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Carbon-centered free radicals and radical cations [[electronic resource] ] : structure, reactivity, and dynamics / / edited by Malcolm D. Forbes
| Carbon-centered free radicals and radical cations [[electronic resource] ] : structure, reactivity, and dynamics / / edited by Malcolm D. Forbes |
| Pubbl/distr/stampa | Hoboken, NJ, : Wiely, c2010 |
| Descrizione fisica | 1 online resource (395 p.) |
| Disciplina | 547.1224 |
| Altri autori (Persone) | ForbesMalcolm D. E. <1960-> |
| Collana | Wiley Series of Reactive Intermediates in Chemistry and Biology |
| Soggetto topico |
Free radicals (Chemistry)
Carbon, Activated Reactivity (Chemistry) Cations |
| ISBN |
1-282-49088-5
9786612490880 0-470-58411-4 0-470-58410-6 |
| Formato | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
CARBON-CENTERED FREE RADICALS AND RADICAL CATIONS; CONTENTS; About the Volume Editor; Preface to Series; Introduction; Contributors; 1. A Brief History of Carbon Radicals; 2. Intermolecular Radical Additions to Alkynes: Cascade-Type Radical Cyclizations; 2.1 Introduction; 2.2 Cascade Reactions Involving Radicals of Second Row Elements; 2.2.1 Cascade Reactions Initiated by Addition of C-Centered Radicals to Alkynes; 2.2.2 Cascade Reactions Initiated by Addition of O-Centered Radicals to Alkynes (Self-Terminating Radical Oxygenations)
2.2.3 Cascade Reactions Initiated by Addition of N-Centered Radicals to Alkynes 2.3 Cascade Reactions Initiated by Addition of Higher Main Group (VI)-Centered Radicals to Alkynes; 2.3.1 Cascade Reactions Initiated by Addition of Sn-Centered Radicals to Alkynes; 2.4 Cascade Reactions Initiated by Addition of Higher Main Group (VI)-Centered Radicals to Alkynes; 2.4.1 Cascade Reactions Initiated by Addition of S-Centered Radicals to Alkynes; 2.4.2 Cascade Reactions Initiated by Addition of Se-Centered Radicals to Alkynes 2.5 Cascade Reactions Initiated by Addition of Higher Main Group (V)-Centered Radicals to Alkynes 2.5.1 Cascade Reactions Initiated by Addition of P-Centered Radicals to Alkynes; 3. Radical Cation Fragmentation Reactions in Organic Synthesis; 3.1 Introduction; 3.1.1 Oxidative Carbon-Carbon Bond Cleavage; 3.1.2 Thermodynamic and Kinetic Considerations; 3.1.3 Reactive Intermediate Lifetime; 3.2 Electron Transfer-Initiated Cyclization Reactions; 3.2.1 Rate Enhancement and Mechanistic Studies; 3.2.2 Development of a Catalytic Aerobic Protocol; 3.2.3 Oxidative Cascade Reactions 3.3 Oxidative Acyliminium Ion Formation 3.4 Carbon-Carbon Bond Formation; 3.4.1 Chemoselectivity and Reactivity; 3.4.2 Reaction Scope; 3.5 Summary and Outlook; 4. Selectivity in Radical Cation Cycloadditions; 4.1 Introduction; 4.2 Mechanism and the Origin of the Rate Acceleration; 4.3 Selectivity in Radical Cation Cycloadditions; 4.4 Chemoselectivity; 4.4.1 Effect of Dienophile Substituents on Chemoselectivity; 4.4.2 Effect of Sensitizers and Solvents on Chemoselectivity; 4.4.3 Effect of Concentrations on Chemoselectivity; 4.4.4 Effect of Electron-Rich Dienophiles on Chemoselectivity 4.5 Regioselectivity 4.6 Periselectivity; 4.6.1 Effects of Solvent and Concentration on Periselectivity; 4.6.2 Effect of Diene/Dienophile Redox Potentials on Periselectivity; 4.6.3 Substituent and Steric Effects on Periselectivity; 4.6.4 Quantifying Periselectivity Through Ion Pair Association; 4.7 Endo/Exo Selectivity; 4.7.1 Effects of Secondary Orbital Interaction and Solvents on Endo/Exo Selectivity; 4.7.2 Effect of Sensitizer on Endo/Exo Selectivity; 4.7.3 Ion Pairs and Endo/Exo Selectivities; 4.8 Conclusions; 5. The Stability of Carbon-Centered Radicals; 5.1 Introduction 5.1.1 The Consequences of Different Stability Definitions: How Stable Are Ethyl and Fluoromethyl Radicals? |
