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Advanced organic chemistry [[electronic resource] ] : reaction mechanisms / / Reinhard Bruckner
| Advanced organic chemistry [[electronic resource] ] : reaction mechanisms / / Reinhard Bruckner |
| Autore | Bruckner Reinhard <1955-> |
| Pubbl/distr/stampa | San Diego, : Harcourt/Academic Press, c2002 |
| Descrizione fisica | 1 online resource (661 p.) |
| Disciplina | 547/.139 |
| Collana | Advanced organic chemistry series |
| Soggetto topico | Organic reaction mechanisms |
| Soggetto genere / forma | Electronic books. |
| ISBN |
1-281-46679-4
9786611466794 0-08-049880-9 |
| Formato | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Front Cover; Advanced Organic Chemistry; Copyright Page; Contents; Foreword; Preface to the English Edition; Preface to the German Edition; Acknowledgments; Chapter 1. Radical Substitution Reactions at the Saturated C Atom; 1.1 Bonding and Preferred Geometries in C Radicals, Carbenium Ions and Carbanions; 1.2 Stability of Radicals; 1.3 Relative Rates of Analogous Radical Reactions; 1.4 Radical Substitution Reactions: Chain Reactions; 1.5 Radical Initiators; 1.6 Radical Chemistry of Alkylmercury(II) Hydrides; 1.7 Radical Halogenation of Hydrocarbons; 1.8 Autoxidations
1.9 Defunctionalizations via Radical Substitution ReactionsReferences; Chapter 2. Nucleophilic Substitution Reactions at the Saturated C Atom; 2.1 Nucleophiles and Electrophiles; Leaving Groups; 2.2 Good and Poor Nucleophiles; 2.3 Leaving Groups and the Quality of Leaving Groups; 2.4 SN2 Reactions: Kinetic and Stereochemical Analysis-Substituent Effects on Reactivity; 2.5 SN1 Reactions: Kinetic and Stereochemical Analysis; Substituent Effects on Reactivity 2.6 When Do SN Reactions at Saturated C Atoms Take Place According to the SN1 Mechanism and When Do They Take Place According to the SN2 Mechanism?2.7 Unimolecular SN Reactions That Do Not Take Place via Simple Carbenium Ion Intermediates: Neighboring Group Participation; 2.8 Preparatively Useful SN2 Reactions: Alkylations; References; Chapter 3. Additions to the Olefinic C=C Double Bond; 3.1 The Concept of cis and trans Addition; 3.2 Vocabulary of Stereochemistry and Stereoselective Synthesis I; 3.3 Additions That Take Place Diastereoselectivity as cis Additions 3.4 Enantioselective cis Additions to C=C Double Bonds3.5 Additions That Take Place Diastereoselectively as trans Additions (Additions via Onium Intermediates); 3.6 Additions That Take Place or Can Take Place without Stereocontrol Depending on the Mechanism; References; Chapter 4. ß-Eliminations; 4.1 Concepts of Elimination Reactions; 4.2 b-Eliminations of H/Het via Cyclic Transition States; 4.3 b-Eliminations of H/Het via Acyclic Transition States: The Mechanistic Alternatives; 4.4 E2 Eliminations of H/Het and the E2/SN2 Competition 4.5 E1 Elimination of H/Het from Rtert-X and the E1/SN1 Competition4.6 E1cb Eliminations; 4.7 ß-Eliminations of Het1/Het2; References; Chapter 5. Substitution Reactions on Aromatic Compounds; 5.1 Electrophilic Aromatic Substitutions via Wheland Complexes (""Ar-SE Reactions""); 5.2 Ar-SE Reactions via Wheland Complexes: Individual Reactions; 5.3 Electrophilic Substitution Reactions on Metallated Aromatic Compounds; 5.4 Nucleophilic Substitution Reactions in Aryldiazonium Salts; 5.5 Nucleophilic Substitution Reactions via Meisenheimer Complexes 5.6 Nucleophilic Aromatic Substitution via Arynes, cine Substitution |
| Record Nr. | UNINA-9910458258703321 |
Bruckner Reinhard <1955->
|
||
| San Diego, : Harcourt/Academic Press, c2002 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Advanced organic chemistry : reaction mechanisms / / Reinhard Bruckner [[electronic resource]]
| Advanced organic chemistry : reaction mechanisms / / Reinhard Bruckner [[electronic resource]] |
| Autore | Bruckner Reinhard <1955-> |
| Pubbl/distr/stampa | San Diego, : Harcourt/Academic Press, c2002 |
| Descrizione fisica | 1 online resource (661 p.) |
| Disciplina | 547/.139 |
| Collana | Advanced organic chemistry series |
| Soggetto topico | Organic reaction mechanisms |
| ISBN |
1-281-46679-4
9786611466794 0-08-049880-9 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Front Cover; Advanced Organic Chemistry; Copyright Page; Contents; Foreword; Preface to the English Edition; Preface to the German Edition; Acknowledgments; Chapter 1. Radical Substitution Reactions at the Saturated C Atom; 1.1 Bonding and Preferred Geometries in C Radicals, Carbenium Ions and Carbanions; 1.2 Stability of Radicals; 1.3 Relative Rates of Analogous Radical Reactions; 1.4 Radical Substitution Reactions: Chain Reactions; 1.5 Radical Initiators; 1.6 Radical Chemistry of Alkylmercury(II) Hydrides; 1.7 Radical Halogenation of Hydrocarbons; 1.8 Autoxidations
1.9 Defunctionalizations via Radical Substitution ReactionsReferences; Chapter 2. Nucleophilic Substitution Reactions at the Saturated C Atom; 2.1 Nucleophiles and Electrophiles; Leaving Groups; 2.2 Good and Poor Nucleophiles; 2.3 Leaving Groups and the Quality of Leaving Groups; 2.4 SN2 Reactions: Kinetic and Stereochemical Analysis-Substituent Effects on Reactivity; 2.5 SN1 Reactions: Kinetic and Stereochemical Analysis; Substituent Effects on Reactivity 2.6 When Do SN Reactions at Saturated C Atoms Take Place According to the SN1 Mechanism and When Do They Take Place According to the SN2 Mechanism?2.7 Unimolecular SN Reactions That Do Not Take Place via Simple Carbenium Ion Intermediates: Neighboring Group Participation; 2.8 Preparatively Useful SN2 Reactions: Alkylations; References; Chapter 3. Additions to the Olefinic C=C Double Bond; 3.1 The Concept of cis and trans Addition; 3.2 Vocabulary of Stereochemistry and Stereoselective Synthesis I; 3.3 Additions That Take Place Diastereoselectivity as cis Additions 3.4 Enantioselective cis Additions to C=C Double Bonds3.5 Additions That Take Place Diastereoselectively as trans Additions (Additions via Onium Intermediates); 3.6 Additions That Take Place or Can Take Place without Stereocontrol Depending on the Mechanism; References; Chapter 4. ß-Eliminations; 4.1 Concepts of Elimination Reactions; 4.2 b-Eliminations of H/Het via Cyclic Transition States; 4.3 b-Eliminations of H/Het via Acyclic Transition States: The Mechanistic Alternatives; 4.4 E2 Eliminations of H/Het and the E2/SN2 Competition 4.5 E1 Elimination of H/Het from Rtert-X and the E1/SN1 Competition4.6 E1cb Eliminations; 4.7 ß-Eliminations of Het1/Het2; References; Chapter 5. Substitution Reactions on Aromatic Compounds; 5.1 Electrophilic Aromatic Substitutions via Wheland Complexes (""Ar-SE Reactions""); 5.2 Ar-SE Reactions via Wheland Complexes: Individual Reactions; 5.3 Electrophilic Substitution Reactions on Metallated Aromatic Compounds; 5.4 Nucleophilic Substitution Reactions in Aryldiazonium Salts; 5.5 Nucleophilic Substitution Reactions via Meisenheimer Complexes 5.6 Nucleophilic Aromatic Substitution via Arynes, cine Substitution |
| Record Nr. | UNINA-9910784534903321 |
|
Bruckner Reinhard <1955->
|
||
| San Diego, : Harcourt/Academic Press, c2002 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Advanced organic chemistry : reaction mechanisms / / Reinhard Bruckner [[electronic resource]]
| Advanced organic chemistry : reaction mechanisms / / Reinhard Bruckner [[electronic resource]] |
| Autore | Bruckner Reinhard <1955-> |
| Edizione | [1st ed.] |
| Pubbl/distr/stampa | San Diego, : Harcourt/Academic Press, c2002 |
| Descrizione fisica | 1 online resource (661 p.) |
| Disciplina | 547/.139 |
| Collana | Advanced organic chemistry series |
| Soggetto topico | Organic reaction mechanisms |
| ISBN |
1-281-46679-4
9786611466794 0-08-049880-9 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Front Cover; Advanced Organic Chemistry; Copyright Page; Contents; Foreword; Preface to the English Edition; Preface to the German Edition; Acknowledgments; Chapter 1. Radical Substitution Reactions at the Saturated C Atom; 1.1 Bonding and Preferred Geometries in C Radicals, Carbenium Ions and Carbanions; 1.2 Stability of Radicals; 1.3 Relative Rates of Analogous Radical Reactions; 1.4 Radical Substitution Reactions: Chain Reactions; 1.5 Radical Initiators; 1.6 Radical Chemistry of Alkylmercury(II) Hydrides; 1.7 Radical Halogenation of Hydrocarbons; 1.8 Autoxidations
1.9 Defunctionalizations via Radical Substitution ReactionsReferences; Chapter 2. Nucleophilic Substitution Reactions at the Saturated C Atom; 2.1 Nucleophiles and Electrophiles; Leaving Groups; 2.2 Good and Poor Nucleophiles; 2.3 Leaving Groups and the Quality of Leaving Groups; 2.4 SN2 Reactions: Kinetic and Stereochemical Analysis-Substituent Effects on Reactivity; 2.5 SN1 Reactions: Kinetic and Stereochemical Analysis; Substituent Effects on Reactivity 2.6 When Do SN Reactions at Saturated C Atoms Take Place According to the SN1 Mechanism and When Do They Take Place According to the SN2 Mechanism?2.7 Unimolecular SN Reactions That Do Not Take Place via Simple Carbenium Ion Intermediates: Neighboring Group Participation; 2.8 Preparatively Useful SN2 Reactions: Alkylations; References; Chapter 3. Additions to the Olefinic C=C Double Bond; 3.1 The Concept of cis and trans Addition; 3.2 Vocabulary of Stereochemistry and Stereoselective Synthesis I; 3.3 Additions That Take Place Diastereoselectivity as cis Additions 3.4 Enantioselective cis Additions to C=C Double Bonds3.5 Additions That Take Place Diastereoselectively as trans Additions (Additions via Onium Intermediates); 3.6 Additions That Take Place or Can Take Place without Stereocontrol Depending on the Mechanism; References; Chapter 4. ß-Eliminations; 4.1 Concepts of Elimination Reactions; 4.2 b-Eliminations of H/Het via Cyclic Transition States; 4.3 b-Eliminations of H/Het via Acyclic Transition States: The Mechanistic Alternatives; 4.4 E2 Eliminations of H/Het and the E2/SN2 Competition 4.5 E1 Elimination of H/Het from Rtert-X and the E1/SN1 Competition4.6 E1cb Eliminations; 4.7 ß-Eliminations of Het1/Het2; References; Chapter 5. Substitution Reactions on Aromatic Compounds; 5.1 Electrophilic Aromatic Substitutions via Wheland Complexes (""Ar-SE Reactions""); 5.2 Ar-SE Reactions via Wheland Complexes: Individual Reactions; 5.3 Electrophilic Substitution Reactions on Metallated Aromatic Compounds; 5.4 Nucleophilic Substitution Reactions in Aryldiazonium Salts; 5.5 Nucleophilic Substitution Reactions via Meisenheimer Complexes 5.6 Nucleophilic Aromatic Substitution via Arynes, cine Substitution |
| Record Nr. | UNINA-9910811682803321 |
|
Bruckner Reinhard <1955->
|
||
| San Diego, : Harcourt/Academic Press, c2002 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Advanced organic chemistry : reaction mechanisms / Reinhard Bruckner
| Advanced organic chemistry : reaction mechanisms / Reinhard Bruckner |
| Autore | Bruckner, Reinhard |
| Pubbl/distr/stampa | San Diego : Harcourt/Academic Press, c2002 |
| Descrizione fisica | xxi, 636 p. : ill. ; 24 cm |
| Disciplina | 547 |
| Collana | Advanced organic chemistry series |
| Soggetto topico |
Organic reaction mechanisms
Organic chemistry |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNISALENTO-991001782309707536 |
|
Bruckner, Reinhard
|
||
| San Diego : Harcourt/Academic Press, c2002 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. del Salento | ||
| ||
Catalytic cascade reactions / / edited by Peng-Fei Xu, State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou, P.R. China, Wei Wang, Department of Chemistry and Chemical Biology, University of New Mexico, Albuquerque, New Mexico
| Catalytic cascade reactions / / edited by Peng-Fei Xu, State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou, P.R. China, Wei Wang, Department of Chemistry and Chemical Biology, University of New Mexico, Albuquerque, New Mexico |
| Pubbl/distr/stampa | Hoboken, New Jersey : , : Wiley, , [2014] |
| Descrizione fisica | 1 online resource (446 pages) : illustrations |
| Disciplina | 547/.215 |
| Altri autori (Persone) |
XuPeng-Fei <1964->
WangWei (Associate professor of chemistry) |
| Soggetto topico |
Organic reaction mechanisms
Catalysis Chemical reactions Organic compounds - Synthesis |
| ISBN |
1-118-35665-9
1-118-35663-2 1-118-35664-0 |
| Classificazione | SCI013040 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNINA-9910208821103321 |
| Hoboken, New Jersey : , : Wiley, , [2014] | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Catalytic cascade reactions / / edited by Peng-Fei Xu, State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou, P.R. China, Wei Wang, Department of Chemistry and Chemical Biology, University of New Mexico, Albuquerque, New Mexico
| Catalytic cascade reactions / / edited by Peng-Fei Xu, State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou, P.R. China, Wei Wang, Department of Chemistry and Chemical Biology, University of New Mexico, Albuquerque, New Mexico |
| Pubbl/distr/stampa | Hoboken, New Jersey : , : Wiley, , [2014] |
| Descrizione fisica | 1 online resource (446 pages) : illustrations |
| Disciplina | 547/.215 |
| Altri autori (Persone) |
XuPeng-Fei <1964->
WangWei (Associate professor of chemistry) |
| Soggetto topico |
Organic reaction mechanisms
Catalysis Chemical reactions Organic compounds - Synthesis |
| ISBN |
1-118-35665-9
1-118-35663-2 1-118-35664-0 |
| Classificazione | SCI013040 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNINA-9910810499403321 |
| Hoboken, New Jersey : , : Wiley, , [2014] | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Flash chemistry [[electronic resource] ] : fast organic synthesis in microsystems / / Jun-ichi Yoshida
| Flash chemistry [[electronic resource] ] : fast organic synthesis in microsystems / / Jun-ichi Yoshida |
| Autore | Yoshida Junʼichi <1952-> |
| Pubbl/distr/stampa | Hoboken, N.J., : Wiley, 2008 |
| Descrizione fisica | 1 online resource (248 p.) |
| Disciplina |
547.2
547/.2 |
| Soggetto topico |
Organic compounds - Synthesis
Intermediates (Chemistry) Microreactors Organic reaction mechanisms |
| Soggetto genere / forma | Electronic books. |
| ISBN |
1-281-94011-9
9786611940119 0-470-72342-4 0-470-72341-6 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Flash Chemistry Fast Organic Synthesis in Microsystems; Contents; Preface; 1 Introduction; 1.1 Flask Chemistry; 1.2 Flash Chemistry; 1.3 Flask Chemistry or Flash Chemistry; References; 2 The Background to Flash Chemistry; 2.1 How do Chemical Reactions Take Place?; 2.1.1 Macroscopic View of Chemical Reactions; 2.1.2 Thermodynamic Equilibrium and Kinetics; 2.1.3 Kinetics; 2.1.4 Transition State Theory; 2.1.5 Femtosecond Chemistry and Reaction Dynamics; 2.1.6 Reactions for Dynamics and Reactions for Synthesis; 2.1.7 Bimolecular Reactions in the Gas Phase
2.1.8 Bimolecular Reactions in the Solution Phase2.1.9 Fast Chemical Synthesis Inspired by Reaction Dynamics; References; 3 What is Flash Chemistry?; 4 Why is Flash Chemistry Needed?; 4.1 Chemical Reaction, an Extremely Fast Process at Molecular Level; 4.2 Rapid Construction of Chemical Libraries; 4.3 Rapid Synthesis of Radioactive Positron Emission Tomography Probes; 4.4 On-demand Rapid Synthesis i n Industry 304.5 Conclusions; References; 5 Methods of Activating Molecules; 5.1 Thermal Activation of Organic Molecules; 5.1.1 High Temperature Reactions; 5.1.2 Flash Vacuum Pyrolysis 5.1.3 Microwave Reactions5.2 Photochemical Activation; 5.3 Electrochemical Activation; 5.4 Chemical Activation; 5.5 Accumulation of Reactive Species; 5.5.1 The Cation-pool Method; 5.6 Continuous Generation of Reactive Species in a Flow System; 5.7 Interconversion Between Reactive Species; 5.8 Conclusions; References; 6 Control of Extremely Fast Reactions; 6.1 Mixing; 6.1.1 How Does Mixing Take Place?; 6.1.2 Molecular Diffusion and Brownian Motion; 6.1.3 Disguised Chemical Selectivity; 6.1.4 Lowering the Reaction Temperature; 6.1.5 The High Dilution Method; 6.1.6 Micromixing 6.1.7 Friedel-Crafts Alkylation Using anN-acyliminium Ion Pool6.1.8 Micromixing as a Powerful Tool for Flash Chemistry; 6.1.9 Disguised Chemical Selectivity in Competitive Parallel Reactions; 6.2 Temperature Control; 6.2.1 Exothermicity of Fast Reactions; 6.2.2 Hammond's Postulate; 6.2.3 The Friedel-Crafts Reaction; 6.2.4 Solvent; 6.2.5 Heat Transfer; 6.2.6 Precise Temperature Control in Microflow Systems; 6.3 Residence Time Control; 6.3.1 The Discovery of Benzyne. The Concept of Reactive Intermediates; 6.3.2 o -Bromophenyllithi um; 6.4 Conclusions; References 7 Microfluidic Devices and Microflow Systems7.1 Brief History; 7.1.1 Microflow Systems for Chemical Analysis; 7.1.2 Microflow Systems for Chemical Synthesis; 7.2 Characteristic Features of Microflow Systems; 7.3 Microstructured Fluidic Devices; 7.3.1 Microchip Reactors; 7.3.2 Microtube Reactors; 7.3.3 Micromixer; 7.3.4 Passive Micromixers; 7.3.5 Microheat Exchanger; 7.3.6 Photochemical Microflow Reactor; 7.3.7 Electrochemical Microflow Reactor; 7.3.8 Catalyst-containing Microflow Reactor; 7.3.9 Microflow Reactors for High-pressure and High-temperature Conditions; 7.4 Conclusions; References 8 Applications of Flash Chemistry in Organic Synthesis |
| Record Nr. | UNINA-9910144100303321 |
|
Yoshida Junʼichi <1952->
|
||
| Hoboken, N.J., : Wiley, 2008 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Flash chemistry [[electronic resource] ] : fast organic synthesis in microsystems / / Jun-ichi Yoshida
| Flash chemistry [[electronic resource] ] : fast organic synthesis in microsystems / / Jun-ichi Yoshida |
| Autore | Yoshida Junʼichi <1952-> |
| Pubbl/distr/stampa | Hoboken, N.J., : Wiley, 2008 |
| Descrizione fisica | 1 online resource (248 p.) |
| Disciplina |
547.2
547/.2 |
| Soggetto topico |
Organic compounds - Synthesis
Intermediates (Chemistry) Microreactors Organic reaction mechanisms |
| ISBN |
1-281-94011-9
9786611940119 0-470-72342-4 0-470-72341-6 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Flash Chemistry Fast Organic Synthesis in Microsystems; Contents; Preface; 1 Introduction; 1.1 Flask Chemistry; 1.2 Flash Chemistry; 1.3 Flask Chemistry or Flash Chemistry; References; 2 The Background to Flash Chemistry; 2.1 How do Chemical Reactions Take Place?; 2.1.1 Macroscopic View of Chemical Reactions; 2.1.2 Thermodynamic Equilibrium and Kinetics; 2.1.3 Kinetics; 2.1.4 Transition State Theory; 2.1.5 Femtosecond Chemistry and Reaction Dynamics; 2.1.6 Reactions for Dynamics and Reactions for Synthesis; 2.1.7 Bimolecular Reactions in the Gas Phase
2.1.8 Bimolecular Reactions in the Solution Phase2.1.9 Fast Chemical Synthesis Inspired by Reaction Dynamics; References; 3 What is Flash Chemistry?; 4 Why is Flash Chemistry Needed?; 4.1 Chemical Reaction, an Extremely Fast Process at Molecular Level; 4.2 Rapid Construction of Chemical Libraries; 4.3 Rapid Synthesis of Radioactive Positron Emission Tomography Probes; 4.4 On-demand Rapid Synthesis i n Industry 304.5 Conclusions; References; 5 Methods of Activating Molecules; 5.1 Thermal Activation of Organic Molecules; 5.1.1 High Temperature Reactions; 5.1.2 Flash Vacuum Pyrolysis 5.1.3 Microwave Reactions5.2 Photochemical Activation; 5.3 Electrochemical Activation; 5.4 Chemical Activation; 5.5 Accumulation of Reactive Species; 5.5.1 The Cation-pool Method; 5.6 Continuous Generation of Reactive Species in a Flow System; 5.7 Interconversion Between Reactive Species; 5.8 Conclusions; References; 6 Control of Extremely Fast Reactions; 6.1 Mixing; 6.1.1 How Does Mixing Take Place?; 6.1.2 Molecular Diffusion and Brownian Motion; 6.1.3 Disguised Chemical Selectivity; 6.1.4 Lowering the Reaction Temperature; 6.1.5 The High Dilution Method; 6.1.6 Micromixing 6.1.7 Friedel-Crafts Alkylation Using anN-acyliminium Ion Pool6.1.8 Micromixing as a Powerful Tool for Flash Chemistry; 6.1.9 Disguised Chemical Selectivity in Competitive Parallel Reactions; 6.2 Temperature Control; 6.2.1 Exothermicity of Fast Reactions; 6.2.2 Hammond's Postulate; 6.2.3 The Friedel-Crafts Reaction; 6.2.4 Solvent; 6.2.5 Heat Transfer; 6.2.6 Precise Temperature Control in Microflow Systems; 6.3 Residence Time Control; 6.3.1 The Discovery of Benzyne. The Concept of Reactive Intermediates; 6.3.2 o -Bromophenyllithi um; 6.4 Conclusions; References 7 Microfluidic Devices and Microflow Systems7.1 Brief History; 7.1.1 Microflow Systems for Chemical Analysis; 7.1.2 Microflow Systems for Chemical Synthesis; 7.2 Characteristic Features of Microflow Systems; 7.3 Microstructured Fluidic Devices; 7.3.1 Microchip Reactors; 7.3.2 Microtube Reactors; 7.3.3 Micromixer; 7.3.4 Passive Micromixers; 7.3.5 Microheat Exchanger; 7.3.6 Photochemical Microflow Reactor; 7.3.7 Electrochemical Microflow Reactor; 7.3.8 Catalyst-containing Microflow Reactor; 7.3.9 Microflow Reactors for High-pressure and High-temperature Conditions; 7.4 Conclusions; References 8 Applications of Flash Chemistry in Organic Synthesis |
| Record Nr. | UNINA-9910830745903321 |
|
Yoshida Junʼichi <1952->
|
||
| Hoboken, N.J., : Wiley, 2008 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Flash chemistry [[electronic resource] ] : fast organic synthesis in microsystems / / Jun-ichi Yoshida
| Flash chemistry [[electronic resource] ] : fast organic synthesis in microsystems / / Jun-ichi Yoshida |
| Autore | Yoshida Junʼichi <1952-> |
| Pubbl/distr/stampa | Hoboken, N.J., : Wiley, 2008 |
| Descrizione fisica | 1 online resource (248 p.) |
| Disciplina |
547.2
547/.2 |
| Soggetto topico |
Organic compounds - Synthesis
Intermediates (Chemistry) Microreactors Organic reaction mechanisms |
| ISBN |
1-281-94011-9
9786611940119 0-470-72342-4 0-470-72341-6 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Flash Chemistry Fast Organic Synthesis in Microsystems; Contents; Preface; 1 Introduction; 1.1 Flask Chemistry; 1.2 Flash Chemistry; 1.3 Flask Chemistry or Flash Chemistry; References; 2 The Background to Flash Chemistry; 2.1 How do Chemical Reactions Take Place?; 2.1.1 Macroscopic View of Chemical Reactions; 2.1.2 Thermodynamic Equilibrium and Kinetics; 2.1.3 Kinetics; 2.1.4 Transition State Theory; 2.1.5 Femtosecond Chemistry and Reaction Dynamics; 2.1.6 Reactions for Dynamics and Reactions for Synthesis; 2.1.7 Bimolecular Reactions in the Gas Phase
2.1.8 Bimolecular Reactions in the Solution Phase2.1.9 Fast Chemical Synthesis Inspired by Reaction Dynamics; References; 3 What is Flash Chemistry?; 4 Why is Flash Chemistry Needed?; 4.1 Chemical Reaction, an Extremely Fast Process at Molecular Level; 4.2 Rapid Construction of Chemical Libraries; 4.3 Rapid Synthesis of Radioactive Positron Emission Tomography Probes; 4.4 On-demand Rapid Synthesis i n Industry 304.5 Conclusions; References; 5 Methods of Activating Molecules; 5.1 Thermal Activation of Organic Molecules; 5.1.1 High Temperature Reactions; 5.1.2 Flash Vacuum Pyrolysis 5.1.3 Microwave Reactions5.2 Photochemical Activation; 5.3 Electrochemical Activation; 5.4 Chemical Activation; 5.5 Accumulation of Reactive Species; 5.5.1 The Cation-pool Method; 5.6 Continuous Generation of Reactive Species in a Flow System; 5.7 Interconversion Between Reactive Species; 5.8 Conclusions; References; 6 Control of Extremely Fast Reactions; 6.1 Mixing; 6.1.1 How Does Mixing Take Place?; 6.1.2 Molecular Diffusion and Brownian Motion; 6.1.3 Disguised Chemical Selectivity; 6.1.4 Lowering the Reaction Temperature; 6.1.5 The High Dilution Method; 6.1.6 Micromixing 6.1.7 Friedel-Crafts Alkylation Using anN-acyliminium Ion Pool6.1.8 Micromixing as a Powerful Tool for Flash Chemistry; 6.1.9 Disguised Chemical Selectivity in Competitive Parallel Reactions; 6.2 Temperature Control; 6.2.1 Exothermicity of Fast Reactions; 6.2.2 Hammond's Postulate; 6.2.3 The Friedel-Crafts Reaction; 6.2.4 Solvent; 6.2.5 Heat Transfer; 6.2.6 Precise Temperature Control in Microflow Systems; 6.3 Residence Time Control; 6.3.1 The Discovery of Benzyne. The Concept of Reactive Intermediates; 6.3.2 o -Bromophenyllithi um; 6.4 Conclusions; References 7 Microfluidic Devices and Microflow Systems7.1 Brief History; 7.1.1 Microflow Systems for Chemical Analysis; 7.1.2 Microflow Systems for Chemical Synthesis; 7.2 Characteristic Features of Microflow Systems; 7.3 Microstructured Fluidic Devices; 7.3.1 Microchip Reactors; 7.3.2 Microtube Reactors; 7.3.3 Micromixer; 7.3.4 Passive Micromixers; 7.3.5 Microheat Exchanger; 7.3.6 Photochemical Microflow Reactor; 7.3.7 Electrochemical Microflow Reactor; 7.3.8 Catalyst-containing Microflow Reactor; 7.3.9 Microflow Reactors for High-pressure and High-temperature Conditions; 7.4 Conclusions; References 8 Applications of Flash Chemistry in Organic Synthesis |
| Record Nr. | UNINA-9910841300003321 |
|
Yoshida Junʼichi <1952->
|
||
| Hoboken, N.J., : Wiley, 2008 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
How to Solve Organic Reaction Mechanisms : A Stepwise Approach
| How to Solve Organic Reaction Mechanisms : A Stepwise Approach |
| Autore | Moloney Mark G |
| Edizione | [1st ed.] |
| Pubbl/distr/stampa | New York : , : John Wiley & Sons, Incorporated, , 2015 |
| Descrizione fisica | 1 online resource (245 pages) |
| Disciplina | 547/.2 |
| Soggetto topico | Organic reaction mechanisms |
| Soggetto genere / forma | Electronic books. |
| ISBN |
9781118698525
9781118401590 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto | Cover -- Title Page -- Copyright -- Contents -- Preface -- Abbreviations -- About the companion website -- Introduction -- Chapter 1 Nucleophilic substitution and elimination -- Nucleophilic substitution: SN1 and SN2 reactions -- Elimination: E1 and E2 eliminations -- Chapter 2 Alkene and alkyne chemistry -- Alkene and alkyne bonding -- Electrophilic addition -- Nucleophilic addition to C = C bonds conjugated to a C = O -- Other types of additions -- Chapter 3 Nucleophilic additions to carbonyl groups -- Chapter 4 Enolate chemistry -- Halogenation -- Deuteriation -- Alkylation -- Condensation reactions -- Chapter 5 Aromatic chemistry -- Bonding in aromatic compounds -- Electrophilic aromatic substitution (SEAr) -- Nucleophilic aromatic substitution (SNAr) -- Oxidation -- Chapter 6 Rearrangements -- Chapter 7 Ligand coupling processes -- Index -- EULA. |
| Record Nr. | UNINA-9910795986103321 |
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Moloney Mark G
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| New York : , : John Wiley & Sons, Incorporated, , 2015 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
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