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Carbene / / Satyen Saha, Arunava Manna
| Carbene / / Satyen Saha, Arunava Manna |
| Autore | Saha Satyen |
| Pubbl/distr/stampa | London : , : IntechOpen, , 2022 |
| Descrizione fisica | 1 online resource (182pages) |
| Disciplina | 547.412 |
| Soggetto topico | Carbenes (Methylene compounds) |
| Formato | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNINA-9910688240503321 |
Saha Satyen
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| London : , : IntechOpen, , 2022 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
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Carbene / / edited by Satyen Saha, Arunava Manna
| Carbene / / edited by Satyen Saha, Arunava Manna |
| Pubbl/distr/stampa | London, England : , : IntechOpen, , [2022] |
| Descrizione fisica | 1 online resource (184 pages) : illustrations |
| Disciplina | 547.412 |
| Soggetto topico | Carbenes (Methylene compounds) |
| ISBN | 1-83969-930-2 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNINA-9910586653403321 |
| London, England : , : IntechOpen, , [2022] | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
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Contemporary carbene chemistry / / edited by Robert A. Moss, Michael P. Doyle
| Contemporary carbene chemistry / / edited by Robert A. Moss, Michael P. Doyle |
| Autore | Moss Robert A. |
| Pubbl/distr/stampa | Hoboken, New Jersey : , : John Wiley and Sons, , 2014 |
| Descrizione fisica | 1 online resource (606 p.) |
| Disciplina | 547/.01 |
| Altri autori (Persone) |
MossRobert A
DoyleMichael P |
| Collana | Wiley Series of Reactive Intermediates in Chemistry and Biology |
| Soggetto topico |
Carbenes (Methylene compounds)
Carbon compounds |
| ISBN |
1-118-73026-7
1-118-73037-2 1-118-73040-2 |
| Classificazione | SCI013050 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto | Machine generated contents note: Preface PART 1: PROPERTIES AND REACTIONS OF CARBENES 1 Carbene Stability S. Gronert and R. M. O'Ferrall 2 Stable Carbenes J. P. Moerdyk and C. W. Bielawski 3 Acid-Base Chemistry of Carbenes A. M. O'Donoghue and R. S. Massey 4 Computational Methods for the Study of Carbenes and their Excited States H. L. Luk, S. Vyas, and C. M. Hadad 5 Dynamics in Carbene Reactions D. Merrer, K. Houk, and L. Xu 6 Ultrafast Kinetics of Carbene Reactions G. Burdzinski and M. S. Platz 7 Tunneling in the Reactions of Carbenes and Oxacarbenes D. Gerbig and P. R. Schreiner 8 Carbodicarbenes G. Frenking and R. Tonner 9 Catalytic Reactions with N-Mesityl Substituted N-Heterocyclic Carbenes J. Mahatthananchai and J. W. Bode 10 Supramolecular Carbene Chemistry U. Brinker, J.-L. Mieusset, and M. G. Rosenberg PART 2: METAL CARBENES 11 Modern Lithium Carbenoid Chemistry V. Capriati 12 Rhodium Carbenes H. Davies and B. Parr 13 Ruthenium Carbenes S. T. Diver and J. M. French 14 Nucleophilic Carbenes of the Chromium Triad Z. J. Tonzetich 15 Cobalt-Mediated Carbene Transfer Reactions X. Cui and X. P. Zhang 16 Gold Carbenes L. Zhang . |
| Record Nr. | UNINA-9910138853703321 |
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Moss Robert A.
