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Asymmetric catalysis on industrial scale : challenges, approaches and solutions / / edited by Hans-Ulrich Blaser and Hans-Jürgen Federsel
| Asymmetric catalysis on industrial scale : challenges, approaches and solutions / / edited by Hans-Ulrich Blaser and Hans-Jürgen Federsel |
| Edizione | [2nd ed.] |
| Pubbl/distr/stampa | Weinheim : , : Wiley-VCH, , [2010] |
| Descrizione fisica | 1 online resource (582 p.) |
| Disciplina | 547.1395 |
| Soggetto topico |
Enantioselective catalysis
Asymmetric synthesis Enantioselective catalysis - Industrial applications |
| Soggetto genere / forma | Electronic books. |
| ISBN |
1-282-78388-2
9786612783883 3-527-64216-1 3-527-63064-3 3-527-63063-5 |
| Formato | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Asymmetric Catalysis on Industrial Scale; Contents; List of Contributors; Introduction; Part I New processes for Existing Active Compounds (APIs); 1 Some Recent Examples in Developing Biocatalytic Pharmaceutical Processes; 2 Enantioselective Hydrogenation: Applications in Process R&D of Pharmaceuticals; 3 Chiral Lactones by Asymmetric Hydrogenation - a Step Forward in (+)-Biotin Production; 4 Biocatalytic Asymmetric Oxidation for the Production of Bicyclic Proline Peptidomimetics
10 Development of Efficient Technical Processes for the Production of Enantiopure Amino Alcohols in the Pharmaceutical Industry11 The Asymmetric Hydrogenation of Enones - Access to a New L-Menthol Synthesis; 12 Eliminating Barriers in Large-Scale Asymmetric Synthesis; 13 Catalytic Asymmetric Ring Opening: A Transfer from Academia to Industry; 14 Asymmetric Baeyer-Villiger Reactions Using Whole-Cell Biocatalysts; 15 Large-Scale Applications of Hydrolases in Biocatalytic Asymmetric Synthesis; 16 Scale-Up Studies in Asymmetric Transfer Hydrogenation 17 2,2 ,5,5 -Tetramethyl-4,4 -bis(diphenylphoshino)-3,3 -bithiophene: A Very Efficient Chiral Ligand for Ru-Catalyzed Asymmetric Hydrogenations on the Multi-Kilograms Scale18 The Power of Whole-Cell Reaction: Efficient Production of Hydroxyproline, Sugar Nucleotides, Oligosaccharides, and Dipeptides; 19 Enantioselective Ketone Hydrogenation: from Research to Pilot Scale with Industrially Viable Ru-(Phosphine-Oxazoline) Complexes; Part III Processes for New Chemical Entities (NCEs); 20 Enabling Asymmetric Hydrogenation for the Design of Ef.cient Synthesis of Drug Substances 21 Scale-up of a Telescoped Enzymatic Hydrolysis Process for an Intermediate in the Synthesis of a Factor Xa Inhibitor22 An Efficient, Asymmetric Synthesis of Odanacatib, a Selective Inhibitor of Cathepsin K for the Treatment of Osteoporosis, Using an Enzyme-Mediated Dynamic Kinetic Resolution; 23 Biocatalytic Routes to the GPIIb/IIIa Antagonist Lotrafiban, SB 214857; 24 Discovery and Development of a Catalytic Asymmetric Conjugate Addition of Ketoesters to Nitroalkenes and Its Use in the Large-Scale Preparation of ABT-546 25 The Kagan Oxidation - Industrial-Scale Asymmetric Sulfoxidations in the Synthesis of Two Related NK1/NK2 Antagonists |
| Record Nr. | UNINA-9910140344403321 |
| Weinheim : , : Wiley-VCH, , [2010] | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Asymmetric catalysis on industrial scale : challenges, approaches and solutions / / edited by Hans-Ulrich Blaser and Hans-Jürgen Federsel
| Asymmetric catalysis on industrial scale : challenges, approaches and solutions / / edited by Hans-Ulrich Blaser and Hans-Jürgen Federsel |
| Edizione | [2nd ed.] |
| Pubbl/distr/stampa | Weinheim : , : Wiley-VCH, , [2010] |
| Descrizione fisica | 1 online resource (582 p.) |
| Disciplina | 547.1395 |
| Soggetto topico |
Enantioselective catalysis
Asymmetric synthesis Enantioselective catalysis - Industrial applications |
| ISBN |
1-282-78388-2
9786612783883 3-527-64216-1 3-527-63064-3 3-527-63063-5 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Asymmetric Catalysis on Industrial Scale; Contents; List of Contributors; Introduction; Part I New processes for Existing Active Compounds (APIs); 1 Some Recent Examples in Developing Biocatalytic Pharmaceutical Processes; 2 Enantioselective Hydrogenation: Applications in Process R&D of Pharmaceuticals; 3 Chiral Lactones by Asymmetric Hydrogenation - a Step Forward in (+)-Biotin Production; 4 Biocatalytic Asymmetric Oxidation for the Production of Bicyclic Proline Peptidomimetics
10 Development of Efficient Technical Processes for the Production of Enantiopure Amino Alcohols in the Pharmaceutical Industry11 The Asymmetric Hydrogenation of Enones - Access to a New L-Menthol Synthesis; 12 Eliminating Barriers in Large-Scale Asymmetric Synthesis; 13 Catalytic Asymmetric Ring Opening: A Transfer from Academia to Industry; 14 Asymmetric Baeyer-Villiger Reactions Using Whole-Cell Biocatalysts; 15 Large-Scale Applications of Hydrolases in Biocatalytic Asymmetric Synthesis; 16 Scale-Up Studies in Asymmetric Transfer Hydrogenation 17 2,2 ,5,5 -Tetramethyl-4,4 -bis(diphenylphoshino)-3,3 -bithiophene: A Very Efficient Chiral Ligand for Ru-Catalyzed Asymmetric Hydrogenations on the Multi-Kilograms Scale18 The Power of Whole-Cell Reaction: Efficient Production of Hydroxyproline, Sugar Nucleotides, Oligosaccharides, and Dipeptides; 19 Enantioselective Ketone Hydrogenation: from Research to Pilot Scale with Industrially Viable Ru-(Phosphine-Oxazoline) Complexes; Part III Processes for New Chemical Entities (NCEs); 20 Enabling Asymmetric Hydrogenation for the Design of Ef.cient Synthesis of Drug Substances 21 Scale-up of a Telescoped Enzymatic Hydrolysis Process for an Intermediate in the Synthesis of a Factor Xa Inhibitor22 An Efficient, Asymmetric Synthesis of Odanacatib, a Selective Inhibitor of Cathepsin K for the Treatment of Osteoporosis, Using an Enzyme-Mediated Dynamic Kinetic Resolution; 23 Biocatalytic Routes to the GPIIb/IIIa Antagonist Lotrafiban, SB 214857; 24 Discovery and Development of a Catalytic Asymmetric Conjugate Addition of Ketoesters to Nitroalkenes and Its Use in the Large-Scale Preparation of ABT-546 25 The Kagan Oxidation - Industrial-Scale Asymmetric Sulfoxidations in the Synthesis of Two Related NK1/NK2 Antagonists |
| Record Nr. | UNINA-9910830875203321 |
| Weinheim : , : Wiley-VCH, , [2010] | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Asymmetric heterogeneous supported catalysis [[electronic resource] ] : use of nitrogen-containing ligands / / Christine Saluzzo and Stephane Guillarme
| Asymmetric heterogeneous supported catalysis [[electronic resource] ] : use of nitrogen-containing ligands / / Christine Saluzzo and Stephane Guillarme |
| Autore | Saluzzo Christine |
| Pubbl/distr/stampa | New York, : Nova Science Publishers, c2011 |
| Descrizione fisica | 1 online resource (185 p.) |
| Disciplina | 541/.395 |
| Altri autori (Persone) | GuillarmeStéphane |
| Collana | Polymer science and technology |
| Soggetto topico |
Asymmetric synthesis
Enantioselective catalysis Ligands Nitrogen compounds |
| Soggetto genere / forma | Electronic books. |
| ISBN | 1-61728-101-8 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNINA-9910462369503321 |
Saluzzo Christine
|
||
| New York, : Nova Science Publishers, c2011 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Asymmetric heterogeneous supported catalysis [[electronic resource] ] : use of nitrogen-containing ligands / / Christine Saluzzo and Stephane Guillarme
| Asymmetric heterogeneous supported catalysis [[electronic resource] ] : use of nitrogen-containing ligands / / Christine Saluzzo and Stephane Guillarme |
| Autore | Saluzzo Christine |
| Pubbl/distr/stampa | New York, : Nova Science Publishers, c2011 |
| Descrizione fisica | 1 online resource (185 p.) |
| Disciplina | 541/.395 |
| Altri autori (Persone) | GuillarmeStéphane |
| Collana | Polymer science and technology |
| Soggetto topico |
Asymmetric synthesis
Enantioselective catalysis Ligands Nitrogen compounds |
| ISBN | 1-61728-101-8 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNINA-9910786822703321 |
|
Saluzzo Christine
|
||
| New York, : Nova Science Publishers, c2011 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Asymmetric heterogeneous supported catalysis [[electronic resource] ] : use of nitrogen-containing ligands / / Christine Saluzzo and Stephane Guillarme
| Asymmetric heterogeneous supported catalysis [[electronic resource] ] : use of nitrogen-containing ligands / / Christine Saluzzo and Stephane Guillarme |
| Autore | Saluzzo Christine |
| Edizione | [1st ed.] |
| Pubbl/distr/stampa | New York, : Nova Science Publishers, c2011 |
| Descrizione fisica | 1 online resource (185 p.) |
| Disciplina | 541/.395 |
| Altri autori (Persone) | GuillarmeStéphane |
| Collana | Polymer science and technology |
| Soggetto topico |
Asymmetric synthesis
Enantioselective catalysis Ligands Nitrogen compounds |
| ISBN | 1-61728-101-8 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Intro -- ASYMMETRIC HETEROGENEOUS SUPPORTED CATALYSIS: USE OF NITROGEN-CONTAINING LIGANDS -- Library of Congress Cataloging-in-Publication Data -- Contents -- Preface -- Chapter 1: Introduction -- Chapter 2: Reduction of C=O and C=N Bond -- 2.1. Hydrogenation -- 2.2. Hydrogenation Transfer Reduction -- 2.2.1. 1,2-Diamine and Derivatives -- 2.2.2. Imprinting Technique for Hydrogen Transfer Reduction with 1,2-Diamines -- 2.2.3. Aminoalcohol as Ligand -- 2.2.4. Dialdimine Ligand as Ligand -- 2.3. Enantioselective Hydride Reduction -- 2.4. Hydrosilylation with Ligands as Pendent Group -- 2.5. Reduction of C=N bond -- Chapter 3: Cyclopropanation -- 3.1. Oxazolines Ligands -- 3.1.1. Insoluble Supported-Polymer Box a Ligands -- 3.1.2. Insoluble Supported-Polymer AzaBOX as Ligands -- 3.1.3. Insoluble Supported-Polymer PyBox as Ligands -- 3.1.4. Immobilization of PyBox on Natural Polymers -- 3.1.5. Soluble Supported-Polymer Box as Ligands -- 3.1.6. Soluble Supported-Polymer AzaBox as Ligands -- 3.2. Porphyrins -- 3.3. Miscellaneous -- Chapter 4: Cycloadditions and Heterocycloadditions -- 4.1. Supported Box Ligands -- 4.2. Supported Aminoalcohol and N-Sulfonylamino Acid-Derived Oxazaborolidine or Oxazaborolidinone -- 4.3. Supported Salen as Ligand -- Chapter 5: Addition of Organometallic Reagents to Aldehydes, Ketones and Imines -- 5.1. Supported Aminoalcohols as Ligands -- 5.2. Supported Sulfonamide -- and N-Sulfonylated Aminoalcohols -- 5.3. Supported Oxazoline -- or Oxazolidine as Ligands -- 5.4. Supported Salen as Chiral Ligands -- Chapter 6: Asymmetric (-Allylic Substitution -- Chapter 7: Dihydroxylation and Aminohydroxylation -- 7.1. Insoluble Supported Alkaloid as Ligand -- 7.2. Soluble Supported Alkaloid as Ligand -- Chapter 8: Epoxidation -- 8.1. Supported Salen as Ligand -- 8.2. Porphyrins -- 8.3. Soluble Polymers.
