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Characterization techniques employed to determine the energy release of reactive materials / / John J. Ritter .. [and others]
| Characterization techniques employed to determine the energy release of reactive materials / / John J. Ritter .. [and others] |
| Autore | Ritter John J |
| Pubbl/distr/stampa | Aberdeen Proving Ground, MD : , : Army Research Laboratory, , [2010] |
| Descrizione fisica | 1 online resource (vi, 26 pages) : illustrations (some color) |
| Collana | ARL-TR |
| Soggetto topico |
Intermediates (Chemistry)
Reactive polymers |
| Formato | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNINA-9910697126103321 |
Ritter John J
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| Aberdeen Proving Ground, MD : , : Army Research Laboratory, , [2010] | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
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Cyclopropane Derived Reactive Intermediates: Updates from the Chemistry of Functional Groups
| Cyclopropane Derived Reactive Intermediates: Updates from the Chemistry of Functional Groups |
| Autore | Boche Gernot |
| Pubbl/distr/stampa | [Place of publication not identified], : John Wiley & Sons Incorporated, 1990 |
| Descrizione fisica | 1 online resource (ix, 256 pages) : illustrations |
| Disciplina | 547/.512 |
| Collana | PATAI'S Chemistry of Functional Groups |
| Soggetto topico |
Cycloprane
Intermediates (Chemistry) organic compounds |
| ISBN |
0-470-77896-2
0-470-77240-9 0-470-77241-7 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto | Cyclopropyl radicals, anion radicals, and anions [with appendix] -- Cyclopropyl cations -- Cyclopropyl carbenoids -- Cyclopropane cation radicals. |
| Record Nr. | UNINA-9910830045703321 |
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Boche Gernot
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| [Place of publication not identified], : John Wiley & Sons Incorporated, 1990 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
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Cyclopropane Derived Reactive Intermediates: Updates from the Chemistry of Functional Groups
| Cyclopropane Derived Reactive Intermediates: Updates from the Chemistry of Functional Groups |
| Autore | Boche Gernot |
| Pubbl/distr/stampa | [Place of publication not identified], : John Wiley & Sons Incorporated, 1990 |
| Descrizione fisica | 1 online resource (ix, 256 pages) : illustrations |
| Disciplina | 547/.512 |
| Collana | PATAI'S Chemistry of Functional Groups |
| Soggetto topico |
Cycloprane
Intermediates (Chemistry) Organic compounds |
| ISBN |
0-470-77896-2
0-470-77240-9 0-470-77241-7 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto | Cyclopropyl radicals, anion radicals, and anions [with appendix] -- Cyclopropyl cations -- Cyclopropyl carbenoids -- Cyclopropane cation radicals. |
| Record Nr. | UNINA-9911018881703321 |
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Boche Gernot
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| [Place of publication not identified], : John Wiley & Sons Incorporated, 1990 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
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Flash chemistry [[electronic resource] ] : fast organic synthesis in microsystems / / Jun-ichi Yoshida
| Flash chemistry [[electronic resource] ] : fast organic synthesis in microsystems / / Jun-ichi Yoshida |
| Autore | Yoshida Junʼichi <1952-> |
| Pubbl/distr/stampa | Hoboken, N.J., : Wiley, 2008 |
| Descrizione fisica | 1 online resource (248 p.) |
| Disciplina |
547.2
547/.2 |
| Soggetto topico |
Organic compounds - Synthesis
Intermediates (Chemistry) Microreactors Organic reaction mechanisms |
| Soggetto genere / forma | Electronic books. |
| ISBN |
1-281-94011-9
9786611940119 0-470-72342-4 0-470-72341-6 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Flash Chemistry Fast Organic Synthesis in Microsystems; Contents; Preface; 1 Introduction; 1.1 Flask Chemistry; 1.2 Flash Chemistry; 1.3 Flask Chemistry or Flash Chemistry; References; 2 The Background to Flash Chemistry; 2.1 How do Chemical Reactions Take Place?; 2.1.1 Macroscopic View of Chemical Reactions; 2.1.2 Thermodynamic Equilibrium and Kinetics; 2.1.3 Kinetics; 2.1.4 Transition State Theory; 2.1.5 Femtosecond Chemistry and Reaction Dynamics; 2.1.6 Reactions for Dynamics and Reactions for Synthesis; 2.1.7 Bimolecular Reactions in the Gas Phase
2.1.8 Bimolecular Reactions in the Solution Phase2.1.9 Fast Chemical Synthesis Inspired by Reaction Dynamics; References; 3 What is Flash Chemistry?; 4 Why is Flash Chemistry Needed?; 4.1 Chemical Reaction, an Extremely Fast Process at Molecular Level; 4.2 Rapid Construction of Chemical Libraries; 4.3 Rapid Synthesis of Radioactive Positron Emission Tomography Probes; 4.4 On-demand Rapid Synthesis i n Industry 304.5 Conclusions; References; 5 Methods of Activating Molecules; 5.1 Thermal Activation of Organic Molecules; 5.1.1 High Temperature Reactions; 5.1.2 Flash Vacuum Pyrolysis 5.1.3 Microwave Reactions5.2 Photochemical Activation; 5.3 Electrochemical Activation; 5.4 Chemical Activation; 5.5 Accumulation of Reactive Species; 5.5.1 The Cation-pool Method; 5.6 Continuous Generation of Reactive Species in a Flow System; 5.7 Interconversion Between Reactive Species; 5.8 Conclusions; References; 6 Control of Extremely Fast Reactions; 6.1 Mixing; 6.1.1 How Does Mixing Take Place?; 6.1.2 Molecular Diffusion and Brownian Motion; 6.1.3 Disguised Chemical Selectivity; 6.1.4 Lowering the Reaction Temperature; 6.1.5 The High Dilution Method; 6.1.6 Micromixing 6.1.7 Friedel-Crafts Alkylation Using anN-acyliminium Ion Pool6.1.8 Micromixing as a Powerful Tool for Flash Chemistry; 6.1.9 Disguised Chemical Selectivity in Competitive Parallel Reactions; 6.2 Temperature Control; 6.2.1 Exothermicity of Fast Reactions; 6.2.2 Hammond's Postulate; 6.2.3 The Friedel-Crafts Reaction; 6.2.4 Solvent; 6.2.5 Heat Transfer; 6.2.6 Precise Temperature Control in Microflow Systems; 6.3 Residence Time Control; 6.3.1 The Discovery of Benzyne. The Concept of Reactive Intermediates; 6.3.2 o -Bromophenyllithi um; 6.4 Conclusions; References 7 Microfluidic Devices and Microflow Systems7.1 Brief History; 7.1.1 Microflow Systems for Chemical Analysis; 7.1.2 Microflow Systems for Chemical Synthesis; 7.2 Characteristic Features of Microflow Systems; 7.3 Microstructured Fluidic Devices; 7.3.1 Microchip Reactors; 7.3.2 Microtube Reactors; 7.3.3 Micromixer; 7.3.4 Passive Micromixers; 7.3.5 Microheat Exchanger; 7.3.6 Photochemical Microflow Reactor; 7.3.7 Electrochemical Microflow Reactor; 7.3.8 Catalyst-containing Microflow Reactor; 7.3.9 Microflow Reactors for High-pressure and High-temperature Conditions; 7.4 Conclusions; References 8 Applications of Flash Chemistry in Organic Synthesis |
| Record Nr. | UNINA-9910144100303321 |
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Yoshida Junʼichi <1952->
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| Hoboken, N.J., : Wiley, 2008 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
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Flash chemistry [[electronic resource] ] : fast organic synthesis in microsystems / / Jun-ichi Yoshida
| Flash chemistry [[electronic resource] ] : fast organic synthesis in microsystems / / Jun-ichi Yoshida |
| Autore | Yoshida Junʼichi <1952-> |
| Pubbl/distr/stampa | Hoboken, N.J., : Wiley, 2008 |
