top

  Info

  • Utilizzare la checkbox di selezione a fianco di ciascun documento per attivare le funzionalità di stampa, invio email, download nei formati disponibili del (i) record.

  Info

  • Utilizzare questo link per rimuovere la selezione effettuata.

Biblioteca

MARC Lista (tabellare)
50 Years of Structure and Bonding – The Anniversary Volume / / edited by D. Michael P. Mingos
50 Years of Structure and Bonding – The Anniversary Volume / / edited by D. Michael P. Mingos
Edizione [1st ed. 2017.]
Pubbl/distr/stampa Cham : , : Springer International Publishing : , : Imprint : Springer, , 2017
Descrizione fisica 1 online resource (VIII, 347 p. 100 illus., 64 illus. in color.)
Disciplina 546
Collana Structure and Bonding
Soggetto topico Chemistry, Inorganic
Chemistry, Physical and theoretical
Inorganic Chemistry
Physical Chemistry
Theoretical and Computational Chemistry
ISBN 3-319-35138-9
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Fullerene Based Materials -- Single Molecule Magnets and Related Phenomena -- Photofunctional Transition Metal Complexes -- High Energy Density Materials -- Recognition of Anions -- Functional Phthalocyanine Molecular Materials -- Molecular Catalysis of Rare Earth Elements -- Electron Density and Chemical Bonding -- Molecular Design and Inorganic Biochemistry -- Optical Spectra and Chemical Bonding in Inorganic Compounds.
Record Nr. UNINA-9910254048003321
Cham : , : Springer International Publishing : , : Imprint : Springer, , 2017
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
ACS organic & inorganic Au
ACS organic & inorganic Au
Pubbl/distr/stampa [Columbus, OH] : , : American Chemical Society, , [2021]-
Descrizione fisica 1 online resource
Disciplina 547
Soggetto topico Chemistry, Organic
Chemistry, Inorganic
Organometallic chemistry
Soggetto genere / forma Periodical
Periodicals.
ISSN 2694-247X
Formato Materiale a stampa
Livello bibliografico Periodico
Lingua di pubblicazione eng
Altri titoli varianti ACS organic and inorganic Au
American Chemical Society organic and inorganic Au
ACS organic and inorganic, gold
Record Nr. UNISA-996453749303316
[Columbus, OH] : , : American Chemical Society, , [2021]-
Materiale a stampa
Lo trovi qui: Univ. di Salerno
Opac: Controlla la disponibilità qui
ACS organic & inorganic Au
ACS organic & inorganic Au
Pubbl/distr/stampa [Columbus, OH] : , : American Chemical Society, , [2021]-
Descrizione fisica 1 online resource
Disciplina 547
Soggetto topico Chemistry, Organic
Chemistry, Inorganic
Organometallic chemistry
Soggetto genere / forma Periodical
Periodicals.
ISSN 2694-247X
Formato Materiale a stampa
Livello bibliografico Periodico
Lingua di pubblicazione eng
Altri titoli varianti ACS organic and inorganic Au
American Chemical Society organic and inorganic Au
ACS organic and inorganic, gold
Record Nr. UNINA-9910508486603321
[Columbus, OH] : , : American Chemical Society, , [2021]-
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Acta chemica Scandinavica
Acta chemica Scandinavica
Pubbl/distr/stampa Copenhagen, : Munksgaard, ©1989-©1999
Descrizione fisica 1 online resource
Disciplina 540.5
Soggetto topico Chemistry
Biochemistry
Chemistry, Inorganic
Chemistry, Organic
Chemistry, Physical
biochemistry
chemistry
Chimie organique - Périodiques
Chimie physique et théorique - Périodiques
35.00 chemistry: general
Chemie
Soggetto genere / forma Periodical
Periodicals.
