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Boron hydrides, high potential hydrogen storage materials [[electronic resource] /] / Umit B. Demirci and Philippe Miele, editors
Boron hydrides, high potential hydrogen storage materials [[electronic resource] /] / Umit B. Demirci and Philippe Miele, editors
Pubbl/distr/stampa New York, : Nova Science Publishers, c2011
Descrizione fisica 1 online resource (276 p.)
Disciplina 665.8/1
Altri autori (Persone) DemirciUmit B
MielePhilippe
Collana Chemistry research and applications
Soggetto topico Hydrogen - Storage - Materials
Boranes
Soggetto genere / forma Electronic books.
ISBN 1-61470-326-4
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Record Nr. UNINA-9910457672303321
New York, : Nova Science Publishers, c2011
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Boron hydrides, high potential hydrogen storage materials [[electronic resource] /] / Umit B. Demirci and Philippe Miele, editors
Boron hydrides, high potential hydrogen storage materials [[electronic resource] /] / Umit B. Demirci and Philippe Miele, editors
Pubbl/distr/stampa New York, : Nova Science Publishers, c2011
Descrizione fisica 1 online resource (276 p.)
Disciplina 665.8/1
Altri autori (Persone) DemirciUmit B
MielePhilippe
Collana Chemistry research and applications
Soggetto topico Hydrogen - Storage - Materials
Boranes
ISBN 1-61470-326-4
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Record Nr. UNINA-9910781854603321
New York, : Nova Science Publishers, c2011
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Boron hydrides, high potential hydrogen storage materials [[electronic resource] /] / Umit B. Demirci and Philippe Miele, editors
Boron hydrides, high potential hydrogen storage materials [[electronic resource] /] / Umit B. Demirci and Philippe Miele, editors
Edizione [1st ed.]
Pubbl/distr/stampa New York, : Nova Science Publishers, c2011
Descrizione fisica 1 online resource (276 p.)
Disciplina 665.8/1
Altri autori (Persone) DemirciUmit B
MielePhilippe
Collana Chemistry research and applications
Soggetto topico Hydrogen - Storage - Materials
Boranes
ISBN 1-61470-326-4
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Intro -- BORON HYDRIDES, HIGH POTENTIAL HYDROGEN STORAGE MATERIALS -- BORON HYDRIDES, HIGH POTENTIAL HYDROGEN STORAGE MATERIALS -- CONTENTS -- PREFACE -- Chapter 1 SOLID-STATE HYDROGEN STORAGE -- Abstract -- Introduction -- 2. Issues Encountering Hydrogen Economy -- 3. Hydrogen Storage Issue -- 3.1 Technical Targets -- 3.2 Physical Methods for Hydrogen Storage -- 3.2.1 High Pressure Storage -- 3.2.2 Cryogenic Storage -- 3.3 Chemical Methods for Hydrogen Storage -- 4. Solids for Hydrogen Storage or Chemical Storage -- 4.1 Adsorption in Porous Materials -- 4.1.1 Activated Carbons including Carbon Nanostructures -- 4.1.2 Hydrogen Physisorption in other Materials -- 4.2 Storage by Absorption -- 4.2.1 Metal Hydrides -- 4.2.2 Complex Hydrides -- 4.2.3 Storage via Chemical Reactions -- Conclusion -- References -- Chapter 2 BORON HYDRIDES -- Abstract -- 1. Introduction -- 2. Boron Compounds -- 2.1 Borides -- 2.2 Boron Hydrides -- 2.3 Boron Halides -- 2.4 Boron-Oxygen Compounds -- 2.5 Boron-Nitrogen Compounds -- 2.6 Other Boron-Based Compounds -- 2.7 Summary -- 3. Borohydrides -- 3.1 All of the Borohydrides -- 3.2 Thermolysis of Borohydrides -- 3.3 Hydrolysis of Borohydrides -- 3.4 Safety Data -- 3.5 Conclusion -- 4. Ammoniaborane and its Derivatives -- 4.1 Ammoniaborane -- 4.2 Amidoboranes -- 4.3 Safety Data -- Conclusion -- References -- Chapter 3 LITHIUM BOROHYDRIDE: SYNTHESIS, PROPERTIES AND THERMAL DECOMPOSITION -- Abstract -- 1. Introduction -- 2. Synthesis Methods -- 3. Crystal Structures -- 4. Ionic Superconduction -- 5. Thermal Decomposition -- 6. Hydrogen Release Enhancement by Catalysts Addition -- 7. Modification of Hydrogen Release by Confinement into Nanoporous Carbons -- Conclusions -- Acknowledgments -- References -- Chapter 4 HYDROGEN CYCLE WITH SODIUM BOROHYDRIDE -- Abstract -- 1. Importance of Sodium Borohydride in Hydrogen Cycle.
