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Aziridines and epoxides in organic synthesis [[electronic resource] /] / edited by Andrei K. Yudin
| Aziridines and epoxides in organic synthesis [[electronic resource] /] / edited by Andrei K. Yudin |
| Pubbl/distr/stampa | Weinheim ; ; Chichester, : Wiley, 2006 |
| Descrizione fisica | 1 online resource (516 p.) |
| Disciplina | 547.2 |
| Altri autori (Persone) | YudinAndrei K |
| Soggetto topico |
Epoxy compounds
Organic compounds - Synthesis |
| Soggetto genere / forma | Electronic books. |
| ISBN |
1-280-72273-8
9786610722730 3-527-60786-2 3-527-60748-X |
| Formato | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Aziridines and Epoxides in Organic Synthesis; Foreword; Table of Contents; Preface; List of Contributors; 1 Asymmetric Synthesis of Epoxides and Aziridines from Aldehydes and Imines; 1.1 Introduction; 1.2 Asymmetric Epoxidation of Carbonyl Compounds; 1.2.1 Aryl, Vinyl, and Alkyl Epoxides; 1.2.1.1 Stoichiometric Ylide-mediated Epoxidation; 1.2.1.2 Catalytic Ylide-mediated Epoxidation; 1.2.1.3 Discussion of Factors Affecting Diastereo- and Enantioselectivity; 1.2.2 Terminal Epoxides; 1.2.3 Epoxy Esters, Amides, Acids, Ketones, and Sulfones; 1.2.3.1 Sulfur Ylide-mediated Epoxidation
1.2.3.2 Darzens Reaction1.2.3.3 Darzens Reactions in the Presence of Chiral Auxiliaries; 1.2.3.4 Darzens Reactions with Chiral Reagents; 1.2.3.5 Darzens Reactions with Chiral Catalysts; 1.3 Asymmetric Aziridination of Imines; 1.3.1 Aziridines Bearing Electron-withdrawing Groups: Esters and Amides; 1.3.1.1 Aza-Darzens Route; 1.3.1.2 Reactions between Imines and Carbenes; 1.3.1.3 Aziridines by Guanidinium Ylide Chemistry; 1.3.2 Aziridines Bearing Alkyl, Aryl, Propargyl, and Vinyl Groups; 1.3.2.1 Aryl, Vinyl, and Alkyl Aziridines: Stoichiometric Asymmetric Ylide-mediated Aziridination 1.3.2.2 Aryl, Vinyl, and Alkyl Aziridines: Catalytic Asymmetric Ylide-mediated Aziridination1.4 Summary and Outlook; References; 2 Vinylaziridines in Organic Synthesis; 2.1 Introduction; 2.2 Direct Synthesis of Vinylaziridines [1]; 2.2.1 Addition of Nitrene to Dienes; 2.2.2 Addition of Allylic Ylides and Related Reagents to Imines; 2.2.3 Cyclization of Amino Alcohols and Related Compounds; 2.2.4 Cyclization of Amino Allenes; 2.2.5 Aziridination of α,β-unsaturated Oximes and Hydrazones; 2.3 Ring-opening Reactions with Nucleophiles; 2.3.1 Hydride Reduction 2.3.2 Organocopper-mediated Alkylation2.3.3 Reactions with Oxygen Nucleophiles; 2.3.4 Reactions with Other Nucleophiles; 2.4 Isomerization Including Rearrangement; 2.4.1 Aza-[3,3]-Claisen Rearrangement; 2.4.2 Pyrroline Formation; 2.4.3 Aza-[2,3]-Wittig Rearrangement; 2.4.4 Hydrogen Shift; 2.4.5 Rearrangement with an Aryl Group on the Aziridine Carbon; 2.4.6 Epimerization; 2.5 Cycloaddition; 2.5.1 Cycloadditions of Isocyanates and Related Compounds; 2.5.2 Carbonylative Ring-expansion to Lactams; 2.6 Electron Transfer to Vinylaziridines; 2.7 Conclusions; References 3 Asymmetric Syntheses with Aziridinecarboxylate and Aziridinephosphonate Building Blocks3.1 Introduction; 3.2 Preparation of Aziridine-2-carboxylates and Aziridine-2-phosphonates; 3.2.1 Preparation of Aziridine-2-carboxylates; 3.2.1.1 Cyclization of Hydroxy Amino Esters; 3.2.1.2 Cyclization of Hydroxy Azido Esters; 3.2.1.3 Cyclization of α-Halo- and α-Sulfonyloxy-β-amino Esters and Amides; 3.2.1.4 Aziridination of α,β-unsaturated Esters; 3.2.1.5 Aziridination of Imines; 3.2.1.6 Aziridination of Aldehydes; 3.2.1.7 2-Carboxylation of Aziridines 3.2.1.8 Resolution of Racemic Aziridine-2-carboxylates |
| Record Nr. | UNINA-9910144322703321 |
| Weinheim ; ; Chichester, : Wiley, 2006 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Aziridines and epoxides in organic synthesis / edited by Andrei K. Yudin
| Aziridines and epoxides in organic synthesis / edited by Andrei K. Yudin |
| Pubbl/distr/stampa | Weinheim : Wiley-VCH, 2006 |
| Descrizione fisica | xxi, 492 p. : ill. ; 25 cm |
| Disciplina | 547.2 |
| Altri autori (Persone) | Yudin, Andrei K. |
| Soggetto topico |
Epoxy compounds
Organic compounds - Synthesis |
| ISBN | 3527312137 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNISALENTO-991001642809707536 |
| Weinheim : Wiley-VCH, 2006 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. del Salento | ||
| ||
Aziridines and epoxides in organic synthesis [[electronic resource] /] / edited by Andrei K. Yudin
| Aziridines and epoxides in organic synthesis [[electronic resource] /] / edited by Andrei K. Yudin |
| Pubbl/distr/stampa | Weinheim ; ; Chichester, : Wiley, 2006 |
| Descrizione fisica | 1 online resource (516 p.) |
| Disciplina | 547.2 |
| Altri autori (Persone) | YudinAndrei K |
| Soggetto topico |
Epoxy compounds
Organic compounds - Synthesis |
| ISBN |
1-280-72273-8
9786610722730 3-527-60786-2 3-527-60748-X |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Aziridines and Epoxides in Organic Synthesis; Foreword; Table of Contents; Preface; List of Contributors; 1 Asymmetric Synthesis of Epoxides and Aziridines from Aldehydes and Imines; 1.1 Introduction; 1.2 Asymmetric Epoxidation of Carbonyl Compounds; 1.2.1 Aryl, Vinyl, and Alkyl Epoxides; 1.2.1.1 Stoichiometric Ylide-mediated Epoxidation; 1.2.1.2 Catalytic Ylide-mediated Epoxidation; 1.2.1.3 Discussion of Factors Affecting Diastereo- and Enantioselectivity; 1.2.2 Terminal Epoxides; 1.2.3 Epoxy Esters, Amides, Acids, Ketones, and Sulfones; 1.2.3.1 Sulfur Ylide-mediated Epoxidation
1.2.3.2 Darzens Reaction1.2.3.3 Darzens Reactions in the Presence of Chiral Auxiliaries; 1.2.3.4 Darzens Reactions with Chiral Reagents; 1.2.3.5 Darzens Reactions with Chiral Catalysts; 1.3 Asymmetric Aziridination of Imines; 1.3.1 Aziridines Bearing Electron-withdrawing Groups: Esters and Amides; 1.3.1.1 Aza-Darzens Route; 1.3.1.2 Reactions between Imines and Carbenes; 1.3.1.3 Aziridines by Guanidinium Ylide Chemistry; 1.3.2 Aziridines Bearing Alkyl, Aryl, Propargyl, and Vinyl Groups; 1.3.2.1 Aryl, Vinyl, and Alkyl Aziridines: Stoichiometric Asymmetric Ylide-mediated Aziridination 1.3.2.2 Aryl, Vinyl, and Alkyl Aziridines: Catalytic Asymmetric Ylide-mediated Aziridination1.4 Summary and Outlook; References; 2 Vinylaziridines in Organic Synthesis; 2.1 Introduction; 2.2 Direct Synthesis of Vinylaziridines [1]; 2.2.1 Addition of Nitrene to Dienes; 2.2.2 Addition of Allylic Ylides and Related Reagents to Imines; 2.2.3 Cyclization of Amino Alcohols and Related Compounds; 2.2.4 Cyclization of Amino Allenes; 2.2.5 Aziridination of α,β-unsaturated Oximes and Hydrazones; 2.3 Ring-opening Reactions with Nucleophiles; 2.3.1 Hydride Reduction 2.3.2 Organocopper-mediated Alkylation2.3.3 Reactions with Oxygen Nucleophiles; 2.3.4 Reactions with Other Nucleophiles; 2.4 Isomerization Including Rearrangement; 2.4.1 Aza-[3,3]-Claisen Rearrangement; 2.4.2 Pyrroline Formation; 2.4.3 Aza-[2,3]-Wittig Rearrangement; 2.4.4 Hydrogen Shift; 2.4.5 Rearrangement with an Aryl Group on the Aziridine Carbon; 2.4.6 Epimerization; 2.5 Cycloaddition; 2.5.1 Cycloadditions of Isocyanates and Related Compounds; 2.5.2 Carbonylative Ring-expansion to Lactams; 2.6 Electron Transfer to Vinylaziridines; 2.7 Conclusions; References 3 Asymmetric Syntheses with Aziridinecarboxylate and Aziridinephosphonate Building Blocks3.1 Introduction; 3.2 Preparation of Aziridine-2-carboxylates and Aziridine-2-phosphonates; 3.2.1 Preparation of Aziridine-2-carboxylates; 3.2.1.1 Cyclization of Hydroxy Amino Esters; 3.2.1.2 Cyclization of Hydroxy Azido Esters; 3.2.1.3 Cyclization of α-Halo- and α-Sulfonyloxy-β-amino Esters and Amides; 3.2.1.4 Aziridination of α,β-unsaturated Esters; 3.2.1.5 Aziridination of Imines; 3.2.1.6 Aziridination of Aldehydes; 3.2.1.7 2-Carboxylation of Aziridines 3.2.1.8 Resolution of Racemic Aziridine-2-carboxylates |
| Record Nr. | UNINA-9910830455203321 |
| Weinheim ; ; Chichester, : Wiley, 2006 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Aziridines and epoxides in organic synthesis / / edited by Andrei K. Yudin
| Aziridines and epoxides in organic synthesis / / edited by Andrei K. Yudin |
| Pubbl/distr/stampa | Weinheim ; ; Chichester, : Wiley, 2006 |
| Descrizione fisica | 1 online resource (516 p.) |
| Disciplina | 547.2 |
| Altri autori (Persone) | YudinAndrei K |
| Soggetto topico |
Epoxy compounds
Organic compounds - Synthesis |
| ISBN |
1-280-72273-8
9786610722730 3-527-60786-2 3-527-60748-X |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Aziridines and Epoxides in Organic Synthesis; Foreword; Table of Contents; Preface; List of Contributors; 1 Asymmetric Synthesis of Epoxides and Aziridines from Aldehydes and Imines; 1.1 Introduction; 1.2 Asymmetric Epoxidation of Carbonyl Compounds; 1.2.1 Aryl, Vinyl, and Alkyl Epoxides; 1.2.1.1 Stoichiometric Ylide-mediated Epoxidation; 1.2.1.2 Catalytic Ylide-mediated Epoxidation; 1.2.1.3 Discussion of Factors Affecting Diastereo- and Enantioselectivity; 1.2.2 Terminal Epoxides; 1.2.3 Epoxy Esters, Amides, Acids, Ketones, and Sulfones; 1.2.3.1 Sulfur Ylide-mediated Epoxidation
1.2.3.2 Darzens Reaction1.2.3.3 Darzens Reactions in the Presence of Chiral Auxiliaries; 1.2.3.4 Darzens Reactions with Chiral Reagents; 1.2.3.5 Darzens Reactions with Chiral Catalysts; 1.3 Asymmetric Aziridination of Imines; 1.3.1 Aziridines Bearing Electron-withdrawing Groups: Esters and Amides; 1.3.1.1 Aza-Darzens Route; 1.3.1.2 Reactions between Imines and Carbenes; 1.3.1.3 Aziridines by Guanidinium Ylide Chemistry; 1.3.2 Aziridines Bearing Alkyl, Aryl, Propargyl, and Vinyl Groups; 1.3.2.1 Aryl, Vinyl, and Alkyl Aziridines: Stoichiometric Asymmetric Ylide-mediated Aziridination 1.3.2.2 Aryl, Vinyl, and Alkyl Aziridines: Catalytic Asymmetric Ylide-mediated Aziridination1.4 Summary and Outlook; References; 2 Vinylaziridines in Organic Synthesis; 2.1 Introduction; 2.2 Direct Synthesis of Vinylaziridines [1]; 2.2.1 Addition of Nitrene to Dienes; 2.2.2 Addition of Allylic Ylides and Related Reagents to Imines; 2.2.3 Cyclization of Amino Alcohols and Related Compounds; 2.2.4 Cyclization of Amino Allenes; 2.2.5 Aziridination of α,β-unsaturated Oximes and Hydrazones; 2.3 Ring-opening Reactions with Nucleophiles; 2.3.1 Hydride Reduction 2.3.2 Organocopper-mediated Alkylation2.3.3 Reactions with Oxygen Nucleophiles; 2.3.4 Reactions with Other Nucleophiles; 2.4 Isomerization Including Rearrangement; 2.4.1 Aza-[3,3]-Claisen Rearrangement; 2.4.2 Pyrroline Formation; 2.4.3 Aza-[2,3]-Wittig Rearrangement; 2.4.4 Hydrogen Shift; 2.4.5 Rearrangement with an Aryl Group on the Aziridine Carbon; 2.4.6 Epimerization; 2.5 Cycloaddition; 2.5.1 Cycloadditions of Isocyanates and Related Compounds; 2.5.2 Carbonylative Ring-expansion to Lactams; 2.6 Electron Transfer to Vinylaziridines; 2.7 Conclusions; References 3 Asymmetric Syntheses with Aziridinecarboxylate and Aziridinephosphonate Building Blocks3.1 Introduction; 3.2 Preparation of Aziridine-2-carboxylates and Aziridine-2-phosphonates; 3.2.1 Preparation of Aziridine-2-carboxylates; 3.2.1.1 Cyclization of Hydroxy Amino Esters; 3.2.1.2 Cyclization of Hydroxy Azido Esters; 3.2.1.3 Cyclization of α-Halo- and α-Sulfonyloxy-β-amino Esters and Amides; 3.2.1.4 Aziridination of α,β-unsaturated Esters; 3.2.1.5 Aziridination of Imines; 3.2.1.6 Aziridination of Aldehydes; 3.2.1.7 2-Carboxylation of Aziridines 3.2.1.8 Resolution of Racemic Aziridine-2-carboxylates |
| Record Nr. | UNINA-9910877069203321 |
| Weinheim ; ; Chichester, : Wiley, 2006 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Epoxidised natural rubber : properties & applications / / edited by Siti Salina Sarkawi, Fatimah Rubaizah Mohd Rasdi, Veronica Charlotte
| Epoxidised natural rubber : properties & applications / / edited by Siti Salina Sarkawi, Fatimah Rubaizah Mohd Rasdi, Veronica Charlotte |
| Edizione | [1st ed. 2023.] |
| Pubbl/distr/stampa | Singapore : , : Springer Nature Singapore : , : Imprint : Springer, , 2023 |
| Descrizione fisica | 1 online resource (306 pages) : illustrations (black and white, and color) |
| Disciplina | 929.374 |
| Soggetto topico |
Epoxy compounds
Rubber |
| Soggetto non controllato |
Engineering
Technology & Engineering |
| ISBN | 981-19-8836-6 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto | Epoxidised Natural Rubber and Its Chemistry -- The Processing Technology of Epoxidised Natural Rubbe -- The Rheology & Properties of raw Epoxidised Natural Rubber -- General Compounding and Properties of ENR -- ENR in Tyre Applications -- ENR in Technical Rubber Goods -- ENR in footwear -- ENR in Latex Related Products -- ENR in other applications -- Environmental Sustainability and Life Cycle Analysis (LCA) for ENR Processin -- Economic and market trend of specialty rubber. |
| Record Nr. | UNINA-9910735393103321 |
| Singapore : , : Springer Nature Singapore : , : Imprint : Springer, , 2023 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Epoxy polymers [[electronic resource] ] : new materials and innovations / / edited by Jean-Pierre Pascault and Roberto J.J. Williams
| Epoxy polymers [[electronic resource] ] : new materials and innovations / / edited by Jean-Pierre Pascault and Roberto J.J. Williams |
| Pubbl/distr/stampa | Weinheim, : Wiley-VCH Verlag GmbH, c2010 |
| Descrizione fisica | 1 online resource (389 p.) |
| Disciplina |
620.192
668.4226 |
| Altri autori (Persone) |
PascaultJean-Pierre <1943->
WilliamsRobert J. J |
| Soggetto topico |
Epoxy compounds
Polymers |
| ISBN |
1-282-47229-1
9786612472299 3-527-62870-3 3-527-62871-1 |
| Classificazione |
660
VK 8000 ZM 5300 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Epoxy Polymers: New Materials and Innovations; Contents; Preface; List of Contributors; 1: General Concepts about Epoxy Polymers; 1.1 Polymerization Chemistry of Epoxy Monomers; 1.1.1 Typical Epoxy Monomers and Polymer Growth Mechanisms; 1.1.2 Step Growth Polymerization; 1.1.3 Chain Homopolymerization; 1.1.4 Chain Copolymerization; 1.1.5 Dual Polymerization Systems; 1.2 Transformations During the Formation of an Epoxy Network; 1.2.1 General Considerations; 1.2.2 Gelation; 1.2.3 Vitrification; 1.2.4 Reaction-Induced Phase Separation; 1.2.5 Transformation Diagrams
1.3 General Properties of Epoxy NetworksReferences; Part One: New Polymers/Materials; 2: Thermoplastic Epoxy Polymers; 2.1 Introduction; 2.2 Synthesis and Characterization of Epoxy Thermoplastics; 2.2.1 Poly(hydroxy ethers) and Poly(hydroxy ether sulfides); 2.2.2 Poly(hydroxy ether sulfonamides); 2.2.3 Poly(hydroxy ester ethers); 2.2.4 Poly(hydroxy amino ethers); 2.3 Fundamental Properties of Epoxy Thermoplastics; 2.3.1 Mechanical Behavior; 2.3.2 Adhesive Characteristics; 2.3.3 Optical Properties of Poly(hydroxy amino ether) 19b; 2.3.4 Gas Barrier Properties of Epoxy Thermoplastics 2.4 ConclusionsAcknowledgments; References; 3: Epoxy Functional Acrylic Polymers for High Performance Coating Applications; 3.1 Introduction; 3.2 Epoxy Functional Acrylic Polymers (Epoxy Acrylates); 3.3 Synthesis of Epoxy Acrylates; 3.3.1 Semi-Batch Process; 3.3.2 Mass Polymerization; 3.3.3 Suspension Polymerization; 3.3.4 Polymerization in Supercritical Carbon Dioxide; 3.4 Design of Epoxy Acrylates as Film-forming Components in Coatings; 3.4.1 Glass Transition Temperature; 3.4.2 Molar Mass; 3.4.3 Choice of Co-monomers; 3.4.4 Epoxy Acrylates with a Dual-Cure 3.4.5 Structure of the Polymer: Block Copolymers3.4.6 Structure of the Polymer: Branched Epoxy Acrylates; 3.5 Cross-linking Reactions in Coating Systems; 3.5.1 Epoxy Acrylates in Etch-resistant One-Component Liquid Coatings; 3.5.2 Epoxy Acrylates in Powder Coatings; 3.5.3 Epoxy Acrylates in Water - Borne Coatings; 3.6 Conclusions; References; 4: Epoxy Polymers Based on Renewable Resources; 4.1 Introduction; 4.2 Synthesis and Polymerization of Monomers and Macromonomers Bearing Multiple Epoxy Functions; 4.2.1 Vegetable Oils; 4.2.2 Natural Rubber; 4.2.3 Lignin; 4.2.4 Cellulosics and Wood 4.2.5 Sugars4.2.6 Terpenes; 4.3 Synthesis and Polymerization of Monomers Bearing a Single Epoxy Group; 4.3.1 2-Furyloxirane; 4.3.2 Other Monomers; 4.4 Conclusions; References; Part Two: (Nano)Structured Epoxy Networks; 5: Nanostructured Epoxies by the Use of Block Copolymers; 5.1 Introduction; 5.2 Formation Mechanisms of Nanostructures in Thermosets; 5.2.1 Self-Assembly Approach; 5.2.2 Reaction-Induced Microphase Separation; 5.3 Morphologies of Epoxy Thermosets Modified With Block Copolymers; 5.3.1 Selection of Block Copolymers; 5.3.2 Nanophase Behavior of Epoxies Containing Block Copolymers 5.3.3 Demixing Behavior of Epoxy-Miscible Blocks Induced by Curing Reaction |
| Record Nr. | UNINA-9910139539903321 |
| Weinheim, : Wiley-VCH Verlag GmbH, c2010 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Epoxy polymers : new materials and innovations / edited by Jean-Pierre Pascault and Roberto J.J. Williams
| Epoxy polymers : new materials and innovations / edited by Jean-Pierre Pascault and Roberto J.J. Williams |
| Pubbl/distr/stampa | Weinheim : Wiley-VCH, c2010 |
| Descrizione fisica | xix, 367 p. : ill. (some col.) ; 25 cm |
| Disciplina | 668.4226 |
| Altri autori (Persone) |
Pascault, Jean-Pierre, 1943-
Williams, R. J. J. |
| Soggetto topico |
Epoxy compounds
Polymers Epoxy resins Epoxidharz |
| ISBN | 9783527324804 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNISALENTO-991002098119707536 |
| Weinheim : Wiley-VCH, c2010 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. del Salento | ||
| ||
Epoxy polymers [[electronic resource] ] : new materials and innovations / / edited by Jean-Pierre Pascault and Roberto J.J. Williams
| Epoxy polymers [[electronic resource] ] : new materials and innovations / / edited by Jean-Pierre Pascault and Roberto J.J. Williams |
| Pubbl/distr/stampa | Weinheim, : Wiley-VCH Verlag GmbH, c2010 |
| Descrizione fisica | 1 online resource (389 p.) |
| Disciplina |
620.192
668.4226 |
| Altri autori (Persone) |
PascaultJean-Pierre <1943->
WilliamsRobert J. J |
| Soggetto topico |
Epoxy compounds
Polymers |
| ISBN |
1-282-47229-1
9786612472299 3-527-62870-3 3-527-62871-1 |
| Classificazione |
660
VK 8000 ZM 5300 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Epoxy Polymers: New Materials and Innovations; Contents; Preface; List of Contributors; 1: General Concepts about Epoxy Polymers; 1.1 Polymerization Chemistry of Epoxy Monomers; 1.1.1 Typical Epoxy Monomers and Polymer Growth Mechanisms; 1.1.2 Step Growth Polymerization; 1.1.3 Chain Homopolymerization; 1.1.4 Chain Copolymerization; 1.1.5 Dual Polymerization Systems; 1.2 Transformations During the Formation of an Epoxy Network; 1.2.1 General Considerations; 1.2.2 Gelation; 1.2.3 Vitrification; 1.2.4 Reaction-Induced Phase Separation; 1.2.5 Transformation Diagrams
1.3 General Properties of Epoxy NetworksReferences; Part One: New Polymers/Materials; 2: Thermoplastic Epoxy Polymers; 2.1 Introduction; 2.2 Synthesis and Characterization of Epoxy Thermoplastics; 2.2.1 Poly(hydroxy ethers) and Poly(hydroxy ether sulfides); 2.2.2 Poly(hydroxy ether sulfonamides); 2.2.3 Poly(hydroxy ester ethers); 2.2.4 Poly(hydroxy amino ethers); 2.3 Fundamental Properties of Epoxy Thermoplastics; 2.3.1 Mechanical Behavior; 2.3.2 Adhesive Characteristics; 2.3.3 Optical Properties of Poly(hydroxy amino ether) 19b; 2.3.4 Gas Barrier Properties of Epoxy Thermoplastics 2.4 ConclusionsAcknowledgments; References; 3: Epoxy Functional Acrylic Polymers for High Performance Coating Applications; 3.1 Introduction; 3.2 Epoxy Functional Acrylic Polymers (Epoxy Acrylates); 3.3 Synthesis of Epoxy Acrylates; 3.3.1 Semi-Batch Process; 3.3.2 Mass Polymerization; 3.3.3 Suspension Polymerization; 3.3.4 Polymerization in Supercritical Carbon Dioxide; 3.4 Design of Epoxy Acrylates as Film-forming Components in Coatings; 3.4.1 Glass Transition Temperature; 3.4.2 Molar Mass; 3.4.3 Choice of Co-monomers; 3.4.4 Epoxy Acrylates with a Dual-Cure 3.4.5 Structure of the Polymer: Block Copolymers3.4.6 Structure of the Polymer: Branched Epoxy Acrylates; 3.5 Cross-linking Reactions in Coating Systems; 3.5.1 Epoxy Acrylates in Etch-resistant One-Component Liquid Coatings; 3.5.2 Epoxy Acrylates in Powder Coatings; 3.5.3 Epoxy Acrylates in Water - Borne Coatings; 3.6 Conclusions; References; 4: Epoxy Polymers Based on Renewable Resources; 4.1 Introduction; 4.2 Synthesis and Polymerization of Monomers and Macromonomers Bearing Multiple Epoxy Functions; 4.2.1 Vegetable Oils; 4.2.2 Natural Rubber; 4.2.3 Lignin; 4.2.4 Cellulosics and Wood 4.2.5 Sugars4.2.6 Terpenes; 4.3 Synthesis and Polymerization of Monomers Bearing a Single Epoxy Group; 4.3.1 2-Furyloxirane; 4.3.2 Other Monomers; 4.4 Conclusions; References; Part Two: (Nano)Structured Epoxy Networks; 5: Nanostructured Epoxies by the Use of Block Copolymers; 5.1 Introduction; 5.2 Formation Mechanisms of Nanostructures in Thermosets; 5.2.1 Self-Assembly Approach; 5.2.2 Reaction-Induced Microphase Separation; 5.3 Morphologies of Epoxy Thermosets Modified With Block Copolymers; 5.3.1 Selection of Block Copolymers; 5.3.2 Nanophase Behavior of Epoxies Containing Block Copolymers 5.3.3 Demixing Behavior of Epoxy-Miscible Blocks Induced by Curing Reaction |
| Record Nr. | UNINA-9910830961203321 |
| Weinheim, : Wiley-VCH Verlag GmbH, c2010 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Epoxy polymers : new materials and innovations / / edited by Jean-Pierre Pascault and Roberto J.J. Williams
| Epoxy polymers : new materials and innovations / / edited by Jean-Pierre Pascault and Roberto J.J. Williams |
| Pubbl/distr/stampa | Weinheim, : Wiley-VCH Verlag GmbH, c2010 |
| Descrizione fisica | 1 online resource (389 p.) |
| Disciplina |
620.192
668.4226 |
| Altri autori (Persone) |
PascaultJean-Pierre <1943->
WilliamsRobert J. J |
| Soggetto topico |
Epoxy compounds
Polymers |
| ISBN |
1-282-47229-1
9786612472299 3-527-62870-3 3-527-62871-1 |
| Classificazione |
660
VK 8000 ZM 5300 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Epoxy Polymers: New Materials and Innovations; Contents; Preface; List of Contributors; 1: General Concepts about Epoxy Polymers; 1.1 Polymerization Chemistry of Epoxy Monomers; 1.1.1 Typical Epoxy Monomers and Polymer Growth Mechanisms; 1.1.2 Step Growth Polymerization; 1.1.3 Chain Homopolymerization; 1.1.4 Chain Copolymerization; 1.1.5 Dual Polymerization Systems; 1.2 Transformations During the Formation of an Epoxy Network; 1.2.1 General Considerations; 1.2.2 Gelation; 1.2.3 Vitrification; 1.2.4 Reaction-Induced Phase Separation; 1.2.5 Transformation Diagrams
1.3 General Properties of Epoxy NetworksReferences; Part One: New Polymers/Materials; 2: Thermoplastic Epoxy Polymers; 2.1 Introduction; 2.2 Synthesis and Characterization of Epoxy Thermoplastics; 2.2.1 Poly(hydroxy ethers) and Poly(hydroxy ether sulfides); 2.2.2 Poly(hydroxy ether sulfonamides); 2.2.3 Poly(hydroxy ester ethers); 2.2.4 Poly(hydroxy amino ethers); 2.3 Fundamental Properties of Epoxy Thermoplastics; 2.3.1 Mechanical Behavior; 2.3.2 Adhesive Characteristics; 2.3.3 Optical Properties of Poly(hydroxy