Charge transfer in DNA [[electronic resource] ] : from mechanism to application / / edited by Hans-Achim Wagenknecht |
Pubbl/distr/stampa | Weinheim, Germany, : Wiley-VCH, c2005 |
Descrizione fisica | 1 online resource (247 p.) |
Disciplina | 572.86 |
Altri autori (Persone) | WagenknechtHans-Achim |
Soggetto topico |
Charge transfer in biology
DNA |
Soggetto genere / forma | Electronic books. |
ISBN |
1-280-52120-1
9786610521203 3-527-60662-9 3-527-60690-4 |
Formato | Materiale a stampa |
Livello bibliografico | Monografia |
Lingua di pubblicazione | eng |
Nota di contenuto |
Charge Transfer in DNA; Foreword; Preface; Contents; List of Contributors; 1 Principles and Mechanisms of Photoinduced Charge Injection, Transport, and Trapping in DNA; 1.1 Introduction; 1.2 Synthetic DNA-Donor-Acceptor Systems; 1.3 Photoinduced Oxidative Hole Transfer vs. Reductive Electron Transfer in DNA; 1.4 Hole Transfer and Hole Hopping in DNA; 1.4.1 Spectroscopic Studies and Mechanisms of Hole Transfer in DNA; 1.4.2 Biochemical and Chemical Hole Trapping in DNA; 1.4.3 Modulation of DNA-mediated Hole Transfer; 1.5 Reductive Electron Transfer in DNA
1.5.1 Mechanisms of Electron Transfer in DNA1.5.2 Outlook: Electron Transfer in DNA Chip Technology; 1.6 Conclusions; References; 2 Sequence-dependent DNA Dynamics: The Regulator of DNA-mediated Charge Transport; 2.1 Introduction; 2.2 Experimental Approaches to Studies of DNA-mediated Charge Transport Over Varied Energetic and Time Regimes; 2.2.1 Metallointercalators, Organic Intercalators, and Modified Bases as Probes; 2.2.1.1 Metallointercalators; 2.2.1.2 Organic Intercalators; 2.2.1.3 Modified Bases; 2.2.2 Spectroscopic, Biochemical, and Electrochemical Approaches 2.3 Understanding the Fundamental Parameters Governing DNA-mediated Charge Transport2.3.1 The Base Pair π-Stack of Double-helical DNA Regulates Charge Transport; 2.3.1.1 Spectroscopic Investigations of Charge Transport through DNA; 2.3.1.2 Biochemical Investigations of Long-range Oxidative Damage; 2.3.2 The Role of the Oxidant in DNA-mediated Charge Transport: Energetics, Coupling, Lifetimes, and Back Electron Transfer; 2.3.2.1 Rate Constants and Net Yields of Charge Injection; 2.3.2.2 Long-range Oxidative Damage; 2.3.3 Conformational Dynamics of the DNA Bases 2.3.4 Charge Delocalization and Participation of All DNA Bases2.3.5 Transport of Holes Versus "Excess Electrons"; 2.4 A Mechanistic Model for DNA-mediated Charge Transport: Beyond Superexchange and Incoherent Hopping; 2.5 DNA-mediated Charge Transport in Biology; 2.6 Conclusions and Outlook; References; 3 Excess Electron Transfer in DNA Probed with Flavin- and Thymine Dimer-modified Oligonucleotides; 3.1 Introduction; 3.2 Excess Electron Transfer-driven DNA Repair by DNA Photolyases; 3.3 Excess Electron Transfer in DNA; 3.3.1 Distance Dependence; 3.3.2 Directional Dependence 3.3.3 Sequence Dependence3.4 The Catalytic Electron? Or, Can One Electron Repair More Than One Dimer Lesion?; 3.5 Future Directions; References; 4 Dynamics of Photoinitiated Hole and Electron Injection in Duplex DNA; 4.1 Introduction; 4.2 DNA Hairpin Synthesis, Structure, and Energetics; 4.2.1 Hairpin Synthesis and Structure; 4.2.2 Electron Transfer Energetics; 4.2.3 Electron Transfer Dynamics; 4.3 Hole Injection; 4.3.1 Distance Dependence; 4.3.2 Electron Donor-Acceptor End-capped Hairpins; 4.3.3 Variation of the Tunneling Energy Gap; 4.3.4 Driving Force Dependence 4.3.5 GG and GGG as Hole Acceptors |
