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ACS organic & inorganic Au
| ACS organic & inorganic Au |
| Pubbl/distr/stampa | [Columbus, OH] : , : American Chemical Society, , [2021]- |
| Descrizione fisica | 1 online resource |
| Disciplina | 547 |
| Soggetto topico |
Chemistry, Organic
Chemistry, Inorganic Organometallic chemistry |
| Soggetto genere / forma |
Periodical
Periodicals. |
| ISSN | 2694-247X |
| Formato | Materiale a stampa  |
| Livello bibliografico | Periodico |
| Lingua di pubblicazione | eng |
| Altri titoli varianti |
ACS organic and inorganic Au
American Chemical Society organic and inorganic Au ACS organic and inorganic, gold |
| Record Nr. | UNISA-996453749303316 |
| [Columbus, OH] : , : American Chemical Society, , [2021]- | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. di Salerno | ||
| ||
ACS organic & inorganic Au
| ACS organic & inorganic Au |
| Pubbl/distr/stampa | [Columbus, OH] : , : American Chemical Society, , [2021]- |
| Descrizione fisica | 1 online resource |
| Disciplina | 547 |
| Soggetto topico |
Chemistry, Organic
Chemistry, Inorganic Organometallic chemistry |
| Soggetto genere / forma |
Periodical
Periodicals. |
| ISSN | 2694-247X |
| Formato | Materiale a stampa |
| Livello bibliografico | Periodico |
| Lingua di pubblicazione | eng |
| Altri titoli varianti |
ACS organic and inorganic Au
American Chemical Society organic and inorganic Au ACS organic and inorganic, gold |
| Record Nr. | UNINA-9910508486603321 |
| [Columbus, OH] : , : American Chemical Society, , [2021]- | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Acta chemica Scandinavica
| Acta chemica Scandinavica |
| Pubbl/distr/stampa | Copenhagen, : Munksgaard, ©1989-©1999 |
| Descrizione fisica | 1 online resource |
| Disciplina | 540.5 |
| Soggetto topico |
Chemistry
Biochemistry Chemistry, Inorganic Chemistry, Organic Chemistry, Physical biochemistry chemistry Chimie organique - Périodiques Chimie physique et théorique - Périodiques 35.00 chemistry: general Chemie |
| Soggetto genere / forma |
Periodical
Periodicals. |
| Formato | Materiale a stampa |
| Livello bibliografico | Periodico |
| Lingua di pubblicazione | eng |
| Record Nr. | UNISA-996205051403316 |
| Copenhagen, : Munksgaard, ©1989-©1999 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. di Salerno | ||
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Advanced inorganic chemistry : applications in everyday life / / Narayan S. Hosmane, Northern Illinois University
| Advanced inorganic chemistry : applications in everyday life / / Narayan S. Hosmane, Northern Illinois University |
| Autore | Hosmane Narayan S. |
| Pubbl/distr/stampa | London : , : Academic Press, and imprint of Elsevier, , [2017] |
| Descrizione fisica | 1 online resource (xix, 255 pages) : illustrations (some color) |
| Disciplina | 546 |
| Collana | Gale eBooks |
| Soggetto topico | Chemistry, Inorganic |
| ISBN | 0-12-801993-X |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto | Foundations: concepts in chemical bonding and stereochemistry. Electronic structure: quantum theory revisited. Introduction: Why do we need to know quantum theory? ; Quantum mechanical description of the hydrogen atom -- Molecular geometries. Introduction: Why do we need to know molecular geometries or shapes of molecules? ; Shapes of molecules- valence shell electron pair repulsion (VSEPR) model ; Nonrigid shapes of molecules (stereochemistry) -- Molecular symmetry- Part I: Point group assignment. Introduction: Is it necessary to learn molecular symmetry? ; Elements of symmetry ; Point groups -- Group theory: matrix representation and character tables. Introduction: Is it necessary to learn group theory? ; Other properties of symmetry operations ; Applications to molecular structure and properties ; Examples of other structures ; Molecular spectroscopy -- Advanced topics 1: Introduction to ligands and metal complexes. Ligands and d-block metal complexes. Introduction: Is it necessary to know about ligands and metal complexes? ; Transition metals ; Nomenclature of coordination compounds ; Isomerism in coordination compounds -- Review of bonding theories for d-block metal complexes. Introduction: Why bonding theories of metal complexes are important? ; Valence bond theory ; Crystal field theory ; Molecular orbital theory -- Coordination chemistry: reaction mechanisms and their influencing factors. Introduction: What makes coordination chemistry interesting? ; Modes of substitution reaction mechanisms ; Complications involving metal complexes ; Activation parameters ; Examples of different coordination numbers with geometries and factors influencing reaction mechanism -- Advanced topics 2: electronic spectra, clusters & isolobal fragments. Coordination chemistry: electronic spectra. Introduction: why do we need to learn electronic spectra? ; Electronic spectra ; Tanabe- sugano diagrams ; Charge transfer spectra -- Cluster chemistry and isolobal fragments. Introduction: Role of cluster chemistry in nature ; Clusters of boranes, carboranes, and their metal complexes ; Clusters of other main group elements and transition metals ; Extension of Wade's rules beyond boron clusters -- Advanced topics 3: Organometallic chemistry and catalysis. Organometallic chemistry. Introduction: What is in organometallic chemistry? ; Definitions and nomenclature of organometallic compounds ; Molecular formulas and structures of organometallic compounds -- Catalysis with organometallic. Introduction: What is so special about catalytic processes in our daily life? ; Homogeneous catalysts ; Hydrogenation catalysts ; Other catalytic processes -- Advanced topics 4: Bioinorganic chemistry and applications. Introduction ; History and medical relevance ; Transport and storage of metal ions ; Oxygen transport and activation proteins ; Biomineralization. |
| Record Nr. | UNINA-9910583076003321 |
Hosmane Narayan S.
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| London : , : Academic Press, and imprint of Elsevier, , [2017] | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
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Advances in functional inorganic materials prepared by wet chemical methods / / edited by Aleksej Zarkov, Aivaras Kareiva and Loreta Tamasauskaite-Tamasiunaite
| Advances in functional inorganic materials prepared by wet chemical methods / / edited by Aleksej Zarkov, Aivaras Kareiva and Loreta Tamasauskaite-Tamasiunaite |
| Pubbl/distr/stampa | Basel : , : MDPI - Multidisciplinary Digital Publishing Institute, , 2022 |
| Descrizione fisica | 1 online resource (154 pages) |
| Disciplina | 546 |
| Soggetto topico |
Chemistry, Inorganic
Chemistry |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNINA-9910674373003321 |
| Basel : , : MDPI - Multidisciplinary Digital Publishing Institute, , 2022 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Advances in inorganic chemistry . Volume sixty seven NOx related chemistry / / edited by Rudi van Eldik, José A. Olabe ; contributors, Dennis Awasabisah [and nineteen others]
| Advances in inorganic chemistry . Volume sixty seven NOx related chemistry / / edited by Rudi van Eldik, José A. Olabe ; contributors, Dennis Awasabisah [and nineteen others] |
| Pubbl/distr/stampa | Waltham, Massachusetts : , : Academic Press, , 2015 |
| Descrizione fisica | 1 online resource (388 p.) |
| Disciplina | 546 |
| Collana | Advances in Inorganic Chemistry |
| Soggetto topico |
Nitrogen oxides
Chemistry, Inorganic |
| Soggetto genere / forma | Electronic books. |
| ISBN | 0-12-801837-2 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Front Cover; NOx Related Chemistry; Copyright; Contents; Contributors; Preface; Chapter One: NOx Linkage Isomerization in Metal Complexes; 1. Introduction; 1.1. Modes of binding of NOx moieties in monometallic complexes; 1.1.1. Nitric oxide complexes; 1.1.2. NO2 complexes; 1.1.3. NO3 complexes; 1.2. Methods that induce linkage isomerization; 1.3. Techniques for detecting linkage isomers; 1.4. Factors that affect linkage isomerization; 2. Linkage Isomerism in Non-Porphyrin NOx Complexes; 2.1. Group 6 (Cr and Mo) complexes; 2.1.1. NO complexes; 2.1.2. NO2 complexes
2.2. Group 7 (Mn and Re) complexes2.2.1. NO complexes; 2.3. Group 8 (Fe, Ru, and Os) complexes; 2.3.1. NO complexes; 2.3.2. NO2 complexes; 2.3.3. NO3 complexes; 2.4. Group 9 (Co, Rh, and Ir) complexes; 2.4.1. NO complexes; 2.4.2. NO2 complexes; 2.5. Group 10 (Ni, Pd, and Pt) complexes; 2.5.1. NO complexes; 2.5.2. NO2 complexes; 3. Linkage Isomerism in NOx-Coordinated Metalloporphyrins; 3.1. Manganese NOx porphyrins; 3.2. Ruthenium and iron NOx porphyrin complexes; 3.3. Cobalt NOx porphyrins; 3.4. Hyponitrite complexes of transition metal porphyrins 3.4.1. The nitric oxide dimer and its reduced forms3.4.2. Metal hyponitrite binding modes; 3.5. Heme proteins; 4. Conclusion; Acknowledgment; References; Chapter Two: Three Redox States of Metallonitrosyls in Aqueous Solution; 1. Introduction: General Scope; 2. Complexes with n=6; 2.1. Structure, spectroscopy, and electronic description. Total spin S=0. Dominant M-NO+ distribution; 2.1.1. Significance and importance of the ``back-bonding model ́ ́; 2.1.2. Role of the σ*-FeNO interaction in the trans-effect exerted over NO; 2.1.3. ``Negative ́ ́ trans-influence of the nitrosyl moiety 2.1.4. Different reactivity of the L ligand trans to NO2.1.5. Other metal centers: Validity of the formal charge descriptions; 2.1.6. Frontier MOs; 2.2. Formation and dissociation of NO-complexes: Nitrosylations and denitrosylations; 2.2.1. Reactions with M(II) precursors (M=Fe, Ru): Proton-assisted dehydration of bound nitrite; 2.2.2. Reactions with high-spin M(III) precursors; 2.2.3. Reactions with low-spin, nonheme Fe(III) systems; 2.2.4. Nitrosylation of nitrile-hydratase and models; 2.2.5. Nitrosylation of low-spin Fe(III)-heme models, [FeIII(TMPS)(CN)(H2O)]4- and [FeIII(TMPS)(CN)2]5- 2.2.6. Nitrosylations of other [FeIII(CN)5(Y)]n- complexes2.2.7. Nitrosylations with Ru(III) precursors; 2.2.8. Why is the release of NO so fast for the {FeIINO+} heme-nitrosyls?; 2.3. Electrophilic reactivity toward O-, N-, and S-binding nucleophiles; 2.3.1. General approach to electrophilic reactivity; 2.3.2. Correlation of nucleophilic rates with M(NO+)/M(NO) redox potentials; 3. Complexes with n=7; 3.1. Structure, spectroscopy, and electronic descriptions for 5- and 6-coordination. Total spin S=1/2 or 3/2. Alternative...; 3.1.1. Heme and nonheme 5C nitrosyls with S=1/2 3.1.2. Nonheme and heme 6C nitrosyls with S=1/2 |
| Record Nr. | UNINA-9910460523103321 |
| Waltham, Massachusetts : , : Academic Press, , 2015 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Advances in inorganic chemistry . Volume sixty seven NOx related chemistry / / edited by Rudi van Eldik, José A. Olabe ; contributors, Dennis Awasabisah [and nineteen others]
| Advances in inorganic chemistry . Volume sixty seven NOx related chemistry / / edited by Rudi van Eldik, José A. Olabe ; contributors, Dennis Awasabisah [and nineteen others] |
| Pubbl/distr/stampa | Waltham, Massachusetts : , : Academic Press, , 2015 |
| Descrizione fisica | 1 online resource (388 p.) |
| Disciplina | 546 |
| Collana | Advances in Inorganic Chemistry |
| Soggetto topico |
Nitrogen oxides
Chemistry, Inorganic |
| ISBN | 0-12-801837-2 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Front Cover; NOx Related Chemistry; Copyright; Contents; Contributors; Preface; Chapter One: NOx Linkage Isomerization in Metal Complexes; 1. Introduction; 1.1. Modes of binding of NOx moieties in monometallic complexes; 1.1.1. Nitric oxide complexes; 1.1.2. NO2 complexes; 1.1.3. NO3 complexes; 1.2. Methods that induce linkage isomerization; 1.3. Techniques for detecting linkage isomers; 1.4. Factors that affect linkage isomerization; 2. Linkage Isomerism in Non-Porphyrin NOx Complexes; 2.1. Group 6 (Cr and Mo) complexes; 2.1.1. NO complexes; 2.1.2. NO2 complexes
2.2. Group 7 (Mn and Re) complexes2.2.1. NO complexes; 2.3. Group 8 (Fe, Ru, and Os) complexes; 2.3.1. NO complexes; 2.3.2. NO2 complexes; 2.3.3. NO3 complexes; 2.4. Group 9 (Co, Rh, and Ir) complexes; 2.4.1. NO complexes; 2.4.2. NO2 complexes; 2.5. Group 10 (Ni, Pd, and Pt) complexes; 2.5.1. NO complexes; 2.5.2. NO2 complexes; 3. Linkage Isomerism in NOx-Coordinated Metalloporphyrins; 3.1. Manganese NOx porphyrins; 3.2. Ruthenium and iron NOx porphyrin complexes; 3.3. Cobalt NOx porphyrins; 3.4. Hyponitrite complexes of transition metal porphyrins 3.4.1. The nitric oxide dimer and its reduced forms3.4.2. Metal hyponitrite binding modes; 3.5. Heme proteins; 4. Conclusion; Acknowledgment; References; Chapter Two: Three Redox States of Metallonitrosyls in Aqueous Solution; 1. Introduction: General Scope; 2. Complexes with n=6; 2.1. Structure, spectroscopy, and electronic description. Total spin S=0. Dominant M-NO+ distribution; 2.1.1. Significance and importance of the ``back-bonding model ́ ́; 2.1.2. Role of the σ*-FeNO interaction in the trans-effect exerted over NO; 2.1.3. ``Negative ́ ́ trans-influence of the nitrosyl moiety 2.1.4. Different reactivity of the L ligand trans to NO2.1.5. Other metal centers: Validity of the formal charge descriptions; 2.1.6. Frontier MOs; 2.2. Formation and dissociation of NO-complexes: Nitrosylations and denitrosylations; 2.2.1. Reactions with M(II) precursors (M=Fe, Ru): Proton-assisted dehydration of bound nitrite; 2.2.2. Reactions with high-spin M(III) precursors; 2.2.3. Reactions with low-spin, nonheme Fe(III) systems; 2.2.4. Nitrosylation of nitrile-hydratase and models; 2.2.5. Nitrosylation of low-spin Fe(III)-heme models, [FeIII(TMPS)(CN)(H2O)]4- and [FeIII(TMPS)(CN)2]5- 2.2.6. Nitrosylations of other [FeIII(CN)5(Y)]n- complexes2.2.7. Nitrosylations with Ru(III) precursors; 2.2.8. Why is the release of NO so fast for the {FeIINO+} heme-nitrosyls?; 2.3. Electrophilic reactivity toward O-, N-, and S-binding nucleophiles; 2.3.1. General approach to electrophilic reactivity; 2.3.2. Correlation of nucleophilic rates with M(NO+)/M(NO) redox potentials; 3. Complexes with n=7; 3.1. Structure, spectroscopy, and electronic descriptions for 5- and 6-coordination. Total spin S=1/2 or 3/2. Alternative...; 3.1.1. Heme and nonheme 5C nitrosyls with S=1/2 3.1.2. Nonheme and heme 6C nitrosyls with S=1/2 |
| Record Nr. | UNINA-9910787446903321 |
| Waltham, Massachusetts : , : Academic Press, , 2015 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Advances in inorganic chemistry . Volume sixty seven NOx related chemistry / / edited by Rudi van Eldik, José A. Olabe ; contributors, Dennis Awasabisah [and nineteen others]
| Advances in inorganic chemistry . Volume sixty seven NOx related chemistry / / edited by Rudi van Eldik, José A. Olabe ; contributors, Dennis Awasabisah [and nineteen others] |
| Pubbl/distr/stampa | Waltham, Massachusetts : , : Academic Press, , 2015 |
| Descrizione fisica | 1 online resource (388 p.) |
| Disciplina | 546 |
| Collana | Advances in Inorganic Chemistry |
| Soggetto topico |
Nitrogen oxides
Chemistry, Inorganic |
| ISBN | 0-12-801837-2 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Front Cover; NOx Related Chemistry; Copyright; Contents; Contributors; Preface; Chapter One: NOx Linkage Isomerization in Metal Complexes; 1. Introduction; 1.1. Modes of binding of NOx moieties in monometallic complexes; 1.1.1. Nitric oxide complexes; 1.1.2. NO2 complexes; 1.1.3. NO3 complexes; 1.2. Methods that induce linkage isomerization; 1.3. Techniques for detecting linkage isomers; 1.4. Factors that affect linkage isomerization; 2. Linkage Isomerism in Non-Porphyrin NOx Complexes; 2.1. Group 6 (Cr and Mo) complexes; 2.1.1. NO complexes; 2.1.2. NO2 complexes
2.2. Group 7 (Mn and Re) complexes2.2.1. NO complexes; 2.3. Group 8 (Fe, Ru, and Os) complexes; 2.3.1. NO complexes; 2.3.2. NO2 complexes; 2.3.3. NO3 complexes; 2.4. Group 9 (Co, Rh, and Ir) complexes; 2.4.1. NO complexes; 2.4.2. NO2 complexes; 2.5. Group 10 (Ni, Pd, and Pt) complexes; 2.5.1. NO complexes; 2.5.2. NO2 complexes; 3. Linkage Isomerism in NOx-Coordinated Metalloporphyrins; 3.1. Manganese NOx porphyrins; 3.2. Ruthenium and iron NOx porphyrin complexes; 3.3. Cobalt NOx porphyrins; 3.4. Hyponitrite complexes of transition metal porphyrins 3.4.1. The nitric oxide dimer and its reduced forms3.4.2. Metal hyponitrite binding modes; 3.5. Heme proteins; 4. Conclusion; Acknowledgment; References; Chapter Two: Three Redox States of Metallonitrosyls in Aqueous Solution; 1. Introduction: General Scope; 2. Complexes with n=6; 2.1. Structure, spectroscopy, and electronic description. Total spin S=0. Dominant M-NO+ distribution; 2.1.1. Significance and importance of the ``back-bonding model ́ ́; 2.1.2. Role of the σ*-FeNO interaction in the trans-effect exerted over NO; 2.1.3. ``Negative ́ ́ trans-influence of the nitrosyl moiety 2.1.4. Different reactivity of the L ligand trans to NO2.1.5. Other metal centers: Validity of the formal charge descriptions; 2.1.6. Frontier MOs; 2.2. Formation and dissociation of NO-complexes: Nitrosylations and denitrosylations; 2.2.1. Reactions with M(II) precursors (M=Fe, Ru): Proton-assisted dehydration of bound nitrite; 2.2.2. Reactions with high-spin M(III) precursors; 2.2.3. Reactions with low-spin, nonheme Fe(III) systems; 2.2.4. Nitrosylation of nitrile-hydratase and models; 2.2.5. Nitrosylation of low-spin Fe(III)-heme models, [FeIII(TMPS)(CN)(H2O)]4- and [FeIII(TMPS)(CN)2]5- 2.2.6. Nitrosylations of other [FeIII(CN)5(Y)]n- complexes2.2.7. Nitrosylations with Ru(III) precursors; 2.2.8. Why is the release of NO so fast for the {FeIINO+} heme-nitrosyls?; 2.3. Electrophilic reactivity toward O-, N-, and S-binding nucleophiles; 2.3.1. General approach to electrophilic reactivity; 2.3.2. Correlation of nucleophilic rates with M(NO+)/M(NO) redox potentials; 3. Complexes with n=7; 3.1. Structure, spectroscopy, and electronic descriptions for 5- and 6-coordination. Total spin S=1/2 or 3/2. Alternative...; 3.1.1. Heme and nonheme 5C nitrosyls with S=1/2 3.1.2. Nonheme and heme 6C nitrosyls with S=1/2 |
| Record Nr. | UNINA-9910814434003321 |
| Waltham, Massachusetts : , : Academic Press, , 2015 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
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Analyses of rocks from the laboratory of the United States Geological survey 1880-1899 / / tabulated by F.W. Clarke
| Analyses of rocks from the laboratory of the United States Geological survey 1880-1899 / / tabulated by F.W. Clarke |
| Autore | Clarke Frank Wigglesworth <1847-1931, > |
| Pubbl/distr/stampa | Washington, D.C. : , : Department of the Interior, United States Geological Survey, , 1900 |
| Descrizione fisica | 1 online resource (308 pages) |
| Collana | Bulletin of the United States Geological Survey |
| Soggetto topico |
Rocks - United States
Rocks - Analysis Chemistry, Inorganic |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNINA-9910703892303321 |
|
Clarke Frank Wigglesworth <1847-1931, >
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| Washington, D.C. : , : Department of the Interior, United States Geological Survey, , 1900 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
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Analyses of rocks, with a chapter on analytical methods, laboratory of the United States Geological survey 1880 to 1896 / / by F.W. Clarke and W.F. Hillebrand
| Analyses of rocks, with a chapter on analytical methods, laboratory of the United States Geological survey 1880 to 1896 / / by F.W. Clarke and W.F. Hillebrand |
| Autore | Clarke Frank Wigglesworth <1847-1931, > |
| Pubbl/distr/stampa | Washington, D.C. : , : Department of the Interior, United States Geological Survey, , 1897 |
| Descrizione fisica | 1 online resource (306 pages) |
| Collana | Bulletin of the United States Geological Survey |
| Soggetto topico |
Rocks - Analysis
Chemistry, Inorganic Metallurgical analysis Mineralogy, Determinative |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Altri titoli varianti | Analyses of rocks and analytical methods |
| Record Nr. | UNINA-9910703895503321 |
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Clarke Frank Wigglesworth <1847-1931, >
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| Washington, D.C. : , : Department of the Interior, United States Geological Survey, , 1897 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
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Soggetto topico
-
Chemistry, Inorganic
(533)
- Chemistry (193)
- Inorganic compounds - Synthesis (112)
- Chemistry, Physical and theoretical (17)
- Chemistry, Organic (15)