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Aqueous-phase organometallic catalysis [[electronic resource] ] : concepts and applications / / edited by Boy Cornils and Wolfgang A. Herrmann
Aqueous-phase organometallic catalysis [[electronic resource] ] : concepts and applications / / edited by Boy Cornils and Wolfgang A. Herrmann
Edizione [2nd, completely rev. and enl. ed.]
Pubbl/distr/stampa Weinheim, : Wiley-VCH, c2004
Descrizione fisica 1 online resource (782 p.)
Disciplina 660.2995
660/.2995
Altri autori (Persone) CornilsBoy
HerrmannW. A (Wolfgang A.)
Collana Green chemistry
Soggetto topico Catalysis
Metal catalysts
Water-soluble organometallic compounds
Catalysts - Recycling
Heterogeneous catalysis
Soggetto genere / forma Electronic books.
ISBN 1-280-52055-8
9786610520558
3-527-60546-0
3-527-60248-8
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Aqueous-Phase Organometallic Catalysis; Preface to the Second Edition; Preface to the First Edition; Contents; Contributors; 1 Introduction; 1 Introduction; 2 Basic Aqueous Chemistry; 2.1 Organic Chemistry in Water; 2.1.1 Introduction; 2.1.2 Origin of the Reactivity in Water; 2.1.3 Pericyclic Reactions; 2.1.3.1 Diels - Alder Reactions; 2.1.3.2 Hetero Diels - Alder Reactions; 2.1.3.3 Other Cycloadditions; 2.1.3.4 Claisen Rearrangements; 2.1.4 Carbonyl Additions; 2.1.4.1 Aldol-type Reactions; 2.1.4.2 Michael-type Reactions; 2.1.4.3 Allylation Reactions; 2.1.5 Oxido-reductions
2.1.5.1 Oxidations2.1.5.2 Reductions; 2.1.6 Radical Reactions; 2.1.7 Outlook; 2.2 Organometallic Chemistry in Water; 2.2.1 Introduction; 2.2.2 Water as a Solvent and Ligand; 2.2.3 Organometallic Reactions of Water; 2.2.4 Catalytic Reactions with Water; 2.2.4.1 Water-gas Shift Reaction; 2.2.4.2 Wacker- Hoechst Acetaldehyde Process; 2.2.4.3 Olefin Hydration; 2.2.4.4 Hydrodimerization; 2.2.5 Water-soluble Metal Complexes; 2.2.6 Perspectives; 2.3 Characterization of Organometallic Compounds in Water; 2.3.1 Introduction; 2.3.2 General Survey
2.3.3 Effect of High Hydrostatic Pressure on Aqueous Organometallic Systems2.3.4 Aqueous Organometallics with Pressurized Gases; 2.3.5 Concluding Remarks; 3 Catalysts for an Aqueous Catalysis; 3.1 Variation of Central Atoms; 3.1.1 Transition Metals; 3.1.1.1 Introduction; 3.1.1.2 Water-soluble Catalysts by Virtue of Water-soluble Ligands; 3.1.1.3 Water-soluble Catalysts through Water Coordination; 3.1.2 Lanthanides in Aqueous-phase Catalysis; 3.1.2.1 Introduction; 3.1.2.2 Aldol Reactions; 3.1.2.3 Mannich-type Reactions; 3.1.2.4 Diels - Alder Reactions; 3.1.2.5 Micellar Systems
3.1.2.6 Asymmetric Catalysis in Aqueous Media3.1.2.7 Conclusions; 3.2 Variation of Ligands; 3.2.1 Monophosphines; 3.2.1.1 General Features, Scope, and Limitations; 3.2.1.2 Anionic Phosphines; 3.2.1.3 Cationic Phosphines; 3.2.1.4 Nonionic Water-soluble Phosphines; 3.2.2 Diphosphines and Other Phosphines; 3.2.2.1 General; 3.2.2.2 Diphosphines - Introduction of Sulfonate Groups by Direct Sulfonation; 3.2.2.3 Introduction of Sulfonate Groups During Synthesis; 3.2.2.4 Diphosphines with Quaternized Aminoalkyl or Aminoaryl Groups; 3.2.2.5 Diphosphines with Hydroxyalkyl or Polyether Substituents
