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Chiral Lewis acids in organic synthesis / / edited by Jacek Mlynarski
| Chiral Lewis acids in organic synthesis / / edited by Jacek Mlynarski |
| Pubbl/distr/stampa | Weinheim, Germany : , : Wiley-VCH, , [2017] |
| Descrizione fisica | 1 online resource (398 pages) : illustrations |
| Soggetto topico |
Organic compounds - Synthesis
Lewis acids |
| Soggetto genere / forma | Electronic books. |
| ISBN |
1-5231-1525-4
3-527-80213-4 3-527-80215-0 3-527-80214-2 |
| Formato | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNINA-9910270916503321 |
| Weinheim, Germany : , : Wiley-VCH, , [2017] | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Chiral Lewis acids in organic synthesis / / edited by Jacek Mlynarski
| Chiral Lewis acids in organic synthesis / / edited by Jacek Mlynarski |
| Pubbl/distr/stampa | Weinheim, Germany : , : Wiley-VCH, , [2017] |
| Descrizione fisica | 1 online resource (398 pages) : illustrations |
| Soggetto topico |
Organic compounds - Synthesis
Lewis acids |
| ISBN |
1-5231-1525-4
3-527-80213-4 3-527-80215-0 3-527-80214-2 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNINA-9910830625903321 |
| Weinheim, Germany : , : Wiley-VCH, , [2017] | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Frustrated Lewis pairs / / editors, Chris Slootweg and Andrew R. Jupp
| Frustrated Lewis pairs / / editors, Chris Slootweg and Andrew R. Jupp |
| Edizione | [1st ed. 2021.] |
| Pubbl/distr/stampa | Cham, Switzerland : , : Springer, , [2021] |
| Descrizione fisica | 1 online resource (VIII, 404 p. 363 illus., 178 illus. in color.) |
| Disciplina | 541.395 |
| Collana | Molecular Catalysis |
| Soggetto topico |
Catalysis
Lewis acids |
| ISBN | 3-030-58888-2 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto | Frustrated Lewis Pair Catalysis -- Frustrated Lewis Pairs in Asymmetric Catalysis -- New Developments in Small Molecule Activation -- Metal-free C-H Activation -- Computational Insights in Frustrated Lewis Pair Chemistry -- Boranes with Reduced Lewis Acidity -- Heterogeneous Frustrated Lewis Pair Chemistry -- Frustrated Lewis Pairs in Polymer Synthesis -- Transition Metals in Frustrated Lewis Pairs -- Radical Frustrated Lewis Pair Chemistry -- Frustrated Lewis Pairs as a Pedagogical Tool. |
| Record Nr. | UNINA-9910483392103321 |
| Cham, Switzerland : , : Springer, , [2021] | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Lewis acids in organic synthesis
| Lewis acids in organic synthesis |
| Pubbl/distr/stampa | [Place of publication not identified], : Wiley VCH, 2000 |
| Disciplina | 547/.2 |
| Soggetto topico |
Organic compounds - Synthesis
Lewis acids Organic Chemistry Chemistry Physical Sciences & Mathematics |
| ISBN | 3-527-61830-9 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNINA-9910144376503321 |
| [Place of publication not identified], : Wiley VCH, 2000 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Lewis acids in organic synthesis
| Lewis acids in organic synthesis |
| Pubbl/distr/stampa | [Place of publication not identified], : Wiley VCH, 2000 |
| Disciplina | 547/.2 |
| Soggetto topico |
Organic compounds - Synthesis
Lewis acids Organic Chemistry Chemistry Physical Sciences & Mathematics |
| ISBN | 3-527-61830-9 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNINA-9910877402303321 |
| [Place of publication not identified], : Wiley VCH, 2000 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Lewis basicity and affinity scales [[electronic resource] ] : data and measurement / / Christian Laurence, Jean-Franc ʹois Gal
| Lewis basicity and affinity scales [[electronic resource] ] : data and measurement / / Christian Laurence, Jean-Franc ʹois Gal |
| Autore | Laurence Christian |
| Pubbl/distr/stampa | Chichester, : Wiley, 2010 |
| Descrizione fisica | 1 online resource (490 p.) |
| Disciplina |
541.39
541.395 546.24 |
| Altri autori (Persone) | GalJean-Franc ʹois |
| Soggetto topico |
Lewis acids
Chemistry |
| Soggetto genere / forma | Electronic books. |
| ISBN |
1-282-68724-7
9786612687242 0-470-68190-X 0-470-68189-6 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Lewis Basicity and Affinity Scales; Contents; Preface; 1 Lewis Basicity and Affinity Measurement: Definitions and Context; 1.1 The Br ̈onsted Definition of Acids and Bases; 1.2 Scales of Br ̈onsted Basicity and Affinity in Solution; 1.3 Scales of Br ̈onsted Basicity and Affinity in the Gas Phase; 1.4 The Lewis Definition of Acids and Bases; 1.5 Quantum Chemical Descriptions of Lewis Acid/Base Complexes; 1.5.1 Valence-Bond Model; 1.5.2 Perturbation Molecular Orbital Theory; 1.5.3 Variational Supermolecular Method and Energy Decomposition Schemes; 1.5.4 Natural Bond Orbital Theory
1.5.5 Quantum Theory of Atoms in Molecules1.6 Measurement of Lewis Basicity; 1.6.1 Gas-phase Reactions; 1.6.2 Solution Reactions; 1.6.3 Standard State Transformations; 1.6.4 Choice of Solvent; 1.7 Measurement of Lewis Affinity; 1.8 The Role of the Solvent; 1.9 Spectroscopic Scales of Basicity (Affinity); 1.10 Polybasic Compounds; 1.11 Attempts at a Quantitative Formulation of the Lewis Definition of Acids and Bases; 1.11.1 Hard and Soft Acids and Bases; 1.11.2 The ECW and ECT Models; 1.11.3 The Beta and Xi Equation; 1.11.4 A Chemometric Approach 1.11.5 Quantum Chemical Descriptors for Basicity Scales1.12 Concluding Remarks and Content of Chapters 2-7; References; 2 The Donor Number or SbCl5 Affinity Scale; 2.1 Structure of SbCl5 Complexes; 2.2 Definition of the Donor Number Scale; 2.3 Experimental Determination of the Donor Number; 2.4 The Donor Number Scale: Data; 2.5 Critical Discussion; References; 3 The BF3 Affinity Scale; 3.1 Structure of BF3 Complexes; 3.2 Definition of the BF3 Affinity Scale; 3.3 Experimental Determination of the BF3 Affinity Scale; 3.4 The BF3 Affinity Scale: Data; 3.5 Discussion; 3.5.1 Medium Effects 3.5.2 Hardness of BF33.5.3 Comparison of the BF3 and SbCl5 Affinity Scales; 3.5.4 Computation of the BF3 Affinity; 3.6 Conclusion; References; 4 Thermodynamic and Spectroscopic Scales of Hydrogen-Bond Basicity and Affinity; 4.1 Structure of Hydrogen-Bonded Complexes; 4.2 Hydrogen-Bond Basicity Scales: Early Works; 4.3 The 4-Fluorophenol Hydrogen-Bond Basicity Scale; 4.3.1 Definition; 4.3.2 Method of Determination; 4.3.3 Polyfunctional Hydrogen-Bond Acceptors; 4.3.4 Data; 4.3.5 Range of Validity of the Scale; 4.4 Hydrogen-Bond Affinity Scales: Early Studies 4.5 The 4-Fluorophenol Affinity Scale4.6 Comparison of 4-Fluorophenol Affinity and Basicity Scales; 4.7 Spectroscopic Scales; 4.7.1 Infrared Shift of Methanol; 4.7.2 Solvatochromic Shifts of 4-Nitrophenol and 4-Nitroaniline; 4.8 Conclusion; References; 5 Thermodynamic and Spectroscopic Scales of Halogen-Bond Basicity and Affinity; 5.1 Structure of Halogen-Bonded Complexes; 5.2 The Diiodine Basicity Scale; 5.2.1 Definition of the Scale; 5.2.2 Methods for the Determination of Diiodine Complexation Constants; 5.2.3 Temperature Correction; 5.2.4 Solvent Effects; 5.2.5 Data 5.3 Is the Diiodine Basicity Scale a General Halogen-Bond Basicity Scale? |
| Record Nr. | UNINA-9910139364503321 |
Laurence Christian
|
||
| Chichester, : Wiley, 2010 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Lewis basicity and affinity scales [[electronic resource] ] : data and measurement / / Christian Laurence, Jean-Franc ʹois Gal
| Lewis basicity and affinity scales [[electronic resource] ] : data and measurement / / Christian Laurence, Jean-Franc ʹois Gal |
| Autore | Laurence Christian |
| Pubbl/distr/stampa | Chichester, : Wiley, 2010 |
| Descrizione fisica | 1 online resource (490 p.) |
| Disciplina |
541.39
541.395 546.24 |
| Altri autori (Persone) | GalJean-Franc ʹois |
| Soggetto topico |
Lewis acids
Chemistry |
| ISBN |
1-282-68724-7
9786612687242 0-470-68190-X 0-470-68189-6 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Lewis Basicity and Affinity Scales; Contents; Preface; 1 Lewis Basicity and Affinity Measurement: Definitions and Context; 1.1 The Br ̈onsted Definition of Acids and Bases; 1.2 Scales of Br ̈onsted Basicity and Affinity in Solution; 1.3 Scales of Br ̈onsted Basicity and Affinity in the Gas Phase; 1.4 The Lewis Definition of Acids and Bases; 1.5 Quantum Chemical Descriptions of Lewis Acid/Base Complexes; 1.5.1 Valence-Bond Model; 1.5.2 Perturbation Molecular Orbital Theory; 1.5.3 Variational Supermolecular Method and Energy Decomposition Schemes; 1.5.4 Natural Bond Orbital Theory
1.5.5 Quantum Theory of Atoms in Molecules1.6 Measurement of Lewis Basicity; 1.6.1 Gas-phase Reactions; 1.6.2 Solution Reactions; 1.6.3 Standard State Transformations; 1.6.4 Choice of Solvent; 1.7 Measurement of Lewis Affinity; 1.8 The Role of the Solvent; 1.9 Spectroscopic Scales of Basicity (Affinity); 1.10 Polybasic Compounds; 1.11 Attempts at a Quantitative Formulation of the Lewis Definition of Acids and Bases; 1.11.1 Hard and Soft Acids and Bases; 1.11.2 The ECW and ECT Models; 1.11.3 The Beta and Xi Equation; 1.11.4 A Chemometric Approach 1.11.5 Quantum Chemical Descriptors for Basicity Scales1.12 Concluding Remarks and Content of Chapters 2-7; References; 2 The Donor Number or SbCl5 Affinity Scale; 2.1 Structure of SbCl5 Complexes; 2.2 Definition of the Donor Number Scale; 2.3 Experimental Determination of the Donor Number; 2.4 The Donor Number Scale: Data; 2.5 Critical Discussion; References; 3 The BF3 Affinity Scale; 3.1 Structure of BF3 Complexes; 3.2 Definition of the BF3 Affinity Scale; 3.3 Experimental Determination of the BF3 Affinity Scale; 3.4 The BF3 Affinity Scale: Data; 3.5 Discussion; 3.5.1 Medium Effects 3.5.2 Hardness of BF33.5.3 Comparison of the BF3 and SbCl5 Affinity Scales; 3.5.4 Computation of the BF3 Affinity; 3.6 Conclusion; References; 4 Thermodynamic and Spectroscopic Scales of Hydrogen-Bond Basicity and Affinity; 4.1 Structure of Hydrogen-Bonded Complexes; 4.2 Hydrogen-Bond Basicity Scales: Early Works; 4.3 The 4-Fluorophenol Hydrogen-Bond Basicity Scale; 4.3.1 Definition; 4.3.2 Method of Determination; 4.3.3 Polyfunctional Hydrogen-Bond Acceptors; 4.3.4 Data; 4.3.5 Range of Validity of the Scale; 4.4 Hydrogen-Bond Affinity Scales: Early Studies 4.5 The 4-Fluorophenol Affinity Scale4.6 Comparison of 4-Fluorophenol Affinity and Basicity Scales; 4.7 Spectroscopic Scales; 4.7.1 Infrared Shift of Methanol; 4.7.2 Solvatochromic Shifts of 4-Nitrophenol and 4-Nitroaniline; 4.8 Conclusion; References; 5 Thermodynamic and Spectroscopic Scales of Halogen-Bond Basicity and Affinity; 5.1 Structure of Halogen-Bonded Complexes; 5.2 The Diiodine Basicity Scale; 5.2.1 Definition of the Scale; 5.2.2 Methods for the Determination of Diiodine Complexation Constants; 5.2.3 Temperature Correction; 5.2.4 Solvent Effects; 5.2.5 Data 5.3 Is the Diiodine Basicity Scale a General Halogen-Bond Basicity Scale? |
| Record Nr. | UNINA-9910830530703321 |
|
Laurence Christian
|
||
| Chichester, : Wiley, 2010 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Lewis basicity and affinity scales : data and measurement / / Christian Laurence, Jean-Franc ois Gal
| Lewis basicity and affinity scales : data and measurement / / Christian Laurence, Jean-Franc ois Gal |
| Autore | Laurence Christian |
| Pubbl/distr/stampa | Chichester, : Wiley, 2010 |
| Descrizione fisica | 1 online resource (490 p.) |
| Disciplina |
541.39
541.395 546.24 |
| Altri autori (Persone) | GalJean-Franc ois |
| Soggetto topico |
Lewis acids
Chemistry |
| ISBN |
1-282-68724-7
9786612687242 0-470-68190-X 0-470-68189-6 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Lewis Basicity and Affinity Scales; Contents; Preface; 1 Lewis Basicity and Affinity Measurement: Definitions and Context; 1.1 The Br ̈onsted Definition of Acids and Bases; 1.2 Scales of Br ̈onsted Basicity and Affinity in Solution; 1.3 Scales of Br ̈onsted Basicity and Affinity in the Gas Phase; 1.4 The Lewis Definition of Acids and Bases; 1.5 Quantum Chemical Descriptions of Lewis Acid/Base Complexes; 1.5.1 Valence-Bond Model; 1.5.2 Perturbation Molecular Orbital Theory; 1.5.3 Variational Supermolecular Method and Energy Decomposition Schemes; 1.5.4 Natural Bond Orbital Theory
1.5.5 Quantum Theory of Atoms in Molecules1.6 Measurement of Lewis Basicity; 1.6.1 Gas-phase Reactions; 1.6.2 Solution Reactions; 1.6.3 Standard State Transformations; 1.6.4 Choice of Solvent; 1.7 Measurement of Lewis Affinity; 1.8 The Role of the Solvent; 1.9 Spectroscopic Scales of Basicity (Affinity); 1.10 Polybasic Compounds; 1.11 Attempts at a Quantitative Formulation of the Lewis Definition of Acids and Bases; 1.11.1 Hard and Soft Acids and Bases; 1.11.2 The ECW and ECT Models; 1.11.3 The Beta and Xi Equation; 1.11.4 A Chemometric Approach 1.11.5 Quantum Chemical Descriptors for Basicity Scales1.12 Concluding Remarks and Content of Chapters 2-7; References; 2 The Donor Number or SbCl5 Affinity Scale; 2.1 Structure of SbCl5 Complexes; 2.2 Definition of the Donor Number Scale; 2.3 Experimental Determination of the Donor Number; 2.4 The Donor Number Scale: Data; 2.5 Critical Discussion; References; 3 The BF3 Affinity Scale; 3.1 Structure of BF3 Complexes; 3.2 Definition of the BF3 Affinity Scale; 3.3 Experimental Determination of the BF3 Affinity Scale; 3.4 The BF3 Affinity Scale: Data; 3.5 Discussion; 3.5.1 Medium Effects 3.5.2 Hardness of BF33.5.3 Comparison of the BF3 and SbCl5 Affinity Scales; 3.5.4 Computation of the BF3 Affinity; 3.6 Conclusion; References; 4 Thermodynamic and Spectroscopic Scales of Hydrogen-Bond Basicity and Affinity; 4.1 Structure of Hydrogen-Bonded Complexes; 4.2 Hydrogen-Bond Basicity Scales: Early Works; 4.3 The 4-Fluorophenol Hydrogen-Bond Basicity Scale; 4.3.1 Definition; 4.3.2 Method of Determination; 4.3.3 Polyfunctional Hydrogen-Bond Acceptors; 4.3.4 Data; 4.3.5 Range of Validity of the Scale; 4.4 Hydrogen-Bond Affinity Scales: Early Studies 4.5 The 4-Fluorophenol Affinity Scale4.6 Comparison of 4-Fluorophenol Affinity and Basicity Scales; 4.7 Spectroscopic Scales; 4.7.1 Infrared Shift of Methanol; 4.7.2 Solvatochromic Shifts of 4-Nitrophenol and 4-Nitroaniline; 4.8 Conclusion; References; 5 Thermodynamic and Spectroscopic Scales of Halogen-Bond Basicity and Affinity; 5.1 Structure of Halogen-Bonded Complexes; 5.2 The Diiodine Basicity Scale; 5.2.1 Definition of the Scale; 5.2.2 Methods for the Determination of Diiodine Complexation Constants; 5.2.3 Temperature Correction; 5.2.4 Solvent Effects; 5.2.5 Data 5.3 Is the Diiodine Basicity Scale a General Halogen-Bond Basicity Scale? |
| Record Nr. | UNINA-9910877696703321 |
|
Laurence Christian
|
||
| Chichester, : Wiley, 2010 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
