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Activated carbon [[electronic resource] /] / Harry Marsh, Francisco Rodríguez-Reinoso
| Activated carbon [[electronic resource] /] / Harry Marsh, Francisco Rodríguez-Reinoso |
| Autore | Marsh Harry |
| Edizione | [1st ed.] |
| Pubbl/distr/stampa | Amsterdam, : Elsevier, 2006 |
| Descrizione fisica | 1 online resource (555 p.) |
| Disciplina | 662.93 |
| Altri autori (Persone) | Rodríguez-ReinosoF. <1941-> |
| Soggetto topico |
Carbon, Activated
Inorganic compounds |
| Soggetto genere / forma | Electronic books. |
| ISBN |
1-280-64095-2
9786610640959 0-08-045596-4 |
| Formato | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Front cover; Title page; Copyright page; Table of contents; Preface; Acknowledgments; 1 Introduction to the Scope of the Text; 1.1 Activated Carbon; 1.1.1 Talking About Porosity; 1.2 Activated Carbon (Origins): Chapter 2; 1.3 Porosity in Carbons (Modeling): Chapter 3; 1.4 Characterization of Porosity: Chapter 4; 1.5 Activation Processes (Thermal or Physical): Chapter 5; 1.6 Activation Processes (Chemical): Chapter 6; 1.7 SEM and TEM Images of Structures in Activated Carbon: Chapter 7; 1.8 Applications of Activated Carbon: Chapter 8; 1.8.1 Introduction; 1.8.2 Adsorptions from Aqueous Solutions
1.9 Production of Activated Carbon and Reference Material: Chapter 92 Activated Carbon (Origins); 2.1 Carbon Materials; 2.2 Parent Materials for Carbons; 2.3 Carbon Nomenclature; 2.4 The Element Carbon; 2.5 Carbons with Industrial Applications; 2.6 Preparation of Carbons in Solid Phase; 2.6.1 Introduction; 2.6.2 Solid-phase Carbonizations; 2.6.2.1 Variation of surface area with HTT; 2.6.2.2 Variation of free spin concentration (ESR) with HTT; 2.6.2.3 Activated carbon from coal; 2.6.2.4 Coal rank; 2.6.2.5 Microporosity in coal; 2.7 Preparation of Carbons in Liquid Phase: Liquid Crystals 2.7.1 Introduction 2.7.2 Nematic Liquid Crystals; 2.8 Preparation of Carbons in Gas Phase; 2.8.1 Introduction; 2.8.2 Carbon Black; 2.8.3 Fullerenes, Nanotubes and Necklaces; 2.9 Structures Within Carbons; 2.9.1 Bonding and Structure; 2.10 The Non-validity of the ""Crystallite"" (Graphitic Microcrystallite) Concept; 2.10.1 Introduction; 2.10.2 Graphitic Microcrystallites in Coal?; 2.10.3 Causes of Line-broadening in XRD; 2.10.4 The Graphitic Microcrystallite Theory: Conclusions; 2.11 Raman Microspectroscopy in Structural Analyses: An Assessment; 2.11.1 Introduction to the Use of RMS 2.11.2 Incorrect Interpretations of RMS Data 2.11.3 Definitive Studies Using Pitch (Dumont et al., 2002); 2.11.4 Interpretations of RMS Data; 2.12 Quantitative Reflectance Microscopy and Carbon Structure; 2.13 What is Carbon Structure? Concluding Comments; 2.14 Applications Related to Porous and Chemical Structure; 2.14.1 The uses of Porous Carbons; 2.14.2 Take-up of Lithium into Carbons for Batteries; References; 3 Porosity in Carbons: Modeling; 3.1 Introduction; 3.2 Model Requirements; 3.3 Why Modeling?; 3.4 Models to be Considered; 3.4.1 The Drill-hole Models; 3.4.2 The Branched-tree Model 3.4.3 The Norit Model 3.4.4 Carbon from Benzene Hexachloride, Gibson et al. (1946) and Riley (1947); 3.4.5 Potato-chip Models; 3.4.6 Models of Kaneko et al. (1992a, b); 3.4.7 Model of Ruike et al. (1994); 3.4.8 Falling Card Model of Dahn et al. (1997); 3.4.9 Glassy Carbon Model of Yoshida et al. (1991); 3.4.10 Model of Porous Microtexture of a Carbonaceous Particle of Oberlin et al. (1980, 1999) and Oberlin (1989); 3.4.11 The Model of Virtual Porous Solids of Biggs and Agarwal (1992, 1994) and Biggs et al. (2004a, b); 3.4.12 Model of Porous Carbon of Segarra and Glandt (1994) 3.4.13 Tight-binding Model of Wang et al. (1996) |
| Record Nr. | UNINA-9910458753003321 |
Marsh Harry
|
||
| Amsterdam, : Elsevier, 2006 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Activated carbon [[electronic resource] /] / Harry Marsh, Francisco Rodríguez-Reinoso
| Activated carbon [[electronic resource] /] / Harry Marsh, Francisco Rodríguez-Reinoso |
| Autore | Marsh Harry |
| Edizione | [1st ed.] |
| Pubbl/distr/stampa | Amsterdam, : Elsevier, 2006 |
| Descrizione fisica | 1 online resource (555 p.) |
| Disciplina | 662.93 |
| Altri autori (Persone) | Rodríguez-ReinosoF. <1941-> |
| Soggetto topico |
Carbon, Activated
Inorganic compounds |
| ISBN |
1-280-64095-2
9786610640959 0-08-045596-4 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Front cover; Title page; Copyright page; Table of contents; Preface; Acknowledgments; 1 Introduction to the Scope of the Text; 1.1 Activated Carbon; 1.1.1 Talking About Porosity; 1.2 Activated Carbon (Origins): Chapter 2; 1.3 Porosity in Carbons (Modeling): Chapter 3; 1.4 Characterization of Porosity: Chapter 4; 1.5 Activation Processes (Thermal or Physical): Chapter 5; 1.6 Activation Processes (Chemical): Chapter 6; 1.7 SEM and TEM Images of Structures in Activated Carbon: Chapter 7; 1.8 Applications of Activated Carbon: Chapter 8; 1.8.1 Introduction; 1.8.2 Adsorptions from Aqueous Solutions
1.9 Production of Activated Carbon and Reference Material: Chapter 92 Activated Carbon (Origins); 2.1 Carbon Materials; 2.2 Parent Materials for Carbons; 2.3 Carbon Nomenclature; 2.4 The Element Carbon; 2.5 Carbons with Industrial Applications; 2.6 Preparation of Carbons in Solid Phase; 2.6.1 Introduction; 2.6.2 Solid-phase Carbonizations; 2.6.2.1 Variation of surface area with HTT; 2.6.2.2 Variation of free spin concentration (ESR) with HTT; 2.6.2.3 Activated carbon from coal; 2.6.2.4 Coal rank; 2.6.2.5 Microporosity in coal; 2.7 Preparation of Carbons in Liquid Phase: Liquid Crystals 2.7.1 Introduction 2.7.2 Nematic Liquid Crystals; 2.8 Preparation of Carbons in Gas Phase; 2.8.1 Introduction; 2.8.2 Carbon Black; 2.8.3 Fullerenes, Nanotubes and Necklaces; 2.9 Structures Within Carbons; 2.9.1 Bonding and Structure; 2.10 The Non-validity of the ""Crystallite"" (Graphitic Microcrystallite) Concept; 2.10.1 Introduction; 2.10.2 Graphitic Microcrystallites in Coal?; 2.10.3 Causes of Line-broadening in XRD; 2.10.4 The Graphitic Microcrystallite Theory: Conclusions; 2.11 Raman Microspectroscopy in Structural Analyses: An Assessment; 2.11.1 Introduction to the Use of RMS 2.11.2 Incorrect Interpretations of RMS Data 2.11.3 Definitive Studies Using Pitch (Dumont et al., 2002); 2.11.4 Interpretations of RMS Data; 2.12 Quantitative Reflectance Microscopy and Carbon Structure; 2.13 What is Carbon Structure? Concluding Comments; 2.14 Applications Related to Porous and Chemical Structure; 2.14.1 The uses of Porous Carbons; 2.14.2 Take-up of Lithium into Carbons for Batteries; References; 3 Porosity in Carbons: Modeling; 3.1 Introduction; 3.2 Model Requirements; 3.3 Why Modeling?; 3.4 Models to be Considered; 3.4.1 The Drill-hole Models; 3.4.2 The Branched-tree Model 3.4.3 The Norit Model 3.4.4 Carbon from Benzene Hexachloride, Gibson et al. (1946) and Riley (1947); 3.4.5 Potato-chip Models; 3.4.6 Models of Kaneko et al. (1992a, b); 3.4.7 Model of Ruike et al. (1994); 3.4.8 Falling Card Model of Dahn et al. (1997); 3.4.9 Glassy Carbon Model of Yoshida et al. (1991); 3.4.10 Model of Porous Microtexture of a Carbonaceous Particle of Oberlin et al. (1980, 1999) and Oberlin (1989); 3.4.11 The Model of Virtual Porous Solids of Biggs and Agarwal (1992, 1994) and Biggs et al. (2004a, b); 3.4.12 Model of Porous Carbon of Segarra and Glandt (1994) 3.4.13 Tight-binding Model of Wang et al. (1996) |
| Record Nr. | UNINA-9910784538503321 |
|
Marsh Harry
|
||
| Amsterdam, : Elsevier, 2006 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Activated carbon / / Harry Marsh, Francisco Rodriguez-Reinoso
| Activated carbon / / Harry Marsh, Francisco Rodriguez-Reinoso |
| Autore | Marsh Harry |
| Edizione | [1st ed.] |
| Pubbl/distr/stampa | Amsterdam, : Elsevier, 2006 |
| Descrizione fisica | 1 online resource (555 p.) |
| Disciplina | 662.93 |
