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Bioinspired catalysis : metal-sulfur complexes / / edited by Wolfgang Weigand and Philippe Schollhammer ; contributors Ulf-Peter Apfel [and thirty three others]
| Bioinspired catalysis : metal-sulfur complexes / / edited by Wolfgang Weigand and Philippe Schollhammer ; contributors Ulf-Peter Apfel [and thirty three others] |
| Pubbl/distr/stampa | Weinheim, Germany : , : Wiley-VCH, , 2015 |
| Descrizione fisica | 1 online resource (438 p.) |
| Disciplina | 541.2242 |
| Soggetto topico | Metal complexes |
| ISBN |
3-527-66418-1
3-527-66416-5 3-527-66419-X |
| Formato | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Bioinspired Catalysis; Contents; List of Contributors; Preface; Part I Primordial Metal-Sulfur-Mediated Reactions; Chapter 1 From Chemical Invariance to Genetic Variability; 1.1 Heuristic of Biochemical Retrodiction; 1.2 Retrodicting the Elements of Life; 1.3 Retrodicting Pioneer Catalysis; 1.4 Retrodicting Metabolic Reproduction and Evolution; 1.5 Retrodicting Pioneer-Metabolic Reactions; 1.6 Early Evolution in a Spatiotemporal Flow Context; Acknowledgments; References; Chapter 2 Fe-S Clusters: Biogenesis and Redox, Catalytic, and Regulatory Properties; 2.1 Introduction
2.2 Fe-S Cluster Biogenesis and Trafficking2.3 Redox Properties of Fe-S Clusters; 2.4 Fe-S Clusters and Catalysis; 2.4.1 Redox Catalysis; 2.4.2 Nonredox Fe-S Cluster-Based Catalysis; 2.5 Fe-S Clusters and Oxidative Stress; 2.6 Regulation of Protein Expression by Fe-S Clusters; 2.6.1 Eukaryotic Iron Regulatory Protein 1 (IRP1); 2.6.1.1 IRP1 and Fe-S Cluster Biogenesis; 2.6.1.2 Reactive Oxygen Species and IRP1 Fe-S Cluster Stability; 2.6.1.3 X-Ray Structural Studies of IRP1-IRE Complexes; 2.6.2 Bacterial Fumarate Nitrate Reduction Regulator (FNR); 2.6.3 The ISC Assembly Machinery Regulator IscR 2.7 ConclusionReferences; Part II Model Complexes of the Active Site of Hydrogenases - Proton and Dihydrogen Activation; Chapter 3 [NiFe] Hydrogenases; 3.1 Introduction; 3.2 Introduction to [NiFe] Hydrogenases; 3.3 Nickel Thiolate Complexes as Analogs of [NiFe] Hydrogenase; 3.4 [NiFe] Hydrogenase Model Complexes; 3.4.1 Amine [N2Ni(μ-S2)Fe] Complexes; 3.4.2 Phosphine [P2Ni(μ-S2)Fe] Complexes; 3.4.3 Thiolate [SxNi(μ-Sy)Fe] Complexes; 3.4.4 Polymetallic [Ni(μ-S)zFey] Complexes; 3.5 Analogs of [NiFe] Hydrogenase Incorporating Proton Relays; 3.5.1 Nickel Complexes Incorporating Protonation Sites 3.5.2 [NiFe] Complexes Incorporating Protonation Sites3.6 Perspectives and Future Challenges; Acknowledgments; References; Chapter 4 [FeFe] Hydrogenase Models: an Overview; 4.1 Introduction; 4.2 Synthetic Strategies toward [FeFe] Hydrogenase Model Complexes; 4.3 Properties of Model Complexes; 4.3.1 Biomimetic Models of the ""Rotated State""; 4.3.2 Electron Transfer in [FeFe] Hydrogenase Models; 4.3.3 Protonation Chemistry of [FeFe] Hydrogenase Models; 4.3.3.1 Hydride Formation; 4.3.3.2 Ligand Protonation and Proton Relays; 4.3.4 Water-Soluble Hydrogenase Mimics; 4.4 Conclusion; References Chapter 5 The Third Hydrogenase5.1 Introduction; 5.2 Initial Studies of Hmd; 5.3 Discovery that Hmd Contains a Bound Cofactor; 5.4 Discovery that Hmd is a Metalloenzyme; 5.5 Crystal Structure Studies of [Fe] Hydrogenase; 5.6 Mechanistic Models of [Fe] Hydrogenase; 5.6.1 Studies Before the Most Recent Assignment of the FeGP Cofactor; 5.6.2 Studies After the Most Recent Assignment of the FeGP Cofactor; 5.6.3 Synthesized Model Complexes of the FeGP Cofactor; References; Chapter 6 DFT Investigation of Models Related to the Active Site of Hydrogenases; 6.1 Introduction 6.2 QM Studies of Hydrogenases |
| Record Nr. | UNINA-9910132344203321 |
| Weinheim, Germany : , : Wiley-VCH, , 2015 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Bioinspired catalysis : metal-sulfur complexes / / edited by Wolfgang Weigand and Philippe Schollhammer ; contributors Ulf-Peter Apfel [and thirty three others]
| Bioinspired catalysis : metal-sulfur complexes / / edited by Wolfgang Weigand and Philippe Schollhammer ; contributors Ulf-Peter Apfel [and thirty three others] |
| Pubbl/distr/stampa | Weinheim, Germany : , : Wiley-VCH, , 2015 |
| Descrizione fisica | 1 online resource (438 p.) |
| Disciplina | 541.2242 |
| Soggetto topico | Metal complexes |
| ISBN |
3-527-66418-1
3-527-66416-5 3-527-66419-X |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Bioinspired Catalysis; Contents; List of Contributors; Preface; Part I Primordial Metal-Sulfur-Mediated Reactions; Chapter 1 From Chemical Invariance to Genetic Variability; 1.1 Heuristic of Biochemical Retrodiction; 1.2 Retrodicting the Elements of Life; 1.3 Retrodicting Pioneer Catalysis; 1.4 Retrodicting Metabolic Reproduction and Evolution; 1.5 Retrodicting Pioneer-Metabolic Reactions; 1.6 Early Evolution in a Spatiotemporal Flow Context; Acknowledgments; References; Chapter 2 Fe-S Clusters: Biogenesis and Redox, Catalytic, and Regulatory Properties; 2.1 Introduction
2.2 Fe-S Cluster Biogenesis and Trafficking2.3 Redox Properties of Fe-S Clusters; 2.4 Fe-S Clusters and Catalysis; 2.4.1 Redox Catalysis; 2.4.2 Nonredox Fe-S Cluster-Based Catalysis; 2.5 Fe-S Clusters and Oxidative Stress; 2.6 Regulation of Protein Expression by Fe-S Clusters; 2.6.1 Eukaryotic Iron Regulatory Protein 1 (IRP1); 2.6.1.1 IRP1 and Fe-S Cluster Biogenesis; 2.6.1.2 Reactive Oxygen Species and IRP1 Fe-S Cluster Stability; 2.6.1.3 X-Ray Structural Studies of IRP1-IRE Complexes; 2.6.2 Bacterial Fumarate Nitrate Reduction Regulator (FNR); 2.6.3 The ISC Assembly Machinery Regulator IscR 2.7 ConclusionReferences; Part II Model Complexes of the Active Site of Hydrogenases - Proton and Dihydrogen Activation; Chapter 3 [NiFe] Hydrogenases; 3.1 Introduction; 3.2 Introduction to [NiFe] Hydrogenases; 3.3 Nickel Thiolate Complexes as Analogs of [NiFe] Hydrogenase; 3.4 [NiFe] Hydrogenase Model Complexes; 3.4.1 Amine [N2Ni(μ-S2)Fe] Complexes; 3.4.2 Phosphine [P2Ni(μ-S2)Fe] Complexes; 3.4.3 Thiolate [SxNi(μ-Sy)Fe] Complexes; 3.4.4 Polymetallic [Ni(μ-S)zFey] Complexes; 3.5 Analogs of [NiFe] Hydrogenase Incorporating Proton Relays; 3.5.1 Nickel Complexes Incorporating Protonation Sites 3.5.2 [NiFe] Complexes Incorporating Protonation Sites3.6 Perspectives and Future Challenges; Acknowledgments; References; Chapter 4 [FeFe] Hydrogenase Models: an Overview; 4.1 Introduction; 4.2 Synthetic Strategies toward [FeFe] Hydrogenase Model Complexes; 4.3 Properties of Model Complexes; 4.3.1 Biomimetic Models of the ""Rotated State""; 4.3.2 Electron Transfer in [FeFe] Hydrogenase Models; 4.3.3 Protonation Chemistry of [FeFe] Hydrogenase Models; 4.3.3.1 Hydride Formation; 4.3.3.2 Ligand Protonation and Proton Relays; 4.3.4 Water-Soluble Hydrogenase Mimics; 4.4 Conclusion; References Chapter 5 The Third Hydrogenase5.1 Introduction; 5.2 Initial Studies of Hmd; 5.3 Discovery that Hmd Contains a Bound Cofactor; 5.4 Discovery that Hmd is a Metalloenzyme; 5.5 Crystal Structure Studies of [Fe] Hydrogenase; 5.6 Mechanistic Models of [Fe] Hydrogenase; 5.6.1 Studies Before the Most Recent Assignment of the FeGP Cofactor; 5.6.2 Studies After the Most Recent Assignment of the FeGP Cofactor; 5.6.3 Synthesized Model Complexes of the FeGP Cofactor; References; Chapter 6 DFT Investigation of Models Related to the Active Site of Hydrogenases; 6.1 Introduction 6.2 QM Studies of Hydrogenases |
| Record Nr. | UNINA-9910817867803321 |
| Weinheim, Germany : , : Wiley-VCH, , 2015 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Crystal Structures of Metal Complexes / / edited by Hiroshi Sakiyama
| Crystal Structures of Metal Complexes / / edited by Hiroshi Sakiyama |
| Pubbl/distr/stampa | [Place of publication not identified] : , : MDPI - Multidisciplinary Digital Publishing Institute, , 2023 |
| Descrizione fisica | 1 online resource (164 pages) |
| Disciplina | 541.2242 |
| Soggetto topico | Metal complexes |
| ISBN | 3-0365-6452-7 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto | Preface to "Crystal Structures of Metal Complexes" . vii -- Ryusei Hoshikawa, Ryoji Mitsuhashi, Eiji Asato, Jianqiang Liu and Hiroshi Sakiyama Structures of Dimer-of-Dimers Type Defect Cubane Tetranuclear Copper(II) Complexes with Novel Dinucleating Ligands Reprinted from: Molecules 2022, 27, 576, doi:10.3390/molecules27020576 1 -- Franz A. Mautner, Florian Bierbaumer, Ramon Vicente, Saskia Speed, Annia Tubau and ´ Merc `e Font-Bard´ıa et al. Magnetic and Luminescence Properties of 8-Coordinate Holmium(III) Complexes Containing 4,4,4-Trifluoro-1-Phenyl- and 1-(Naphthalen-2-yl)-1,3-Butanedionates Reprinted from: Molecules 2022, 27, 1129, doi:10.3390/molecules27031129 15 -- Mezna Saleh Altowyan, Saied M. Soliman, Jamal Lasri, Naser E. Eltayeb, Matti Haukka and Assem Barakat et al. A New Pt(II) Complex with Anionic s-Triazine Based NNO-Donor Ligand: Synthesis, X-ray Structure, Hirshfeld Analysis and DFT Studies Reprinted from: Molecules 2022, 27, 1628, doi:10.3390/molecules27051628 31 -- Ryoji Mitsuhashi, Yuya Imai, Takayoshi Suzuki and Yoshihito Hayashi Selective Formation of Intramolecular Hydrogen-Bonding Palladium(II) Complexes with Nucleosides Using Unsymmetrical Tridentate Ligands Reprinted from: Molecules 2022, 27, 2098, doi:10.3390/molecules27072098 43 -- Sabrina Grenda, Maxime Beau and Dominique Luneau Synthesis, Crystal Structure and Magnetic Properties of a Trinuclear Copper(II) Complex Based on P-Cresol-Substituted Bis(α-Nitronyl Nitroxide) Biradical Reprinted from: Molecules 2022, 27, 3218, doi:10.3390/molecules27103218 57 -- Richard F. D'Vries, Germ´an E. Gomez and Javier Ellena Highlighting Recent Crystalline Engineering Aspects of Luminescent Coordination Polymers Based on F-Elements and Ditopic Aliphatic Ligands Reprinted from: Molecules 2022, 27, 3830, doi:10.3390/molecules27123830 73 -- Sifani Zavahir, Hamdi Ben Yahia, Julian Schneider, DongSuk Han, Igor Krupa and Tausif Altamash et al. Fluorescent Zn(II)-Based Metal-Organic Framework: Interaction with Organic Solvents and CO2 and Methane Capture Reprinted from: Molecules 2022, 27, 3845, doi:10.3390/molecules27123845 87 -- Masahiro Mikuriya, Yuko Naka, Ayumi Inaoka, Mika Okayama, Daisuke Yoshioka and Hiroshi Sakiyama et al. Mixed-Valent Trinuclear CoIII-CoII-CoIII Complex with 1,3-Bis(5-chlorosalicylideneamino)-2-propanol Reprinted from: Molecules 2022, 27, 4211, doi:10.3390/molecules27134211 101 -- Kennedy Mawunya Hayibor, Yukinari Sunatsuki and Takayoshi Suzuki Selective Formation of Unsymmetric Multidentate Azine-Based Ligands in Nickel(II) Complexes Reprinted from: Molecules 2022, 27, 6788, doi:10.3390/molecules27206788 115 -- Izabela Pospieszna-Markiewicz, Marta A. Fik-Jask ´ołka, Zbigniew Hnatejko, Violetta Patroniak and Maciej Kubicki Synthesis and Characterization of Lanthanide Metal Ion Complexes of New Polydentate Hydrazone Schiff Base Ligand Reprinted from: Molecules 2022, 27, 8390, doi:10.3390/molecules27238390 125 -- Alexander G. Medvedev, Oleg Yu. Savelyev, Dmitry P. Krut'ko, Alexey A. Mikhaylov, Ovadia Lev and Petr V. Prikhodchenko Speciation of Tellurium(VI) in Aqueous Solutions: Identification of Trinuclear Tellurates by 17O, 123Te, and 125Te NMR Spectroscopy Reprinted from: Molecules 2022, 27, 8654, doi:10.3390/molecules27248654 139. |
| Record Nr. | UNINA-9910647219303321 |
| [Place of publication not identified] : , : MDPI - Multidisciplinary Digital Publishing Institute, , 2023 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Electrochemistry of metal complexes : applications from electroplating to oxide layer formation / / Arvydas Survila
| Electrochemistry of metal complexes : applications from electroplating to oxide layer formation / / Arvydas Survila |
| Autore | Survila Arvydas |
| Pubbl/distr/stampa | Weinheim, Germany : , : Wiley-VCH, , 2015 |
| Descrizione fisica | 1 online resource (306 p.) |
| Disciplina | 541.37 |
| Soggetto topico |
Electrochemistry
Metal complexes Chemical equilibrium |
| ISBN |
3-527-69125-1
3-527-69124-3 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Cover; Title Page; Copyright; Contents; Preface; Symbols and Abbreviations; Chapter 1 Introduction; 1.1 Equilibrium Properties of Complex Systems; 1.1.1 General Definitions; 1.1.2 Equilibrium in the Solutions of Complex Compounds; 1.1.3 Distribution of Complexes and Ligands in the Solution; References; Chapter 2 Equilibrium Electrode Potentials; 2.1 Electrodes of the First Kind; 2.2 Equilibria Involving Ions of the Intermediate Oxidation State; 2.3 Electrodes of the Second Kind; 2.4 Open-Circuit Potentials: Examples of Experimental Investigations; 2.4.1 System Cu/Cu(I),CN-
2.4.2 System Cu/Cu(II), β-AlanineReferences; Chapter 3 Mass Transport; 3.1 Two Models of Linear Mass Transport; 3.2 Other Cases of Diffusional Mass Transport; 3.3 Mass Transport of Chemically Interacting Particles; 3.4 Concentration Profiles; 3.4.1 Concentration Profiles in Ideally Labile Systems; 4.2 Potential Transients; 3.4.2 Concentration Profiles in Systems of Limited Lability; References; Chapter 4 Peculiarities of Electrochemical Processes Involving Labile Complexes; 4.1 Steady-State Voltammograms; 4.3 Current Transients; References Chapter 5 Quantitative Modeling of Quasi-Reversible Electrochemical Processes Involving Labile Complexes of Metals5.1 Kinetic Equations; 5.2 Employment of Voltammetric Data; 5.2.1 Tafel Plots Normalized with Respect to the Surface Concentration of EAC; 5.2.2 Analysis of LPS Current Maxima; 5.3 Techniques Based on the Control of the Intensity of Forced Convection; 5.3.1 Isosurface Concentration Voltammetry; 5.3.2 Determination of the Exchange Current Density from Polarization Resistance; 5.3.3 Electrochemical Impedance Spectroscopy (EIS) under Forced Convection Conditions; References Chapter 6 Determination of Mechanism of Electrochemical Processes Involving Metal Complexes6.1 Determination of the Mechanism by Reaction Orders; 6.2 Method of Isopotential Solutions; References; Chapter 7 Adsorption; 7.1 Thermodynamic Aspects; 7.2 Model Aspects; References; Chapter 8 Electrochemical Processes in Real Systems; 8.1 Experimental Details; 8.2 Cyanide Systems; 8.2.1 System Cu|Cu(I), CN-; 8.2.2 System Ag|Ag(I), CN-; 8.2.3 System Au|Au(I), CN-; 8.3 Ecological Systems Containing Hydroxy Acids; 8.3.1 Electroreduction of Cu(II) Complexes; 8.3.2 Electroreduction of Sn(II) Complexes 8.3.3 Electroreduction of Zn(II) ComplexesAppendix; References; Chapter 9 Electrochemical Deposition of Alloys; 9.1 Mass Transport during the Codeposition of Metals; 9.2 Codeposition of Cobalt and Tin; 9.3 Deposition of Brass Coatings; 9.4 Deposition of Bronze Coatings; 9.4.1 Surface Activity of Polyethers on Copper and Tin Substrates; 9.4.2 Effect of Halides. Formation of Surface Complexes; 9.4.3 Effect of Length of the Hydrocarbon Chain; 9.4.4 Codeposition of Copper and Tin; 9.4.5 Related Phenomena: Current Oscillations; 9.5 Codeposition of Cobalt and Molybdenum; References Chapter 10 Spontaneous Formation of Photosensitive Cuprous Oxide Layers |
| Record Nr. | UNINA-9910140494103321 |
Survila Arvydas
|
||
| Weinheim, Germany : , : Wiley-VCH, , 2015 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Electrochemistry of metal complexes : applications from electroplating to oxide layer formation / / Arvydas Survila
| Electrochemistry of metal complexes : applications from electroplating to oxide layer formation / / Arvydas Survila |
| Autore | Survila Arvydas |
| Pubbl/distr/stampa | Weinheim, Germany : , : Wiley-VCH, , 2015 |
| Descrizione fisica | 1 online resource (306 p.) |
| Disciplina | 541.37 |
| Soggetto topico |
Electrochemistry
Metal complexes Chemical equilibrium |
| ISBN |
3-527-69125-1
3-527-69124-3 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Cover; Title Page; Copyright; Contents; Preface; Symbols and Abbreviations; Chapter 1 Introduction; 1.1 Equilibrium Properties of Complex Systems; 1.1.1 General Definitions; 1.1.2 Equilibrium in the Solutions of Complex Compounds; 1.1.3 Distribution of Complexes and Ligands in the Solution; References; Chapter 2 Equilibrium Electrode Potentials; 2.1 Electrodes of the First Kind; 2.2 Equilibria Involving Ions of the Intermediate Oxidation State; 2.3 Electrodes of the Second Kind; 2.4 Open-Circuit Potentials: Examples of Experimental Investigations; 2.4.1 System Cu/Cu(I),CN-
2.4.2 System Cu/Cu(II), β-AlanineReferences; Chapter 3 Mass Transport; 3.1 Two Models of Linear Mass Transport; 3.2 Other Cases of Diffusional Mass Transport; 3.3 Mass Transport of Chemically Interacting Particles; 3.4 Concentration Profiles; 3.4.1 Concentration Profiles in Ideally Labile Systems; 4.2 Potential Transients; 3.4.2 Concentration Profiles in Systems of Limited Lability; References; Chapter 4 Peculiarities of Electrochemical Processes Involving Labile Complexes; 4.1 Steady-State Voltammograms; 4.3 Current Transients; References Chapter 5 Quantitative Modeling of Quasi-Reversible Electrochemical Processes Involving Labile Complexes of Metals5.1 Kinetic Equations; 5.2 Employment of Voltammetric Data; 5.2.1 Tafel Plots Normalized with Respect to the Surface Concentration of EAC; 5.2.2 Analysis of LPS Current Maxima; 5.3 Techniques Based on the Control of the Intensity of Forced Convection; 5.3.1 Isosurface Concentration Voltammetry; 5.3.2 Determination of the Exchange Current Density from Polarization Resistance; 5.3.3 Electrochemical Impedance Spectroscopy (EIS) under Forced Convection Conditions; References Chapter 6 Determination of Mechanism of Electrochemical Processes Involving Metal Complexes6.1 Determination of the Mechanism by Reaction Orders; 6.2 Method of Isopotential Solutions; References; Chapter 7 Adsorption; 7.1 Thermodynamic Aspects; 7.2 Model Aspects; References; Chapter 8 Electrochemical Processes in Real Systems; 8.1 Experimental Details; 8.2 Cyanide Systems; 8.2.1 System Cu|Cu(I), CN-; 8.2.2 System Ag|Ag(I), CN-; 8.2.3 System Au|Au(I), CN-; 8.3 Ecological Systems Containing Hydroxy Acids; 8.3.1 Electroreduction of Cu(II) Complexes; 8.3.2 Electroreduction of Sn(II) Complexes 8.3.3 Electroreduction of Zn(II) ComplexesAppendix; References; Chapter 9 Electrochemical Deposition of Alloys; 9.1 Mass Transport during the Codeposition of Metals; 9.2 Codeposition of Cobalt and Tin; 9.3 Deposition of Brass Coatings; 9.4 Deposition of Bronze Coatings; 9.4.1 Surface Activity of Polyethers on Copper and Tin Substrates; 9.4.2 Effect of Halides. Formation of Surface Complexes; 9.4.3 Effect of Length of the Hydrocarbon Chain; 9.4.4 Codeposition of Copper and Tin; 9.4.5 Related Phenomena: Current Oscillations; 9.5 Codeposition of Cobalt and Molybdenum; References Chapter 10 Spontaneous Formation of Photosensitive Cuprous Oxide Layers |
| Record Nr. | UNINA-9910828871103321 |
|
Survila Arvydas
|
||
| Weinheim, Germany : , : Wiley-VCH, , 2015 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Homogeneous catalysis with metal complexes [[electronic resource] ] : kinetic aspects and mechanisms / / O.N. Temkin ; translated from the Russian by P.P. Pozdeev
| Homogeneous catalysis with metal complexes [[electronic resource] ] : kinetic aspects and mechanisms / / O.N. Temkin ; translated from the Russian by P.P. Pozdeev |
| Autore | Temkin O. N |
| Edizione | [2nd ed.] |
| Pubbl/distr/stampa | Chichester, U.K., : Wiley, 2012 |
| Descrizione fisica | 1 online resource (832 p.) |
| Disciplina | 541.395 |
| Soggetto topico |
Catalysis
Metal catalysts Metal complexes |
| ISBN |
1-119-96682-5
1-283-42537-8 9786613425379 1-119-96622-1 1-119-96623-X |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Homogeneous Catalysis with Metal Complexes; Contents; Notations and Abbreviations; Preface to English Edition; Preface; Acknowledgments; About the Author; Introduction; 1 State-of-the-Art in the Theory of Kinetics of Complex Reactions; 1.1 Main concepts of the Horiuti-Temkin theory of steady-state reactions; 1.1.1 Reaction mechanism: Stoichiometry and routes; 1.1.2 Kinetics: Reaction rates with respect to substances and over routes; 1.1.3 Kinetic polynomial; 1.1.4 Determining the number of independent parameters in a kinetic model. The problem of identifiability of parameters
1.2 Quasi-steady-state and quasi-equilibrium approximations in chemical kinetics1.2.1 Theoretical criteria of quasi-steady-state intermediate concentrations and quasi-equilibrium steps; 1.2.2 Experimental criteria of applicability of quasi-steady-state approximation in various systems; 1.3 Methods of graph theory in chemical kinetics and in theory of complex reaction mechanisms; 1.3.1 Linear mechanisms; 1.3.2 Nonlinear mechanisms; 1.3.3 Other fields of application of kinetic and bipartite graphs in chemical kinetics and in theory of complex reaction mechanisms 1.4 Elementary steps - Selection rules1.4.1 Main postulates, laws, and principles; 1.4.2 Energy selection rules for elementary steps; 1.4.3 Quantum-chemical selection rules for elementary steps; 1.4.4 Topological selection rules for elementary steps; References; 2 Complexity Functions of Catalysts and Reactants in Reactions Involving Metal Complexes; 2.1 Mononuclear metal complexes; 2.1.1 Complexity functions: variants I and II; 2.1.2 Complexity functions: variants III and IV; 2.1.3 General problems and recommendations 2.2 Polynuclear complexes in homogeneous catalytic and noncatalytic reactions2.2.1 Systems with formation of associates; 2.2.2 Systems with mononuclear and polynuclear complexes of various types; 2.3 Catalysis with polynuclear copper(I) halide complexes in superconcentrated solutions; 2.3.1 Copper(I) chloride complexes in solution and in crystalline state; 2.3.2 Kinetics of catalytic reactions of alkynes in concentrated NH4Cl-CuCl aqueous solutions at constant complexity functions FCu and FCl; 2.3.3 Determination of compositions of catalytically active copper(I) complexes in various reactions 2.3.4 Studying p and s complexes of copper(I) with alkynes in crystalline state and in solution2.3.5 Mechanisms of acetylene dimerization and hydrocyanation reactions. Crystallochemical aspects; References; 3 Multi-Route Mechanisms in Reactions Involving Metal Complexes; 3.1 Factors accounting for the appearance and kinetic features of multi-route mechanisms; 3.2 Analysis of multi-route reaction kinetics; 3.3 Conjugation nodes and artificial multi-route character; 3.4 Conjugate processes; 3.4.1 Classical approach; 3.4.2 Kinetic and thermodynamic conjugation in consecutive reactions 3.4.3 Conjugation in chain reactions |
| Record Nr. | UNINA-9910139294503321 |
|
Temkin O. N
|
||
| Chichester, U.K., : Wiley, 2012 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Homogeneous catalysis with metal complexes : kinetic aspects and mechanisms / / O.N. Temkin ; translated from the Russian by P.P. Pozdeev
| Homogeneous catalysis with metal complexes : kinetic aspects and mechanisms / / O.N. Temkin ; translated from the Russian by P.P. Pozdeev |
| Autore | Temkin O. N |
| Edizione | [2nd ed.] |
| Pubbl/distr/stampa | Chichester, U.K., : Wiley, 2012 |
| Descrizione fisica | 1 online resource (832 p.) |
| Disciplina | 541.395 |
| Soggetto topico |
Catalysis
Metal catalysts Metal complexes |
| ISBN |
1-119-96682-5
1-283-42537-8 9786613425379 1-119-96622-1 1-119-96623-X |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Homogeneous Catalysis with Metal Complexes; Contents; Notations and Abbreviations; Preface to English Edition; Preface; Acknowledgments; About the Author; Introduction; 1 State-of-the-Art in the Theory of Kinetics of Complex Reactions; 1.1 Main concepts of the Horiuti-Temkin theory of steady-state reactions; 1.1.1 Reaction mechanism: Stoichiometry and routes; 1.1.2 Kinetics: Reaction rates with respect to substances and over routes; 1.1.3 Kinetic polynomial; 1.1.4 Determining the number of independent parameters in a kinetic model. The problem of identifiability of parameters
1.2 Quasi-steady-state and quasi-equilibrium approximations in chemical kinetics1.2.1 Theoretical criteria of quasi-steady-state intermediate concentrations and quasi-equilibrium steps; 1.2.2 Experimental criteria of applicability of quasi-steady-state approximation in various systems; 1.3 Methods of graph theory in chemical kinetics and in theory of complex reaction mechanisms; 1.3.1 Linear mechanisms; 1.3.2 Nonlinear mechanisms; 1.3.3 Other fields of application of kinetic and bipartite graphs in chemical kinetics and in theory of complex reaction mechanisms 1.4 Elementary steps - Selection rules1.4.1 Main postulates, laws, and principles; 1.4.2 Energy selection rules for elementary steps; 1.4.3 Quantum-chemical selection rules for elementary steps; 1.4.4 Topological selection rules for elementary steps; References; 2 Complexity Functions of Catalysts and Reactants in Reactions Involving Metal Complexes; 2.1 Mononuclear metal complexes; 2.1.1 Complexity functions: variants I and II; 2.1.2 Complexity functions: variants III and IV; 2.1.3 General problems and recommendations 2.2 Polynuclear complexes in homogeneous catalytic and noncatalytic reactions2.2.1 Systems with formation of associates; 2.2.2 Systems with mononuclear and polynuclear complexes of various types; 2.3 Catalysis with polynuclear copper(I) halide complexes in superconcentrated solutions; 2.3.1 Copper(I) chloride complexes in solution and in crystalline state; 2.3.2 Kinetics of catalytic reactions of alkynes in concentrated NH4Cl-CuCl aqueous solutions at constant complexity functions FCu and FCl; 2.3.3 Determination of compositions of catalytically active copper(I) complexes in various reactions 2.3.4 Studying p and s complexes of copper(I) with alkynes in crystalline state and in solution2.3.5 Mechanisms of acetylene dimerization and hydrocyanation reactions. Crystallochemical aspects; References; 3 Multi-Route Mechanisms in Reactions Involving Metal Complexes; 3.1 Factors accounting for the appearance and kinetic features of multi-route mechanisms; 3.2 Analysis of multi-route reaction kinetics; 3.3 Conjugation nodes and artificial multi-route character; 3.4 Conjugate processes; 3.4.1 Classical approach; 3.4.2 Kinetic and thermodynamic conjugation in consecutive reactions 3.4.3 Conjugation in chain reactions |
| Record Nr. | UNINA-9910817073903321 |
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Temkin O. N
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| Chichester, U.K., : Wiley, 2012 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
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Kinetically controlled stepwise syntheses of a heterometallic complex and a tetrahedral chiral-at-metal complex / / Kenichi Endo
| Kinetically controlled stepwise syntheses of a heterometallic complex and a tetrahedral chiral-at-metal complex / / Kenichi Endo |
| Autore | Endō Ken'ichi <1961-> |
| Pubbl/distr/stampa | Singapore : , : Springer, , [2021] |
| Descrizione fisica | 1 online resource (xv, 80 pages) |
| Disciplina | 541.2242 |
| Collana | Springer theses |
| Soggetto topico | Metal complexes |
| ISBN | 981-16-1163-7 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto | Intro -- Supervisor's Foreword -- Acknowledgments -- Contents -- Abbreviations -- 1 General Introduction -- 1.1 Selective Synthesis of Metal Complexes -- 1.2 Target Scope of Kinetically Controlled Stepwise Synthesis -- 1.3 Overview of This Study -- References -- 2 Heterometallic CoIINi3II Complex -- 2.1 Introduction -- 2.2 Step 1: Complexation with a Redox-Active Metal -- 2.3 Step 2: Site-Selective Oxidation -- 2.4 Step 3: Site-Selective Transmetalation -- 2.5 Step 4: Reduction -- 2.6 Comparison with Other Strategies -- 2.7 Conclusions -- 2.8 Experimental Section -- 2.8.1 Materials and Methods -- 2.8.2 Synthesis of Compounds -- 2.8.3 Miscellaneous Experiments -- 2.8.4 Single-Crystal XRD Analyses -- References -- 3 Tetrahedral Chiral-at-Metal ZnII Complex -- 3.1 Introduction -- 3.2 Molecular Design -- 3.3 Strategy for Enantioselective Synthesis -- 3.4 Step 1: Racemic Complexation -- 3.5 Step 2: Asymmetric Induction with a Chiral Ligand -- 3.6 Step 3: Replacement of the Chiral Ligand -- 3.7 Configurational Stability -- 3.8 Enantioselective Catalysis -- 3.9 Conclusions -- 3.10 Experimental Section -- 3.10.1 Materials and Methods -- 3.10.2 Synthesis of the Ligand -- 3.10.3 Syntheses of the Metal Complexes -- 3.10.4 Single-Crystal X-Ray Diffraction Analyses -- 3.10.5 Miscellaneous Experiments -- References -- 4 Conclusions -- 4.1 Conclusions -- Curriculum Vitae -- Education -- Appointment -- Research Interest -- Major Awards -- Fellowship. |
| Record Nr. | UNINA-9910483028303321 |
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Endō Ken'ichi <1961->
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| Singapore : , : Springer, , [2021] | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
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Main group metal coordination polymers : structures and nanostructures / / Lida Hashemi and Ali Morsali
| Main group metal coordination polymers : structures and nanostructures / / Lida Hashemi and Ali Morsali |
| Autore | Hashemi Lida |
| Pubbl/distr/stampa | Hoboken, New Jersey ; ; Beverly, Massachusetts : , : Scrivener Publishing : , : Wiley, , 2017 |
| Descrizione fisica | 1 online resource (261 pages) |
| Disciplina | 547.7 |
| Soggetto topico |
Coordination polymers
Polymers Metal complexes |
| ISBN |
1-119-37076-0
1-119-37077-9 1-119-37075-2 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNINA-9910162922803321 |
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Hashemi Lida
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| Hoboken, New Jersey ; ; Beverly, Massachusetts : , : Scrivener Publishing : , : Wiley, , 2017 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Main group metal coordination polymers : structures and nanostructures / / Lida Hashemi and Ali Morsali
| Main group metal coordination polymers : structures and nanostructures / / Lida Hashemi and Ali Morsali |
| Autore | Hashemi Lida |
| Pubbl/distr/stampa | Hoboken, New Jersey ; ; Beverly, Massachusetts : , : Scrivener Publishing : , : Wiley, , 2017 |
| Descrizione fisica | 1 online resource (261 pages) |
| Disciplina | 547.7 |
| Soggetto topico |
Coordination polymers
Polymers Metal complexes |
| ISBN |
1-119-37076-0
1-119-37077-9 1-119-37075-2 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNINA-9910807072703321 |
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Hashemi Lida
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| Hoboken, New Jersey ; ; Beverly, Massachusetts : , : Scrivener Publishing : , : Wiley, , 2017 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Soggetto topico
-
Metal complexes
(33)
- Macromolecules (19)
- Organometallic polymers (9)
- Polymers (5)
- Chemistry (3)