amino ether) 19b; 2.3.4 Gas Barrier Properties of Epoxy Thermoplastics 2.4 ConclusionsAcknowledgments; References; 3: Epoxy Functional Acrylic Polymers for High Performance Coating Applications; 3.1 Introduction; 3.2 Epoxy Functional Acrylic Polymers (Epoxy Acrylates); 3.3 Synthesis of Epoxy Acrylates; 3.3.1 Semi-Batch Process; 3.3.2 Mass Polymerization; 3.3.3 Suspension Polymerization; 3.3.4 Polymerization in Supercritical Carbon Dioxide; 3.4 Design of Epoxy Acrylates as Film-forming Components in Coatings; 3.4.1 Glass Transition Temperature; 3.4.2 Molar Mass; 3.4.3 Choice of Co-monomers; 3.4.4 Epoxy Acrylates with a Dual-Cure 3.4.5 Structure of the Polymer: Block Copolymers3.4.6 Structure of the Polymer: Branched Epoxy Acrylates; 3.5 Cross-linking Reactions in Coating Systems; 3.5.1 Epoxy Acrylates in Etch-resistant One-Component Liquid Coatings; 3.5.2 Epoxy Acrylates in Powder Coatings; 3.5.3 Epoxy Acrylates in Water - Borne Coatings; 3.6 Conclusions; References; 4: Epoxy Polymers Based on Renewable Resources; 4.1 Introduction; 4.2 Synthesis and Polymerization of Monomers and Macromonomers Bearing Multiple Epoxy Functions; 4.2.1 Vegetable Oils; 4.2.2 Natural Rubber; 4.2.3 Lignin; 4.2.4 Cellulosics and Wood 4.2.5 Sugars4.2.6 Terpenes; 4.3 Synthesis and Polymerization of Monomers Bearing a Single Epoxy Group; 4.3.1 2-Furyloxirane; 4.3.2 Other Monomers; 4.4 Conclusions; References; Part Two: (Nano)Structured Epoxy Networks; 5: Nanostructured Epoxies by the Use of Block Copolymers; 5.1 Introduction; 5.2 Formation Mechanisms of Nanostructures in Thermosets; 5.2.1 Self-Assembly Approach; 5.2.2 Reaction-Induced Microphase Separation; 5.3 Morphologies of Epoxy Thermosets Modified With Block Copolymers; 5.3.1 Selection of Block Copolymers; 5.3.2 Nanophase Behavior of Epoxies Containing Block Copolymers 5.3.3 Demixing Behavior of Epoxy-Miscible Blocks Induced by Curing Reaction |
| Record Nr. | UNINA-9910877893803321 |
| Weinheim, : Wiley-VCH Verlag GmbH, c2010 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
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Handbook of epoxy blends / / Jyotishkumar Parameswaranpillai [and three others] editors
| Handbook of epoxy blends / / Jyotishkumar Parameswaranpillai [and three others] editors |
| Edizione | [1st ed. 2017.] |
| Pubbl/distr/stampa | Cham, Switzerland : , : Springer, , [2017] |
| Descrizione fisica | 1 online resource (558 illus., 164 illus. in color. eReference.) |
| Disciplina | 547.412 |
| Soggetto topico | Epoxy compounds |
| ISBN | 3-319-40043-6 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto | Part I Epoxy/Rubber Blends -- Introduction to Rubber epoxy polymers -- Novel techniques for the preparation of different rubber (CTBN, ATBN, ENR, HNR, liquid rubbers)/epoxy blends -- Miscibility and phase separation of epoxy/rubber blends -- Part II Epoxy/Thermoplastic Blends -- Introduction to epoxy/thermoplastic blends -- Part III Epoxy/Block-Copolymer Blends -- Introduction to epoxy/block-copolymer blends. |
| Record Nr. | UNINA-9910483857803321 |
| Cham, Switzerland : , : Springer, , [2017] | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Soggetto topico
-
Epoxy compounds
(16)
- Organic compounds - Synthesis (4)
- Polymers (4)
- Adhesives (2)
- Acrylic resins (1)