2. Sodium Borohydride Production Techniques -- 2.1. Borax Reactions -- 2.2. Trimetyl Borate Reactions -- 2.3. NaBH4 Reactions -- 3. Dehydrogenation of NaBH4 and its usage as Hydrogen Carrier -- 3.1. Thermal Dehydrogenation -- 3.2. Catalytic Dehydrogenation -- 3.2.1. Alkaline Hydrolysis Solution -- 3.2.2. Water Requirement for Hydrolysis -- 3.2.3. Catalyst Preparation and its Effect on Hydrolysis -- 3.2.4. Supported Materials of Heterogeneous Catalysts -- 3.2.5. Processing Magnetic Catalysts -- 3.2.6. Co-Ni Couple Catalysts and Reaction Mechanism -- 3.2.7. Electrochemical Catalysts -- 3.2.8. Fuel Cell Application of Catalytic Hydrolysis -- 4. NaBO2 Recycle -- 5. NaBO2-Borax Conversion -- 6. Characterization of NaBH4 -- Conclusion -- References -- Chapter 5 POTENTIAL AND LIMITATION OF THE DIRECT BOROHYDRIDE FUEL CELL. SPECIAL EMPHASIS ON THE BOROHYDRIDE OXIDATION REACTION (BOR) MECHANISM AND KINETICS ON GOLD ELECTROCATALYSTS -- Abstract -- 1. Introduction -- 2. Experimental -- 2.1 Reagents and Solutions -- 2.2 On-Line Electrochemical Mass Spectroscopy (OLEMSlems) -- 2.3 Ftir FTIR Spectroscopy -- 2.4 CV and EIS -- 3. The Ideal Reactant for DBFC -- 3.1 Fuel Composition for DBFC -- 3.2 Alternative Reactants -- 3.3 Fuel Monitoring -- 4. Principle of Operation of a DBFC -- 4.1 Basics and Performance -- 4.2 Influence of the Electrode Geometry and Reactant Channel Design -- 4.3 Membrane and Electrode Materials -- 5. Survey of the BOR on Gold -- 5.1 Is Gold Inactive Regarding the Heterogeneous Hydrolysis of BH4- Aanion? -- 5.2 Evidencing the BOR Intermediates on Gold by FTIR Spectroscopy -- 5.3 Towards a Simplified BOR Pathway for Gold Electrodes -- Conclusion -- Acknowledgments -- References -- Chapter 6 CRYSTAL CHEMISTRY OF LIGHT METAL BOROHYDRIDES -- Abstract -- Introduction -- Crystal Structures -- LiBH4 -- NaBH4 -- KBH4 -- NH4BH4 -- Be(BH4)2 -- Mg(BH4)2.