Record Nr. | UNINA-9910143964503321 |
Weinheim, Germany, : Wiley-VCH, c2005 | ||
Materiale a stampa | ||
Lo trovi qui: Univ. Federico II | ||
|
Charge transfer in DNA [[electronic resource] ] : from mechanism to application / / edited by Hans-Achim Wagenknecht |
Pubbl/distr/stampa | Weinheim, Germany, : Wiley-VCH, c2005 |
Descrizione fisica | 1 online resource (247 p.) |
Disciplina | 572.86 |
Altri autori (Persone) | WagenknechtHans-Achim |
Soggetto topico |
Charge transfer in biology
DNA |
ISBN |
1-280-52120-1
9786610521203 3-527-60662-9 3-527-60690-4 |
Formato | Materiale a stampa |
Livello bibliografico | Monografia |
Lingua di pubblicazione | eng |
Nota di contenuto |
Charge Transfer in DNA; Foreword; Preface; Contents; List of Contributors; 1 Principles and Mechanisms of Photoinduced Charge Injection, Transport, and Trapping in DNA; 1.1 Introduction; 1.2 Synthetic DNA-Donor-Acceptor Systems; 1.3 Photoinduced Oxidative Hole Transfer vs. Reductive Electron Transfer in DNA; 1.4 Hole Transfer and Hole Hopping in DNA; 1.4.1 Spectroscopic Studies and Mechanisms of Hole Transfer in DNA; 1.4.2 Biochemical and Chemical Hole Trapping in DNA; 1.4.3 Modulation of DNA-mediated Hole Transfer; 1.5 Reductive Electron Transfer in DNA
1.5.1 Mechanisms of Electron Transfer in DNA1.5.2 Outlook: Electron Transfer in DNA Chip Technology; 1.6 Conclusions; References; 2 Sequence-dependent DNA Dynamics: The Regulator of DNA-mediated Charge Transport; 2.1 Introduction; 2.2 Experimental Approaches to Studies of DNA-mediated Charge Transport Over Varied Energetic and Time Regimes; 2.2.1 Metallointercalators, Organic Intercalators, and Modified Bases as Probes; 2.2.1.1 Metallointercalators; 2.2.1.2 Organic Intercalators; 2.2.1.3 Modified Bases; 2.2.2 Spectroscopic, Biochemical, and Electrochemical Approaches 2.3 Understanding the Fundamental Parameters Governing DNA-mediated Charge Transport2.3.1 The Base Pair π-Stack of Double-helical DNA Regulates Charge Transport; 2.3.1.1 Spectroscopic Investigations of Charge Transport through DNA; 2.3.1.2 Biochemical Investigations of Long-range Oxidative Damage; 2.3.2 The Role of the Oxidant in DNA-mediated Charge Transport: Energetics, Coupling, Lifetimes, and Back Electron Transfer; 2.3.2.1 Rate Constants and Net Yields of Charge Injection; 2.3.2.2 Long-range Oxidative Damage; 2.3.3 Conformational Dynamics of the DNA Bases 2.3.4 Charge Delocalization and Participation of All DNA Bases2.3.5 Transport of Holes Versus "Excess Electrons"; 2.4 A Mechanistic Model for DNA-mediated Charge Transport: Beyond Superexchange and Incoherent Hopping; 2.5 DNA-mediated Charge Transport in Biology; 2.6 Conclusions and Outlook; References; 3 Excess Electron Transfer in DNA Probed with Flavin- and Thymine Dimer-modified Oligonucleotides; 3.1 Introduction; 3.2 Excess Electron Transfer-driven DNA Repair by DNA Photolyases; 3.3 Excess Electron Transfer in DNA; 3.3.1 Distance Dependence; 3.3.2 Directional Dependence 3.3.3 Sequence Dependence3.4 The Catalytic Electron? Or, Can One Electron Repair More Than One Dimer Lesion?; 3.5 Future Directions; References; 4 Dynamics of Photoinitiated Hole and Electron Injection in Duplex DNA; 4.1 Introduction; 4.2 DNA Hairpin Synthesis, Structure, and Energetics; 4.2.1 Hairpin Synthesis and Structure; 4.2.2 Electron Transfer Energetics; 4.2.3 Electron Transfer Dynamics; 4.3 Hole Injection; 4.3.1 Distance Dependence; 4.3.2 Electron Donor-Acceptor End-capped Hairpins; 4.3.3 Variation of the Tunneling Energy Gap; 4.3.4 Driving Force Dependence 4.3.5 GG and GGG as Hole Acceptors |
