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Chemical equilibria / / Michel Soustelle
| Chemical equilibria / / Michel Soustelle |
| Autore | Soustelle Michel |
| Pubbl/distr/stampa | Hoboken, NJ : , : Wiley, , 2015 |
| Descrizione fisica | 1 online resource (179 p.) |
| Disciplina | 541.392 |
| Collana | Chemical engineering series : chemical thermodynamics set |
| Soggetto topico |
Thermodynamics - Mathematical models
Chemical equilibrium - Mathematical models Phase transformations (Statistical physics) |
| ISBN |
1-119-17856-8
1-119-17854-1 1-119-17855-X |
| Formato | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Table of Contents; Title; Copyright; Preface; Notations and Symbols; 1: Physico-Chemical Transformations and Equilibria; 1.1. Characteristic parameters of physico-chemical transformations; 1.2. Entropy production during the course of a transformation in a closed system; 1.3. Affinity of a transformation; 1.4. De Donder's inequality - direction of the transformations and equilibrium conditions; 1.5. Heats of transformation; 1.6. Set of points representing the equilibrium states of a transformation; 1.7. Closed systems accommodating multiple reactions
1.8. Direction of evolution and equilibrium conditions in an open system1.9. Azeotropic transformations; 2: Properties of States of Physico-Chemical Equilibrium; 2.1. Laws of displacement of an equilibrium; 2.2. Properties of all the equilibria in a system; 2.3. Phase laws; 2.4. Indifferent states; 2.5. Thermodynamically-equivalent systems; 2.6. Stability of equilibria; 3: Molecular Chemical Equilibria; 3.1. Law of mass action - equilibrium constants; 3.2. Graphical representations of equilibria - pole diagrams; 3.3. Representation of the evolution of an equilibrium with the temperature 3.4. Binary diagrams for chemical equilibrium3.5. Ternary diagrams of chemical equilibria; 3.6. Quaternary diagrams of chemical equilibria; 4: Determination of the Values Associated with Reactions - Equilibrium Calculations; 4.1. Reminders of a few thermodynamic relations; 4.2. Enthalpies of reaction - thermochemistry; 4.3. Reaction entropies; 4.4. Specific heat capacities; 4.5. Experimental determination of the equilibrium constants; 4.6. Calculation of the equilibrium constants on the basis of other thermodynamic data 4.7. Determination of the equilibrium constants on the basis of spectral data and statistical thermodynamics4.8. Thermodynamic tables and databanks; 4.9. Estimation of thermodynamic data; 4.10. Thermodynamic calculations for complex systems; APPENDICES; Appendix 1: Recap on the Reference States of Solutions; A1.1. Concentration and molar fraction; A1.2. Chemical potentials and activity coefficients; A1.3. Characterization of the imperfection of a real solution by the excess Gibbs energy; Appendix 2: Recap of statistical thermodynamics; A2.1. The three branches of statistics A2.2. Partition functions of a molecule objectA2.3. Canonical partition function; A2.4. Canonical partition functions and thermodynamic functions; A2.5. Equilibrium constants and molecular partition functions; Bibliography; Index; End User License Agreement |
| Record Nr. | UNINA-9910131529403321 |
Soustelle Michel
|
||
| Hoboken, NJ : , : Wiley, , 2015 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Chemical equilibria / / Michel Soustelle
| Chemical equilibria / / Michel Soustelle |
| Autore | Soustelle Michel |
| Pubbl/distr/stampa | Hoboken, NJ : , : Wiley, , 2015 |
| Descrizione fisica | 1 online resource (179 p.) |
| Disciplina | 541.392 |
| Collana | Chemical engineering series : chemical thermodynamics set |
| Soggetto topico |
Thermodynamics - Mathematical models
Chemical equilibrium - Mathematical models Phase transformations (Statistical physics) |
| ISBN |
1-119-17856-8
1-119-17854-1 1-119-17855-X |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Table of Contents; Title; Copyright; Preface; Notations and Symbols; 1: Physico-Chemical Transformations and Equilibria; 1.1. Characteristic parameters of physico-chemical transformations; 1.2. Entropy production during the course of a transformation in a closed system; 1.3. Affinity of a transformation; 1.4. De Donder's inequality - direction of the transformations and equilibrium conditions; 1.5. Heats of transformation; 1.6. Set of points representing the equilibrium states of a transformation; 1.7. Closed systems accommodating multiple reactions
1.8. Direction of evolution and equilibrium conditions in an open system1.9. Azeotropic transformations; 2: Properties of States of Physico-Chemical Equilibrium; 2.1. Laws of displacement of an equilibrium; 2.2. Properties of all the equilibria in a system; 2.3. Phase laws; 2.4. Indifferent states; 2.5. Thermodynamically-equivalent systems; 2.6. Stability of equilibria; 3: Molecular Chemical Equilibria; 3.1. Law of mass action - equilibrium constants; 3.2. Graphical representations of equilibria - pole diagrams; 3.3. Representation of the evolution of an equilibrium with the temperature 3.4. Binary diagrams for chemical equilibrium3.5. Ternary diagrams of chemical equilibria; 3.6. Quaternary diagrams of chemical equilibria; 4: Determination of the Values Associated with Reactions - Equilibrium Calculations; 4.1. Reminders of a few thermodynamic relations; 4.2. Enthalpies of reaction - thermochemistry; 4.3. Reaction entropies; 4.4. Specific heat capacities; 4.5. Experimental determination of the equilibrium constants; 4.6. Calculation of the equilibrium constants on the basis of other thermodynamic data 4.7. Determination of the equilibrium constants on the basis of spectral data and statistical thermodynamics4.8. Thermodynamic tables and databanks; 4.9. Estimation of thermodynamic data; 4.10. Thermodynamic calculations for complex systems; APPENDICES; Appendix 1: Recap on the Reference States of Solutions; A1.1. Concentration and molar fraction; A1.2. Chemical potentials and activity coefficients; A1.3. Characterization of the imperfection of a real solution by the excess Gibbs energy; Appendix 2: Recap of statistical thermodynamics; A2.1. The three branches of statistics A2.2. Partition functions of a molecule objectA2.3. Canonical partition function; A2.4. Canonical partition functions and thermodynamic functions; A2.5. Equilibrium constants and molecular partition functions; Bibliography; Index; End User License Agreement |
| Record Nr. | UNINA-9910809214603321 |
|
Soustelle Michel
|
||
| Hoboken, NJ : , : Wiley, , 2015 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