Ca(BH4)2 -- Mn(BH4)2 -- Al(BH4)3 -- LiK(BH4)2 -- MSc(BH4)4 (M = Li, Na) -- MZn2(BH4)5 (M = Li, Na) -- NaZn(BH4)3 -- Structural Evolution under Non-Ambient Conditions -- Diffraction Studies of the Stability Regions and Structure Evolution under External Stimuli -- Phenomenological and Crystal-Chemical Analysis of the Mechanisms of the Phase Transitions -- Crystal Chemistry -- Geometry of the BH4 Group -- BH4…M and BH4…BH4 Contacts -- Chemical Destabilization: Mixed-Cation and Mixed-Anion Borohydrides -- Chemical Destabilization: Substitution in the BH4 Group -- References -- Chapter 7 AMMONIA BORANE: THERMOLYSIS -- Abstract -- 1. Introduction -- 2. Ammonia Borane -- 3. Solid Neat Ammonia Borane Thermolysis -- 3.1 The Induction Period -- 3.2 The First Reaction Step -- 3.3 The Second Reaction Step -- 3.4 The Third Reaction Step -- 4. Thermolysis of Neat Ammonia Borane in Solution -- 5. Catalyzed Ammonia Borane Thermolysis -- 5.1 Catalyzed Solid State Ammonia Borane -- 5.2 Catalyzed Ammonia Borane in Solution -- 6. Ammonia Borane Compounds Thermolysis -- 6.1 Solid State Ammonia Borane Compounds Thermolysis -- 7. Supported Ammonia Borane Thermolysis -- 8. Regeneration of Ammonia Borane Dehydrogenation Products -- Conclusion -- References -- Chapter 8 AMMONIA BORANE: HYDROLYSIS AND ELECTROOXIDATION -- Abstract -- 1. Introduction -- 2. Ammonia Borane Hydrolysis -- 2.1 Concept -- 2.2 State-of-the-Art -- 2.2.1 Transition Metal Catalyst -- 2.2.2 Effective Gravimetric Hydrogen Storage Capacity -- 2.2.3 Recycling of the Reaction by-Products -- 2.3 Ammonia Borane versus Sodium Borohydride -- 3. Ammonia Borane Electrooxidation -- 3.1 Direct Liquid Fuel Cells -- 3.2 Basics -- 3.3 State-of-the-art and Issues -- 3.4 Direct Ammonia Borane Fuel Cell Vversus Direct Borohydride Ffuel Cell -- Conclusion -- References -- Chapter 9 METAL AMIDOBORANES -- Abstract.
Introduction -- Syntheses -- Structures and Crystal Chemistry -- 1. Metal Amidoboranes -- 2. Other Amidoborane Complexes -- Dehydrogenation Properties -- 1. Lithium Amidoborane -- 2. Sodium Amidoborane -- 3. Calcium Amidoborane -- 4. Structural Characteristics Responsible for the Dehydrogenation Properties -- 5. Other Amidoborane Complexes -- Conclusions -- Acknowledgment -- References -- Chapter 10 CONCLUSION AND OUTLOOK: WHICH FUTURE FOR BORON HYDRIDES? -- Abstract -- 1. Introduction -- 2. Current Potentials of the Boron Hydrides -- 2.1 Borohydrides -- 2.2 Ammonia Borane and Amidoboranes -- 2.3 Summary -- 3. Always the same Challenges -- 3.1 Hydrogen Production and Distribution -- 3.2 Hydrogen Storage -- 3.3 Summary -- 4. The Most Critical Challenges Facing Boron Hydrides -- 4.1 Effective Storage Capacity -- 4.2 Storage Reversibility -- 4.3 Summary -- 5. Greenness Considerations -- 5.1 Green Chemistry -- 5.2 Greenness of the Boron Hydrides -- 5.3 Summary -- Conclusion and Outlook -- References -- INDEX -- Blank Page.
Record Nr. UNINA-9910827129103321
New York, : Nova Science Publishers, c2011
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Handbook of hydrogen storage [[electronic resource] ] : new materials for future energy storage / / edited by Michael Hirscher
Handbook of hydrogen storage [[electronic resource] ] : new materials for future energy storage / / edited by Michael Hirscher
Pubbl/distr/stampa Weinheim, : Wiley-VCH Verlag GmbH & Co., c2010
Descrizione fisica 1 online resource (375 p.)
