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Chemical synthesis using supercritical fluids [[electronic resource] /] / edited by Philip G. Jessop and Walter Leitner
| Chemical synthesis using supercritical fluids [[electronic resource] /] / edited by Philip G. Jessop and Walter Leitner |
| Pubbl/distr/stampa | Weinheim ; ; New York, : Wiley-VCH, c1999 |
| Descrizione fisica | 1 online resource (503 p.) |
| Disciplina |
541.3
541.39 |
| Altri autori (Persone) |
JessopPhilip G
LeitnerWalter |
| Soggetto topico |
High pressure chemistry
Organic compounds - Synthesis Supercritical fluids |
| Soggetto genere / forma | Electronic books. |
| ISBN |
1-281-76423-X
9786611764234 3-527-61368-4 3-527-61369-2 |
| Formato | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Chemical Synthesis Using Supercritical Fluids; Preface; Contents; Contents; List of Contributors; 1 Introduction; 1.1 Supercritical Fluids as Media for Chemical Reactions; 1.1.1 What is a Supercritical Fluid (SCF)?; 1.1.2 Practical Aspects of Reactions in Supercritical Fluids (SFRs); 1.1.3 Motivation for Use of SCFs in Modern Chemical Synthesis; 1.1.4 A Brief History of Chemical Synthesis in SCFs; 1.1.4.1 Discovery of SCFs and their Use as Solvents; 1.1.4.2 Early Examples of Chemical Reactions in SCFs; 1.1.4.3 Industrial Use of SCFs as Reaction Media; References
1.2 Phase Behavior and Solubility1.2.1 Basic Physical Properties of Supercritical Fluids; 1.2.2 Phase Behavior in High Pressure Systems; 1.2.2.1 Types of Binary Phase Diagrams; 1.2.2.2 Asymmetric Binary Mixtures; 1.2.3 Factors Affecting Solubility in Supercritical Fluids; 1.2.3.1 SCF Solvent; 1.2.3.2 Chemical Functionality of the Solute; 1.2.3.3 Temperature and Pressure Effects; References; 1.3 Physical Properties as Related to Chemical Reactions; 1.3.1 Behavior of Diffusion Coefficients; 1.3.2 Diffusional Effects on Reactions; 1.3.3 Transition-state Theory Applied to SCFs 1.3.4 Density Dependence of Two Competing Reactions1.3.5 Solvation Effects on Reactions; 1.3.6 Conclusions; References; 2 Experimental Techniques; 2.1 High-pressure Reaction Equipment Design; 2.1.1 Introduction; 2.1.2 Basic Equipment and Components; 2.1.2.1 Design of Thick-Walled Vessels; 2.1.2.2 Closures and Connectors; 2.1.2.3 Tubing and Fittings; 2.1.2.4 Valves; 2.1.2.5 Compressors and Pumps; 2.1.2.6 Stirring and Mixing; 2.1.2.7 Optical Windows; 2.1.3 High Pressure Systems; 2.1.3.1 Single-batch High-pressure Reactors; 2.1.3.2 View Cells; 2.1.3.3 Systems for Continuous Processing 2.1.4 SummaryReferences; 2.2 Extraction and Related Separation Techniques; 2.2.1 General Aspects of Supercritical Fluids as Mass Separating Agents; 2.2.2 Extraction from Solids; 2.2.2.1 Basic Process Design; 2.2.2.2 Process Parameters; 2.2.2.3 Modeling the Extraction; 2.2.2.4 Solids in Multiple Stages and Countercurrent Operation in SFE; 2.2.2.5 Continuous Extraction of Contaminated Soil with Supercritical Water; 2.2.3 Countercurrent Multistage Extraction; 2.2.3.1 Basic Process Design; 2.2.3.2 Phase Equilibria; 2.2.3.3 Separation Analysis with Respect to Theoretical Stages 2.2.3.4 Multicomponent Process Simulation2.2.3.5 Determination of the Height (Length) of a Theoretical Stage; 2.2.3.6 Determination of Column Diameter; 2.2.4 Chromatographic Separation with Supercritical Fluids; 2.2.4.1 Design of SFC Apparatus; 2.2.4.2 Methods for Scale-up of Chromatography; 2.2.5 Conclusion; References; 2.3 Precipitation and Crystallization Techniques; 2.3.1 Introduction; 2.3.2 Thermodynamics and Phase Equilibria; 2.3.2.1 CSS, PGSS and RESS; 2.3.2.2 GASP; 2.3.3 Process Basics and Reference Schemes; 2.3.3.1 Crystallization from a Supercritical Solution (CSS) 2.3.3.2 Formation of Particles from Gas Saturated Solution (PGSS) |
| Record Nr. | UNINA-9910144282503321 |
| Weinheim ; ; New York, : Wiley-VCH, c1999 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Chemical synthesis using supercritical fluids [[electronic resource] /] / edited by Philip G. Jessop and Walter Leitner
| Chemical synthesis using supercritical fluids [[electronic resource] /] / edited by Philip G. Jessop and Walter Leitner |
| Pubbl/distr/stampa | Weinheim ; ; New York, : Wiley-VCH, c1999 |
| Descrizione fisica | 1 online resource (503 p.) |
| Disciplina |
541.3
541.39 |
| Altri autori (Persone) |
JessopPhilip G
LeitnerWalter |
| Soggetto topico |
High pressure chemistry
Organic compounds - Synthesis Supercritical fluids |
| ISBN |
1-281-76423-X
9786611764234 3-527-61368-4 3-527-61369-2 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Chemical Synthesis Using Supercritical Fluids; Preface; Contents; Contents; List of Contributors; 1 Introduction; 1.1 Supercritical Fluids as Media for Chemical Reactions; 1.1.1 What is a Supercritical Fluid (SCF)?; 1.1.2 Practical Aspects of Reactions in Supercritical Fluids (SFRs); 1.1.3 Motivation for Use of SCFs in Modern Chemical Synthesis; 1.1.4 A Brief History of Chemical Synthesis in SCFs; 1.1.4.1 Discovery of SCFs and their Use as Solvents; 1.1.4.2 Early Examples of Chemical Reactions in SCFs; 1.1.4.3 Industrial Use of SCFs as Reaction Media; References
1.2 Phase Behavior and Solubility1.2.1 Basic Physical Properties of Supercritical Fluids; 1.2.2 Phase Behavior in High Pressure Systems; 1.2.2.1 Types of Binary Phase Diagrams; 1.2.2.2 Asymmetric Binary Mixtures; 1.2.3 Factors Affecting Solubility in Supercritical Fluids; 1.2.3.1 SCF Solvent; 1.2.3.2 Chemical Functionality of the Solute; 1.2.3.3 Temperature and Pressure Effects; References; 1.3 Physical Properties as Related to Chemical Reactions; 1.3.1 Behavior of Diffusion Coefficients; 1.3.2 Diffusional Effects on Reactions; 1.3.3 Transition-state Theory Applied to SCFs 1.3.4 Density Dependence of Two Competing Reactions1.3.5 Solvation Effects on Reactions; 1.3.6 Conclusions; References; 2 Experimental Techniques; 2.1 High-pressure Reaction Equipment Design; 2.1.1 Introduction; 2.1.2 Basic Equipment and Components; 2.1.2.1 Design of Thick-Walled Vessels; 2.1.2.2 Closures and Connectors; 2.1.2.3 Tubing and Fittings; 2.1.2.4 Valves; 2.1.2.5 Compressors and Pumps; 2.1.2.6 Stirring and Mixing; 2.1.2.7 Optical Windows; 2.1.3 High Pressure Systems; 2.1.3.1 Single-batch High-pressure Reactors; 2.1.3.2 View Cells; 2.1.3.3 Systems for Continuous Processing 2.1.4 SummaryReferences; 2.2 Extraction and Related Separation Techniques; 2.2.1 General Aspects of Supercritical Fluids as Mass Separating Agents; 2.2.2 Extraction from Solids; 2.2.2.1 Basic Process Design; 2.2.2.2 Process Parameters; 2.2.2.3 Modeling the Extraction; 2.2.2.4 Solids in Multiple Stages and Countercurrent Operation in SFE; 2.2.2.5 Continuous Extraction of Contaminated Soil with Supercritical Water; 2.2.3 Countercurrent Multistage Extraction; 2.2.3.1 Basic Process Design; 2.2.3.2 Phase Equilibria; 2.2.3.3 Separation Analysis with Respect to Theoretical Stages 2.2.3.4 Multicomponent Process Simulation2.2.3.5 Determination of the Height (Length) of a Theoretical Stage; 2.2.3.6 Determination of Column Diameter; 2.2.4 Chromatographic Separation with Supercritical Fluids; 2.2.4.1 Design of SFC Apparatus; 2.2.4.2 Methods for Scale-up of Chromatography; 2.2.5 Conclusion; References; 2.3 Precipitation and Crystallization Techniques; 2.3.1 Introduction; 2.3.2 Thermodynamics and Phase Equilibria; 2.3.2.1 CSS, PGSS and RESS; 2.3.2.2 GASP; 2.3.3 Process Basics and Reference Schemes; 2.3.3.1 Crystallization from a Supercritical Solution (CSS) 2.3.3.2 Formation of Particles from Gas Saturated Solution (PGSS) |
| Record Nr. | UNINA-9910830740303321 |
| Weinheim ; ; New York, : Wiley-VCH, c1999 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Chemical synthesis using supercritical fluids / / edited by Philip G. Jessop and Walter Leitner
| Chemical synthesis using supercritical fluids / / edited by Philip G. Jessop and Walter Leitner |
| Pubbl/distr/stampa | Weinheim ; ; New York, : Wiley-VCH, c1999 |
| Descrizione fisica | 1 online resource (503 p.) |
| Disciplina |
541.3
541.39 |
| Altri autori (Persone) |
JessopPhilip G
LeitnerWalter |
| Soggetto topico |
High pressure chemistry
Organic compounds - Synthesis Supercritical fluids |
| ISBN |
1-281-76423-X
9786611764234 3-527-61368-4 3-527-61369-2 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Chemical Synthesis Using Supercritical Fluids; Preface; Contents; Contents; List of Contributors; 1 Introduction; 1.1 Supercritical Fluids as Media for Chemical Reactions; 1.1.1 What is a Supercritical Fluid (SCF)?; 1.1.2 Practical Aspects of Reactions in Supercritical Fluids (SFRs); 1.1.3 Motivation for Use of SCFs in Modern Chemical Synthesis; 1.1.4 A Brief History of Chemical Synthesis in SCFs; 1.1.4.1 Discovery of SCFs and their Use as Solvents; 1.1.4.2 Early Examples of Chemical Reactions in SCFs; 1.1.4.3 Industrial Use of SCFs as Reaction Media; References
1.2 Phase Behavior and Solubility1.2.1 Basic Physical Properties of Supercritical Fluids; 1.2.2 Phase Behavior in High Pressure Systems; 1.2.2.1 Types of Binary Phase Diagrams; 1.2.2.2 Asymmetric Binary Mixtures; 1.2.3 Factors Affecting Solubility in Supercritical Fluids; 1.2.3.1 SCF Solvent; 1.2.3.2 Chemical Functionality of the Solute; 1.2.3.3 Temperature and Pressure Effects; References; 1.3 Physical Properties as Related to Chemical Reactions; 1.3.1 Behavior of Diffusion Coefficients; 1.3.2 Diffusional Effects on Reactions; 1.3.3 Transition-state Theory Applied to SCFs 1.3.4 Density Dependence of Two Competing Reactions1.3.5 Solvation Effects on Reactions; 1.3.6 Conclusions; References; 2 Experimental Techniques; 2.1 High-pressure Reaction Equipment Design; 2.1.1 Introduction; 2.1.2 Basic Equipment and Components; 2.1.2.1 Design of Thick-Walled Vessels; 2.1.2.2 Closures and Connectors; 2.1.2.3 Tubing and Fittings; 2.1.2.4 Valves; 2.1.2.5 Compressors and Pumps; 2.1.2.6 Stirring and Mixing; 2.1.2.7 Optical Windows; 2.1.3 High Pressure Systems; 2.1.3.1 Single-batch High-pressure Reactors; 2.1.3.2 View Cells; 2.1.3.3 Systems for Continuous Processing 2.1.4 SummaryReferences; 2.2 Extraction and Related Separation Techniques; 2.2.1 General Aspects of Supercritical Fluids as Mass Separating Agents; 2.2.2 Extraction from Solids; 2.2.2.1 Basic Process Design; 2.2.2.2 Process Parameters; 2.2.2.3 Modeling the Extraction; 2.2.2.4 Solids in Multiple Stages and Countercurrent Operation in SFE; 2.2.2.5 Continuous Extraction of Contaminated Soil with Supercritical Water; 2.2.3 Countercurrent Multistage Extraction; 2.2.3.1 Basic Process Design; 2.2.3.2 Phase Equilibria; 2.2.3.3 Separation Analysis with Respect to Theoretical Stages 2.2.3.4 Multicomponent Process Simulation2.2.3.5 Determination of the Height (Length) of a Theoretical Stage; 2.2.3.6 Determination of Column Diameter; 2.2.4 Chromatographic Separation with Supercritical Fluids; 2.2.4.1 Design of SFC Apparatus; 2.2.4.2 Methods for Scale-up of Chromatography; 2.2.5 Conclusion; References; 2.3 Precipitation and Crystallization Techniques; 2.3.1 Introduction; 2.3.2 Thermodynamics and Phase Equilibria; 2.3.2.1 CSS, PGSS and RESS; 2.3.2.2 GASP; 2.3.3 Process Basics and Reference Schemes; 2.3.3.1 Crystallization from a Supercritical Solution (CSS) 2.3.3.2 Formation of Particles from Gas Saturated Solution (PGSS) |
| Record Nr. | UNINA-9910877316203321 |
| Weinheim ; ; New York, : Wiley-VCH, c1999 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Cleaning with solvents : science and technology / / John B. Durkee, II
| Cleaning with solvents : science and technology / / John B. Durkee, II |
| Autore | Durkee John B |
| Pubbl/distr/stampa | Oxford : , : William Andrew, , [2014] |
| Descrizione fisica | 1 online resource (779 p.) |
| Disciplina | 541.2 |
| Soggetto topico |
Solvents
Cleaning Industrial housekeeping High pressure chemistry Supercritical fluids |
| Soggetto genere / forma | Electronic books. |
| ISBN | 1-4557-3161-7 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Front Cover; Cleaning with Solvents: Science and Technology; Copyright; Contents; Preface; Acknowledgments; Disclaimer; What You Can Dowith This Book; A Note onOrganization; Units Used in This Book; External References Citedin This Book; Chapter 1 -Relationship of Solvent Properties to Structure; 1.1 BACKGROUND; 1.2 THE ELEMENTS OF CLEANINGSOLVENTS; 1.3 THE INCREDIBLE SHRINKINGPERIODIC TABLE; 1.4 A SOLVENT CAN BE ELEMENTSARRANGED IN A STRUCTURE; 1.5 A SOLVENT CAN ALSO BEA STRUCTURE POPULATED WITHADDITIONAL ELEMENTS; 1.6 THE FUTURE OF SOLVENTDESIGN
1.7 SPECIFIC RELATIONSHIPS OFCOMPOSITION AND STRUCTURE TOSOLVENT PROPERTIES1.8 SOLVENT DESIGN ISMULTIDIMENSIONAL; 1.9 SOLVENT DESIGN GOALS; 1.10 DESIGN OF NON-TRADITIONALSOLVENTS; 1.11 SOLVENT SELECTION; Endnotes; Chapter 2 -Solubility Scales (Parameters); 2.1ABSOLUTE AND RELATIVE INFORMATION; 2.2MOLECULAR SOUP; 2.3MAY THE FORCE(S)BB.A FULL AND COMPLETE DISCUSSION OF ALL IDENTIFIED INTERMOLECULAR (AS WELL AS INTERATOMIC) FORCES IS BEYON ...; 2.4SOLUBILITY PARAMETERS; 2.5KAURI BUTANOL (KB) VALUE; 2.6OTHER MEASURES OF SOLVENCY; 2.7HILDEBRAND SOLUBILITY PARAMETER 2.8HANSEN THREE-DIMENSIONAL SOLUBILITY PARAMETERS2.9NUMERICAL VALUES OF HANSEN SOLUBILITY PARAMETERS; 2.10THE BASIC APPROACH - COMPARISON TO OTHER MATERIALS; Chapter 3 -Solvent Selection for Specific Tasks; 3.1BACKGROUND; 3.2THE NATURE OF SOILS; 3.3THE BASIC APPROACH TO SOLVENT SELECTION; 3.4THIS AUTHOR'S APPROACH; 3.5AUTOPSY OF SOME SOILS; 3.6FOOD-DERIVED RESIDUE; 3.7LUBRICANTS; 3.8GREASES; 3.9COOLANTS OR HYDRAULIC FLUIDS; 3.10 POLYMER-DERIVED RESIDUES; 3.11BIOLOGICAL RESIDUE(S); 3.12GENERAL OBSERVATIONS ABOUT SOILS; 3.13USE OF HANSEN SOLUBILITY PARAMETERS IN SOLVENT SELECTION 3.14ANALYSIS FOR SPECIFIC SOIL COMPONENTS3.15GENERAL RESULTS FROM THE USE OF HSP; 3.16APPROACH USING MIXTURES OF IDENTIFIED SOIL COMPONENTS; 3.17SOLVENT SELECTION TO CLEAN COLLECTIONS OF SOILS; 3.18FOOD-DERIVED RESIDUE AS A SOIL COLLECTION; 3.19SOIL COMPOSITION REALLY DOESN'T MATTER; 3.20LUBRICANTS AS A SOIL COLLECTION; 3.21GREASE AS A SOIL COLLECTION; 3.22COOLANTS OR HYDRAULIC FLUIDS AS A SOIL COLLECTION; 3.23POLYMER-DERIVED RESIDUES AS A SOIL COLLECTION; 3.24MEDICAL RESIDUES AS A SOIL COLLECTION; 3.25A SUMMARY OF LESSONS CONCERNING CLEANING SOIL COMPOSITES 3.26IDENTIFICATION OF THE HSP VALUES OF INDUSTRIAL SOIL COMPOSITES3.27WORKING WITHOUT NUMBERS-USE OF THE HSP WITHOUT SOIL IDENTIFICATION; 3.28LIMITATIONS OF HSP SEPARATION (RA) FOR GOOD SOLVENT CLEANING PERFORMANCE; 3.29ABOUT CLEANING OF ALL SOILS; 3.30THE EFFECT OF NORMAL100 BOILING TEMPERATURE; 3.31VAPOR DEGREASING VS. COLD CLEANING; 3.32HSP FOR VAPOR DEGREASING VS. COLD CLEANING; Chapter 4 -SHE Management (Solvent Substitution); 4.1BACKGROUND; 4.2WHY SUBSTITUTE SOLVENTS?; It's About Time(ing); Technology-Forcing Regulations; 4.3REACH FOR THE STARS; 4.4BECOMING GLOBALLY HARMONIZED Becoming Globally Harmonized in the US |
| Record Nr. | UNINA-9910453734803321 |
Durkee John B
|
||
| Oxford : , : William Andrew, , [2014] | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
High pressure chemistry [[electronic resource] ] : synthetic, mechanistic, and supercritical applications / / edited by Rudi Van Eldik and Frank-Gerrit Klärner
| High pressure chemistry [[electronic resource] ] : synthetic, mechanistic, and supercritical applications / / edited by Rudi Van Eldik and Frank-Gerrit Klärner |
| Pubbl/distr/stampa | Weinheim, : Wiley-VCH, c2002 |
| Descrizione fisica | 1 online resource (476 p.) |
| Disciplina | 541.3 |
| Altri autori (Persone) |
EldikRudi van
KlärnerFrank-Gerrit |
| Soggetto topico |
High pressure chemistry
Chemistry, Physical and theoretical |
| Soggetto genere / forma | Electronic books. |
| ISBN |
1-281-76394-2
9786611763947 3-527-61262-9 3-527-61263-7 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
High Pressure Chemistry; Contents; I Basic Principles; 1 Effect of Pressure on Inorganic Reactions: Introduction and Mechanistic Applications; 1.1 Introduction; 1.2 Determination of Volumes of Activation; 1.3 Thermal-Induced Reactions; 1.3.1 Ligand Substitution Reactions; 1.3.1.1 Octahedral Complexes; 1.3.1.2 Square-Planar Complexes; 1.3.2 Electron Transfer Reactions; 1.3.2.1 Self-Exchange Reactions; 1.3.2.2 Non-Symmetrical Reactions; 1.3.3 Actvation of Small Molecules; 1.3.4 Addition and Elimination Reactions; 1.4 Photo- and Radiation-Induced Reactions; 1.5 Concluding Remarks
AcknowledgmentsReferences; 2 The Effect of Pressure on Organic Reactions: Basic Principles and Mechanistic Applications; 2.1 Introduction; 2.2 Cycloadditions; 2.2.1 Diels-Alder Reactions, Mechanistic Aspects; 2.2.2 Complex Reactions and Synthetic Applications; 2.2.3 1,3-Dipolar [3 + 2] Cycloadditions; 2.2.4 [2 + 2] Cycloadditions; 2.2.5 [6 + 4] and [8 + 2] Cycloadditions; 2.2.6 Cheletropic Reactions; 2.3 Pericydic Rearrangements; 2.3.1 Sigmatropic [3.3] Shifts: Cope and Claisen Rearrangement; 2.3.2 Electrocyclic Rearrangements; 2.3.3 Intramolecular Diels-Alder Reactions; 2.3.4 Ene Reactions 2.3.5 The Relationship Between Activation or Reaction Volume and Ring Size2.4 Free-Radical Reactions; 2.4.1 Homolytic Bond Dissociations; 2.4.2 Quinone Oxidations (Hydrogen Transfer Reactions); 2.4.3 Free Radical Cyclizations; 2.5 Ionic Reactions; 2.6 Concluding Remarks; Acknowledgments; References; 3 High-pressure Kinetics and Highly Viscous Media; 3.1 High Pressure and Dynamic Solvent Effects; 3.2 Selection of Reaction Systems; 3.3 Z/E Isomerization of N-Benzylideneanilines; 3.4 Z/E Isomerization of Push-Pull Substituted Azobenzenes; 3.5 Z/E Isomerization of Carbocyanine Cations 3.6 Z/E Isomerization of DNAB in a Polymeric Medium3.7 Concluding Remarks; Acknowledgments; References; II Mechanistic and Synthetic Applications of High Pressure; 4 Water Exchange on Metal Ions: The Effect of Pressure; 4.1 Introduction; 4.2 Concepts of Solvent Exchange Reactions; 4.3 Water Exchange from the First Coordination Shell; 4.3.1 First Row Transition Metal Ions; 4.3.2 Second- and Third-Row Transition Metal Ions; 4.3.3 Lanthanides; 4.3.4 Main Group Elements; 4.4 Water Exchange from the Second Coordination Shell; 4.5 Conclusions; Acknowledgments; References 5 insights into Solution Chemistry from High Pressure Electrochemistry5.1 Introduction; 5.2 Pressure Effects on the Kinetics of Self-Exchange Reactions; 5.2.1 Principles; 5.2.2 Experimental Observations with Aqueous Media; 5.2.3 Experimental Observations with Non-aqueous Media; 5.2.4 Approaches Involving Electrochemistry; 5.3 Electrochemical Measurements at High Pressure; 5.4 Homogeneous Versus Heterogeneous Electron Transfer; 5.4.1 Aqueous Solutions; 5.4.2 Non-aqueous Media; 5.5 Conclusions; Acknowledgments; References; 6 Pressure Effects on the Photoreactions of Transition Metal Complexes 6.1 Introduction |
| Record Nr. | UNINA-9910143990903321 |
| Weinheim, : Wiley-VCH, c2002 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
High pressure chemistry [[electronic resource] ] : synthetic, mechanistic, and supercritical applications / / edited by Rudi Van Eldik and Frank-Gerrit Klärner
| High pressure chemistry [[electronic resource] ] : synthetic, mechanistic, and supercritical applications / / edited by Rudi Van Eldik and Frank-Gerrit Klärner |
| Pubbl/distr/stampa | Weinheim, : Wiley-VCH, c2002 |
| Descrizione fisica | 1 online resource (476 p.) |
| Disciplina | 541.3 |
| Altri autori (Persone) |
EldikRudi van
KlärnerFrank-Gerrit |
| Soggetto topico |
High pressure chemistry
Chemistry, Physical and theoretical |
| ISBN |
1-281-76394-2
9786611763947 3-527-61262-9 3-527-61263-7 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
High Pressure Chemistry; Contents; I Basic Principles; 1 Effect of Pressure on Inorganic Reactions: Introduction and Mechanistic Applications; 1.1 Introduction; 1.2 Determination of Volumes of Activation; 1.3 Thermal-Induced Reactions; 1.3.1 Ligand Substitution Reactions; 1.3.1.1 Octahedral Complexes; 1.3.1.2 Square-Planar Complexes; 1.3.2 Electron Transfer Reactions; 1.3.2.1 Self-Exchange Reactions; 1.3.2.2 Non-Symmetrical Reactions; 1.3.3 Actvation of Small Molecules; 1.3.4 Addition and Elimination Reactions; 1.4 Photo- and Radiation-Induced Reactions; 1.5 Concluding Remarks
AcknowledgmentsReferences; 2 The Effect of Pressure on Organic Reactions: Basic Principles and Mechanistic Applications; 2.1 Introduction; 2.2 Cycloadditions; 2.2.1 Diels-Alder Reactions, Mechanistic Aspects; 2.2.2 Complex Reactions and Synthetic Applications; 2.2.3 1,3-Dipolar [3 + 2] Cycloadditions; 2.2.4 [2 + 2] Cycloadditions; 2.2.5 [6 + 4] and [8 + 2] Cycloadditions; 2.2.6 Cheletropic Reactions; 2.3 Pericydic Rearrangements; 2.3.1 Sigmatropic [3.3] Shifts: Cope and Claisen Rearrangement; 2.3.2 Electrocyclic Rearrangements; 2.3.3 Intramolecular Diels-Alder Reactions; 2.3.4 Ene Reactions 2.3.5 The Relationship Between Activation or Reaction Volume and Ring Size2.4 Free-Radical Reactions; 2.4.1 Homolytic Bond Dissociations; 2.4.2 Quinone Oxidations (Hydrogen Transfer Reactions); 2.4.3 Free Radical Cyclizations; 2.5 Ionic Reactions; 2.6 Concluding Remarks; Acknowledgments; References; 3 High-pressure Kinetics and Highly Viscous Media; 3.1 High Pressure and Dynamic Solvent Effects; 3.2 Selection of Reaction Systems; 3.3 Z/E Isomerization of N-Benzylideneanilines; 3.4 Z/E Isomerization of Push-Pull Substituted Azobenzenes; 3.5 Z/E Isomerization of Carbocyanine Cations 3.6 Z/E Isomerization of DNAB in a Polymeric Medium3.7 Concluding Remarks; Acknowledgments; References; II Mechanistic and Synthetic Applications of High Pressure; 4 Water Exchange on Metal Ions: The Effect of Pressure; 4.1 Introduction; 4.2 Concepts of Solvent Exchange Reactions; 4.3 Water Exchange from the First Coordination Shell; 4.3.1 First Row Transition Metal Ions; 4.3.2 Second- and Third-Row Transition Metal Ions; 4.3.3 Lanthanides; 4.3.4 Main Group Elements; 4.4 Water Exchange from the Second Coordination Shell; 4.5 Conclusions; Acknowledgments; References 5 insights into Solution Chemistry from High Pressure Electrochemistry5.1 Introduction; 5.2 Pressure Effects on the Kinetics of Self-Exchange Reactions; 5.2.1 Principles; 5.2.2 Experimental Observations with Aqueous Media; 5.2.3 Experimental Observations with Non-aqueous Media; 5.2.4 Approaches Involving Electrochemistry; 5.3 Electrochemical Measurements at High Pressure; 5.4 Homogeneous Versus Heterogeneous Electron Transfer; 5.4.1 Aqueous Solutions; 5.4.2 Non-aqueous Media; 5.5 Conclusions; Acknowledgments; References; 6 Pressure Effects on the Photoreactions of Transition Metal Complexes 6.1 Introduction |
| Record Nr. | UNINA-9910830772403321 |
| Weinheim, : Wiley-VCH, c2002 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
High pressure chemistry : synthetic, mechanistic, and supercritical applications / / edited by Rudi Van Eldik and Frank-Gerrit Klarner
| High pressure chemistry : synthetic, mechanistic, and supercritical applications / / edited by Rudi Van Eldik and Frank-Gerrit Klarner |
| Pubbl/distr/stampa | Weinheim, : Wiley-VCH, c2002 |
| Descrizione fisica | 1 online resource (476 p.) |
| Disciplina | 541.3 |
| Altri autori (Persone) |
EldikRudi van
KlarnerFrank-Gerrit |
| Soggetto topico |
High pressure chemistry
Chemistry, Physical and theoretical |
| ISBN |
1-281-76394-2
9786611763947 3-527-61262-9 3-527-61263-7 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
High Pressure Chemistry; Contents; I Basic Principles; 1 Effect of Pressure on Inorganic Reactions: Introduction and Mechanistic Applications; 1.1 Introduction; 1.2 Determination of Volumes of Activation; 1.3 Thermal-Induced Reactions; 1.3.1 Ligand Substitution Reactions; 1.3.1.1 Octahedral Complexes; 1.3.1.2 Square-Planar Complexes; 1.3.2 Electron Transfer Reactions; 1.3.2.1 Self-Exchange Reactions; 1.3.2.2 Non-Symmetrical Reactions; 1.3.3 Actvation of Small Molecules; 1.3.4 Addition and Elimination Reactions; 1.4 Photo- and Radiation-Induced Reactions; 1.5 Concluding Remarks
AcknowledgmentsReferences; 2 The Effect of Pressure on Organic Reactions: Basic Principles and Mechanistic Applications; 2.1 Introduction; 2.2 Cycloadditions; 2.2.1 Diels-Alder Reactions, Mechanistic Aspects; 2.2.2 Complex Reactions and Synthetic Applications; 2.2.3 1,3-Dipolar [3 + 2] Cycloadditions; 2.2.4 [2 + 2] Cycloadditions; 2.2.5 [6 + 4] and [8 + 2] Cycloadditions; 2.2.6 Cheletropic Reactions; 2.3 Pericydic Rearrangements; 2.3.1 Sigmatropic [3.3] Shifts: Cope and Claisen Rearrangement; 2.3.2 Electrocyclic Rearrangements; 2.3.3 Intramolecular Diels-Alder Reactions; 2.3.4 Ene Reactions 2.3.5 The Relationship Between Activation or Reaction Volume and Ring Size2.4 Free-Radical Reactions; 2.4.1 Homolytic Bond Dissociations; 2.4.2 Quinone Oxidations (Hydrogen Transfer Reactions); 2.4.3 Free Radical Cyclizations; 2.5 Ionic Reactions; 2.6 Concluding Remarks; Acknowledgments; References; 3 High-pressure Kinetics and Highly Viscous Media; 3.1 High Pressure and Dynamic Solvent Effects; 3.2 Selection of Reaction Systems; 3.3 Z/E Isomerization of N-Benzylideneanilines; 3.4 Z/E Isomerization of Push-Pull Substituted Azobenzenes; 3.5 Z/E Isomerization of Carbocyanine Cations 3.6 Z/E Isomerization of DNAB in a Polymeric Medium3.7 Concluding Remarks; Acknowledgments; References; II Mechanistic and Synthetic Applications of High Pressure; 4 Water Exchange on Metal Ions: The Effect of Pressure; 4.1 Introduction; 4.2 Concepts of Solvent Exchange Reactions; 4.3 Water Exchange from the First Coordination Shell; 4.3.1 First Row Transition Metal Ions; 4.3.2 Second- and Third-Row Transition Metal Ions; 4.3.3 Lanthanides; 4.3.4 Main Group Elements; 4.4 Water Exchange from the Second Coordination Shell; 4.5 Conclusions; Acknowledgments; References 5 insights into Solution Chemistry from High Pressure Electrochemistry5.1 Introduction; 5.2 Pressure Effects on the Kinetics of Self-Exchange Reactions; 5.2.1 Principles; 5.2.2 Experimental Observations with Aqueous Media; 5.2.3 Experimental Observations with Non-aqueous Media; 5.2.4 Approaches Involving Electrochemistry; 5.3 Electrochemical Measurements at High Pressure; 5.4 Homogeneous Versus Heterogeneous Electron Transfer; 5.4.1 Aqueous Solutions; 5.4.2 Non-aqueous Media; 5.5 Conclusions; Acknowledgments; References; 6 Pressure Effects on the Photoreactions of Transition Metal Complexes 6.1 Introduction |
| Record Nr. | UNINA-9910877674303321 |
| Weinheim, : Wiley-VCH, c2002 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
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High pressure materials properties : magnetic properties of oxides under pressure ; A supplement to Landolt-Börnstein IV/22 Series / / Yoshiyuki Kawazoe, Takeshi Kanomata, Ryunosuke Note
| High pressure materials properties : magnetic properties of oxides under pressure ; A supplement to Landolt-Börnstein IV/22 Series / / Yoshiyuki Kawazoe, Takeshi Kanomata, Ryunosuke Note |
| Autore | Kawazoe Y (Yoshiyuki), <1947-> |
| Edizione | [1st ed. 2023.] |
| Pubbl/distr/stampa | Berlin : ; Heidelberg : , : Springer Berlin Heidelberg : , : Imprint : Springer, , 2023 |
| Descrizione fisica | 1 online resource (774 pages) |
| Disciplina | 336.7305 |
| Soggetto topico |
High pressure chemistry
Oxides - Magnetic properties |
| ISBN | 3-662-64593-9 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto | Introduction -- MO-type compounds -- MO2-type compounds -- M2O3-type compounds -- M3O4-type compounds -- M7O13-type compound -- M8O15-type compound -- MOX (X=F, Cl, Br)-type compounds -- MM’O2-type compounds -- MM’(MoO4)2-type compound -- MM’O2.5-type compound -- MM’O3-type compounds. |
| Record Nr. | UNINA-9910739445903321 |
|
Kawazoe Y (Yoshiyuki), <1947->
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| Berlin : ; Heidelberg : , : Springer Berlin Heidelberg : , : Imprint : Springer, , 2023 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
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High-energy chemistry and processing in liquids / / edited by Yoshie Ishikawa [and six others]
| High-energy chemistry and processing in liquids / / edited by Yoshie Ishikawa [and six others] |
| Pubbl/distr/stampa | Singapore : , : Springer, , [2022] |
| Descrizione fisica | 1 online resource (353 pages) |
| Disciplina | 541.3 |
| Soggetto topico |
High pressure chemistry
High temperature chemistry Liquids |
| ISBN |
981-16-7797-2
981-16-7798-0 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNINA-9910743220203321 |
| Singapore : , : Springer, , [2022] | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
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High-Pressure Physical and Chemical Behaviors of Minerals and Rocks / / edited by Lidong Dai, Haiying Hu, Jianjun Jiang
| High-Pressure Physical and Chemical Behaviors of Minerals and Rocks / / edited by Lidong Dai, Haiying Hu, Jianjun Jiang |
| Pubbl/distr/stampa | [Place of publication not identified] : , : MDPI - Multidisciplinary Digital Publishing Institute, , 2023 |
| Descrizione fisica | 1 online resource (172 pages) |
| Disciplina | 541.3 |
| Soggetto topico |
High pressure chemistry
Minerals - Thermal properties Rocks - Thermal properties |
| ISBN | 3-0365-7291-0 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNINA-9910719767703321 |
| [Place of publication not identified] : , : MDPI - Multidisciplinary Digital Publishing Institute, , 2023 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
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