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Asymmetric heterogeneous supported catalysis [[electronic resource] ] : use of nitrogen-containing ligands / / Christine Saluzzo and Stephane Guillarme
| Asymmetric heterogeneous supported catalysis [[electronic resource] ] : use of nitrogen-containing ligands / / Christine Saluzzo and Stephane Guillarme |
| Autore | Saluzzo Christine |
| Pubbl/distr/stampa | New York, : Nova Science Publishers, c2011 |
| Descrizione fisica | 1 online resource (185 p.) |
| Disciplina | 541/.395 |
| Altri autori (Persone) | GuillarmeStéphane |
| Collana | Polymer science and technology |
| Soggetto topico |
Asymmetric synthesis
Enantioselective catalysis Ligands Nitrogen compounds |
| Soggetto genere / forma | Electronic books. |
| ISBN | 1-61728-101-8 |
| Formato | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNINA-9910462369503321 |
Saluzzo Christine
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| New York, : Nova Science Publishers, c2011 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Asymmetric heterogeneous supported catalysis [[electronic resource] ] : use of nitrogen-containing ligands / / Christine Saluzzo and Stephane Guillarme
| Asymmetric heterogeneous supported catalysis [[electronic resource] ] : use of nitrogen-containing ligands / / Christine Saluzzo and Stephane Guillarme |
| Autore | Saluzzo Christine |
| Pubbl/distr/stampa | New York, : Nova Science Publishers, c2011 |
| Descrizione fisica | 1 online resource (185 p.) |
| Disciplina | 541/.395 |
| Altri autori (Persone) | GuillarmeStéphane |
| Collana | Polymer science and technology |
| Soggetto topico |
Asymmetric synthesis
Enantioselective catalysis Ligands Nitrogen compounds |
| ISBN | 1-61728-101-8 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNINA-9910786822703321 |
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Saluzzo Christine
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| New York, : Nova Science Publishers, c2011 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Asymmetric heterogeneous supported catalysis [[electronic resource] ] : use of nitrogen-containing ligands / / Christine Saluzzo and Stephane Guillarme
| Asymmetric heterogeneous supported catalysis [[electronic resource] ] : use of nitrogen-containing ligands / / Christine Saluzzo and Stephane Guillarme |
| Autore | Saluzzo Christine |
| Edizione | [1st ed.] |
| Pubbl/distr/stampa | New York, : Nova Science Publishers, c2011 |
| Descrizione fisica | 1 online resource (185 p.) |
| Disciplina | 541/.395 |
| Altri autori (Persone) | GuillarmeStéphane |
| Collana | Polymer science and technology |
| Soggetto topico |
Asymmetric synthesis
Enantioselective catalysis Ligands Nitrogen compounds |
| ISBN | 1-61728-101-8 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Intro -- ASYMMETRIC HETEROGENEOUS SUPPORTED CATALYSIS: USE OF NITROGEN-CONTAINING LIGANDS -- Library of Congress Cataloging-in-Publication Data -- Contents -- Preface -- Chapter 1: Introduction -- Chapter 2: Reduction of C=O and C=N Bond -- 2.1. Hydrogenation -- 2.2. Hydrogenation Transfer Reduction -- 2.2.1. 1,2-Diamine and Derivatives -- 2.2.2. Imprinting Technique for Hydrogen Transfer Reduction with 1,2-Diamines -- 2.2.3. Aminoalcohol as Ligand -- 2.2.4. Dialdimine Ligand as Ligand -- 2.3. Enantioselective Hydride Reduction -- 2.4. Hydrosilylation with Ligands as Pendent Group -- 2.5. Reduction of C=N bond -- Chapter 3: Cyclopropanation -- 3.1. Oxazolines Ligands -- 3.1.1. Insoluble Supported-Polymer Box a Ligands -- 3.1.2. Insoluble Supported-Polymer AzaBOX as Ligands -- 3.1.3. Insoluble Supported-Polymer PyBox as Ligands -- 3.1.4. Immobilization of PyBox on Natural Polymers -- 3.1.5. Soluble Supported-Polymer Box as Ligands -- 3.1.6. Soluble Supported-Polymer AzaBox as Ligands -- 3.2. Porphyrins -- 3.3. Miscellaneous -- Chapter 4: Cycloadditions and Heterocycloadditions -- 4.1. Supported Box Ligands -- 4.2. Supported Aminoalcohol and N-Sulfonylamino Acid-Derived Oxazaborolidine or Oxazaborolidinone -- 4.3. Supported Salen as Ligand -- Chapter 5: Addition of Organometallic Reagents to Aldehydes, Ketones and Imines -- 5.1. Supported Aminoalcohols as Ligands -- 5.2. Supported Sulfonamide -- and N-Sulfonylated Aminoalcohols -- 5.3. Supported Oxazoline -- or Oxazolidine as Ligands -- 5.4. Supported Salen as Chiral Ligands -- Chapter 6: Asymmetric (-Allylic Substitution -- Chapter 7: Dihydroxylation and Aminohydroxylation -- 7.1. Insoluble Supported Alkaloid as Ligand -- 7.2. Soluble Supported Alkaloid as Ligand -- Chapter 8: Epoxidation -- 8.1. Supported Salen as Ligand -- 8.2. Porphyrins -- 8.3. Soluble Polymers.
Chapter 9: Kinetic Resolution of Terminal Epoxides -- Chapter 10: Miscellaneous -- Chapter 11: Conclusion -- References -- Index. |
| Record Nr. | UNINA-9910806234203321 |
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Saluzzo Christine
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| New York, : Nova Science Publishers, c2011 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Ferrocenes [[electronic resource] ] : ligands, materials and biomolecules / / editor, Petr Štěpnička
| Ferrocenes [[electronic resource] ] : ligands, materials and biomolecules / / editor, Petr Štěpnička |
| Pubbl/distr/stampa | Chichester, England ; ; Hoboken, NJ, : J.Wiley, c2008 |
| Descrizione fisica | 1 online resource (669 p.) |
| Disciplina |
547
547.05621 547/.05621 |
| Altri autori (Persone) | ŠtěpničkaPetr |
| Soggetto topico |
Ferrocene
Ligands Biomolecules |
| ISBN |
1-281-31984-8
9786611319847 0-470-98566-6 0-470-98565-8 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Ferrocenes; Contents; Preface; Contributors; PART I FERROCENE LIGANDS; 1 Monodentate Ferrocene Donor Ligands; 2 The Coordination and Homogeneous Catalytic Chemistry of 1,1 -Bis(diphenylphosphino)ferrocene and its Chalcogenide Derivatives; 3 Synthesis, Coordination Chemistry and Catalytic Use of dppf Analogs; 4 Other Symmetric 1,1 -Bidentate Ferrocene Ligands; 5 1 -Functionalised Ferrocene Phosphines: Synthesis, Coordination Chemistry and Catalytic Applications; 6 Chiral 1,2-Disubstituted Ferrocene Diphosphines for Asymmetric Catalysis
7 Synthesis and Catalytic Use of Planar Chiral and Polydentate Ferrocene DonorsPART II MATERIALS, MOLECULAR DEVICES AND BIOMOLECULES; 8 Ferrocene Sensors; 9 Ferrocene-Based Electro-Optical Materials; 10 Ferrocene-Containing Polymers and Dendrimers; 11 Ferrocene-Containing Thermotropic Liquid Crystals; 12 Crystal Engineering with Ferrocene Compounds; 13 The Bioorganometallic Chemistry of Ferrocene; Index |
| Record Nr. | UNINA-9910145421803321 |
| Chichester, England ; ; Hoboken, NJ, : J.Wiley, c2008 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Ferrocenes : ligands, materials and biomolecules / / editor, Petr Stepnicka
| Ferrocenes : ligands, materials and biomolecules / / editor, Petr Stepnicka |
| Edizione | [1st ed.] |
| Pubbl/distr/stampa | Chichester, England ; ; Hoboken, NJ, : J.Wiley, c2008 |
| Descrizione fisica | 1 online resource (669 p.) |
| Disciplina |
547
547.05621 547/.05621 |
| Altri autori (Persone) | StepnickaPetr |
| Soggetto topico |
Ferrocene
Ligands Biomolecules |
| ISBN |
1-281-31984-8
9786611319847 0-470-98566-6 0-470-98565-8 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Ferrocenes; Contents; Preface; Contributors; PART I FERROCENE LIGANDS; 1 Monodentate Ferrocene Donor Ligands; 2 The Coordination and Homogeneous Catalytic Chemistry of 1,1 -Bis(diphenylphosphino)ferrocene and its Chalcogenide Derivatives; 3 Synthesis, Coordination Chemistry and Catalytic Use of dppf Analogs; 4 Other Symmetric 1,1 -Bidentate Ferrocene Ligands; 5 1 -Functionalised Ferrocene Phosphines: Synthesis, Coordination Chemistry and Catalytic Applications; 6 Chiral 1,2-Disubstituted Ferrocene Diphosphines for Asymmetric Catalysis
7 Synthesis and Catalytic Use of Planar Chiral and Polydentate Ferrocene DonorsPART II MATERIALS, MOLECULAR DEVICES AND BIOMOLECULES; 8 Ferrocene Sensors; 9 Ferrocene-Based Electro-Optical Materials; 10 Ferrocene-Containing Polymers and Dendrimers; 11 Ferrocene-Containing Thermotropic Liquid Crystals; 12 Crystal Engineering with Ferrocene Compounds; 13 The Bioorganometallic Chemistry of Ferrocene; Index |
| Record Nr. | UNINA-9910821787503321 |
| Chichester, England ; ; Hoboken, NJ, : J.Wiley, c2008 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Functionalised N-heterocyclic carbene complexes / / Olaf Kuhl
| Functionalised N-heterocyclic carbene complexes / / Olaf Kuhl |
| Autore | Kuhl Olaf |
| Pubbl/distr/stampa | Chichester, West Sussex, : Wiley, 2010 |
| Descrizione fisica | 1 online resource (365 p.) |
| Disciplina | 541/.2242 |
| Soggetto topico |
Ligands
Heterocyclic compounds Transition metal complexes |
| ISBN |
1-282-48220-3
9786612482205 0-470-68583-2 0-470-68584-0 |
| Classificazione |
CHE 330f
CHE 612f CHE 670f |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Cover; Contents; Abbreviations; Introduction; Chapter 1 The Nature of N-Heterocyclic Carbenes; 1.1 Synthesis; 1.1.1 Synthesis of the Imidazolium Salts; 1.1.2 Closing the Ring; 1.1.3 Synthesis of the Free Carbenes; 1.1.4 Synthesis of Transition Metal Complexes of NHC; 1.2 Properties of NHC; 1.2.1 The Internal Electronic Structure; 1.2.2 Basicity of NHC; 1.2.3 Steric Properties; 1.2.4 The Carbene-Metal Bond; 1.2.5 Decomposition Pathways; References; Chapter 2 Why Functionalisation?; 2.1 Phosphane Mimic; 2.2 Hemilability; 2.3 Chirality; 2.3.1 Planar Chirality; 2.3.2 Axial Chirality
2.4 Ligand Geometry2.5 Catalysis; 2.5.1 Allylic Alkylation; 2.5.2 Coupling Reactions; 2.5.3 Olefin Metathesis; 2.5.4 Polymerisations; 2.5.5 Organocatalysis; References; Chapter 3 N-Heterocyclic Carbenes with Neutral Tethers; 3.1 Amine Functionalities; 3.1.1 Heteroaromatic Functional Groups; 3.1.2 Oxazolines; 3.1.3 Imino Functional Groups; 3.1.4 Amino Functionalised NHC; 3.2 Oxygen-Containing Groups; 3.3 Phosphane Functionalities; 3.4 Bis-Carbene Ligands; 3.5 Tris-N-Heterocyclic Carbene Ligands; 3.6 Pincer Carbenes; References; Chapter 4 N-Heterocyclic Carbenes with Anionic Functional Groups 4.1 Oxygen-Containing Groups4.2 Nitrogen-Containing Groups; 4.3 NHC Ligands Incorporating Cp Moieties; 4.4 Transition Metal NHC Complexes Involved in the Activation of C-H Bonds; 4.5 Immobilisation of the Catalyst; 4.6 Sulfur-Containing Functional Groups; References; Chapter 5 Chiral N-Heterocyclic Carbenes; References; Chapter 6 Natural Products; 6.1 Thiazole; 6.1.1 Isolation and Stability of Thiazolylidene; 6.1.2 Benzothiazoles; 6.1.3 Metal Complexes; 6.2 Amino Acids; 6.3 Purines and Xanthines; 6.4 Carbohydrates; 6.5 Miscellaneous; References; Index; A; B; C; D; E; F; G; H; I; J; K; L; M; N OP; Q; R; S; T; U; V; W; X; Z |
| Record Nr. | UNINA-9910877181203321 |
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Kuhl Olaf
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| Chichester, West Sussex, : Wiley, 2010 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Functionalised N-heterocyclic carbene complexes [[electronic resource] /] / Olaf Kühl
| Functionalised N-heterocyclic carbene complexes [[electronic resource] /] / Olaf Kühl |
| Autore | Kühl Olaf |
| Pubbl/distr/stampa | Chichester, West Sussex, : Wiley, 2010 |
| Descrizione fisica | 1 online resource (365 p.) |
| Disciplina |
541.2242
547.05 |
| Soggetto topico |
Ligands
Heterocyclic compounds Transition metal complexes |
| ISBN |
1-282-48220-3
9786612482205 0-470-68583-2 0-470-68584-0 |
| Classificazione |
CHE 330f
CHE 612f CHE 670f |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Cover; Contents; Abbreviations; Introduction; Chapter 1 The Nature of N-Heterocyclic Carbenes; 1.1 Synthesis; 1.1.1 Synthesis of the Imidazolium Salts; 1.1.2 Closing the Ring; 1.1.3 Synthesis of the Free Carbenes; 1.1.4 Synthesis of Transition Metal Complexes of NHC; 1.2 Properties of NHC; 1.2.1 The Internal Electronic Structure; 1.2.2 Basicity of NHC; 1.2.3 Steric Properties; 1.2.4 The Carbene-Metal Bond; 1.2.5 Decomposition Pathways; References; Chapter 2 Why Functionalisation?; 2.1 Phosphane Mimic; 2.2 Hemilability; 2.3 Chirality; 2.3.1 Planar Chirality; 2.3.2 Axial Chirality
2.4 Ligand Geometry2.5 Catalysis; 2.5.1 Allylic Alkylation; 2.5.2 Coupling Reactions; 2.5.3 Olefin Metathesis; 2.5.4 Polymerisations; 2.5.5 Organocatalysis; References; Chapter 3 N-Heterocyclic Carbenes with Neutral Tethers; 3.1 Amine Functionalities; 3.1.1 Heteroaromatic Functional Groups; 3.1.2 Oxazolines; 3.1.3 Imino Functional Groups; 3.1.4 Amino Functionalised NHC; 3.2 Oxygen-Containing Groups; 3.3 Phosphane Functionalities; 3.4 Bis-Carbene Ligands; 3.5 Tris-N-Heterocyclic Carbene Ligands; 3.6 Pincer Carbenes; References; Chapter 4 N-Heterocyclic Carbenes with Anionic Functional Groups 4.1 Oxygen-Containing Groups4.2 Nitrogen-Containing Groups; 4.3 NHC Ligands Incorporating Cp Moieties; 4.4 Transition Metal NHC Complexes Involved in the Activation of C-H Bonds; 4.5 Immobilisation of the Catalyst; 4.6 Sulfur-Containing Functional Groups; References; Chapter 5 Chiral N-Heterocyclic Carbenes; References; Chapter 6 Natural Products; 6.1 Thiazole; 6.1.1 Isolation and Stability of Thiazolylidene; 6.1.2 Benzothiazoles; 6.1.3 Metal Complexes; 6.2 Amino Acids; 6.3 Purines and Xanthines; 6.4 Carbohydrates; 6.5 Miscellaneous; References; Index; A; B; C; D; E; F; G; H; I; J; K; L; M; N OP; Q; R; S; T; U; V; W; X; Z |
| Record Nr. | UNINA-9910139504603321 |
|
Kühl Olaf
|
||
| Chichester, West Sussex, : Wiley, 2010 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Functionalised N-heterocyclic carbene complexes [[electronic resource] /] / Olaf Kühl
| Functionalised N-heterocyclic carbene complexes [[electronic resource] /] / Olaf Kühl |
| Autore | Kühl Olaf |
| Pubbl/distr/stampa | Chichester, West Sussex, : Wiley, 2010 |
| Descrizione fisica | 1 online resource (365 p.) |
| Disciplina |
541.2242
547.05 |
| Soggetto topico |
Ligands
Heterocyclic compounds Transition metal complexes |
| ISBN |
1-282-48220-3
9786612482205 0-470-68583-2 0-470-68584-0 |
| Classificazione |
CHE 330f
CHE 612f CHE 670f |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Cover; Contents; Abbreviations; Introduction; Chapter 1 The Nature of N-Heterocyclic Carbenes; 1.1 Synthesis; 1.1.1 Synthesis of the Imidazolium Salts; 1.1.2 Closing the Ring; 1.1.3 Synthesis of the Free Carbenes; 1.1.4 Synthesis of Transition Metal Complexes of NHC; 1.2 Properties of NHC; 1.2.1 The Internal Electronic Structure; 1.2.2 Basicity of NHC; 1.2.3 Steric Properties; 1.2.4 The Carbene-Metal Bond; 1.2.5 Decomposition Pathways; References; Chapter 2 Why Functionalisation?; 2.1 Phosphane Mimic; 2.2 Hemilability; 2.3 Chirality; 2.3.1 Planar Chirality; 2.3.2 Axial Chirality
2.4 Ligand Geometry2.5 Catalysis; 2.5.1 Allylic Alkylation; 2.5.2 Coupling Reactions; 2.5.3 Olefin Metathesis; 2.5.4 Polymerisations; 2.5.5 Organocatalysis; References; Chapter 3 N-Heterocyclic Carbenes with Neutral Tethers; 3.1 Amine Functionalities; 3.1.1 Heteroaromatic Functional Groups; 3.1.2 Oxazolines; 3.1.3 Imino Functional Groups; 3.1.4 Amino Functionalised NHC; 3.2 Oxygen-Containing Groups; 3.3 Phosphane Functionalities; 3.4 Bis-Carbene Ligands; 3.5 Tris-N-Heterocyclic Carbene Ligands; 3.6 Pincer Carbenes; References; Chapter 4 N-Heterocyclic Carbenes with Anionic Functional Groups 4.1 Oxygen-Containing Groups4.2 Nitrogen-Containing Groups; 4.3 NHC Ligands Incorporating Cp Moieties; 4.4 Transition Metal NHC Complexes Involved in the Activation of C-H Bonds; 4.5 Immobilisation of the Catalyst; 4.6 Sulfur-Containing Functional Groups; References; Chapter 5 Chiral N-Heterocyclic Carbenes; References; Chapter 6 Natural Products; 6.1 Thiazole; 6.1.1 Isolation and Stability of Thiazolylidene; 6.1.2 Benzothiazoles; 6.1.3 Metal Complexes; 6.2 Amino Acids; 6.3 Purines and Xanthines; 6.4 Carbohydrates; 6.5 Miscellaneous; References; Index; A; B; C; D; E; F; G; H; I; J; K; L; M; N OP; Q; R; S; T; U; V; W; X; Z |
| Record Nr. | UNINA-9910830352403321 |
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Kühl Olaf
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| Chichester, West Sussex, : Wiley, 2010 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Insertion of guest molecules into a mixed ligand metal-organic framework via single-crystal-to-single-crystal guest exchange / / Lily Giri [and three others]
| Insertion of guest molecules into a mixed ligand metal-organic framework via single-crystal-to-single-crystal guest exchange / / Lily Giri [and three others] |
| Autore | Giri Lily |
| Pubbl/distr/stampa | Aberdeen Proving Ground, MD : , : Army Research Laboratory, , July 2014 |
| Descrizione fisica | 1 online resource (v, 14 pages) : illustrations |
| Collana | ARL-TR |
| Soggetto topico |
Ligands
Metal ions Molecular sieves |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNINA-9910698628003321 |
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Giri Lily
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| Aberdeen Proving Ground, MD : , : Army Research Laboratory, , July 2014 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Introduction to Coordination Chemistry [[electronic resource]]
| Introduction to Coordination Chemistry [[electronic resource]] |
| Autore | Lawrance Geoffrey A |
| Pubbl/distr/stampa | Hoboken, : Wiley, 2010 |
| Descrizione fisica | 1 online resource (306 p.) |
| Collana | Inorganic Chemistry: A Textbook Series |
| Soggetto topico |
Chemistry
Coordination Coordination compounds Ligands |
| Soggetto genere / forma | Electronic books. |
| ISBN |
1-282-46098-6
9780470519318 9786612460982 0-470-68713-4 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Introduction to Coordination Chemistry; Contents; Preface; Preamble; 1 The Central Atom; 1.1 Key Concepts in Coordination Chemistry; 1.2 A Who's Who of Metal Ions; 1.2.1 Commoners and 'Uncommoners'; 1.2.2 Redefining Commoners; 1.3 Metals in Molecules; 1.3.1 Metals in the Natural World; 1.3.2 Metals in Contrived Environments; 1.3.3 Natural or Made-to-Measure Complexes; 1.4 The Road Ahead; Concept Keys; Further Reading; 2 Ligands; 2.1 Membership: Being a Ligand; 2.1.1 What Makes a Ligand?; 2.1.2 Making Attachments - Coordination; 2.1.3 Putting the Bite on Metals - Chelation
2.1.4 Do I Look Big on That? - Chelate Ring Size2.1.5 Different Tribes - Donor Group Variation; 2.1.6 Ligands with More Bite - Denticity; 2.2 Monodentate Ligands - The Simple Type; 2.2.1 Basic Binders; 2.2.2 Amines Ain't Ammines - Ligand Families; 2.2.3 Meeting More Metals - Bridging Ligands; 2.3 Greed is Good - Polydentate Ligands; 2.3.1 The Simple Chelate; 2.3.2 More Teeth, Stronger Bite - Polydentates; 2.3.3 Many-Armed Monsters - Introducing Ligand Shape; 2.4 Polynucleating Species - Molecular Bigamists; 2.4.1 When One is Not Enough; 2.4.2 Vive la Difference - Mixed-metal Complexation 2.4.3 Supersized - Binding to Macromolecules2.5 A Separate Race - Organometallic Species; Concept Keys; Further Reading; 3 Complexes; 3.1 The Central Metal Ion; 3.2 Metal-Ligand Marriage; 3.2.1 The Coordinate Bond; 3.2.2 The Foundation of Coordination Chemistry; 3.2.3 Complex Shape - Not Just Any Which Way; 3.3 Holding On - The Nature of Bonding in Metal Complexes; 3.3.1 An Ionic Bonding Model - Introducing Crystal Field Theory; 3.3.2 A Covalent Bonding Model - Embracing Molecular Orbital Theory; 3.3.3 Ligand Field Theory - Making Compromises; 3.3.4 Bonding Models Extended 3.4 Coupling - Polymetallic Complexes3.5 Making Choices; 3.5.1 Selectivity - Of all the Molecules in all the World, Why This One?; 3.5.2 Preferences - Do You Like What I Like?; 3.5.3 Complex Lifetimes - Together, Forever?; 3.6 Complexation Consequences; Concept Keys; Further Reading; 4 Shape; 4.1 Getting in Shape; 4.2 Forms of Complex Life - Coordination Number and Shape; 4.2.1 One Coordination (ML); 4.2.2 Two Coordination (ML2); 4.2.3 Three Coordination (ML3); 4.2.4 Four Coordination (ML4); 4.2.5 Five Coordination (ML5); 4.2.6 Six Coordination (ML6) 4.2.7 Higher Coordination Numbers (ML7 to ML9)4.3 Influencing Shape; 4.3.1 Metallic Genetics - Metal Ion Influences; 4.3.2 Moulding a Relationship - Ligand Influences; 4.3.3 Chameleon Complexes; 4.4 Isomerism - Real 3D Effects; 4.4.1 Introducing Stereoisomers; 4.4.2 Constitutional (Structural) Isomerism; 4.4.3 Stereoisomerism: in Place - Positional Isomers; in Space - Optical Isomers; 4.4.4 What's Best? - Isomer Preferences; 4.5 Sophisticated Shapes; 4.5.1 Compounds of Polydentate Ligands; 4.5.2 Encapsulation Compounds; 4.5.3 Host-Guest Molecular Assemblies; 4.6 Defining Shape; Concept Keys Further Reading |
| Record Nr. | UNINA-9910455102703321 |
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Lawrance Geoffrey A
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| Hoboken, : Wiley, 2010 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
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