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Catalysis in Confined Frameworks : Synthesis, Characterization, and Applications
| Catalysis in Confined Frameworks : Synthesis, Characterization, and Applications |
| Autore | Garcia Hermenegildo |
| Edizione | [1st ed.] |
| Pubbl/distr/stampa | Newark : , : John Wiley & Sons, Incorporated, , 2023 |
| Descrizione fisica | 1 online resource (499 pages) |
| Disciplina | 541.395 |
| Altri autori (Persone) | DhakshinamoorthyAmarajothi |
| Soggetto topico |
Metal-organic frameworks
Catalysis |
| ISBN | 9783527839254 |
| Formato | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto | Cover -- Title Page -- Copyright -- Contents -- Preface -- Chapter 1 Engineering of Metal Active Sites in MOFs -- 1.1 Metal Node Engineering -- 1.1.1 Frameworks with Intrinsically Active Metal Nodes -- 1.1.1.1 Metal–Organic Frameworks with Only One Metal -- 1.1.1.2 Metal–Organic Frameworks with more than One Metal in its Cluster -- 1.1.2 Introducing Defectivity as a Powerful Tool to Tune Metal‐node Catalytic Properties in MOFs -- 1.1.3 Incorporating Metals to Already‐Synthetized Metal–Organic Frameworks: Isolating the Catalytic Site -- 1.1.4 Metal Exchange -- 1.1.5 Attaching Metallic Units to the MOF -- 1.1.6 Grafting of Organometallic Complexes into the MOF Nodes -- 1.2 Ligand Engineering -- 1.2.1 Ligands as Active Metal Sites -- 1.2.1.1 Creating Metal Sites in the Organic Linkers. Types of Ligands -- 1.2.1.2 Cooperation Between Single‐Metal Sites and Metalloligands -- 1.2.1.3 Ligand Accelerated Catalysis (LAC) -- 1.2.2 Introduction of Metals by Direct Synthesis -- 1.2.2.1 In‐situ Metalation -- 1.2.2.2 Premetalated Linker -- 1.2.2.3 Postgrafting Metal Complexes -- 1.2.3 Introduction of Metals by Post‐synthetic Modifications -- 1.2.3.1 Post‐synthetic Exchange or Solvent‐Assisted Linker Exchange (SALE) -- 1.2.3.2 Post‐synthetic Metalation -- 1.3 Metal‐Based Guest Pore Engineering -- 1.3.1 Encapsulation Methodologies in As‐Made Metal–Organic Frameworks -- 1.3.1.1 Incipient Wetness Impregnation |
| Record Nr. | UNINA-9911019505503321 |
Garcia Hermenegildo
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| Newark : , : John Wiley & Sons, Incorporated, , 2023 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
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Functional metal-organic frameworks : structure, properties and applications / / Ali Morsali and Sayed Ali Akbar Razavi
| Functional metal-organic frameworks : structure, properties and applications / / Ali Morsali and Sayed Ali Akbar Razavi |
| Autore | Morsali Ali |
| Pubbl/distr/stampa | Hoboken, NJ : , : Wiley-Scrivener, , 2021 |
| Descrizione fisica | 1 online resource (x, 242 pages) |
| Disciplina | 547.05 |
| Soggetto topico | Metal-organic frameworks |
| Soggetto genere / forma | Electronic books. |
| ISBN |
1-119-64099-7
1-119-64102-0 1-119-64103-9 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNINA-9910555185403321 |
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Morsali Ali
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| Hoboken, NJ : , : Wiley-Scrivener, , 2021 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
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Functional metal-organic frameworks : structure, properties and applications / / Ali Morsali and Sayed Ali Akbar Razavi
| Functional metal-organic frameworks : structure, properties and applications / / Ali Morsali and Sayed Ali Akbar Razavi |
| Autore | Morsali Ali |
| Pubbl/distr/stampa | Hoboken, NJ : , : Wiley-Scrivener, , 2021 |
| Descrizione fisica | 1 online resource (x, 242 pages) |
| Disciplina | 547.05 |
| Soggetto topico | Metal-organic frameworks |
| ISBN |
1-119-64099-7
1-119-64102-0 1-119-64103-9 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNINA-9910830296803321 |
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Morsali Ali
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| Hoboken, NJ : , : Wiley-Scrivener, , 2021 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
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Mechanically Interlocked Materials : Polymers, Nanomaterials, MOFs, and More
| Mechanically Interlocked Materials : Polymers, Nanomaterials, MOFs, and More |
| Autore | Pérez Emilio M |
| Edizione | [1st ed.] |
| Pubbl/distr/stampa | Newark : , : John Wiley & Sons, Incorporated, , 2024 |
| Descrizione fisica | 1 online resource (300 pages) |
| Disciplina | 547.1226 |
| Soggetto topico |
Molecular machinery
Metal-organic frameworks |
| ISBN |
9783527828951
3527828958 9783527828968 3527828966 9783527828975 3527828974 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto | Cover -- Title Page -- Copyright -- Contents -- Preface -- Chapter 1 Force‐Promoted Transformations in Mechanically Linked Molecules -- 1.1 Introduction -- 1.2 SMFS in the Study of Non‐covalent Interactions -- 1.2.1 Rotaxanes -- 1.2.2 Poly‐(pseudo)rotaxanes -- 1.2.3 Catenanes -- 1.3 Strength of Mechanical Bonds -- 1.3.1 Polymers Containing a Rotaxane -- 1.3.2 Polymers Containing a Catenane -- 1.4 Changes in Optical Properties – Reversible and Irreversible Changes of Optical Properties by Movement of Macrocycle in a Rotaxane -- 1.5 Conclusions -- References -- Chapter 2 Colloidal Nanomaterials with Mechanically Interlocked Parts -- 2.1 Introduction -- 2.2 Installing and Actuating Mechanically Interlocked Molecular Architectures at Colloidal Nanoparticle Surfaces -- 2.3 Modulating Nanoparticle Physicochemical Properties Using Switchable Mechanically Interlocked Architectures -- 2.4 Interlocked Gates for Nanoparticle Pores: From Cargo Release to Nanoscale Communication -- 2.4.1 Optimizing Mechanisms for Cargo Release -- 2.4.2 Autonomous Drug Delivery Triggered By Endogenous Conditions -- 2.4.3 Cargo Release Using Tissue‐Penetrating External Triggers -- 2.4.4 Nanoscale Communication Between Responsive Nanoparticles -- 2.5 Mechanically Interlocked Molecular Links for Nanoparticle Assemblies -- 2.5.1 Pseudorotaxane‐linked Nanoparticle Assembly–Disassembly -- 2.5.2 Fully Interlocked Molecular Links for Nanoparticle Assemblies -- 2.6 From Switches to Motors and Beyond: The Future of Colloidal Nanomaterials with Mechanically Interlocked Parts |
| Record Nr. | UNINA-9910877114503321 |
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Pérez Emilio M
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| Newark : , : John Wiley & Sons, Incorporated, , 2024 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
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Metal organic frameworks for wastewater contaminant removal / / edited by Arun Lal Srivastav [and three others]
| Metal organic frameworks for wastewater contaminant removal / / edited by Arun Lal Srivastav [and three others] |
| Edizione | [1st ed.] |
| Pubbl/distr/stampa | Weinheim, Germany : , : WILEY-VCH GmbH, , [2023] |
| Descrizione fisica | 1 online resource (464 pages) |
| Disciplina | 547.05 |
| Soggetto topico |
Metal-organic frameworks
Sewage - Purification - Metals removal Sewage - Purification - Organic compounds removal |
| ISBN |
3-527-84152-0
3-527-84153-9 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Intro -- Title Page -- Copyright Page -- Preface -- 1 Application of MOFs on Removal of Emerging Water Contaminants -- Abbreviated list -- 1.1 Introduction -- 1.1.1 Sources of Emerging Water Contaminants -- 1.1.2 Emerging Water Contaminants Treatment Methods -- 1.1.3 MOFs as Exceptional Materials for Water Remediation -- 1.2 MOFs Strategies in Water Remediation -- 1.2.1 Adsorption -- 1.2.2 Catalyst -- 1.2.3 Synergistic Effect of Adsorption and Photocatalyst -- 1.3 Emerging Water Contaminants by MOFs -- 1.3.1 Organic Dyes -- 1.3.2 Adsorption -- 1.3.3 Photocatalytic and Electrostatic Activities -- 1.3.4 PPCPs -- 1.3.5 Adsorption -- 1.3.6 Photocatalytic Activities -- 1.3.7 Herbicides and Pesticides -- 1.3.8 Adsorption -- 1.3.9 Photocatalytic Activities -- 1.3.10 Industrial Compounds/By-products -- 1.3.11 Adsorption -- 1.3.12 Photocatalytic Activities -- 1.4 Challenges and Perspective in Using MOFs for the Removal of Emerging Water Contaminants -- 1.5 Conclusion -- 2 Metal-Organic Frameworks and Their Stepwise Preparatory Methods (Synthesis) for Water Treatment -- 2.1 Introduction -- 2.2 Classification of Metal-Organic Frameworks -- 2.3 Synthesis of MOFs -- 2.3.1 Conventional Solvothermal/Hydrothermal and Non-Solvothermal Method -- 2.3.2 Room-Temperature Synthesis -- 2.3.3 Unconventional Methods -- 2.4 Alternative Synthesis Methods -- 2.4.1 Microwave-Assisted Synthesis -- 2.4.2 Electrochemical Synthesis -- 2.4.3 Sonochemical Synthesis -- 2.4.4 Surfactant-Assisted Synthesis -- 2.4.5 Layer-by-Layer Synthesis -- 2.5 Factors Affecting the Synthesis of MOFs -- 2.5.1 Solvents -- 2.6 Temperature and pH Effects on the Synthesis of MOFs -- 2.7 Water Regeneration and Wastewater Treatment Using MOF Membranes -- 2.8 Membrane Filtration -- 2.9 Microfiltration (MF) -- 2.10 Ultrafiltration (UF) -- 2.11 Nanofiltration (NF).
2.12 Reverse Osmosis (RO) and Forward Osmosis (FO) -- 2.13 Membrane Distillation (MD) -- 2.14 Membrane Pervaporation (PV) -- 2.15 Conclusion -- 3 Application of MOFs in the Removal of Pharmaceutical Waste from Aquatic Environments -- 3.1 Introduction -- 3.2 The Potential of MOFs and Their Analogs to Resist Water Stability -- 3.3 Methods for the Development and Design of Aqueous-Stable Composites of Metal-Organic Frameworks -- 3.4 Synthesis and Design of Water-Stable MOF-Derived Materials -- 3.5 MOFs and Their Hybrids as Versatile Adsorbents for Capturing Pharmaceutical Drugs -- 3.6 MILs and Their Derived Compounds -- 3.7 Pristine MILs -- 3.8 MILs Composites -- 3.9 MILs-Derived Materials -- 3.10 ZIFs and Their Derived Compounds -- 3.11 Pristine ZIFs -- 3.12 ZIFs Composites -- 3.13 Materials Derived from ZIFs -- 3.14 UiOs Composite Materials -- 3.15 UiOs-Derived Materials -- 3.16 Pharmaceutical Drug Resistance -- 3.17 Conclusion -- 4 Efficiency of MOFs in Water Treatment Against the Emerging Water Contaminants Such as Endocrine Disruptors, Pharmaceuticals, Microplastics, Pesticides, and Other Contaminants -- 4.1 Introduction -- 4.2 Chemical Contaminants: Those Mysterious Ingredients in Ground and Surface Water -- 4.2.1 Endocrine Disruptors (EDs) -- 4.2.2 Microplastics (MPs) -- 4.2.3 Contaminants from the Agriculture Sector -- 4.2.4 Pharmaceutical Effluents -- 4.3 MOFs -- 4.3.1 MOF Stability in the Aqueous Phase -- 4.3.2 Improving the Water Stability of MOFs: General Enhancement Strategies -- 4.4 Possibilities for Wastewater Treatment Applications Using MOFs -- 4.4.1 MOF-Supported Adsorption & -- Photocatalysis -- 4.4.2 π-π Interactions -- 4.4.3 Electrostatic Interactions -- 4.4.4 Hydrophobic Interactions -- 4.4.5 H-Bonding -- 4.5 Use of MOFs for Water Remediation: Issues & -- Perspectives -- 4.6 Future -- 4.7 Conclusions. 5 Metal-Organic Frameworks for Wastewater Contaminants Removal -- 5.1 Introduction -- 5.2 Aqueous Phase MOF Stability -- 5.3 MOF Degradation in Water -- 5.4 Influence of MOF Structure -- 5.5 2D Nanostructured Coating -- 5.6 3D Nanostructure of MOF -- 5.7 MOF-Based Materials' Adsorption Processes for Heavy Metal Oxyanion -- 5.8 Remediation Through Perfect MOFs -- 5.9 Interaction of MOFs with Other Species -- 5.10 With the Use of MOF Composites -- 5.11 Removal of Metal Ions through Adsorption -- 5.12 MOF Composites are Used for Removal -- 5.13 COFs are a New Class of Materials that Have Similar MOF Structures -- 5.14 Application of MOF Composites -- 5.15 Gas Separation and Adsorption -- 5.16 MOF Composites -- 5.17 Agrochemical Adsorption and Removal -- 5.18 Pharmaceutical and Personal Care Adsorption Removal Products (PPCPs) -- 5.19 MOFs for Photocatalytic Elimination of Organic Pollutants -- 5.20 Conclusion -- Acknowledgment -- Author Contributions -- Conflicts of Interest -- 6 "Green Applications of Metal-Organic Frameworks for Wastewater Treatment" -- 6.1 Introduction -- 6.2 Role of Green Chemistry in Preparation of MOFs -- 6.3 Green Application of MOFs in the Removal of Contaminants from Wastewater -- 6.3.1 MOFs for the Removal of Inorganic Contaminants -- 6.3.2 MOFs for the Removal of Organic Contaminants -- 6.4 Conclusion and Future Prospects -- 6.5 Conflict of Interest -- 7 Case Studies (Success Stories) on the Application of Metal-Organic Frameworks (MOFs) in Wastewater Treatment and Their Implementations -- Review -- 7.1 Introduction -- Sewage Treatment Policies and State Implementation Strategies -- 7.2 Metal-Organic Framework (MOF) -- 7.2.1 Properties and Applications of MOFs -- 7.3 Applications of MOFs in Wastewater Treatment: Case Studies -- 7.3.1 Forward Osmosis (FO) Membranes -- 7.3.2 Application and Effectiveness. 7.3.3 Reverse Osmosis (RO) Membranes -- 7.3.4 Application and Effectiveness -- 7.3.5 Nano Filter (NF) Membranes -- 7.3.6 Application and Effectiveness -- 7.3.7 Ultrafiltration (UF) Membranes -- 7.3.8 Application and Effectiveness -- Summary -- Acknowledgment -- 8 Prospects and Potentials of Microbial Applications on Heavy-Metal Removal from Wastewater -- 8.1 Introduction -- 8.2 Mainstream Avenues to Remediate Heavy Metals in Wastewater -- 8.3 The Microbial Recycling Approach -- 8.4 General Overview of Heavy-Metal Pollution in Wastewater -- 8.5 Techniques for Heavy-Metal Removal -- 8.6 Microbial and Biological Approaches for Removing Heavy Metals from Wastewater -- 8.7 Biological Remediation Approaches for Heavy-Metal Removal -- 8.8 Microbial Bioremediation Approaches -- 8.9 Bioengineering Approaches on Microbes for Improving Heavy-Metal Removal from Wastewater -- 8.10 Conclusion -- Acknowledgment -- 9 Removal of Organic Contaminants from Aquatic Environments Using Metal-Organic Framework (MOF) Based Materials -- 9.1 Introduction -- 9.2 MOF-Based Materials -- 9.2.1 MOF-Metal Nanoparticle Materials -- 9.2.2 MOF-MO Materials -- 9.2.3 MOF-Quantum Dot Materials -- 9.2.4 MOF-Silica Materials -- 9.2.5 MOF-Carbon Materials -- 9.2.6 Core-shell Structures of MOFs -- 9.2.7 MOF-Enzyme Materials -- 9.2.8 MOF-Organic Polymer Materials -- 9.3 Environmental Effects of MOF-Based Materials -- 9.4 Conclusion -- 10 Reformed Metal-Organic Frameworks (MOFs) for Abstraction of Water Contaminants - Heavy-Metal Ions -- 10.1 Introduction -- 10.2 Metal-Organic Frameworks -- 10.3 Sorption Enrichment by Modification of MOFs -- 10.4 Toxic-Metal Ion Adsorption by MOFs -- 10.4.1 MOFs for Mercury Adsorption -- 10.4.2 MOFs for Lead Adsorption -- 10.4.3 MOFs for Cadmium Adsorption -- 10.4.4 MOFs for Chromium Removal -- 10.4.5 MOFs for Arsenic Removal. 10.4.6 MOFs for Heavy Metals Phosphate Removal -- 10.4.7 MOFs for Nickel Adsorption -- 10.4.8 MOFs for Selenium Adsorption -- 10.4.9 MOFs for Uranium Adsorption -- 10.5 Future Perspective -- 10.6 Future Scope -- 10.7 Conclusions -- 11 Application of Algal-Polysaccharide Metal-Organic Frameworks in Wastewater Treatment -- 11.1 Introduction -- 11.1.1 Water Pollutants and Sources -- 11.1.2 Common Wastewater Treatment Techniques -- 11.1.3 Metal-Organic Frameworks for Wastewater Treatment -- 11.1.4 Polysaccharide-Metal-organic Frameworks (Ps-MOFs) -- 11.2 Polysaccharides in Algae/cyanobacteria (AlPs) -- 11.2.1 Polysaccharides in Cyanophyceae -- 11.2.2 Polysaccharides in Chlorophyceae -- 11.2.3 Polysaccharides in Rhodophyceae -- 11.2.4 Polysaccharides in Phaeophyceae -- 11.3 Synthesis of Algal Polysaccharide MOFs (ALPs-MOFs) -- 11.3.1 Alginate-MOFs -- 11.3.2 Cellulose-MOFs -- 11.3.3 Agar-MOFs -- 11.4 Characterization of AlP-MOFs -- 11.5 Adsorption Mechanism of AlPs-MOFs -- 11.6 Regeneration of AlPs-MOFs -- 11.7 Conclusion and Future Prospects -- 12 Ecological Risk Assessment of Heavy Metal Pollution in Water Resources -- 12.1 Introduction -- 12.2 Natural and Anthropogenic Sources of Heavy Metals in the Environment -- 12.3 Impacts of Heavy Metal Pollution -- 12.4 Water Quality Assessment Using Pollution Indices -- 12.4.1 Heavy Metal Pollution Index (HPI) -- 12.4.2 Statistical Technique -- 12.5 MOFs for Heavy Metal Contaminant Removal from Water -- 12.6 Conclusion -- 13 Organic Contaminants in Aquatic Environments: Sources and Impact Assessment -- 13.1 Introduction -- 13.2 The Various Forms and Causes of Chemical Pollutants -- 13.3 Increasing Contaminant Occurrence in Aquatic Systems -- 13.4 Identifying Potential Points of Entry for New Pollutants into Aquatic Systems -- 13.5 Groups of Trace Pollutants and ECs -- 13.5.1 Polybrominated Diphenyl Ethers (PBDEs). 13.6 Pharmaceuticals and Personal Care Products (PPCPs). |
| Record Nr. | UNINA-9910830301803321 |
| Weinheim, Germany : , : WILEY-VCH GmbH, , [2023] | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
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Metal-organic frameworks / / edited by Fahmina Zafar, Eram Sharmin
| Metal-organic frameworks / / edited by Fahmina Zafar, Eram Sharmin |
| Pubbl/distr/stampa | Rijeka, Croatia : , : IntechOpen, , [2016] |
| Descrizione fisica | 1 online resource (166 pages) |
| Disciplina | 547.05 |
| Soggetto topico | Metal-organic frameworks |
| ISBN |
953-51-6680-8
953-51-2663-6 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNINA-9910317690703321 |
| Rijeka, Croatia : , : IntechOpen, , [2016] | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
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Metal-organic frameworks (MOFs) as catalysts / / edited by Shikha Gulati
| Metal-organic frameworks (MOFs) as catalysts / / edited by Shikha Gulati |
| Pubbl/distr/stampa | Singapore : , : Springer, , [2022] |
| Descrizione fisica | 1 online resource (785 pages) : illustrations (chiefly color) |
| Disciplina | 660.2995 |
| Soggetto topico |
Catalysts
Metal-organic frameworks |
| ISBN |
981-16-7959-2
981-16-7958-4 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto | Chapter 1. MOFs as catalysts: introduction and prospects --Chapter 2. Stability of MOFs and kinetics of MOF-catalyzed reactions --Chapter 3. Strategies for the synthesis and functionalization of MOFs --Chapter 4. Characterization techniques of MOFs --Chapter 5.Reactions catalyzed by MOFs and prospects for applications --Chapter 6. MOFs as catalysts for CO2 capture and fixation --Chapter 7. Covalent organic frameworks as catalysts --Chapter 8. MOFs as heterogeneous catalysts --Chapter 9. MOFs as sensors --Chapter 9. MOFs as catalysts for the capture and degradation of chemical warfare agents --Chapter 10.Chiral MOFs for Asymmetric catalysis --Chapter 11. MOFs as Catalysts for the storage of methane --Chapter 12. Photocatalysis by MOFs. |
| Record Nr. | UNINA-9910743233703321 |
| Singapore : , : Springer, , [2022] | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
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Metal-organic frameworks in biomedical and environmental field / / Patricia Horcajada Cortés, Sara Rojas Macías, editors
| Metal-organic frameworks in biomedical and environmental field / / Patricia Horcajada Cortés, Sara Rojas Macías, editors |
| Pubbl/distr/stampa | Cham, Switzerland : , : Springer, , [2021] |
| Descrizione fisica | 1 online resource (xiii, 503 pages) : illustrations |
| Disciplina | 547.05 |
| Soggetto topico | Metal-organic frameworks |
| ISBN | 3-030-63380-2 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Intro -- Preface -- Contents -- Contributors -- Chapter 1: Robust and Environmentally Friendly MOFs -- 1.1 Introduction -- 1.2 Stability of Metal-Organic Frameworks -- 1.2.1 Chemical Stability -- 1.2.1.1 Reinforcing the Coordination Bond -- 1.2.1.2 Preserving the Coordination Bond -- 1.2.2 Thermal Stability -- 1.2.3 Mechanical Stability -- 1.3 Environmentally Friendly MOFs -- 1.3.1 Chemicals -- 1.3.1.1 Metal-Ion Precursors -- 1.3.1.2 Linkers -- 1.3.1.3 Solvent -- 1.3.1.4 Additives -- 1.3.2 Synthesis and Purification Processes -- 1.3.2.1 Synthesis Process -- 1.3.2.2 Purification Processes -- 1.4 Concluding Remarks -- References -- Chapter 2: Large-Scale Synthesis and Shaping of Metal-Organic Frameworks -- 2.1 Introduction -- 2.2 Scale-Up Synthesis of MOFs -- 2.2.1 Batch-Type Production -- 2.2.2 Continuous-Flow Production of MOFs -- 2.3 Shaping of MOF -- 2.3.1 Conventional Methods of Powder Shaping (Fig. 2.6) -- 2.3.1.1 Granulation -- 2.3.1.2 Extrusion -- 2.3.1.3 Pressing -- 2.3.2 Solidifying Methods -- 2.3.2.1 Spray-Drying -- 2.3.2.2 Foaming -- 2.3.2.3 Alginate -- 2.4 Summary -- References -- Chapter 3: Green Energy Generation Using Metal-Organic Frameworks -- 3.1 General Introduction -- 3.2 Initial Considerations -- 3.2.1 Parameters Affecting Photocatalysis -- 3.2.1.1 Surface Area Effect -- 3.2.1.2 Active Cluster -- 3.2.1.3 Light Absorption -- 3.2.1.4 Excitation Lifetime/Rate-Determining Step -- 3.2.1.5 Sacrificial Agents -- 3.2.2 Parameters Affecting Electrocatalysis -- 3.2.2.1 Catalytic Activity of the Reaction Site -- 3.2.2.2 Intrinsic Conductivity of the Material -- 3.2.2.3 Electrical Contact to the Current Collector/CP-Collector Interface -- 3.3 Photocatalysis -- 3.3.1 Hydrogen Evolution Reaction -- 3.3.2 Oxygen Evolution Reaction -- 3.4 Electrocatalysis -- 3.4.1 Hydrogen Evolution Reaction -- 3.4.1.1 Acidic Medium -- 3.4.1.2 Alkaline Medium.
3.4.2 Oxygen Evolution Reaction -- 3.4.2.1 Alkaline Medium -- 3.4.2.2 Neutral Medium -- 3.4.3 Oxygen Reduction Reaction -- 3.4.3.1 Alkaline Medium -- 3.4.3.2 Neutral Medium -- 3.4.3.3 Acidic Medium -- 3.5 Conclusions and Perspectives -- References -- Chapter 4: The Potential of MOFs in the Field of Electrochemical Energy Storage -- 4.1 Introduction -- 4.1.1 Batteries and Supercapacitors: Definitions, Basic Principles, and Characteristics -- 4.1.2 Devices -- 4.2 MOF as Active Materials -- 4.2.1 High-Potential Materials: Insertion Mechanism -- 4.2.2 Low-Potential Materials: Conversion and Alloying -- 4.2.3 Combining Organic and Inorganic Redox Activity: From Redox-Active Core to Non-innocent Ligands -- 4.3 MOFs as Host for Active Species -- 4.3.1 Organic Molecules -- 4.3.2 Sulfur -- 4.4 MOFs for as Coatings of Active Materials -- 4.4.1 Coating on Cathode Materials -- 4.4.2 Coating on Anode Materials -- 4.5 MOF-Based Separators -- 4.5.1 Separator for Li-Ion and Li-Metal Batteries -- 4.5.2 Separators for Emerging Battery Technologies -- 4.6 MOFs as Solid Electrolytes -- 4.7 Conclusion and Prospects -- References -- Chapter 5: Carbon Capture Using Metal-Organic Frameworks -- 5.1 Introduction -- 5.2 Targets for Carbon Capture: CO2-Containing Gas Streams -- 5.2.1 Power Generation -- 5.2.2 Natural Gas and Biogas Upgrading -- 5.3 Solid Adsorbents -- 5.3.1 Fundamentals of Adsorption and Separation over Solid Adsorbents -- 5.3.2 Pressure and Temperature Swing Adsorption on Solid Adsorbents -- 5.3.3 Selectivity of Adsorption -- 5.4 MOFs as Adsorbents for Carbon Capture by PSA and TSA -- 5.4.1 Background -- 5.4.2 Precombustion Gas Streams -- 5.4.3 Post-combustion Carbon Capture -- 5.4.3.1 Background -- 5.4.3.2 Physisorption Approaches -- 5.4.3.3 Chemisorption Approaches -- 5.4.4 Air Capture: Ultramicroporous and Biomimetic MOFs. 5.4.5 Biogas and Natural Gas Upgrading -- 5.4.6 Summary of MOFs as Solid Adsorbents for Carbon Capture -- 5.5 MOFs as Fillers for Mixed Matrix Membranes -- 5.5.1 Introduction -- 5.5.2 Fundamentals of Gas Transport Through Membranes -- 5.5.2.1 Mechanism -- 5.5.2.2 Robeson Plots -- 5.5.2.3 Testing Membranes -- 5.5.3 MOF-Based Mixed Matrix Membranes -- 5.5.3.1 Introduction -- 5.5.3.2 Polymer Choice -- 5.5.3.3 Choice of MOF Fillers -- 5.5.3.4 Interface Engineering and Textural Optimisation -- 5.5.4 Summary of Mixed Matrix Membrane Performance -- 5.5.5 Towards Industrial Application: Hollow Fibre Membranes -- 5.5.6 Summary -- 5.6 A Word on CO2 Utilisation -- 5.7 Conclusions -- References -- Chapter 6: Computational Screening of MOFs for CO2 Capture -- 6.1 Introduction -- 6.2 Molecular Simulations of MOFs for CO2 Capture -- 6.2.1 Identifying Structural Properties of MOFs -- 6.2.2 Computing CO2 Adsorption in MOFs -- 6.2.3 Calculating CO2 Separation Performances of MOFs -- 6.3 Large-Scale Molecular Simulations of MOFs for CO2 Capture -- 6.3.1 Refining MOF Databases -- 6.3.2 Screening of MOFs -- 6.4 Role of QSPR and Machine Learning in Screening of MOFs for CO2 Capture -- 6.5 Conclusions and Outlook -- References -- Chapter 7: Water Purification: Removal of Heavy Metals Using Metal-Organic Frameworks (MOFs) -- 7.1 Heavy Metals -- 7.1.1 Sources of Heavy Metals in Water -- 7.1.2 Effects on Health -- 7.2 MOFs for Removal of Heavy Metals from Water -- 7.2.1 Mercury -- 7.2.2 Lead -- 7.2.3 Cadmium -- 7.3 Summary -- References -- Chapter 8: Adsorptive Purification of Water Contaminated with Hazardous Organics by Using Functionalized Metal-Organic Framewo... -- 8.1 Introduction -- 8.2 Discussion -- 8.2.1 Introduction to Functionalized MOFs -- 8.2.2 Mechanism of Adsorptive Purification -- 8.2.2.1 Electrostatic Interaction -- 8.2.2.2 H-Bonding Interaction. 8.2.2.3 Pi-Interactions -- 8.2.2.4 Other Mechanisms -- 8.2.3 Contribution of Functional Groups on Adsorption -- 8.2.3.1 Functional Group of -NH2 or -NH- -- 8.2.3.2 Functional Group of -OH -- 8.2.3.3 Functional Group of -COOH -- 8.2.3.4 Functional Group of -SO3H -- 8.2.3.5 Other Functional Groups -- 8.3 Conclusions and Perspective -- References -- Chapter 9: MOFs Constructed from Biomolecular Building Blocks -- 9.1 Introduction -- 9.2 Nucleobases -- 9.2.1 Discrete Complexes and 1-D Polymers -- 9.2.2 Purine-Based Bio-MOFs -- 9.2.3 Purine-Based Bio-MOFs with Secondary Linkers -- 9.3 Amino Acids, Peptides, and Proteins -- 9.3.1 Amino Acids -- 9.3.2 Small Peptides and Secondary Linkers -- 9.3.3 Functionalized Peptides -- 9.3.4 Proteins -- 9.4 Saccharides -- 9.4.1 Bio-MOFs Constructed from Simple Sugars -- 9.4.2 Cyclodextrin Bio-MOFs -- 9.5 Conclusions and Future Outlook -- References -- Chapter 10: Natural Polymer-Based MOF Composites -- 10.1 Introduction -- 10.2 Processing Methodologies -- 10.2.1 Electrospinning -- 10.2.2 Hot-Pressing Method -- 10.2.3 Biomimetic Biomineralization -- 10.2.4 Layer-by-Layer Deposition -- 10.3 Natural Polymer-MOF Composites -- 10.3.1 Cellulose-Based Composites -- 10.3.1.1 Cellulose Nanofiber-Based Composites -- 10.3.1.2 Cellulose Aerogel-Based Composites -- 10.3.2 Cotton-Based Composites -- 10.3.3 Pulp (Paper)-Based Composites -- 10.3.4 Silk-Based Composites -- 10.3.5 Chitosan- and Chitin-Based Composites -- 10.4 Conclusion, Outlook, and Future Perspective -- References -- Chapter 11: Metal-Organic Frameworks as Delivery Systems of Small Drugs and Biological Gases -- 11.1 An Ideal Drug Delivery System -- 11.2 Metal-Organic Frameworks as Drug Delivery Systems -- 11.3 The Importance of Material Selection -- 11.4 The Control of Small Molecule Drug Release -- 11.5 Metal-Organic Frameworks as Delivery Systems for Biological Gases. 11.6 The Intracellular Fate of MOFs -- 11.7 External Surface Chemistry -- 11.8 Current Challenges -- 11.9 Outlook -- References -- Chapter 12: MOFs and Biomacromolecules for Biomedical Applications -- 12.1 Introduction -- 12.2 Synthesis Methods -- 12.2.1 Surface Immobilization -- 12.2.1.1 Adsorption of Biomacromolecules on MOFs -- 12.2.1.2 Grafting of Biomacromolecules on MOFs -- 12.2.1.3 General Considerations for Biomacromolecules-On-MOF Composites -- 12.2.2 Embedding of Biomacromolecules in MOFs -- 12.2.2.1 Infiltration -- 12.2.2.2 Encapsulation -- Influence of the Biomacromolecule Surface Chemistry on the Encapsulation Process -- The Relative Size of Biomacromolecules and MOF Pores -- Influence of the Chemical Properties of the MOF on the Encapsulation Process -- Influence of Coprecipitation Agents on the Encapsulation Process -- Crystalline Phase of Biomacromolecules@ZIF-8 -- Recent Developments of Encapsulation Synthetic Protocols -- General Considerations on Biomacromolecules@MOF Composites Obtained Via Encapsulation -- 12.2.3 General Properties of MOFs Biocomposites -- 12.2.3.1 Controlled MOF Degradation and Cargo Release -- 12.2.3.2 MOF Biocompatibility -- Biocomposite Particle Size -- 12.3 Applications of Biomacromolecules and MOF Biocomposites -- 12.3.1 Protein@MOF as Drug Delivery Systems -- 12.3.2 Protein@MOFs for Biopreservation -- 12.3.3 Protein-On-MOFs and Proteins@MOFs Biocomposites in Assays -- 12.3.3.1 Applications of Protein@MOF Biocomposites for Small Molecule Detection -- Protein@MOF as H2O2 Sensors -- Protein@MOF as Glucose Sensors -- 12.3.3.2 Protein-On-MOFs and Proteins@MOFs Biocomposites in Immunoassays -- 12.3.4 Carbohydrates@MOF and Carbohydrates-On-MOF Biocomposites as Drug Delivery Systems -- 12.3.4.1 MOFs as Carriers for CH-Based Therapeutics -- 12.3.4.2 Carbohydrates-On-MOF Biocomposites for DDS. 12.3.5 Nucleic Acid and MOF Biocomposites. |
| Record Nr. | UNINA-9910484824803321 |
| Cham, Switzerland : , : Springer, , [2021] | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Metal-organic frameworks with heterogeneous structures / / edited by Ali Morsali, Kayhaneh Berijani
| Metal-organic frameworks with heterogeneous structures / / edited by Ali Morsali, Kayhaneh Berijani |
| Pubbl/distr/stampa | Hoboken, New Jersey : , : Wiley-Scrivener, , [2021] |
| Descrizione fisica | 1 online resource (240 pages) |
| Disciplina | 547.05 |
| Soggetto topico | Metal-organic frameworks |
| Soggetto genere / forma | Electronic books. |
| ISBN |
1-119-79309-2
1-119-79311-4 1-119-79310-6 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNINA-9910555257203321 |
| Hoboken, New Jersey : , : Wiley-Scrivener, , [2021] | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Metal-organic frameworks with heterogeneous structures / / edited by Ali Morsali, Kayhaneh Berijani
| Metal-organic frameworks with heterogeneous structures / / edited by Ali Morsali, Kayhaneh Berijani |
| Pubbl/distr/stampa | Hoboken, New Jersey : , : Wiley-Scrivener, , [2021] |
| Descrizione fisica | 1 online resource (240 pages) |
| Disciplina | 547.05 |
| Soggetto topico | Metal-organic frameworks |
| ISBN |
1-119-79309-2
1-119-79311-4 1-119-79310-6 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNINA-9910830483803321 |
| Hoboken, New Jersey : , : Wiley-Scrivener, , [2021] | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