3.2.2.6 Carboxylated Diphosphines3.2.2.7 Amphiphilic Diphosphines; 3.2.2.8 Other Phosphines; 3.2.3 Ligands or Complexes Containing Ancillary Functionalities; 3.2.3.1 Complexes Containing at Least Two Classical Functionalities; 3.2.3.2 Cationic Complexes; 3.2.3.3 Immobilization on Silica Supports; 3.2.3.4 Macromolecular Ligands or Supports; 3.2.3.5 Ligands not Containing Phosphorus; 3.2.3.6 Additional Perspectives; 3.2.4 Tenside Ligands; 3.2.4.1 Introduction; 3.2.4.2 Tenside Phosphines and Amines; 3.2.4.3 Hydroformylation Reactions Catalyzed by Transition Metal Surfactant - Phosphine Complexes
3.2.4.4 Hydrogenation Reactions Catalyzed by Transition Metal Surfactant - Phosphine Complexes
Record Nr. UNINA-9910146237003321
Weinheim, : Wiley-VCH, c2004
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Aqueous-phase organometallic catalysis [[electronic resource] ] : concepts and applications / / edited by Boy Cornils and Wolfgang A. Herrmann
Aqueous-phase organometallic catalysis [[electronic resource] ] : concepts and applications / / edited by Boy Cornils and Wolfgang A. Herrmann
Edizione [2nd, completely rev. and enl. ed.]
Pubbl/distr/stampa Weinheim, : Wiley-VCH, c2004
Descrizione fisica 1 online resource (782 p.)
Disciplina 660.2995
660/.2995
Altri autori (Persone) CornilsBoy
HerrmannW. A (Wolfgang A.)
Collana Green chemistry
Soggetto topico Catalysis
Metal catalysts
Water-soluble organometallic compounds
Catalysts - Recycling
Heterogeneous catalysis
ISBN 1-280-52055-8
9786610520558
3-527-60546-0
3-527-60248-8
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Aqueous-Phase Organometallic Catalysis; Preface to the Second Edition; Preface to the First Edition; Contents; Contributors; 1 Introduction; 1 Introduction; 2 Basic Aqueous Chemistry; 2.1 Organic Chemistry in Water; 2.1.1 Introduction; 2.1.2 Origin of the Reactivity in Water; 2.1.3 Pericyclic Reactions; 2.1.3.1 Diels - Alder Reactions; 2.1.3.2 Hetero Diels - Alder Reactions; 2.1.3.3 Other Cycloadditions; 2.1.3.4 Claisen Rearrangements; 2.1.4 Carbonyl Additions; 2.1.4.1 Aldol-type Reactions; 2.1.4.2 Michael-type Reactions; 2.1.4.3 Allylation Reactions; 2.1.5 Oxido-reductions
2.1.5.1 Oxidations2.1.5.2 Reductions; 2.1.6 Radical Reactions; 2.1.7 Outlook; 2.2 Organometallic Chemistry in Water; 2.2.1 Introduction; 2.2.2 Water as a Solvent and Ligand; 2.2.3 Organometallic Reactions of Water; 2.2.4 Catalytic Reactions with Water; 2.2.4.1 Water-gas Shift Reaction; 2.2.4.2 Wacker- Hoechst Acetaldehyde Process; 2.2.4.3 Olefin Hydration; 2.2.4.4 Hydrodimerization; 2.2.5 Water-soluble Metal Complexes; 2.2.6 Perspectives; 2.3 Characterization of Organometallic Compounds in Water; 2.3.1 Introduction; 2.3.2 General Survey
2.3.3 Effect of High Hydrostatic Pressure on Aqueous Organometallic Systems2.3.4 Aqueous Organometallics with Pressurized Gases; 2.3.5 Concluding Remarks; 3 Catalysts for an Aqueous Catalysis; 3.1 Variation of Central Atoms; 3.1.1 Transition Metals; 3.1.1.1 Introduction; 3.1.1.2 Water-soluble Catalysts by Virtue of Water-soluble Ligands; 3.1.1.3 Water-soluble Catalysts through Water Coordination; 3.1.2 Lanthanides in Aqueous-phase Catalysis; 3.1.2.1 Introduction; 3.1.2.2 Aldol Reactions; 3.1.2.3 Mannich-type Reactions; 3.1.2.4 Diels - Alder Reactions; 3.1.2.5 Micellar Systems
