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Adhesion between volcanic glass and spacecraft materials in an airless body environment [[electronic resource] /] / Stephen Berkebile, Kenneth W. Street, Jr., and James R. Gaier ; prepared for the 3rd Atmospheric and Space Environments Conference sponsored by the American Institute of Aeronautics and Astronautics, Honolulu, Hawaii, June 27-30, 2011
| Adhesion between volcanic glass and spacecraft materials in an airless body environment [[electronic resource] /] / Stephen Berkebile, Kenneth W. Street, Jr., and James R. Gaier ; prepared for the 3rd Atmospheric and Space Environments Conference sponsored by the American Institute of Aeronautics and Astronautics, Honolulu, Hawaii, June 27-30, 2011 |
| Autore | Berkebile Stephen |
| Pubbl/distr/stampa | Cleveland, Ohio : , : National Aeronautics and Space Administration, Glenn Research Center, , [2012] |
| Descrizione fisica | 1 online resource (13 pages) : illustrations |
| Altri autori (Persone) |
StreetKenneth W
GaierJames R |
| Collana | NASA/TM |
| Soggetto topico |
Temperature control
Surface energy Adhesion Dust Control surfaces Meteorite collisions Charge transfer Gas giant planets |
| Formato | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNINA-9910701910803321 |
Berkebile Stephen
|
||
| Cleveland, Ohio : , : National Aeronautics and Space Administration, Glenn Research Center, , [2012] | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Adhesion in a vacuum environment and its implications for dust mitigation techniques on airless bodies / / Stephen Berkebile and James R. Gaier
| Adhesion in a vacuum environment and its implications for dust mitigation techniques on airless bodies / / Stephen Berkebile and James R. Gaier |
| Autore | Berkebile Stephen |
| Pubbl/distr/stampa | Cleveland, Ohio : , : National Aeronautics and Space Administration, Glenn Research Center, , 2012 |
| Descrizione fisica | 1 online resource (10 pages) : color illustrations |
| Collana | NASA/TM |
| Soggetto topico |
Temperature control
Surface energy Adhesion Dust Charge transfer Control surfaces |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNINA-9910702486403321 |
|
Berkebile Stephen
|
||
| Cleveland, Ohio : , : National Aeronautics and Space Administration, Glenn Research Center, , 2012 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Charge and energy transfer dynamics in molecular systems [[electronic resource] /] / Volkhard May and Oliver Kühn
| Charge and energy transfer dynamics in molecular systems [[electronic resource] /] / Volkhard May and Oliver Kühn |
| Autore | May Volkhard |
| Edizione | [3rd ed.] |
| Pubbl/distr/stampa | Weinheim, : Wiley-VCH, 2011 |
| Descrizione fisica | 1 online resource (584 p.) |
| Disciplina | 541.22 |
| Altri autori (Persone) | KühnOliver |
| Soggetto topico |
Energy transfer
Charge transfer Molecules Quantum chemistry Molecular dynamics |
| ISBN |
3-527-63381-2
3-527-63380-4 3-527-63379-0 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Charge and Energy Transfer Dynamics in Molecular Systems; Contents; Preface to the Third Edition; Preface to the Second Edition; Preface to the First Edition; 1 Introduction; 2 Electronic and Vibrational Molecular States; 2.1 Introduction; 2.2 Molecular Schrödinger Equation; 2.3 Born-Oppenheimer Separation; 2.3.1 Born-Oppenheimer Approximation; 2.3.2 Some Estimates; 2.4 Electronic Structure Methods; 2.4.1 The Hartree-Fock Equations; 2.4.2 Density Functional Theory; 2.5 Condensed Phase Approaches; 2.5.1 Dielectric Continuum Model; 2.5.2 Explicit Quantum-Classical Solvent Model
2.6 Potential Energy Surfaces2.6.1 Harmonic Approximation and Normal Mode Analysis; 2.6.2 Operator Representation of the Normal Mode Hamiltonian; 2.6.3 Reaction Paths; 2.7 Diabatic versus Adiabatic Representation of the Molecular Hamiltonian; 2.8 Supplement; 2.8.1 The Hartree-Fock Equations; 2.8.2 Franck-Condon Factors; 2.8.3 The Two-Level System; 2.8.4 The Linear Molecular Chain and the Molecular Ring; References; Further Reading; 3 Dynamics of Isolated and Open Quantum Systems; 3.1 Introduction; 3.2 Time-Dependent Schrödinger Equation; 3.2.1 Wave Packets 3.2.2 The Interaction Representation3.2.3 Multidimensional Wave Packet Dynamics; 3.3 The Golden Rule of Quantum Mechanics; 3.3.1 Transition from a Single State into a Continuum; 3.3.2 Transition Rate for a Thermal Ensemble; 3.3.3 Green's Function Approach; 3.4 The Nonequilibrium Statistical Operator and the Density Matrix; 3.4.1 The Density Operator; 3.4.2 The Density Matrix; 3.4.3 Equation of Motion for the Density Operator; 3.4.4 Wigner Representation of the Density Operator; 3.4.5 Dynamics of Coupled Multilevel Systems in a Heat Bath 3.5 The Reduced Density Operator and the Reduced Density Matrix3.5.1 The Reduced Density Operator; 3.5.2 Equation of Motion for the Reduced Density Operator; 3.5.3 Mean-Field Approximation; 3.5.4 The Interaction Representation of the Reduced Density Operator; 3.5.5 The Projection Superoperator; 3.5.6 Second-Order Equation of Motion for the Reduced Density Operator; 3.6 The Reservoir Correlation Function; 3.6.1 General Properties of Cuv(t); 3.6.2 Harmonic Oscillator Reservoir; 3.6.3 The Spectral Density; 3.6.4 Linear Response Theory for the Reservoir; 3.6.5 Classical description of Cuv(t) 3.7 Quantum Master Equation3.7.1 Markov Approximation; 3.8 Reduced Density Matrix in Energy Representation; 3.8.1 The Quantum Master Equation in Energy Representation; 3.8.2 Multilevel Redfield Equations; 3.8.3 The Secular Approximation; 3.8.4 State Expansion of the System-Reservoir Coupling; 3.8.5 From Coherent to Dissipative Dynamics: A Simple Example; 3.8.6 Coordinate and Wigner Representation of the Reduced Density Matrix; 3.9 Generalized Rate Equations: The Liouville Space Approach; 3.9.1 Projection Operator Technique; 3.9.2 Generalized Rate Equations; 3.9.3 Rate Equations 3.9.4 The Memory Kernels |
| Record Nr. | UNINA-9910130882503321 |
|
May Volkhard
|
||
| Weinheim, : Wiley-VCH, 2011 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Charge and energy transfer dynamics in molecular systems : a theoretical introduction / Volkhard May, Oliver Kühn
| Charge and energy transfer dynamics in molecular systems : a theoretical introduction / Volkhard May, Oliver Kühn |
| Autore | May, Volkhard |
| Pubbl/distr/stampa | Berlin ; New York : Wiley-VCH, c2000 |
| Descrizione fisica | 416 p. : ill. ; 25 cm |
| Disciplina | 541.2/2 |
| Altri autori (Persone) | Kühn, Oliverauthor |
| Soggetto topico |
Molecular dynamics
Energy transfer Charge transfer Quantum chemistry |
| ISBN | 9783527296088 |
| Classificazione | LC QD461 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNISALENTO-991003786309707536 |
|
May, Volkhard
|
||
| Berlin ; New York : Wiley-VCH, c2000 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. del Salento | ||
| ||
Electron transfer- from isolated molecules to biomolecules . Part 1 [[electronic resource] /] / edited by Joshua Jortner and M. Bixon ; series editors, I. Prigogine, Stuart A. Rice
| Electron transfer- from isolated molecules to biomolecules . Part 1 [[electronic resource] /] / edited by Joshua Jortner and M. Bixon ; series editors, I. Prigogine, Stuart A. Rice |
| Pubbl/distr/stampa | New York, : J. Wiley, c1999 |
| Descrizione fisica | 1 online resource (758 p.) |
| Disciplina |
539.72112
541.305 541/.08 |
| Altri autori (Persone) |
JortnerJoshua
BixonM PrigogineI (Ilya) RiceStuart Alan <1932-> |
| Collana | Advances in chemical physics |
| Soggetto topico |
Charge exchange
Charge transfer Charge transfer in biology Electron donor-acceptor complexes Molecular dynamics |
| Soggetto genere / forma | Electronic books. |
| ISBN |
1-282-68199-0
9786612681998 0-470-14165-4 0-470-14218-9 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
ELECTRON TRANSFER FROM ISOLATED MOLECULES TO BIOMOLECULES; CONTENTS TO VOLUME 106; ELECTRON TRANSFER PAST AND FUTURE; ELECTRON TRANSFER REACTIONS IN SOLUTION: A HISTORICAL PERSPECTIVE; ELECTRON TRANSFER-FROM ISOLATED MOLECULES TO BIOMOLECULES; CHARGE TRANSFER IN BICHROMOPHORIC MOLECULES IN THE GAS PHASE; LONG-RANGE CHARGE SEPARATION IN SOLVENT-FREE DONOR-BRIDGE-ACCEPTOR SYSTEMS; ELECTRON TRANSFER AND CHARGE SEPARATION IN CLUSTERS; CONTROL OF ELECTRON TRANSFER KINETICS: MODELS FOR MEDIUM REORGANIZATION AND DONOR-ACCEPTOR COUPLING
THEORIES OF STRUCTURE-FUNCTION RELATIONSHIPS FOR BRIDGE-MEDIATED ELECTRON TRANSFER REACTIONSFLUCTUATIONS AND COHERENCE IN LONG-RANGE AND MULTICENTER ELECTRON TRANSFER; LANCZOS ALGORITHM FOR ELECTRON TRANSFER RATES IN SOLVENTS WITH COMPLEX SPECTRAL DENSITIES; SPECTROSCOPIC DETERMINATION OF ELECTRON TRANSFER BARRIERS AND RATE CONSTANTS; PHOTOINDUCED ELECTRON TRANSFER WITHIN DONOR-SPACER-ACCEPTOR MOLECULAR ASSEMBLIES STUDIED BY TIME-RESOLVED MICROWAVE CONDUCTIVITY; FROM CLOSE CONTACT TO LONG-RANGE INTRAMOLECULAR ELECTRON TRANSFER; PHOTOINDUCED ELECTRON TRANSFERS THROUGH o BONDS IN SOLUTION AUTHOR INDEXSUBJECT INDEX |
| Record Nr. | UNINA-9910144265303321 |
| New York, : J. Wiley, c1999 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Electron transfer- from isolated molecules to biomolecules . Part 1 [[electronic resource] /] / edited by Joshua Jortner and M. Bixon ; series editors, I. Prigogine, Stuart A. Rice
| Electron transfer- from isolated molecules to biomolecules . Part 1 [[electronic resource] /] / edited by Joshua Jortner and M. Bixon ; series editors, I. Prigogine, Stuart A. Rice |
| Pubbl/distr/stampa | New York, : J. Wiley, c1999 |
| Descrizione fisica | 1 online resource (758 p.) |
| Disciplina |
539.72112
541.305 541/.08 |
| Altri autori (Persone) |
JortnerJoshua
BixonM PrigogineI (Ilya) RiceStuart Alan <1932-> |
| Collana | Advances in chemical physics |
| Soggetto topico |
Charge exchange
Charge transfer Charge transfer in biology Electron donor-acceptor complexes Molecular dynamics |
| ISBN |
1-282-68199-0
9786612681998 0-470-14165-4 0-470-14218-9 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
ELECTRON TRANSFER FROM ISOLATED MOLECULES TO BIOMOLECULES; CONTENTS TO VOLUME 106; ELECTRON TRANSFER PAST AND FUTURE; ELECTRON TRANSFER REACTIONS IN SOLUTION: A HISTORICAL PERSPECTIVE; ELECTRON TRANSFER-FROM ISOLATED MOLECULES TO BIOMOLECULES; CHARGE TRANSFER IN BICHROMOPHORIC MOLECULES IN THE GAS PHASE; LONG-RANGE CHARGE SEPARATION IN SOLVENT-FREE DONOR-BRIDGE-ACCEPTOR SYSTEMS; ELECTRON TRANSFER AND CHARGE SEPARATION IN CLUSTERS; CONTROL OF ELECTRON TRANSFER KINETICS: MODELS FOR MEDIUM REORGANIZATION AND DONOR-ACCEPTOR COUPLING
THEORIES OF STRUCTURE-FUNCTION RELATIONSHIPS FOR BRIDGE-MEDIATED ELECTRON TRANSFER REACTIONSFLUCTUATIONS AND COHERENCE IN LONG-RANGE AND MULTICENTER ELECTRON TRANSFER; LANCZOS ALGORITHM FOR ELECTRON TRANSFER RATES IN SOLVENTS WITH COMPLEX SPECTRAL DENSITIES; SPECTROSCOPIC DETERMINATION OF ELECTRON TRANSFER BARRIERS AND RATE CONSTANTS; PHOTOINDUCED ELECTRON TRANSFER WITHIN DONOR-SPACER-ACCEPTOR MOLECULAR ASSEMBLIES STUDIED BY TIME-RESOLVED MICROWAVE CONDUCTIVITY; FROM CLOSE CONTACT TO LONG-RANGE INTRAMOLECULAR ELECTRON TRANSFER; PHOTOINDUCED ELECTRON TRANSFERS THROUGH o BONDS IN SOLUTION AUTHOR INDEXSUBJECT INDEX |
| Record Nr. | UNINA-9910830414403321 |
| New York, : J. Wiley, c1999 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Electron transfer- from isolated molecules to biomolecules . Part 1 [[electronic resource] /] / edited by Joshua Jortner and M. Bixon ; series editors, I. Prigogine, Stuart A. Rice
| Electron transfer- from isolated molecules to biomolecules . Part 1 [[electronic resource] /] / edited by Joshua Jortner and M. Bixon ; series editors, I. Prigogine, Stuart A. Rice |
| Pubbl/distr/stampa | New York, : J. Wiley, c1999 |
| Descrizione fisica | 1 online resource (758 p.) |
| Disciplina |
539.72112
541.305 541/.08 |
| Altri autori (Persone) |
JortnerJoshua
BixonM PrigogineI (Ilya) RiceStuart Alan <1932-> |
| Collana | Advances in chemical physics |
| Soggetto topico |
Charge exchange
Charge transfer Charge transfer in biology Electron donor-acceptor complexes Molecular dynamics |
| ISBN |
1-282-68199-0
9786612681998 0-470-14165-4 0-470-14218-9 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
ELECTRON TRANSFER FROM ISOLATED MOLECULES TO BIOMOLECULES; CONTENTS TO VOLUME 106; ELECTRON TRANSFER PAST AND FUTURE; ELECTRON TRANSFER REACTIONS IN SOLUTION: A HISTORICAL PERSPECTIVE; ELECTRON TRANSFER-FROM ISOLATED MOLECULES TO BIOMOLECULES; CHARGE TRANSFER IN BICHROMOPHORIC MOLECULES IN THE GAS PHASE; LONG-RANGE CHARGE SEPARATION IN SOLVENT-FREE DONOR-BRIDGE-ACCEPTOR SYSTEMS; ELECTRON TRANSFER AND CHARGE SEPARATION IN CLUSTERS; CONTROL OF ELECTRON TRANSFER KINETICS: MODELS FOR MEDIUM REORGANIZATION AND DONOR-ACCEPTOR COUPLING
THEORIES OF STRUCTURE-FUNCTION RELATIONSHIPS FOR BRIDGE-MEDIATED ELECTRON TRANSFER REACTIONSFLUCTUATIONS AND COHERENCE IN LONG-RANGE AND MULTICENTER ELECTRON TRANSFER; LANCZOS ALGORITHM FOR ELECTRON TRANSFER RATES IN SOLVENTS WITH COMPLEX SPECTRAL DENSITIES; SPECTROSCOPIC DETERMINATION OF ELECTRON TRANSFER BARRIERS AND RATE CONSTANTS; PHOTOINDUCED ELECTRON TRANSFER WITHIN DONOR-SPACER-ACCEPTOR MOLECULAR ASSEMBLIES STUDIED BY TIME-RESOLVED MICROWAVE CONDUCTIVITY; FROM CLOSE CONTACT TO LONG-RANGE INTRAMOLECULAR ELECTRON TRANSFER; PHOTOINDUCED ELECTRON TRANSFERS THROUGH o BONDS IN SOLUTION AUTHOR INDEXSUBJECT INDEX |
| Record Nr. | UNINA-9910841095303321 |
| New York, : J. Wiley, c1999 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Electron-transfer and electrochemical reactions [[electronic resource] ] : photochemical and other energized reactions / / editor, J.J. Zuckerman; subject index editor, A.P. Hagen
| Electron-transfer and electrochemical reactions [[electronic resource] ] : photochemical and other energized reactions / / editor, J.J. Zuckerman; subject index editor, A.P. Hagen |
| Pubbl/distr/stampa | [Deerfield Beach, FL], : VCH, c1986 |
| Descrizione fisica | 1 online resource (426 p.) |
| Disciplina |
541.3/9
541.39 |
| Altri autori (Persone) | ZuckermanJ. J <1936-1987.> (Jerold J.) |
| Collana | Inorganic reactions and methods |
| Soggetto topico |
Photochemistry
Charge transfer |
| Soggetto genere / forma | Electronic books. |
| ISBN |
1-282-30827-0
9786612308277 0-470-14530-7 0-470-14551-X |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Inorganic Reactions and Methods; Contents; How to Use this Book; Preface to the Series; Editorial Consultants to the Series; Contributors to Volume 15; Electron-Transfer and Electrochemical Reactions; Introduction; Electron Transfer; Introduction; Classification of Electron-Transfer Reactions; Outer-Sphere Reactions; Examples of Outer-Sphere Reactions; Outer-Sphere Transition States; Inner-Sphere Reactions; Inner-Sphere Reactions: Scheme I; Inner-Sphere Reactions: Scheme II; Inner-Sphere Reactions: Scheme Ill; Double-Ligand Bridging; Other Reaction Classes
Mixed Outer- and Innersphere ReactionsIntramolecular Electron Transfer; Two-Electron Transfers; Theory of Electron-Transfer Reactions; The Stability of the Precursor Complex; Potential-Energy Surfaces; of Zero Order.; of First Order.; The Electronic Factor; Electron-Exchange Reactions; The Reorganization Energy; Nuclear Tunneling in Electron Exchange; Quantum-Mechanical Treatment; Comparison of Observed and Calculated Parameters for Electron Exchange; Electron Transfer Accompanied by a Net Chemical Change; Semiclassical Treatment; Cross Reactions and Electron-Exchange Rates Quantum-Mechanical TreatmentConclusions; General Reactivity Patterns in Electron Transfer; The Inner-Shell Reorganization Energy: Exchange Rates of Aquo Ions; Variations with Ligand: The Outer-Shell Reorganization Energy; Electronic Factors: Nonadiabaticity; Free-Energy Relations; Inner-Sphere Versus Outer-Sphere Electron Transfer; Rate Saturation in Electron Transfer; Specific Reactivity Patterns in Electron-Transfer Reactions; Variation with the Reductant; One-Electron Reductants; Two-Electron Reductants; Variation with the Oxidant; One-Electron Oxidants; Multiple-Electron Oxidants Oxidation and Reduction of Coordinated LigandsCatalysis in Electron-Transfer Reactions; Catalyzed Electron Transfer; Catalyzed Ligand Substitution; Induced Electron-Transfer Reactions; Photoinduced Electron-Transfer Reactions; Electrochemical Reactions; Introduction; The Electrode Process; Reversibility; Electrochemical Reversibility; Chemical Reversibility; Complex Electrode Mechanisms; Diagnostic Electrochemical Measurements; Voltammetric Methods; Direct-Current Polarography; Pulse-Polarographic Methods; Alternating-Current Polarography; Cyclic Voltammetry; Evaluation of Formal Potentials Involving Stable Reactants and Products.Involving Unstable Electrode Products.; Involving Reactants Undergoing Multiple- Electrode Reactions.; Chemical Reactions Accompanying Electrode Reactions; Reactions Preceding Electron Transfer (CE); Slow-Reaction (1 >a) Limit; Intermediate-Reaction Kinetics; Reactions Following Electron Transfer (EC); Giving Electroinactive Products.; Giving Electroactive Products (ECE).; Other Coupled Chemical Reactions; Electrochemical Synthesis; by Controlled-Potential Electrolysis.; Involving Bulk Preparations.; Conclusions Thermodynamics of Simple Electrochemical Reactions |
| Record Nr. | UNINA-9910144319203321 |
| [Deerfield Beach, FL], : VCH, c1986 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Electron-transfer and electrochemical reactions [[electronic resource] ] : photochemical and other energized reactions / / editor, J.J. Zuckerman; subject index editor, A.P. Hagen
| Electron-transfer and electrochemical reactions [[electronic resource] ] : photochemical and other energized reactions / / editor, J.J. Zuckerman; subject index editor, A.P. Hagen |
| Pubbl/distr/stampa | [Deerfield Beach, FL], : VCH, c1986 |
| Descrizione fisica | 1 online resource (426 p.) |
| Disciplina |
541.3/9
541.39 |
| Altri autori (Persone) | ZuckermanJ. J <1936-1987.> (Jerold J.) |
| Collana | Inorganic reactions and methods |
| Soggetto topico |
Photochemistry
Charge transfer |
| ISBN |
1-282-30827-0
9786612308277 0-470-14530-7 0-470-14551-X |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Inorganic Reactions and Methods; Contents; How to Use this Book; Preface to the Series; Editorial Consultants to the Series; Contributors to Volume 15; Electron-Transfer and Electrochemical Reactions; Introduction; Electron Transfer; Introduction; Classification of Electron-Transfer Reactions; Outer-Sphere Reactions; Examples of Outer-Sphere Reactions; Outer-Sphere Transition States; Inner-Sphere Reactions; Inner-Sphere Reactions: Scheme I; Inner-Sphere Reactions: Scheme II; Inner-Sphere Reactions: Scheme Ill; Double-Ligand Bridging; Other Reaction Classes
Mixed Outer- and Innersphere ReactionsIntramolecular Electron Transfer; Two-Electron Transfers; Theory of Electron-Transfer Reactions; The Stability of the Precursor Complex; Potential-Energy Surfaces; of Zero Order.; of First Order.; The Electronic Factor; Electron-Exchange Reactions; The Reorganization Energy; Nuclear Tunneling in Electron Exchange; Quantum-Mechanical Treatment; Comparison of Observed and Calculated Parameters for Electron Exchange; Electron Transfer Accompanied by a Net Chemical Change; Semiclassical Treatment; Cross Reactions and Electron-Exchange Rates Quantum-Mechanical TreatmentConclusions; General Reactivity Patterns in Electron Transfer; The Inner-Shell Reorganization Energy: Exchange Rates of Aquo Ions; Variations with Ligand: The Outer-Shell Reorganization Energy; Electronic Factors: Nonadiabaticity; Free-Energy Relations; Inner-Sphere Versus Outer-Sphere Electron Transfer; Rate Saturation in Electron Transfer; Specific Reactivity Patterns in Electron-Transfer Reactions; Variation with the Reductant; One-Electron Reductants; Two-Electron Reductants; Variation with the Oxidant; One-Electron Oxidants; Multiple-Electron Oxidants Oxidation and Reduction of Coordinated LigandsCatalysis in Electron-Transfer Reactions; Catalyzed Electron Transfer; Catalyzed Ligand Substitution; Induced Electron-Transfer Reactions; Photoinduced Electron-Transfer Reactions; Electrochemical Reactions; Introduction; The Electrode Process; Reversibility; Electrochemical Reversibility; Chemical Reversibility; Complex Electrode Mechanisms; Diagnostic Electrochemical Measurements; Voltammetric Methods; Direct-Current Polarography; Pulse-Polarographic Methods; Alternating-Current Polarography; Cyclic Voltammetry; Evaluation of Formal Potentials Involving Stable Reactants and Products.Involving Unstable Electrode Products.; Involving Reactants Undergoing Multiple- Electrode Reactions.; Chemical Reactions Accompanying Electrode Reactions; Reactions Preceding Electron Transfer (CE); Slow-Reaction (1 >a) Limit; Intermediate-Reaction Kinetics; Reactions Following Electron Transfer (EC); Giving Electroinactive Products.; Giving Electroactive Products (ECE).; Other Coupled Chemical Reactions; Electrochemical Synthesis; by Controlled-Potential Electrolysis.; Involving Bulk Preparations.; Conclusions Thermodynamics of Simple Electrochemical Reactions |
| Record Nr. | UNINA-9910643494803321 |
| [Deerfield Beach, FL], : VCH, c1986 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Electron-transfer and electrochemical reactions [[electronic resource] ] : photochemical and other energized reactions / / editor, J.J. Zuckerman; subject index editor, A.P. Hagen
| Electron-transfer and electrochemical reactions [[electronic resource] ] : photochemical and other energized reactions / / editor, J.J. Zuckerman; subject index editor, A.P. Hagen |
| Pubbl/distr/stampa | [Deerfield Beach, FL], : VCH, c1986 |
| Descrizione fisica | 1 online resource (426 p.) |
| Disciplina |
541.3/9
541.39 |
| Altri autori (Persone) | ZuckermanJ. J <1936-1987.> (Jerold J.) |
| Collana | Inorganic reactions and methods |
| Soggetto topico |
Photochemistry
Charge transfer |
| ISBN |
1-282-30827-0
9786612308277 0-470-14530-7 0-470-14551-X |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Inorganic Reactions and Methods; Contents; How to Use this Book; Preface to the Series; Editorial Consultants to the Series; Contributors to Volume 15; Electron-Transfer and Electrochemical Reactions; Introduction; Electron Transfer; Introduction; Classification of Electron-Transfer Reactions; Outer-Sphere Reactions; Examples of Outer-Sphere Reactions; Outer-Sphere Transition States; Inner-Sphere Reactions; Inner-Sphere Reactions: Scheme I; Inner-Sphere Reactions: Scheme II; Inner-Sphere Reactions: Scheme Ill; Double-Ligand Bridging; Other Reaction Classes
Mixed Outer- and Innersphere ReactionsIntramolecular Electron Transfer; Two-Electron Transfers; Theory of Electron-Transfer Reactions; The Stability of the Precursor Complex; Potential-Energy Surfaces; of Zero Order.; of First Order.; The Electronic Factor; Electron-Exchange Reactions; The Reorganization Energy; Nuclear Tunneling in Electron Exchange; Quantum-Mechanical Treatment; Comparison of Observed and Calculated Parameters for Electron Exchange; Electron Transfer Accompanied by a Net Chemical Change; Semiclassical Treatment; Cross Reactions and Electron-Exchange Rates Quantum-Mechanical TreatmentConclusions; General Reactivity Patterns in Electron Transfer; The Inner-Shell Reorganization Energy: Exchange Rates of Aquo Ions; Variations with Ligand: The Outer-Shell Reorganization Energy; Electronic Factors: Nonadiabaticity; Free-Energy Relations; Inner-Sphere Versus Outer-Sphere Electron Transfer; Rate Saturation in Electron Transfer; Specific Reactivity Patterns in Electron-Transfer Reactions; Variation with the Reductant; One-Electron Reductants; Two-Electron Reductants; Variation with the Oxidant; One-Electron Oxidants; Multiple-Electron Oxidants Oxidation and Reduction of Coordinated LigandsCatalysis in Electron-Transfer Reactions; Catalyzed Electron Transfer; Catalyzed Ligand Substitution; Induced Electron-Transfer Reactions; Photoinduced Electron-Transfer Reactions; Electrochemical Reactions; Introduction; The Electrode Process; Reversibility; Electrochemical Reversibility; Chemical Reversibility; Complex Electrode Mechanisms; Diagnostic Electrochemical Measurements; Voltammetric Methods; Direct-Current Polarography; Pulse-Polarographic Methods; Alternating-Current Polarography; Cyclic Voltammetry; Evaluation of Formal Potentials Involving Stable Reactants and Products.Involving Unstable Electrode Products.; Involving Reactants Undergoing Multiple- Electrode Reactions.; Chemical Reactions Accompanying Electrode Reactions; Reactions Preceding Electron Transfer (CE); Slow-Reaction (1 >a) Limit; Intermediate-Reaction Kinetics; Reactions Following Electron Transfer (EC); Giving Electroinactive Products.; Giving Electroactive Products (ECE).; Other Coupled Chemical Reactions; Electrochemical Synthesis; by Controlled-Potential Electrolysis.; Involving Bulk Preparations.; Conclusions Thermodynamics of Simple Electrochemical Reactions |
| Record Nr. | UNISA-996211961703316 |
| [Deerfield Beach, FL], : VCH, c1986 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. di Salerno | ||
| ||
