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Bridging heterogeneous and homogeneous catalysis : concepts, strategies, and applications / / edited by Can Li and Yan Liu
| Bridging heterogeneous and homogeneous catalysis : concepts, strategies, and applications / / edited by Can Li and Yan Liu |
| Pubbl/distr/stampa | Weinheim an der Bergstrasse, Germany : , : Wiley-VCH, , 2014 |
| Descrizione fisica | 1 online resource (651 p.) |
| Disciplina | 541.395 |
| Soggetto topico |
Heterogeneous catalysis - Data processing
Catalysis - Industrial applications |
| ISBN |
3-527-67592-2
3-527-67590-6 3-527-67593-0 |
| Formato | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Bridging Heterogeneous and Homogeneous Catalysis; Contents; Preface; List of Contributors; Chapter 1 Acid-Base Cooperative Catalysis for Organic Reactions by Designed Solid Surfaces with Organofunctional Groups; 1.1 Introduction; 1.2 Bifunctional Catalysts Possessing Both Acidic and Basic Organic Groups; 1.2.1 Urea-Amine Bifunctional Catalyst; 1.2.2 Sulfonic or Carboxylic Acid-Amine Bifunctional Catalyst; 1.3 Bifunctional Catalysts Possessing Basic Organic Groups and Acid Sites Derived from Their Support Surface; 1.3.1 Organic Base-Catalyzed Reactions Enhanced by SiO2
1.3.2 Amine-Catalyzed Reactions Enhanced by Acid Site on Silica-Alumina1.3.3 Control of Acid-Base Interaction on Solid Surface; 1.3.4 Cooperative Catalysis of Acid Site, Primary Amine, and Tertiary Amine; 1.4 Prospect; References; Chapter 2 Catalytic Reactions in or by Room-Temperature Ionic Liquids: Bridging the Gap between Homogeneous and Heterogeneous Catalysis; 2.1 Introduction and Background; 2.2 Catalysis with IL-Supported or Mediated Metal Nanoparticles; 2.2.1 Preparation of MNPs in ILs; 2.2.1.1 IL Itself as the Reducing Agent; 2.2.1.2 Molecular Hydrogen as Reducing Agent 2.2.1.3 NaBH4 as the Reducing Agent2.2.1.4 Other Reducing Agents; 2.2.2 Characterization of IL-Supported or Mediated MNPs; 2.2.2.1 XPS and NMR; 2.2.2.2 SEM and TEM; 2.2.2.3 Molecular Dynamics Simulations; 2.2.3 Hydrogenation Reactions; 2.2.4 IL-Supported Pd NPs; 2.2.5 IL-Supported Pt and Ir NPs; 2.2.6 IL-Supported Ru NPs; 2.2.6.1 IL-Supported Rh NPs; 2.2.7 C-C Coupling Reactions; 2.2.7.1 Suzuki Reaction; 2.2.7.2 Mizoroki-Heck Reaction; 2.2.7.3 Stille Reaction; 2.2.7.4 Sonogashira Reaction; 2.2.7.5 Ullmann Reaction; 2.2.8 Brief Summary 2.3 Reactions Catalyzed by Solid-Supported IL: Heterogeneous Catalysis with Homogeneous Performance2.3.1 Introduction; 2.3.1.1 Design, Preparation, and Properties of Supported IL-Phase Catalysis; 2.3.2 Design, Preparation, and Properties of Silica Gel-Confined IL Catalysts; 2.3.2.1 Design, Preparation, and Properties of Covalently Supported IL Catalysts; 2.3.3 Catalytic Reaction with Supported IL Catalysts; 2.3.3.1 Catalytic Hydrogenation; 2.3.3.2 Selective Oxidation; 2.3.3.3 Catalytic Carbonylation Reaction; 2.3.3.4 Water-Gas Shift Reaction; 2.3.3.5 Isomerization and Oligomerization 2.3.3.6 Alkylation and Esterification Reactions2.3.3.7 Asymmetric Catalysis; 2.3.3.8 Enzyme Catalysis; 2.3.4 Brief Summary; 2.4 Outlook; References; Chapter 3 Heterogeneous Catalysis with Organic-Inorganic Hybrid Materials; 3.1 Introduction; 3.1.1 Ordered Mesoporous Silica; 3.1.2 Organic-Inorganic Hybrid Materials; 3.1.3 Heterogeneous Catalysis; 3.2 Organic-Inorganic Hybrid Materials; 3.2.1 General Advantages of Organic-Inorganic Hybrid Materials; 3.2.2 Grafting and Co-Condensation; 3.2.2.1 Amine Groups; 3.2.2.2 Ionic Liquids (ILs); 3.2.2.3 Others 3.2.3 Periodic Mesoporous Organosilicas (PMOs) |
| Record Nr. | UNINA-9910132214703321 |
| Weinheim an der Bergstrasse, Germany : , : Wiley-VCH, , 2014 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Bridging heterogeneous and homogeneous catalysis : concepts, strategies, and applications / / edited by Can Li and Yan Liu
| Bridging heterogeneous and homogeneous catalysis : concepts, strategies, and applications / / edited by Can Li and Yan Liu |
| Pubbl/distr/stampa | Weinheim an der Bergstrasse, Germany : , : Wiley-VCH, , 2014 |
| Descrizione fisica | 1 online resource (651 p.) |
| Disciplina | 541.395 |
| Soggetto topico |
Heterogeneous catalysis - Data processing
Catalysis - Industrial applications |
| ISBN |
3-527-67592-2
3-527-67590-6 3-527-67593-0 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Bridging Heterogeneous and Homogeneous Catalysis; Contents; Preface; List of Contributors; Chapter 1 Acid-Base Cooperative Catalysis for Organic Reactions by Designed Solid Surfaces with Organofunctional Groups; 1.1 Introduction; 1.2 Bifunctional Catalysts Possessing Both Acidic and Basic Organic Groups; 1.2.1 Urea-Amine Bifunctional Catalyst; 1.2.2 Sulfonic or Carboxylic Acid-Amine Bifunctional Catalyst; 1.3 Bifunctional Catalysts Possessing Basic Organic Groups and Acid Sites Derived from Their Support Surface; 1.3.1 Organic Base-Catalyzed Reactions Enhanced by SiO2
1.3.2 Amine-Catalyzed Reactions Enhanced by Acid Site on Silica-Alumina1.3.3 Control of Acid-Base Interaction on Solid Surface; 1.3.4 Cooperative Catalysis of Acid Site, Primary Amine, and Tertiary Amine; 1.4 Prospect; References; Chapter 2 Catalytic Reactions in or by Room-Temperature Ionic Liquids: Bridging the Gap between Homogeneous and Heterogeneous Catalysis; 2.1 Introduction and Background; 2.2 Catalysis with IL-Supported or Mediated Metal Nanoparticles; 2.2.1 Preparation of MNPs in ILs; 2.2.1.1 IL Itself as the Reducing Agent; 2.2.1.2 Molecular Hydrogen as Reducing Agent 2.2.1.3 NaBH4 as the Reducing Agent2.2.1.4 Other Reducing Agents; 2.2.2 Characterization of IL-Supported or Mediated MNPs; 2.2.2.1 XPS and NMR; 2.2.2.2 SEM and TEM; 2.2.2.3 Molecular Dynamics Simulations; 2.2.3 Hydrogenation Reactions; 2.2.4 IL-Supported Pd NPs; 2.2.5 IL-Supported Pt and Ir NPs; 2.2.6 IL-Supported Ru NPs; 2.2.6.1 IL-Supported Rh NPs; 2.2.7 C-C Coupling Reactions; 2.2.7.1 Suzuki Reaction; 2.2.7.2 Mizoroki-Heck Reaction; 2.2.7.3 Stille Reaction; 2.2.7.4 Sonogashira Reaction; 2.2.7.5 Ullmann Reaction; 2.2.8 Brief Summary 2.3 Reactions Catalyzed by Solid-Supported IL: Heterogeneous Catalysis with Homogeneous Performance2.3.1 Introduction; 2.3.1.1 Design, Preparation, and Properties of Supported IL-Phase Catalysis; 2.3.2 Design, Preparation, and Properties of Silica Gel-Confined IL Catalysts; 2.3.2.1 Design, Preparation, and Properties of Covalently Supported IL Catalysts; 2.3.3 Catalytic Reaction with Supported IL Catalysts; 2.3.3.1 Catalytic Hydrogenation; 2.3.3.2 Selective Oxidation; 2.3.3.3 Catalytic Carbonylation Reaction; 2.3.3.4 Water-Gas Shift Reaction; 2.3.3.5 Isomerization and Oligomerization 2.3.3.6 Alkylation and Esterification Reactions2.3.3.7 Asymmetric Catalysis; 2.3.3.8 Enzyme Catalysis; 2.3.4 Brief Summary; 2.4 Outlook; References; Chapter 3 Heterogeneous Catalysis with Organic-Inorganic Hybrid Materials; 3.1 Introduction; 3.1.1 Ordered Mesoporous Silica; 3.1.2 Organic-Inorganic Hybrid Materials; 3.1.3 Heterogeneous Catalysis; 3.2 Organic-Inorganic Hybrid Materials; 3.2.1 General Advantages of Organic-Inorganic Hybrid Materials; 3.2.2 Grafting and Co-Condensation; 3.2.2.1 Amine Groups; 3.2.2.2 Ionic Liquids (ILs); 3.2.2.3 Others 3.2.3 Periodic Mesoporous Organosilicas (PMOs) |
| Record Nr. | UNINA-9910819201203321 |
| Weinheim an der Bergstrasse, Germany : , : Wiley-VCH, , 2014 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
