Lithium compounds in organic synthesis : from fundamentals to applications / / edited by Renzo Luisi and Vito Capriati |
Pubbl/distr/stampa | Weinheim, Germany : , : Wiley-VCH Verlag, , 2014 |
Descrizione fisica | 1 online resource (571 p.) |
Disciplina | 547.05381 |
Soggetto topico |
Cyclic compounds
Lithium compounds Organic compounds - Synthesis |
ISBN |
3-527-66753-9
3-527-66751-2 3-527-66754-7 |
Formato | Materiale a stampa ![]() |
Livello bibliografico | Monografia |
Lingua di pubblicazione | ger |
Nota di contenuto |
Lithium Compounds in Organic Synthesis; Contents; List of Contributors; Foreword; Preface; Part I New Structural Aspects of Lithium Compounds; Chapter 1 Structure-Reactivity Relationship in Organolithium Compounds; 1.1 Structural Principles in Organolithium Compounds; 1.2 Donor-Base-Free Structures; 1.2.1 Tetramers; 1.2.2 Hexamers; 1.2.3 Comparison of [Me3SiCH2Li]6 and [n-BuLi]6; 1.3 Disaggregation with Lewis Bases; 1.3.1 Tetramers of Alkyllithium Compounds; 1.3.2 Asymmetric Aggregates of [Me3SiCH2Li] (4); 1.3.3 An Octameric Aggregate of [Me3SiCH2Li]6
1.4 Donor-Base-Induced Dimers and Monomers1.4.1 Alkyllithium and Trimethylsilylmethyllithium Compounds; 1.4.2 PMDETA Aggregated Monomers; 1.5 Heterobimetallic Organolithium Compounds; 1.6 Conclusion and Outlook; References; Further Reading; Chapter 2 Computational Perspectives on Organolithiums; 2.1 Introduction; 2.2 The Nature of Bonds to Lithium; 2.3 Aggregation of Lithium Organic Compounds; 2.4 Solvation Effects; 2.5 Lithium Alkoxides and Lithium Amides; 2.6 Computational Studies on Various Organolithium Applications; 2.7 Conclusion and Outlook; References; Further Reading Chapter 3 Spectroscopic Advances in Organolithium Reactivity: The Contribution of Rapid-Injection NMR (RINMR)3.1 Introduction; 3.2 The Curtin-Hammett Principle; 3.3 Organolithium NMR; 3.4 Features of RINMR; 3.4.1 Brief History; 3.4.2 Apparatus Descriptions and Rapidity of Acquisition; 3.4.3 Temperature Range and Control; 3.4.4 Volume Accuracy of Injection; 3.5 Use of RINMR to Study Organometallic Reactions; 3.5.1 n-Butyllithium Aggregate Reactivity (1985); 3.5.2 Magnesium Chelates in Carbonyl Additions (1987/1990); 3.5.3 Lithium Enolate Aldol (1992) 3.5.4 Alkyllithium Polymerization (1995/1999)3.5.5 Tin Transmetallation (2007); 3.5.6 Cuprates (2002-Present); 3.5.7 n-BuLi Aggregate Reactivity Revisited (2007); 3.5.8 Tris(trimethylsilyl)methyllithium (2008/2009); 3.5.9 Enolization and Lithium Aldol (2011); 3.6 Conclusion and Outlook; References; Further Reading; Chapter 4 Spectroscopic Advances in Structural Lithium Chemistry: Diffusion-Ordered Spectroscopy and Solid-State NMR; 4.1 General Introduction; 4.2 Application of Solution NMR to the Structural Characterization of Organolithium Compounds; 4.2.1 Diffusion NMR Measurement Methods 4.2.1.1 Pulsed Field Gradient Spin Echo (PFGSE)4.2.1.2 From the First to the Second Dimension: DOSY NMR Experiment; 4.2.2 DOSY Application to the Structural Analysis of Organolithium Compounds; 4.2.2.1 Structure of the Mixed Methyllithium/Lithium Chloride Aggregate; 4.2.2.2 Structure of a Lithium Phosphido-Borane; 4.2.2.3 Structure of Lithium Zincate; 4.2.3 Conclusion; 4.3 Solid-State NMR; 4.3.1 Basic Principles; 4.3.1.1 Homo and Heteronuclear Dipole-Dipole Couplings (D: Dipole-Dipole); 4.3.1.2 Chemical Shift Anisotropy (CSA); 4.3.1.3 Quadrupolar Interactions for Nuclei with I< 1/2 (Q) 4.3.1.4 Magic Angle Spinning (MAS) |
Record Nr. | UNINA-9910140280003321 |
Weinheim, Germany : , : Wiley-VCH Verlag, , 2014 | ||
![]() | ||
Lo trovi qui: Univ. Federico II | ||
|
Lithium compounds in organic synthesis : from fundamentals to applications / / edited by Renzo Luisi and Vito Capriati |
Pubbl/distr/stampa | Weinheim, Germany : , : Wiley-VCH Verlag, , 2014 |
Descrizione fisica | 1 online resource (571 p.) |
Disciplina | 547.05381 |
Soggetto topico |
Cyclic compounds
Lithium compounds Organic compounds - Synthesis |
ISBN |
3-527-66753-9
3-527-66751-2 3-527-66754-7 |
Formato | Materiale a stampa ![]() |
Livello bibliografico | Monografia |
Lingua di pubblicazione | ger |
Nota di contenuto |
Lithium Compounds in Organic Synthesis; Contents; List of Contributors; Foreword; Preface; Part I New Structural Aspects of Lithium Compounds; Chapter 1 Structure-Reactivity Relationship in Organolithium Compounds; 1.1 Structural Principles in Organolithium Compounds; 1.2 Donor-Base-Free Structures; 1.2.1 Tetramers; 1.2.2 Hexamers; 1.2.3 Comparison of [Me3SiCH2Li]6 and [n-BuLi]6; 1.3 Disaggregation with Lewis Bases; 1.3.1 Tetramers of Alkyllithium Compounds; 1.3.2 Asymmetric Aggregates of [Me3SiCH2Li] (4); 1.3.3 An Octameric Aggregate of [Me3SiCH2Li]6
1.4 Donor-Base-Induced Dimers and Monomers1.4.1 Alkyllithium and Trimethylsilylmethyllithium Compounds; 1.4.2 PMDETA Aggregated Monomers; 1.5 Heterobimetallic Organolithium Compounds; 1.6 Conclusion and Outlook; References; Further Reading; Chapter 2 Computational Perspectives on Organolithiums; 2.1 Introduction; 2.2 The Nature of Bonds to Lithium; 2.3 Aggregation of Lithium Organic Compounds; 2.4 Solvation Effects; 2.5 Lithium Alkoxides and Lithium Amides; 2.6 Computational Studies on Various Organolithium Applications; 2.7 Conclusion and Outlook; References; Further Reading Chapter 3 Spectroscopic Advances in Organolithium Reactivity: The Contribution of Rapid-Injection NMR (RINMR)3.1 Introduction; 3.2 The Curtin-Hammett Principle; 3.3 Organolithium NMR; 3.4 Features of RINMR; 3.4.1 Brief History; 3.4.2 Apparatus Descriptions and Rapidity of Acquisition; 3.4.3 Temperature Range and Control; 3.4.4 Volume Accuracy of Injection; 3.5 Use of RINMR to Study Organometallic Reactions; 3.5.1 n-Butyllithium Aggregate Reactivity (1985); 3.5.2 Magnesium Chelates in Carbonyl Additions (1987/1990); 3.5.3 Lithium Enolate Aldol (1992) 3.5.4 Alkyllithium Polymerization (1995/1999)3.5.5 Tin Transmetallation (2007); 3.5.6 Cuprates (2002-Present); 3.5.7 n-BuLi Aggregate Reactivity Revisited (2007); 3.5.8 Tris(trimethylsilyl)methyllithium (2008/2009); 3.5.9 Enolization and Lithium Aldol (2011); 3.6 Conclusion and Outlook; References; Further Reading; Chapter 4 Spectroscopic Advances in Structural Lithium Chemistry: Diffusion-Ordered Spectroscopy and Solid-State NMR; 4.1 General Introduction; 4.2 Application of Solution NMR to the Structural Characterization of Organolithium Compounds; 4.2.1 Diffusion NMR Measurement Methods 4.2.1.1 Pulsed Field Gradient Spin Echo (PFGSE)4.2.1.2 From the First to the Second Dimension: DOSY NMR Experiment; 4.2.2 DOSY Application to the Structural Analysis of Organolithium Compounds; 4.2.2.1 Structure of the Mixed Methyllithium/Lithium Chloride Aggregate; 4.2.2.2 Structure of a Lithium Phosphido-Borane; 4.2.2.3 Structure of Lithium Zincate; 4.2.3 Conclusion; 4.3 Solid-State NMR; 4.3.1 Basic Principles; 4.3.1.1 Homo and Heteronuclear Dipole-Dipole Couplings (D: Dipole-Dipole); 4.3.1.2 Chemical Shift Anisotropy (CSA); 4.3.1.3 Quadrupolar Interactions for Nuclei with I< 1/2 (Q) 4.3.1.4 Magic Angle Spinning (MAS) |
Record Nr. | UNINA-9910825598203321 |
Weinheim, Germany : , : Wiley-VCH Verlag, , 2014 | ||
![]() | ||
Lo trovi qui: Univ. Federico II | ||
|
Lithium iron phosphate : a promising cathode-active material for lithium secondary batteries / / Gouri Cheruvally |
Autore | Cheruvally Gouri |
Pubbl/distr/stampa | Stafa-Zuerich ; ; Enfield, New Hampshire : , : Trans Tech Publications Limited, , [2008] |
Descrizione fisica | 1 online resource (142 p.) |
Collana | Materials science foundations |
Soggetto topico |
Lithium cells - Research
Lithium compounds |
Soggetto genere / forma | Electronic books. |
ISBN | 3-03813-240-3 |
Formato | Materiale a stampa ![]() |
Livello bibliografico | Monografia |
Lingua di pubblicazione | eng |
Nota di contenuto |
Lithium Iron Phosphate: A Promising Cathode-Active Material for Lithium Secondary Batteries; Dedication; Author; Preface; Table of Contents; Abbreviations; Table of Contents; 1. Introduction; 2. Characteristics of LiFePO4 as a Cathode-Active Material; 3. Synthesis of LiFePO4: Different Methods; 4. Synthesis of LiFePO4/C; 5. Influence of Synthesis Parameters on the Properties of LiFePO4 and LiFePO4/C; 6. Metal Ion-Doped LiFePO4: Synthesis and Properties; 7. LiFePO4-Based Cathode: Influence of Different Parameters on Properties
8. Lithium Cells with LiFePO4 Cathode: Influence of Cell Components and Operating Temperature9. Safety and Storage of Lithium Batteries with LiFePO4 Cathodes; 10. Theoretical and Modeling Studies on LiFePO4; 11. Phosphate Olivines as Cathode-Active Materials; 12. An Overview; References; Authors Index |
Record Nr. | UNINA-9910465321603321 |
Cheruvally Gouri
![]() |
||
Stafa-Zuerich ; ; Enfield, New Hampshire : , : Trans Tech Publications Limited, , [2008] | ||
![]() | ||
Lo trovi qui: Univ. Federico II | ||
|
Lithium iron phosphate : a promising cathode-active material for lithium secondary batteries / / Gouri Cheruvally |
Autore | Cheruvally Gouri |
Pubbl/distr/stampa | Stafa-Zuerich ; ; Enfield, New Hampshire : , : Trans Tech Publications Limited, , [2008] |
Descrizione fisica | 1 online resource (142 p.) |
Collana | Materials science foundations |
Soggetto topico |
Lithium cells - Research
Lithium compounds |
ISBN | 3-03813-240-3 |
Formato | Materiale a stampa ![]() |
Livello bibliografico | Monografia |
Lingua di pubblicazione | eng |
Nota di contenuto |
Lithium Iron Phosphate: A Promising Cathode-Active Material for Lithium Secondary Batteries; Dedication; Author; Preface; Table of Contents; Abbreviations; Table of Contents; 1. Introduction; 2. Characteristics of LiFePO4 as a Cathode-Active Material; 3. Synthesis of LiFePO4: Different Methods; 4. Synthesis of LiFePO4/C; 5. Influence of Synthesis Parameters on the Properties of LiFePO4 and LiFePO4/C; 6. Metal Ion-Doped LiFePO4: Synthesis and Properties; 7. LiFePO4-Based Cathode: Influence of Different Parameters on Properties
8. Lithium Cells with LiFePO4 Cathode: Influence of Cell Components and Operating Temperature9. Safety and Storage of Lithium Batteries with LiFePO4 Cathodes; 10. Theoretical and Modeling Studies on LiFePO4; 11. Phosphate Olivines as Cathode-Active Materials; 12. An Overview; References; Authors Index |
Record Nr. | UNINA-9910786508703321 |
Cheruvally Gouri
![]() |
||
Stafa-Zuerich ; ; Enfield, New Hampshire : , : Trans Tech Publications Limited, , [2008] | ||
![]() | ||
Lo trovi qui: Univ. Federico II | ||
|
Lithium iron phosphate : a promising cathode-active material for lithium secondary batteries / / Gouri Cheruvally |
Autore | Cheruvally Gouri |
Pubbl/distr/stampa | Stafa-Zuerich ; ; Enfield, New Hampshire : , : Trans Tech Publications Limited, , [2008] |
Descrizione fisica | 1 online resource (142 p.) |
Collana | Materials science foundations |
Soggetto topico |
Lithium cells - Research
Lithium compounds |
ISBN | 3-03813-240-3 |
Formato | Materiale a stampa ![]() |
Livello bibliografico | Monografia |
Lingua di pubblicazione | eng |
Nota di contenuto |
Lithium Iron Phosphate: A Promising Cathode-Active Material for Lithium Secondary Batteries; Dedication; Author; Preface; Table of Contents; Abbreviations; Table of Contents; 1. Introduction; 2. Characteristics of LiFePO4 as a Cathode-Active Material; 3. Synthesis of LiFePO4: Different Methods; 4. Synthesis of LiFePO4/C; 5. Influence of Synthesis Parameters on the Properties of LiFePO4 and LiFePO4/C; 6. Metal Ion-Doped LiFePO4: Synthesis and Properties; 7. LiFePO4-Based Cathode: Influence of Different Parameters on Properties
8. Lithium Cells with LiFePO4 Cathode: Influence of Cell Components and Operating Temperature9. Safety and Storage of Lithium Batteries with LiFePO4 Cathodes; 10. Theoretical and Modeling Studies on LiFePO4; 11. Phosphate Olivines as Cathode-Active Materials; 12. An Overview; References; Authors Index |
Record Nr. | UNINA-9910822575303321 |
Cheruvally Gouri
![]() |
||
Stafa-Zuerich ; ; Enfield, New Hampshire : , : Trans Tech Publications Limited, , [2008] | ||
![]() | ||
Lo trovi qui: Univ. Federico II | ||
|