Record Nr. | UNINA-9910830091703321 |
Weinheim, Germany, : Wiley-VCH, c2005 | ||
Materiale a stampa | ||
Lo trovi qui: Univ. Federico II | ||
|
Charge transfer in DNA : from mechanism to application / / edited by Hans-Achim Wagenknecht |
Pubbl/distr/stampa | Weinheim, Germany, : Wiley-VCH, c2005 |
Descrizione fisica | 1 online resource (247 p.) |
Disciplina | 572.86 |
Altri autori (Persone) | WagenknechtHans-Achim |
Soggetto topico |
Charge transfer in biology
DNA |
ISBN |
1-280-52120-1
9786610521203 3-527-60662-9 3-527-60690-4 |
Formato | Materiale a stampa |
Livello bibliografico | Monografia |
Lingua di pubblicazione | eng |
Nota di contenuto |
Charge Transfer in DNA; Foreword; Preface; Contents; List of Contributors; 1 Principles and Mechanisms of Photoinduced Charge Injection, Transport, and Trapping in DNA; 1.1 Introduction; 1.2 Synthetic DNA-Donor-Acceptor Systems; 1.3 Photoinduced Oxidative Hole Transfer vs. Reductive Electron Transfer in DNA; 1.4 Hole Transfer and Hole Hopping in DNA; 1.4.1 Spectroscopic Studies and Mechanisms of Hole Transfer in DNA; 1.4.2 Biochemical and Chemical Hole Trapping in DNA; 1.4.3 Modulation of DNA-mediated Hole Transfer; 1.5 Reductive Electron Transfer in DNA
1.5.1 Mechanisms of Electron Transfer in DNA1.5.2 Outlook: Electron Transfer in DNA Chip Technology; 1.6 Conclusions; References; 2 Sequence-dependent DNA Dynamics: The Regulator of DNA-mediated Charge Transport; 2.1 Introduction; 2.2 Experimental Approaches to Studies of DNA-mediated Charge Transport Over Varied Energetic and Time Regimes; 2.2.1 Metallointercalators, Organic Intercalators, and Modified Bases as Probes; 2.2.1.1 Metallointercalators; 2.2.1.2 Organic Intercalators; 2.2.1.3 Modified Bases; 2.2.2 Spectroscopic, Biochemical, and Electrochemical Approaches 2.3 Understanding the Fundamental Parameters Governing DNA-mediated Charge Transport2.3.1 The Base Pair π-Stack of Double-helical DNA Regulates Charge Transport; 2.3.1.1 Spectroscopic Investigations of Charge Transport through DNA; 2.3.1.2 Biochemical Investigations of Long-range Oxidative Damage; 2.3.2 The Role of the Oxidant in DNA-mediated Charge Transport: Energetics, Coupling, Lifetimes, and Back Electron Transfer; 2.3.2.1 Rate Constants and Net Yields of Charge Injection; 2.3.2.2 Long-range Oxidative Damage; 2.3.3 Conformational Dynamics of the DNA Bases 2.3.4 Charge Delocalization and Participation of All DNA Bases2.3.5 Transport of Holes Versus "Excess Electrons"; 2.4 A Mechanistic Model for DNA-mediated Charge Transport: Beyond Superexchange and Incoherent Hopping; 2.5 DNA-mediated Charge Transport in Biology; 2.6 Conclusions and Outlook; References; 3 Excess Electron Transfer in DNA Probed with Flavin- and Thymine Dimer-modified Oligonucleotides; 3.1 Introduction; 3.2 Excess Electron Transfer-driven DNA Repair by DNA Photolyases; 3.3 Excess Electron Transfer in DNA; 3.3.1 Distance Dependence; 3.3.2 Directional Dependence 3.3.3 Sequence Dependence3.4 The Catalytic Electron? Or, Can One Electron Repair More Than One Dimer Lesion?; 3.5 Future Directions; References; 4 Dynamics of Photoinitiated Hole and Electron Injection in Duplex DNA; 4.1 Introduction; 4.2 DNA Hairpin Synthesis, Structure, and Energetics; 4.2.1 Hairpin Synthesis and Structure; 4.2.2 Electron Transfer Energetics; 4.2.3 Electron Transfer Dynamics; 4.3 Hole Injection; 4.3.1 Distance Dependence; 4.3.2 Electron Donor-Acceptor End-capped Hairpins; 4.3.3 Variation of the Tunneling Energy Gap; 4.3.4 Driving Force Dependence 4.3.5 GG and GGG as Hole Acceptors |
Altri titoli varianti | Charge transfer in deoxyribonucleic acid |
Record Nr. | UNINA-9910877133703321 |
Weinheim, Germany, : Wiley-VCH, c2005 | ||
Materiale a stampa | ||
Lo trovi qui: Univ. Federico II | ||
|
Electron transfer- from isolated molecules to biomolecules . Part 1 [[electronic resource] /] / edited by Joshua Jortner and M. Bixon ; series editors, I. Prigogine, Stuart A. Rice |
Pubbl/distr/stampa | New York, : J. Wiley, c1999 |
Descrizione fisica | 1 online resource (758 p.) |
Disciplina |
539.72112
541.305 541/.08 |
Altri autori (Persone) |
JortnerJoshua
BixonM PrigogineI (Ilya) RiceStuart Alan <1932-> |
Collana | Advances in chemical physics |
Soggetto topico |
Charge exchange
Charge transfer Charge transfer in biology Electron donor-acceptor complexes Molecular dynamics |
Soggetto genere / forma | Electronic books. |
ISBN |
1-282-68199-0
9786612681998 0-470-14165-4 0-470-14218-9 |
Formato | Materiale a stampa |
Livello bibliografico | Monografia |
Lingua di pubblicazione | eng |
Nota di contenuto |
ELECTRON TRANSFER FROM ISOLATED MOLECULES TO BIOMOLECULES; CONTENTS TO VOLUME 106; ELECTRON TRANSFER PAST AND FUTURE; ELECTRON TRANSFER REACTIONS IN SOLUTION: A HISTORICAL PERSPECTIVE; ELECTRON TRANSFER-FROM ISOLATED MOLECULES TO BIOMOLECULES; CHARGE TRANSFER IN BICHROMOPHORIC MOLECULES IN THE GAS PHASE; LONG-RANGE CHARGE SEPARATION IN SOLVENT-FREE DONOR-BRIDGE-ACCEPTOR SYSTEMS; ELECTRON TRANSFER AND CHARGE SEPARATION IN CLUSTERS; CONTROL OF ELECTRON TRANSFER KINETICS: MODELS FOR MEDIUM REORGANIZATION AND DONOR-ACCEPTOR COUPLING
THEORIES OF STRUCTURE-FUNCTION RELATIONSHIPS FOR BRIDGE-MEDIATED ELECTRON TRANSFER REACTIONSFLUCTUATIONS AND COHERENCE IN LONG-RANGE AND MULTICENTER ELECTRON TRANSFER; LANCZOS ALGORITHM FOR ELECTRON TRANSFER RATES IN SOLVENTS WITH COMPLEX SPECTRAL DENSITIES; SPECTROSCOPIC DETERMINATION OF ELECTRON TRANSFER BARRIERS AND RATE CONSTANTS; PHOTOINDUCED ELECTRON TRANSFER WITHIN DONOR-SPACER-ACCEPTOR MOLECULAR ASSEMBLIES STUDIED BY TIME-RESOLVED MICROWAVE CONDUCTIVITY; FROM CLOSE CONTACT TO LONG-RANGE INTRAMOLECULAR ELECTRON TRANSFER; PHOTOINDUCED ELECTRON TRANSFERS THROUGH o BONDS IN SOLUTION AUTHOR INDEXSUBJECT INDEX |
Record Nr. | UNINA-9910144265303321 |
New York, : J. Wiley, c1999 | ||
Materiale a stampa | ||
Lo trovi qui: Univ. Federico II | ||
|
Electron transfer- from isolated molecules to biomolecules . Part 1 [[electronic resource] /] / edited by Joshua Jortner and M. Bixon ; series editors, I. Prigogine, Stuart A. Rice |
Pubbl/distr/stampa | New York, : J. Wiley, c1999 |
Descrizione fisica | 1 online resource (758 p.) |
Disciplina |
539.72112
541.305 541/.08 |
Altri autori (Persone) |
JortnerJoshua
BixonM PrigogineI (Ilya) RiceStuart Alan <1932-> |
Collana | Advances in chemical physics |
Soggetto topico |
Charge exchange
Charge transfer Charge transfer in biology Electron donor-acceptor complexes Molecular dynamics |
ISBN |
1-282-68199-0
9786612681998 0-470-14165-4 0-470-14218-9 |
Formato | Materiale a stampa |
Livello bibliografico | Monografia |
Lingua di pubblicazione | eng |
Nota di contenuto |
ELECTRON TRANSFER FROM ISOLATED MOLECULES TO BIOMOLECULES; CONTENTS TO VOLUME 106; ELECTRON TRANSFER PAST AND FUTURE; ELECTRON TRANSFER REACTIONS IN SOLUTION: A HISTORICAL PERSPECTIVE; ELECTRON TRANSFER-FROM ISOLATED MOLECULES TO BIOMOLECULES; CHARGE TRANSFER IN BICHROMOPHORIC MOLECULES IN THE GAS PHASE; LONG-RANGE CHARGE SEPARATION IN SOLVENT-FREE DONOR-BRIDGE-ACCEPTOR SYSTEMS; ELECTRON TRANSFER AND CHARGE SEPARATION IN CLUSTERS; CONTROL OF ELECTRON TRANSFER KINETICS: MODELS FOR MEDIUM REORGANIZATION AND DONOR-ACCEPTOR COUPLING
THEORIES OF STRUCTURE-FUNCTION RELATIONSHIPS FOR BRIDGE-MEDIATED ELECTRON TRANSFER REACTIONSFLUCTUATIONS AND COHERENCE IN LONG-RANGE AND MULTICENTER ELECTRON TRANSFER; LANCZOS ALGORITHM FOR ELECTRON TRANSFER RATES IN SOLVENTS WITH COMPLEX SPECTRAL DENSITIES; SPECTROSCOPIC DETERMINATION OF ELECTRON TRANSFER BARRIERS AND RATE CONSTANTS; PHOTOINDUCED ELECTRON TRANSFER WITHIN DONOR-SPACER-ACCEPTOR MOLECULAR ASSEMBLIES STUDIED BY TIME-RESOLVED MICROWAVE CONDUCTIVITY; FROM CLOSE CONTACT TO LONG-RANGE INTRAMOLECULAR ELECTRON TRANSFER; PHOTOINDUCED ELECTRON TRANSFERS THROUGH o BONDS IN SOLUTION AUTHOR INDEXSUBJECT INDEX |
Record Nr. | UNINA-9910830414403321 |
New York, : J. Wiley, c1999 | ||
Materiale a stampa | ||
Lo trovi qui: Univ. Federico II | ||
|
Electron transfer- from isolated molecules to biomolecules . Part 1 / / edited by Joshua Jortner and M. Bixon ; series editors, I. Prigogine, Stuart A. Rice |
Pubbl/distr/stampa | New York, : J. Wiley, c1999 |
Descrizione fisica | 1 online resource (758 p.) |
Disciplina |
539.72112
541.305 541/.08 |
Altri autori (Persone) |
JortnerJoshua
BixonM PrigogineI (Ilya) RiceStuart Alan <1932-> |
Collana | Advances in chemical physics |
Soggetto topico |
Charge exchange
Charge transfer Charge transfer in biology Electron donor-acceptor complexes Molecular dynamics |
ISBN |
1-282-68199-0
9786612681998 0-470-14165-4 0-470-14218-9 |
Formato | Materiale a stampa |
Livello bibliografico | Monografia |
Lingua di pubblicazione | eng |
Nota di contenuto |
ELECTRON TRANSFER FROM ISOLATED MOLECULES TO BIOMOLECULES; CONTENTS TO VOLUME 106; ELECTRON TRANSFER PAST AND FUTURE; ELECTRON TRANSFER REACTIONS IN SOLUTION: A HISTORICAL PERSPECTIVE; ELECTRON TRANSFER-FROM ISOLATED MOLECULES TO BIOMOLECULES; CHARGE TRANSFER IN BICHROMOPHORIC MOLECULES IN THE GAS PHASE; LONG-RANGE CHARGE SEPARATION IN SOLVENT-FREE DONOR-BRIDGE-ACCEPTOR SYSTEMS; ELECTRON TRANSFER AND CHARGE SEPARATION IN CLUSTERS; CONTROL OF ELECTRON TRANSFER KINETICS: MODELS FOR MEDIUM REORGANIZATION AND DONOR-ACCEPTOR COUPLING
THEORIES OF STRUCTURE-FUNCTION RELATIONSHIPS FOR BRIDGE-MEDIATED ELECTRON TRANSFER REACTIONSFLUCTUATIONS AND COHERENCE IN LONG-RANGE AND MULTICENTER ELECTRON TRANSFER; LANCZOS ALGORITHM FOR ELECTRON TRANSFER RATES IN SOLVENTS WITH COMPLEX SPECTRAL DENSITIES; SPECTROSCOPIC DETERMINATION OF ELECTRON TRANSFER BARRIERS AND RATE CONSTANTS; PHOTOINDUCED ELECTRON TRANSFER WITHIN DONOR-SPACER-ACCEPTOR MOLECULAR ASSEMBLIES STUDIED BY TIME-RESOLVED MICROWAVE CONDUCTIVITY; FROM CLOSE CONTACT TO LONG-RANGE INTRAMOLECULAR ELECTRON TRANSFER; PHOTOINDUCED ELECTRON TRANSFERS THROUGH o BONDS IN SOLUTION AUTHOR INDEXSUBJECT INDEX |
Record Nr. | UNINA-9910877232103321 |
New York, : J. Wiley, c1999 | ||
Materiale a stampa | ||
Lo trovi qui: Univ. Federico II | ||
|