Boronic acids [[electronic resource] ] : preparation and applications in organic synthesis, medicine and materials / / edited by Dennis G. Hall ; with a foreword by Akira Suszuki |
Edizione | [2nd completely rev. ed.] |
Pubbl/distr/stampa | Weinheim, : Wiley-VCH, c2011 |
Descrizione fisica | 1 online resource (729 p.) |
Disciplina | 547.05671 |
Altri autori (Persone) | HallDennis G. <1968-> |
Soggetto topico |
Organic acids
Organoboron compounds Organic acids - Therapeutic use Organoboron compounds - Therapeutic use Organic acids - Synthesis Organoboron compounds - Synthesis |
ISBN |
1-283-60404-3
9786613916495 3-527-33214-6 3-527-63934-9 3-527-63932-2 |
Formato | Materiale a stampa |
Livello bibliografico | Monografia |
Lingua di pubblicazione | eng |
Nota di contenuto |
Boronic Acids: Preparation and Applications in Organic Synthesis, Medicine and Materials; Foreword; Contents to Volume 1; Contents to Volume 2; Preface; List of Contributors; 1 Structure, Properties, and Preparation of Boronic Acid Derivatives: Overview of Their Reactions and Applications; 1.1 Introduction and Historical Background; 1.2 Structure and Properties of Boronic Acid Derivatives; 1.2.1 General Types and Nomenclature of Boronic Acid Derivatives; 1.2.2 Boronic Acids; 1.2.2.1 Structure and Bonding; 1.2.2.2 Physical Properties and Handling; 1.2.2.3 Safety Considerations
1.2.2.4 Acidic Character1.2.2.5 Chemical Stability; 1.2.3 Boronic Acid Derivatives; 1.2.3.1 Boroxines (Cyclic Anhydrides); 1.2.3.2 Boronic Esters; 1.2.3.3 Acyloxy- and Diacyloxyboronates; 1.2.3.4 Dialkoxyboranes and Other Heterocyclic Boranes; 1.2.3.5 Diboronyl Esters; 1.2.3.6 Azaborolidines and Other Boron-Nitrogen Heterocycles; 1.2.3.7 Dihaloboranes and Dihydroalkylboranes; 1.2.3.8 Trifluoro- and Trihydroxyborate Salts; 1.3 Preparation of Boronic Acids and Their Esters; 1.3.1 Arylboronic Acids; 1.3.1.1 Electrophilic Trapping of Arylmetal Intermediates with Borates 1.3.1.2 Transmetalation of Aryl Silanes and Stannanes1.3.1.3 Coupling of Aryl Halides with Diboronyl Reagents; 1.3.1.4 Direct Boronation by Transition Metal-Catalyzed Aromatic C-H Functionalization; 1.3.1.5 Cycloadditions of Alkynylboronates; 1.3.1.6 Other Methods; 1.3.2 Diboronic Acids; 1.3.3 Heterocyclic Boronic Acids; 1.3.4 Alkenylboronic Acids; 1.3.4.1 Electrophilic Trapping of Alkenylmetal Intermediates with Borates; 1.3.4.2 Transmetalation Methods; 1.3.4.3 Transition Metal-Catalyzed Coupling between Alkenyl Halides/ Triflates and Diboronyl Reagents; 1.3.4.4 Hydroboration of Alkynes 1.3.4.5 Alkene Metathesis1.3.4.6 Diboronylation and Silaboration of Unsaturated Compounds; 1.3.4.7 Other Methods; 1.3.5 Alkynylboronic Acids; 1.3.6 Alkylboronic Acids; 1.3.7 Allylic Boronic Acids; 1.3.8 Chemoselective Transformations of Compounds Containing a Boronic Acid (Ester) Substituent; 1.3.8.1 Oxidative Methods; 1.3.8.2 Reductive Methods; 1.3.8.3 Generation and Reactions of a-Boronyl-Substituted Carbanions and Radicals; 1.3.8.4 Reactions of a-Haloalkylboronic Esters; 1.3.8.5 Other Transformations; 1.3.8.6 Protection