Disciplina 665.81
665.81 22
Altri autori (Persone) HirscherMichael
Soggetto topico Hydrogen - Storage - Materials
Energy storage
Soggetto genere / forma Electronic books.
ISBN 3-527-62980-7
1-282-54928-6
9786612549281
3-527-62981-5
Classificazione 540
ERG 770b
VE 9850
ZP 4150
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Handbook of Hydrogen Storage: New Materials for Future Energy Storage; Foreword; Contents; Preface; List of Contributors; 1 Storage of Hydrogen in the Pure Form; 1.1 Introduction; 1.2 Thermodynamic State and Properties; 1.2.1 Variables of State; 1.2.2 T-s-Diagram; 1.2.2.1 Joule-Thomson Coefficient; 1.2.3 Properties; 1.3 Gaseous Storage; 1.3.1 Compression and Expansion; 1.3.2 Tank Systems; 1.3.3 High Pressure Infrastructure; 1.4 Liquid Storage; 1.4.1 Liquefaction; 1.4.2 Thermodynamic Analysis; 1.4.2.1 Pressure Build-Up; 1.4.2.2 Boil-Off; 1.4.2.3 Cooling and Filling; 1.4.2.4 Back-Gas
1.4.3 Tank Systems1.4.4 Distribution Facilities; 1.5 Hybrid Storage; 1.5.1 Supercritical Storage; 1.5.2 Hydrogen Slush; 1.6 Comparison of Energy Densities; 1.7 Conclusion; References; 2 Physisorption in Porous Materials; 2.1 Introduction; 2.2 Carbon Materials; 2.3 Organic Polymers; 2.4 Zeolites; 2.5 Coordination Polymers; 2.6 Conclusions; References; 3 Clathrate Hydrates; 3.1 Introduction; 3.2 Clathrate Hydrate Structures; 3.3 Hydrogen Clathrate Hydrate; 3.4 Kinetic Aspects of Hydrogen Clathrate Hydrate; 3.5 Modeling of Hydrogen Clathrate Hydrates; 3.6 Future of Hydrogen Storage; References
4 Metal Hydrides4.1 Introduction; 4.2 Elemental Hydrides; 4.2.1 Ionic or Saline Hydrides; 4.2.2 Covalent Hydrides; 4.2.3 Metallic Hydrides; 4.3 Thermodynamics of Metal Hydrides; 4.3.1 Introduction; 4.3.2 Low Concentration; 4.3.3 High Concentration; 4.4 Intermetallic Compounds; 4.4.1 Thermodynamics; 4.4.1.1 Miedema's Model; 4.4.1.2 Semi-Empirical Band Structure Model; 4.4.2 Crystal Structure; 4.4.3 Electronic Structure; 4.5 Practical Considerations; 4.5.1 Synthesis; 4.5.2 Activation; 4.5.3 Hysteresis; 4.5.4 Plateau Slope; 4.5.5 Reversible Capacity; 4.5.6 Hydrogenation Kinetics
4.5.7 Cycle Life4.5.8 Decrepitation; 4.6 Metal Hydrides Systems; 4.6.1 AB5; 4.6.2 TiFe; 4.6.3 AB2 Laves Phases; 4.6.4 BCC Solid Solution; 4.7 Nanocrystalline Mg and Mg-Based Alloys; 4.7.1 Hydrogen Sorption Kinetics; 4.7.2 Reduction of the Heat of Formation; 4.7.3 Severe Plastic Deformation Techniques; 4.8 Conclusion; 4.8.1 Alloys Development; 4.8.2 Synthesis; 4.8.3 System Engineering; References; 5 Complex Hydrides; 5.1 Introduction; 5.2 Complex Borohydrides; 5.2.1 Introduction; 5.2.2 Stability of Metal Borohydrides; 5.2.3 Decomposition of Complex Borohydrides
5.2.4 Lithium Borohydride, LiBH45.2.4.1 Synthesis and Crystal Structure; 5.2.4.2 Decomposition of LiBH4; 5.2.5 Sodium Borohydride, NaBH4; 5.2.5.1 Synthesis and Crystal Structure; 5.2.5.2 Decomposition of NaBH4; 5.2.6 Potassium Borohydride KBH4; 5.2.7 Beryllium Borohydride Be(BH4)2; 5.2.8 Magnesium Borohydride Mg(BH4)2; 5.2.8.1 Synthesis and Crystal Structure; 5.2.8.2 Decomposition; 5.2.9 Calcium Borohydride Ca(BH4)2; 5.2.9.1 Synthesis and Crystal Structure; 5.2.9.2 Decomposition; 5.2.10 Aluminum Borohydride Al(BH4)3; 5.2.10.1 Synthesis and Crystal Structure; 5.2.10.2 Decomposition
5.2.11 Zinc Borohydride Zn(BH4)2
Record Nr. UNINA-9910140615203321
Weinheim, : Wiley-VCH Verlag GmbH & Co., c2010
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Handbook of hydrogen storage [[electronic resource] ] : new materials for future energy storage / / edited by Michael Hirscher
Handbook of hydrogen storage [[electronic resource] ] : new materials for future energy storage / / edited by Michael Hirscher
Pubbl/distr/stampa Weinheim, : Wiley-VCH Verlag GmbH & Co., c2010
Descrizione fisica 1 online resource (375 p.)
Disciplina 665.81
665.81 22
Altri autori (Persone) HirscherMichael
Soggetto topico Hydrogen - Storage - Materials
Energy storage
ISBN 3-527-62980-7
1-282-54928-6
9786612549281
3-527-62981-5
Classificazione 540
ERG 770b
VE 9850
ZP 4150
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Handbook of Hydrogen Storage: New Materials for Future Energy Storage; Foreword; Contents; Preface; List of Contributors; 1 Storage of Hydrogen in the Pure Form; 1.1 Introduction; 1.2 Thermodynamic State and Properties; 1.2.1 Variables of State; 1.2.2 T-s-Diagram; 1.2.2.1 Joule-Thomson Coefficient; 1.2.3 Properties; 1.3 Gaseous Storage; 1.3.1 Compression and Expansion; 1.3.2 Tank Systems; 1.3.3 High Pressure Infrastructure; 1.4 Liquid Storage; 1.4.1 Liquefaction; 1.4.2 Thermodynamic Analysis; 1.4.2.1 Pressure Build-Up; 1.4.2.2 Boil-Off; 1.4.2.3 Cooling and Filling; 1.4.2.4 Back-Gas
1.4.3 Tank Systems1.4.4 Distribution Facilities; 1.5 Hybrid Storage; 1.5.1 Supercritical Storage; 1.5.2 Hydrogen Slush; 1.6 Comparison of Energy Densities; 1.7 Conclusion; References; 2 Physisorption in Porous Materials; 2.1 Introduction; 2.2 Carbon Materials; 2.3 Organic Polymers; 2.4 Zeolites; 2.5 Coordination Polymers; 2.6 Conclusions; References; 3 Clathrate Hydrates; 3.1 Introduction; 3.2 Clathrate Hydrate Structures; 3.3 Hydrogen Clathrate Hydrate; 3.4 Kinetic Aspects of Hydrogen Clathrate Hydrate; 3.5 Modeling of Hydrogen Clathrate Hydrates; 3.6 Future of Hydrogen Storage; References