3.1.2.6 Asymmetric Catalysis in Aqueous Media3.1.2.7 Conclusions; 3.2 Variation of Ligands; 3.2.1 Monophosphines; 3.2.1.1 General Features, Scope, and Limitations; 3.2.1.2 Anionic Phosphines; 3.2.1.3 Cationic Phosphines; 3.2.1.4 Nonionic Water-soluble Phosphines; 3.2.2 Diphosphines and Other Phosphines; 3.2.2.1 General; 3.2.2.2 Diphosphines - Introduction of Sulfonate Groups by Direct Sulfonation; 3.2.2.3 Introduction of Sulfonate Groups During Synthesis; 3.2.2.4 Diphosphines with Quaternized Aminoalkyl or Aminoaryl Groups; 3.2.2.5 Diphosphines with Hydroxyalkyl or Polyether Substituents
3.2.2.6 Carboxylated Diphosphines3.2.2.7 Amphiphilic Diphosphines; 3.2.2.8 Other Phosphines; 3.2.3 Ligands or Complexes Containing Ancillary Functionalities; 3.2.3.1 Complexes Containing at Least Two Classical Functionalities; 3.2.3.2 Cationic Complexes; 3.2.3.3 Immobilization on Silica Supports; 3.2.3.4 Macromolecular Ligands or Supports; 3.2.3.5 Ligands not Containing Phosphorus; 3.2.3.6 Additional Perspectives; 3.2.4 Tenside Ligands; 3.2.4.1 Introduction; 3.2.4.2 Tenside Phosphines and Amines; 3.2.4.3 Hydroformylation Reactions Catalyzed by Transition Metal Surfactant - Phosphine Complexes
3.2.4.4 Hydrogenation Reactions Catalyzed by Transition Metal Surfactant - Phosphine Complexes
Record Nr. UNINA-9910830585403321
Weinheim, : Wiley-VCH, c2004
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Aqueous-phase organometallic catalysis [[electronic resource] ] : concepts and applications / / edited by Boy Cornils and Wolfgang A. Herrmann
Aqueous-phase organometallic catalysis [[electronic resource] ] : concepts and applications / / edited by Boy Cornils and Wolfgang A. Herrmann
Edizione [2nd, completely rev. and enl. ed.]
Pubbl/distr/stampa Weinheim, : Wiley-VCH, c2004
Descrizione fisica 1 online resource (782 p.)
Disciplina 660.2995
660/.2995
Altri autori (Persone) CornilsBoy
HerrmannW. A (Wolfgang A.)
Collana Green chemistry
Soggetto topico Catalysis
Metal catalysts
Water-soluble organometallic compounds
Catalysts - Recycling
Heterogeneous catalysis
ISBN 1-280-52055-8
9786610520558
3-527-60546-0
3-527-60248-8
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Aqueous-Phase Organometallic Catalysis; Preface to the Second Edition; Preface to the First Edition; Contents; Contributors; 1 Introduction; 1 Introduction; 2 Basic Aqueous Chemistry; 2.1 Organic Chemistry in Water; 2.1.1 Introduction; 2.1.2 Origin of the Reactivity in Water; 2.1.3 Pericyclic Reactions; 2.1.3.1 Diels - Alder Reactions; 2.1.3.2 Hetero Diels - Alder Reactions; 2.1.3.3 Other Cycloadditions; 2.1.3.4 Claisen Rearrangements; 2.1.4 Carbonyl Additions; 2.1.4.1 Aldol-type Reactions; 2.1.4.2 Michael-type Reactions; 2.1.4.3 Allylation Reactions; 2.1.5 Oxido-reductions
2.1.5.1 Oxidations2.1.5.2 Reductions; 2.1.6 Radical Reactions; 2.1.7 Outlook; 2.2 Organometallic Chemistry in Water; 2.2.1 Introduction; 2.2.2 Water as a Solvent and Ligand; 2.2.3 Organometallic Reactions of Water; 2.2.4 Catalytic Reactions with Water; 2.2.4.1 Water-gas Shift Reaction; 2.2.4.2 Wacker- Hoechst Acetaldehyde Process; 2.2.4.3 Olefin Hydration; 2.2.4.4 Hydrodimerization; 2.2.5 Water-soluble Metal Complexes; 2.2.6 Perspectives; 2.3 Characterization of Organometallic Compounds in Water; 2.3.1 Introduction; 2.3.2 General Survey
