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Arrow pushing in inorganic chemistry : a logical approach to the chemistry of the main group elements / / Abhik Ghosh, Steffen Berg
| Arrow pushing in inorganic chemistry : a logical approach to the chemistry of the main group elements / / Abhik Ghosh, Steffen Berg |
| Autore | Ghosh Abhik |
| Pubbl/distr/stampa | Hoboken, New Jersey : , : John Wiley & Sons, Ltd., , 2014 |
| Descrizione fisica | 1 online resource (347 p.) |
| Disciplina | 540.151 |
| Soggetto topico |
Chemistry, Inorganic - Experiments
Chemistry, Inorganic |
| ISBN |
1-118-92452-5
1-118-92453-3 1-118-92454-1 |
| Formato | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Cover; Title Page; Contents; Foreword; Preface; Acknowledgments; Chapter 1 A Collection of Basic Concepts; 1.1 Nucleophiles and Electrophiles: The SN2 Paradigm; 1.2 What Makes for a Good Nucleophile?; 1.3 Hard and Soft Acids and Bases: The HSAB Principle; 1.4 pKa Values: What Makes for a Good Leaving Group?; 1.5 Redox Potentials; 1.6 Thermodynamic Control: Bond Dissociation Energies (BDEs); 1.7 Bimolecular \beta-Elimination (E2); 1.8 Proton Transfers (PTs); 1.9 Elementary Associative and Dissociative Processes (A and D); 1.10 Two-Step Ionic Mechanisms: The SN2-Si Pathway
1.11 Two-Step Ionic Mechanisms: The SN1 and E1 Pathways1.12 Electrophilic Addition to Carbon-Carbon Multiple Bonds; 1.13 Electrophilic Substitution on Aromatics: Addition-Elimination; 1.14 Nucleophilic Addition to Carbon-Heteroatom Multiple Bonds; 1.15 Carbanions and Related Synthetic Intermediates; 1.16 Carbenes; 1.17 Oxidative Additions and Reductive Eliminations; 1.18 Migrations; 1.19 Ligand Exchange Reactions; 1.20 Radical Reactions; 1.21 Pericyclic Reactions; 1.22 Arrow Pushing: Organic Paradigms; 1.23 Inorganic Arrow Pushing: Thinking Like a Lone Pair 1.24 Definitions: Valence, Oxidation State, Formal Charge, and Coordination Number1.25 Elements of Bonding in Hypervalent Compounds; 1.26 The \lambda Convention; 1.27 The Inert Pair Effect; 1.28 Summary; Further Reading; Chapter 2 The s-Block Elements: Alkali and Alkaline Earth Metals; 2.1 Solubility; 2.2 The s-Block Metals as Reducing Agents; 2.3 Reductive Couplings; 2.4 Dissolving Metal Reactions; 2.5 Organolithium and Organomagnesium Compounds; 2.6 Dihydrogen Activation by Frustrated Lewis Pairs (FLPs); 2.7 A MgI-MgI Bond; 2.8 Summary; Further Reading; Chapter 3 Group 13 Elements 3.1 Group 13 Compounds as Lewis Acids3.2 Hydroboration; 3.3 Group 13-Based Reducing Agents; 3.4 From Borazine to Gallium Arsenide: 13-15 Compounds; 3.5 Low-Oxidation-State Compounds; 3.6 The Boryl Anion; 3.7 Indium-Mediated Allylations; 3.8 Thallium Reagents; 3.9 Summary; Further Reading; Chapter 4 Group 14 Elements; 4.1 Silyl Protecting Groups; 4.2 A Case Study: Peterson Olefination; 4.3 Silanes; 4.4 The \beta-Silicon Effect: Allylsilanes; 4.5 Silyl Anions; 4.6 Organostannanes; 4.7 Polystannanes; 4.8* Carbene and Alkene Analogs; 4.9* Alkyne Analogs; 4.10 Silyl Cations 4.11 Glycol Cleavage by Lead Tetraacetate4.12 Summary; Further Reading; Chapter 5A Nitrogen; 5A.1 Ammonia and Some Other Common Nitrogen Nucleophiles; 5A.2 Some Common Nitrogen Electrophiles: Oxides, Oxoacids, and Oxoanions; 5A.3 N-N Bonded Molecules: Synthesis of Hydrazine; 5A.4 Multiple Bond Formation: Synthesis of Sodium Azide; 5A.5 Thermal Decomposition of NH4NO2 and NH4NO3; 5A.6 Diazonium Salts; 5A.7 Azo Compounds and Diazene; 5A.8* Imines and Related Functional Groups: The Wolff-Kishner Reduction and the Shapiro Reaction; 5A.9 Diazo Compounds 5A.10 Nitrenes and Nitrenoids: The Curtius Rearrangement |
| Record Nr. | UNINA-9910139131903321 |
Ghosh Abhik
|
||
| Hoboken, New Jersey : , : John Wiley & Sons, Ltd., , 2014 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Arrow pushing in inorganic chemistry : a logical approach to the chemistry of the main group elements / / Abhik Ghosh, Steffen Berg
| Arrow pushing in inorganic chemistry : a logical approach to the chemistry of the main group elements / / Abhik Ghosh, Steffen Berg |
| Autore | Ghosh Abhik |
| Pubbl/distr/stampa | Hoboken, New Jersey : , : John Wiley & Sons, Ltd., , 2014 |
| Descrizione fisica | 1 online resource (347 p.) |
| Disciplina | 540.151 |
| Soggetto topico |
Chemistry, Inorganic - Experiments
Chemistry, Inorganic |
| ISBN |
1-118-92452-5
1-118-92453-3 1-118-92454-1 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Cover; Title Page; Contents; Foreword; Preface; Acknowledgments; Chapter 1 A Collection of Basic Concepts; 1.1 Nucleophiles and Electrophiles: The SN2 Paradigm; 1.2 What Makes for a Good Nucleophile?; 1.3 Hard and Soft Acids and Bases: The HSAB Principle; 1.4 pKa Values: What Makes for a Good Leaving Group?; 1.5 Redox Potentials; 1.6 Thermodynamic Control: Bond Dissociation Energies (BDEs); 1.7 Bimolecular \beta-Elimination (E2); 1.8 Proton Transfers (PTs); 1.9 Elementary Associative and Dissociative Processes (A and D); 1.10 Two-Step Ionic Mechanisms: The SN2-Si Pathway
1.11 Two-Step Ionic Mechanisms: The SN1 and E1 Pathways1.12 Electrophilic Addition to Carbon-Carbon Multiple Bonds; 1.13 Electrophilic Substitution on Aromatics: Addition-Elimination; 1.14 Nucleophilic Addition to Carbon-Heteroatom Multiple Bonds; 1.15 Carbanions and Related Synthetic Intermediates; 1.16 Carbenes; 1.17 Oxidative Additions and Reductive Eliminations; 1.18 Migrations; 1.19 Ligand Exchange Reactions; 1.20 Radical Reactions; 1.21 Pericyclic Reactions; 1.22 Arrow Pushing: Organic Paradigms; 1.23 Inorganic Arrow Pushing: Thinking Like a Lone Pair 1.24 Definitions: Valence, Oxidation State, Formal Charge, and Coordination Number1.25 Elements of Bonding in Hypervalent Compounds; 1.26 The \lambda Convention; 1.27 The Inert Pair Effect; 1.28 Summary; Further Reading; Chapter 2 The s-Block Elements: Alkali and Alkaline Earth Metals; 2.1 Solubility; 2.2 The s-Block Metals as Reducing Agents; 2.3 Reductive Couplings; 2.4 Dissolving Metal Reactions; 2.5 Organolithium and Organomagnesium Compounds; 2.6 Dihydrogen Activation by Frustrated Lewis Pairs (FLPs); 2.7 A MgI-MgI Bond; 2.8 Summary; Further Reading; Chapter 3 Group 13 Elements 3.1 Group 13 Compounds as Lewis Acids3.2 Hydroboration; 3.3 Group 13-Based Reducing Agents; 3.4 From Borazine to Gallium Arsenide: 13-15 Compounds; 3.5 Low-Oxidation-State Compounds; 3.6 The Boryl Anion; 3.7 Indium-Mediated Allylations; 3.8 Thallium Reagents; 3.9 Summary; Further Reading; Chapter 4 Group 14 Elements; 4.1 Silyl Protecting Groups; 4.2 A Case Study: Peterson Olefination; 4.3 Silanes; 4.4 The \beta-Silicon Effect: Allylsilanes; 4.5 Silyl Anions; 4.6 Organostannanes; 4.7 Polystannanes; 4.8* Carbene and Alkene Analogs; 4.9* Alkyne Analogs; 4.10 Silyl Cations 4.11 Glycol Cleavage by Lead Tetraacetate4.12 Summary; Further Reading; Chapter 5A Nitrogen; 5A.1 Ammonia and Some Other Common Nitrogen Nucleophiles; 5A.2 Some Common Nitrogen Electrophiles: Oxides, Oxoacids, and Oxoanions; 5A.3 N-N Bonded Molecules: Synthesis of Hydrazine; 5A.4 Multiple Bond Formation: Synthesis of Sodium Azide; 5A.5 Thermal Decomposition of NH4NO2 and NH4NO3; 5A.6 Diazonium Salts; 5A.7 Azo Compounds and Diazene; 5A.8* Imines and Related Functional Groups: The Wolff-Kishner Reduction and the Shapiro Reaction; 5A.9 Diazo Compounds 5A.10 Nitrenes and Nitrenoids: The Curtius Rearrangement |
| Record Nr. | UNINA-9910830479303321 |
|
Ghosh Abhik
|
||
| Hoboken, New Jersey : , : John Wiley & Sons, Ltd., , 2014 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Progress in inorganic chemistry . Volume 59 / / edited by Kenneth D. Karlin
| Progress in inorganic chemistry . Volume 59 / / edited by Kenneth D. Karlin |
| Pubbl/distr/stampa | Hoboken, New Jersey : , : John Wiley & Sons, Inc., , 2014 |
| Descrizione fisica | 1 online resource (593 p.) |
| Disciplina | 546.851 |
| Collana | Progress in Inorganic Chemistry |
| Soggetto topico |
Chemistry, Inorganic - Experiments
Chemistry, Inorganic |
| Soggetto genere / forma | Electronic books. |
| ISBN |
1-118-87003-4
1-118-86999-0 1-118-86988-5 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Progress in Inorganic Chemistry; Contents; Chapter 1: Iron Catalysis in Synthetic Chemistry; I. INTRODUCTION; II. ADDITION REACTIONS; A. Cycloadditions; 1. The [2+2] Cycloaddition; 2. The [3+2] Cycloaddition; 3. The [2+2+2] Cycloaddition; 4. The [4+2] Cycloaddition; B. Cyclopropanation; C. Aziridination and Aziridine Ring-Opening Reactions; D. Carbometalation of C-C Unsaturated Bond; E. Michael Addition; F. Barbier-Type Reaction; G. Kharasch Reaction; III. THE C-C BOND FORMATIONS VIA C-H FUNCTIONALIZATION; A. The C-H Arylation; 1. Direct Arylation With Organometallic Reagents
2. Direct Arylation With Aryl HalidesB. The C-C Bond Formation Via Cross-Dehydrogenative Coupling; 1. The CDC Between Two sp3 C-H Bonds; 2. The CDC Between sp3 and sp2 C-H Bonds; 3. The CDC Between sp3 and sp C-H Bonds; C. The C-C Bond Formation via Cross-Decarboxylative Coupling; D. The C-C Bond Formation via Alkene Insertion; E. Oxidative Coupling of Two C-H Bonds; IV. THE C-H BOND OXIDATION; A. Hydroxylation; B. Epoxidation; C. cis-Dihydroxylation; V. CROSS-COUPLING REACTIONS; A. Alkenyl Derivatives as Coupling Partners; B. Aryl Derivatives as Coupling Partners C. Alkyl Derivatives as Coupling Partners1. Low-Valent Iron Complex in Cross-Coupling Reactions; D. Acyl Derivatives as Coupling Partners; E. Iron-Catalyzed C-O, C-S, and C-N Cross-Coupling Reaction; F. Iron-Catalyzed Mizoraki-Heck Reaction; G. Iron-Catalyzed Negishi Coupling Reaction; H. Suzuki-Miyaura Coupling Reaction; I. Sonogashira Reaction; J. Mechanism of Cross-Coupling Reactions; K. Hydrocarboxylation; L. Enyne Cross-Coupling Reaction; VI. DIRECT C-N BOND FORMATION VIA C-H OXIDATION; VII. IRON-CATALYZED AMINATION; A. Allylic Aminations; B. Intramolecular Allylic Amination VIII. SULFOXIDATIONS AND SYNTHESIS OF SULFOXIMINES, SULFIMIDES, AND SULFOXIMIDESA. Sulfoxidation; B. Synthesis of Sulfoximines, Sulfimides, and Sulfoximides; 1. Mechanism; IX. REDUCTION REACTIONS; A. Hydrosilylation of Alkenes; B. Hydrosilylation of Aldehydes and Ketones; C. Hydrogenation of C-C Unsaturated Bonds; D. Hydrogenation of Ketones; E. Hydrogenation of Imines; F. Reduction of Nitroarene to Anilines; G. Hydrogenation of Carbon Dioxide and Bicarbonate; H. Amide Reduction; I. Reductive Aminations; X. TRIFLUOROMETHYLATION; XI. CONCLUSION; ACKNOWLEDGMENTS; ABBREVIATIONS; REFERENCES Chapter 2: A New Paradigm for Photodynamic Therapy Drug Design: Multifunctional, Supramolecular DNA Photomodification Agents Featuring Ru(II)/Os(II) Light Absorbers Coupled to Pt(II) or Rh(III) Bioactive SitesI. INTRODUCTION; A. Scope and Limitations; B. Cancer; C. Deoxyribonucleic Acid as a Target; II. PHOTODYNAMIC THERAPY; A. Requirements; B. Traditional PDT Agents; C. Ruthenium(II) Light Absorbers as PDT Agents; III. PLATINUM AND RHODIUM CENTERS AS BIOACTIVE SITES; A. Platinum(II) Based Chemotherapeutics; 1. Cisplatin; 2. Second and Third Generation Pt(II) Drugs B. Rhodium as a Bioactive Site |
| Record Nr. | UNINA-9910132195403321 |
| Hoboken, New Jersey : , : John Wiley & Sons, Inc., , 2014 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Progress in inorganic chemistry . Volume 59 / / edited by Kenneth D. Karlin
| Progress in inorganic chemistry . Volume 59 / / edited by Kenneth D. Karlin |
| Pubbl/distr/stampa | Hoboken, New Jersey : , : John Wiley & Sons, Inc., , 2014 |
| Descrizione fisica | 1 online resource (593 p.) |
| Disciplina | 546.851 |
| Collana | Progress in Inorganic Chemistry |
| Soggetto topico |
Chemistry, Inorganic - Experiments
Chemistry, Inorganic |
| ISBN |
1-118-87003-4
1-118-86999-0 1-118-86988-5 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Progress in Inorganic Chemistry; Contents; Chapter 1: Iron Catalysis in Synthetic Chemistry; I. INTRODUCTION; II. ADDITION REACTIONS; A. Cycloadditions; 1. The [2+2] Cycloaddition; 2. The [3+2] Cycloaddition; 3. The [2+2+2] Cycloaddition; 4. The [4+2] Cycloaddition; B. Cyclopropanation; C. Aziridination and Aziridine Ring-Opening Reactions; D. Carbometalation of C-C Unsaturated Bond; E. Michael Addition; F. Barbier-Type Reaction; G. Kharasch Reaction; III. THE C-C BOND FORMATIONS VIA C-H FUNCTIONALIZATION; A. The C-H Arylation; 1. Direct Arylation With Organometallic Reagents
2. Direct Arylation With Aryl HalidesB. The C-C Bond Formation Via Cross-Dehydrogenative Coupling; 1. The CDC Between Two sp3 C-H Bonds; 2. The CDC Between sp3 and sp2 C-H Bonds; 3. The CDC Between sp3 and sp C-H Bonds; C. The C-C Bond Formation via Cross-Decarboxylative Coupling; D. The C-C Bond Formation via Alkene Insertion; E. Oxidative Coupling of Two C-H Bonds; IV. THE C-H BOND OXIDATION; A. Hydroxylation; B. Epoxidation; C. cis-Dihydroxylation; V. CROSS-COUPLING REACTIONS; A. Alkenyl Derivatives as Coupling Partners; B. Aryl Derivatives as Coupling Partners C. Alkyl Derivatives as Coupling Partners1. Low-Valent Iron Complex in Cross-Coupling Reactions; D. Acyl Derivatives as Coupling Partners; E. Iron-Catalyzed C-O, C-S, and C-N Cross-Coupling Reaction; F. Iron-Catalyzed Mizoraki-Heck Reaction; G. Iron-Catalyzed Negishi Coupling Reaction; H. Suzuki-Miyaura Coupling Reaction; I. Sonogashira Reaction; J. Mechanism of Cross-Coupling Reactions; K. Hydrocarboxylation; L. Enyne Cross-Coupling Reaction; VI. DIRECT C-N BOND FORMATION VIA C-H OXIDATION; VII. IRON-CATALYZED AMINATION; A. Allylic Aminations; B. Intramolecular Allylic Amination VIII. SULFOXIDATIONS AND SYNTHESIS OF SULFOXIMINES, SULFIMIDES, AND SULFOXIMIDESA. Sulfoxidation; B. Synthesis of Sulfoximines, Sulfimides, and Sulfoximides; 1. Mechanism; IX. REDUCTION REACTIONS; A. Hydrosilylation of Alkenes; B. Hydrosilylation of Aldehydes and Ketones; C. Hydrogenation of C-C Unsaturated Bonds; D. Hydrogenation of Ketones; E. Hydrogenation of Imines; F. Reduction of Nitroarene to Anilines; G. Hydrogenation of Carbon Dioxide and Bicarbonate; H. Amide Reduction; I. Reductive Aminations; X. TRIFLUOROMETHYLATION; XI. CONCLUSION; ACKNOWLEDGMENTS; ABBREVIATIONS; REFERENCES Chapter 2: A New Paradigm for Photodynamic Therapy Drug Design: Multifunctional, Supramolecular DNA Photomodification Agents Featuring Ru(II)/Os(II) Light Absorbers Coupled to Pt(II) or Rh(III) Bioactive SitesI. INTRODUCTION; A. Scope and Limitations; B. Cancer; C. Deoxyribonucleic Acid as a Target; II. PHOTODYNAMIC THERAPY; A. Requirements; B. Traditional PDT Agents; C. Ruthenium(II) Light Absorbers as PDT Agents; III. PLATINUM AND RHODIUM CENTERS AS BIOACTIVE SITES; A. Platinum(II) Based Chemotherapeutics; 1. Cisplatin; 2. Second and Third Generation Pt(II) Drugs B. Rhodium as a Bioactive Site |
| Record Nr. | UNINA-9910830249403321 |
| Hoboken, New Jersey : , : John Wiley & Sons, Inc., , 2014 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
