Pubbl/distr/stampa	Weinheim, : Wiley-VCH, c2006
Descrizione fisica	1 online resource (383 p.)
Disciplina	541.22
Altri autori (Persone)	TolmanWilliam B
Soggetto topico	Molecules Ions Inorganic compounds Inorganic compounds - Synthesis
Soggetto genere / forma	Electronic books.
ISBN	1-280-72285-1 9786610722853 3-527-60935-0 3-527-60937-7
Classificazione	35.60
Formato	Materiale a stampa
Livello bibliografico	Monografia
Lingua di pubblicazione	eng
Nota di contenuto	Activation of Small Molecules; Contents; Preface; List of Contributors; 1 Carbon Dioxide Reduction and Uses as a Chemical Feedstock; 1.1 Introduction; 1.2 Properties of the CO(2) Molecule; 1.2.1 Molecular Geometry; 1.2.2 Spectroscopic Properties; 1.2.2.1 Vibrational; 1.2.2.2 UV-Vis; 1.2.2.3 (13)C-Nuclear Magnetic Resonance (NMR); 1.2.3 Energy Data and Reaction Kinetics Relevant to CO(2) Conversion; 1.3 CO(2) Coordination to Metal Centers and Reactivity of Coordinated CO(2); 1.3.1 Modes of Coordination; 1.3.2 Interaction of CO(2) with Metal Atoms at Low Temperature: Stability of the Adducts 1.3.3 Reactivity of CO(2) Coordinated to Transition Metal Systems1.4 CO(2) Conversion; 1.4.1 Carboxylation Reactions; 1.4.1.1 C-C Bond Formation; 1.4.1.1.1 Natural Processes; 1.4.1.1.2 Artificial Processes; 1.4.1.2 N-C Bond Formation; 1.4.1.3 O-C Bond Formation; 1.4.1.3.1 Cyclic Carbonates; 1.4.1.3.2 Linear Carbonates; 1.4.1.4 Use of Urea as an Active-CO(2) Form; 1.4.1.5 Transesterification Reactions; 1.4.2 Reduction Reactions; 1.4.2.1 Energetics of the Reactions; 1.4.2.1.1 Natural Processes; 1.4.2.1.2 Artificial Processes; 1.4.2.1.3 Photoelectrochemical Reduction; 1.5 Conclusions; References 2 Nitrogen Monoxide and Nitrous Oxide Binding and Reduction2.1 Introduction; 2.2 NO; 2.2.1 Bonding and Structures of Metal Nitrosyls; 2.2.1.1 Heme Proteins: Guanylate Cyclase - NO Binding and Trans-bond Labilization; 2.2.1.2 Bridging (η(1)-μ(2)-) Complexes; 2.2.1.3 η(1)-μ(3)-NO Bridging Complexes; 2.2.1.4 η(2)-NO Bridging Complexes; 2.2.1.5 Isonitrosyl and Side-on η(2)-NO Complexes; 2.2.1.6 Side-on η(2)-NO Copper Protein Structures; 2.2.1.7 Spectroscopic Features of Nitrosyl Metal Complexes; 2.2.2 Chemical Reduction of NO and Related Chemistry; 2.2.2.1 Chemical Reduction of Metal-bound NO 2.2.2.1.1 Metal-NO Reduction Accompanied by N-O Cleavage2.2.2.2 Electrophilic Attack on Metal-bound NO:HNO (Nitroxyl) Complexes; 2.2.2.3 Electrocatalytic Reduction of NO; 2.2.2.4 Biological NO Reduction: NORs; 2.2.2.4.1 Bacterial NORs of the Heme Copper Oxidase (HCO) Type [54, 147]; 2.2.2.4.2 Models for NORs; 2.2.2.4.3 Fungal P450-type NORs; 2.2.2.4.4 Flavorubredoxins as Scavenging (S)-NORs; 2.2.2.5 Metal Complex-mediated NO Disproportionation; 2.3 N(2)O; 2.3.1 Structure and Bonding; 2.3.2 Metal-mediated N(2)O Reduction; 2.3.2.1 Oxo Transfer Reactions; 2.3.2.2 Catalytic Oxo Transfer 2.3.2.3 N(2)O N-N Bond Cleavage2.3.2.4 Electrocatalytic Reduction of N(2)O to N(2); 2.3.2.5 Biological N(2)O Reduction; 2.4 Summary and Conclusions; References; 3 Bio-organometallic Approaches to Nitrogen Fixation Chemistry; 3.1 Introduction - The N(2) Fixation Challenge; 3.2 Biological N(2) Reduction; 3.2.1 General Comments; 3.2.2 Structural Data; 3.2.3 Assigning the FeMoco Oxidation States; 3.3 Biomimetic Systems that Model Structure and Function; 3.3.1 General Comments; 3.3.2 Mononuclear Molybdenum Systems of Biomimetic Interest; 3.3.2.1 The Originally Proposed "Chatt Cycle" 3.3.2.2 An Electrocatalytic Reduction Cycle using Low-valent Tungsten
Record Nr.	UNINA-9910144319803321

Pubbl/distr/stampa	[Santiago, RM, Chile] : , : USACH
Descrizione fisica	1 online resource
Soggetto topico	Inorganic compounds - Synthesis
Soggetto genere / forma	Periodicals.
Soggetto non controllato	Inorganic Chemistry
ISSN	0719-2827
Formato	Materiale a stampa
Livello bibliografico	Periodico
Lingua di pubblicazione	eng
Altri titoli varianti	Comm. Inorg. Synth
Record Nr.	UNINA-9910136265003321

Autore	Rao C. N. R (Chintamani Nagesa Ramachandra), <1934->
Pubbl/distr/stampa	Hoboken, New Jersey : , : Wiley, , 2015
Descrizione fisica	1 online resource (234 p.)
Disciplina	541/.39
Soggetto topico	Inorganic compounds - Synthesis
ISBN	1-118-89266-6 1-118-89267-4
Classificazione	SCI013030TEC021000SCI050000
Formato	Materiale a stampa
Livello bibliografico	Monografia
Lingua di pubblicazione	eng
Nota di contenuto	Title Page; Copyright Page; Contents; Author Biographies; Preface; Chapter 1 Introduction; References; Chapter 2 Common Reactions Employed in Synthesis; 2.1 Soft-Chemistry Routes; References; Chapter 3 Ceramic Methods; References; Chapter 4 Decomposition of Precursor Compounds; References; Chapter 5 Combustion Synthesis; References; Chapter 6 Arc and Skull Methods; References; Chapter 7 Reactions at High Pressures; References; Chapter 8 Mechanochemical and Sonochemical Methods; 8.1 Mechanochemistry; 8.2 Sonochemistry; References; Chapter 9 Use of Microwaves; References Chapter 10 Soft Chemistry Routes10.1 Topochemical Reactions; References; 10.2 Intercalation Chemistry; References; 10.3 Ion Exchange Reactions; References; 10.4 Use of Fluxes; References; 10.5 Sol-Gel Synthesis; References; 10.6 Electrochemical Methods; References; 10.7 Hydrothermal, Solvothermal and Ionothermal Synthesis; References; Chapter 11 Nebulized Spray Pyrolysis; References; Chapter 12 Chemical Vapour Deposition and Atomic Layer Deposition; References; Chapter 13 Nanomaterials; 13.1 Nanoparticles; 13.1.1 Use of Microemulsions; 13.1.2 Thermal Decomposition 13.1.3 Hydrothermal and Solvothermal Synthesis13.1.4 Sol-Gel Method; 13.1.5 Phase-Transfer Method; 13.1.6 Microwave Synthesis; 13.1.7 Use of the Liquid-Liquid Interface; 13.2 Core-Shell Nanocrystals; 13.3 Nanowires; 13.3.1 Metals; 13.3.2 Elemental Semiconductors; 13.3.3 Metal Oxides; 13.3.4 Metal Chalcogenides; 13.3.5 Metal Pnictides and Other Materials; 13.3.6 Oriented Attachment; 13.3.7 Coaxial Cables and Other Hybrid Nanostructures; 13.4 Inorganic Nanotubes; 13.5 Graphene-like Structures of Layered Inorganic Materials; References; Chapter 14 Materials 14.1 Metal Borides, Carbides and NitridesReferences; 14.2 Metal Chalcogenides; References; 14.3 Metal Halides; References; 14.4 Metal Silicides and Phosphides; References; 14.5 Intergrowth Structures and Misfit Compounds; 14.5.1 Intergrowth Structures; 14.5.2 Misfit Compounds; References; 14.6 Intermetallic Compounds; References; 14.7 Superconducting Compounds; References; 14.8 Porous Materials; 14.8.1 Mesoporous Silica Materials; 14.8.2 Aluminophosphates ; 14.8.3 Metal Organic Frameworks (MOFs); References; Index; Supplemental Images; EULA
Record Nr.	UNINA-9910140488903321

Pubbl/distr/stampa	New York, N.Y., : VCH Publishers, 1991
Descrizione fisica	1 online resource (633 p.)
Disciplina	541.3/9 541.39
Altri autori (Persone)	ZuckermanJ. J <1936-1987.> (Jerold J.) HagenA. P
Collana	Inorganic reactions and methods
Soggetto topico	Chemical kinetics - Effect of temperature on Inorganic compounds - Synthesis
Soggetto genere / forma	Electronic books.
ISBN	1-282-30813-0 9786612308130 0-470-14523-4 0-470-14544-7
Formato	Materiale a stampa
Livello bibliografico	Monografia
Lingua di pubblicazione	eng
Nota di contenuto	Inorganic Reactions and Methods; Contents; How to use this book; Preface to the Series; Editorial Consultants to the Series; Contributors to Volume 9; Formation of the Bonds to the Group-IVB (C, Si, Ge, Sn, Pb) Elements; Introduction; Formation of the Group-IVB (C, Si, Ge, Sn, Pb)-Group-IVB (C, Si, Ge, Sn, Pb) Element Bond; Introduction; Formation of the Carbon-Carbon Bond; Formation of the Si-Si Bond; in Elemental Silicon; from Oxides.; by Other Methods.; Formation of High-Purity Silicon; Electrochemical Formation of Compounds with Si-Si Bonds (Including Elemental Silicon) from Metal Silicidesby Solvolysis in Aqueous or Liquid Ammonia Solutions.; Formation of Oligosilanes; Formation of Polymeric Compounds; from Silicon Hydrides and Organosilicon Hydrides; by the Action of a Silent Electric Discharge.; by Direct Photolysis.; by Sensitized Photolysis.; by Catalyzed Reactions.; by Reaction with Silylmetallic Compounds.; from Silicon Halides and Organosilicon Halides; by Electrochemical Reduction.; by Halide Elimination with Active Metals.; by Reaction with Silylmetallics.; by Catalyzed Disproportionation.; by Reaction with Organomagnesium Halide Reagents. by the Action of Silent Electric Discharge.by Mercury-Photosensitized Photolyses.; from Bissilylmercury Compounds; by Thermolysis.; by Photolysis.; from Organosilanes and Silicon Halides by Hydrogenolysis.; from Silylenes; by Oligomerization.; by Insertions into Bonds of Silicon to Hydrogen, Oxygen and Silicon.; by Addition to Si = C.; in the Direct Reaction of Methyl Chloride with Silicon-Copper.; Formation of the Germanium-Germanium Bond; in Elemental Germanium; from Oxides.; from Sulfides.; by Other Syntheses.; Formation of High-Purity Germanium.; from Organogermanium Hydrides by Reaction with Diorganomercury Compounds in the Presence of UV Radiation.by Hydrogermolysis Reaction.; by Germanium Hydride Decomposition.; from Ge(lV) Halides and Organogermanium(IV) Halides; by the Action of a Microwave Discharge of Ge(lV) Halides.; by Electrochemical Reduction.; by Halide Elimination with Active Metals.; by Reaction with Germyl-Metal Reagents.; by Reaction with Organometallic Reagents.; from Germanium(lI) Halides; by Reactions with Germyl-Metal Reagents.; by Reaction with Organometallic Reagents.; from Germyl Compounds of Cadmium, Mercury, Thallium, Antimony and Bismuth by Thermolysis or Photolysis.from Germylenes; by Oligomerization of Germylenes.; by Insertions into Bonds of Germanium to Hydrogen, Halogen, Carbon, Oxygen, Sulfur, Nitrogen, Phosphorus and Germanium.; The Formation of the Tin-Tin Bond; in Elemental Tin; from Oxides.; from Sulfides.; by Other Syntheses.; Allotropy of Tin; from Organotin Hydrides; by Catalytic Hydrogen Elimination.; by Reaction with Organotin Halogen, Pseudohalogen, Chalcogen and Pnictogen Compounds.; by Reaction with Organometallic Compounds.; by Reaction with Reducible Organic Compounds.; from Organotin Halides by Electrochemical Reduction.
Record Nr.	UNINA-9910144322603321