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Handbook of metathesis . Volume 1 : catalyst development and mechanism / / edited by Robert H. Grubbs and Anna G. Wenzel
| Handbook of metathesis . Volume 1 : catalyst development and mechanism / / edited by Robert H. Grubbs and Anna G. Wenzel |
| Edizione | [2nd ed.] |
| Pubbl/distr/stampa | Weinheim, Germany : , : Wiley-VCH Verlag GmbH & Co., , 2015 |
| Descrizione fisica | 1 online resource (444 p.) |
| Disciplina | 660.299 |
| Soggetto topico |
Metathesis (Chemistry)
Metal catalysts - Industrial applications |
| ISBN |
3-527-69399-8
3-527-69400-5 |
| Formato | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Cover; Contents; Preface; List of Contributors; Chapter 1 High-Oxidation State Molybdenum and Tungsten Complexes Relevant to Olefin Metathesis; 1.1 Introduction; 1.2 New Imido Ligands and Synthetic Approaches; 1.3 Bispyrrolide and Related Complexes; 1.4 Monoalkoxide Pyrrolide (MAP) Complexes; 1.5 Reactions of Alkylidenes with Olefins; 1.6 Olefin and Metallacyclopentane Complexes; 1.7 Tungsten Oxo Complexes; 1.8 Bisaryloxides; 1.9 Other Constructs; 1.10 Conclusions; Acknowledgments; References; Chapter 2 Alkane Metathesis; 2.1 Introduction; 2.2 Alkane Metathesis by Single-Catalyst Systems
2.2.1 Supported Metal Hydrides2.2.1.1 Supported Zr-Polyhydrides; 2.2.1.2 Supported Ta-Polyhydrides; 2.2.1.3 Supported W-Polyhydrides; 2.2.2 Metal Alkylidene/Alkylidyne on Surface Oxide; 2.2.2.1 Structure-Activity Relationship of Alkylidene Complexes; 2.2.2.2 Stoichiometric Activity of Well-Defined, Metal Alkylidenes with Alkanes; 2.2.2.3 Synthesis of Supported WMe6 on Silica; 2.3 Alkane Metathesis by Tandem, Dual-Catalytic Systems; 2.3.1 Introduction; 2.3.2 The Chevron Process Using WO3/SiO2 and Pt-Li/Al2O3 2.3.3 Tandem, Dual Catalytic System Using Ir-Pincer Ligands and Mo-Alkylidene Complexes2.3.3.1 The Development of Robust, Iridium-Based Alkane Dehydrogenation Catalysts; 2.3.3.2 Cyclic and Cross-Alkane Metathesis; 2.4 Conclusion; References; Chapter 3 Diastereocontrol in Olefin Metathesis: the Development of Z-Selective Ruthenium Catalysts; 3.1 Introduction; 3.2 The Challenge of Z-Selective Olefin Metathesis; 3.3 Previous Strategies; 3.4 A Serendipitous Discovery; 3.5 Catalyst Studies; 3.5.1 Summary of Substituent Effects; 3.5.1.1 Investigating the X-type Ligand; 3.5.1.2 Effect of the NHC 3.5.2 Decomposition of Z-Selective Ru Metathesis Catalysts3.6 Applications of Z-Selective Ru Metathesis Catalysts; 3.6.1 Cross Metathesis; 3.6.1.1 Homodimerization or Homocoupling; 3.6.1.2 Other Cross-Metathesis Reactions; 3.6.2 Ring-Closing Metathesis (RCM); 3.6.3 Ring-Opening Metathesis Polymerization (ROMP); 3.7 Conclusion; References; Chapter 4 Ruthenium Olefin Metathesis Catalysts Supported by Cyclic Alkyl Aminocarbenes (CAACs); 4.1 Introduction; 4.2 Properties and Preparation of CAAC Ligands; 4.3 CAAC-Supported, Ruthenium Olefin Metathesis Catalysts 4.3.1 CAAC Catalyst Development and Their Application to Ring-Closing Metathesis4.3.2 Application to Cross Metathesis, Ethenolysis, and Degenerate Metathesis; 4.4 Summary; References; Chapter 5 Supported Catalysts and Nontraditional Reaction Media; 5.1 Introduction; 5.2 Supported Catalyst Systems; 5.2.1 Supported Catalysts via Covalent Interactions; 5.2.1.1 Grubbs-Type, Ru-Based Systems; 5.2.1.2 Schrock-Type, Mo- or W-Based Systems; 5.2.2 Supported Catalysts via Non-covalent Interactions; 5.2.2.1 Grubbs-Type, Ru-Based Systems; 5.2.2.2 Early Transition-Metal Systems 5.3 Olefin Metathesis in Nontraditional Media |
| Record Nr. | UNINA-9910787418703321 |
| Weinheim, Germany : , : Wiley-VCH Verlag GmbH & Co., , 2015 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Handbook of metathesis . Volume 3 Polymer synthesis / / edited by Robert H. Grubbs and Ezat Khosravi
| Handbook of metathesis . Volume 3 Polymer synthesis / / edited by Robert H. Grubbs and Ezat Khosravi |
| Edizione | [2nd ed.] |
| Pubbl/distr/stampa | Weinheim, Germany : , : Wiley-VCH, , 2015 |
| Descrizione fisica | 1 online resource (424 p.) |
| Disciplina | 547.412 |
| Soggetto topico |
Polymerization
Metathesis (Chemistry) |
| ISBN |
3-527-69405-6
3-527-69407-2 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | ger |
| Nota di contenuto |
Cover; Contents; Preface; List of Contributors; Chapter 1 Synthesis of Homopolymers and Copolymers; 1.1 Introduction; 1.2 Initiators; 1.3 Monomers; 1.4 Synthesis of Polymers with Complex Architectures; 1.5 Stereochemistry and Sequence Control in ROMP; 1.6 Conclusion; References; Chapter 2 ROMP in Dispersed Media; 2.1 Introduction; 2.2 Emulsion ROMP; 2.2.1 Mini-emulsion ROMP; 2.2.2 Micro-emulsion ROMP; 2.2.3 Micellar ROMP; 2.2.4 ROMP in Nonaqueous Emulsions; 2.3 Dispersion ROMP; 2.3.1 Biomedical Applications of PNBE-PEO Core-Shell Nanoparticles; 2.4 Suspension ROMP
2.5 Formation of Nanoparticles2.5.1 Photoactive ROMP Assemblies; 2.5.2 Miscellaneous; 2.6 Conclusion; References; Chapter 3 Telechelic Polymers; 3.1 Introduction; 3.2 Mono-telechelic Polymers; 3.2.1 Reaction with Substituted Vinyl Ethers; 3.2.2 Vinyl Lactone Quenching; 3.2.3 Terminal Cross Metathesis; 3.2.3.1 Using Symmetrical Olefins; 3.2.3.2 Using Asymmetrical Olefins; 3.2.4 Reaction with Oxygen; 3.2.5 Sacrificial Diblock Copolymer Synthesis; 3.2.6 Catalyst Prefunctionalization; 3.2.6.1 Functional Catalysts from Precursor Complexes; 3.2.6.2 Functional Catalysts via Cross Metathesis 3.2.7 Aldehyde Quenching3.3 Homo-telechelic Polymers; 3.3.1 Degradation of Unsaturated Polymers and ADMET Polymerization; 3.3.2 ROMP/Chain Transfer; 3.3.3 Sacrificial Multiblock Copolymers; 3.4 Hetero-telechelic Polymers; 3.4.1 Prefunctionalization with Functional Alkylidene Initiators; 3.4.2 Prefunctionalization with Sacrificial Synthesis; 3.5 Conclusions and Outlook; Acknowledgments; References; Chapter 4 Supramolecular Polymers; 4.1 Introduction; 4.2 Main-Chain Supramolecular Polymers; 4.2.1 Macromonomers; 4.2.2 ABC Triblock Copolymers; 4.3 Side-Chain-Functionalized Supramolecular Polymers 4.3.1 Hydrogen-Bonding Recognition Motifs4.3.2 Metal Coordination-Based Recognition Motifs; 4.3.3 Mixed Orthogonal Recognition Motifs; 4.4 Supramolecular Architectures by Design; 4.5 Conclusion; References; Chapter 5 Synthesis of Materials with Nanostructured Periodicity; 5.1 Introduction; 5.2 Sequential ROMP; 5.3 Inorganic Composite Materials; 5.4 ABA Triblock Copolymers; 5.5 Nanostructures with Domain Sizes Exceeding 100 nm; 5.6 Conclusions; References; Chapter 6 Synthesis of Nanoparticles; 6.1 Introduction; 6.2 Formation of Nanoparticles; 6.3 Synthesis via Grafting-through Approach 6.4 Synthesis via Grafting-to Approach6.4.1 Grafting-to Polymer Backbones via an Activated Ester; 6.4.2 Grafting-to Polymer Backbones via Copper-Catalyzed Click Reaction; 6.5 Synthesis via Grafting-from Approach; 6.6 Summary; References; Chapter 7 Synthesis of Biodegradable Copolymers; 7.1 Introduction; 7.2 Polyester-Functionalized Polymers; 7.3 Peptide-Functionalized Polymers; 7.4 Carbohydrate-Functionalized Polymers; 7.5 Antimicrobial Polymers; 7.6 Polymeric Betaines; 7.7 ROMP Polymers as Drug Carriers; 7.8 ROMP Polymers for Tissue Scaffolds; 7.9 Conclusion; References Chapter 8 Biologically Active Polymers |
| Record Nr. | UNINA-9910787418803321 |
| Weinheim, Germany : , : Wiley-VCH, , 2015 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Handbook of metathesis . Volume 2 Applications in organic synthesis / / editors, Prof. Robert H. Grubbs, Prof. Daniel J. O'Leary
| Handbook of metathesis . Volume 2 Applications in organic synthesis / / editors, Prof. Robert H. Grubbs, Prof. Daniel J. O'Leary |
| Edizione | [2nd ed.] |
| Pubbl/distr/stampa | Weinheim an der Bergstrasse, Germany : , : Wiley-VCH, , 2015 |
| Descrizione fisica | 1 online resource (772 p.) |
| Disciplina | 660.299 |
| Soggetto topico |
Metathesis (Chemistry)
Alkenes Organic compounds - Synthesis |
| ISBN |
3-527-69404-8
3-527-69402-1 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Cover; Contents; Preface; List of Contributors; List of Abbreviations; Chapter 1 General Ring-Closing Metathesis; 1.1 Introduction; 1.2 Carbocycles (Introduction); 1.2.1 Small-Sized Carbocycles; 1.2.2 Medium-Sized Carbocycles; 1.2.3 Spiro Carbocycles; 1.3 Synthesis of Bridged Bicycloalkenes; 1.4 Synthesis of Heterocycles Containing Si, P, S, or B; 1.4.1 Si-Heterocycles; 1.4.2 P-Heterocycles; 1.4.3 S-Heterocycles; 1.4.4 B-Heterocycles; 1.5 Synthesis of O-Heterocycles; 1.5.1 Small and Medium-Size Cyclic Ethers; 1.5.2 Polycyclic Ethers; 1.6 Synthesis of N-Heterocycles; 1.6.1 N-Heterocycles
1.6.2 Small and Medium-Sized Lactams1.7 Synthesis of Cyclic Conjugated Dienes; 1.8 Alkyne Metathesis; 1.9 Enyne Metathesis; 1.9.1 General Enyne Metathesis; 1.9.2 Dienyne Metathesis; 1.10 Tandem Processes; 1.10.1 Tandem ROM/RCM; 1.10.2 Other Tandem RCMs; 1.11 Synthesis of Macrocycles; 1.11.1 Macrocycles; 1.11.2 Macrolactones; 1.11.3 Macrolactams; 1.12 RCM and Isomerization via Ru-H; 1.13 Relay RCM (RRCM); 1.14 Z-Selective RCM; 1.14.1 Substrate-Controlled Z-Selective RCM; 1.14.2 Catalyst-Controlled Z-Selective RCM; 1.15 Enantioselective RCM; 1.16 Conclusion; Acknowledgments; References Chapter 2 Cross-Metathesis2.1 Early Examples Using Well-Defined Molybdenum and Ruthenium Catalysts; 2.2 The General Model for Selectivity in CM Reactions; 2.3 Definition of Cross-Metathesis Reaction Categories and Chapter Organization; 2.4 Hydrocarbons; 2.4.1 Alkane Extensions; 2.4.2 Unsaturated Hydrocarbons, Including Styrene; 2.4.3 Ethylene Cross-Metathesis; 2.5 Boron; 2.6 Nitrogen; 2.6.1 Amines; 2.6.2 Amines as CM Partners in Heterocycle Syntheses; 2.6.3 Acrylonitrile and Other Nitrile-Based CM Applications; 2.6.4 Other Nitrogenous Substrates; 2.7 Oxygen 2.7.1 Primary Allylic Alcohols and Derivatives2.7.2 Secondary Allylic Alcohols and Derivatives; 2.7.3 Tertiary Allylic Alcohols and Derivatives; 2.7.4 Homoallylic Alcohols and Derivatives; 2.7.5 Vinyl Ethers; 2.7.6 Acrolein, Crotonaldehyde, and Methacrolein; 2.7.7 Methyl Vinyl Ketone and Related Systems; 2.7.8 Acrylic Acid; 2.7.9 Acrylic Acid Derivatives, Including Esters, Thioesters, and Amides; 2.8 Halides; 2.9 Phosphorus; 2.10 Sulfur; 2.11 Fragment Coupling Reactions; 2.11.1 Acetogenins; 2.11.2 Cross-Metathesis Selectivity; 2.11.3 Tuning Metathesis Selectivity 2.11.4 CM as an Alternative Coupling Strategy2.11.5 CM-Based Analog Synthesis; 2.11.6 Polyene Metathesis; 2.11.7 Cross-Metathesis Reaction Optimization: Pinnaic Acid; 2.12 Conclusions; References; Chapter 3 Vignette: Extending the Application of Metathesis in Chemical Biology - The Development of Site-Selective Peptide and Protein Modifications; 3.1 Introduction; 3.2 Cross-Metathesis Methodology Studies in Aqueous Media; 3.2.1 Allyl Sulfides are Reactive Substrates in Olefin Metathesis; 3.2.2 Sulfur-Relayed Cross-Metathesis 3.2.3 Application of Aqueous Metathesis of Allyl Sulfides in Synthesis |
| Record Nr. | UNINA-9910787418903321 |
| Weinheim an der Bergstrasse, Germany : , : Wiley-VCH, , 2015 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Handbook of Metathesis / / edited by Robert H. Grubbs [and three others]
| Handbook of Metathesis / / edited by Robert H. Grubbs [and three others] |
| Edizione | [Second edition.] |
| Pubbl/distr/stampa | Weinheim : , : Wiley‐VCH Verlag GmbH & Co. KGaA, , 2015 |
| Descrizione fisica | 1 online resource (3 volumes) |
| Disciplina | 547.215 |
| Soggetto topico | Metathesis (Chemistry) |
| ISBN | 3-527-67410-1 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto | Volume 1. Catalyst Development and Mechanism / edited by Robert H. Grubbs and Anna G. Wenzel -- Volume 2. Applications in Organic Synthesis / edited by Robert H. Grubbs and Daniel J. O'Leary -- Volume 3. Polymer Synthesis edited by Robert H. Grubbs and Ezat Khosravi. |
| Record Nr. | UNINA-9910830410703321 |
| Weinheim : , : Wiley‐VCH Verlag GmbH & Co. KGaA, , 2015 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Handbook of metathesis . Volume 2 Applications in organic synthesis / / editors, Prof. Robert H. Grubbs, Prof. Daniel J. O'Leary
| Handbook of metathesis . Volume 2 Applications in organic synthesis / / editors, Prof. Robert H. Grubbs, Prof. Daniel J. O'Leary |
| Edizione | [2nd ed.] |
| Pubbl/distr/stampa | Weinheim an der Bergstrasse, Germany : , : Wiley-VCH, , 2015 |
| Descrizione fisica | 1 online resource (772 p.) |
| Disciplina | 660.299 |
| Soggetto topico |
Metathesis (Chemistry)
Alkenes Organic compounds - Synthesis |
| ISBN |
3-527-69404-8
3-527-69402-1 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Cover; Contents; Preface; List of Contributors; List of Abbreviations; Chapter 1 General Ring-Closing Metathesis; 1.1 Introduction; 1.2 Carbocycles (Introduction); 1.2.1 Small-Sized Carbocycles; 1.2.2 Medium-Sized Carbocycles; 1.2.3 Spiro Carbocycles; 1.3 Synthesis of Bridged Bicycloalkenes; 1.4 Synthesis of Heterocycles Containing Si, P, S, or B; 1.4.1 Si-Heterocycles; 1.4.2 P-Heterocycles; 1.4.3 S-Heterocycles; 1.4.4 B-Heterocycles; 1.5 Synthesis of O-Heterocycles; 1.5.1 Small and Medium-Size Cyclic Ethers; 1.5.2 Polycyclic Ethers; 1.6 Synthesis of N-Heterocycles; 1.6.1 N-Heterocycles