| Altri autori (Persone) | Rodriguez-ReinosoF. <1941-> |
| Soggetto topico |
Carbon, Activated
Inorganic compounds |
| ISBN |
1-280-64095-2
9786610640959 0-08-045596-4 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Front cover; Title page; Copyright page; Table of contents; Preface; Acknowledgments; 1 Introduction to the Scope of the Text; 1.1 Activated Carbon; 1.1.1 Talking About Porosity; 1.2 Activated Carbon (Origins): Chapter 2; 1.3 Porosity in Carbons (Modeling): Chapter 3; 1.4 Characterization of Porosity: Chapter 4; 1.5 Activation Processes (Thermal or Physical): Chapter 5; 1.6 Activation Processes (Chemical): Chapter 6; 1.7 SEM and TEM Images of Structures in Activated Carbon: Chapter 7; 1.8 Applications of Activated Carbon: Chapter 8; 1.8.1 Introduction; 1.8.2 Adsorptions from Aqueous Solutions
1.9 Production of Activated Carbon and Reference Material: Chapter 92 Activated Carbon (Origins); 2.1 Carbon Materials; 2.2 Parent Materials for Carbons; 2.3 Carbon Nomenclature; 2.4 The Element Carbon; 2.5 Carbons with Industrial Applications; 2.6 Preparation of Carbons in Solid Phase; 2.6.1 Introduction; 2.6.2 Solid-phase Carbonizations; 2.6.2.1 Variation of surface area with HTT; 2.6.2.2 Variation of free spin concentration (ESR) with HTT; 2.6.2.3 Activated carbon from coal; 2.6.2.4 Coal rank; 2.6.2.5 Microporosity in coal; 2.7 Preparation of Carbons in Liquid Phase: Liquid Crystals 2.7.1 Introduction 2.7.2 Nematic Liquid Crystals; 2.8 Preparation of Carbons in Gas Phase; 2.8.1 Introduction; 2.8.2 Carbon Black; 2.8.3 Fullerenes, Nanotubes and Necklaces; 2.9 Structures Within Carbons; 2.9.1 Bonding and Structure; 2.10 The Non-validity of the ""Crystallite"" (Graphitic Microcrystallite) Concept; 2.10.1 Introduction; 2.10.2 Graphitic Microcrystallites in Coal?; 2.10.3 Causes of Line-broadening in XRD; 2.10.4 The Graphitic Microcrystallite Theory: Conclusions; 2.11 Raman Microspectroscopy in Structural Analyses: An Assessment; 2.11.1 Introduction to the Use of RMS 2.11.2 Incorrect Interpretations of RMS Data 2.11.3 Definitive Studies Using Pitch (Dumont et al., 2002); 2.11.4 Interpretations of RMS Data; 2.12 Quantitative Reflectance Microscopy and Carbon Structure; 2.13 What is Carbon Structure? Concluding Comments; 2.14 Applications Related to Porous and Chemical Structure; 2.14.1 The uses of Porous Carbons; 2.14.2 Take-up of Lithium into Carbons for Batteries; References; 3 Porosity in Carbons: Modeling; 3.1 Introduction; 3.2 Model Requirements; 3.3 Why Modeling?; 3.4 Models to be Considered; 3.4.1 The Drill-hole Models; 3.4.2 The Branched-tree Model 3.4.3 The Norit Model 3.4.4 Carbon from Benzene Hexachloride, Gibson et al. (1946) and Riley (1947); 3.4.5 Potato-chip Models; 3.4.6 Models of Kaneko et al. (1992a, b); 3.4.7 Model of Ruike et al. (1994); 3.4.8 Falling Card Model of Dahn et al. (1997); 3.4.9 Glassy Carbon Model of Yoshida et al. (1991); 3.4.10 Model of Porous Microtexture of a Carbonaceous Particle of Oberlin et al. (1980, 1999) and Oberlin (1989); 3.4.11 The Model of Virtual Porous Solids of Biggs and Agarwal (1992, 1994) and Biggs et al. (2004a, b); 3.4.12 Model of Porous Carbon of Segarra and Glandt (1994) 3.4.13 Tight-binding Model of Wang et al. (1996) |
| Record Nr. | UNINA-9910828346803321 |
|
Marsh Harry
|
||
| Amsterdam, : Elsevier, 2006 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Activation of small molecules [[electronic resource] ] : organometallic and bioinorganic perspectives / / edited by William B. Tolman
| Activation of small molecules [[electronic resource] ] : organometallic and bioinorganic perspectives / / edited by William B. Tolman |
| Pubbl/distr/stampa | Weinheim, : Wiley-VCH, c2006 |
| Descrizione fisica | 1 online resource (383 p.) |
| Disciplina | 541.22 |
| Altri autori (Persone) | TolmanWilliam B |
| Soggetto topico |
Molecules
Ions Inorganic compounds Inorganic compounds - Synthesis |
| Soggetto genere / forma | Electronic books. |
| ISBN |
1-280-72285-1
9786610722853 3-527-60935-0 3-527-60937-7 |
| Classificazione | 35.60 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Activation of Small Molecules; Contents; Preface; List of Contributors; 1 Carbon Dioxide Reduction and Uses as a Chemical Feedstock; 1.1 Introduction; 1.2 Properties of the CO(2) Molecule; 1.2.1 Molecular Geometry; 1.2.2 Spectroscopic Properties; 1.2.2.1 Vibrational; 1.2.2.2 UV-Vis; 1.2.2.3 (13)C-Nuclear Magnetic Resonance (NMR); 1.2.3 Energy Data and Reaction Kinetics Relevant to CO(2) Conversion; 1.3 CO(2) Coordination to Metal Centers and Reactivity of Coordinated CO(2); 1.3.1 Modes of Coordination; 1.3.2 Interaction of CO(2) with Metal Atoms at Low Temperature: Stability of the Adducts
1.3.3 Reactivity of CO(2) Coordinated to Transition Metal Systems1.4 CO(2) Conversion; 1.4.1 Carboxylation Reactions; 1.4.1.1 C-C Bond Formation; 1.4.1.1.1 Natural Processes; 1.4.1.1.2 Artificial Processes; 1.4.1.2 N-C Bond Formation; 1.4.1.3 O-C Bond Formation; 1.4.1.3.1 Cyclic Carbonates; 1.4.1.3.2 Linear Carbonates; 1.4.1.4 Use of Urea as an Active-CO(2) Form; 1.4.1.5 Transesterification Reactions; 1.4.2 Reduction Reactions; 1.4.2.1 Energetics of the Reactions; 1.4.2.1.1 Natural Processes; 1.4.2.1.2 Artificial Processes; 1.4.2.1.3 Photoelectrochemical Reduction; 1.5 Conclusions; References 2 Nitrogen Monoxide and Nitrous Oxide Binding and Reduction2.1 Introduction; 2.2 NO; 2.2.1 Bonding and Structures of Metal Nitrosyls; 2.2.1.1 Heme Proteins: Guanylate Cyclase - NO Binding and Trans-bond Labilization; 2.2.1.2 Bridging (η(1)-μ(2)-) Complexes; 2.2.1.3 η(1)-μ(3)-NO Bridging Complexes; 2.2.1.4 η(2)-NO Bridging Complexes; 2.2.1.5 Isonitrosyl and Side-on η(2)-NO Complexes; 2.2.1.6 Side-on η(2)-NO Copper Protein Structures; 2.2.1.7 Spectroscopic Features of Nitrosyl Metal Complexes; 2.2.2 Chemical Reduction of NO and Related Chemistry; 2.2.2.1 Chemical Reduction of Metal-bound NO 2.2.2.1.1 Metal-NO Reduction Accompanied by N-O Cleavage2.2.2.2 Electrophilic Attack on Metal-bound NO:HNO (Nitroxyl) Complexes; 2.2.2.3 Electrocatalytic Reduction of NO; 2.2.2.4 Biological NO Reduction: NORs; 2.2.2.4.1 Bacterial NORs of the Heme Copper Oxidase (HCO) Type [54, 147]; 2.2.2.4.2 Models for NORs; 2.2.2.4.3 Fungal P450-type NORs; 2.2.2.4.4 Flavorubredoxins as Scavenging (S)-NORs; 2.2.2.5 Metal Complex-mediated NO Disproportionation; 2.3 N(2)O; 2.3.1 Structure and Bonding; 2.3.2 Metal-mediated N(2)O Reduction; 2.3.2.1 Oxo Transfer Reactions; 2.3.2.2 Catalytic Oxo Transfer 2.3.2.3 N(2)O N-N Bond Cleavage2.3.2.4 Electrocatalytic Reduction of N(2)O to N(2); 2.3.2.5 Biological N(2)O Reduction; 2.4 Summary and Conclusions; References; 3 Bio-organometallic Approaches to Nitrogen Fixation Chemistry; 3.1 Introduction - The N(2) Fixation Challenge; 3.2 Biological N(2) Reduction; 3.2.1 General Comments; 3.2.2 Structural Data; 3.2.3 Assigning the FeMoco Oxidation States; 3.3 Biomimetic Systems that Model Structure and Function; 3.3.1 General Comments; 3.3.2 Mononuclear Molybdenum Systems of Biomimetic Interest; 3.3.2.1 The Originally Proposed "Chatt Cycle" 3.3.2.2 An Electrocatalytic Reduction Cycle using Low-valent Tungsten |
| Record Nr. | UNINA-9910144319803321 |
| Weinheim, : Wiley-VCH, c2006 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Activation of small molecules [[electronic resource] ] : organometallic and bioinorganic perspectives / / edited by William B. Tolman
| Activation of small molecules [[electronic resource] ] : organometallic and bioinorganic perspectives / / edited by William B. Tolman |
| Pubbl/distr/stampa | Weinheim, : Wiley-VCH, c2006 |
| Descrizione fisica | 1 online resource (383 p.) |
| Disciplina | 541.22 |
| Altri autori (Persone) | TolmanWilliam B |
| Soggetto topico |
Molecules
Ions Inorganic compounds Inorganic compounds - Synthesis |
| ISBN |
1-280-72285-1
9786610722853 3-527-60935-0 3-527-60937-7 |
| Classificazione | 35.60 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Activation of Small Molecules; Contents; Preface; List of Contributors; 1 Carbon Dioxide Reduction and Uses as a Chemical Feedstock; 1.1 Introduction; 1.2 Properties of the CO(2) Molecule; 1.2.1 Molecular Geometry; 1.2.2 Spectroscopic Properties; 1.2.2.1 Vibrational; 1.2.2.2 UV-Vis; 1.2.2.3 (13)C-Nuclear Magnetic Resonance (NMR); 1.2.3 Energy Data and Reaction Kinetics Relevant to CO(2) Conversion; 1.3 CO(2) Coordination to Metal Centers and Reactivity of Coordinated CO(2); 1.3.1 Modes of Coordination; 1.3.2 Interaction of CO(2) with Metal Atoms at Low Temperature: Stability of the Adducts
1.3.3 Reactivity of CO(2) Coordinated to Transition Metal Systems1.4 CO(2) Conversion; 1.4.1 Carboxylation Reactions; 1.4.1.1 C-C Bond Formation; 1.4.1.1.1 Natural Processes; 1.4.1.1.2 Artificial Processes; 1.4.1.2 N-C Bond Formation; 1.4.1.3 O-C Bond Formation; 1.4.1.3.1 Cyclic Carbonates; 1.4.1.3.2 Linear Carbonates; 1.4.1.4 Use of Urea as an Active-CO(2) Form; 1.4.1.5 Transesterification Reactions; 1.4.2 Reduction Reactions; 1.4.2.1 Energetics of the Reactions; 1.4.2.1.1 Natural Processes; 1.4.2.1.2 Artificial Processes; 1.4.2.1.3 Photoelectrochemical Reduction; 1.5 Conclusions; References 2 Nitrogen Monoxide and Nitrous Oxide Binding and Reduction2.1 Introduction; 2.2 NO; 2.2.1 Bonding and Structures of Metal Nitrosyls; 2.2.1.1 Heme Proteins: Guanylate Cyclase - NO Binding and Trans-bond Labilization; 2.2.1.2 Bridging (η(1)-μ(2)-) Complexes; 2.2.1.3 η(1)-μ(3)-NO Bridging Complexes; 2.2.1.4 η(2)-NO Bridging Complexes; 2.2.1.5 Isonitrosyl and Side-on η(2)-NO Complexes; 2.2.1.6 Side-on η(2)-NO Copper Protein Structures; 2.2.1.7 Spectroscopic Features of Nitrosyl Metal Complexes; 2.2.2 Chemical Reduction of NO and Related Chemistry; 2.2.2.1 Chemical Reduction of Metal-bound NO 2.2.2.1.1 Metal-NO Reduction Accompanied by N-O Cleavage2.2.2.2 Electrophilic Attack on Metal-bound NO:HNO (Nitroxyl) Complexes; 2.2.2.3 Electrocatalytic Reduction of NO; 2.2.2.4 Biological NO Reduction: NORs; 2.2.2.4.1 Bacterial NORs of the Heme Copper Oxidase (HCO) Type [54, 147]; 2.2.2.4.2 Models for NORs; 2.2.2.4.3 Fungal P450-type NORs; 2.2.2.4.4 Flavorubredoxins as Scavenging (S)-NORs; 2.2.2.5 Metal Complex-mediated NO Disproportionation; 2.3 N(2)O; 2.3.1 Structure and Bonding; 2.3.2 Metal-mediated N(2)O Reduction; 2.3.2.1 Oxo Transfer Reactions; 2.3.2.2 Catalytic Oxo Transfer 2.3.2.3 N(2)O N-N Bond Cleavage2.3.2.4 Electrocatalytic Reduction of N(2)O to N(2); 2.3.2.5 Biological N(2)O Reduction; 2.4 Summary and Conclusions; References; 3 Bio-organometallic Approaches to Nitrogen Fixation Chemistry; 3.1 Introduction - The N(2) Fixation Challenge; 3.2 Biological N(2) Reduction; 3.2.1 General Comments; 3.2.2 Structural Data; 3.2.3 Assigning the FeMoco Oxidation States; 3.3 Biomimetic Systems that Model Structure and Function; 3.3.1 General Comments; 3.3.2 Mononuclear Molybdenum Systems of Biomimetic Interest; 3.3.2.1 The Originally Proposed "Chatt Cycle" 3.3.2.2 An Electrocatalytic Reduction Cycle using Low-valent Tungsten |
| Record Nr. | UNINA-9910830157403321 |
| Weinheim, : Wiley-VCH, c2006 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Activation of small molecules : organometallic and bioinorganic perspectives / / edited by William B. Tolman
| Activation of small molecules : organometallic and bioinorganic perspectives / / edited by William B. Tolman |
| Pubbl/distr/stampa | Weinheim, : Wiley-VCH, c2006 |
| Descrizione fisica | 1 online resource (383 p.) |
| Disciplina | 541.22 |
| Altri autori (Persone) | TolmanWilliam B |
| Soggetto topico |
Molecules
Ions Inorganic compounds Inorganic compounds - Synthesis |
| ISBN |
1-280-72285-1
9786610722853 3-527-60935-0 3-527-60937-7 |
| Classificazione | 35.60 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Activation of Small Molecules; Contents; Preface; List of Contributors; 1 Carbon Dioxide Reduction and Uses as a Chemical Feedstock; 1.1 Introduction; 1.2 Properties of the CO(2) Molecule; 1.2.1 Molecular Geometry; 1.2.2 Spectroscopic Properties; 1.2.2.1 Vibrational; 1.2.2.2 UV-Vis; 1.2.2.3 (13)C-Nuclear Magnetic Resonance (NMR); 1.2.3 Energy Data and Reaction Kinetics Relevant to CO(2) Conversion; 1.3 CO(2) Coordination to Metal Centers and Reactivity of Coordinated CO(2); 1.3.1 Modes of Coordination; 1.3.2 Interaction of CO(2) with Metal Atoms at Low Temperature: Stability of the Adducts
1.3.3 Reactivity of CO(2) Coordinated to Transition Metal Systems1.4 CO(2) Conversion; 1.4.1 Carboxylation Reactions; 1.4.1.1 C-C Bond Formation; 1.4.1.1.1 Natural Processes; 1.4.1.1.2 Artificial Processes; 1.4.1.2 N-C Bond Formation; 1.4.1.3 O-C Bond Formation; 1.4.1.3.1 Cyclic Carbonates; 1.4.1.3.2 Linear Carbonates; 1.4.1.4 Use of Urea as an Active-CO(2) Form; 1.4.1.5 Transesterification Reactions; 1.4.2 Reduction Reactions; 1.4.2.1 Energetics of the Reactions; 1.4.2.1.1 Natural Processes; 1.4.2.1.2 Artificial Processes; 1.4.2.1.3 Photoelectrochemical Reduction; 1.5 Conclusions; References 2 Nitrogen Monoxide and Nitrous Oxide Binding and Reduction2.1 Introduction; 2.2 NO; 2.2.1 Bonding and Structures of Metal Nitrosyls; 2.2.1.1 Heme Proteins: Guanylate Cyclase - NO Binding and Trans-bond Labilization; 2.2.1.2 Bridging (η(1)-μ(2)-) Complexes; 2.2.1.3 η(1)-μ(3)-NO Bridging Complexes; 2.2.1.4 η(2)-NO Bridging Complexes; 2.2.1.5 Isonitrosyl and Side-on η(2)-NO Complexes; 2.2.1.6 Side-on η(2)-NO Copper Protein Structures; 2.2.1.7 Spectroscopic Features of Nitrosyl Metal Complexes; 2.2.2 Chemical Reduction of NO and Related Chemistry; 2.2.2.1 Chemical Reduction of Metal-bound NO 2.2.2.1.1 Metal-NO Reduction Accompanied by N-O Cleavage2.2.2.2 Electrophilic Attack on Metal-bound NO:HNO (Nitroxyl) Complexes; 2.2.2.3 Electrocatalytic Reduction of NO; 2.2.2.4 Biological NO Reduction: NORs; 2.2.2.4.1 Bacterial NORs of the Heme Copper Oxidase (HCO) Type [54, 147]; 2.2.2.4.2 Models for NORs; 2.2.2.4.3 Fungal P450-type NORs; 2.2.2.4.4 Flavorubredoxins as Scavenging (S)-NORs; 2.2.2.5 Metal Complex-mediated NO Disproportionation; 2.3 N(2)O; 2.3.1 Structure and Bonding; 2.3.2 Metal-mediated N(2)O Reduction; 2.3.2.1 Oxo Transfer Reactions; 2.3.2.2 Catalytic Oxo Transfer 2.3.2.3 N(2)O N-N Bond Cleavage2.3.2.4 Electrocatalytic Reduction of N(2)O to N(2); 2.3.2.5 Biological N(2)O Reduction; 2.4 Summary and Conclusions; References; 3 Bio-organometallic Approaches to Nitrogen Fixation Chemistry; 3.1 Introduction - The N(2) Fixation Challenge; 3.2 Biological N(2) Reduction; 3.2.1 General Comments; 3.2.2 Structural Data; 3.2.3 Assigning the FeMoco Oxidation States; 3.3 Biomimetic Systems that Model Structure and Function; 3.3.1 General Comments; 3.3.2 Mononuclear Molybdenum Systems of Biomimetic Interest; 3.3.2.1 The Originally Proposed "Chatt Cycle" 3.3.2.2 An Electrocatalytic Reduction Cycle using Low-valent Tungsten |
| Record Nr. | UNINA-9910876731103321 |
| Weinheim, : Wiley-VCH, c2006 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
AppliedChem
| AppliedChem |
| Pubbl/distr/stampa | Basel, Switzerland : , : MDPI |
| Descrizione fisica | 1 online resource |
| Disciplina | 500 |
| Soggetto topico |
Inorganic compounds
Organic compounds |
| ISSN | 2673-9623 |
| Formato | Materiale a stampa |
| Livello bibliografico | Periodico |
| Lingua di pubblicazione | eng |
| Record Nr. | UNINA-9910647268003321 |
| Basel, Switzerland : , : MDPI | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Atomic structure / / Goldhil Video (Firm)
| Atomic structure / / Goldhil Video (Firm) |
| Pubbl/distr/stampa | New York, N.Y., : Infobase, [2005], c2000 |
| Descrizione fisica | 1 streaming video file (27 min.) : sd., col., digital file |
| Collana | Chemistry: The Standard Deviants Core Curriculum |
| Soggetto topico |
Cell metabolism
Chemical elements Chemistry, Physical and theoretical Inorganic compounds Organic compounds |
| Soggetto genere / forma |
Educational films.
Internet videos. Videorecording |
| Formato | Videoregistrazioni  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto | Quantum Mechanics (2:28) -- Quantum Numbers (4:40) -- Electron Shells (2:55) -- Orbitals (4:19) -- Periodic Table and Orbitals (3:36) -- Writing Electron Configurations (4:14) -- Review of Atomic Structure (1:50) |
| Record Nr. | UNINA-9910596956403321 |
| New York, N.Y., : Infobase, [2005], c2000 | ||
| Videoregistrazioni | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Bio- and bioinspired nanomaterials / / edited by Daniel Ruiz-Molina, Fernando Novio, and Claudio Roscini
| Bio- and bioinspired nanomaterials / / edited by Daniel Ruiz-Molina, Fernando Novio, and Claudio Roscini |
| Pubbl/distr/stampa | Weinheim, Germany : , : Wiley-VCH, , 2015 |
| Descrizione fisica | 1 online resource (487 p.) |
| Disciplina | 572.51 |
| Soggetto topico |
Bioinorganic chemistry
Inorganic compounds Nanostructured materials |
| ISBN |
3-527-67584-1
3-527-67582-5 3-527-67585-X |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Bio- and Bioinspired Nanomaterials; Contents; List of Contributors; Foreword; Preface; Part I: Bionanomaterials; 1 Synthesis of Colloidal Gold and Silver Nanoparticles and their Properties; 1.1 Introduction; 1.2 Physical and Chemical Properties of Gold and Silver Nanoparticles; 1.2.1 Optical Properties of Gold and Silver Nanoparticles; 1.2.2 Electronic Properties of Gold and Silver Nanoparticles; 1.3 Synthesis of Gold and Silver Core Nanoparticles; 1.4 Transfer to Aqueous Media of Gold and Silver Nanoparticles from Organic Solvents; 1.5 Some Applications of Gold and Silver Nanoparticles
AcknowledgmentsReferences; 2 Ceramic Smart Drug Delivery Nanomaterials; 2.1 Introduction; 2.2 Biodistribution, Toxicity, and Excretion of Nanoparticles; 2.3 Mesoporous Silica Nanoparticles; 2.4 Calcium Phosphate Nanoparticles; 2.5 Carbon Allotropes; 2.6 Iron Oxide Nanoparticles; References; 3 Polymersomes and their Biological Implications; 3.1 Introduction; 3.2 Self-Assembly of Amphiphiles; 3.3 Polymersome - The Synthetic Analog of a Liposome; 3.3.1 Polymersome Preparation Methods; 3.3.1.1 Batch Methods; 3.3.1.2 Continuous Flow Methods; 3.3.2 Characterization of Polymersomes 3.4 Polymersomes as Drug Delivery Devices3.4.1 Tuning Membrane Properties and Controlling the Release; 3.4.1.1 pH-Responsive Polymersomes; 3.4.1.2 Hydrolysis of Polymersomes Built from Biodegradable Polymers; 3.4.1.3 GSH-Responsive (Redox) Vesicles; 3.4.1.4 Temperature-Responsive Polymers; 3.4.1.5 Magnetic Release; 3.4.2 Surface Functionalization and Targeting Strategies; 3.5 Embedding Channel Proteins in Artificial Polymer Membranes and Creating New Applications; 3.6 Conclusions and Outlook; List of Abbreviations; References; 4 MOFs in Pharmaceutical Technology; 4.1 Introduction 4.2 Metal-Organic Frameworks4.2.1 Description; 4.2.2 Synthesis, Formulation, and Functionalization/Shaping; 4.2.2.1 Synthesis and Formulation/Shaping; 4.2.2.2 Functionalization; 4.2.3 Stability and Toxicity; 4.3 MOFs for Therapeutics; 4.3.1 BioMOFs; 4.3.2 Active Ingredient Adsorption and Release from MOFs; 4.3.2.1 Drugs; 4.3.2.2 Cosmetics; 4.3.3 Understanding; 4.3.3.1 Encapsulation; 4.3.3.2 Release; 4.3.4 Theranostics; 4.3.5 Efficacy; 4.4 Conclusions; List of Abbreviations; References; 5 Amorphous Coordination Polymer Particles for Biomedicine; 5.1 Introduction 5.2 Interaction of Nanoplatforms with the Biological Environment5.3 CPPs as Realistic Alternative to Classical Nanosystems; 5.3.1 Encapsulation Systems Based on CPPs; 5.3.2 Active Metal-Organic Units; 5.3.2.1 Active Metal Ions; 5.3.2.2 Drugs as Bridging Ligands; 5.3.2.3 Active Complexes; 5.3.3 Smart Delivery Systems; 5.3.4 Bioimaging; 5.3.5 Biocompatibility of CPPs; 5.4 Conclusion and Future Challenges; References; 6 Magnetic Nanoparticles for Magnetic Hyperthermia and Controlled Drug Delivery; 6.1 Introduction; 6.2 Principles of Magnetically Induced Heat Generation 6.3 Synthesis of MNPs and their Heat Performance |
| Record Nr. | UNINA-9910139146803321 |
| Weinheim, Germany : , : Wiley-VCH, , 2015 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Bio- and bioinspired nanomaterials / / edited by Daniel Ruiz-Molina, Fernando Novio, and Claudio Roscini
| Bio- and bioinspired nanomaterials / / edited by Daniel Ruiz-Molina, Fernando Novio, and Claudio Roscini |
| Pubbl/distr/stampa | Weinheim, Germany : , : Wiley-VCH, , 2015 |
| Descrizione fisica | 1 online resource (487 p.) |
| Disciplina | 572.51 |
| Soggetto topico |
Bioinorganic chemistry
Inorganic compounds Nanostructured materials |
| ISBN |
3-527-67584-1
3-527-67582-5 3-527-67585-X |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Bio- and Bioinspired Nanomaterials; Contents; List of Contributors; Foreword; Preface; Part I: Bionanomaterials; 1 Synthesis of Colloidal Gold and Silver Nanoparticles and their Properties; 1.1 Introduction; 1.2 Physical and Chemical Properties of Gold and Silver Nanoparticles; 1.2.1 Optical Properties of Gold and Silver Nanoparticles; 1.2.2 Electronic Properties of Gold and Silver Nanoparticles; 1.3 Synthesis of Gold and Silver Core Nanoparticles; 1.4 Transfer to Aqueous Media of Gold and Silver Nanoparticles from Organic Solvents; 1.5 Some Applications of Gold and Silver Nanoparticles
AcknowledgmentsReferences; 2 Ceramic Smart Drug Delivery Nanomaterials; 2.1 Introduction; 2.2 Biodistribution, Toxicity, and Excretion of Nanoparticles; 2.3 Mesoporous Silica Nanoparticles; 2.4 Calcium Phosphate Nanoparticles; 2.5 Carbon Allotropes; 2.6 Iron Oxide Nanoparticles; References; 3 Polymersomes and their Biological Implications; 3.1 Introduction; 3.2 Self-Assembly of Amphiphiles; 3.3 Polymersome - The Synthetic Analog of a Liposome; 3.3.1 Polymersome Preparation Methods; 3.3.1.1 Batch Methods; 3.3.1.2 Continuous Flow Methods; 3.3.2 Characterization of Polymersomes 3.4 Polymersomes as Drug Delivery Devices3.4.1 Tuning Membrane Properties and Controlling the Release; 3.4.1.1 pH-Responsive Polymersomes; 3.4.1.2 Hydrolysis of Polymersomes Built from Biodegradable Polymers; 3.4.1.3 GSH-Responsive (Redox) Vesicles; 3.4.1.4 Temperature-Responsive Polymers; 3.4.1.5 Magnetic Release; 3.4.2 Surface Functionalization and Targeting Strategies; 3.5 Embedding Channel Proteins in Artificial Polymer Membranes and Creating New Applications; 3.6 Conclusions and Outlook; List of Abbreviations; References; 4 MOFs in Pharmaceutical Technology; 4.1 Introduction 4.2 Metal-Organic Frameworks4.2.1 Description; 4.2.2 Synthesis, Formulation, and Functionalization/Shaping; 4.2.2.1 Synthesis and Formulation/Shaping; 4.2.2.2 Functionalization; 4.2.3 Stability and Toxicity; 4.3 MOFs for Therapeutics; 4.3.1 BioMOFs; 4.3.2 Active Ingredient Adsorption and Release from MOFs; 4.3.2.1 Drugs; 4.3.2.2 Cosmetics; 4.3.3 Understanding; 4.3.3.1 Encapsulation; 4.3.3.2 Release; 4.3.4 Theranostics; 4.3.5 Efficacy; 4.4 Conclusions; List of Abbreviations; References; 5 Amorphous Coordination Polymer Particles for Biomedicine; 5.1 Introduction 5.2 Interaction of Nanoplatforms with the Biological Environment5.3 CPPs as Realistic Alternative to Classical Nanosystems; 5.3.1 Encapsulation Systems Based on CPPs; 5.3.2 Active Metal-Organic Units; 5.3.2.1 Active Metal Ions; 5.3.2.2 Drugs as Bridging Ligands; 5.3.2.3 Active Complexes; 5.3.3 Smart Delivery Systems; 5.3.4 Bioimaging; 5.3.5 Biocompatibility of CPPs; 5.4 Conclusion and Future Challenges; References; 6 Magnetic Nanoparticles for Magnetic Hyperthermia and Controlled Drug Delivery; 6.1 Introduction; 6.2 Principles of Magnetically Induced Heat Generation 6.3 Synthesis of MNPs and their Heat Performance |
| Record Nr. | UNINA-9910816401303321 |
| Weinheim, Germany : , : Wiley-VCH, , 2015 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