| Record Nr. | UNISA-996212676503316 |
| Hoboken, NJ, : Wiely, c2010 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. di Salerno | ||
| ||
Carbon-centered free radicals and radical cations [[electronic resource] ] : structure, reactivity, and dynamics / / edited by Malcolm D. Forbes
| Carbon-centered free radicals and radical cations [[electronic resource] ] : structure, reactivity, and dynamics / / edited by Malcolm D. Forbes |
| Pubbl/distr/stampa | Hoboken, NJ, : Wiely, c2010 |
| Descrizione fisica | 1 online resource (395 p.) |
| Disciplina | 547.1224 |
| Altri autori (Persone) | ForbesMalcolm D. E. <1960-> |
| Collana | Wiley Series of Reactive Intermediates in Chemistry and Biology |
| Soggetto topico |
Free radicals (Chemistry)
Carbon, Activated Reactivity (Chemistry) Cations |
| ISBN |
1-282-49088-5
9786612490880 0-470-58411-4 0-470-58410-6 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
CARBON-CENTERED FREE RADICALS AND RADICAL CATIONS; CONTENTS; About the Volume Editor; Preface to Series; Introduction; Contributors; 1. A Brief History of Carbon Radicals; 2. Intermolecular Radical Additions to Alkynes: Cascade-Type Radical Cyclizations; 2.1 Introduction; 2.2 Cascade Reactions Involving Radicals of Second Row Elements; 2.2.1 Cascade Reactions Initiated by Addition of C-Centered Radicals to Alkynes; 2.2.2 Cascade Reactions Initiated by Addition of O-Centered Radicals to Alkynes (Self-Terminating Radical Oxygenations)
2.2.3 Cascade Reactions Initiated by Addition of N-Centered Radicals to Alkynes 2.3 Cascade Reactions Initiated by Addition of Higher Main Group (VI)-Centered Radicals to Alkynes; 2.3.1 Cascade Reactions Initiated by Addition of Sn-Centered Radicals to Alkynes; 2.4 Cascade Reactions Initiated by Addition of Higher Main Group (VI)-Centered Radicals to Alkynes; 2.4.1 Cascade Reactions Initiated by Addition of S-Centered Radicals to Alkynes; 2.4.2 Cascade Reactions Initiated by Addition of Se-Centered Radicals to Alkynes 2.5 Cascade Reactions Initiated by Addition of Higher Main Group (V)-Centered Radicals to Alkynes 2.5.1 Cascade Reactions Initiated by Addition of P-Centered Radicals to Alkynes; 3. Radical Cation Fragmentation Reactions in Organic Synthesis; 3.1 Introduction; 3.1.1 Oxidative Carbon-Carbon Bond Cleavage; 3.1.2 Thermodynamic and Kinetic Considerations; 3.1.3 Reactive Intermediate Lifetime; 3.2 Electron Transfer-Initiated Cyclization Reactions; 3.2.1 Rate Enhancement and Mechanistic Studies; 3.2.2 Development of a Catalytic Aerobic Protocol; 3.2.3 Oxidative Cascade Reactions 3.3 Oxidative Acyliminium Ion Formation 3.4 Carbon-Carbon Bond Formation; 3.4.1 Chemoselectivity and Reactivity; 3.4.2 Reaction Scope; 3.5 Summary and Outlook; 4. Selectivity in Radical Cation Cycloadditions; 4.1 Introduction; 4.2 Mechanism and the Origin of the Rate Acceleration; 4.3 Selectivity in Radical Cation Cycloadditions; 4.4 Chemoselectivity; 4.4.1 Effect of Dienophile Substituents on Chemoselectivity; 4.4.2 Effect of Sensitizers and Solvents on Chemoselectivity; 4.4.3 Effect of Concentrations on Chemoselectivity; 4.4.4 Effect of Electron-Rich Dienophiles on Chemoselectivity 4.5 Regioselectivity 4.6 Periselectivity; 4.6.1 Effects of Solvent and Concentration on Periselectivity; 4.6.2 Effect of Diene/Dienophile Redox Potentials on Periselectivity; 4.6.3 Substituent and Steric Effects on Periselectivity; 4.6.4 Quantifying Periselectivity Through Ion Pair Association; 4.7 Endo/Exo Selectivity; 4.7.1 Effects of Secondary Orbital Interaction and Solvents on Endo/Exo Selectivity; 4.7.2 Effect of Sensitizer on Endo/Exo Selectivity; 4.7.3 Ion Pairs and Endo/Exo Selectivities; 4.8 Conclusions; 5. The Stability of Carbon-Centered Radicals; 5.1 Introduction 5.1.1 The Consequences of Different Stability Definitions: How Stable Are Ethyl and Fluoromethyl Radicals? |
| Record Nr. | UNINA-9910139517803321 |
| Hoboken, NJ, : Wiely, c2010 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Carbon-centered free radicals and radical cations : structure, reactivity, and dynamics / / edited by Malcolm D. Forbes
| Carbon-centered free radicals and radical cations : structure, reactivity, and dynamics / / edited by Malcolm D. Forbes |
| Edizione | [1st ed.] |
| Pubbl/distr/stampa | Hoboken, NJ, : Wiely, c2010 |
| Descrizione fisica | 1 online resource (395 p.) |
| Disciplina | 547.1224 |
| Altri autori (Persone) | ForbesMalcolm D. E. <1960-> |
| Collana | Wiley Series of Reactive Intermediates in Chemistry and Biology |
| Soggetto topico |
Free radicals (Chemistry)
Carbon, Activated Reactivity (Chemistry) Cations |
| ISBN |
1-282-49088-5
9786612490880 0-470-58411-4 0-470-58410-6 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
CARBON-CENTERED FREE RADICALS AND RADICAL CATIONS; CONTENTS; About the Volume Editor; Preface to Series; Introduction; Contributors; 1. A Brief History of Carbon Radicals; 2. Intermolecular Radical Additions to Alkynes: Cascade-Type Radical Cyclizations; 2.1 Introduction; 2.2 Cascade Reactions Involving Radicals of Second Row Elements; 2.2.1 Cascade Reactions Initiated by Addition of C-Centered Radicals to Alkynes; 2.2.2 Cascade Reactions Initiated by Addition of O-Centered Radicals to Alkynes (Self-Terminating Radical Oxygenations)
2.2.3 Cascade Reactions Initiated by Addition of N-Centered Radicals to Alkynes 2.3 Cascade Reactions Initiated by Addition of Higher Main Group (VI)-Centered Radicals to Alkynes; 2.3.1 Cascade Reactions Initiated by Addition of Sn-Centered Radicals to Alkynes; 2.4 Cascade Reactions Initiated by Addition of Higher Main Group (VI)-Centered Radicals to Alkynes; 2.4.1 Cascade Reactions Initiated by Addition of S-Centered Radicals to Alkynes; 2.4.2 Cascade Reactions Initiated by Addition of Se-Centered Radicals to Alkynes 2.5 Cascade Reactions Initiated by Addition of Higher Main Group (V)-Centered Radicals to Alkynes 2.5.1 Cascade Reactions Initiated by Addition of P-Centered Radicals to Alkynes; 3. Radical Cation Fragmentation Reactions in Organic Synthesis; 3.1 Introduction; 3.1.1 Oxidative Carbon-Carbon Bond Cleavage; 3.1.2 Thermodynamic and Kinetic Considerations; 3.1.3 Reactive Intermediate Lifetime; 3.2 Electron Transfer-Initiated Cyclization Reactions; 3.2.1 Rate Enhancement and Mechanistic Studies; 3.2.2 Development of a Catalytic Aerobic Protocol; 3.2.3 Oxidative Cascade Reactions 3.3 Oxidative Acyliminium Ion Formation 3.4 Carbon-Carbon Bond Formation; 3.4.1 Chemoselectivity and Reactivity; 3.4.2 Reaction Scope; 3.5 Summary and Outlook; 4. Selectivity in Radical Cation Cycloadditions; 4.1 Introduction; 4.2 Mechanism and the Origin of the Rate Acceleration; 4.3 Selectivity in Radical Cation Cycloadditions; 4.4 Chemoselectivity; 4.4.1 Effect of Dienophile Substituents on Chemoselectivity; 4.4.2 Effect of Sensitizers and Solvents on Chemoselectivity; 4.4.3 Effect of Concentrations on Chemoselectivity; 4.4.4 Effect of Electron-Rich Dienophiles on Chemoselectivity 4.5 Regioselectivity 4.6 Periselectivity; 4.6.1 Effects of Solvent and Concentration on Periselectivity; 4.6.2 Effect of Diene/Dienophile Redox Potentials on Periselectivity; 4.6.3 Substituent and Steric Effects on Periselectivity; 4.6.4 Quantifying Periselectivity Through Ion Pair Association; 4.7 Endo/Exo Selectivity; 4.7.1 Effects of Secondary Orbital Interaction and Solvents on Endo/Exo Selectivity; 4.7.2 Effect of Sensitizer on Endo/Exo Selectivity; 4.7.3 Ion Pairs and Endo/Exo Selectivities; 4.8 Conclusions; 5. The Stability of Carbon-Centered Radicals; 5.1 Introduction 5.1.1 The Consequences of Different Stability Definitions: How Stable Are Ethyl and Fluoromethyl Radicals? |
| Record Nr. | UNINA-9910828353703321 |
| Hoboken, NJ, : Wiely, c2010 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
EPR of free radicals in solids I : trends in methods and applications / / edited by Anders Lund, Masaru Shiotani
| EPR of free radicals in solids I : trends in methods and applications / / edited by Anders Lund, Masaru Shiotani |
| Edizione | [2nd ed.] |
| Pubbl/distr/stampa | Dordrecht, : Springer, 2013 |
| Descrizione fisica | 1 online resource (423 p.) |
| Disciplina | 538.364 |
| Altri autori (Persone) |
LundA (Anders)
ShiotaniMasaru |
| Collana | Progress in theoretical chemistry and physics |
| Soggetto topico |
Electron paramagnetic resonance
Free radicals (Chemistry) Solid state physics |
| ISBN |
1-283-93814-6
94-007-4893-0 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto | Continuous Wave EPR of Radicals in Solids (Anders Lund and Wei Liu) -- Pulse EPR of Paramagnetic Centers in Solid Phases (Marina Brustolon and Antonio Barbon) -- Dynamical Effects in CW and Pulsed EPR -- Deuterium Labeling Studies and Quantum Effects of Radicals in Solids (Nikolas- Ploutarch Benetis, Yurij Dmitriev) -- XSophe - Sophe - XeprView and Molecular Sophe: Computer Simulation Software (Masaru Shiotani and Kenji Komaguchi) -- Suites for the Analysis of Continuous Wave and Pulsed EPR and ENDOR Spectra (Graeme R. Hanson, Christopher J. Noble, Simon Benson) -- The Calculation of the Hyperfine Coupling Tensors of Biological Radicals (Fuqiang Ban, James W. Gauld, Stacey D. Wetmore and Russell J. Boyd) -- Ab initio and Density Functional Calculations of Electronic g-Tensors for Organic Radicals (Martin Kaupp) -- Quantum Chemical Calculations of the Zero-Field Splitting Tensors for Organic Spin Multiplets (Kenji Sugisaki, Kazuo Toyota, Kazunobu Sato, Daisuke Shiomi, Masahiro Kitagawa and Takeji Takui). |
| Record Nr. | UNINA-9910437812603321 |
| Dordrecht, : Springer, 2013 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Free radical biology & medicine
| Free radical biology & medicine |
| Pubbl/distr/stampa | [New York, NY], : Elsevier Science |
| Soggetto topico |
Free radicals (Chemistry)
Free radicals (Chemistry) - Physiological effect Free radicals (Chemistry) - Toxicology Biology Free Radicals Medicine Radicaux libres (Chimie) Radicaux libres (Chimie) - Effets physiologiques Radicaux libres (Chimie) - Toxicologie Biologie biology |
| Soggetto genere / forma |
Periodical
periodicals. Periodicals. Périodiques. |
| Soggetto non controllato |
Titles of electronic journals
ScienceDirect - Text files |
| ISSN | 1873-4596 |
| Formato | Materiale a stampa |
| Livello bibliografico | Periodico |
| Lingua di pubblicazione | eng |
| Altri titoli varianti | Free radical biology and medicine |
| Record Nr. | UNISA-996203104903316 |
| [New York, NY], : Elsevier Science | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. di Salerno | ||
| ||
Free radical biology & medicine
| Free radical biology & medicine |
| Pubbl/distr/stampa | [New York, NY], : Elsevier Science |
| Soggetto topico |
Free radicals (Chemistry)
Free radicals (Chemistry) - Physiological effect Free radicals (Chemistry) - Toxicology Biology Free Radicals Medicine Radicaux libres (Chimie) Radicaux libres (Chimie) - Effets physiologiques Radicaux libres (Chimie) - Toxicologie Biologie biology |
| Soggetto genere / forma |
Periodical
periodicals. Periodicals. Périodiques. |
| Soggetto non controllato |
Titles of electronic journals
ScienceDirect - Text files |
| ISSN | 1873-4596 |
| Formato | Materiale a stampa |
| Livello bibliografico | Periodico |
| Lingua di pubblicazione | eng |
| Altri titoli varianti | Free radical biology and medicine |
| Record Nr. | UNINA-9910145869003321 |
| [New York, NY], : Elsevier Science | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Free radical medicine and biology / / edited by Kusal K. Das [and four others]
| Free radical medicine and biology / / edited by Kusal K. Das [and four others] |
| Pubbl/distr/stampa | London, United Kingdom : , : IntechOpen, , [2020] |
| Descrizione fisica | 1 online resource (130 pages) : illustrations |
| Disciplina | 541.224 |
| Collana | Physiology |
| Soggetto topico | Free radicals (Chemistry) |
| ISBN | 1-78985-144-0 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNINA-9910417994503321 |
| London, United Kingdom : , : IntechOpen, , [2020] | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Free radical research
| Free radical research |
| Pubbl/distr/stampa | [London], : Gordon and Breach Pub. Group, 1994- |
| Disciplina | 541.224 |
| Soggetto topico |
Free radicals (Chemistry)
Antioxidants Vitamin C Vitamin E Biochemistry Free Radicals Radicalen (chemie) |
| Soggetto genere / forma |
Periodical
Periodicals. |
| ISSN | 1029-2470 |
| Formato | Materiale a stampa |
| Livello bibliografico | Periodico |
| Lingua di pubblicazione | eng |
| Record Nr. | UNISA-996209160903316 |
| [London], : Gordon and Breach Pub. Group, 1994- | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. di Salerno | ||
| ||
Free radical research
| Free radical research |
| Pubbl/distr/stampa | [London], : Gordon and Breach Pub. Group, 1994- |
| Disciplina | 541.224 |
| Soggetto topico |
Free radicals (Chemistry)
Antioxidants Vitamin C Vitamin E Biochemistry Free Radicals Radicalen (chemie) Radicaux libres (Chimie) Réactions radicalaires Antioxydants |
| Soggetto genere / forma |
Periodical
Periodicals. |
| ISSN | 1029-2470 |
| Formato | Materiale a stampa |
| Livello bibliografico | Periodico |
| Lingua di pubblicazione | eng |
| Record Nr. | UNINA-9910144290503321 |
| [London], : Gordon and Breach Pub. Group, 1994- | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Free radicals and antioxidants
| Free radicals and antioxidants |
| Pubbl/distr/stampa | Bangalore, India : , : EManuscript Services, , 2011- |
| Descrizione fisica | 1 online resource |
| Soggetto topico |
Free radicals (Chemistry)
Antioxidants Oxidation, Physiological Free Radicals |
| Soggetto genere / forma |
Periodicals.
Periodical |
| ISSN | 2231-2536 |
| Formato | Materiale a stampa |
| Livello bibliografico | Periodico |
| Lingua di pubblicazione | eng |
| Altri titoli varianti | FRA |
| Record Nr. | UNINA-9910140380203321 |
| Bangalore, India : , : EManuscript Services, , 2011- | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