| Descrizione fisica | 1 online resource (248 p.) |
| Disciplina |
547.2
547/.2 |
| Soggetto topico |
Organic compounds - Synthesis
Intermediates (Chemistry) Microreactors Organic reaction mechanisms |
| ISBN |
1-281-94011-9
9786611940119 0-470-72342-4 0-470-72341-6 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Flash Chemistry Fast Organic Synthesis in Microsystems; Contents; Preface; 1 Introduction; 1.1 Flask Chemistry; 1.2 Flash Chemistry; 1.3 Flask Chemistry or Flash Chemistry; References; 2 The Background to Flash Chemistry; 2.1 How do Chemical Reactions Take Place?; 2.1.1 Macroscopic View of Chemical Reactions; 2.1.2 Thermodynamic Equilibrium and Kinetics; 2.1.3 Kinetics; 2.1.4 Transition State Theory; 2.1.5 Femtosecond Chemistry and Reaction Dynamics; 2.1.6 Reactions for Dynamics and Reactions for Synthesis; 2.1.7 Bimolecular Reactions in the Gas Phase
2.1.8 Bimolecular Reactions in the Solution Phase2.1.9 Fast Chemical Synthesis Inspired by Reaction Dynamics; References; 3 What is Flash Chemistry?; 4 Why is Flash Chemistry Needed?; 4.1 Chemical Reaction, an Extremely Fast Process at Molecular Level; 4.2 Rapid Construction of Chemical Libraries; 4.3 Rapid Synthesis of Radioactive Positron Emission Tomography Probes; 4.4 On-demand Rapid Synthesis i n Industry 304.5 Conclusions; References; 5 Methods of Activating Molecules; 5.1 Thermal Activation of Organic Molecules; 5.1.1 High Temperature Reactions; 5.1.2 Flash Vacuum Pyrolysis 5.1.3 Microwave Reactions5.2 Photochemical Activation; 5.3 Electrochemical Activation; 5.4 Chemical Activation; 5.5 Accumulation of Reactive Species; 5.5.1 The Cation-pool Method; 5.6 Continuous Generation of Reactive Species in a Flow System; 5.7 Interconversion Between Reactive Species; 5.8 Conclusions; References; 6 Control of Extremely Fast Reactions; 6.1 Mixing; 6.1.1 How Does Mixing Take Place?; 6.1.2 Molecular Diffusion and Brownian Motion; 6.1.3 Disguised Chemical Selectivity; 6.1.4 Lowering the Reaction Temperature; 6.1.5 The High Dilution Method; 6.1.6 Micromixing 6.1.7 Friedel-Crafts Alkylation Using anN-acyliminium Ion Pool6.1.8 Micromixing as a Powerful Tool for Flash Chemistry; 6.1.9 Disguised Chemical Selectivity in Competitive Parallel Reactions; 6.2 Temperature Control; 6.2.1 Exothermicity of Fast Reactions; 6.2.2 Hammond's Postulate; 6.2.3 The Friedel-Crafts Reaction; 6.2.4 Solvent; 6.2.5 Heat Transfer; 6.2.6 Precise Temperature Control in Microflow Systems; 6.3 Residence Time Control; 6.3.1 The Discovery of Benzyne. The Concept of Reactive Intermediates; 6.3.2 o -Bromophenyllithi um; 6.4 Conclusions; References 7 Microfluidic Devices and Microflow Systems7.1 Brief History; 7.1.1 Microflow Systems for Chemical Analysis; 7.1.2 Microflow Systems for Chemical Synthesis; 7.2 Characteristic Features of Microflow Systems; 7.3 Microstructured Fluidic Devices; 7.3.1 Microchip Reactors; 7.3.2 Microtube Reactors; 7.3.3 Micromixer; 7.3.4 Passive Micromixers; 7.3.5 Microheat Exchanger; 7.3.6 Photochemical Microflow Reactor; 7.3.7 Electrochemical Microflow Reactor; 7.3.8 Catalyst-containing Microflow Reactor; 7.3.9 Microflow Reactors for High-pressure and High-temperature Conditions; 7.4 Conclusions; References 8 Applications of Flash Chemistry in Organic Synthesis |
| Record Nr. | UNINA-9910830745903321 |
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Yoshida Junʼichi <1952->
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| Hoboken, N.J., : Wiley, 2008 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
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Flash chemistry : fast organic synthesis in microsystems / / Jun-ichi Yoshida
| Flash chemistry : fast organic synthesis in microsystems / / Jun-ichi Yoshida |
| Autore | Yoshida Junichi <1952-> |
| Pubbl/distr/stampa | Hoboken, N.J., : Wiley, 2008 |
| Descrizione fisica | 1 online resource (248 p.) |
| Disciplina | 547/.2 |
| Soggetto topico |
Organic compounds - Synthesis
Intermediates (Chemistry) Microreactors Organic reaction mechanisms |
| ISBN |
9786611940119
9781281940117 1281940119 9780470723425 0470723424 9780470723418 0470723416 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Flash Chemistry Fast Organic Synthesis in Microsystems; Contents; Preface; 1 Introduction; 1.1 Flask Chemistry; 1.2 Flash Chemistry; 1.3 Flask Chemistry or Flash Chemistry; References; 2 The Background to Flash Chemistry; 2.1 How do Chemical Reactions Take Place?; 2.1.1 Macroscopic View of Chemical Reactions; 2.1.2 Thermodynamic Equilibrium and Kinetics; 2.1.3 Kinetics; 2.1.4 Transition State Theory; 2.1.5 Femtosecond Chemistry and Reaction Dynamics; 2.1.6 Reactions for Dynamics and Reactions for Synthesis; 2.1.7 Bimolecular Reactions in the Gas Phase
2.1.8 Bimolecular Reactions in the Solution Phase2.1.9 Fast Chemical Synthesis Inspired by Reaction Dynamics; References; 3 What is Flash Chemistry?; 4 Why is Flash Chemistry Needed?; 4.1 Chemical Reaction, an Extremely Fast Process at Molecular Level; 4.2 Rapid Construction of Chemical Libraries; 4.3 Rapid Synthesis of Radioactive Positron Emission Tomography Probes; 4.4 On-demand Rapid Synthesis i n Industry 304.5 Conclusions; References; 5 Methods of Activating Molecules; 5.1 Thermal Activation of Organic Molecules; 5.1.1 High Temperature Reactions; 5.1.2 Flash Vacuum Pyrolysis 5.1.3 Microwave Reactions5.2 Photochemical Activation; 5.3 Electrochemical Activation; 5.4 Chemical Activation; 5.5 Accumulation of Reactive Species; 5.5.1 The Cation-pool Method; 5.6 Continuous Generation of Reactive Species in a Flow System; 5.7 Interconversion Between Reactive Species; 5.8 Conclusions; References; 6 Control of Extremely Fast Reactions; 6.1 Mixing; 6.1.1 How Does Mixing Take Place?; 6.1.2 Molecular Diffusion and Brownian Motion; 6.1.3 Disguised Chemical Selectivity; 6.1.4 Lowering the Reaction Temperature; 6.1.5 The High Dilution Method; 6.1.6 Micromixing 6.1.7 Friedel-Crafts Alkylation Using anN-acyliminium Ion Pool6.1.8 Micromixing as a Powerful Tool for Flash Chemistry; 6.1.9 Disguised Chemical Selectivity in Competitive Parallel Reactions; 6.2 Temperature Control; 6.2.1 Exothermicity of Fast Reactions; 6.2.2 Hammond's Postulate; 6.2.3 The Friedel-Crafts Reaction; 6.2.4 Solvent; 6.2.5 Heat Transfer; 6.2.6 Precise Temperature Control in Microflow Systems; 6.3 Residence Time Control; 6.3.1 The Discovery of Benzyne. The Concept of Reactive Intermediates; 6.3.2 o -Bromophenyllithi um; 6.4 Conclusions; References 7 Microfluidic Devices and Microflow Systems7.1 Brief History; 7.1.1 Microflow Systems for Chemical Analysis; 7.1.2 Microflow Systems for Chemical Synthesis; 7.2 Characteristic Features of Microflow Systems; 7.3 Microstructured Fluidic Devices; 7.3.1 Microchip Reactors; 7.3.2 Microtube Reactors; 7.3.3 Micromixer; 7.3.4 Passive Micromixers; 7.3.5 Microheat Exchanger; 7.3.6 Photochemical Microflow Reactor; 7.3.7 Electrochemical Microflow Reactor; 7.3.8 Catalyst-containing Microflow Reactor; 7.3.9 Microflow Reactors for High-pressure and High-temperature Conditions; 7.4 Conclusions; References 8 Applications of Flash Chemistry in Organic Synthesis |
| Record Nr. | UNINA-9911019926603321 |
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Yoshida Junichi <1952->
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| Hoboken, N.J., : Wiley, 2008 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
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High-octane gasoline from lignocellulosic biomass via syngas and methanol/dimethyl ether intermediates : ... state of technology and future research
| High-octane gasoline from lignocellulosic biomass via syngas and methanol/dimethyl ether intermediates : ... state of technology and future research |
| Pubbl/distr/stampa | Golden, CO : , : National Renewable Energy Laboratory, , 2018- |
| Descrizione fisica | 1 online resource (volumes) : illustrations |
| Collana | NREL/TP |
| Soggetto topico |
Gasoline - United States - Anti-knock and anti-knock mixtures
Biomass chemicals - United States Lignocellulose - Biotechnology - United States Synthesis gas Intermediates (Chemistry) |
| Soggetto genere / forma | Technical reports. |
| Formato | Materiale a stampa |
| Livello bibliografico | Periodico |
| Lingua di pubblicazione | eng |
| Altri titoli varianti | High-octane gasoline from lignocellulosic biomass via syngas and methanol/dimethyl ether intermediates |
| Record Nr. | UNINA-9910717032403321 |
| Golden, CO : , : National Renewable Energy Laboratory, , 2018- | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
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Photochemically-generated intermediates in synthesis [[electronic resource] /] / Angelo Albini, Maurizio Fagnoni
| Photochemically-generated intermediates in synthesis [[electronic resource] /] / Angelo Albini, Maurizio Fagnoni |
| Autore | Albini Angelo |
| Pubbl/distr/stampa | Hoboken, N.J., : Wiley, c2013 |
| Descrizione fisica | 1 online resource (382 p.) |
| Disciplina | 547/.1372 |
| Altri autori (Persone) | FagnoniMaurizio |
| Soggetto topico |
Carbocations
Carbanions Intermediates (Chemistry) Photochemistry |
| ISBN |
1-118-68930-5
1-118-68920-8 1-118-68914-3 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto | Photogenerated intermediates : principles and practice -- Photogeneration of carbon centered radicals -- Photogeneration of heteroatom-centered radicals -- Photogeneration of biradicals and radical pairs -- Photochemical generation of radical ions -- Photogeneration of carbocations and carbanions -- Photogeneration of carbenes and nitrenes -- Manipulating intermediates the photochemical way. |
| Record Nr. | UNINA-9910141838003321 |
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Albini Angelo
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| Hoboken, N.J., : Wiley, c2013 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
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Photochemically-generated intermediates in synthesis / / Angelo Albini, Maurizio Fagnoni
| Photochemically-generated intermediates in synthesis / / Angelo Albini, Maurizio Fagnoni |
| Autore | Albini Angelo |
| Edizione | [1st ed.] |
| Pubbl/distr/stampa | Wiley, 2013 |
| Descrizione fisica | 1 online resource (382 p.) |
| Disciplina | 547/.1372 |
| Altri autori (Persone) | FagnoniMaurizio |
| Soggetto topico |
Carbocations
Carbanions Intermediates (Chemistry) Photochemistry |
| ISBN |
9781118689301
1118689305 9781118689202 1118689208 9781118689141 1118689143 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto | Photogenerated intermediates : principles and practice -- Photogeneration of carbon centered radicals -- Photogeneration of heteroatom-centered radicals -- Photogeneration of biradicals and radical pairs -- Photochemical generation of radical ions -- Photogeneration of carbocations and carbanions -- Photogeneration of carbenes and nitrenes -- Manipulating intermediates the photochemical way. |
| Record Nr. | UNINA-9910827733403321 |
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Albini Angelo
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| Wiley, 2013 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
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Quinone methides [[electronic resource] /] / edited by Steven E. Rokita
| Quinone methides [[electronic resource] /] / edited by Steven E. Rokita |
| Pubbl/distr/stampa | Hoboken, N.J., : Wiley, 2009 |
| Descrizione fisica | 1 online resource (460 p.) |
| Disciplina |
547.2
547/.2 |
| Altri autori (Persone) | RokitaSteven Edward |
| Collana | Wiley series on reactive intermediates in chemistry and biology |
| Soggetto topico | Intermediates (Chemistry) |
| ISBN |
1-282-68959-2
9786612689598 0-470-45288-9 0-470-45287-0 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
QUINONE METHIDES; CONTENTS; Preface to Series; Introduction; Contributors; 1 Photochemical Generation and Characterization of Quinone Methides; 1.1 Introduction; 1.2 Quinone Methides from Benzylic Photoelimination; 1.2.1 Photoelimination of Fluoride; 1.2.2 Photodehydration; 1.2.3 Photoelimination of Quaternary Ammonium Salts; 1.2.4 Photoelimination of Alcohols and Esters; 1.3 Quinone Methides from ESIPT to Unsaturated Systems; 1.3.1 Quinone Methides from ESIPT to Carbonyls; 1.3.2 Quinone Methides from ESIPT to Alkenes and Alkynes; 1.3.3 Quinone Methides from ESIPT to Aromatic Carbon
1.4 Other Photochemical Routes to Quinone Methides1.5 Conclusions and Outlook; References; 2 Modeling Properties and Reactivity of Quinone Methides by DFT Calculations; 2.1 Introduction; 2.2 QM Reactivity as Alkylating Agents; 2.2.1 Computational Models; 2.2.1.1 Basis Set Choice; 2.2.1.2 Energetics of the Benzylation by o-QM in the Gas Phase and in Aqueous Solution; 2.2.2 H-Bonding and Solvent Effects in the Benzylation of Purine and Pyrimidine Bases; 2.2.2.1 Cytosine Benzylation under Kinetic Control; 2.2.2.2 Stability/Reactivity of the QM-Cytosine Conjugates 2.2.2.3 Purine Bases Benzylation: Kinetic and Thermodynamic Aspects2.3 Reactivity as Heterodiene; 2.4 Tautomerizations Involving Quinones and Quinone Methides; 2.4.1 QM Versus Quinone Stability: Substituent Effects; 2.5 o-Quinone Methide Metal Complexes; 2.5.1 Geometries and Reactivity as Function of the Metal and the Structural Features; 2.6 Generation of o-QM; 2.6.1 Generation of o-QM Tethered to Naphthalene Diimides by Mild Activation; 2.6.2 Thermal Generation of o-QM in Oxidative Processes in the Gas Phase; 2.7 Thermal Decomposition of o-QM in the Gas Phase 2.8 QM Generation in Lignin Formation2.9 Conclusion and Perspective; References; 3 Quinone Methide Stabilization by Metal Complexation; 3.1 Introduction; 3.2 QM-Based Pincer Complexes; 3.2.1 Formation; 3.2.2 Reactivity and Modifications; 3.2.3 Os-Based, p-QM Complexes; 3.3 One-Site Coordinated QM Complexes; 3.3.1 η(2)-ortho-QM Complexes; 3.3.1.1 Formation; 3.3.1.2 Release and Reactivity of η(2)-o-QMs; 3.3.2 η(2)-p-QM Complexes; 3.3.2.1 Formation; 3.3.2.2 Controlled Release and Modification of η(2)-p-QMs; 3.4 η(4)-Coordinated QM Complexes; 3.4.1 Formation of η(4)-Coordinated QM Complexes 3.4.2 Reactivity of η(4)-Coordinated QM Complexes3.4.3 η(4)-Coordinated QM Complexes of Mn; 3.5 Characterization of QM Complexes; 3.5.1 IR; 3.5.2 (1)H and (13)C {(1)H} NMR; 3.5.3 X-Ray; 3.6 Conclusion and Future Applications; Acknowledgments; References; 4 Intermolecular Applications of o-Quinone Methides (o-QMs) Anionically Generated at Low Temperatures: Kinetic Conditions; 4.1 Introduction to o-QMs; 4.2 Thermal Generation Conditions; 4.3 Low-Temperature Kinetic Generation of o-QMs; 4.3.1 Formation of the o-QMs Triggered by Fluoride Ion; 4.3.2 Stepwise Formation of o-QMs 4.3.3 Kinetically Controlled Cycloadditions |
| Record Nr. | UNINA-9910146086703321 |
| Hoboken, N.J., : Wiley, 2009 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
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