4 Metal Hydrides4.1 Introduction; 4.2 Elemental Hydrides; 4.2.1 Ionic or Saline Hydrides; 4.2.2 Covalent Hydrides; 4.2.3 Metallic Hydrides; 4.3 Thermodynamics of Metal Hydrides; 4.3.1 Introduction; 4.3.2 Low Concentration; 4.3.3 High Concentration; 4.4 Intermetallic Compounds; 4.4.1 Thermodynamics; 4.4.1.1 Miedema's Model; 4.4.1.2 Semi-Empirical Band Structure Model; 4.4.2 Crystal Structure; 4.4.3 Electronic Structure; 4.5 Practical Considerations; 4.5.1 Synthesis; 4.5.2 Activation; 4.5.3 Hysteresis; 4.5.4 Plateau Slope; 4.5.5 Reversible Capacity; 4.5.6 Hydrogenation Kinetics
4.5.7 Cycle Life4.5.8 Decrepitation; 4.6 Metal Hydrides Systems; 4.6.1 AB5; 4.6.2 TiFe; 4.6.3 AB2 Laves Phases; 4.6.4 BCC Solid Solution; 4.7 Nanocrystalline Mg and Mg-Based Alloys; 4.7.1 Hydrogen Sorption Kinetics; 4.7.2 Reduction of the Heat of Formation; 4.7.3 Severe Plastic Deformation Techniques; 4.8 Conclusion; 4.8.1 Alloys Development; 4.8.2 Synthesis; 4.8.3 System Engineering; References; 5 Complex Hydrides; 5.1 Introduction; 5.2 Complex Borohydrides; 5.2.1 Introduction; 5.2.2 Stability of Metal Borohydrides; 5.2.3 Decomposition of Complex Borohydrides
5.2.4 Lithium Borohydride, LiBH45.2.4.1 Synthesis and Crystal Structure; 5.2.4.2 Decomposition of LiBH4; 5.2.5 Sodium Borohydride, NaBH4; 5.2.5.1 Synthesis and Crystal Structure; 5.2.5.2 Decomposition of NaBH4; 5.2.6 Potassium Borohydride KBH4; 5.2.7 Beryllium Borohydride Be(BH4)2; 5.2.8 Magnesium Borohydride Mg(BH4)2; 5.2.8.1 Synthesis and Crystal Structure; 5.2.8.2 Decomposition; 5.2.9 Calcium Borohydride Ca(BH4)2; 5.2.9.1 Synthesis and Crystal Structure; 5.2.9.2 Decomposition; 5.2.10 Aluminum Borohydride Al(BH4)3; 5.2.10.1 Synthesis and Crystal Structure; 5.2.10.2 Decomposition
5.2.11 Zinc Borohydride Zn(BH4)2
Record Nr. UNINA-9910830554603321
Weinheim, : Wiley-VCH Verlag GmbH & Co., c2010
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Handbook of hydrogen storage : new materials for future energy storage / / edited by Michael Hirscher
Handbook of hydrogen storage : new materials for future energy storage / / edited by Michael Hirscher
Pubbl/distr/stampa Weinheim, : Wiley-VCH Verlag GmbH & Co., c2010
Descrizione fisica 1 online resource (375 p.)