1.6.2 Small and Medium-Sized Lactams1.7 Synthesis of Cyclic Conjugated Dienes; 1.8 Alkyne Metathesis; 1.9 Enyne Metathesis; 1.9.1 General Enyne Metathesis; 1.9.2 Dienyne Metathesis; 1.10 Tandem Processes; 1.10.1 Tandem ROM/RCM; 1.10.2 Other Tandem RCMs; 1.11 Synthesis of Macrocycles; 1.11.1 Macrocycles; 1.11.2 Macrolactones; 1.11.3 Macrolactams; 1.12 RCM and Isomerization via Ru-H; 1.13 Relay RCM (RRCM); 1.14 Z-Selective RCM; 1.14.1 Substrate-Controlled Z-Selective RCM; 1.14.2 Catalyst-Controlled Z-Selective RCM; 1.15 Enantioselective RCM; 1.16 Conclusion; Acknowledgments; References Chapter 2 Cross-Metathesis2.1 Early Examples Using Well-Defined Molybdenum and Ruthenium Catalysts; 2.2 The General Model for Selectivity in CM Reactions; 2.3 Definition of Cross-Metathesis Reaction Categories and Chapter Organization; 2.4 Hydrocarbons; 2.4.1 Alkane Extensions; 2.4.2 Unsaturated Hydrocarbons, Including Styrene; 2.4.3 Ethylene Cross-Metathesis; 2.5 Boron; 2.6 Nitrogen; 2.6.1 Amines; 2.6.2 Amines as CM Partners in Heterocycle Syntheses; 2.6.3 Acrylonitrile and Other Nitrile-Based CM Applications; 2.6.4 Other Nitrogenous Substrates; 2.7 Oxygen 2.7.1 Primary Allylic Alcohols and Derivatives2.7.2 Secondary Allylic Alcohols and Derivatives; 2.7.3 Tertiary Allylic Alcohols and Derivatives; 2.7.4 Homoallylic Alcohols and Derivatives; 2.7.5 Vinyl Ethers; 2.7.6 Acrolein, Crotonaldehyde, and Methacrolein; 2.7.7 Methyl Vinyl Ketone and Related Systems; 2.7.8 Acrylic Acid; 2.7.9 Acrylic Acid Derivatives, Including Esters, Thioesters, and Amides; 2.8 Halides; 2.9 Phosphorus; 2.10 Sulfur; 2.11 Fragment Coupling Reactions; 2.11.1 Acetogenins; 2.11.2 Cross-Metathesis Selectivity; 2.11.3 Tuning Metathesis Selectivity 2.11.4 CM as an Alternative Coupling Strategy2.11.5 CM-Based Analog Synthesis; 2.11.6 Polyene Metathesis; 2.11.7 Cross-Metathesis Reaction Optimization: Pinnaic Acid; 2.12 Conclusions; References; Chapter 3 Vignette: Extending the Application of Metathesis in Chemical Biology - The Development of Site-Selective Peptide and Protein Modifications; 3.1 Introduction; 3.2 Cross-Metathesis Methodology Studies in Aqueous Media; 3.2.1 Allyl Sulfides are Reactive Substrates in Olefin Metathesis; 3.2.2 Sulfur-Relayed Cross-Metathesis 3.2.3 Application of Aqueous Metathesis of Allyl Sulfides in Synthesis |
| Record Nr. | UNINA-9910828172403321 |
| Weinheim an der Bergstrasse, Germany : , : Wiley-VCH, , 2015 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Handbook of metathesis . Volume 1 : catalyst development and mechanism / / edited by Robert H. Grubbs and Anna G. Wenzel
| Handbook of metathesis . Volume 1 : catalyst development and mechanism / / edited by Robert H. Grubbs and Anna G. Wenzel |
| Edizione | [2nd ed.] |
| Pubbl/distr/stampa | Weinheim, Germany : , : Wiley-VCH Verlag GmbH & Co., , 2015 |
| Descrizione fisica | 1 online resource (444 p.) |
| Disciplina | 660.299 |
| Soggetto topico |
Metathesis (Chemistry)
Metal catalysts - Industrial applications |
| ISBN |
3-527-69399-8
3-527-69400-5 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Cover; Contents; Preface; List of Contributors; Chapter 1 High-Oxidation State Molybdenum and Tungsten Complexes Relevant to Olefin Metathesis; 1.1 Introduction; 1.2 New Imido Ligands and Synthetic Approaches; 1.3 Bispyrrolide and Related Complexes; 1.4 Monoalkoxide Pyrrolide (MAP) Complexes; 1.5 Reactions of Alkylidenes with Olefins; 1.6 Olefin and Metallacyclopentane Complexes; 1.7 Tungsten Oxo Complexes; 1.8 Bisaryloxides; 1.9 Other Constructs; 1.10 Conclusions; Acknowledgments; References; Chapter 2 Alkane Metathesis; 2.1 Introduction; 2.2 Alkane Metathesis by Single-Catalyst Systems
2.2.1 Supported Metal Hydrides2.2.1.1 Supported Zr-Polyhydrides; 2.2.1.2 Supported Ta-Polyhydrides; 2.2.1.3 Supported W-Polyhydrides; 2.2.2 Metal Alkylidene/Alkylidyne on Surface Oxide; 2.2.2.1 Structure-Activity Relationship of Alkylidene Complexes; 2.2.2.2 Stoichiometric Activity of Well-Defined, Metal Alkylidenes with Alkanes; 2.2.2.3 Synthesis of Supported WMe6 on Silica; 2.3 Alkane Metathesis by Tandem, Dual-Catalytic Systems; 2.3.1 Introduction; 2.3.2 The Chevron Process Using WO3/SiO2 and Pt-Li/Al2O3 2.3.3 Tandem, Dual Catalytic System Using Ir-Pincer Ligands and Mo-Alkylidene Complexes2.3.3.1 The Development of Robust, Iridium-Based Alkane Dehydrogenation Catalysts; 2.3.3.2 Cyclic and Cross-Alkane Metathesis; 2.4 Conclusion; References; Chapter 3 Diastereocontrol in Olefin Metathesis: the Development of Z-Selective Ruthenium Catalysts; 3.1 Introduction; 3.2 The Challenge of Z-Selective Olefin Metathesis; 3.3 Previous Strategies; 3.4 A Serendipitous Discovery; 3.5 Catalyst Studies; 3.5.1 Summary of Substituent Effects; 3.5.1.1 Investigating the X-type Ligand; 3.5.1.2 Effect of the NHC 3.5.2 Decomposition of Z-Selective Ru Metathesis Catalysts3.6 Applications of Z-Selective Ru Metathesis Catalysts; 3.6.1 Cross Metathesis; 3.6.1.1 Homodimerization or Homocoupling; 3.6.1.2 Other Cross-Metathesis Reactions; 3.6.2 Ring-Closing Metathesis (RCM); 3.6.3 Ring-Opening Metathesis Polymerization (ROMP); 3.7 Conclusion; References; Chapter 4 Ruthenium Olefin Metathesis Catalysts Supported by Cyclic Alkyl Aminocarbenes (CAACs); 4.1 Introduction; 4.2 Properties and Preparation of CAAC Ligands; 4.3 CAAC-Supported, Ruthenium Olefin Metathesis Catalysts 4.3.1 CAAC Catalyst Development and Their Application to Ring-Closing Metathesis4.3.2 Application to Cross Metathesis, Ethenolysis, and Degenerate Metathesis; 4.4 Summary; References; Chapter 5 Supported Catalysts and Nontraditional Reaction Media; 5.1 Introduction; 5.2 Supported Catalyst Systems; 5.2.1 Supported Catalysts via Covalent Interactions; 5.2.1.1 Grubbs-Type, Ru-Based Systems; 5.2.1.2 Schrock-Type, Mo- or W-Based Systems; 5.2.2 Supported Catalysts via Non-covalent Interactions; 5.2.2.1 Grubbs-Type, Ru-Based Systems; 5.2.2.2 Early Transition-Metal Systems 5.3 Olefin Metathesis in Nontraditional Media |
| Record Nr. | UNINA-9910828172003321 |
| Weinheim, Germany : , : Wiley-VCH Verlag GmbH & Co., , 2015 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Handbook of metathesis . Volume 3 Polymer synthesis / / edited by Robert H. Grubbs and Ezat Khosravi
| Handbook of metathesis . Volume 3 Polymer synthesis / / edited by Robert H. Grubbs and Ezat Khosravi |
| Edizione | [2nd ed.] |
| Pubbl/distr/stampa | Weinheim, Germany : , : Wiley-VCH, , 2015 |
| Descrizione fisica | 1 online resource (424 p.) |
| Disciplina | 547.412 |
| Soggetto topico |
Polymerization
Metathesis (Chemistry) |
| ISBN |
3-527-69405-6
3-527-69407-2 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | ger |
| Nota di contenuto |
Cover; Contents; Preface; List of Contributors; Chapter 1 Synthesis of Homopolymers and Copolymers; 1.1 Introduction; 1.2 Initiators; 1.3 Monomers; 1.4 Synthesis of Polymers with Complex Architectures; 1.5 Stereochemistry and Sequence Control in ROMP; 1.6 Conclusion; References; Chapter 2 ROMP in Dispersed Media; 2.1 Introduction; 2.2 Emulsion ROMP; 2.2.1 Mini-emulsion ROMP; 2.2.2 Micro-emulsion ROMP; 2.2.3 Micellar ROMP; 2.2.4 ROMP in Nonaqueous Emulsions; 2.3 Dispersion ROMP; 2.3.1 Biomedical Applications of PNBE-PEO Core-Shell Nanoparticles; 2.4 Suspension ROMP
2.5 Formation of Nanoparticles2.5.1 Photoactive ROMP Assemblies; 2.5.2 Miscellaneous; 2.6 Conclusion; References; Chapter 3 Telechelic Polymers; 3.1 Introduction; 3.2 Mono-telechelic Polymers; 3.2.1 Reaction with Substituted Vinyl Ethers; 3.2.2 Vinyl Lactone Quenching; 3.2.3 Terminal Cross Metathesis; 3.2.3.1 Using Symmetrical Olefins; 3.2.3.2 Using Asymmetrical Olefins; 3.2.4 Reaction with Oxygen; 3.2.5 Sacrificial Diblock Copolymer Synthesis; 3.2.6 Catalyst Prefunctionalization; 3.2.6.1 Functional Catalysts from Precursor Complexes; 3.2.6.2 Functional Catalysts via Cross Metathesis 3.2.7 Aldehyde Quenching3.3 Homo-telechelic Polymers; 3.3.1 Degradation of Unsaturated Polymers and ADMET Polymerization; 3.3.2 ROMP/Chain Transfer; 3.3.3 Sacrificial Multiblock Copolymers; 3.4 Hetero-telechelic Polymers; 3.4.1 Prefunctionalization with Functional Alkylidene Initiators; 3.4.2 Prefunctionalization with Sacrificial Synthesis; 3.5 Conclusions and Outlook; Acknowledgments; References; Chapter 4 Supramolecular Polymers; 4.1 Introduction; 4.2 Main-Chain Supramolecular Polymers; 4.2.1 Macromonomers; 4.2.2 ABC Triblock Copolymers; 4.3 Side-Chain-Functionalized Supramolecular Polymers 4.3.1 Hydrogen-Bonding Recognition Motifs4.3.2 Metal Coordination-Based Recognition Motifs; 4.3.3 Mixed Orthogonal Recognition Motifs; 4.4 Supramolecular Architectures by Design; 4.5 Conclusion; References; Chapter 5 Synthesis of Materials with Nanostructured Periodicity; 5.1 Introduction; 5.2 Sequential ROMP; 5.3 Inorganic Composite Materials; 5.4 ABA Triblock Copolymers; 5.5 Nanostructures with Domain Sizes Exceeding 100 nm; 5.6 Conclusions; References; Chapter 6 Synthesis of Nanoparticles; 6.1 Introduction; 6.2 Formation of Nanoparticles; 6.3 Synthesis via Grafting-through Approach 6.4 Synthesis via Grafting-to Approach6.4.1 Grafting-to Polymer Backbones via an Activated Ester; 6.4.2 Grafting-to Polymer Backbones via Copper-Catalyzed Click Reaction; 6.5 Synthesis via Grafting-from Approach; 6.6 Summary; References; Chapter 7 Synthesis of Biodegradable Copolymers; 7.1 Introduction; 7.2 Polyester-Functionalized Polymers; 7.3 Peptide-Functionalized Polymers; 7.4 Carbohydrate-Functionalized Polymers; 7.5 Antimicrobial Polymers; 7.6 Polymeric Betaines; 7.7 ROMP Polymers as Drug Carriers; 7.8 ROMP Polymers for Tissue Scaffolds; 7.9 Conclusion; References Chapter 8 Biologically Active Polymers |
| Record Nr. | UNINA-9910807971503321 |
| Weinheim, Germany : , : Wiley-VCH, , 2015 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Handbook of transition metal polymerization catalysts / / edited by Ray Hoff
| Handbook of transition metal polymerization catalysts / / edited by Ray Hoff |
| Edizione | [Second edition.] |
| Pubbl/distr/stampa | Hoboken, New Jersey : , : John Wiley & Sons, Inc., , [2018] |
| Descrizione fisica | 1 online resource (865 pages) |
| Disciplina | 668.9/2 |
| Soggetto topico |
Metathesis (Chemistry)
Polymerization Transition metal catalysts |
| ISBN |
1-119-24221-5
1-5231-1919-5 1-119-24215-0 1-119-24227-4 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNINA-9910270863003321 |
| Hoboken, New Jersey : , : John Wiley & Sons, Inc., , [2018] | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Handbook of transition metal polymerization catalysts / / edited by Ray Hoff
| Handbook of transition metal polymerization catalysts / / edited by Ray Hoff |
| Edizione | [Second edition.] |
| Pubbl/distr/stampa | Hoboken, New Jersey : , : John Wiley & Sons, Inc., , [2018] |
| Descrizione fisica | 1 online resource (865 pages) |
| Disciplina | 668.9/2 |
| Soggetto topico |
Metathesis (Chemistry)
Polymerization Transition metal catalysts |
| ISBN |
1-119-24221-5
1-5231-1919-5 1-119-24215-0 1-119-24227-4 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNINA-9910820332403321 |
| Hoboken, New Jersey : , : John Wiley & Sons, Inc., , [2018] | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Handbook of transition metal polymerization catalysts [[electronic resource] /] / edited by Ray Hoff, Robert T. Mathers
| Handbook of transition metal polymerization catalysts [[electronic resource] /] / edited by Ray Hoff, Robert T. Mathers |
| Pubbl/distr/stampa | Hoboken, N.J., : Wiley, c2010 |
| Descrizione fisica | 1 online resource (599 p.) |
| Disciplina | 668.9/2 |
| Altri autori (Persone) |
HoffRaymond E
MathersRobert T |
| Soggetto topico |
Polymerization
Transition metal catalysts Metathesis (Chemistry) |
| ISBN |
1-282-81669-1
9786612816697 0-470-50443-9 0-470-50442-0 |
| Classificazione |
VH 7900
VH 9700 VK 8000 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
HANDBOOK OF TRANSITION METAL POLYMERIZATION CATALYSTS; CONTENTS; Introduction; About the Authors; 1 Commercially Available Metal Alkyls and Their Use in Polyolefin Catalysts; 2 Porous Silica in Transition Metal Polymerization Catalysts; 3 Computational Modeling of Polymerization Catalysts; 4 Scale-Up of Catalyst Recipes to Commercial Production; 5 Commercialization of Olefin Polymerization Catalysts: Model for Success; 6 Supported Magnesium/Titanium-Based Ziegler Catalysts for Production of Polyethylene; 7 Stereospecific α-Olefin Polymerization with Heterogeneous Catalysts
8 MgCl(2)-Supported TiCl(4) Catalysts for Production of Morphology-Controlled Polyethylene9 Product Morphology in Olefin Polymerization with Polymer Supported Metallocene Catalysts; 10 Review of Phillips Chromium Catalyst for Ethylene Polymerization; 11 Silica-Supported Silyl Chromate-Based Ethylene Polymerization Catalysts; 12 Ethylene Polymerization and α-Olefin Oligomerization Using Catalysts Derived from Phosphoranes and Ni(II) and Ni(0) Precursors; 13 Late Transition Metal-Catalyzed Co- and Terpolymerization of α-Olefins with Carbon Monoxide-Polyketones: Synthesis and Modification 14 Copper Catalysts for Olefin Polymerization15 Ring-Opening Metathesis Polymerizations and Acyclic Diene Metathesis Polymerizations with Homogeneous Ruthenium and Molybdenum Catalysts and Initiators; 16 Cobalt Ziegler-Natta Catalysts for Synthesis of Poly-cis-1,4-Butadiene; Appendix A Pyrophoricity of Metal Alkyls; Appendix B Rheological Terms for Polymerization Catalyst Chemists; Index |
| Record Nr. | UNINA-9910785239103321 |
| Hoboken, N.J., : Wiley, c2010 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
