahem Kaftory, Moshe Kapon and Mark Botoshansky -- ²⁹Si NMR spectroscopy of organosilicon compounds / Yoshito Takeuchi and Toshio Takayama -- Activating and directive effects of silicon / Alan R. Bassindale, Simon J. Glynn and Peter G. Taylor -- Steric effects of silyl groups / Jih Ru Hwu, Shwu-Chen Tsay and Buh-Luen Cheng -- Reaction mechanisms of nucleophilic attack at silicon / Alan R. Bassindale, Simon J. Glynn and Peter G. Taylor -- Silicenium ions : quantum chemical computations / Christoph Maerker and Paul von Ragué Schleyer -- Silicenium ions : experimental aspects / Paul D. Lickiss -- Silyl-substituted carbocations / Hans-Ullrich Siehl and Thomas Müller -- Silicon-substituted carbenes / Gerhard Maas -- Alkaline and alkaline earth silyl compounds preparation and structure / Johannes Belzner and Uwe Dehnert -- Mechanism and structures in alcohol addition reactions of disilenes and silenes / Hideki Sakurai -- [pt. 2.] Silicon-carbon and silicon-nitrogen multiply bonded compounds / Thomas Müller, Wolfgang Ziche and Norbert Auner -- Recent advances in the chemistry of silicon-heteroatom multiple bonds / Norihiro Tokitoh and Renji Okazaki -- Gas-phase ion chemistry of silicon-containing molecules / Norman Goldberg and Helmut Schwarz -- Matrix isolation studies of silicon compounds -- Günther Maier [and others] -- Electrochemistry of organosilicon compounds / Toshio Fuchigami -- The photochemistry of organosilicon compounds / A.G. Brook -- Mechanistic aspects of the photochemistry of organosilicon compounds / Mitsuo Kira and Takashi Miyazawa -- Hypervalent silicon compounds / Daniel Kost and Inna Kalikhman -- Silatranes and their tricyclic analogs / Vadim Pestunovich, Svetlana Kirpichenko and Mikhail Voronkov -- Tris(trimethylsilyl)silane in organic synthesis / C. Chatgilialoglu, C. Ferreri and T. Gimisis -- Recent advances in the direct process / Larry N. Lewis -- Acyl silanes / Philip C. Bulman Page, Michael J. McKenzie, Sukhbinder S. Klair and Stephen Rosenthal -- Recent synthetic applications of organosilicon reagents / Ernest W. Colvin -- Recent advances in the hydrosilylation and related reactions / Iwao Ojima, Zhaoyang Li and Jiawang Zhu -- [pt. 3.] Synthetic applications of allylsilanes and vinylsilanes / Tien-Yau Luh and Shiuh-Tzung Liu -- Chemistry of compounds with silicon-sulphur, silicon-selenium and silicon-tellurium bonds / D.A. ("Fred") Armitage -- Cyclic polychalcogenide compounds with silicon / Nami Choi and Wataru Ando -- Organosilicon derivatives of fullerenes / Wataru Ando and Takahiro Kusukawa -- Group 14 metalloles, ionic species and coordination compounds / Jacques Dubac, Christian Guérin and Philippe Meunier -- Transition-metal silyl complexes / Moris S. Eisen -- Cyclopentadienyl silicon compounds / Peter Jutzi -- Recent advances in the chemistry of cyclopolysilanes / Edwin Hengge and Harald Stüger -- Recent advances in the chemistry of siloxane polymers and copolymers / Robert Drake, Iain MacKinnon and Richard Taylor -- Si-containing ceramic precursors / R.M. Laine and A. Sellinger -- Organo-silica sol-gel materials / David Avnir, Lisa C. Klein, David Levy, Ulrich Schubert and Anna B. Wojcik -- Chirality in bioorganosilicon chemistry / Reinhold Tacke and Stephan A. Wagner -- Highly reactive small-ring monosilacycles and medium-ring oligosilacycles / Wataru Ando and Yoshio -- Silylenes / Peter P. Gaspar and Robert West. v. 3. 2001. Theoretical aspects of compounds containing Si, Ge, Sn and Pb / Miriam Karni, Yitzhak Apeloig, Jürgen Kapp and Paul von R. Schleyer -- (Helium I)-photoelectron spectra of silicon compounds : history and achievements concerning their molecular states / H. Bock and B. Solouki -- ²⁹Si NMR experiments in solutions of organosilicon compounds / Jan Schraml -- Silyl radicals / C. Chatgilialoglu and C.H. Schiesser -- Recent advances in the chemistry of silicon-silicon multiple bonds / Manfred Weidenbruch -- Recent developments in the chemistry of compounds with silicon-nitrogen bonds / Peter Neugebauer, Bettina Jaschke and Uwe Klingebiel -- Organosilicon halides : synthesis and properties / Uwe Herzog -- Synthesis of multiply bonded phosphorus compounds using silylphosphines and silylphosphides / Masaaki Yoshifuji and Kozo Toyota -- Polysilanes : conformations, chromotropism and conductivity / Robert West -- Nanostructured hybrid organic-inorganic solids : from molecules to materials / Bruno Boury and Robert J.P. Corriu -- Polysiloles and related silole-containing polymers / Shigehiro Yamaguchi and Kohei Tamao -- Polysilanols / Paul D. Lickiss -- Silicon-based dendrimers and hyperbranched polymers / David Y. Son -- Biotechnology reveals new routes to synthesis and structural control of silica and polysilsesquioxanes / Daniel E. Morse -- Chemistry on silicon surfaces / Cheol Ho Choi and Mark S. Gordon -- Silyl migrations / Mitsuo Kira and Takeaki Iwamoto -- Kinetic studies of the reactions of Si=C and Si=Si bonds / Tracy L. Morkin, Thomas R. Owens and William J. Leigh -- Ion-molecule reactions of silicon cations / Simonetta Fornarini. |
| Record Nr. | UNINA-9910146066303321 |
Patai Saul
|
||
| Chichester [England] ; ; New York, : Wiley, 1989 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
The chemistry of organic silicon compounds / / edited by Saul Patai and Zvi Rappoport [[electronic resource]]
| The chemistry of organic silicon compounds / / edited by Saul Patai and Zvi Rappoport [[electronic resource]] |
| Autore | Patai Saul |
| Pubbl/distr/stampa | Chichester [England] ; ; New York, : Wiley, 1989 |
| Descrizione fisica | 1 online resource (2 v. (xvi, 1668 p.) ) : ill. ; |
| Disciplina | 547/.08 |
| Altri autori (Persone) |
RappoportZvi
PataiSaul ApeloigYitzhak |
| Collana |
The Chemistry of functional groups The chemistry of organic silicon compounds
The Chemistry of functional groups |
| Soggetto topico |
Organosilicon compounds
Composés organosiliciés |
| Soggetto non controllato | Organic silicon compounds |
| ISBN |
1-280-55441-X
9786610554416 0-470-02510-7 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
v. 1. 1989. [pt. 1.] Historical overview and comparison of silicon with carbon / Joyce Y. Corey -- Theoretical aspects of organosilicon compounds / Yitzhak Apeloig -- Structural chemistry of organic silicon compounds / W.S. Sheldrick -- Dynamic stereochemistry at silicon / Robert J.P. Corriu, Christian Guerin and Joel J.E. Moreau -- Thermochemistry / R. Walsh -- Analysis of organosilicon compounds / T.R. Crompton -- Positive and negative ion chemistry of silicon-containing molecules in the gas phase / Helmut Schwarz -- NMR spectroscopy of organosilicon compounds / Elizabeth A. Williams -- Photoelectron Spectra of Silicon Compounds / H. Bock and B. Solouki -- General synthetic pathways to organosilicon compounds / Leonhard Birkofer and Oskar Stuhl -- Recent synthetic applications of organosilanes / Gerald L. Larson -- Acidity, basicity and complex formation of organosilicon compounds / Alan R. Bassindale and Peter G. Taylor -- Reaction mechanisms of nucleophilic attack at silicon / Alan R. Bassindale and Peter G. Taylor -- [pt. 2.] Activating and directive effects of silicon / Alan R. Bassindale and Peter G. Taylor -- The photochemistry of organosilicon compounds / A.G. Brook -- Trivalent silyl ions / Joseph B. Lambert and W.J. Schulz -- Multiple bonds to silicon / Gerhard Raabe and Josef Michl -- Bioorganosilicon chemistry / Reinhold Tacke and Haryanto Linoh -- Polysilanes / Robert West -- Hypervalent silicon compounds / Robert J.P. Corriu and J. Colin Young -- Siloxane polymers and copolymers / T.C. Kendrick, B. Parbhoo and J.W. White -- Organosilicon derivatives of phosphorus, arsenic, antimony and bismuth / D.A. ("Fred") Armitage -- Chemistry of compounds with silicon-sulphur, silicon-selenium and silicon-tellurium bonds / D.A. ("Fred") Armitage -- Transition-metal silyl derivatives / T. Don Tilley -- The hydrosilylation reaction / Iwao Ojima.
v. 2. 1998. [pt. 1.] Theoretical aspects and quantum mechanical calculations of silaaromatic compounds / Yitzhak Apeloig and Miriam Karni -- A molecular modeling of the bonded interactions of crystalline silica / G.V. Gibbs and M.B. Boisen -- Polyhedral silicon compounds / Akira Sekiguchi and Shigeru Nagase -- Thermochemistry / Rosa Becerra and Robin Walsh -- The structural chemistry of organosilicon compounds / Menahem Kaftory, Moshe Kapon and Mark Botoshansky -- ²⁹Si NMR spectroscopy of organosilicon compounds / Yoshito Takeuchi and Toshio Takayama -- Activating and directive effects of silicon / Alan R. Bassindale, Simon J. Glynn and Peter G. Taylor -- Steric effects of silyl groups / Jih Ru Hwu, Shwu-Chen Tsay and Buh-Luen Cheng -- Reaction mechanisms of nucleophilic attack at silicon / Alan R. Bassindale, Simon J. Glynn and Peter G. Taylor -- Silicenium ions : quantum chemical computations / Christoph Maerker and Paul von Ragué Schleyer -- Silicenium ions : experimental aspects / Paul D. Lickiss -- Silyl-substituted carbocations / Hans-Ullrich Siehl and Thomas Müller -- Silicon-substituted carbenes / Gerhard Maas -- Alkaline and alkaline earth silyl compounds preparation and structure / Johannes Belzner and Uwe Dehnert -- Mechanism and structures in alcohol addition reactions of disilenes and silenes / Hideki Sakurai -- [pt. 2.] Silicon-carbon and silicon-nitrogen multiply bonded compounds / Thomas Müller, Wolfgang Ziche and Norbert Auner -- Recent advances in the chemistry of silicon-heteroatom multiple bonds / Norihiro Tokitoh and Renji Okazaki -- Gas-phase ion chemistry of silicon-containing molecules / Norman Goldberg and Helmut Schwarz -- Matrix isolation studies of silicon compounds -- Günther Maier [and others] -- Electrochemistry of organosilicon compounds / Toshio Fuchigami -- The photochemistry of organosilicon compounds / A.G. Brook -- Mechanistic aspects of the photochemistry of organosilicon compounds / Mitsuo Kira and Takashi Miyazawa -- Hypervalent silicon compounds / Daniel Kost and Inna Kalikhman -- Silatranes and their tricyclic analogs / Vadim Pestunovich, Svetlana Kirpichenko and Mikhail Voronkov -- Tris(trimethylsilyl)silane in organic synthesis / C. Chatgilialoglu, C. Ferreri and T. Gimisis -- Recent advances in the direct process / Larry N. Lewis -- Acyl silanes / Philip C. Bulman Page, Michael J. McKenzie, Sukhbinder S. Klair and Stephen Rosenthal -- Recent synthetic applications of organosilicon reagents / Ernest W. Colvin -- Recent advances in the hydrosilylation and related reactions / Iwao Ojima, Zhaoyang Li and Jiawang Zhu -- [pt. 3.] Synthetic applications of allylsilanes and vinylsilanes / Tien-Yau Luh and Shiuh-Tzung Liu -- Chemistry of compounds with silicon-sulphur, silicon-selenium and silicon-tellurium bonds / D.A. ("Fred") Armitage -- Cyclic polychalcogenide compounds with silicon / Nami Choi and Wataru Ando -- Organosilicon derivatives of fullerenes / Wataru Ando and Takahiro Kusukawa -- Group 14 metalloles, ionic species and coordination compounds / Jacques Dubac, Christian Guérin and Philippe Meunier -- Transition-metal silyl complexes / Moris S. Eisen -- Cyclopentadienyl silicon compounds / Peter Jutzi -- Recent advances in the chemistry of cyclopolysilanes / Edwin Hengge and Harald Stüger -- Recent advances in the chemistry of siloxane polymers and copolymers / Robert Drake, Iain MacKinnon and Richard Taylor -- Si-containing ceramic precursors / R.M. Laine and A. Sellinger -- Organo-silica sol-gel materials / David Avnir, Lisa C. Klein, David Levy, Ulrich Schubert and Anna B. Wojcik -- Chirality in bioorganosilicon chemistry / Reinhold Tacke and Stephan A. Wagner -- Highly reactive small-ring monosilacycles and medium-ring oligosilacycles / Wataru Ando and Yoshio -- Silylenes / Peter P. Gaspar and Robert West. v. 3. 2001. Theoretical aspects of compounds containing Si, Ge, Sn and Pb / Miriam Karni, Yitzhak Apeloig, Jürgen Kapp and Paul von R. Schleyer -- (Helium I)-photoelectron spectra of silicon compounds : history and achievements concerning their molecular states / H. Bock and B. Solouki -- ²⁹Si NMR experiments in solutions of organosilicon compounds / Jan Schraml -- Silyl radicals / C. Chatgilialoglu and C.H. Schiesser -- Recent advances in the chemistry of silicon-silicon multiple bonds / Manfred Weidenbruch -- Recent developments in the chemistry of compounds with silicon-nitrogen bonds / Peter Neugebauer, Bettina Jaschke and Uwe Klingebiel -- Organosilicon halides : synthesis and properties / Uwe Herzog -- Synthesis of multiply bonded phosphorus compounds using silylphosphines and silylphosphides / Masaaki Yoshifuji and Kozo Toyota -- Polysilanes : conformations, chromotropism and conductivity / Robert West -- Nanostructured hybrid organic-inorganic solids : from molecules to materials / Bruno Boury and Robert J.P. Corriu -- Polysiloles and related silole-containing polymers / Shigehiro Yamaguchi and Kohei Tamao -- Polysilanols / Paul D. Lickiss -- Silicon-based dendrimers and hyperbranched polymers / David Y. Son -- Biotechnology reveals new routes to synthesis and structural control of silica and polysilsesquioxanes / Daniel E. Morse -- Chemistry on silicon surfaces / Cheol Ho Choi and Mark S. Gordon -- Silyl migrations / Mitsuo Kira and Takeaki Iwamoto -- Kinetic studies of the reactions of Si=C and Si=Si bonds / Tracy L. Morkin, Thomas R. Owens and William J. Leigh -- Ion-molecule reactions of silicon cations / Simonetta Fornarini. |
| Record Nr. | UNINA-9910830262403321 |
|
Patai Saul
|
||
| Chichester [England] ; ; New York, : Wiley, 1989 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Ionic and organometallic-catalyzed organosilane reductions [[electronic resource] /] / Gerald L. Larson and James L. Fry
| Ionic and organometallic-catalyzed organosilane reductions [[electronic resource] /] / Gerald L. Larson and James L. Fry |
| Autore | Larson G. L (Gerald L.) |
| Pubbl/distr/stampa | Hoboken, NJ, : Wiley, c2010 |
| Descrizione fisica | 1 online resource (768 p.) |
| Disciplina | 547.08 |
| Altri autori (Persone) | FryJames L |
| Collana | Organic Reactions |
| Soggetto topico |
Organosilicon compounds
Silicon compounds |
| ISBN |
1-282-45532-X
9786612455322 0-470-09899-6 0-470-57268-X 0-470-57267-1 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto | Ionic and Organometallic-Catalyzed Organosilane Reductions; CONTENTS; FOREWORD; PREFACE; IONIC AND ORGANOMETALLIC-CATALYZED ORGANOSILANE REDUCTIONS; INDEX |
| Record Nr. | UNINA-9910139984803321 |
|
Larson G. L (Gerald L.)
|
||
| Hoboken, NJ, : Wiley, c2010 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Ionic and organometallic-catalyzed organosilane reductions [[electronic resource] /] / Gerald L. Larson and James L. Fry
| Ionic and organometallic-catalyzed organosilane reductions [[electronic resource] /] / Gerald L. Larson and James L. Fry |
| Autore | Larson G. L (Gerald L.) |
| Pubbl/distr/stampa | Hoboken, NJ, : Wiley, c2010 |
| Descrizione fisica | 1 online resource (768 p.) |
| Disciplina | 547.08 |
| Altri autori (Persone) | FryJames L |
| Collana | Organic Reactions |
| Soggetto topico |
Organosilicon compounds
Silicon compounds |
| ISBN |
1-282-45532-X
9786612455322 0-470-09899-6 0-470-57268-X 0-470-57267-1 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto | Ionic and Organometallic-Catalyzed Organosilane Reductions; CONTENTS; FOREWORD; PREFACE; IONIC AND ORGANOMETALLIC-CATALYZED ORGANOSILANE REDUCTIONS; INDEX |
| Record Nr. | UNINA-9910816987303321 |
|
Larson G. L (Gerald L.)
|
||
| Hoboken, NJ, : Wiley, c2010 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Organosilanes in radical chemistry [[electronic resource] /] / Chryssostomos Chatgilialoglu
| Organosilanes in radical chemistry [[electronic resource] /] / Chryssostomos Chatgilialoglu |
| Autore | Chatgilialoglu Chryssostomos |
| Pubbl/distr/stampa | West Sussex, England, : Wiley, c2004 |
| Descrizione fisica | 1 online resource (241 p.) |
| Disciplina |
547
547.08 547/.08 |
| Soggetto topico |
Organosilicon compounds
Free radicals (Chemistry) |
| Soggetto genere / forma | Electronic books. |
| ISBN |
1-280-26956-1
9786610269563 0-470-09425-7 0-470-02475-5 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Organosilanes in Radical Chemistry; CONTENTS; Preface; Acknowledgements; 1 Formation and Structures of Silyl Radicals; 1.1 Methods of Generation of Silyl Radicals; 1.2 Structural Properties of Silyl Radicals; 1.2.1 Chemical Studies; 1.2.2 Electron Paramagnetic Resonance (EPR) Spectra; 1.2.3 Crystal Structures; 1.2.4 UV-Visible Spectra; 1.2.5 Theoretical Studies; 1.3 References; 2 Thermochemistry; 2.1 General Considerations; 2.2 Bond Dissociation Enthalpies; 2.2.1 Radical Kinetics; 2.2.2 Photoacoustic Calorimetry; 2.2.3 Theoretical Data; 2.2.4 Derived Bond Dissociation Energies
2.3 Ion Thermochemistry2.3.1 Negative-ion Cycles; 2.3.2 Hydride-affinity Cycles; 2.4 References; 3 Hydrogen Donor Abilities of Silicon Hydrides; 3.1 Carbon-centred Radicals; 3.1.1 Primary Alkyl Radicals and Free-Radical Clock Methodology; 3.1.2 Other Types of Carbon-centred Radicals; 3.2 Nitrogen-centred Radicals; 3.3 Oxygen-centred Radicals; 3.3.1 Alkoxyl Radicals; 3.3.2 Peroxyl Radicals; 3.3.3 Aryloxyl and Aroyloxyl Radicals; 3.4 Sulfur-centred Radicals; 3.5 Ketone Triplets; 3.6 Hydrogen Atom: An Example of Gas-phase Kinetics; 3.7 Theoretical Approaches; 3.8 References; 4 Reducing Agents 4.1 General Aspects of Radical Chain Reactions4.1.1 Radical-Radical Reactions; 4.2 Radical Initiators; 4.3 Tris(trimethylsilyl)silane; 4.3.1 Dehalogenations; 4.3.2 Reductive Removal of Chalcogen Groups (RS and RSe); 4.3.3 Deoxygenation of Alcohols (Barton-McCombie Reaction); 4.3.4 Miscellaneous Reactions; 4.3.5 Appendix; 4.4 Other Silicon Hydrides; 4.4.1 Trialkylsilanes; 4.4.2 Phenyl Substituted Silicon Hydrides; 4.4.3 Silyl Substituted Silicon Hydrides; 4.4.4 Alkylthio Substituted Silicon Hydrides; 4.5 Silicon Hydride/Thiol Mixture; 4.6 Silanethiols; 4.7 Silylated Cyclohexadienes 4.8 References5 Addition to Unsaturated Bonds; 5.1 Carbon-Carbon Double Bonds; 5.1.1 Formation of Silyl Radical Adducts; 5.1.2 Hydrosilylation of Alkenes; 5.2 Carbon-Carbon Triple Bonds; 5.2.1 Formation of Silyl Radical Adducts; 5.2.2 Hydrosilylation of Alkynes; 5.3 Carbon-Oxygen Double Bonds; 5.3.1 Formation of Silyl Radical Adducts; 5.3.2 Hydrosilylation of Carbonyl Groups; 5.3.3 Radical Brook Rearrangement; 5.4 Other Carbon-Heteroatom Multiple Bonds; 5.5 Cumulenes and Hetero-Cumulenes; 5.6 Heteroatom-Heteroatom Multiple Bonds; 5.7 References; 6 Unimolecular Reactions 6.1 Cyclization Reactions of Silyl Radicals6.1.1 Five-membered Ring Expansion; 6.2 Aryl Migration; 6.3 Acyloxy Migration; 6.4 Intramolecular Homolytic Substitution at Silicon; 6.5 Homolytic Organosilicon Group Transfer; 6.6 References; 7 Consecutive Radical Reactions; 7.1 Basic Concepts of Carbon-Carbon Bond Formation; 7.2 Intermolecular Formation of Carbon-Carbon Bonds; 7.3 Intramolecular Formation of Carbon-Carbon Bonds (Cyclizations); 7.3.1 Construction of Carbocycles; 7.3.2 Construction of Cyclic Ethers and Lactones; 7.3.3 Construction of Cyclic Amines and Lactames 7.4 Formation of Carbon-Heteroatom Bonds |
| Record Nr. | UNINA-9910146249703321 |
|
Chatgilialoglu Chryssostomos
|
||
| West Sussex, England, : Wiley, c2004 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Organosilanes in radical chemistry [[electronic resource] /] / Chryssostomos Chatgilialoglu
| Organosilanes in radical chemistry [[electronic resource] /] / Chryssostomos Chatgilialoglu |
| Autore | Chatgilialoglu Chryssostomos |
| Pubbl/distr/stampa | West Sussex, England, : Wiley, c2004 |
| Descrizione fisica | 1 online resource (241 p.) |
| Disciplina |
547
547.08 547/.08 |
| Soggetto topico |
Organosilicon compounds
Free radicals (Chemistry) |
| ISBN |
1-280-26956-1
9786610269563 0-470-09425-7 0-470-02475-5 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Organosilanes in Radical Chemistry; CONTENTS; Preface; Acknowledgements; 1 Formation and Structures of Silyl Radicals; 1.1 Methods of Generation of Silyl Radicals; 1.2 Structural Properties of Silyl Radicals; 1.2.1 Chemical Studies; 1.2.2 Electron Paramagnetic Resonance (EPR) Spectra; 1.2.3 Crystal Structures; 1.2.4 UV-Visible Spectra; 1.2.5 Theoretical Studies; 1.3 References; 2 Thermochemistry; 2.1 General Considerations; 2.2 Bond Dissociation Enthalpies; 2.2.1 Radical Kinetics; 2.2.2 Photoacoustic Calorimetry; 2.2.3 Theoretical Data; 2.2.4 Derived Bond Dissociation Energies
2.3 Ion Thermochemistry2.3.1 Negative-ion Cycles; 2.3.2 Hydride-affinity Cycles; 2.4 References; 3 Hydrogen Donor Abilities of Silicon Hydrides; 3.1 Carbon-centred Radicals; 3.1.1 Primary Alkyl Radicals and Free-Radical Clock Methodology; 3.1.2 Other Types of Carbon-centred Radicals; 3.2 Nitrogen-centred Radicals; 3.3 Oxygen-centred Radicals; 3.3.1 Alkoxyl Radicals; 3.3.2 Peroxyl Radicals; 3.3.3 Aryloxyl and Aroyloxyl Radicals; 3.4 Sulfur-centred Radicals; 3.5 Ketone Triplets; 3.6 Hydrogen Atom: An Example of Gas-phase Kinetics; 3.7 Theoretical Approaches; 3.8 References; 4 Reducing Agents 4.1 General Aspects of Radical Chain Reactions4.1.1 Radical-Radical Reactions; 4.2 Radical Initiators; 4.3 Tris(trimethylsilyl)silane; 4.3.1 Dehalogenations; 4.3.2 Reductive Removal of Chalcogen Groups (RS and RSe); 4.3.3 Deoxygenation of Alcohols (Barton-McCombie Reaction); 4.3.4 Miscellaneous Reactions; 4.3.5 Appendix; 4.4 Other Silicon Hydrides; 4.4.1 Trialkylsilanes; 4.4.2 Phenyl Substituted Silicon Hydrides; 4.4.3 Silyl Substituted Silicon Hydrides; 4.4.4 Alkylthio Substituted Silicon Hydrides; 4.5 Silicon Hydride/Thiol Mixture; 4.6 Silanethiols; 4.7 Silylated Cyclohexadienes 4.8 References5 Addition to Unsaturated Bonds; 5.1 Carbon-Carbon Double Bonds; 5.1.1 Formation of Silyl Radical Adducts; 5.1.2 Hydrosilylation of Alkenes; 5.2 Carbon-Carbon Triple Bonds; 5.2.1 Formation of Silyl Radical Adducts; 5.2.2 Hydrosilylation of Alkynes; 5.3 Carbon-Oxygen Double Bonds; 5.3.1 Formation of Silyl Radical Adducts; 5.3.2 Hydrosilylation of Carbonyl Groups; 5.3.3 Radical Brook Rearrangement; 5.4 Other Carbon-Heteroatom Multiple Bonds; 5.5 Cumulenes and Hetero-Cumulenes; 5.6 Heteroatom-Heteroatom Multiple Bonds; 5.7 References; 6 Unimolecular Reactions 6.1 Cyclization Reactions of Silyl Radicals6.1.1 Five-membered Ring Expansion; 6.2 Aryl Migration; 6.3 Acyloxy Migration; 6.4 Intramolecular Homolytic Substitution at Silicon; 6.5 Homolytic Organosilicon Group Transfer; 6.6 References; 7 Consecutive Radical Reactions; 7.1 Basic Concepts of Carbon-Carbon Bond Formation; 7.2 Intermolecular Formation of Carbon-Carbon Bonds; 7.3 Intramolecular Formation of Carbon-Carbon Bonds (Cyclizations); 7.3.1 Construction of Carbocycles; 7.3.2 Construction of Cyclic Ethers and Lactones; 7.3.3 Construction of Cyclic Amines and Lactames 7.4 Formation of Carbon-Heteroatom Bonds |
| Record Nr. | UNINA-9910829802503321 |
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Chatgilialoglu Chryssostomos
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| West Sussex, England, : Wiley, c2004 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
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Organosilicon chemistry : novel approaches and reactions / / edited by Tamejiro Hiyama, Martin Oestreich
| Organosilicon chemistry : novel approaches and reactions / / edited by Tamejiro Hiyama, Martin Oestreich |
| Autore | Hiyama Tamejiro |
| Pubbl/distr/stampa | Weinheim, Germany : , : Wiley-VCH, , [2019] |
| Descrizione fisica | 1 online resource (569 pages) |
| Disciplina | 547.08 |
| Soggetto topico | Organosilicon compounds |
| Soggetto genere / forma | Electronic books. |
| ISBN |
3-527-81477-9
1-5231-3315-5 3-527-81478-7 3-527-81475-2 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNINA-9910554853503321 |
|
Hiyama Tamejiro
|
||
| Weinheim, Germany : , : Wiley-VCH, , [2019] | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Organosilicon chemistry : novel approaches and reactions / / edited by Tamejiro Hiyama, Martin Oestreich
| Organosilicon chemistry : novel approaches and reactions / / edited by Tamejiro Hiyama, Martin Oestreich |
| Autore | Hiyama Tamejiro |
| Pubbl/distr/stampa | Weinheim, Germany : , : Wiley-VCH, , [2019] |
| Descrizione fisica | 1 online resource (569 pages) |
| Disciplina | 547.08 |
| Soggetto topico | Organosilicon compounds |
| ISBN |
3-527-81477-9
1-5231-3315-5 3-527-81478-7 3-527-81475-2 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNINA-9910830900103321 |
|
Hiyama Tamejiro
|
||
| Weinheim, Germany : , : Wiley-VCH, , [2019] | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Organosilicon chemistry . III : from molecules to materials / / edited by Norbert Auner and Johann Weis
| Organosilicon chemistry . III : from molecules to materials / / edited by Norbert Auner and Johann Weis |
| Pubbl/distr/stampa | Weinheim, [Germany] : , : Wiley-VCH, , 1998 |
| Descrizione fisica | 1 online resource (744 p.) |
| Disciplina | 547.08 |
| Soggetto topico | Organosilicon compounds |
| Soggetto genere / forma | Electronic books. |
| ISBN |
1-281-76470-1
9786611764708 3-527-61990-9 3-527-62074-5 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | ger |
| Nota di contenuto |
Organosilicon Chemistry III, from Molecules to Materials; Contents; I. Fascinating Organosilicon Compounds; Introduction; More Compelling Evidence that Silicon is Better Than Carbon: The Thermal Isomerization of Olefins to Carbenes; NMR and Quantum Chemical Characterization of Silicon-Substituted Carbocations; Matrix Isolation Studies of the Reactions of Silicon Atoms; Cycloaddition Reactions of Dimethylaminomethylsilylene with Dienes and Heterodienes; Do Unsubstituted Silacyclobutadienes Exist?; A Thermally Stable Silylene: Reactivity of the Bis(amino)silylene Si[{N(CH2tBu))2}C6H4-1,2]
Pyrido[b]- 1 ,3,2λ2-diazasilole: The First Stable Unsymmetrical SilyleneA New Route to Silaheterocycles: Heterobutadiene Cycloaddition; Base Coordination: A Way to Nucleophilic Silylenes?; Isoelectronic Replacement of Si by P+: A Comparative Study of the Structures of the Spirocyclic EII Compounds E[C(PMe2)2(X)]2 (E = Si, Ge, Sn; X = PMe2,SiMes) and a Novel Spirocyclic 10 e-Phosphorus Cation(Pm) P[C(PPh2)2(SiMe3)]2+; The Main Group Carbonyls mi-CO and R2Si-CO: An Ab Initio Study Unprecedented Multistep Reactions of Decamethylsilicocene, (Me5Cs)zSi:, with C02, CSZ, COS, RNCS (R = Me, Ph), with CF3CCCF3, and with HMn(C0)5Rearrangement of Bis(hypersilyl)silylene and Related Compounds - An Unusual Way to Three-Membered Rings; Oxidation of Silenes and Silylenes: Matrix Isolation of Unusual Silicon Species; New Silaheterocycles: Formation and Properties; Cycloaddition Reactions of 1,l-Dichloro-2-neopentylsilene with Monoterpenes; Silaspirocycles as Precursors for a 2-Silaallene; Catalytic Carbon-Carbon Hydrogenation of Silicon-Functionalized Olefins Dieno- and Enophilicity of Sila-, Germa-, and StannaethenesIminosilanes and Silaamidides: Synthesis and Reactions; Metastable Compounds Containing Silicon-Phosphorus and Silicon-Arsenic Multiple Bonds: Syntheses, Structures and Reactivity; Silole and Germole Dianions and their Dilithium Derivatives - Are they Aromatic?; Supersilylmetal Compounds; Trialkylsilyl Substituted Homobimetallic Phosphanides of the Alkaline Earth Metals as well as Zinc; The Tris(trimethylsily1)silyl Substituent: An Old Hat With A New Feather Functionalized Trisilylmethanes and Trisilylsilanes as Precursors of a New Class of Tripodal Amido LigandsMethoxy-bis[tris(trimethylsilyl)silyl]methane: The First Geminal Di(hypersily1) Compound; The Use of the Tris(trimethylsily1)silyl Group in Stabilization of Low Valent Gallium Compounds; Synthesis, Structure, and Reactions of Tris(trimethylsi1yl)silyl Gallanes and Gallates; Novel Pathways in the Reactions of Vinylsilanes with Lithium Metal; New Organosilicon Reagents : Synthesis, Structure, and Reactivity of (Lithiomethyl)(aminomethyl)silanes (Phenylthiomethyl)silanes as New Bihnctional Assembling Ligands for the Construction of Heterometallic Complexes |
| Record Nr. | UNINA-9910144133203321 |
| Weinheim, [Germany] : , : Wiley-VCH, , 1998 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Organosilicon chemistry . III : from molecules to materials / / edited by Norbert Auner and Johann Weis
| Organosilicon chemistry . III : from molecules to materials / / edited by Norbert Auner and Johann Weis |
| Pubbl/distr/stampa | Weinheim, [Germany] : , : Wiley-VCH, , 1998 |
| Descrizione fisica | 1 online resource (744 p.) |
| Disciplina | 547.08 |
| Soggetto topico | Organosilicon compounds |
| ISBN |
1-281-76470-1
9786611764708 3-527-61990-9 3-527-62074-5 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | ger |
| Nota di contenuto |
Organosilicon Chemistry III, from Molecules to Materials; Contents; I. Fascinating Organosilicon Compounds; Introduction; More Compelling Evidence that Silicon is Better Than Carbon: The Thermal Isomerization of Olefins to Carbenes; NMR and Quantum Chemical Characterization of Silicon-Substituted Carbocations; Matrix Isolation Studies of the Reactions of Silicon Atoms; Cycloaddition Reactions of Dimethylaminomethylsilylene with Dienes and Heterodienes; Do Unsubstituted Silacyclobutadienes Exist?; A Thermally Stable Silylene: Reactivity of the Bis(amino)silylene Si[{N(CH2tBu))2}C6H4-1,2]
Pyrido[b]- 1 ,3,2λ2-diazasilole: The First Stable Unsymmetrical SilyleneA New Route to Silaheterocycles: Heterobutadiene Cycloaddition; Base Coordination: A Way to Nucleophilic Silylenes?; Isoelectronic Replacement of Si by P+: A Comparative Study of the Structures of the Spirocyclic EII Compounds E[C(PMe2)2(X)]2 (E = Si, Ge, Sn; X = PMe2,SiMes) and a Novel Spirocyclic 10 e-Phosphorus Cation(Pm) P[C(PPh2)2(SiMe3)]2+; The Main Group Carbonyls mi-CO and R2Si-CO: An Ab Initio Study Unprecedented Multistep Reactions of Decamethylsilicocene, (Me5Cs)zSi:, with C02, CSZ, COS, RNCS (R = Me, Ph), with CF3CCCF3, and with HMn(C0)5Rearrangement of Bis(hypersilyl)silylene and Related Compounds - An Unusual Way to Three-Membered Rings; Oxidation of Silenes and Silylenes: Matrix Isolation of Unusual Silicon Species; New Silaheterocycles: Formation and Properties; Cycloaddition Reactions of 1,l-Dichloro-2-neopentylsilene with Monoterpenes; Silaspirocycles as Precursors for a 2-Silaallene; Catalytic Carbon-Carbon Hydrogenation of Silicon-Functionalized Olefins Dieno- and Enophilicity of Sila-, Germa-, and StannaethenesIminosilanes and Silaamidides: Synthesis and Reactions; Metastable Compounds Containing Silicon-Phosphorus and Silicon-Arsenic Multiple Bonds: Syntheses, Structures and Reactivity; Silole and Germole Dianions and their Dilithium Derivatives - Are they Aromatic?; Supersilylmetal Compounds; Trialkylsilyl Substituted Homobimetallic Phosphanides of the Alkaline Earth Metals as well as Zinc; The Tris(trimethylsily1)silyl Substituent: An Old Hat With A New Feather Functionalized Trisilylmethanes and Trisilylsilanes as Precursors of a New Class of Tripodal Amido LigandsMethoxy-bis[tris(trimethylsilyl)silyl]methane: The First Geminal Di(hypersily1) Compound; The Use of the Tris(trimethylsily1)silyl Group in Stabilization of Low Valent Gallium Compounds; Synthesis, Structure, and Reactions of Tris(trimethylsi1yl)silyl Gallanes and Gallates; Novel Pathways in the Reactions of Vinylsilanes with Lithium Metal; New Organosilicon Reagents : Synthesis, Structure, and Reactivity of (Lithiomethyl)(aminomethyl)silanes (Phenylthiomethyl)silanes as New Bihnctional Assembling Ligands for the Construction of Heterometallic Complexes |
| Record Nr. | UNINA-9910830667103321 |
| Weinheim, [Germany] : , : Wiley-VCH, , 1998 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
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