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Ferrocenes [[electronic resource] ] : compounds, properties and applications / / Elisabeth S. Phillips, editor
| Ferrocenes [[electronic resource] ] : compounds, properties and applications / / Elisabeth S. Phillips, editor |
| Pubbl/distr/stampa | New York, : Nova Science Publishers, c2011 |
| Descrizione fisica | 1 online resource (413 p.) |
| Disciplina | 547/.05621 |
| Altri autori (Persone) | PhillipsElisabeth S |
| Collana | Chemical engineering methods and technology |
| Soggetto topico |
Ferrocene
Organoiron compounds |
| Soggetto genere / forma | Electronic books. |
| ISBN | 1-61122-224-9 |
| Formato | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
""FERROCENES: COMPOUNDS, PROPERTIES AND APPLICATIONS ""; ""FERROCENES: COMPOUNDS, PROPERTIES AND APPLICATIONS""; ""CONTENTS""; ""PREFACE""; ""SYNTHESIS OF PRISTINE AND DOPED CARBON NANOTUBES USING FERROCENE""; ""ABSTRACT ""; ""INTRODUCTION ""; ""STRUCTURE AND PROPERTIES OF FERROCENE ""; ""STRUCTURE AND BONDING ""; ""SYNTHESIS OF PRISTINE CARBON NANOTUBES ""; ""SYNTHESIS OF DOPED CARBON NANOTUBES""; ""CONCLUSION ""; ""REFERENCES ""; ""USE OF FERROCENE AND FERROCENE ADMIXED PRECURSORS FOR THE SYNTHESIS OF CARBON NANOTUBES""; ""ABSTRACT ""; ""1. INTRODUCTION""
""2. SYNTHESIS OF CNTS USING FERROCENE """"3. SYNTHESIS OF CNTS BY FERROCENE AND HYDROCARBON MIXTURE ""; ""3.1. Synthesis of CNTs by Ferrocene and Gaseous Hydrocarbon""; ""3.2. Synthesis of CNTs by Ferrocene and Liquid Hydrocarbon ""; ""3.2.1. CVD of Ferrocene - Liquid Hydrocarbon Through Syringe Pump""; ""3. 2.2. Spray Assisted CVD Method ""; ""3.2.3. Aerosol and Nebulized Spray Assisted CVD Method""; ""4. SYNTHESIS OF CNTS USING FERROCENE AND NATURAL PRECURSOR""; ""5. SYNTHESIS OF CNTS USING FERROCENE AND OTHER CARBON SOURCES""; ""6. SUMMARY ""; ""ACKNOWLEDGMENTS ""; ""REFERENCES "" ""TRANSITION-METAL CATALYZED REACTIONS IN THE SYNTHESIS OF FERROCENE DERIVATIVES""""ABSTRACT ""; ""1. INTRODUCTION ""; ""2. HOMOGENEOUS CATALYTIC HYDROGENATION OF FERROCENE DERIVATIVES ""; ""3. SYNTHESIS OF CHIRAL DIOLS BY ASYMMETRIC DIHYDROXYLATION OF FERROCENYL ALKENES ""; ""4. HOMOGENEOUS CATALYTIC HYDROSILYLATION OF FERROCENE DERIVATIVES ""; ""5. CARBON-CARBON BOND-FORMING REACTIONS ""; ""5.1. Heck Reactions of Ferrocenyl Substrates ""; ""5.2. Cross-Coupling Reactions ""; ""5.2.1. Stille Coupling ""; ""5.2.2. Suzuki Coupling ""; ""5.2.3. Negishi Coupling "" ""5.2.4. Cross-Coupling of Organomercurials """"5.2.5. Other Coupling Reactions with Organometallic Reagents""; ""5.2.6. Sonogashira Coupling ""; ""5.3. Metathesis Reactions ""; ""5.3.1. Ring-Closing Metathesis Reactions ""; ""5.3.2. Ring-Opening Metathesis Polymerization ""; ""6. C-HETEROATOM COUPLING REACTIONS OF FERROCENE DERIVATIVES ""; ""7. RING-OPENING POLYMERIZATION REACTIONS ""; ""8. COPPER CATALYZED AZIDE-ALKYNE CYCLOADDITION ""; ""9. CARBONYLATION REACTIONS LEADING TO CARBOXYLIC ACID DERIVATIVES AND CARBONYL COMPOUNDS ""; ""9.1. Palladium-Catalyzed Aminocarbonylation "" ""9.2. Carbonylative Coupling Reactions """"10. MISCELLANEOUS REACTIONS ""; ""CONCLUSION ""; ""REFERENCES ""; ""EXPLOITING FERROCENE TO DEVELOP SYNTHETIC MOLECULAR MACHINES ""; ""ABSTRACT ""; ""1. INTRODUCTION""; ""2. FERROCENE HOST-GUEST CHEMISTRY AND STIMULI RESPONSIVE HOST-GUEST SYSTEMS ""; ""2.1. Ferrocene Host-Guest Chemistry ""; ""2.2 Stimuli Responsive Host-Guest Systems Containing Ferrocene""; ""3. STIMULI RESPONSIVE INTERLOCKED ARCHITECTURES CONTAINING FERROCENE ""; ""3.1. Introduction to Mechanically Interlocked Architectures "" ""3.2 Ferrocene Containing Mechanically Interlocked Architectures"" |
| Record Nr. | UNINA-9910461206703321 |
| New York, : Nova Science Publishers, c2011 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Ferrocenes [[electronic resource] ] : compounds, properties and applications / / Elisabeth S. Phillips, editor
| Ferrocenes [[electronic resource] ] : compounds, properties and applications / / Elisabeth S. Phillips, editor |
| Pubbl/distr/stampa | New York, : Nova Science Publishers, c2011 |
| Descrizione fisica | 1 online resource (413 p.) |
| Disciplina | 547/.05621 |
| Altri autori (Persone) | PhillipsElisabeth S |
| Collana | Chemical engineering methods and technology |
| Soggetto topico |
Ferrocene
Organoiron compounds |
| ISBN | 1-61122-224-9 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
""FERROCENES: COMPOUNDS, PROPERTIES AND APPLICATIONS ""; ""FERROCENES: COMPOUNDS, PROPERTIES AND APPLICATIONS""; ""CONTENTS""; ""PREFACE""; ""SYNTHESIS OF PRISTINE AND DOPED CARBON NANOTUBES USING FERROCENE""; ""ABSTRACT ""; ""INTRODUCTION ""; ""STRUCTURE AND PROPERTIES OF FERROCENE ""; ""STRUCTURE AND BONDING ""; ""SYNTHESIS OF PRISTINE CARBON NANOTUBES ""; ""SYNTHESIS OF DOPED CARBON NANOTUBES""; ""CONCLUSION ""; ""REFERENCES ""; ""USE OF FERROCENE AND FERROCENE ADMIXED PRECURSORS FOR THE SYNTHESIS OF CARBON NANOTUBES""; ""ABSTRACT ""; ""1. INTRODUCTION""
""2. SYNTHESIS OF CNTS USING FERROCENE """"3. SYNTHESIS OF CNTS BY FERROCENE AND HYDROCARBON MIXTURE ""; ""3.1. Synthesis of CNTs by Ferrocene and Gaseous Hydrocarbon""; ""3.2. Synthesis of CNTs by Ferrocene and Liquid Hydrocarbon ""; ""3.2.1. CVD of Ferrocene - Liquid Hydrocarbon Through Syringe Pump""; ""3. 2.2. Spray Assisted CVD Method ""; ""3.2.3. Aerosol and Nebulized Spray Assisted CVD Method""; ""4. SYNTHESIS OF CNTS USING FERROCENE AND NATURAL PRECURSOR""; ""5. SYNTHESIS OF CNTS USING FERROCENE AND OTHER CARBON SOURCES""; ""6. SUMMARY ""; ""ACKNOWLEDGMENTS ""; ""REFERENCES "" ""TRANSITION-METAL CATALYZED REACTIONS IN THE SYNTHESIS OF FERROCENE DERIVATIVES""""ABSTRACT ""; ""1. INTRODUCTION ""; ""2. HOMOGENEOUS CATALYTIC HYDROGENATION OF FERROCENE DERIVATIVES ""; ""3. SYNTHESIS OF CHIRAL DIOLS BY ASYMMETRIC DIHYDROXYLATION OF FERROCENYL ALKENES ""; ""4. HOMOGENEOUS CATALYTIC HYDROSILYLATION OF FERROCENE DERIVATIVES ""; ""5. CARBON-CARBON BOND-FORMING REACTIONS ""; ""5.1. Heck Reactions of Ferrocenyl Substrates ""; ""5.2. Cross-Coupling Reactions ""; ""5.2.1. Stille Coupling ""; ""5.2.2. Suzuki Coupling ""; ""5.2.3. Negishi Coupling "" ""5.2.4. Cross-Coupling of Organomercurials """"5.2.5. Other Coupling Reactions with Organometallic Reagents""; ""5.2.6. Sonogashira Coupling ""; ""5.3. Metathesis Reactions ""; ""5.3.1. Ring-Closing Metathesis Reactions ""; ""5.3.2. Ring-Opening Metathesis Polymerization ""; ""6. C-HETEROATOM COUPLING REACTIONS OF FERROCENE DERIVATIVES ""; ""7. RING-OPENING POLYMERIZATION REACTIONS ""; ""8. COPPER CATALYZED AZIDE-ALKYNE CYCLOADDITION ""; ""9. CARBONYLATION REACTIONS LEADING TO CARBOXYLIC ACID DERIVATIVES AND CARBONYL COMPOUNDS ""; ""9.1. Palladium-Catalyzed Aminocarbonylation "" ""9.2. Carbonylative Coupling Reactions """"10. MISCELLANEOUS REACTIONS ""; ""CONCLUSION ""; ""REFERENCES ""; ""EXPLOITING FERROCENE TO DEVELOP SYNTHETIC MOLECULAR MACHINES ""; ""ABSTRACT ""; ""1. INTRODUCTION""; ""2. FERROCENE HOST-GUEST CHEMISTRY AND STIMULI RESPONSIVE HOST-GUEST SYSTEMS ""; ""2.1. Ferrocene Host-Guest Chemistry ""; ""2.2 Stimuli Responsive Host-Guest Systems Containing Ferrocene""; ""3. STIMULI RESPONSIVE INTERLOCKED ARCHITECTURES CONTAINING FERROCENE ""; ""3.1. Introduction to Mechanically Interlocked Architectures "" ""3.2 Ferrocene Containing Mechanically Interlocked Architectures"" |
| Record Nr. | UNINA-9910790033003321 |
| New York, : Nova Science Publishers, c2011 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Ferrocenes : compounds, properties and applications / / Elisabeth S. Phillips, editor
| Ferrocenes : compounds, properties and applications / / Elisabeth S. Phillips, editor |
| Edizione | [1st ed.] |
| Pubbl/distr/stampa | New York, : Nova Science Publishers, c2011 |
| Descrizione fisica | 1 online resource (413 p.) |
| Disciplina | 547/.05621 |
| Altri autori (Persone) | PhillipsElisabeth S |
| Collana | Chemical engineering methods and technology |
| Soggetto topico |
Ferrocene
Organoiron compounds |
| ISBN | 1-61122-224-9 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
""FERROCENES: COMPOUNDS, PROPERTIES AND APPLICATIONS ""; ""FERROCENES: COMPOUNDS, PROPERTIES AND APPLICATIONS""; ""CONTENTS""; ""PREFACE""; ""SYNTHESIS OF PRISTINE AND DOPED CARBON NANOTUBES USING FERROCENE""; ""ABSTRACT ""; ""INTRODUCTION ""; ""STRUCTURE AND PROPERTIES OF FERROCENE ""; ""STRUCTURE AND BONDING ""; ""SYNTHESIS OF PRISTINE CARBON NANOTUBES ""; ""SYNTHESIS OF DOPED CARBON NANOTUBES""; ""CONCLUSION ""; ""REFERENCES ""; ""USE OF FERROCENE AND FERROCENE ADMIXED PRECURSORS FOR THE SYNTHESIS OF CARBON NANOTUBES""; ""ABSTRACT ""; ""1. INTRODUCTION""
""2. SYNTHESIS OF CNTS USING FERROCENE """"3. SYNTHESIS OF CNTS BY FERROCENE AND HYDROCARBON MIXTURE ""; ""3.1. Synthesis of CNTs by Ferrocene and Gaseous Hydrocarbon""; ""3.2. Synthesis of CNTs by Ferrocene and Liquid Hydrocarbon ""; ""3.2.1. CVD of Ferrocene - Liquid Hydrocarbon Through Syringe Pump""; ""3. 2.2. Spray Assisted CVD Method ""; ""3.2.3. Aerosol and Nebulized Spray Assisted CVD Method""; ""4. SYNTHESIS OF CNTS USING FERROCENE AND NATURAL PRECURSOR""; ""5. SYNTHESIS OF CNTS USING FERROCENE AND OTHER CARBON SOURCES""; ""6. SUMMARY ""; ""ACKNOWLEDGMENTS ""; ""REFERENCES "" ""TRANSITION-METAL CATALYZED REACTIONS IN THE SYNTHESIS OF FERROCENE DERIVATIVES""""ABSTRACT ""; ""1. INTRODUCTION ""; ""2. HOMOGENEOUS CATALYTIC HYDROGENATION OF FERROCENE DERIVATIVES ""; ""3. SYNTHESIS OF CHIRAL DIOLS BY ASYMMETRIC DIHYDROXYLATION OF FERROCENYL ALKENES ""; ""4. HOMOGENEOUS CATALYTIC HYDROSILYLATION OF FERROCENE DERIVATIVES ""; ""5. CARBON-CARBON BOND-FORMING REACTIONS ""; ""5.1. Heck Reactions of Ferrocenyl Substrates ""; ""5.2. Cross-Coupling Reactions ""; ""5.2.1. Stille Coupling ""; ""5.2.2. Suzuki Coupling ""; ""5.2.3. Negishi Coupling "" ""5.2.4. Cross-Coupling of Organomercurials """"5.2.5. Other Coupling Reactions with Organometallic Reagents""; ""5.2.6. Sonogashira Coupling ""; ""5.3. Metathesis Reactions ""; ""5.3.1. Ring-Closing Metathesis Reactions ""; ""5.3.2. Ring-Opening Metathesis Polymerization ""; ""6. C-HETEROATOM COUPLING REACTIONS OF FERROCENE DERIVATIVES ""; ""7. RING-OPENING POLYMERIZATION REACTIONS ""; ""8. COPPER CATALYZED AZIDE-ALKYNE CYCLOADDITION ""; ""9. CARBONYLATION REACTIONS LEADING TO CARBOXYLIC ACID DERIVATIVES AND CARBONYL COMPOUNDS ""; ""9.1. Palladium-Catalyzed Aminocarbonylation "" ""9.2. Carbonylative Coupling Reactions """"10. MISCELLANEOUS REACTIONS ""; ""CONCLUSION ""; ""REFERENCES ""; ""EXPLOITING FERROCENE TO DEVELOP SYNTHETIC MOLECULAR MACHINES ""; ""ABSTRACT ""; ""1. INTRODUCTION""; ""2. FERROCENE HOST-GUEST CHEMISTRY AND STIMULI RESPONSIVE HOST-GUEST SYSTEMS ""; ""2.1. Ferrocene Host-Guest Chemistry ""; ""2.2 Stimuli Responsive Host-Guest Systems Containing Ferrocene""; ""3. STIMULI RESPONSIVE INTERLOCKED ARCHITECTURES CONTAINING FERROCENE ""; ""3.1. Introduction to Mechanically Interlocked Architectures "" ""3.2 Ferrocene Containing Mechanically Interlocked Architectures"" |
| Record Nr. | UNINA-9910828609503321 |
| New York, : Nova Science Publishers, c2011 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Ferrocenes [[electronic resource] ] : homogeneous catalysis, organic synthesis, materials science / / edited by Antonio Togni and Tamio Hayashi
| Ferrocenes [[electronic resource] ] : homogeneous catalysis, organic synthesis, materials science / / edited by Antonio Togni and Tamio Hayashi |
| Pubbl/distr/stampa | Weinheim ; ; New York, : VCH Publishers, c1995 |
| Descrizione fisica | 1 online resource (562 p.) |
| Disciplina | 547.05621 |
| Altri autori (Persone) |
TogniAntonio
HayashiTamio |
| Soggetto topico |
Ferrocene
Organoiron compounds |
| Soggetto genere / forma | Electronic books. |
| ISBN |
1-281-75871-X
9786611758714 3-527-61559-8 3-527-61558-X |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Ferrocenes; Preface; Contents; List of Contributors; List of Abbreviations; Part 1. Homogeneous Catalysis; 1 1,1'-Bis (dipheny1phosphino)ferrocene - Coordination Chemistry, Organic Syntheses, and Catalysis; 1.1 Introduction; 1.2 Preparation and Complexation; 1.3 Structural Properties; 1.3.1 Modes of Coordination; 1.3.2 Geometrical Distortions; 1.4 Spectroscopic Characteristics; 1.4.1 Techniques; 1.4.1.1 31P NMR Spectroscopy; 1.4.1.2 1H NMR Spectroscopy; 1.4.1.3 Mössbauer Spectroscopy; 1.4.2 NMR Fluxionality; 1.5 Catalysis; 1.5.1 Cross Coupling
1.5.1.1 Organic Electrophile and Organometallic Coupling1.5.1.2 Arylation and Vinylation of Alkenes; 1.5.1.3 Carbonylation and Carbonylative Coupling; 1.5.1.4 Nucleophilic Substitution; 1.5.1.5 Polycondensation and Polymerization; 1.5.2 Olefin Functionalization; 1.5.2.1 Hydroformylation; 1.5.2.2 Hydrogenation and Reduction; 1.5.2.3 Hydroboration and Hydrosilylation; 1.5.2.4 Isomerization; 1.6 Cluster Complexes; 1.7 Electrochemistry; 1.8 Biomedical Applications; 1.9 Summary; References; 2 Asymmetric Catalysis with Chiral Ferrocenylphosphine Ligands; 2.1 Introduction 2.2 Preparation of Chiral Ferrocenylphosphines2.3 Structure of Chiral Ferrocenylphosphines and their Transition-Metal Complexes; 2.4 Catalytic Asymmetric Reactions with Chiral Ferrocenylphosphine Ligands; 2.4.1 Cross-Coupling of Organometallics with Halides; 2.4.2 Allylic Substitution Reactions via π-Ally1 Complexes; 2.4.3 Hydrogenation of Olefins and Ketones; 2.4.4 Hydrosilylation of Olefins and Ketones; 2.4.5 Aldol Reaction of α-Isocyanocarboxylates; 2.4.6 Others; References; 3 Enantioselective Addition of Dialkylzinc to Aldehydes Catalyzed by Chiral Ferrocenyl Aminoalcohols 3.1 Introduction3.2 Chiral Ferrocenylzincs Bearing an Aminoethanol Auxiliary [12]; 3.2.1 Synthesis of the Catalysts; 3.2.2 Addition of Diethylzinc to Benzaldehyde; 3.3 N- (1-Ferrocenylalky1)-N-alk ylnorephedrines [13]; 3.3.1 Synthesis of the Catalysts; 3.3.2 Addition of Diethylzinc to Aldehydes; 3.4 Chiral Polymers Bearing N-Ferrocenylmethylephedrine [14]; 3.4.1 Synthesis of the Catalysts; 3.4.2 Addition of Diethylzinc to Benzaldehyde; 3.5 Chiral 1,2-Disubstituted Ferrocenyl Aminoalcohols [15]; 3.5.1 Synthesis of the Catalysts; 3.5.2 Addition of Dialkylzinc to Aldehydes 3.5.3 Addition of Dialkylzincs to o-Phthalaldehyde: A Facile Synthesis of Optically Active 3-Alkylphthalides [16]3.5.4 Enantio- and Diastereoselective Addition of Diethylzinc to Racemic α-Thio- and α-Selenoaldehydes [17]; 3.6 Summary; References; Part 2. Organic Synthesis - Selected Aspects; 4 Chiral Ferrocene Derivatives. An Introduction; 4.1 Central and Planar Chirality in Metallocenes; 4.2 a-Ferrocenylalkyl Carbocations; 4.2.1 Structure and Stability; 4.2.2 Stereochemistry; 4.3 Central Chiral Ferrocene Derivatives; 4.3.1 Syntheses; 4.3.1.1 By Resolution; 4.3.1.2 By Asymmetric Synthesis 4.3.1.3 From the Chiral Pool |
| Record Nr. | UNINA-9910144280003321 |
| Weinheim ; ; New York, : VCH Publishers, c1995 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Ferrocenes [[electronic resource] ] : homogeneous catalysis, organic synthesis, materials science / / edited by Antonio Togni and Tamio Hayashi
| Ferrocenes [[electronic resource] ] : homogeneous catalysis, organic synthesis, materials science / / edited by Antonio Togni and Tamio Hayashi |
| Pubbl/distr/stampa | Weinheim ; ; New York, : VCH Publishers, c1995 |
| Descrizione fisica | 1 online resource (562 p.) |
| Disciplina | 547.05621 |
| Altri autori (Persone) |
TogniAntonio
HayashiTamio |
| Soggetto topico |
Ferrocene
Organoiron compounds |
| ISBN |
1-281-75871-X
9786611758714 3-527-61559-8 3-527-61558-X |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Ferrocenes; Preface; Contents; List of Contributors; List of Abbreviations; Part 1. Homogeneous Catalysis; 1 1,1'-Bis (dipheny1phosphino)ferrocene - Coordination Chemistry, Organic Syntheses, and Catalysis; 1.1 Introduction; 1.2 Preparation and Complexation; 1.3 Structural Properties; 1.3.1 Modes of Coordination; 1.3.2 Geometrical Distortions; 1.4 Spectroscopic Characteristics; 1.4.1 Techniques; 1.4.1.1 31P NMR Spectroscopy; 1.4.1.2 1H NMR Spectroscopy; 1.4.1.3 Mössbauer Spectroscopy; 1.4.2 NMR Fluxionality; 1.5 Catalysis; 1.5.1 Cross Coupling
1.5.1.1 Organic Electrophile and Organometallic Coupling1.5.1.2 Arylation and Vinylation of Alkenes; 1.5.1.3 Carbonylation and Carbonylative Coupling; 1.5.1.4 Nucleophilic Substitution; 1.5.1.5 Polycondensation and Polymerization; 1.5.2 Olefin Functionalization; 1.5.2.1 Hydroformylation; 1.5.2.2 Hydrogenation and Reduction; 1.5.2.3 Hydroboration and Hydrosilylation; 1.5.2.4 Isomerization; 1.6 Cluster Complexes; 1.7 Electrochemistry; 1.8 Biomedical Applications; 1.9 Summary; References; 2 Asymmetric Catalysis with Chiral Ferrocenylphosphine Ligands; 2.1 Introduction 2.2 Preparation of Chiral Ferrocenylphosphines2.3 Structure of Chiral Ferrocenylphosphines and their Transition-Metal Complexes; 2.4 Catalytic Asymmetric Reactions with Chiral Ferrocenylphosphine Ligands; 2.4.1 Cross-Coupling of Organometallics with Halides; 2.4.2 Allylic Substitution Reactions via π-Ally1 Complexes; 2.4.3 Hydrogenation of Olefins and Ketones; 2.4.4 Hydrosilylation of Olefins and Ketones; 2.4.5 Aldol Reaction of α-Isocyanocarboxylates; 2.4.6 Others; References; 3 Enantioselective Addition of Dialkylzinc to Aldehydes Catalyzed by Chiral Ferrocenyl Aminoalcohols 3.1 Introduction3.2 Chiral Ferrocenylzincs Bearing an Aminoethanol Auxiliary [12]; 3.2.1 Synthesis of the Catalysts; 3.2.2 Addition of Diethylzinc to Benzaldehyde; 3.3 N- (1-Ferrocenylalky1)-N-alk ylnorephedrines [13]; 3.3.1 Synthesis of the Catalysts; 3.3.2 Addition of Diethylzinc to Aldehydes; 3.4 Chiral Polymers Bearing N-Ferrocenylmethylephedrine [14]; 3.4.1 Synthesis of the Catalysts; 3.4.2 Addition of Diethylzinc to Benzaldehyde; 3.5 Chiral 1,2-Disubstituted Ferrocenyl Aminoalcohols [15]; 3.5.1 Synthesis of the Catalysts; 3.5.2 Addition of Dialkylzinc to Aldehydes 3.5.3 Addition of Dialkylzincs to o-Phthalaldehyde: A Facile Synthesis of Optically Active 3-Alkylphthalides [16]3.5.4 Enantio- and Diastereoselective Addition of Diethylzinc to Racemic α-Thio- and α-Selenoaldehydes [17]; 3.6 Summary; References; Part 2. Organic Synthesis - Selected Aspects; 4 Chiral Ferrocene Derivatives. An Introduction; 4.1 Central and Planar Chirality in Metallocenes; 4.2 a-Ferrocenylalkyl Carbocations; 4.2.1 Structure and Stability; 4.2.2 Stereochemistry; 4.3 Central Chiral Ferrocene Derivatives; 4.3.1 Syntheses; 4.3.1.1 By Resolution; 4.3.1.2 By Asymmetric Synthesis 4.3.1.3 From the Chiral Pool |
| Record Nr. | UNISA-996202136003316 |
| Weinheim ; ; New York, : VCH Publishers, c1995 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. di Salerno | ||
| ||
Ferrocenes [[electronic resource] ] : homogeneous catalysis, organic synthesis, materials science / / edited by Antonio Togni and Tamio Hayashi
| Ferrocenes [[electronic resource] ] : homogeneous catalysis, organic synthesis, materials science / / edited by Antonio Togni and Tamio Hayashi |
| Pubbl/distr/stampa | Weinheim ; ; New York, : VCH Publishers, c1995 |
| Descrizione fisica | 1 online resource (562 p.) |
| Disciplina | 547.05621 |
| Altri autori (Persone) |
TogniAntonio
HayashiTamio |
| Soggetto topico |
Ferrocene
Organoiron compounds |
| ISBN |
1-281-75871-X
9786611758714 3-527-61559-8 3-527-61558-X |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Ferrocenes; Preface; Contents; List of Contributors; List of Abbreviations; Part 1. Homogeneous Catalysis; 1 1,1'-Bis (dipheny1phosphino)ferrocene - Coordination Chemistry, Organic Syntheses, and Catalysis; 1.1 Introduction; 1.2 Preparation and Complexation; 1.3 Structural Properties; 1.3.1 Modes of Coordination; 1.3.2 Geometrical Distortions; 1.4 Spectroscopic Characteristics; 1.4.1 Techniques; 1.4.1.1 31P NMR Spectroscopy; 1.4.1.2 1H NMR Spectroscopy; 1.4.1.3 Mössbauer Spectroscopy; 1.4.2 NMR Fluxionality; 1.5 Catalysis; 1.5.1 Cross Coupling
1.5.1.1 Organic Electrophile and Organometallic Coupling1.5.1.2 Arylation and Vinylation of Alkenes; 1.5.1.3 Carbonylation and Carbonylative Coupling; 1.5.1.4 Nucleophilic Substitution; 1.5.1.5 Polycondensation and Polymerization; 1.5.2 Olefin Functionalization; 1.5.2.1 Hydroformylation; 1.5.2.2 Hydrogenation and Reduction; 1.5.2.3 Hydroboration and Hydrosilylation; 1.5.2.4 Isomerization; 1.6 Cluster Complexes; 1.7 Electrochemistry; 1.8 Biomedical Applications; 1.9 Summary; References; 2 Asymmetric Catalysis with Chiral Ferrocenylphosphine Ligands; 2.1 Introduction 2.2 Preparation of Chiral Ferrocenylphosphines2.3 Structure of Chiral Ferrocenylphosphines and their Transition-Metal Complexes; 2.4 Catalytic Asymmetric Reactions with Chiral Ferrocenylphosphine Ligands; 2.4.1 Cross-Coupling of Organometallics with Halides; 2.4.2 Allylic Substitution Reactions via π-Ally1 Complexes; 2.4.3 Hydrogenation of Olefins and Ketones; 2.4.4 Hydrosilylation of Olefins and Ketones; 2.4.5 Aldol Reaction of α-Isocyanocarboxylates; 2.4.6 Others; References; 3 Enantioselective Addition of Dialkylzinc to Aldehydes Catalyzed by Chiral Ferrocenyl Aminoalcohols 3.1 Introduction3.2 Chiral Ferrocenylzincs Bearing an Aminoethanol Auxiliary [12]; 3.2.1 Synthesis of the Catalysts; 3.2.2 Addition of Diethylzinc to Benzaldehyde; 3.3 N- (1-Ferrocenylalky1)-N-alk ylnorephedrines [13]; 3.3.1 Synthesis of the Catalysts; 3.3.2 Addition of Diethylzinc to Aldehydes; 3.4 Chiral Polymers Bearing N-Ferrocenylmethylephedrine [14]; 3.4.1 Synthesis of the Catalysts; 3.4.2 Addition of Diethylzinc to Benzaldehyde; 3.5 Chiral 1,2-Disubstituted Ferrocenyl Aminoalcohols [15]; 3.5.1 Synthesis of the Catalysts; 3.5.2 Addition of Dialkylzinc to Aldehydes 3.5.3 Addition of Dialkylzincs to o-Phthalaldehyde: A Facile Synthesis of Optically Active 3-Alkylphthalides [16]3.5.4 Enantio- and Diastereoselective Addition of Diethylzinc to Racemic α-Thio- and α-Selenoaldehydes [17]; 3.6 Summary; References; Part 2. Organic Synthesis - Selected Aspects; 4 Chiral Ferrocene Derivatives. An Introduction; 4.1 Central and Planar Chirality in Metallocenes; 4.2 a-Ferrocenylalkyl Carbocations; 4.2.1 Structure and Stability; 4.2.2 Stereochemistry; 4.3 Central Chiral Ferrocene Derivatives; 4.3.1 Syntheses; 4.3.1.1 By Resolution; 4.3.1.2 By Asymmetric Synthesis 4.3.1.3 From the Chiral Pool |
| Record Nr. | UNINA-9910830440803321 |
| Weinheim ; ; New York, : VCH Publishers, c1995 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Ferrocenes : homogeneous catalysis, organic synthesis, materials science / / edited by Antonio Togni and Tamio Hayashi
| Ferrocenes : homogeneous catalysis, organic synthesis, materials science / / edited by Antonio Togni and Tamio Hayashi |
| Pubbl/distr/stampa | Weinheim ; ; New York, : VCH Publishers, c1995 |
| Descrizione fisica | 1 online resource (562 p.) |
| Disciplina | 547.05621 |
| Altri autori (Persone) |
TogniAntonio
HayashiTamio |
| Soggetto topico |
Ferrocene
Organoiron compounds |
| ISBN |
1-281-75871-X
9786611758714 3-527-61559-8 3-527-61558-X |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Ferrocenes; Preface; Contents; List of Contributors; List of Abbreviations; Part 1. Homogeneous Catalysis; 1 1,1'-Bis (dipheny1phosphino)ferrocene - Coordination Chemistry, Organic Syntheses, and Catalysis; 1.1 Introduction; 1.2 Preparation and Complexation; 1.3 Structural Properties; 1.3.1 Modes of Coordination; 1.3.2 Geometrical Distortions; 1.4 Spectroscopic Characteristics; 1.4.1 Techniques; 1.4.1.1 31P NMR Spectroscopy; 1.4.1.2 1H NMR Spectroscopy; 1.4.1.3 Mössbauer Spectroscopy; 1.4.2 NMR Fluxionality; 1.5 Catalysis; 1.5.1 Cross Coupling
1.5.1.1 Organic Electrophile and Organometallic Coupling1.5.1.2 Arylation and Vinylation of Alkenes; 1.5.1.3 Carbonylation and Carbonylative Coupling; 1.5.1.4 Nucleophilic Substitution; 1.5.1.5 Polycondensation and Polymerization; 1.5.2 Olefin Functionalization; 1.5.2.1 Hydroformylation; 1.5.2.2 Hydrogenation and Reduction; 1.5.2.3 Hydroboration and Hydrosilylation; 1.5.2.4 Isomerization; 1.6 Cluster Complexes; 1.7 Electrochemistry; 1.8 Biomedical Applications; 1.9 Summary; References; 2 Asymmetric Catalysis with Chiral Ferrocenylphosphine Ligands; 2.1 Introduction 2.2 Preparation of Chiral Ferrocenylphosphines2.3 Structure of Chiral Ferrocenylphosphines and their Transition-Metal Complexes; 2.4 Catalytic Asymmetric Reactions with Chiral Ferrocenylphosphine Ligands; 2.4.1 Cross-Coupling of Organometallics with Halides; 2.4.2 Allylic Substitution Reactions via π-Ally1 Complexes; 2.4.3 Hydrogenation of Olefins and Ketones; 2.4.4 Hydrosilylation of Olefins and Ketones; 2.4.5 Aldol Reaction of α-Isocyanocarboxylates; 2.4.6 Others; References; 3 Enantioselective Addition of Dialkylzinc to Aldehydes Catalyzed by Chiral Ferrocenyl Aminoalcohols 3.1 Introduction3.2 Chiral Ferrocenylzincs Bearing an Aminoethanol Auxiliary [12]; 3.2.1 Synthesis of the Catalysts; 3.2.2 Addition of Diethylzinc to Benzaldehyde; 3.3 N- (1-Ferrocenylalky1)-N-alk ylnorephedrines [13]; 3.3.1 Synthesis of the Catalysts; 3.3.2 Addition of Diethylzinc to Aldehydes; 3.4 Chiral Polymers Bearing N-Ferrocenylmethylephedrine [14]; 3.4.1 Synthesis of the Catalysts; 3.4.2 Addition of Diethylzinc to Benzaldehyde; 3.5 Chiral 1,2-Disubstituted Ferrocenyl Aminoalcohols [15]; 3.5.1 Synthesis of the Catalysts; 3.5.2 Addition of Dialkylzinc to Aldehydes 3.5.3 Addition of Dialkylzincs to o-Phthalaldehyde: A Facile Synthesis of Optically Active 3-Alkylphthalides [16]3.5.4 Enantio- and Diastereoselective Addition of Diethylzinc to Racemic α-Thio- and α-Selenoaldehydes [17]; 3.6 Summary; References; Part 2. Organic Synthesis - Selected Aspects; 4 Chiral Ferrocene Derivatives. An Introduction; 4.1 Central and Planar Chirality in Metallocenes; 4.2 a-Ferrocenylalkyl Carbocations; 4.2.1 Structure and Stability; 4.2.2 Stereochemistry; 4.3 Central Chiral Ferrocene Derivatives; 4.3.1 Syntheses; 4.3.1.1 By Resolution; 4.3.1.2 By Asymmetric Synthesis 4.3.1.3 From the Chiral Pool |
| Record Nr. | UNINA-9910877171803321 |
| Weinheim ; ; New York, : VCH Publishers, c1995 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Organoiron polymers [[electronic resource] /] / edited by Alaa S. Abd-El-Aziz ... [et al.]
| Organoiron polymers [[electronic resource] /] / edited by Alaa S. Abd-El-Aziz ... [et al.] |
| Pubbl/distr/stampa | Hoboken, N.J., : Wiley-Interscience, c2004 |
| Descrizione fisica | 1 online resource (305 p.) |
| Disciplina |
547.7
547/.05621 |
| Altri autori (Persone) | Abd-El-AzizAlaa S |
| Collana | Macromolecules containing metal and metal-like elements |
| Soggetto topico |
Ferrocene
Organometallic polymers Organoiron compounds Macromolecules Metal complexes |
| Soggetto genere / forma | Electronic books. |
| ISBN |
1-280-34385-0
9786610343850 0-470-24444-5 0-471-46656-5 0-471-46657-3 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Macromolecules Containing Metal and Metal-Like Elements Volume 2; Contributors; Contents; Preface; Series Preface; 1. Overview of Organoiron Polymers; I. Introduction; II. Ferrocene-Based Polymers; III. Polymers Containing Cyclopentadienyliron-Complexed Arenes; IV. Polymers Containing Iron Carbonyl Complexes; V. Iron Polyynes; VI. Polymers with Iron-Iron Bonds; VII. Outlook; VIII. References; 2. Synthesis and Properties of Hyperbranched Polyferrocenylenesilynes; I. Introduction; II. Polymer Synthesis; III. Structural Characterization; IV. Electronic and Thermal Transitions
V. Pyrolytic CeramizationVI. Ceramic Composition; VII. Magnetic Susceptibility; VIII. Summary and Perspectives; IX. Experimentation; A. Materials; B. Instrumentation; C. Polymerization; D. Ceramization; X. Acknowledgments; XI. References and Notes; 3. Ring-Opened Polyferrocenes: Metal-Containing Polymers for Materials Science, Self-Assembly, and Nanostructure Applications; I. Introduction; II. Properties of Polyferrocenylsilanes; III. Water-Soluble PFS Derivatives for Layer-by-Layer Self-Assembly Applications IV. Metal-Containing Block Copolymers: Formation of Self-Assembled, Supramolecular Materials and Nanoscopic Ceramic PatternsV. Summary; VI. Acknowledgments; VII. References; 4. Synthesis and Solution Self-Assembly of Polyferrocene-Based AB Diblock and ABC Triblock Copolymers; I. Introduction; II. Results and Discussion; A. Synthesis and Aqueous Micellization of PFS-PDMAEMA; B. Synthesis and Micellization of PFP-PFS-PDMS; III. Summary and Outlook; IV. References 5. Synthesis and Self-Assembly of Polyisoprene-block-Polyferrocenyldimethylsilane Diblock Copolymers: Fabrication of Ceramic Nanolines on Semiconducting SubstratesI. Introduction; II. Experimental; III. Results and Discussion; A. Block Copolymer Synthesis; B. PI-b-PFDMS Micelles; C. Fabrication of Ceramic Nanolines; IV. Conclusions; V. Acknowledgments; VI. References; 6. Water-Soluble Polyferrocenylsilanes for Supramolecular Assemblies by Layer-by-Layer Deposition; I. Introduction; II. Synthesis of Polyferrocenylsilane Polyions; III. Polymer Characterization; IV. Multilayer Characterization V. Patterned Polyferrocenylsilane Multilayer Thin FilmsVI. Summary; VII. Experimentation; VIII. Acknowledgment; IX. References; 7. Metal-Containing Polymers for High-Performance Resist Applications; I. Introduction; II. Organic Resists; A. Chemical Amplification; III. Inorganic Resists; IV. Organic-Inorganic Composite Resists; V. Organometallic Polymers; A. Polyferrocenyldimethylsilane as Reactive Ion Etch Barrier; B. Printing of Organometallic Polymers by Soft Lithography; 1. Directed Dewetting; VI. Organic-Organometallic Block Copolymers A. Structure Formation via Block Copolymer Self-Assembly |
| Record Nr. | UNINA-9910143517303321 |
| Hoboken, N.J., : Wiley-Interscience, c2004 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Organoiron polymers [[electronic resource] /] / edited by Alaa S. Abd-El-Aziz ... [et al.]
| Organoiron polymers [[electronic resource] /] / edited by Alaa S. Abd-El-Aziz ... [et al.] |
| Pubbl/distr/stampa | Hoboken, N.J., : Wiley-Interscience, c2004 |
| Descrizione fisica | 1 online resource (305 p.) |
| Disciplina |
547.7
547/.05621 |
| Altri autori (Persone) | Abd-El-AzizAlaa S |
| Collana | Macromolecules containing metal and metal-like elements |
| Soggetto topico |
Ferrocene
Organometallic polymers Organoiron compounds Macromolecules Metal complexes |
| ISBN |
1-280-34385-0
9786610343850 0-470-24444-5 0-471-46656-5 0-471-46657-3 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Macromolecules Containing Metal and Metal-Like Elements Volume 2; Contributors; Contents; Preface; Series Preface; 1. Overview of Organoiron Polymers; I. Introduction; II. Ferrocene-Based Polymers; III. Polymers Containing Cyclopentadienyliron-Complexed Arenes; IV. Polymers Containing Iron Carbonyl Complexes; V. Iron Polyynes; VI. Polymers with Iron-Iron Bonds; VII. Outlook; VIII. References; 2. Synthesis and Properties of Hyperbranched Polyferrocenylenesilynes; I. Introduction; II. Polymer Synthesis; III. Structural Characterization; IV. Electronic and Thermal Transitions
V. Pyrolytic CeramizationVI. Ceramic Composition; VII. Magnetic Susceptibility; VIII. Summary and Perspectives; IX. Experimentation; A. Materials; B. Instrumentation; C. Polymerization; D. Ceramization; X. Acknowledgments; XI. References and Notes; 3. Ring-Opened Polyferrocenes: Metal-Containing Polymers for Materials Science, Self-Assembly, and Nanostructure Applications; I. Introduction; II. Properties of Polyferrocenylsilanes; III. Water-Soluble PFS Derivatives for Layer-by-Layer Self-Assembly Applications IV. Metal-Containing Block Copolymers: Formation of Self-Assembled, Supramolecular Materials and Nanoscopic Ceramic PatternsV. Summary; VI. Acknowledgments; VII. References; 4. Synthesis and Solution Self-Assembly of Polyferrocene-Based AB Diblock and ABC Triblock Copolymers; I. Introduction; II. Results and Discussion; A. Synthesis and Aqueous Micellization of PFS-PDMAEMA; B. Synthesis and Micellization of PFP-PFS-PDMS; III. Summary and Outlook; IV. References 5. Synthesis and Self-Assembly of Polyisoprene-block-Polyferrocenyldimethylsilane Diblock Copolymers: Fabrication of Ceramic Nanolines on Semiconducting SubstratesI. Introduction; II. Experimental; III. Results and Discussion; A. Block Copolymer Synthesis; B. PI-b-PFDMS Micelles; C. Fabrication of Ceramic Nanolines; IV. Conclusions; V. Acknowledgments; VI. References; 6. Water-Soluble Polyferrocenylsilanes for Supramolecular Assemblies by Layer-by-Layer Deposition; I. Introduction; II. Synthesis of Polyferrocenylsilane Polyions; III. Polymer Characterization; IV. Multilayer Characterization V. Patterned Polyferrocenylsilane Multilayer Thin FilmsVI. Summary; VII. Experimentation; VIII. Acknowledgment; IX. References; 7. Metal-Containing Polymers for High-Performance Resist Applications; I. Introduction; II. Organic Resists; A. Chemical Amplification; III. Inorganic Resists; IV. Organic-Inorganic Composite Resists; V. Organometallic Polymers; A. Polyferrocenyldimethylsilane as Reactive Ion Etch Barrier; B. Printing of Organometallic Polymers by Soft Lithography; 1. Directed Dewetting; VI. Organic-Organometallic Block Copolymers A. Structure Formation via Block Copolymer Self-Assembly |
| Record Nr. | UNINA-9910830635403321 |
| Hoboken, N.J., : Wiley-Interscience, c2004 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Organoiron polymers / / edited by Alaa S. Abd-El-Aziz ... [et al.]
| Organoiron polymers / / edited by Alaa S. Abd-El-Aziz ... [et al.] |
| Pubbl/distr/stampa | Hoboken, N.J., : Wiley-Interscience, c2004 |
| Descrizione fisica | 1 online resource (305 p.) |
| Disciplina | 547/.05621 |
| Altri autori (Persone) | Abd-El-AzizAlaa S |
| Collana | Macromolecules containing metal and metal-like elements |
| Soggetto topico |
Ferrocene
Organometallic polymers Organoiron compounds Macromolecules Metal complexes |
| ISBN |
1-280-34385-0
9786610343850 0-470-24444-5 0-471-46656-5 0-471-46657-3 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Macromolecules Containing Metal and Metal-Like Elements Volume 2; Contributors; Contents; Preface; Series Preface; 1. Overview of Organoiron Polymers; I. Introduction; II. Ferrocene-Based Polymers; III. Polymers Containing Cyclopentadienyliron-Complexed Arenes; IV. Polymers Containing Iron Carbonyl Complexes; V. Iron Polyynes; VI. Polymers with Iron-Iron Bonds; VII. Outlook; VIII. References; 2. Synthesis and Properties of Hyperbranched Polyferrocenylenesilynes; I. Introduction; II. Polymer Synthesis; III. Structural Characterization; IV. Electronic and Thermal Transitions
V. Pyrolytic CeramizationVI. Ceramic Composition; VII. Magnetic Susceptibility; VIII. Summary and Perspectives; IX. Experimentation; A. Materials; B. Instrumentation; C. Polymerization; D. Ceramization; X. Acknowledgments; XI. References and Notes; 3. Ring-Opened Polyferrocenes: Metal-Containing Polymers for Materials Science, Self-Assembly, and Nanostructure Applications; I. Introduction; II. Properties of Polyferrocenylsilanes; III. Water-Soluble PFS Derivatives for Layer-by-Layer Self-Assembly Applications IV. Metal-Containing Block Copolymers: Formation of Self-Assembled, Supramolecular Materials and Nanoscopic Ceramic PatternsV. Summary; VI. Acknowledgments; VII. References; 4. Synthesis and Solution Self-Assembly of Polyferrocene-Based AB Diblock and ABC Triblock Copolymers; I. Introduction; II. Results and Discussion; A. Synthesis and Aqueous Micellization of PFS-PDMAEMA; B. Synthesis and Micellization of PFP-PFS-PDMS; III. Summary and Outlook; IV. References 5. Synthesis and Self-Assembly of Polyisoprene-block-Polyferrocenyldimethylsilane Diblock Copolymers: Fabrication of Ceramic Nanolines on Semiconducting SubstratesI. Introduction; II. Experimental; III. Results and Discussion; A. Block Copolymer Synthesis; B. PI-b-PFDMS Micelles; C. Fabrication of Ceramic Nanolines; IV. Conclusions; V. Acknowledgments; VI. References; 6. Water-Soluble Polyferrocenylsilanes for Supramolecular Assemblies by Layer-by-Layer Deposition; I. Introduction; II. Synthesis of Polyferrocenylsilane Polyions; III. Polymer Characterization; IV. Multilayer Characterization V. Patterned Polyferrocenylsilane Multilayer Thin FilmsVI. Summary; VII. Experimentation; VIII. Acknowledgment; IX. References; 7. Metal-Containing Polymers for High-Performance Resist Applications; I. Introduction; II. Organic Resists; A. Chemical Amplification; III. Inorganic Resists; IV. Organic-Inorganic Composite Resists; V. Organometallic Polymers; A. Polyferrocenyldimethylsilane as Reactive Ion Etch Barrier; B. Printing of Organometallic Polymers by Soft Lithography; 1. Directed Dewetting; VI. Organic-Organometallic Block Copolymers A. Structure Formation via Block Copolymer Self-Assembly |
| Record Nr. | UNINA-9910877320303321 |
| Hoboken, N.J., : Wiley-Interscience, c2004 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Soggetto topico
- Ferrocene (10)
-
Organoiron compounds
(10)
- Macromolecules (3)
- Metal complexes (3)
- Organometallic polymers (3)