2.3.3 Effect of High Hydrostatic Pressure on Aqueous Organometallic Systems2.3.4 Aqueous Organometallics with Pressurized Gases; 2.3.5 Concluding Remarks; 3 Catalysts for an Aqueous Catalysis; 3.1 Variation of Central Atoms; 3.1.1 Transition Metals; 3.1.1.1 Introduction; 3.1.1.2 Water-soluble Catalysts by Virtue of Water-soluble Ligands; 3.1.1.3 Water-soluble Catalysts through Water Coordination; 3.1.2 Lanthanides in Aqueous-phase Catalysis; 3.1.2.1 Introduction; 3.1.2.2 Aldol Reactions; 3.1.2.3 Mannich-type Reactions; 3.1.2.4 Diels - Alder Reactions; 3.1.2.5 Micellar Systems
3.1.2.6 Asymmetric Catalysis in Aqueous Media3.1.2.7 Conclusions; 3.2 Variation of Ligands; 3.2.1 Monophosphines; 3.2.1.1 General Features, Scope, and Limitations; 3.2.1.2 Anionic Phosphines; 3.2.1.3 Cationic Phosphines; 3.2.1.4 Nonionic Water-soluble Phosphines; 3.2.2 Diphosphines and Other Phosphines; 3.2.2.1 General; 3.2.2.2 Diphosphines - Introduction of Sulfonate Groups by Direct Sulfonation; 3.2.2.3 Introduction of Sulfonate Groups During Synthesis; 3.2.2.4 Diphosphines with Quaternized Aminoalkyl or Aminoaryl Groups; 3.2.2.5 Diphosphines with Hydroxyalkyl or Polyether Substituents
3.2.2.6 Carboxylated Diphosphines3.2.2.7 Amphiphilic Diphosphines; 3.2.2.8 Other Phosphines; 3.2.3 Ligands or Complexes Containing Ancillary Functionalities; 3.2.3.1 Complexes Containing at Least Two Classical Functionalities; 3.2.3.2 Cationic Complexes; 3.2.3.3 Immobilization on Silica Supports; 3.2.3.4 Macromolecular Ligands or Supports; 3.2.3.5 Ligands not Containing Phosphorus; 3.2.3.6 Additional Perspectives; 3.2.4 Tenside Ligands; 3.2.4.1 Introduction; 3.2.4.2 Tenside Phosphines and Amines; 3.2.4.3 Hydroformylation Reactions Catalyzed by Transition Metal Surfactant - Phosphine Complexes
3.2.4.4 Hydrogenation Reactions Catalyzed by Transition Metal Surfactant - Phosphine Complexes
Record Nr. UNINA-9910841094903321
Weinheim, : Wiley-VCH, c2004
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Handbook of spent hydroprocessing catalysts / / Meena Marafi, Antony Stanislaus, Edward Furimsky
Handbook of spent hydroprocessing catalysts / / Meena Marafi, Antony Stanislaus, Edward Furimsky
Autore Marafi Meena
Edizione [Second edition.]
Pubbl/distr/stampa Amsterdam, Netherlands : , : Elsevier, , 2017
Descrizione fisica 1 online resource (470 pages)
Disciplina 541.395
Soggetto topico Catalysts - Recycling
Hazardous wastes
Catalysts
ISBN 0-444-63885-7
0-444-63881-4
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Record Nr. UNINA-9910583058603321
Marafi Meena  
Amsterdam, Netherlands : , : Elsevier, , 2017
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Recoverable and recyclable catalysts [[electronic resource] /] / edited by Maurizio Benaglia
Recoverable and recyclable catalysts [[electronic resource] /] / edited by Maurizio Benaglia
Pubbl/distr/stampa Hoboken, N.J., : Wiley, 2009
Descrizione fisica 1 online resource (494 p.)
Disciplina 541
541.395
Altri autori (Persone) BenagliaMaurizio
Soggetto topico Catalysts - Recycling
Catalysis
ISBN 1-4443-0974-9
1-282-29159-9
9786612291593
0-470-68200-0
0-470-68201-9
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Recoverable and Recyclable Catalysts; Contents; Preface; Acknowledgements; Contributors; 1 The Experimental Assay of Catalyst Recovery: General Concepts; 1.1 Introduction; 1.2 Catalyst Precursor vs Catalyst; 1.3 Catalyst vs Catalyst Resting State; 1.4 Catalyst Inventory: Loss Mechanisms; 1.4.1 Catalyst Decomposition; 1.4.2 Catalyst Leaching; 1.5 Evaluation of Catalyst Recovery; 1.5.1 Product Yield, Conversion, or TON as a Function of Cycle: Poor and Potentially Deceptive Criteria; 1.5.2 Reaction Rate or TOF as a Function of Cycle; 1.5.3 Gravimetric and Other Assays of Recovered Catalyst
1.5.4 Special Caveats when 'Residues' are Recycled1.6 Prospective; References; 2 Surface-functionalized Nanoporous Catalysts for Renewable Chemistry; 2.1 Introduction; 2.1.1 Homogeneous Catalysis vs Heterogeneous Catalysis; 2.1.2 Multi-Site vs Single-Site Heterogeneous Catalysis; 2.2 Immobilization Strategies of Heterogeneous Catalysts; 2.2.1 Supported Materials; 2.2.2 Conventional Methods to Functionalize Silica Surfaces; 2.2.3 Alternative Synthesis of Immobilized Complex Catalysts on a Solid Support; 2.2.4 Techniques for Characterization of Heterogeneous Catalysts
2.3 Efficient Heterogeneous Catalysts with Enhanced Reactivity and Selectivity with Functionality2.3.1 Surface Interaction of Silica and Immobilized Homogeneous Catalysts; 2.3.2 Introduction of Functionalities and Control of Silica Support Morphology; 2.3.3 Selective Surface Functionalization of Solid Support for Utilization of Nanospace Inside the Porous Structure; 2.3.4 Cooperative Catalysis by Multifunctionalized Heterogeneous Catalyst Systems; 2.3.5 Mesoporous Mixed Metal Oxides for Heterogeneous Catalysts; 2.4 Other Heterogeneous Catalyst Systems on Nonsilica Supports; 2.5 Conclusion
References3 Insoluble Resin-supported Catalysts; 3.1 Introduction; 3.2 Transition Metal Catalyzed C-C Bond Formation Reactions; 3.2.1 Pd-catalyzed Reactions; 3.2.2 Asymmetric Additions of Organozinc Reagents to Aldehydes; 3.2.3 Rh-catalyzed Asymmetric Intermolecular C-H Activation; 3.2.4 Cu-catalyzed Asymmetric Cyclopropanation; 3.3 Oxidation; 3.3.1 Oxidation of Sulfides to Sulfoxide; 3.3.2 Oxidation of Alkanes, Alkenes and Alcohols; 3.3.3 Epoxidation of Alkenes; 3.3.4 Asymmetric Hydroformylation of Olefins; 3.3.5 Asymmetric Dihydroxylation of Alkenes; 3.4 Reduction
3.4.1 Asymmetric Reduction of Ketones3.4.2 Reduction of Carboxamides to Amines; 3.5 Organocatalyzed Reactions; 3.5.1 Asymmetric Aldol Reaction and Aminoxylation; 3.5.2 Asymmetric Tandem Reaction; 3.5.3 Allylation of Aldehydes; 3.5.4 Nucleophilic Substitution Reactions; 3.6 Annulation Reactions; 3.6.1 Cycloaddition; 3.6.2 Intramolecular Hydroamination; 3.7 Miscellaneous; 3.8 Conclusion; References; 4 Catalysts Bound to Soluble Polymers; 4.1 Introduction; 4.2 Soluble Supports - General Considerations; 4.3 Recent Developments of Soluble Polymer-supported Catalysts
4.3.1 Attachment of Catalysts to Polymer Supports
Record Nr. UNINA-9910139924103321
Hoboken, N.J., : Wiley, 2009
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Recoverable and recyclable catalysts [[electronic resource] /] / edited by Maurizio Benaglia
Recoverable and recyclable catalysts [[electronic resource] /] / edited by Maurizio Benaglia
Pubbl/distr/stampa Hoboken, N.J., : Wiley, 2009
Descrizione fisica 1 online resource (494 p.)
Disciplina 541
541.395
Altri autori (Persone) BenagliaMaurizio
Soggetto topico Catalysts - Recycling
Catalysis
ISBN 1-4443-0974-9
1-282-29159-9
9786612291593
0-470-68200-0
0-470-68201-9
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Recoverable and Recyclable Catalysts; Contents; Preface; Acknowledgements; Contributors; 1 The Experimental Assay of Catalyst Recovery: General Concepts; 1.1 Introduction; 1.2 Catalyst Precursor vs Catalyst; 1.3 Catalyst vs Catalyst Resting State; 1.4 Catalyst Inventory: Loss Mechanisms; 1.4.1 Catalyst Decomposition; 1.4.2 Catalyst Leaching; 1.5 Evaluation of Catalyst Recovery; 1.5.1 Product Yield, Conversion, or TON as a Function of Cycle: Poor and Potentially Deceptive Criteria; 1.5.2 Reaction Rate or TOF as a Function of Cycle; 1.5.3 Gravimetric and Other Assays of Recovered Catalyst
1.5.4 Special Caveats when 'Residues' are Recycled1.6 Prospective; References; 2 Surface-functionalized Nanoporous Catalysts for Renewable Chemistry; 2.1 Introduction; 2.1.1 Homogeneous Catalysis vs Heterogeneous Catalysis; 2.1.2 Multi-Site vs Single-Site Heterogeneous Catalysis; 2.2 Immobilization Strategies of Heterogeneous Catalysts; 2.2.1 Supported Materials; 2.2.2 Conventional Methods to Functionalize Silica Surfaces; 2.2.3 Alternative Synthesis of Immobilized Complex Catalysts on a Solid Support; 2.2.4 Techniques for Characterization of Heterogeneous Catalysts
2.3 Efficient Heterogeneous Catalysts with Enhanced Reactivity and Selectivity with Functionality2.3.1 Surface Interaction of Silica and Immobilized Homogeneous Catalysts; 2.3.2 Introduction of Functionalities and Control of Silica Support Morphology; 2.3.3 Selective Surface Functionalization of Solid Support for Utilization of Nanospace Inside the Porous Structure; 2.3.4 Cooperative Catalysis by Multifunctionalized Heterogeneous Catalyst Systems; 2.3.5 Mesoporous Mixed Metal Oxides for Heterogeneous Catalysts; 2.4 Other Heterogeneous Catalyst Systems on Nonsilica Supports; 2.5 Conclusion
References3 Insoluble Resin-supported Catalysts; 3.1 Introduction; 3.2 Transition Metal Catalyzed C-C Bond Formation Reactions; 3.2.1 Pd-catalyzed Reactions; 3.2.2 Asymmetric Additions of Organozinc Reagents to Aldehydes; 3.2.3 Rh-catalyzed Asymmetric Intermolecular C-H Activation; 3.2.4 Cu-catalyzed Asymmetric Cyclopropanation; 3.3 Oxidation; 3.3.1 Oxidation of Sulfides to Sulfoxide; 3.3.2 Oxidation of Alkanes, Alkenes and Alcohols; 3.3.3 Epoxidation of Alkenes; 3.3.4 Asymmetric Hydroformylation of Olefins; 3.3.5 Asymmetric Dihydroxylation of Alkenes; 3.4 Reduction
3.4.1 Asymmetric Reduction of Ketones3.4.2 Reduction of Carboxamides to Amines; 3.5 Organocatalyzed Reactions; 3.5.1 Asymmetric Aldol Reaction and Aminoxylation; 3.5.2 Asymmetric Tandem Reaction; 3.5.3 Allylation of Aldehydes; 3.5.4 Nucleophilic Substitution Reactions; 3.6 Annulation Reactions; 3.6.1 Cycloaddition; 3.6.2 Intramolecular Hydroamination; 3.7 Miscellaneous; 3.8 Conclusion; References; 4 Catalysts Bound to Soluble Polymers; 4.1 Introduction; 4.2 Soluble Supports - General Considerations; 4.3 Recent Developments of Soluble Polymer-supported Catalysts
4.3.1 Attachment of Catalysts to Polymer Supports
Record Nr. UNINA-9910830589403321
Hoboken, N.J., : Wiley, 2009
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Recoverable and recyclable catalysts [[electronic resource] /] / edited by Maurizio Benaglia
Recoverable and recyclable catalysts [[electronic resource] /] / edited by Maurizio Benaglia
Pubbl/distr/stampa Hoboken, N.J., : Wiley, 2009
Descrizione fisica 1 online resource (494 p.)
Disciplina 541
541.395
Altri autori (Persone) BenagliaMaurizio
Soggetto topico Catalysts - Recycling
Catalysis
ISBN 1-4443-0974-9
1-282-29159-9
9786612291593
0-470-68200-0
0-470-68201-9
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Recoverable and Recyclable Catalysts; Contents; Preface; Acknowledgements; Contributors; 1 The Experimental Assay of Catalyst Recovery: General Concepts; 1.1 Introduction; 1.2 Catalyst Precursor vs Catalyst; 1.3 Catalyst vs Catalyst Resting State; 1.4 Catalyst Inventory: Loss Mechanisms; 1.4.1 Catalyst Decomposition; 1.4.2 Catalyst Leaching; 1.5 Evaluation of Catalyst Recovery; 1.5.1 Product Yield, Conversion, or TON as a Function of Cycle: Poor and Potentially Deceptive Criteria; 1.5.2 Reaction Rate or TOF as a Function of Cycle; 1.5.3 Gravimetric and Other Assays of Recovered Catalyst
1.5.4 Special Caveats when 'Residues' are Recycled1.6 Prospective; References; 2 Surface-functionalized Nanoporous Catalysts for Renewable Chemistry; 2.1 Introduction; 2.1.1 Homogeneous Catalysis vs Heterogeneous Catalysis; 2.1.2 Multi-Site vs Single-Site Heterogeneous Catalysis; 2.2 Immobilization Strategies of Heterogeneous Catalysts; 2.2.1 Supported Materials; 2.2.2 Conventional Methods to Functionalize Silica Surfaces; 2.2.3 Alternative Synthesis of Immobilized Complex Catalysts on a Solid Support; 2.2.4 Techniques for Characterization of Heterogeneous Catalysts
2.3 Efficient Heterogeneous Catalysts with Enhanced Reactivity and Selectivity with Functionality2.3.1 Surface Interaction of Silica and Immobilized Homogeneous Catalysts; 2.3.2 Introduction of Functionalities and Control of Silica Support Morphology; 2.3.3 Selective Surface Functionalization of Solid Support for Utilization of Nanospace Inside the Porous Structure; 2.3.4 Cooperative Catalysis by Multifunctionalized Heterogeneous Catalyst Systems; 2.3.5 Mesoporous Mixed Metal Oxides for Heterogeneous Catalysts; 2.4 Other Heterogeneous Catalyst Systems on Nonsilica Supports; 2.5 Conclusion
References3 Insoluble Resin-supported Catalysts; 3.1 Introduction; 3.2 Transition Metal Catalyzed C-C Bond Formation Reactions; 3.2.1 Pd-catalyzed Reactions; 3.2.2 Asymmetric Additions of Organozinc Reagents to Aldehydes; 3.2.3 Rh-catalyzed Asymmetric Intermolecular C-H Activation; 3.2.4 Cu-catalyzed Asymmetric Cyclopropanation; 3.3 Oxidation; 3.3.1 Oxidation of Sulfides to Sulfoxide; 3.3.2 Oxidation of Alkanes, Alkenes and Alcohols; 3.3.3 Epoxidation of Alkenes; 3.3.4 Asymmetric Hydroformylation of Olefins; 3.3.5 Asymmetric Dihydroxylation of Alkenes; 3.4 Reduction
3.4.1 Asymmetric Reduction of Ketones3.4.2 Reduction of Carboxamides to Amines; 3.5 Organocatalyzed Reactions; 3.5.1 Asymmetric Aldol Reaction and Aminoxylation; 3.5.2 Asymmetric Tandem Reaction; 3.5.3 Allylation of Aldehydes; 3.5.4 Nucleophilic Substitution Reactions; 3.6 Annulation Reactions; 3.6.1 Cycloaddition; 3.6.2 Intramolecular Hydroamination; 3.7 Miscellaneous; 3.8 Conclusion; References; 4 Catalysts Bound to Soluble Polymers; 4.1 Introduction; 4.2 Soluble Supports - General Considerations; 4.3 Recent Developments of Soluble Polymer-supported Catalysts
4.3.1 Attachment of Catalysts to Polymer Supports
Record Nr. UNINA-9910841097603321
Hoboken, N.J., : Wiley, 2009
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui