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Advances in inorganic chemistry . Volume sixty seven NOx related chemistry / / edited by Rudi van Eldik, José A. Olabe ; contributors, Dennis Awasabisah [and nineteen others]
| Advances in inorganic chemistry . Volume sixty seven NOx related chemistry / / edited by Rudi van Eldik, José A. Olabe ; contributors, Dennis Awasabisah [and nineteen others] |
| Pubbl/distr/stampa | Waltham, Massachusetts : , : Academic Press, , 2015 |
| Descrizione fisica | 1 online resource (388 p.) |
| Disciplina | 546 |
| Collana | Advances in Inorganic Chemistry |
| Soggetto topico |
Nitrogen oxides
Chemistry, Inorganic |
| Soggetto genere / forma | Electronic books. |
| ISBN | 0-12-801837-2 |
| Formato | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Front Cover; NOx Related Chemistry; Copyright; Contents; Contributors; Preface; Chapter One: NOx Linkage Isomerization in Metal Complexes; 1. Introduction; 1.1. Modes of binding of NOx moieties in monometallic complexes; 1.1.1. Nitric oxide complexes; 1.1.2. NO2 complexes; 1.1.3. NO3 complexes; 1.2. Methods that induce linkage isomerization; 1.3. Techniques for detecting linkage isomers; 1.4. Factors that affect linkage isomerization; 2. Linkage Isomerism in Non-Porphyrin NOx Complexes; 2.1. Group 6 (Cr and Mo) complexes; 2.1.1. NO complexes; 2.1.2. NO2 complexes
2.2. Group 7 (Mn and Re) complexes2.2.1. NO complexes; 2.3. Group 8 (Fe, Ru, and Os) complexes; 2.3.1. NO complexes; 2.3.2. NO2 complexes; 2.3.3. NO3 complexes; 2.4. Group 9 (Co, Rh, and Ir) complexes; 2.4.1. NO complexes; 2.4.2. NO2 complexes; 2.5. Group 10 (Ni, Pd, and Pt) complexes; 2.5.1. NO complexes; 2.5.2. NO2 complexes; 3. Linkage Isomerism in NOx-Coordinated Metalloporphyrins; 3.1. Manganese NOx porphyrins; 3.2. Ruthenium and iron NOx porphyrin complexes; 3.3. Cobalt NOx porphyrins; 3.4. Hyponitrite complexes of transition metal porphyrins 3.4.1. The nitric oxide dimer and its reduced forms3.4.2. Metal hyponitrite binding modes; 3.5. Heme proteins; 4. Conclusion; Acknowledgment; References; Chapter Two: Three Redox States of Metallonitrosyls in Aqueous Solution; 1. Introduction: General Scope; 2. Complexes with n=6; 2.1. Structure, spectroscopy, and electronic description. Total spin S=0. Dominant M-NO+ distribution; 2.1.1. Significance and importance of the ``back-bonding model ́ ́; 2.1.2. Role of the σ*-FeNO interaction in the trans-effect exerted over NO; 2.1.3. ``Negative ́ ́ trans-influence of the nitrosyl moiety 2.1.4. Different reactivity of the L ligand trans to NO2.1.5. Other metal centers: Validity of the formal charge descriptions; 2.1.6. Frontier MOs; 2.2. Formation and dissociation of NO-complexes: Nitrosylations and denitrosylations; 2.2.1. Reactions with M(II) precursors (M=Fe, Ru): Proton-assisted dehydration of bound nitrite; 2.2.2. Reactions with high-spin M(III) precursors; 2.2.3. Reactions with low-spin, nonheme Fe(III) systems; 2.2.4. Nitrosylation of nitrile-hydratase and models; 2.2.5. Nitrosylation of low-spin Fe(III)-heme models, [FeIII(TMPS)(CN)(H2O)]4- and [FeIII(TMPS)(CN)2]5- 2.2.6. Nitrosylations of other [FeIII(CN)5(Y)]n- complexes2.2.7. Nitrosylations with Ru(III) precursors; 2.2.8. Why is the release of NO so fast for the {FeIINO+} heme-nitrosyls?; 2.3. Electrophilic reactivity toward O-, N-, and S-binding nucleophiles; 2.3.1. General approach to electrophilic reactivity; 2.3.2. Correlation of nucleophilic rates with M(NO+)/M(NO) redox potentials; 3. Complexes with n=7; 3.1. Structure, spectroscopy, and electronic descriptions for 5- and 6-coordination. Total spin S=1/2 or 3/2. Alternative...; 3.1.1. Heme and nonheme 5C nitrosyls with S=1/2 3.1.2. Nonheme and heme 6C nitrosyls with S=1/2 |
| Record Nr. | UNINA-9910460523103321 |
| Waltham, Massachusetts : , : Academic Press, , 2015 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Advances in inorganic chemistry . Volume sixty seven NOx related chemistry / / edited by Rudi van Eldik, José A. Olabe ; contributors, Dennis Awasabisah [and nineteen others]
| Advances in inorganic chemistry . Volume sixty seven NOx related chemistry / / edited by Rudi van Eldik, José A. Olabe ; contributors, Dennis Awasabisah [and nineteen others] |
| Pubbl/distr/stampa | Waltham, Massachusetts : , : Academic Press, , 2015 |
| Descrizione fisica | 1 online resource (388 p.) |
| Disciplina | 546 |
| Collana | Advances in Inorganic Chemistry |
| Soggetto topico |
Nitrogen oxides
Chemistry, Inorganic |
| ISBN | 0-12-801837-2 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Front Cover; NOx Related Chemistry; Copyright; Contents; Contributors; Preface; Chapter One: NOx Linkage Isomerization in Metal Complexes; 1. Introduction; 1.1. Modes of binding of NOx moieties in monometallic complexes; 1.1.1. Nitric oxide complexes; 1.1.2. NO2 complexes; 1.1.3. NO3 complexes; 1.2. Methods that induce linkage isomerization; 1.3. Techniques for detecting linkage isomers; 1.4. Factors that affect linkage isomerization; 2. Linkage Isomerism in Non-Porphyrin NOx Complexes; 2.1. Group 6 (Cr and Mo) complexes; 2.1.1. NO complexes; 2.1.2. NO2 complexes
2.2. Group 7 (Mn and Re) complexes2.2.1. NO complexes; 2.3. Group 8 (Fe, Ru, and Os) complexes; 2.3.1. NO complexes; 2.3.2. NO2 complexes; 2.3.3. NO3 complexes; 2.4. Group 9 (Co, Rh, and Ir) complexes; 2.4.1. NO complexes; 2.4.2. NO2 complexes; 2.5. Group 10 (Ni, Pd, and Pt) complexes; 2.5.1. NO complexes; 2.5.2. NO2 complexes; 3. Linkage Isomerism in NOx-Coordinated Metalloporphyrins; 3.1. Manganese NOx porphyrins; 3.2. Ruthenium and iron NOx porphyrin complexes; 3.3. Cobalt NOx porphyrins; 3.4. Hyponitrite complexes of transition metal porphyrins 3.4.1. The nitric oxide dimer and its reduced forms3.4.2. Metal hyponitrite binding modes; 3.5. Heme proteins; 4. Conclusion; Acknowledgment; References; Chapter Two: Three Redox States of Metallonitrosyls in Aqueous Solution; 1. Introduction: General Scope; 2. Complexes with n=6; 2.1. Structure, spectroscopy, and electronic description. Total spin S=0. Dominant M-NO+ distribution; 2.1.1. Significance and importance of the ``back-bonding model ́ ́; 2.1.2. Role of the σ*-FeNO interaction in the trans-effect exerted over NO; 2.1.3. ``Negative ́ ́ trans-influence of the nitrosyl moiety 2.1.4. Different reactivity of the L ligand trans to NO2.1.5. Other metal centers: Validity of the formal charge descriptions; 2.1.6. Frontier MOs; 2.2. Formation and dissociation of NO-complexes: Nitrosylations and denitrosylations; 2.2.1. Reactions with M(II) precursors (M=Fe, Ru): Proton-assisted dehydration of bound nitrite; 2.2.2. Reactions with high-spin M(III) precursors; 2.2.3. Reactions with low-spin, nonheme Fe(III) systems; 2.2.4. Nitrosylation of nitrile-hydratase and models; 2.2.5. Nitrosylation of low-spin Fe(III)-heme models, [FeIII(TMPS)(CN)(H2O)]4- and [FeIII(TMPS)(CN)2]5- 2.2.6. Nitrosylations of other [FeIII(CN)5(Y)]n- complexes2.2.7. Nitrosylations with Ru(III) precursors; 2.2.8. Why is the release of NO so fast for the {FeIINO+} heme-nitrosyls?; 2.3. Electrophilic reactivity toward O-, N-, and S-binding nucleophiles; 2.3.1. General approach to electrophilic reactivity; 2.3.2. Correlation of nucleophilic rates with M(NO+)/M(NO) redox potentials; 3. Complexes with n=7; 3.1. Structure, spectroscopy, and electronic descriptions for 5- and 6-coordination. Total spin S=1/2 or 3/2. Alternative...; 3.1.1. Heme and nonheme 5C nitrosyls with S=1/2 3.1.2. Nonheme and heme 6C nitrosyls with S=1/2 |
| Record Nr. | UNINA-9910787446903321 |
| Waltham, Massachusetts : , : Academic Press, , 2015 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Advances in inorganic chemistry . Volume sixty seven NOx related chemistry / / edited by Rudi van Eldik, José A. Olabe ; contributors, Dennis Awasabisah [and nineteen others]
| Advances in inorganic chemistry . Volume sixty seven NOx related chemistry / / edited by Rudi van Eldik, José A. Olabe ; contributors, Dennis Awasabisah [and nineteen others] |
| Pubbl/distr/stampa | Waltham, Massachusetts : , : Academic Press, , 2015 |
| Descrizione fisica | 1 online resource (388 p.) |
| Disciplina | 546 |
| Collana | Advances in Inorganic Chemistry |
| Soggetto topico |
Nitrogen oxides
Chemistry, Inorganic |
| ISBN | 0-12-801837-2 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Front Cover; NOx Related Chemistry; Copyright; Contents; Contributors; Preface; Chapter One: NOx Linkage Isomerization in Metal Complexes; 1. Introduction; 1.1. Modes of binding of NOx moieties in monometallic complexes; 1.1.1. Nitric oxide complexes; 1.1.2. NO2 complexes; 1.1.3. NO3 complexes; 1.2. Methods that induce linkage isomerization; 1.3. Techniques for detecting linkage isomers; 1.4. Factors that affect linkage isomerization; 2. Linkage Isomerism in Non-Porphyrin NOx Complexes; 2.1. Group 6 (Cr and Mo) complexes; 2.1.1. NO complexes; 2.1.2. NO2 complexes
2.2. Group 7 (Mn and Re) complexes2.2.1. NO complexes; 2.3. Group 8 (Fe, Ru, and Os) complexes; 2.3.1. NO complexes; 2.3.2. NO2 complexes; 2.3.3. NO3 complexes; 2.4. Group 9 (Co, Rh, and Ir) complexes; 2.4.1. NO complexes; 2.4.2. NO2 complexes; 2.5. Group 10 (Ni, Pd, and Pt) complexes; 2.5.1. NO complexes; 2.5.2. NO2 complexes; 3. Linkage Isomerism in NOx-Coordinated Metalloporphyrins; 3.1. Manganese NOx porphyrins; 3.2. Ruthenium and iron NOx porphyrin complexes; 3.3. Cobalt NOx porphyrins; 3.4. Hyponitrite complexes of transition metal porphyrins 3.4.1. The nitric oxide dimer and its reduced forms3.4.2. Metal hyponitrite binding modes; 3.5. Heme proteins; 4. Conclusion; Acknowledgment; References; Chapter Two: Three Redox States of Metallonitrosyls in Aqueous Solution; 1. Introduction: General Scope; 2. Complexes with n=6; 2.1. Structure, spectroscopy, and electronic description. Total spin S=0. Dominant M-NO+ distribution; 2.1.1. Significance and importance of the ``back-bonding model ́ ́; 2.1.2. Role of the σ*-FeNO interaction in the trans-effect exerted over NO; 2.1.3. ``Negative ́ ́ trans-influence of the nitrosyl moiety 2.1.4. Different reactivity of the L ligand trans to NO2.1.5. Other metal centers: Validity of the formal charge descriptions; 2.1.6. Frontier MOs; 2.2. Formation and dissociation of NO-complexes: Nitrosylations and denitrosylations; 2.2.1. Reactions with M(II) precursors (M=Fe, Ru): Proton-assisted dehydration of bound nitrite; 2.2.2. Reactions with high-spin M(III) precursors; 2.2.3. Reactions with low-spin, nonheme Fe(III) systems; 2.2.4. Nitrosylation of nitrile-hydratase and models; 2.2.5. Nitrosylation of low-spin Fe(III)-heme models, [FeIII(TMPS)(CN)(H2O)]4- and [FeIII(TMPS)(CN)2]5- 2.2.6. Nitrosylations of other [FeIII(CN)5(Y)]n- complexes2.2.7. Nitrosylations with Ru(III) precursors; 2.2.8. Why is the release of NO so fast for the {FeIINO+} heme-nitrosyls?; 2.3. Electrophilic reactivity toward O-, N-, and S-binding nucleophiles; 2.3.1. General approach to electrophilic reactivity; 2.3.2. Correlation of nucleophilic rates with M(NO+)/M(NO) redox potentials; 3. Complexes with n=7; 3.1. Structure, spectroscopy, and electronic descriptions for 5- and 6-coordination. Total spin S=1/2 or 3/2. Alternative...; 3.1.1. Heme and nonheme 5C nitrosyls with S=1/2 3.1.2. Nonheme and heme 6C nitrosyls with S=1/2 |
| Record Nr. | UNINA-9910814434003321 |
| Waltham, Massachusetts : , : Academic Press, , 2015 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
BOREAS TF-1 SSA-OA weekly tower CH₄ and N₂O flux / / George Thurtell and Grant Edwards, Isobel Simpson
| BOREAS TF-1 SSA-OA weekly tower CH₄ and N₂O flux / / George Thurtell and Grant Edwards, Isobel Simpson |
| Autore | Thurtell George |
| Pubbl/distr/stampa | Greenbelt, Maryland : , : National Aeronautics and Space Administration, Goddard Space Flight Center, , October 2000 |
| Descrizione fisica | 1 online resource (15 pages) |
| Collana |
Technical report series on the Boreal Ecosystem-Atmosphere Study (BOREAS)
NASA/TM |
| Soggetto topico |
Data acquisition
Energy transfer Flux density Nitrogen oxides Trace contaminants |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Altri titoli varianti | Boreal ecosystem-atmosphere study tower flux 1 Southern Study Area Old Aspen weekly tower methane and nitrous oxide flux |
| Record Nr. | UNINA-9910695542603321 |
Thurtell George
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| Greenbelt, Maryland : , : National Aeronautics and Space Administration, Goddard Space Flight Center, , October 2000 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Catalysts for low temperature conversion of nitrogen oxides / / vorgelegte dissertation von Martin Ingo Busch
| Catalysts for low temperature conversion of nitrogen oxides / / vorgelegte dissertation von Martin Ingo Busch |
| Autore | Busch Martin Ingo |
| Edizione | [1. Auflage.] |
| Pubbl/distr/stampa | Gottingen, [Germany] : , : Cuvillier Verlag, , 2015 |
| Descrizione fisica | 1 online resource (146 pages) : illustrations, graphs, tables |
| Disciplina | 547.2 |
| Soggetto topico |
Nitrogen oxides
Zeolite catalysts |
| Soggetto genere / forma | Electronic books. |
| ISBN | 3-7369-4990-1 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNINA-9910511434803321 |
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Busch Martin Ingo
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| Gottingen, [Germany] : , : Cuvillier Verlag, , 2015 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Catalysts for low temperature conversion of nitrogen oxides / / vorgelegte dissertation von Martin Ingo Busch
| Catalysts for low temperature conversion of nitrogen oxides / / vorgelegte dissertation von Martin Ingo Busch |
| Autore | Busch Martin Ingo |
| Edizione | [1. Auflage.] |
| Pubbl/distr/stampa | Gottingen, [Germany] : , : Cuvillier Verlag, , 2015 |
| Descrizione fisica | 1 online resource (146 pages) : illustrations, graphs, tables |
| Disciplina | 547.2 |
| Soggetto topico |
Nitrogen oxides
Zeolite catalysts |
| ISBN | 3-7369-4990-1 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNINA-9910794943103321 |
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Busch Martin Ingo
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| Gottingen, [Germany] : , : Cuvillier Verlag, , 2015 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Catalysts for low temperature conversion of nitrogen oxides / / vorgelegte dissertation von Martin Ingo Busch
| Catalysts for low temperature conversion of nitrogen oxides / / vorgelegte dissertation von Martin Ingo Busch |
| Autore | Busch Martin Ingo |
| Edizione | [1. Auflage.] |
| Pubbl/distr/stampa | Gottingen, [Germany] : , : Cuvillier Verlag, , 2015 |
| Descrizione fisica | 1 online resource (146 pages) : illustrations, graphs, tables |
| Disciplina | 547.2 |
| Soggetto topico |
Nitrogen oxides
Zeolite catalysts |
| ISBN | 3-7369-4990-1 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNINA-9910809316503321 |
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Busch Martin Ingo
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| Gottingen, [Germany] : , : Cuvillier Verlag, , 2015 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Comparing spray characteristics from Reynolds Averaged Navier-Stokes (RANS) National Combustion Code (NCC) calculations against experimental data for a turbulent reacting flow [[electronic resource] /] / Anthony C. Iannetti and Jeffery P. Moder ; prepared for the 48th Aerospace Sciences Meeting sponsored by the American Institute of Aeronautics and Astronautics, Orlando, Florida, January 4-7, 2010
| Comparing spray characteristics from Reynolds Averaged Navier-Stokes (RANS) National Combustion Code (NCC) calculations against experimental data for a turbulent reacting flow [[electronic resource] /] / Anthony C. Iannetti and Jeffery P. Moder ; prepared for the 48th Aerospace Sciences Meeting sponsored by the American Institute of Aeronautics and Astronautics, Orlando, Florida, January 4-7, 2010 |
| Autore | Iannetti Anthony C |
| Pubbl/distr/stampa | Cleveland, Ohio : , : National Aeronautics and Space Administration, Glenn Research Center, , [2010] |
| Descrizione fisica | 1 online resource (v, 39 pages) : illustrations |
| Altri autori (Persone) | ModerJeffrey P |
| Collana | NASA/TM |
| Soggetto topico |
Computational fluid dynamics
Turbulent flow Spray characteristics Jet engine fuels Reaction kinetics Hydrocarbons Sulfur dioxides Nitrogen oxides Exhaust emission Fuel injection |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Altri titoli varianti | Comparing spray characteristics from Reynolds Averaged Navier-Stokes |
| Record Nr. | UNINA-9910699641303321 |
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Iannetti Anthony C
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| Cleveland, Ohio : , : National Aeronautics and Space Administration, Glenn Research Center, , [2010] | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
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Development of high temperature gas sensor technology / / Gary W. Hunter [and six others]
| Development of high temperature gas sensor technology / / Gary W. Hunter [and six others] |
| Autore | Hunter G. W (Gary W.) |
| Pubbl/distr/stampa | Cleveland, Ohio : , : National Aeronautics and Space Administration, Lewis Research Center, , June 1997 |
| Descrizione fisica | 1 online resource (7 pages) : illustrations |
| Collana | NASA technical memorandum |
| Soggetto topico |
Gas detectors
Temperature sensors Exhaust emission Exhaust gases High temperature gases Hydrocarbons Nitrogen oxides Oxygen Research and development |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNINA-9910707609303321 |
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Hunter G. W (Gary W.)
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| Cleveland, Ohio : , : National Aeronautics and Space Administration, Lewis Research Center, , June 1997 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
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Draft regulatory analysis, environmental impact statement and NOx pollutant specific study for proposed gaseous emission regulations for 1985 and later model year light-duty trucks and 1986 and later model year heavy-duty engines / / prepared by Office of Mobile Source Air Pollution Control
| Draft regulatory analysis, environmental impact statement and NOx pollutant specific study for proposed gaseous emission regulations for 1985 and later model year light-duty trucks and 1986 and later model year heavy-duty engines / / prepared by Office of Mobile Source Air Pollution Control |
| Pubbl/distr/stampa | [Washington, D.C.] : , : [U.S. Environmental Protection Agency, Office of Mobile Source Air Pollution Control], , 1981 |
| Descrizione fisica | 1 online resource (226 pages) : illustrations |
| Soggetto topico |
Automobiles - Motors - Exhaust gas - Standards
Nitrogen oxides |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNINA-9910711842103321 |
| [Washington, D.C.] : , : [U.S. Environmental Protection Agency, Office of Mobile Source Air Pollution Control], , 1981 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
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Soggetto topico
-
Nitrogen oxides
(35)
- Fuel injection (4)
- Hydrocarbons (4)
- Chemistry (3)
- Chemistry, Inorganic (3)