Disciplina 665.81
665.81 22
Altri autori (Persone) HirscherMichael
Soggetto topico Hydrogen - Storage - Materials
Energy storage
ISBN 3-527-62980-7
1-282-54928-6
9786612549281
3-527-62981-5
Classificazione 540
ERG 770b
VE 9850
ZP 4150
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Handbook of Hydrogen Storage: New Materials for Future Energy Storage; Foreword; Contents; Preface; List of Contributors; 1 Storage of Hydrogen in the Pure Form; 1.1 Introduction; 1.2 Thermodynamic State and Properties; 1.2.1 Variables of State; 1.2.2 T-s-Diagram; 1.2.2.1 Joule-Thomson Coefficient; 1.2.3 Properties; 1.3 Gaseous Storage; 1.3.1 Compression and Expansion; 1.3.2 Tank Systems; 1.3.3 High Pressure Infrastructure; 1.4 Liquid Storage; 1.4.1 Liquefaction; 1.4.2 Thermodynamic Analysis; 1.4.2.1 Pressure Build-Up; 1.4.2.2 Boil-Off; 1.4.2.3 Cooling and Filling; 1.4.2.4 Back-Gas
1.4.3 Tank Systems1.4.4 Distribution Facilities; 1.5 Hybrid Storage; 1.5.1 Supercritical Storage; 1.5.2 Hydrogen Slush; 1.6 Comparison of Energy Densities; 1.7 Conclusion; References; 2 Physisorption in Porous Materials; 2.1 Introduction; 2.2 Carbon Materials; 2.3 Organic Polymers; 2.4 Zeolites; 2.5 Coordination Polymers; 2.6 Conclusions; References; 3 Clathrate Hydrates; 3.1 Introduction; 3.2 Clathrate Hydrate Structures; 3.3 Hydrogen Clathrate Hydrate; 3.4 Kinetic Aspects of Hydrogen Clathrate Hydrate; 3.5 Modeling of Hydrogen Clathrate Hydrates; 3.6 Future of Hydrogen Storage; References
4 Metal Hydrides4.1 Introduction; 4.2 Elemental Hydrides; 4.2.1 Ionic or Saline Hydrides; 4.2.2 Covalent Hydrides; 4.2.3 Metallic Hydrides; 4.3 Thermodynamics of Metal Hydrides; 4.3.1 Introduction; 4.3.2 Low Concentration; 4.3.3 High Concentration; 4.4 Intermetallic Compounds; 4.4.1 Thermodynamics; 4.4.1.1 Miedema's Model; 4.4.1.2 Semi-Empirical Band Structure Model; 4.4.2 Crystal Structure; 4.4.3 Electronic Structure; 4.5 Practical Considerations; 4.5.1 Synthesis; 4.5.2 Activation; 4.5.3 Hysteresis; 4.5.4 Plateau Slope; 4.5.5 Reversible Capacity; 4.5.6 Hydrogenation Kinetics
4.5.7 Cycle Life4.5.8 Decrepitation; 4.6 Metal Hydrides Systems; 4.6.1 AB5; 4.6.2 TiFe; 4.6.3 AB2 Laves Phases; 4.6.4 BCC Solid Solution; 4.7 Nanocrystalline Mg and Mg-Based Alloys; 4.7.1 Hydrogen Sorption Kinetics; 4.7.2 Reduction of the Heat of Formation; 4.7.3 Severe Plastic Deformation Techniques; 4.8 Conclusion; 4.8.1 Alloys Development; 4.8.2 Synthesis; 4.8.3 System Engineering; References; 5 Complex Hydrides; 5.1 Introduction; 5.2 Complex Borohydrides; 5.2.1 Introduction; 5.2.2 Stability of Metal Borohydrides; 5.2.3 Decomposition of Complex Borohydrides
5.2.4 Lithium Borohydride, LiBH45.2.4.1 Synthesis and Crystal Structure; 5.2.4.2 Decomposition of LiBH4; 5.2.5 Sodium Borohydride, NaBH4; 5.2.5.1 Synthesis and Crystal Structure; 5.2.5.2 Decomposition of NaBH4; 5.2.6 Potassium Borohydride KBH4; 5.2.7 Beryllium Borohydride Be(BH4)2; 5.2.8 Magnesium Borohydride Mg(BH4)2; 5.2.8.1 Synthesis and Crystal Structure; 5.2.8.2 Decomposition; 5.2.9 Calcium Borohydride Ca(BH4)2; 5.2.9.1 Synthesis and Crystal Structure; 5.2.9.2 Decomposition; 5.2.10 Aluminum Borohydride Al(BH4)3; 5.2.10.1 Synthesis and Crystal Structure; 5.2.10.2 Decomposition
5.2.11 Zinc Borohydride Zn(BH4)2
Record Nr. UNINA-9910877379003321
Weinheim, : Wiley-VCH Verlag GmbH & Co., c2010
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui