Asymmetric synthesis in organophosphorus chemistry : synthetic methods, catalysis, and applications / / Oleg I. Kolodiazhnyi |
Autore | Kolodiazhnyi Oleg I. |
Pubbl/distr/stampa | Weinheim, Germany : , : Wiley-VCH, , 2017 |
Descrizione fisica | 1 online resource (393 p.) |
Disciplina | 547.07 |
Soggetto topico |
Organophosphorus compounds
Asymmetric synthesis |
ISBN |
3-527-34153-6
3-527-34151-X 3-527-34154-4 |
Formato | Materiale a stampa ![]() |
Livello bibliografico | Monografia |
Lingua di pubblicazione | eng |
Nota di contenuto |
Cover; Title Page; Copyright; Dedication; Contents; Preface; Abbreviations; Chapter 1 Fundamentals of the Stereochemistry of Organophosphorus Compounds; 1.1 Historical Background; 1.2 Some Common Definitions in Stereochemistry; 1.3 Determination of Enantiomer Composition; 1.3.1 Method of Nuclear Magnetic Resonance; 1.3.1.1 Chiral Solvating Agents; 1.3.1.2 Complexes of Metals (Shift Reagents); 1.3.1.3 Chiral Derivatizing Agents for NMR; 1.3.2 Chromatographic Methods of Analysis; 1.3.2.1 Gas Chromatography; 1.3.2.2 Liquid Chromatography; 1.4 Determination of the Absolute Configuration
1.4.1 X-ray Crystal Analysis1.4.2 Method of Chemical Correlation; 1.4.3 The Assignment of Absolute Configuration by NMR; 1.5 Asymmetric Induction and Stereochemistry; 1.5.1 Asymmetric Induction; 1.5.2 Asymmetric Synthesis; 1.5.3 Asymmetric Transformation; 1.5.4 An Enantioselective Reaction; 1.5.5 Enantioselective Synthesis; 1.6 Summary; References; Chapter 2 Asymmetric Synthesis of P-Chirogenic Phosphorus Compounds; 2.1 Introduction; 2.2 Low-Coordinated Phosphorus Compounds; 2.3 Trivalent Tricoordinated Phosphorus Compounds; 2.3.1 Configuration Stability of P(III)-Compounds 2.3.2 Asymmetric Nucleophilic Substitution at P (III)2.3.2.1 Secondary Alcohols as Chiral Auxiliaries; 2.3.2.2 Optically Active Amines as Chiral Auxiliaries; 2.3.2.3 Ephedrine as Inductor of Chirality at P(III); 2.3.3 Asymmetric Oxidation of P(III) Compounds; 2.3.4 Asymmetric Electrophilic Substitution at P(III); 2.3.4.1 Asymmetric Michaelis-Arbuzov Reaction; 2.4 Pentavalent P(IV)-Phosphorus Compounds; 2.4.1 Introduction; 2.4.2 Nucleophilic Substitution Reactions; 2.4.2.1 Nucleophilic Substitution at P(IV) with Chiral Alcohol; 2.4.2.2 Nucleophilic Substitution at P(IV) with Chiral Amines 2.5 Chiral P(V) and P(VI) Phosphorus Compounds2.6 Summary; References; Chapter 3 Phosphorus Compounds with Chiral Side-Chain Centers; 3.1 Introduction; 3.2 Asymmetric Induction in Side Chains; 3.2.1 Transfer of Chirality from Phosphorus to Other Centers; 3.2.1.1 Chiral Phosphorus-Stabilized Anions; 3.2.1.2 1,2-Asymmetric Induction; 3.2.1.3 1,4-Asymmetric Induction; 3.3 Enantioselective Olefination; 3.4 Stereoselective Addition of Phosphorous Nucleophiles to C=X Bonds; 3.4.1 Phospha-Aldol Reaction; 3.4.2 Phospha-Mannich Reaction; 3.4.3 Phospha-Michael Reaction; 3.5 Asymmetric Reduction 3.6 Asymmetric Oxidation3.7 C-Modification; 3.8 Asymmetric Cycloaddition; 3.9 Multiple Stereoselectivity; 3.10 Summary; References; Chapter 4 Asymmetric Catalysis with Metal Complexes; 4.1 Introduction; 4.2 Asymmetric Catalytic Hydrogenation and Other Reactions of Reduction; 4.2.1 Hydrogenation of C=C Phosphorus Compounds; 4.2.2 Hydrogenation of C=O Phosphorus Compounds; 4.3 Asymmetric Reduction and Oxidation; 4.3.1 Reduction of C=O, C=N, and C=C bonds; 4.3.2 Asymmetric Oxidation; 4.4 Electrophilic Asymmetric Catalysis; 4.4.1 Catalytic Electrophilic Substitution at the Phosphorus Atom 4.4.1.1 Alkylation and Arylation of P(III) Compounds |
Record Nr. | UNINA-9910134858903321 |
Kolodiazhnyi Oleg I.
![]() |
||
Weinheim, Germany : , : Wiley-VCH, , 2017 | ||
![]() | ||
Lo trovi qui: Univ. Federico II | ||
|
Asymmetric synthesis in organophosphorus chemistry : synthetic methods, catalysis, and applications / / Oleg I. Kolodiazhnyi |
Autore | Kolodiazhnyi Oleg I. |
Pubbl/distr/stampa | Weinheim, Germany : , : Wiley-VCH, , 2017 |
Descrizione fisica | 1 online resource (393 p.) |
Disciplina | 547.07 |
Soggetto topico |
Organophosphorus compounds
Asymmetric synthesis |
ISBN |
3-527-34153-6
3-527-34151-X 3-527-34154-4 |
Formato | Materiale a stampa ![]() |
Livello bibliografico | Monografia |
Lingua di pubblicazione | eng |
Nota di contenuto |
Cover; Title Page; Copyright; Dedication; Contents; Preface; Abbreviations; Chapter 1 Fundamentals of the Stereochemistry of Organophosphorus Compounds; 1.1 Historical Background; 1.2 Some Common Definitions in Stereochemistry; 1.3 Determination of Enantiomer Composition; 1.3.1 Method of Nuclear Magnetic Resonance; 1.3.1.1 Chiral Solvating Agents; 1.3.1.2 Complexes of Metals (Shift Reagents); 1.3.1.3 Chiral Derivatizing Agents for NMR; 1.3.2 Chromatographic Methods of Analysis; 1.3.2.1 Gas Chromatography; 1.3.2.2 Liquid Chromatography; 1.4 Determination of the Absolute Configuration
1.4.1 X-ray Crystal Analysis1.4.2 Method of Chemical Correlation; 1.4.3 The Assignment of Absolute Configuration by NMR; 1.5 Asymmetric Induction and Stereochemistry; 1.5.1 Asymmetric Induction; 1.5.2 Asymmetric Synthesis; 1.5.3 Asymmetric Transformation; 1.5.4 An Enantioselective Reaction; 1.5.5 Enantioselective Synthesis; 1.6 Summary; References; Chapter 2 Asymmetric Synthesis of P-Chirogenic Phosphorus Compounds; 2.1 Introduction; 2.2 Low-Coordinated Phosphorus Compounds; 2.3 Trivalent Tricoordinated Phosphorus Compounds; 2.3.1 Configuration Stability of P(III)-Compounds 2.3.2 Asymmetric Nucleophilic Substitution at P (III)2.3.2.1 Secondary Alcohols as Chiral Auxiliaries; 2.3.2.2 Optically Active Amines as Chiral Auxiliaries; 2.3.2.3 Ephedrine as Inductor of Chirality at P(III); 2.3.3 Asymmetric Oxidation of P(III) Compounds; 2.3.4 Asymmetric Electrophilic Substitution at P(III); 2.3.4.1 Asymmetric Michaelis-Arbuzov Reaction; 2.4 Pentavalent P(IV)-Phosphorus Compounds; 2.4.1 Introduction; 2.4.2 Nucleophilic Substitution Reactions; 2.4.2.1 Nucleophilic Substitution at P(IV) with Chiral Alcohol; 2.4.2.2 Nucleophilic Substitution at P(IV) with Chiral Amines 2.5 Chiral P(V) and P(VI) Phosphorus Compounds2.6 Summary; References; Chapter 3 Phosphorus Compounds with Chiral Side-Chain Centers; 3.1 Introduction; 3.2 Asymmetric Induction in Side Chains; 3.2.1 Transfer of Chirality from Phosphorus to Other Centers; 3.2.1.1 Chiral Phosphorus-Stabilized Anions; 3.2.1.2 1,2-Asymmetric Induction; 3.2.1.3 1,4-Asymmetric Induction; 3.3 Enantioselective Olefination; 3.4 Stereoselective Addition of Phosphorous Nucleophiles to C=X Bonds; 3.4.1 Phospha-Aldol Reaction; 3.4.2 Phospha-Mannich Reaction; 3.4.3 Phospha-Michael Reaction; 3.5 Asymmetric Reduction 3.6 Asymmetric Oxidation3.7 C-Modification; 3.8 Asymmetric Cycloaddition; 3.9 Multiple Stereoselectivity; 3.10 Summary; References; Chapter 4 Asymmetric Catalysis with Metal Complexes; 4.1 Introduction; 4.2 Asymmetric Catalytic Hydrogenation and Other Reactions of Reduction; 4.2.1 Hydrogenation of C=C Phosphorus Compounds; 4.2.2 Hydrogenation of C=O Phosphorus Compounds; 4.3 Asymmetric Reduction and Oxidation; 4.3.1 Reduction of C=O, C=N, and C=C bonds; 4.3.2 Asymmetric Oxidation; 4.4 Electrophilic Asymmetric Catalysis; 4.4.1 Catalytic Electrophilic Substitution at the Phosphorus Atom 4.4.1.1 Alkylation and Arylation of P(III) Compounds |
Record Nr. | UNINA-9910814764703321 |
Kolodiazhnyi Oleg I.
![]() |
||
Weinheim, Germany : , : Wiley-VCH, , 2017 | ||
![]() | ||
Lo trovi qui: Univ. Federico II | ||
|
Best synthetic methods : organophosphorus (V) chemistry / / co-authored and edited by Christopher M. Timperley ; contributors, Nicholas Cooper [and seven others] |
Autore | Timperley Christopher M. |
Pubbl/distr/stampa | London, England : , : Academic Press, , 2015 |
Descrizione fisica | 1 online resource (787 p.) |
Disciplina | 547.07 |
Collana | Best Synthetic Methods |
Soggetto topico | Organophosphorus compounds |
Soggetto genere / forma | Electronic books. |
ISBN |
0-08-101580-1
0-08-098224-7 |
Formato | Materiale a stampa ![]() |
Livello bibliografico | Monografia |
Lingua di pubblicazione | eng |
Nota di contenuto |
Front Cover; Best Synthetic Methods; OTHER VOLUMES IN THE SERIES; Best Synthetic Methods; Copyright; ACKNOWLEDGEMENTS; REFERENCES; 1.4 PHOSPHORUS COMPOUNDS IN LIVING SYSTEMS; 1.5.3 ORGANOPHOSPHORUS PESTICIDES; 1.6 NOMENCLATURE OF ORGANOPHOSPHORUS COMPOUNDS; 1.7 CHIRAL PHOSPHORUS COMPOUNDS AND BIOLOGICAL IMPLICATIONS; 1.8 PHOSPHORUS-CONTAINING PHARMACEUTICALS; 1.9 FIRE RETARDANTS AND FIRE-EXTINGUISHING COMPOUNDS; 1.10 TOXICOLOGY AND MEDICAL TREATMENT OF ORGANOPHOSPHORUS COMPOUNDS; 1.11 FLUOROGENIC NERVE AGENT MIMICS FOR SCREENING FOR IMPROVED BIOSCAVENGERS
4.48 DIALKYL N-HYDROXY/ALKOXYPHOSPHORAMIDATES (RO)2P(O)NHOR (R=H OR ALKYL) |
Record Nr. | UNINA-9910459089603321 |
Timperley Christopher M.
![]() |
||
London, England : , : Academic Press, , 2015 | ||
![]() | ||
Lo trovi qui: Univ. Federico II | ||
|
Best synthetic methods : organophosphorus (V) chemistry / / co-authored and edited by Christopher M. Timperley ; contributors, Nicholas Cooper [and seven others] |
Autore | Timperley Christopher M. |
Pubbl/distr/stampa | London, England : , : Academic Press, , 2015 |
Descrizione fisica | 1 online resource (787 p.) |
Disciplina | 547.07 |
Collana | Best Synthetic Methods |
Soggetto topico | Organophosphorus compounds |
ISBN |
0-08-101580-1
0-08-098224-7 |
Formato | Materiale a stampa ![]() |
Livello bibliografico | Monografia |
Lingua di pubblicazione | eng |
Nota di contenuto |
Front Cover; Best Synthetic Methods; OTHER VOLUMES IN THE SERIES; Best Synthetic Methods; Copyright; ACKNOWLEDGEMENTS; REFERENCES; 1.4 PHOSPHORUS COMPOUNDS IN LIVING SYSTEMS; 1.5.3 ORGANOPHOSPHORUS PESTICIDES; 1.6 NOMENCLATURE OF ORGANOPHOSPHORUS COMPOUNDS; 1.7 CHIRAL PHOSPHORUS COMPOUNDS AND BIOLOGICAL IMPLICATIONS; 1.8 PHOSPHORUS-CONTAINING PHARMACEUTICALS; 1.9 FIRE RETARDANTS AND FIRE-EXTINGUISHING COMPOUNDS; 1.10 TOXICOLOGY AND MEDICAL TREATMENT OF ORGANOPHOSPHORUS COMPOUNDS; 1.11 FLUOROGENIC NERVE AGENT MIMICS FOR SCREENING FOR IMPROVED BIOSCAVENGERS
4.48 DIALKYL N-HYDROXY/ALKOXYPHOSPHORAMIDATES (RO)2P(O)NHOR (R=H OR ALKYL) |
Record Nr. | UNINA-9910792482903321 |
Timperley Christopher M.
![]() |
||
London, England : , : Academic Press, , 2015 | ||
![]() | ||
Lo trovi qui: Univ. Federico II | ||
|
Best synthetic methods : organophosphorus (V) chemistry / / co-authored and edited by Christopher M. Timperley ; contributors, Nicholas Cooper [and seven others] |
Autore | Timperley Christopher M. |
Pubbl/distr/stampa | London, England : , : Academic Press, , 2015 |
Descrizione fisica | 1 online resource (787 p.) |
Disciplina | 547.07 |
Collana | Best Synthetic Methods |
Soggetto topico | Organophosphorus compounds |
ISBN |
0-08-101580-1
0-08-098224-7 |
Formato | Materiale a stampa ![]() |
Livello bibliografico | Monografia |
Lingua di pubblicazione | eng |
Nota di contenuto |
Front Cover; Best Synthetic Methods; OTHER VOLUMES IN THE SERIES; Best Synthetic Methods; Copyright; ACKNOWLEDGEMENTS; REFERENCES; 1.4 PHOSPHORUS COMPOUNDS IN LIVING SYSTEMS; 1.5.3 ORGANOPHOSPHORUS PESTICIDES; 1.6 NOMENCLATURE OF ORGANOPHOSPHORUS COMPOUNDS; 1.7 CHIRAL PHOSPHORUS COMPOUNDS AND BIOLOGICAL IMPLICATIONS; 1.8 PHOSPHORUS-CONTAINING PHARMACEUTICALS; 1.9 FIRE RETARDANTS AND FIRE-EXTINGUISHING COMPOUNDS; 1.10 TOXICOLOGY AND MEDICAL TREATMENT OF ORGANOPHOSPHORUS COMPOUNDS; 1.11 FLUOROGENIC NERVE AGENT MIMICS FOR SCREENING FOR IMPROVED BIOSCAVENGERS
4.48 DIALKYL N-HYDROXY/ALKOXYPHOSPHORAMIDATES (RO)2P(O)NHOR (R=H OR ALKYL) |
Record Nr. | UNINA-9910815455603321 |
Timperley Christopher M.
![]() |
||
London, England : , : Academic Press, , 2015 | ||
![]() | ||
Lo trovi qui: Univ. Federico II | ||
|
The Chemistry of Organophosphorous Compounds, Phosphine Oxides, Sulphides, Selenides and Tellurides. Vol. 2 |
Autore | Hartley Frank R |
Pubbl/distr/stampa | [Place of publication not identified], : John Wiley & Sons Incorporated, 1992 |
Descrizione fisica | 1 online resource (xvi, 647 pages) : illustrations |
Disciplina | 547.070459 |
Altri autori (Persone) | HartleyF. R |
Collana | PATAI'S Chemistry of Functional Groups |
Soggetto topico | Organophosphorus compounds |
ISBN |
0-470-77903-9
0-470-03442-4 0-470-02772-X |
Formato | Materiale a stampa ![]() |
Livello bibliografico | Monografia |
Lingua di pubblicazione | eng |
Nota di contenuto | Structure and bonding in tertiary phosphine chalcogenides / D.G. Gilheany -- Structure and stereochemistry of secondary and tertiary phosphine chalcogenides / M.J. Gallagher -- Electrochemistry of organophosphorus(V) compounds / K.S.V. Santhanam -- Photochemistry of phosphine chalcogenides / M. Dankowski -- Spectroscopy of phosphine chalcogenides / G. Davidson -- Methods of preparation of phosphine chalcogenides / A.K. Bhattacharya and N.K. Roy -- Chemical properties and reactions of phosphine chalcogenides / R.S. Edmundson -- Coordination chemistry of phosphine chalcogenides and their analytical and catalytic applications / T.S. Lobana. |
Record Nr. | UNINA-9910830100703321 |
Hartley Frank R
![]() |
||
[Place of publication not identified], : John Wiley & Sons Incorporated, 1992 | ||
![]() | ||
Lo trovi qui: Univ. Federico II | ||
|
The Chemistry of Organophosphorous Compounds, Phosphine Oxides, Sulphides, Selenides and Tellurides. Vol. 2 |
Autore | Hartley Frank R |
Pubbl/distr/stampa | [Place of publication not identified], : John Wiley & Sons Incorporated, 1992 |
Descrizione fisica | 1 online resource (xvi, 647 pages) : illustrations |
Disciplina | 547.070459 |
Altri autori (Persone) | HartleyF. R |
Collana | PATAI'S Chemistry of Functional Groups |
Soggetto topico | Organophosphorus compounds |
ISBN |
0-470-77903-9
0-470-03442-4 0-470-02772-X |
Formato | Materiale a stampa ![]() |
Livello bibliografico | Monografia |
Lingua di pubblicazione | eng |
Nota di contenuto | Structure and bonding in tertiary phosphine chalcogenides / D.G. Gilheany -- Structure and stereochemistry of secondary and tertiary phosphine chalcogenides / M.J. Gallagher -- Electrochemistry of organophosphorus(V) compounds / K.S.V. Santhanam -- Photochemistry of phosphine chalcogenides / M. Dankowski -- Spectroscopy of phosphine chalcogenides / G. Davidson -- Methods of preparation of phosphine chalcogenides / A.K. Bhattacharya and N.K. Roy -- Chemical properties and reactions of phosphine chalcogenides / R.S. Edmundson -- Coordination chemistry of phosphine chalcogenides and their analytical and catalytic applications / T.S. Lobana. |
Record Nr. | UNINA-9910876690703321 |
Hartley Frank R
![]() |
||
[Place of publication not identified], : John Wiley & Sons Incorporated, 1992 | ||
![]() | ||
Lo trovi qui: Univ. Federico II | ||
|
The Chemistry of Organophosphorous Compounds. Vol. 1 |
Autore | Hartley Frank R |
Pubbl/distr/stampa | [Place of publication not identified], : John Wiley & Sons Incorporated, 1990 |
Descrizione fisica | 1 online resource (xiv, 739 pages) : illustrations |
Disciplina | 547.070459 |
Altri autori (Persone) | HartleyF. R |
Collana | PATAI'S Chemistry of Functional Groups |
Soggetto topico | Organophosphorus compounds |
ISBN |
0-470-77894-6
0-470-03443-2 0-470-02770-3 |
Formato | Materiale a stampa ![]() |
Livello bibliografico | Monografia |
Lingua di pubblicazione | eng |
Nota di contenuto | V. 1. Primary, secondary, and tertiary phosphines, polyphosphines, and heterocyclic organophosphorus (III) compounds -- v. 2. Phosphine oxides, sulphides, selenides and tellurides -- v. 3. Phosphonium salts, ylides and phosphoranes. |
Record Nr. | UNINA-9910829945603321 |
Hartley Frank R
![]() |
||
[Place of publication not identified], : John Wiley & Sons Incorporated, 1990 | ||
![]() | ||
Lo trovi qui: Univ. Federico II | ||
|
The Chemistry of Organophosphorous Compounds. Vol. 1 |
Autore | Hartley Frank R |
Pubbl/distr/stampa | [Place of publication not identified], : John Wiley & Sons Incorporated, 1990 |
Descrizione fisica | 1 online resource (xiv, 739 pages) : illustrations |
Disciplina | 547.070459 |
Altri autori (Persone) | HartleyF. R |
Collana | PATAI'S Chemistry of Functional Groups |
Soggetto topico | Organophosphorus compounds |
ISBN |
0-470-77894-6
0-470-03443-2 0-470-02770-3 |
Formato | Materiale a stampa ![]() |
Livello bibliografico | Monografia |
Lingua di pubblicazione | eng |
Nota di contenuto | V. 1. Primary, secondary, and tertiary phosphines, polyphosphines, and heterocyclic organophosphorus (III) compounds -- v. 2. Phosphine oxides, sulphides, selenides and tellurides -- v. 3. Phosphonium salts, ylides and phosphoranes. |
Record Nr. | UNINA-9910876691903321 |
Hartley Frank R
![]() |
||
[Place of publication not identified], : John Wiley & Sons Incorporated, 1990 | ||
![]() | ||
Lo trovi qui: Univ. Federico II | ||
|
The Chemistry of Organophosphorus Compounds, Phosphonium Salts, Ylides and Phosphoranes. Vol. 3, Phosphonium Salts, Ylides and Phosphoranes |
Autore | Hartley Frank R |
Pubbl/distr/stampa | [Place of publication not identified], : John Wiley & Sons Incorporated, 1994 |
Descrizione fisica | 1 online resource (442 pages) : illustrations |
Disciplina | 547.07 |
Altri autori (Persone) | HartleyF. R |
Collana | Chemistry of functional groups |
Soggetto topico | Organophosphorus compounds |
ISBN |
0-470-77908-X
0-470-02773-8 0-470-03436-X |
Formato | Materiale a stampa ![]() |
Livello bibliografico | Monografia |
Lingua di pubblicazione | eng |
Nota di contenuto | Structure and bonding in phosphonium ylides, salts and phosphoranes -- D.G. Gilheany -- Preparation, properties and reactions of phosphonium salts -- H.-J. Cristau and F. Plénat -- Preparation, properties and reactions of phosphoranes -- Ramon Burgada and Ralph Setton -- Structure, bonding and spectroscopic properties of phosphonium ylides -- S.M. Bachrach and C.I. Nitsche -- Electrochemistry of ylides, phosphoranes and phosphonium salts -- K.S.V. Santhanam -- Photochemistry of phosphonium salts, phosphoranes and ylides -- M. Dankowski -- Chemical analysis of organophosphorus compounds -- H. Feilchenfeld. |
Record Nr. | UNINA-9910830108503321 |
Hartley Frank R
![]() |
||
[Place of publication not identified], : John Wiley & Sons Incorporated, 1994 | ||
![]() | ||
Lo trovi qui: Univ. Federico II | ||
|