of Boronic Acids for Orthogonal Transformations 1.4 Isolation and Characterization1.4.1 Recrystallization and Chromatography; 1.4.2 Solid Supports for Boronic Acid Immobilization and Purification; 1.4.2.1 Diethanolaminomethyl Polystyrene; 1.4.2.2 Other Solid-Supported Diol Resins; 1.4.3 Analytical and Spectroscopic Methods for Boronic Acid Derivatives; 1.4.3.1 Melting Points, Combustion Analysis, and HPLC; 1.4.3.2 Mass Spectrometry; 1.4.3.3 Nuclear Magnetic Resonance Spectroscopy; 1.4.3.4 Other Spectroscopic Methods; 1.5 Overview of the Reactions of Boronic Acid Derivatives; 1.5.1 Metalation and Metal-Catalyzed Protodeboronation 1.5.2 Oxidative Replacement of Boron |
Record Nr. | UNINA-9910137968003321 |
Weinheim, : Wiley-VCH, c2011 | ||
Materiale a stampa | ||
Lo trovi qui: Univ. Federico II | ||
|
Boronic acids . Volume 2 Preparation and applications in organic synthesis, medicine and materials / / edited by Dennis G. Hall ; with a foreword by Akira Suszuki |
Edizione | [Second completely revised edition] |
Pubbl/distr/stampa | Weinheim : , : Wiley-VCH, , [2011] |
Descrizione fisica | 1 online resource (729 pages) |
Disciplina | 547.05671 |
Soggetto topico |
Àcids orgànics
Compostos organobòrics Organic acids Organoboron compounds Organic acids - Therapeutic use Organoboron compounds - Therapeutic use Organic acids - Synthesis Organoboron compounds - Synthesis |
ISBN |
9783527639328
1-283-60404-3 9786613916495 3-527-33214-6 3-527-63934-9 3-527-63932-2 |
Formato | Materiale a stampa |
Livello bibliografico | Monografia |
Lingua di pubblicazione | eng |
Nota di contenuto |
Boronic Acids: Preparation and Applications in Organic Synthesis, Medicine and Materials; Foreword; Contents to Volume 1; Contents to Volume 2; Preface; List of Contributors; 1 Structure, Properties, and Preparation of Boronic Acid Derivatives: Overview of Their Reactions and Applications; 1.1 Introduction and Historical Background; 1.2 Structure and Properties of Boronic Acid Derivatives; 1.2.1 General Types and Nomenclature of Boronic Acid Derivatives; 1.2.2 Boronic Acids; 1.2.2.1 Structure and Bonding; 1.2.2.2 Physical Properties and Handling; 1.2.2.3 Safety Considerations
1.2.2.4 Acidic Character1.2.2.5 Chemical Stability; 1.2.3 Boronic Acid Derivatives; 1.2.3.1 Boroxines (Cyclic Anhydrides); 1.2.3.2 Boronic Esters; 1.2.3.3 Acyloxy- and Diacyloxyboronates; 1.2.3.4 Dialkoxyboranes and Other Heterocyclic Boranes; 1.2.3.5 Diboronyl Esters; 1.2.3.6 Azaborolidines and Other Boron-Nitrogen Heterocycles; 1.2.3.7 Dihaloboranes and Dihydroalkylboranes; 1.2.3.8 Trifluoro- and Trihydroxyborate Salts; 1.3 Preparation of Boronic Acids and Their Esters; 1.3.1 Arylboronic Acids; 1.3.1.1 Electrophilic Trapping of Arylmetal Intermediates with Borates 1.3.1.2 Transmetalation of Aryl Silanes and Stannanes1.3.1.3 Coupling of Aryl Halides with Diboronyl Reagents; 1.3.1.4 Direct Boronation by Transition Metal-Catalyzed Aromatic C-H Functionalization; 1.3.1.5 Cycloadditions of Alkynylboronates; 1.3.1.6 Other Methods; 1.3.2 Diboronic Acids; 1.3.3 Heterocyclic Boronic Acids; 1.3.4 Alkenylboronic Acids; 1.3.4.1 Electrophilic Trapping of Alkenylmetal Intermediates with Borates; 1.3.4.2 Transmetalation Methods; 1.3.4.3 Transition Metal-Catalyzed Coupling between Alkenyl Halides/ Triflates and Diboronyl Reagents; 1.3.4.4 Hydroboration of Alkynes 1.3.4.5 Alkene Metathesis1.3.4.6 Diboronylation and Silaboration of Unsaturated Compounds; 1.3.4.7 Other Methods; 1.3.5 Alkynylboronic Acids; 1.3.6 Alkylboronic Acids; 1.3.7 Allylic Boronic Acids; 1.3.8 Chemoselective Transformations of Compounds Containing a Boronic Acid (Ester) Substituent; 1.3.8.1 Oxidative Methods; 1.3.8.2 Reductive Methods; 1.3.8.3 Generation and Reactions of a-Boronyl-Substituted Carbanions and Radicals; 1.3.8.4 Reactions of a-Haloalkylboronic Esters; 1.3.8.5 Other Transformations; 1.3.8.6 Protection of Boronic Acids for Orthogonal Transformations 1.4 Isolation and Characterization1.4.1 Recrystallization and Chromatography; 1.4.2 Solid Supports for Boronic Acid Immobilization and Purification; 1.4.2.1 Diethanolaminomethyl Polystyrene; 1.4.2.2 Other Solid-Supported Diol Resins; 1.4.3 Analytical and Spectroscopic Methods for Boronic Acid Derivatives; 1.4.3.1 Melting Points, Combustion Analysis, and HPLC; 1.4.3.2 Mass Spectrometry; 1.4.3.3 Nuclear Magnetic Resonance Spectroscopy; 1.4.3.4 Other Spectroscopic Methods; 1.5 Overview of the Reactions of Boronic Acid Derivatives; 1.5.1 Metalation and Metal-Catalyzed Protodeboronation 1.5.2 Oxidative Replacement of Boron |
Record Nr. | UNINA-9910817010203321 |
Weinheim : , : Wiley-VCH, , [2011] | ||
Materiale a stampa | ||
Lo trovi qui: Univ. Federico II | ||
|
Boronic acids [[electronic resource] ] : preparation and applications in organic synthesis and medicine / / edited by Dennis G. Hall |
Pubbl/distr/stampa | Weinheim, : Wiley-VCH |
Descrizione fisica | 1 online resource (577 p.) |
Disciplina | 547.05671 |
Altri autori (Persone) | HallDennis |
Soggetto topico |
Organic acids
Organoboron compounds Organic acids - Therapeutic use Organoboron compounds - Therapeutic use Organic acids - Synthesis Organoboron compounds - Synthesis |
Soggetto genere / forma | Electronic books. |
ISBN |
1-280-52116-3
9786610521166 3-527-60682-3 3-527-60654-8 1-60119-357-2 |
Formato | Materiale a stampa |
Livello bibliografico | Monografia |
Lingua di pubblicazione | eng |
Nota di contenuto |
Boronic Acids; Table of Contents; Preface; List of Authors; List of Abbreviations; 1 Structure, Properties, and Preparation Of Boronic Acid Derivatives. Overview of Their Reactions and Applications; 1.1 Introduction; 1.2 Structure and Properties of Boronic Acid Derivatives; 1.2.1 General Types and Nomenclature of Boronic Acid Derivatives; 1.2.2 Boronic Acids; 1.2.2.1 Structure and Bonding; 1.2.2.2 Physical Properties and Handling; 1.2.2.3 Safety Considerations; 1.2.2.4 Acidic Character; 1.2.2.5 Chemical Stability; 1.2.3 Boronic Acid Derivatives; 1.2.3.1 Boroxines; 1.2.3.2 Boronic Esters
1.2.3.3 Dialkoxyboranes and other Heterocyclic Boranes1.2.3.4 Diboronyl Esters; 1.2.3.5 Azaborolidines and other Boron Heterocycles; 1.2.3.6 Dihaloboranes and Monoalkylboranes; 1.2.3.7 Trifluoroborate Salts; 1.3 Synthesis of Boronic Acids and their Esters; 1.3.1 Arylboronic Acids; 1.3.1.1 Electrophilic Trapping of Arylmetal Intermediates with Borates; 1.3.1.2 Transmetallation of Aryl Silanes and Stannanes; 1.3.1.3 Coupling of Aryl Halides with Diboronyl Reagents; 1.3.1.4 Direct Boronylation by Transition Metal-catalyzed Aromatic C-H Functionalization; 1.3.1.5 Other Methods 1.3.2 Diboronic Acids1.3.3 Heterocyclic Boronic Acids; 1.3.4 Alkenylboronic Acids; 1.3.4.1 Electrophilic Trapping of Alkenymetal Intermediates with Borates; 1.3.4.2 Transmetallation Methods; 1.3.4.3 Transition-metal Catalyzed Coupling between Alkenyl Halides/Triflates and Diboronyl Reagents; 1.3.4.4 Hydroboration of Alkynes; 1.3.4.5 Alkene Metathesis; 1.3.4.6 Other Methods; 1.3.5 Alkynylboronic Acids; 1.3.6 Alkylboronic Acids; 1.3.7 Allylic Boronic Acids; 1.3.8 Chemoselective Transformations of Compounds containing a Boronic Acid (Ester) Substituent; 1.3.8.1 Oxidative Methods 1.3.8.2 Reductive Methods1.3.8.3 Generation and Reactions of α-Boronyl-substituted Carbanions and Radicals; 1.3.8.4 Reactions of (α-Haloalkyl)boronic Esters; 1.3.8.5 Other Transformations; 1.4 Isolation and Characterization; 1.4.1 Chromatography and Recrystallization; 1.4.2 Solid Supports for Boronic Acid Immobilization and Purification; 1.4.2.1 Diethanolaminomethyl Polystyrene; 1.4.2.2 Other Solid-supported Diol Resins; 1.4.2.3 Soluble Diol Approaches; 1.4.3 Analytical and Spectroscopic Methods for Boronic Acid Derivatives; 1.4.3.1 Melting Points and Combustion Analysis 1.4.3.2 Mass Spectrometry1.4.3.3 Nuclear Magnetic Resonance Spectroscopy; 1.4.3.4 Other Spectroscopic Methods; 1.5 Overview of the Reactions of Boronic Acid Derivatives; 1.5.1 Metallation and Metal-catalyzed Protodeboronation; 1.5.2 Oxidative Replacement of Boron; 1.5.2.1 Oxygenation; 1.5.2.2 Amination; 1.5.2.3 Halogenation; 1.5.3 Carbon-Carbon Bond forming Processes; 1.5.3.1 Palladium-catalyzed Cross-coupling with Carbon Halides (Suzuki Coupling); 1.5.3.2 Allylation of Carbonyl Compounds; 1.5.3.3 Uncatalyzed Additions to Imines and Iminiums 1.5.3.4 Rhodium-catalyzed Additions to Aldehydes and Alkenes |
Record Nr. | UNINA-9910144324903321 |
Weinheim, : Wiley-VCH | ||
Materiale a stampa | ||
Lo trovi qui: Univ. Federico II | ||
|
Boronic acids : preparation and applications in organic synthesis and medicine / / edited by Dennis G. Hall |
Pubbl/distr/stampa | Weinheim, : Wiley-VCH |
Descrizione fisica | 1 online resource (577 p.) |
Disciplina | 547.05671 |
Altri autori (Persone) | HallDennis |
Soggetto topico |
Organic acids
Organoboron compounds Organic acids - Therapeutic use Organoboron compounds - Therapeutic use Organic acids - Synthesis Organoboron compounds - Synthesis |
ISBN |
1-280-52116-3
9786610521166 3-527-60682-3 3-527-60654-8 1-60119-357-2 |
Formato | Materiale a stampa |
Livello bibliografico | Monografia |
Lingua di pubblicazione | eng |
Nota di contenuto |
Boronic Acids; Table of Contents; Preface; List of Authors; List of Abbreviations; 1 Structure, Properties, and Preparation Of Boronic Acid Derivatives. Overview of Their Reactions and Applications; 1.1 Introduction; 1.2 Structure and Properties of Boronic Acid Derivatives; 1.2.1 General Types and Nomenclature of Boronic Acid Derivatives; 1.2.2 Boronic Acids; 1.2.2.1 Structure and Bonding; 1.2.2.2 Physical Properties and Handling; 1.2.2.3 Safety Considerations; 1.2.2.4 Acidic Character; 1.2.2.5 Chemical Stability; 1.2.3 Boronic Acid Derivatives; 1.2.3.1 Boroxines; 1.2.3.2 Boronic Esters
1.2.3.3 Dialkoxyboranes and other Heterocyclic Boranes1.2.3.4 Diboronyl Esters; 1.2.3.5 Azaborolidines and other Boron Heterocycles; 1.2.3.6 Dihaloboranes and Monoalkylboranes; 1.2.3.7 Trifluoroborate Salts; 1.3 Synthesis of Boronic Acids and their Esters; 1.3.1 Arylboronic Acids; 1.3.1.1 Electrophilic Trapping of Arylmetal Intermediates with Borates; 1.3.1.2 Transmetallation of Aryl Silanes and Stannanes; 1.3.1.3 Coupling of Aryl Halides with Diboronyl Reagents; 1.3.1.4 Direct Boronylation by Transition Metal-catalyzed Aromatic C-H Functionalization; 1.3.1.5 Other Methods 1.3.2 Diboronic Acids1.3.3 Heterocyclic Boronic Acids; 1.3.4 Alkenylboronic Acids; 1.3.4.1 Electrophilic Trapping of Alkenymetal Intermediates with Borates; 1.3.4.2 Transmetallation Methods; 1.3.4.3 Transition-metal Catalyzed Coupling between Alkenyl Halides/Triflates and Diboronyl Reagents; 1.3.4.4 Hydroboration of Alkynes; 1.3.4.5 Alkene Metathesis; 1.3.4.6 Other Methods; 1.3.5 Alkynylboronic Acids; 1.3.6 Alkylboronic Acids; 1.3.7 Allylic Boronic Acids; 1.3.8 Chemoselective Transformations of Compounds containing a Boronic Acid (Ester) Substituent; 1.3.8.1 Oxidative Methods 1.3.8.2 Reductive Methods1.3.8.3 Generation and Reactions of α-Boronyl-substituted Carbanions and Radicals; 1.3.8.4 Reactions of (α-Haloalkyl)boronic Esters; 1.3.8.5 Other Transformations; 1.4 Isolation and Characterization; 1.4.1 Chromatography and Recrystallization; 1.4.2 Solid Supports for Boronic Acid Immobilization and Purification; 1.4.2.1 Diethanolaminomethyl Polystyrene; 1.4.2.2 Other Solid-supported Diol Resins; 1.4.2.3 Soluble Diol Approaches; 1.4.3 Analytical and Spectroscopic Methods for Boronic Acid Derivatives; 1.4.3.1 Melting Points and Combustion Analysis 1.4.3.2 Mass Spectrometry1.4.3.3 Nuclear Magnetic Resonance Spectroscopy; 1.4.3.4 Other Spectroscopic Methods; 1.5 Overview of the Reactions of Boronic Acid Derivatives; 1.5.1 Metallation and Metal-catalyzed Protodeboronation; 1.5.2 Oxidative Replacement of Boron; 1.5.2.1 Oxygenation; 1.5.2.2 Amination; 1.5.2.3 Halogenation; 1.5.3 Carbon-Carbon Bond forming Processes; 1.5.3.1 Palladium-catalyzed Cross-coupling with Carbon Halides (Suzuki Coupling); 1.5.3.2 Allylation of Carbonyl Compounds; 1.5.3.3 Uncatalyzed Additions to Imines and Iminiums 1.5.3.4 Rhodium-catalyzed Additions to Aldehydes and Alkenes |
Record Nr. | UNINA-9910877631603321 |
Weinheim, : Wiley-VCH | ||
Materiale a stampa | ||
Lo trovi qui: Univ. Federico II | ||
|