Chapter 9: Kinetic Resolution of Terminal Epoxides -- Chapter 10: Miscellaneous -- Chapter 11: Conclusion -- References -- Index. |
| Record Nr. | UNINA-9910806234203321 |
|
Saluzzo Christine
|
||
| New York, : Nova Science Publishers, c2011 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Chiral analysis : advances in spectroscopy, chromatography and emerging methods / / edited by Prasad L. Polavarapu
| Chiral analysis : advances in spectroscopy, chromatography and emerging methods / / edited by Prasad L. Polavarapu |
| Edizione | [Second edition.] |
| Pubbl/distr/stampa | Amsterdam, Netherlands : , : Elsevier, , [2018] |
| Descrizione fisica | 1 online resource (824 pages) |
| Disciplina | 541.223 |
| Soggetto topico |
Chirality
Enantioselective catalysis |
| ISBN |
0-444-64028-2
0-444-64027-4 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto | Part one. Chirality in nature -- Chiral asymmetry in nature / Dilip Kondepudi -- Remote sensing of homochirality : a proxy for the detection of extraterrestrial life / C.H. Lucas Patty [and three others] -- Part two. Spectroscopic methods and analyses -- Light polarization and signal processing in chiroptical instrumentation / Kenneth W. Busch, Marianna A. Busch -- Chiroptical spectroscopic studies on soft aggregates and their interactions / Vijay Raghavan, Prasad L. Polavarapu -- Vibrational optical activity in chiral analysis / Laurence A. Nafie, Rina K. Dukor -- Raman optical activity / Saeideh Ostovar pour [and three others] -- Chiral molecular tools powerful for the preparation of enantiopure compounds and unambiguous determination of their absolute configurations by X-ray crystallography and/or ¹H MNR diamagnetic anistropy / Nobuyuki Harada -- Chiroptical probes for determination of absolute stereochemistry by circular dichroism exciton chirality method / Kuwahara Chunsuke, Ikeda Mari, Habata Yoichi -- Chiral analysis by NMR spectroscopy : chiral solvating agents / Federica Balzano, Gloria Uccello-Barretta, Federica Aiello -- Chiroptical spectroscopy of biofluids / Vladimír Setnička, Lucie Habartová -- Part three. Chromatographic and electromigration methods -- Chiral gas chromatography / Rahul A. Patil, Choyce A. Weatherly, Daniel W. Armstrong -- Chiral liquid chromatography / Muhammad F. Wahab [and three others] -- Enantioseparations by capillary electromigration techniques / Bezhan Chankvetadze -- Recent developments in chiral separations by supercritical fluid chromatography / Roberta Franzini [and four others] -- Chiral separation strategies in mass spectrometry : integration of chromatography, electrophoresis, and gas-phase mobility / James N. Dodds, Jody C. May, John A. McLean -- Part four. Emerging methods -- Cavity-based chiral polarimetry / Dimitris Sofikitis [and three others] -- Quantitative chiral analysis by molecular rotational spectroscopy / Brooks H. Pate [and seven others] -- Chiral rotational spectroscopy / Robert P. Cameron, Jörg B. Götte, Stephen M. Barnett -- Chiral analysis and separation using molecular rotation / Mirianas Chachisvilis. |
| Record Nr. | UNINA-9910583072903321 |
| Amsterdam, Netherlands : , : Elsevier, , [2018] | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Chiral catalyst immobilization and recycling [[electronic resource] /] / edited by D.E. De Vos, I.F.J. Vankelecom, P.A. Jacobs
| Chiral catalyst immobilization and recycling [[electronic resource] /] / edited by D.E. De Vos, I.F.J. Vankelecom, P.A. Jacobs |
| Pubbl/distr/stampa | Weinheim ; ; New York, : Wiley-VCH, c2000 |
| Descrizione fisica | 1 online resource (342 p.) |
| Disciplina |
541.395
547.1395 |
| Altri autori (Persone) |
VosD. E. de (Dirk E.)
VankelecomI. F. J (Ivo F. J.) JacobsPeter A |
| Soggetto topico |
Enantioselective catalysis
Catalysts |
| Soggetto genere / forma | Electronic books. |
| ISBN |
1-281-76408-6
9786611764081 3-527-61314-5 3-527-61315-3 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Chiral Catalvst Immobilization and Recycling; Contents; 1 Enantioselective Heterogeneous Catalysis: Academic and Industrial Challenges; 1.1 Introduction; 1.2 The Industrial Process in General and the Specific Prerequisites for Chiral Catalysts; 1. 2.1 Characteristics of the Manufacture of Enantiomerically Pure Products; 1.2.2 Process Development: Critical Factors for the Application of (Heterogeneous) Enantioselective Catalysts; 1. 2.3 Important Criteria for Enantioselective Catalysts; 1.3 The General Challenges; 1.3.1 For Academia; 1.3.2 For Industry
1.4 Chiral Heterogeneous Catalysts: State of the Art and Future Challenges1.4.1 Heterogeneous Catalysts Modified with a Chiral Auxiliary; 1.4.1.1 Metallic Catalysts on Chiral Supports; 1.4.1.2 Metallic Catalysts Modified with a Low Molecular Weight Chiral Auxiliary; 1.4.1.3 Metal Oxide Catalysts Modified with a Chiral Auxiliary having Low Molecular Weight; 1.4.2 Immobilized and Functionalized Homogeneous Catalysts; 1.4.2.1 lmmobilized Homogeneous Catalysts; 1.4.2.2 Alternative Methods Using Functionalized Ligands; 1.4.3 Catalysts with No Known Heterogeneous or Homogeneous Precedent 1.4.3.1 Insoluble Polypeptides and Gels1.4.3.2 Artificial Catalytic Antibodies; 1.5 Conclusions; References; 2 Catalyst Immobilization on Inorganic Supports; 2.1 Introduction; 2.2 General Considerations; 2.3 Supports; 2.4 Improved Activity of Heterogeneous Complexes; 2.5 Practical Examples; 2.5.1 Covalent Attachment; 2.5.2 Adsorption or Ion-Pair Formation; 2.5.3 Encapsutation; 2.5.4 Entrapment; 2.5.5 Supported Liquid Phase (SLP); 2.5.6 Modification of an Achiral Heterogeneous Catalyst with a Chiral Auxiliary; 2.5.7 Achiral Metal Catalysts on Chiral Supports; References 3 Organic Polymers as a Catalyst Recovery Vehicle3.1 General Introduction; 3.2 Alkene Hydrogenation; 3.3 Carbonyl and Imine Reduction; 3.4 Carbon-Carbon Bond Formation; 3.5 Carbonyl Alkylation; 3.6 Diels-Alder Reactions; 3.7 Enolate Chemistry; 3.8 Strecker Chemistry; 3.9 Asymmetric Dihydroxylation; 3.10 Epoxidation and Epoxide Ring Opening; 3.11 Acylation Catalysts; 3.12 Conclusion; References; 4 Liquid Biphasic Enantioselective Catalysis; 4.1 Introduction; 4.2 Hydrogenation; 4.3 Hydroformylation; 4.4 Oxidation; 4.5 Lewis Acid-Catalyzed Reactions; 4.6 Enzymatic Reactions; 4.7 Summary References5 Immobilized Enzymes in Enantioselective Organic Synthesis; 5.1 Introduction; 5.2 Immobilization; 5.2.1 Methods of Immobilization; 5.2.1.1 Enzymes; 5.2.1.2 Carriers; 5.2.1.3 Binding Enzymes to Carriers; 5.2.1.4 Cross-Linked Enzyme Crystals; 5.2.2 Activity Assay; 5.2.3 Activity Balance; 5.2.4 Cost of Immobilization; 5.3 Operation; 5.3.1 Reactors; 5.3.2 Operational Stability; 5.4 Summary; References; 6 Enantioselective Hydrogenation Catalyzed by Platinum Group Metals Modified by Natural Alkaloids; 6.1 Historical Perspective 6.2 Enantioselective Hydrogenation of Activated Ketones over Platinum |
| Record Nr. | UNINA-9910144279303321 |
| Weinheim ; ; New York, : Wiley-VCH, c2000 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Chiral catalyst immobilization and recycling [[electronic resource] /] / edited by D.E. De Vos, I.F.J. Vankelecom, P.A. Jacobs
| Chiral catalyst immobilization and recycling [[electronic resource] /] / edited by D.E. De Vos, I.F.J. Vankelecom, P.A. Jacobs |
| Pubbl/distr/stampa | Weinheim ; ; New York, : Wiley-VCH, c2000 |
| Descrizione fisica | 1 online resource (342 p.) |
| Disciplina |
541.395
547.1395 |
| Altri autori (Persone) |
VosD. E. de (Dirk E.)
VankelecomI. F. J (Ivo F. J.) JacobsPeter A |
| Soggetto topico |
Enantioselective catalysis
Catalysts |
| ISBN |
1-281-76408-6
9786611764081 3-527-61314-5 3-527-61315-3 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Chiral Catalvst Immobilization and Recycling; Contents; 1 Enantioselective Heterogeneous Catalysis: Academic and Industrial Challenges; 1.1 Introduction; 1.2 The Industrial Process in General and the Specific Prerequisites for Chiral Catalysts; 1. 2.1 Characteristics of the Manufacture of Enantiomerically Pure Products; 1.2.2 Process Development: Critical Factors for the Application of (Heterogeneous) Enantioselective Catalysts; 1. 2.3 Important Criteria for Enantioselective Catalysts; 1.3 The General Challenges; 1.3.1 For Academia; 1.3.2 For Industry
1.4 Chiral Heterogeneous Catalysts: State of the Art and Future Challenges1.4.1 Heterogeneous Catalysts Modified with a Chiral Auxiliary; 1.4.1.1 Metallic Catalysts on Chiral Supports; 1.4.1.2 Metallic Catalysts Modified with a Low Molecular Weight Chiral Auxiliary; 1.4.1.3 Metal Oxide Catalysts Modified with a Chiral Auxiliary having Low Molecular Weight; 1.4.2 Immobilized and Functionalized Homogeneous Catalysts; 1.4.2.1 lmmobilized Homogeneous Catalysts; 1.4.2.2 Alternative Methods Using Functionalized Ligands; 1.4.3 Catalysts with No Known Heterogeneous or Homogeneous Precedent 1.4.3.1 Insoluble Polypeptides and Gels1.4.3.2 Artificial Catalytic Antibodies; 1.5 Conclusions; References; 2 Catalyst Immobilization on Inorganic Supports; 2.1 Introduction; 2.2 General Considerations; 2.3 Supports; 2.4 Improved Activity of Heterogeneous Complexes; 2.5 Practical Examples; 2.5.1 Covalent Attachment; 2.5.2 Adsorption or Ion-Pair Formation; 2.5.3 Encapsutation; 2.5.4 Entrapment; 2.5.5 Supported Liquid Phase (SLP); 2.5.6 Modification of an Achiral Heterogeneous Catalyst with a Chiral Auxiliary; 2.5.7 Achiral Metal Catalysts on Chiral Supports; References 3 Organic Polymers as a Catalyst Recovery Vehicle3.1 General Introduction; 3.2 Alkene Hydrogenation; 3.3 Carbonyl and Imine Reduction; 3.4 Carbon-Carbon Bond Formation; 3.5 Carbonyl Alkylation; 3.6 Diels-Alder Reactions; 3.7 Enolate Chemistry; 3.8 Strecker Chemistry; 3.9 Asymmetric Dihydroxylation; 3.10 Epoxidation and Epoxide Ring Opening; 3.11 Acylation Catalysts; 3.12 Conclusion; References; 4 Liquid Biphasic Enantioselective Catalysis; 4.1 Introduction; 4.2 Hydrogenation; 4.3 Hydroformylation; 4.4 Oxidation; 4.5 Lewis Acid-Catalyzed Reactions; 4.6 Enzymatic Reactions; 4.7 Summary References5 Immobilized Enzymes in Enantioselective Organic Synthesis; 5.1 Introduction; 5.2 Immobilization; 5.2.1 Methods of Immobilization; 5.2.1.1 Enzymes; 5.2.1.2 Carriers; 5.2.1.3 Binding Enzymes to Carriers; 5.2.1.4 Cross-Linked Enzyme Crystals; 5.2.2 Activity Assay; 5.2.3 Activity Balance; 5.2.4 Cost of Immobilization; 5.3 Operation; 5.3.1 Reactors; 5.3.2 Operational Stability; 5.4 Summary; References; 6 Enantioselective Hydrogenation Catalyzed by Platinum Group Metals Modified by Natural Alkaloids; 6.1 Historical Perspective 6.2 Enantioselective Hydrogenation of Activated Ketones over Platinum |
| Record Nr. | UNINA-9910830973703321 |
| Weinheim ; ; New York, : Wiley-VCH, c2000 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Chiral catalyst immobilization and recycling [[electronic resource] /] / edited by D.E. De Vos, I.F.J. Vankelecom, P.A. Jacobs
| Chiral catalyst immobilization and recycling [[electronic resource] /] / edited by D.E. De Vos, I.F.J. Vankelecom, P.A. Jacobs |
| Pubbl/distr/stampa | Weinheim ; ; New York, : Wiley-VCH, c2000 |
| Descrizione fisica | 1 online resource (342 p.) |
| Disciplina |
541.395
547.1395 |
| Altri autori (Persone) |
VosD. E. de (Dirk E.)
VankelecomI. F. J (Ivo F. J.) JacobsPeter A |
| Soggetto topico |
Enantioselective catalysis
Catalysts |
| ISBN |
1-281-76408-6
9786611764081 3-527-61314-5 3-527-61315-3 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Chiral Catalvst Immobilization and Recycling; Contents; 1 Enantioselective Heterogeneous Catalysis: Academic and Industrial Challenges; 1.1 Introduction; 1.2 The Industrial Process in General and the Specific Prerequisites for Chiral Catalysts; 1. 2.1 Characteristics of the Manufacture of Enantiomerically Pure Products; 1.2.2 Process Development: Critical Factors for the Application of (Heterogeneous) Enantioselective Catalysts; 1. 2.3 Important Criteria for Enantioselective Catalysts; 1.3 The General Challenges; 1.3.1 For Academia; 1.3.2 For Industry
1.4 Chiral Heterogeneous Catalysts: State of the Art and Future Challenges1.4.1 Heterogeneous Catalysts Modified with a Chiral Auxiliary; 1.4.1.1 Metallic Catalysts on Chiral Supports; 1.4.1.2 Metallic Catalysts Modified with a Low Molecular Weight Chiral Auxiliary; 1.4.1.3 Metal Oxide Catalysts Modified with a Chiral Auxiliary having Low Molecular Weight; 1.4.2 Immobilized and Functionalized Homogeneous Catalysts; 1.4.2.1 lmmobilized Homogeneous Catalysts; 1.4.2.2 Alternative Methods Using Functionalized Ligands; 1.4.3 Catalysts with No Known Heterogeneous or Homogeneous Precedent 1.4.3.1 Insoluble Polypeptides and Gels1.4.3.2 Artificial Catalytic Antibodies; 1.5 Conclusions; References; 2 Catalyst Immobilization on Inorganic Supports; 2.1 Introduction; 2.2 General Considerations; 2.3 Supports; 2.4 Improved Activity of Heterogeneous Complexes; 2.5 Practical Examples; 2.5.1 Covalent Attachment; 2.5.2 Adsorption or Ion-Pair Formation; 2.5.3 Encapsutation; 2.5.4 Entrapment; 2.5.5 Supported Liquid Phase (SLP); 2.5.6 Modification of an Achiral Heterogeneous Catalyst with a Chiral Auxiliary; 2.5.7 Achiral Metal Catalysts on Chiral Supports; References 3 Organic Polymers as a Catalyst Recovery Vehicle3.1 General Introduction; 3.2 Alkene Hydrogenation; 3.3 Carbonyl and Imine Reduction; 3.4 Carbon-Carbon Bond Formation; 3.5 Carbonyl Alkylation; 3.6 Diels-Alder Reactions; 3.7 Enolate Chemistry; 3.8 Strecker Chemistry; 3.9 Asymmetric Dihydroxylation; 3.10 Epoxidation and Epoxide Ring Opening; 3.11 Acylation Catalysts; 3.12 Conclusion; References; 4 Liquid Biphasic Enantioselective Catalysis; 4.1 Introduction; 4.2 Hydrogenation; 4.3 Hydroformylation; 4.4 Oxidation; 4.5 Lewis Acid-Catalyzed Reactions; 4.6 Enzymatic Reactions; 4.7 Summary References5 Immobilized Enzymes in Enantioselective Organic Synthesis; 5.1 Introduction; 5.2 Immobilization; 5.2.1 Methods of Immobilization; 5.2.1.1 Enzymes; 5.2.1.2 Carriers; 5.2.1.3 Binding Enzymes to Carriers; 5.2.1.4 Cross-Linked Enzyme Crystals; 5.2.2 Activity Assay; 5.2.3 Activity Balance; 5.2.4 Cost of Immobilization; 5.3 Operation; 5.3.1 Reactors; 5.3.2 Operational Stability; 5.4 Summary; References; 6 Enantioselective Hydrogenation Catalyzed by Platinum Group Metals Modified by Natural Alkaloids; 6.1 Historical Perspective 6.2 Enantioselective Hydrogenation of Activated Ketones over Platinum |
| Record Nr. | UNINA-9910841240203321 |
| Weinheim ; ; New York, : Wiley-VCH, c2000 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
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Enantioselection in asymmetric catalysis / / Ilya Gridnev and Pavel A. Dub
| Enantioselection in asymmetric catalysis / / Ilya Gridnev and Pavel A. Dub |
| Autore | Gridnev Ilya <1963, > |
| Pubbl/distr/stampa | Boca Raton : , : CRC Press, , [2017] |
| Descrizione fisica | 1 online resource (247 pages) : illustrations |
| Disciplina | 541/.395 |
| Soggetto topico |
Enantioselective catalysis
Catalysis Asymmetric synthesis |
| ISBN |
1-315-35334-2
1-315-37041-7 1-4987-2655-0 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto | Chapter 1. Transition metal-catalyzed hydrogenation -- Chapter 2. Other enantioselective reactions catalyzed by transition metals -- Chapter 3. Mechanism of enantioselection in organocatalytic reactions. |
| Record Nr. | UNINA-9910149364703321 |
|
Gridnev Ilya <1963, >
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| Boca Raton : , : CRC Press, , [2017] | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Soggetto topico
-
Enantioselective catalysis
(27)
- Asymmetric synthesis (10)
- Ligands (6)
- Addition reactions (3)
- Catalysts (3)