Formato Materiale a stampa
Livello bibliografico Periodico
Lingua di pubblicazione eng
Record Nr. UNISA-996205051403316
Copenhagen, : Munksgaard, ©1989-©1999
Materiale a stampa
Lo trovi qui: Univ. di Salerno
Opac: Controlla la disponibilità qui
Advanced inorganic chemistry : applications in everyday life / / Narayan S. Hosmane, Northern Illinois University
Advanced inorganic chemistry : applications in everyday life / / Narayan S. Hosmane, Northern Illinois University
Autore Hosmane Narayan S.
Pubbl/distr/stampa London : , : Academic Press, and imprint of Elsevier, , [2017]
Descrizione fisica 1 online resource (xix, 255 pages) : illustrations (some color)
Disciplina 546
Collana Gale eBooks
Soggetto topico Chemistry, Inorganic
ISBN 0-12-801993-X
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Foundations: concepts in chemical bonding and stereochemistry. Electronic structure: quantum theory revisited. Introduction: Why do we need to know quantum theory? ; Quantum mechanical description of the hydrogen atom -- Molecular geometries. Introduction: Why do we need to know molecular geometries or shapes of molecules? ; Shapes of molecules- valence shell electron pair repulsion (VSEPR) model ; Nonrigid shapes of molecules (stereochemistry) -- Molecular symmetry- Part I: Point group assignment. Introduction: Is it necessary to learn molecular symmetry? ; Elements of symmetry ; Point groups -- Group theory: matrix representation and character tables. Introduction: Is it necessary to learn group theory? ; Other properties of symmetry operations ; Applications to molecular structure and properties ; Examples of other structures ; Molecular spectroscopy -- Advanced topics 1: Introduction to ligands and metal complexes. Ligands and d-block metal complexes. Introduction: Is it necessary to know about ligands and metal complexes? ; Transition metals ; Nomenclature of coordination compounds ; Isomerism in coordination compounds -- Review of bonding theories for d-block metal complexes. Introduction: Why bonding theories of metal complexes are important? ; Valence bond theory ; Crystal field theory ; Molecular orbital theory -- Coordination chemistry: reaction mechanisms and their influencing factors. Introduction: What makes coordination chemistry interesting? ; Modes of substitution reaction mechanisms ; Complications involving metal complexes ; Activation parameters ; Examples of different coordination numbers with geometries and factors influencing reaction mechanism -- Advanced topics 2: electronic spectra, clusters & isolobal fragments. Coordination chemistry: electronic spectra. Introduction: why do we need to learn electronic spectra? ; Electronic spectra ; Tanabe- sugano diagrams ; Charge transfer spectra -- Cluster chemistry and isolobal fragments. Introduction: Role of cluster chemistry in nature ; Clusters of boranes, carboranes, and their metal complexes ; Clusters of other main group elements and transition metals ; Extension of Wade's rules beyond boron clusters -- Advanced topics 3: Organometallic chemistry and catalysis. Organometallic chemistry. Introduction: What is in organometallic chemistry? ; Definitions and nomenclature of organometallic compounds ; Molecular formulas and structures of organometallic compounds -- Catalysis with organometallic. Introduction: What is so special about catalytic processes in our daily life? ; Homogeneous catalysts ; Hydrogenation catalysts ; Other catalytic processes -- Advanced topics 4: Bioinorganic chemistry and applications. Introduction ; History and medical relevance ; Transport and storage of metal ions ; Oxygen transport and activation proteins ; Biomineralization.
Record Nr. UNINA-9910583076003321
Hosmane Narayan S.  
London : , : Academic Press, and imprint of Elsevier, , [2017]
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Advances in Bismuth Chemistry / / edited by Crispin Lichtenberg
Advances in Bismuth Chemistry / / edited by Crispin Lichtenberg
Autore Lichtenberg Crispin
Edizione [1st ed. 2025.]
Pubbl/distr/stampa Cham : , : Springer Nature Switzerland : , : Imprint : Springer, , 2025
Descrizione fisica 1 online resource (355 pages)
Disciplina 546
Collana Structure and Bonding
Soggetto topico Chemistry, Inorganic
Catalysis
Microclusters
Pharmaceutical chemistry
Inorganic Chemistry
Atomic and Molecular Clusters
Medicinal Chemistry
ISBN 3-031-96130-7
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Molecular Bismuth Compounds Ligand Design and Reactivity -- Nitrogen Based Ligands in the Coordination Sphere of Bismuth -- Geometrically Constrained Bismuth Compounds -- Bismuthinidenes -- Low Valent Molecular Bismuth Compounds Neutral Bi(I) and Bi(II) Species, Molecular Bi Clusters and Radicals -- Cationic Species and Catalysis -- Green Chemistry Using Bismuth Compounds.
Record Nr. UNINA-9911018661803321
Lichtenberg Crispin  
Cham : , : Springer Nature Switzerland : , : Imprint : Springer, , 2025
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Advances in functional inorganic materials prepared by wet chemical methods / / edited by Aleksej Zarkov, Aivaras Kareiva and Loreta Tamasauskaite-Tamasiunaite
Advances in functional inorganic materials prepared by wet chemical methods / / edited by Aleksej Zarkov, Aivaras Kareiva and Loreta Tamasauskaite-Tamasiunaite
Pubbl/distr/stampa Basel : , : MDPI - Multidisciplinary Digital Publishing Institute, , 2022
Descrizione fisica 1 online resource (154 pages)
Disciplina 546
Soggetto topico Chemistry, Inorganic
Chemistry
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Record Nr. UNINA-9910674373003321
Basel : , : MDPI - Multidisciplinary Digital Publishing Institute, , 2022
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Advances in inorganic chemistry . Volume sixty seven NOx related chemistry / / edited by Rudi van Eldik, José A. Olabe ; contributors, Dennis Awasabisah [and nineteen others]
Advances in inorganic chemistry . Volume sixty seven NOx related chemistry / / edited by Rudi van Eldik, José A. Olabe ; contributors, Dennis Awasabisah [and nineteen others]
Pubbl/distr/stampa Waltham, Massachusetts : , : Academic Press, , 2015
Descrizione fisica 1 online resource (388 p.)
Disciplina 546
Collana Advances in Inorganic Chemistry
Soggetto topico Nitrogen oxides
Chemistry, Inorganic
Soggetto genere / forma Electronic books.
ISBN 0-12-801837-2
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Front Cover; NOx Related Chemistry; Copyright; Contents; Contributors; Preface; Chapter One: NOx Linkage Isomerization in Metal Complexes; 1. Introduction; 1.1. Modes of binding of NOx moieties in monometallic complexes; 1.1.1. Nitric oxide complexes; 1.1.2. NO2 complexes; 1.1.3. NO3 complexes; 1.2. Methods that induce linkage isomerization; 1.3. Techniques for detecting linkage isomers; 1.4. Factors that affect linkage isomerization; 2. Linkage Isomerism in Non-Porphyrin NOx Complexes; 2.1. Group 6 (Cr and Mo) complexes; 2.1.1. NO complexes; 2.1.2. NO2 complexes
2.2. Group 7 (Mn and Re) complexes2.2.1. NO complexes; 2.3. Group 8 (Fe, Ru, and Os) complexes; 2.3.1. NO complexes; 2.3.2. NO2 complexes; 2.3.3. NO3 complexes; 2.4. Group 9 (Co, Rh, and Ir) complexes; 2.4.1. NO complexes; 2.4.2. NO2 complexes; 2.5. Group 10 (Ni, Pd, and Pt) complexes; 2.5.1. NO complexes; 2.5.2. NO2 complexes; 3. Linkage Isomerism in NOx-Coordinated Metalloporphyrins; 3.1. Manganese NOx porphyrins; 3.2. Ruthenium and iron NOx porphyrin complexes; 3.3. Cobalt NOx porphyrins; 3.4. Hyponitrite complexes of transition metal porphyrins
3.4.1. The nitric oxide dimer and its reduced forms3.4.2. Metal hyponitrite binding modes; 3.5. Heme proteins; 4. Conclusion; Acknowledgment; References; Chapter Two: Three Redox States of Metallonitrosyls in Aqueous Solution; 1. Introduction: General Scope; 2. Complexes with n=6; 2.1. Structure, spectroscopy, and electronic description. Total spin S=0. Dominant M-NO+ distribution; 2.1.1. Significance and importance of the ``back-bonding model ́ ́; 2.1.2. Role of the σ*-FeNO interaction in the trans-effect exerted over NO; 2.1.3. ``Negative ́ ́ trans-influence of the nitrosyl moiety
2.1.4. Different reactivity of the L ligand trans to NO2.1.5. Other metal centers: Validity of the formal charge descriptions; 2.1.6. Frontier MOs; 2.2. Formation and dissociation of NO-complexes: Nitrosylations and denitrosylations; 2.2.1. Reactions with M(II) precursors (M=Fe, Ru): Proton-assisted dehydration of bound nitrite; 2.2.2. Reactions with high-spin M(III) precursors; 2.2.3. Reactions with low-spin, nonheme Fe(III) systems; 2.2.4. Nitrosylation of nitrile-hydratase and models; 2.2.5. Nitrosylation of low-spin Fe(III)-heme models, [FeIII(TMPS)(CN)(H2O)]4- and [FeIII(TMPS)(CN)2]5-
2.2.6. Nitrosylations of other [FeIII(CN)5(Y)]n- complexes2.2.7. Nitrosylations with Ru(III) precursors; 2.2.8. Why is the release of NO so fast for the {FeIINO+} heme-nitrosyls?; 2.3. Electrophilic reactivity toward O-, N-, and S-binding nucleophiles; 2.3.1. General approach to electrophilic reactivity; 2.3.2. Correlation of nucleophilic rates with M(NO+)/M(NO) redox potentials; 3. Complexes with n=7; 3.1. Structure, spectroscopy, and electronic descriptions for 5- and 6-coordination. Total spin S=1/2 or 3/2. Alternative...; 3.1.1. Heme and nonheme 5C nitrosyls with S=1/2
3.1.2. Nonheme and heme 6C nitrosyls with S=1/2
Record Nr. UNINA-9910460523103321
Waltham, Massachusetts : , : Academic Press, , 2015
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Advances in inorganic chemistry . Volume sixty seven NOx related chemistry / / edited by Rudi van Eldik, José A. Olabe ; contributors, Dennis Awasabisah [and nineteen others]
Advances in inorganic chemistry . Volume sixty seven NOx related chemistry / / edited by Rudi van Eldik, José A. Olabe ; contributors, Dennis Awasabisah [and nineteen others]
Pubbl/distr/stampa Waltham, Massachusetts : , : Academic Press, , 2015
Descrizione fisica 1 online resource (388 p.)
Disciplina 546
Collana Advances in Inorganic Chemistry
Soggetto topico Nitrogen oxides
Chemistry, Inorganic
ISBN 0-12-801837-2
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Front Cover; NOx Related Chemistry; Copyright; Contents; Contributors; Preface; Chapter One: NOx Linkage Isomerization in Metal Complexes; 1. Introduction; 1.1. Modes of binding of NOx moieties in monometallic complexes; 1.1.1. Nitric oxide complexes; 1.1.2. NO2 complexes; 1.1.3. NO3 complexes; 1.2. Methods that induce linkage isomerization; 1.3. Techniques for detecting linkage isomers; 1.4. Factors that affect linkage isomerization; 2. Linkage Isomerism in Non-Porphyrin NOx Complexes; 2.1. Group 6 (Cr and Mo) complexes; 2.1.1. NO complexes; 2.1.2. NO2 complexes
2.2. Group 7 (Mn and Re) complexes2.2.1. NO complexes; 2.3. Group 8 (Fe, Ru, and Os) complexes; 2.3.1. NO complexes; 2.3.2. NO2 complexes; 2.3.3. NO3 complexes; 2.4. Group 9 (Co, Rh, and Ir) complexes; 2.4.1. NO complexes; 2.4.2. NO2 complexes; 2.5. Group 10 (Ni, Pd, and Pt) complexes; 2.5.1. NO complexes; 2.5.2. NO2 complexes; 3. Linkage Isomerism in NOx-Coordinated Metalloporphyrins; 3.1. Manganese NOx porphyrins; 3.2. Ruthenium and iron NOx porphyrin complexes; 3.3. Cobalt NOx porphyrins; 3.4. Hyponitrite complexes of transition metal porphyrins
3.4.1. The nitric oxide dimer and its reduced forms3.4.2. Metal hyponitrite binding modes; 3.5. Heme proteins; 4. Conclusion; Acknowledgment; References; Chapter Two: Three Redox States of Metallonitrosyls in Aqueous Solution; 1. Introduction: General Scope; 2. Complexes with n=6; 2.1. Structure, spectroscopy, and electronic description. Total spin S=0. Dominant M-NO+ distribution; 2.1.1. Significance and importance of the ``back-bonding model ́ ́; 2.1.2. Role of the σ*-FeNO interaction in the trans-effect exerted over NO; 2.1.3. ``Negative ́ ́ trans-influence of the nitrosyl moiety
2.1.4. Different reactivity of the L ligand trans to NO2.1.5. Other metal centers: Validity of the formal charge descriptions; 2.1.6. Frontier MOs; 2.2. Formation and dissociation of NO-complexes: Nitrosylations and denitrosylations; 2.2.1. Reactions with M(II) precursors (M=Fe, Ru): Proton-assisted dehydration of bound nitrite; 2.2.2. Reactions with high-spin M(III) precursors; 2.2.3. Reactions with low-spin, nonheme Fe(III) systems; 2.2.4. Nitrosylation of nitrile-hydratase and models; 2.2.5. Nitrosylation of low-spin Fe(III)-heme models, [FeIII(TMPS)(CN)(H2O)]4- and [FeIII(TMPS)(CN)2]5-
2.2.6. Nitrosylations of other [FeIII(CN)5(Y)]n- complexes2.2.7. Nitrosylations with Ru(III) precursors; 2.2.8. Why is the release of NO so fast for the {FeIINO+} heme-nitrosyls?; 2.3. Electrophilic reactivity toward O-, N-, and S-binding nucleophiles; 2.3.1. General approach to electrophilic reactivity; 2.3.2. Correlation of nucleophilic rates with M(NO+)/M(NO) redox potentials; 3. Complexes with n=7; 3.1. Structure, spectroscopy, and electronic descriptions for 5- and 6-coordination. Total spin S=1/2 or 3/2. Alternative...; 3.1.1. Heme and nonheme 5C nitrosyls with S=1/2
3.1.2. Nonheme and heme 6C nitrosyls with S=1/2
Record Nr. UNINA-9910787446903321
Waltham, Massachusetts : , : Academic Press, , 2015
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Advances in inorganic chemistry . Volume sixty seven NOx related chemistry / / edited by Rudi van Eldik, José A. Olabe ; contributors, Dennis Awasabisah [and nineteen others]
Advances in inorganic chemistry . Volume sixty seven NOx related chemistry / / edited by Rudi van Eldik, José A. Olabe ; contributors, Dennis Awasabisah [and nineteen others]
Pubbl/distr/stampa Waltham, Massachusetts : , : Academic Press, , 2015
Descrizione fisica 1 online resource (388 p.)
Disciplina 546
Collana Advances in Inorganic Chemistry
Soggetto topico Nitrogen oxides
Chemistry, Inorganic
ISBN 0-12-801837-2
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Front Cover; NOx Related Chemistry; Copyright; Contents; Contributors; Preface; Chapter One: NOx Linkage Isomerization in Metal Complexes; 1. Introduction; 1.1. Modes of binding of NOx moieties in monometallic complexes; 1.1.1. Nitric oxide complexes; 1.1.2. NO2 complexes; 1.1.3. NO3 complexes; 1.2. Methods that induce linkage isomerization; 1.3. Techniques for detecting linkage isomers; 1.4. Factors that affect linkage isomerization; 2. Linkage Isomerism in Non-Porphyrin NOx Complexes; 2.1. Group 6 (Cr and Mo) complexes; 2.1.1. NO complexes; 2.1.2. NO2 complexes
2.2. Group 7 (Mn and Re) complexes2.2.1. NO complexes; 2.3. Group 8 (Fe, Ru, and Os) complexes; 2.3.1. NO complexes; 2.3.2. NO2 complexes; 2.3.3. NO3 complexes; 2.4. Group 9 (Co, Rh, and Ir) complexes; 2.4.1. NO complexes; 2.4.2. NO2 complexes; 2.5. Group 10 (Ni, Pd, and Pt) complexes; 2.5.1. NO complexes; 2.5.2. NO2 complexes; 3. Linkage Isomerism in NOx-Coordinated Metalloporphyrins; 3.1. Manganese NOx porphyrins; 3.2. Ruthenium and iron NOx porphyrin complexes; 3.3. Cobalt NOx porphyrins; 3.4. Hyponitrite complexes of transition metal porphyrins
3.4.1. The nitric oxide dimer and its reduced forms3.4.2. Metal hyponitrite binding modes; 3.5. Heme proteins; 4. Conclusion; Acknowledgment; References; Chapter Two: Three Redox States of Metallonitrosyls in Aqueous Solution; 1. Introduction: General Scope; 2. Complexes with n=6; 2.1. Structure, spectroscopy, and electronic description. Total spin S=0. Dominant M-NO+ distribution; 2.1.1. Significance and importance of the ``back-bonding model ́ ́; 2.1.2. Role of the σ*-FeNO interaction in the trans-effect exerted over NO; 2.1.3. ``Negative ́ ́ trans-influence of the nitrosyl moiety
2.1.4. Different reactivity of the L ligand trans to NO2.1.5. Other metal centers: Validity of the formal charge descriptions; 2.1.6. Frontier MOs; 2.2. Formation and dissociation of NO-complexes: Nitrosylations and denitrosylations; 2.2.1. Reactions with M(II) precursors (M=Fe, Ru): Proton-assisted dehydration of bound nitrite; 2.2.2. Reactions with high-spin M(III) precursors; 2.2.3. Reactions with low-spin, nonheme Fe(III) systems; 2.2.4. Nitrosylation of nitrile-hydratase and models; 2.2.5. Nitrosylation of low-spin Fe(III)-heme models, [FeIII(TMPS)(CN)(H2O)]4- and [FeIII(TMPS)(CN)2]5-
2.2.6. Nitrosylations of other [FeIII(CN)5(Y)]n- complexes2.2.7. Nitrosylations with Ru(III) precursors; 2.2.8. Why is the release of NO so fast for the {FeIINO+} heme-nitrosyls?; 2.3. Electrophilic reactivity toward O-, N-, and S-binding nucleophiles; 2.3.1. General approach to electrophilic reactivity; 2.3.2. Correlation of nucleophilic rates with M(NO+)/M(NO) redox potentials; 3. Complexes with n=7; 3.1. Structure, spectroscopy, and electronic descriptions for 5- and 6-coordination. Total spin S=1/2 or 3/2. Alternative...; 3.1.1. Heme and nonheme 5C nitrosyls with S=1/2
3.1.2. Nonheme and heme 6C nitrosyls with S=1/2
Record Nr. UNINA-9910814434003321
Waltham, Massachusetts : , : Academic Press, , 2015
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui