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Phosphorus ylides : chemistry and application in organic synthesis / / Oleg I. Kolodiazhnyi
| Phosphorus ylides : chemistry and application in organic synthesis / / Oleg I. Kolodiazhnyi |
| Autore | Kolodiazhnyi Oleg I. |
| Pubbl/distr/stampa | Weinheim, [Germany] : , : Wiley-VCH, , 1999 |
| Descrizione fisica | 1 online resource (569 p.) |
| Disciplina |
547.05
547.07 547.070459 |
| Soggetto topico |
Ylides
Organophosphorus compounds Organophosphorus compounds - Synthesis |
| Soggetto genere / forma | Electronic books. |
| ISBN |
1-281-84249-4
9786611842499 3-527-61390-0 3-527-61391-9 |
| Formato | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Phosphorus Ylides; Contents; 1 Introduction; 1.1 Historiography; 1.2 Types of Phosphorus Ylides and Structure of Book; 1.3 Nornenclature; References; 2 C,P-Carbo-Substituted Phosphorus Ylides; 2.1 Introduction; 2.1.1 Types of C,P-Carbo-Substituted Posphorus Ylides; 2.2 Preparation; 2.2.1 Synthesis from Phosphonium Salts; 2.2.1.1 Dehydrohalogenation of Phosphonium Salts; 2.2.1.2 Synthesis from a-Silyl and a-Stannyl-Substituted Phosphonium Salts; 2.2.1.3 Preparation in Heterogeneous Media; 2.2.1.4 Electrochemical Method; 2.2.1.5 Ultrasound; 2.2.2 Modification of Simple Phosphorus Ylides
2.2.2.1 Acylation2.2.2.2 Alkylation; 2.2.2.3 Arylation; 2.2.3 Addition of Tertiary Phosphines to Compounds Containing Multiple Bonds; 2.2.3.1 Alkenes; 2.2.3.2 Alkynes; 2.2.4 Reaction of Tetracoordinatc Phosphorus Compounds with Multiple-Bonded Compounds; 2.2.5 Modification of the Side-Chain; 2.2.6 Miscellaneous Methods; 2.2.6.1 Formation from Carbenes; 2.2.6.2 Phosphorylation of Cornpounds with an Active Methylene Group; 2.3 Chemical Properties; 2.3.1 Stability; 2.3.2 Transformations Accompanied by Cleavage of the P=C Bond; 2.3.2.1 Thermolysis; 2.3.2.2 Photolysis 2.3.2.3 Oxidation-Industrial Synthesis of B-Carotene2.3.2.4 Reactions with Elemental Sulfur and Selenium; 2.3.2.5 Reduction; 2.3.3.6 Hydrolysis of Ylides; 2.3.2.7 Applications in Organic Synthesis; 2.3.3 Substitution at the Ylidic Carbon Atom; 2.3.3.1 Reactions with Alkylation Reagents; 2.3.3.2 Reactions with Acylation Reagents; 2.3.3.3 Examples in Natural Compound Synthesis; 2.3.4 Reactions with Compounds Containing Multiple Bonds; 2.3.4.1 Compounds Containing Carbon-Carbon Multiple Bonds; 2.3.4.2 Reactions with Compounds Containing Carbon-Heteroatom or Heteroatom-Heteroatom Multiple Bonds 2.3.5 Reactions with 1,3-Dipolar Compounds. Synthesis of Heterocyclic Systems2.3.5.1 Reaction with Aziridines and Azomethine Ylides-Synthesis of Pyrrolines; 2.3.5.2 Oxides of Azomethines; 2.3.5.3 Azides-Synthesis of 1,2, 3-Triazoles; 2.3.5.4 Reaction with Nitrile Oxides. Nitrilimines and Nitrilylides - Synthesis of Pyrazoles and Isoxazoles; References; 3 Cumulene Ylides; 3.1 Introduction; 3.1.1 The Structure of Phosphacumulene Ylides; 3.2 Phosphaketene Ylides; 3.2.1 Chemical Properties; 3.2.2 Dimerization; 3.2.3 Addition of Compounds Bearing a Mobile Hydrogen Atom 3.2.4 [2+2] Cycloaddition Reactions3.2.5 1,3-Dipolar Addition Reactions; 3.2.6 [4+2]-Cycloaddition Reactions; 3.2.7 Miscellaneous Reactions; 3.3 Phosphaketeneacetal Ylides; 3.4 Phosphaallene Ylides and Phosphacumulene Ylides; 3.5 Application in Natural Product Synthesis; 3.6 Carbodiphophoranes; 3.6.1 Structural Studies of Carbodiphosphoranes; References; 4 C-Heterosubstituted Phosphorus Ylides; 4.1 Introduction; 4.2 Phosphorus Ylides Substituted on the a-Carbon by Atoms of Element Groups I-IV; 4.2.1 Ylides Containing Group 1A and IIA Elements; 4.2.2 Ylides Containing Group IIIA Elements 4.2.3 Ylides Containing Group IVA Elements |
| Record Nr. | UNINA-9910144281903321 |
Kolodiazhnyi Oleg I.
|
||
| Weinheim, [Germany] : , : Wiley-VCH, , 1999 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Phosphorus ylides : chemistry and application in organic synthesis / / Oleg I. Kolodiazhnyi
| Phosphorus ylides : chemistry and application in organic synthesis / / Oleg I. Kolodiazhnyi |
| Autore | Kolodiazhnyi Oleg I. |
| Pubbl/distr/stampa | Weinheim, [Germany] : , : Wiley-VCH, , 1999 |
| Descrizione fisica | 1 online resource (569 p.) |
| Disciplina |
547.05
547.07 547.070459 |
| Soggetto topico |
Ylides
Organophosphorus compounds Organophosphorus compounds - Synthesis |
| ISBN |
1-281-84249-4
9786611842499 3-527-61390-0 3-527-61391-9 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Phosphorus Ylides; Contents; 1 Introduction; 1.1 Historiography; 1.2 Types of Phosphorus Ylides and Structure of Book; 1.3 Nornenclature; References; 2 C,P-Carbo-Substituted Phosphorus Ylides; 2.1 Introduction; 2.1.1 Types of C,P-Carbo-Substituted Posphorus Ylides; 2.2 Preparation; 2.2.1 Synthesis from Phosphonium Salts; 2.2.1.1 Dehydrohalogenation of Phosphonium Salts; 2.2.1.2 Synthesis from a-Silyl and a-Stannyl-Substituted Phosphonium Salts; 2.2.1.3 Preparation in Heterogeneous Media; 2.2.1.4 Electrochemical Method; 2.2.1.5 Ultrasound; 2.2.2 Modification of Simple Phosphorus Ylides
2.2.2.1 Acylation2.2.2.2 Alkylation; 2.2.2.3 Arylation; 2.2.3 Addition of Tertiary Phosphines to Compounds Containing Multiple Bonds; 2.2.3.1 Alkenes; 2.2.3.2 Alkynes; 2.2.4 Reaction of Tetracoordinatc Phosphorus Compounds with Multiple-Bonded Compounds; 2.2.5 Modification of the Side-Chain; 2.2.6 Miscellaneous Methods; 2.2.6.1 Formation from Carbenes; 2.2.6.2 Phosphorylation of Cornpounds with an Active Methylene Group; 2.3 Chemical Properties; 2.3.1 Stability; 2.3.2 Transformations Accompanied by Cleavage of the P=C Bond; 2.3.2.1 Thermolysis; 2.3.2.2 Photolysis 2.3.2.3 Oxidation-Industrial Synthesis of B-Carotene2.3.2.4 Reactions with Elemental Sulfur and Selenium; 2.3.2.5 Reduction; 2.3.3.6 Hydrolysis of Ylides; 2.3.2.7 Applications in Organic Synthesis; 2.3.3 Substitution at the Ylidic Carbon Atom; 2.3.3.1 Reactions with Alkylation Reagents; 2.3.3.2 Reactions with Acylation Reagents; 2.3.3.3 Examples in Natural Compound Synthesis; 2.3.4 Reactions with Compounds Containing Multiple Bonds; 2.3.4.1 Compounds Containing Carbon-Carbon Multiple Bonds; 2.3.4.2 Reactions with Compounds Containing Carbon-Heteroatom or Heteroatom-Heteroatom Multiple Bonds 2.3.5 Reactions with 1,3-Dipolar Compounds. Synthesis of Heterocyclic Systems2.3.5.1 Reaction with Aziridines and Azomethine Ylides-Synthesis of Pyrrolines; 2.3.5.2 Oxides of Azomethines; 2.3.5.3 Azides-Synthesis of 1,2, 3-Triazoles; 2.3.5.4 Reaction with Nitrile Oxides. Nitrilimines and Nitrilylides - Synthesis of Pyrazoles and Isoxazoles; References; 3 Cumulene Ylides; 3.1 Introduction; 3.1.1 The Structure of Phosphacumulene Ylides; 3.2 Phosphaketene Ylides; 3.2.1 Chemical Properties; 3.2.2 Dimerization; 3.2.3 Addition of Compounds Bearing a Mobile Hydrogen Atom 3.2.4 [2+2] Cycloaddition Reactions3.2.5 1,3-Dipolar Addition Reactions; 3.2.6 [4+2]-Cycloaddition Reactions; 3.2.7 Miscellaneous Reactions; 3.3 Phosphaketeneacetal Ylides; 3.4 Phosphaallene Ylides and Phosphacumulene Ylides; 3.5 Application in Natural Product Synthesis; 3.6 Carbodiphophoranes; 3.6.1 Structural Studies of Carbodiphosphoranes; References; 4 C-Heterosubstituted Phosphorus Ylides; 4.1 Introduction; 4.2 Phosphorus Ylides Substituted on the a-Carbon by Atoms of Element Groups I-IV; 4.2.1 Ylides Containing Group 1A and IIA Elements; 4.2.2 Ylides Containing Group IIIA Elements 4.2.3 Ylides Containing Group IVA Elements |
| Record Nr. | UNISA-996201943103316 |
|
Kolodiazhnyi Oleg I.
|
||
| Weinheim, [Germany] : , : Wiley-VCH, , 1999 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. di Salerno | ||
| ||
Phosphorus ylides : chemistry and application in organic synthesis / / Oleg I. Kolodiazhnyi
| Phosphorus ylides : chemistry and application in organic synthesis / / Oleg I. Kolodiazhnyi |
| Autore | Kolodiazhnyi Oleg I. |
| Pubbl/distr/stampa | Weinheim, [Germany] : , : Wiley-VCH, , 1999 |
| Descrizione fisica | 1 online resource (569 p.) |
| Disciplina |
547.05
547.07 547.070459 |
| Soggetto topico |
Ylides
Organophosphorus compounds Organophosphorus compounds - Synthesis |
| ISBN |
1-281-84249-4
9786611842499 3-527-61390-0 3-527-61391-9 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Phosphorus Ylides; Contents; 1 Introduction; 1.1 Historiography; 1.2 Types of Phosphorus Ylides and Structure of Book; 1.3 Nornenclature; References; 2 C,P-Carbo-Substituted Phosphorus Ylides; 2.1 Introduction; 2.1.1 Types of C,P-Carbo-Substituted Posphorus Ylides; 2.2 Preparation; 2.2.1 Synthesis from Phosphonium Salts; 2.2.1.1 Dehydrohalogenation of Phosphonium Salts; 2.2.1.2 Synthesis from a-Silyl and a-Stannyl-Substituted Phosphonium Salts; 2.2.1.3 Preparation in Heterogeneous Media; 2.2.1.4 Electrochemical Method; 2.2.1.5 Ultrasound; 2.2.2 Modification of Simple Phosphorus Ylides
2.2.2.1 Acylation2.2.2.2 Alkylation; 2.2.2.3 Arylation; 2.2.3 Addition of Tertiary Phosphines to Compounds Containing Multiple Bonds; 2.2.3.1 Alkenes; 2.2.3.2 Alkynes; 2.2.4 Reaction of Tetracoordinatc Phosphorus Compounds with Multiple-Bonded Compounds; 2.2.5 Modification of the Side-Chain; 2.2.6 Miscellaneous Methods; 2.2.6.1 Formation from Carbenes; 2.2.6.2 Phosphorylation of Cornpounds with an Active Methylene Group; 2.3 Chemical Properties; 2.3.1 Stability; 2.3.2 Transformations Accompanied by Cleavage of the P=C Bond; 2.3.2.1 Thermolysis; 2.3.2.2 Photolysis 2.3.2.3 Oxidation-Industrial Synthesis of B-Carotene2.3.2.4 Reactions with Elemental Sulfur and Selenium; 2.3.2.5 Reduction; 2.3.3.6 Hydrolysis of Ylides; 2.3.2.7 Applications in Organic Synthesis; 2.3.3 Substitution at the Ylidic Carbon Atom; 2.3.3.1 Reactions with Alkylation Reagents; 2.3.3.2 Reactions with Acylation Reagents; 2.3.3.3 Examples in Natural Compound Synthesis; 2.3.4 Reactions with Compounds Containing Multiple Bonds; 2.3.4.1 Compounds Containing Carbon-Carbon Multiple Bonds; 2.3.4.2 Reactions with Compounds Containing Carbon-Heteroatom or Heteroatom-Heteroatom Multiple Bonds 2.3.5 Reactions with 1,3-Dipolar Compounds. Synthesis of Heterocyclic Systems2.3.5.1 Reaction with Aziridines and Azomethine Ylides-Synthesis of Pyrrolines; 2.3.5.2 Oxides of Azomethines; 2.3.5.3 Azides-Synthesis of 1,2, 3-Triazoles; 2.3.5.4 Reaction with Nitrile Oxides. Nitrilimines and Nitrilylides - Synthesis of Pyrazoles and Isoxazoles; References; 3 Cumulene Ylides; 3.1 Introduction; 3.1.1 The Structure of Phosphacumulene Ylides; 3.2 Phosphaketene Ylides; 3.2.1 Chemical Properties; 3.2.2 Dimerization; 3.2.3 Addition of Compounds Bearing a Mobile Hydrogen Atom 3.2.4 [2+2] Cycloaddition Reactions3.2.5 1,3-Dipolar Addition Reactions; 3.2.6 [4+2]-Cycloaddition Reactions; 3.2.7 Miscellaneous Reactions; 3.3 Phosphaketeneacetal Ylides; 3.4 Phosphaallene Ylides and Phosphacumulene Ylides; 3.5 Application in Natural Product Synthesis; 3.6 Carbodiphophoranes; 3.6.1 Structural Studies of Carbodiphosphoranes; References; 4 C-Heterosubstituted Phosphorus Ylides; 4.1 Introduction; 4.2 Phosphorus Ylides Substituted on the a-Carbon by Atoms of Element Groups I-IV; 4.2.1 Ylides Containing Group 1A and IIA Elements; 4.2.2 Ylides Containing Group IIIA Elements 4.2.3 Ylides Containing Group IVA Elements |
| Record Nr. | UNINA-9910830570903321 |
|
Kolodiazhnyi Oleg I.
|
||
| Weinheim, [Germany] : , : Wiley-VCH, , 1999 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