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| Hoboken, New Jersey : , : John Wiley and Sons, , 2014 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
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Contemporary carbene chemistry / / edited by Robert A. Moss, Michael P. Doyle
| Contemporary carbene chemistry / / edited by Robert A. Moss, Michael P. Doyle |
| Autore | Moss Robert A. |
| Pubbl/distr/stampa | Hoboken, New Jersey : , : John Wiley and Sons, , 2014 |
| Descrizione fisica | 1 online resource (606 p.) |
| Disciplina | 547/.01 |
| Altri autori (Persone) |
MossRobert A
DoyleMichael P |
| Collana | Wiley Series of Reactive Intermediates in Chemistry and Biology |
| Soggetto topico |
Carbenes (Methylene compounds)
Carbon compounds |
| ISBN |
1-118-73026-7
1-118-73037-2 1-118-73040-2 |
| Classificazione | SCI013050 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto | Machine generated contents note: Preface PART 1: PROPERTIES AND REACTIONS OF CARBENES 1 Carbene Stability S. Gronert and R. M. O'Ferrall 2 Stable Carbenes J. P. Moerdyk and C. W. Bielawski 3 Acid-Base Chemistry of Carbenes A. M. O'Donoghue and R. S. Massey 4 Computational Methods for the Study of Carbenes and their Excited States H. L. Luk, S. Vyas, and C. M. Hadad 5 Dynamics in Carbene Reactions D. Merrer, K. Houk, and L. Xu 6 Ultrafast Kinetics of Carbene Reactions G. Burdzinski and M. S. Platz 7 Tunneling in the Reactions of Carbenes and Oxacarbenes D. Gerbig and P. R. Schreiner 8 Carbodicarbenes G. Frenking and R. Tonner 9 Catalytic Reactions with N-Mesityl Substituted N-Heterocyclic Carbenes J. Mahatthananchai and J. W. Bode 10 Supramolecular Carbene Chemistry U. Brinker, J.-L. Mieusset, and M. G. Rosenberg PART 2: METAL CARBENES 11 Modern Lithium Carbenoid Chemistry V. Capriati 12 Rhodium Carbenes H. Davies and B. Parr 13 Ruthenium Carbenes S. T. Diver and J. M. French 14 Nucleophilic Carbenes of the Chromium Triad Z. J. Tonzetich 15 Cobalt-Mediated Carbene Transfer Reactions X. Cui and X. P. Zhang 16 Gold Carbenes L. Zhang . |
| Record Nr. | UNINA-9910827700303321 |
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Moss Robert A.
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| Hoboken, New Jersey : , : John Wiley and Sons, , 2014 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
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Heterocycles from carbenes and nitrenes : methods, reactions and synthetic applications / / edited by Michael P. Doyle, Xinfang Xu
| Heterocycles from carbenes and nitrenes : methods, reactions and synthetic applications / / edited by Michael P. Doyle, Xinfang Xu |
| Edizione | [1st ed. 2023.] |
| Pubbl/distr/stampa | Cham : , : Springer International Publishing : , : Imprint : Springer, , 2023 |
| Descrizione fisica | 1 online resource (381 pages) |
| Disciplina | 547.59 |
| Altri autori (Persone) |
DoyleMichael P. <1949->
XuXinfang, Professor |
| Collana | Topics in Heterocyclic Chemistry |
| Soggetto topico |
Carbenes (Methylene compounds)
Heterocyclic compounds |
| ISBN | 3-031-36735-9 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto | Photo-induced Carbene Transformations to Heterocycles -- Heterocycles from Onium Ylides -- Heterocycles from Sulfur Ylides -- Heterocycles from Cascade Reactions via Carbene gem-difunctionalization -- Cyclopropanation of Heterocycles -- Heterocycles from Cycloaddition Reaction -- Alkynes as Carbene Precursors for the Synthesis of Heterocycles -- Heterocycles from Donor/Donor Carbenes -- Heterocycles by Nitrene Transfer Reactions. |
| Record Nr. | UNINA-9910739477903321 |
| Cham : , : Springer International Publishing : , : Imprint : Springer, , 2023 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
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Metal carbenes in organic synthesis / / Florencio Zaragoza Dörwald
| Metal carbenes in organic synthesis / / Florencio Zaragoza Dörwald |
| Autore | Dörwald Florencio Zaragoza |
| Pubbl/distr/stampa | Weinheim, [Germany] : , : Wiley-VCH, , 1999 |
| Descrizione fisica | 1 online resource (311 p.) |
| Disciplina |
547.050459
547.2 |
| Soggetto topico |
Carbenes (Methylene compounds)
Organic compounds - Synthesis |
| Soggetto genere / forma | Electronic books. |
| ISBN |
1-281-84252-4
9786611842529 3-527-61406-0 3-527-61407-9 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Metal Carbenes in Organic Synthesis; Table of Contents; Abbreviations; Experimental Procedures; 1 The Carbon-Metal Double Bond; 1 1 Reactivity of Carbene Complexes; 1.2 Fischer-Type and Schrock-Type Carbene Complexes: Theoretical Treatment; 1.3 Olefin Metathesis and Olefin Cyclopropanation; 1.4 Characteristic NMR Data; 2 Heteroatom-Substituted Carbene Complexes; 2.1 Generation of Heteroatom-Substituted Carbene Complexes; 2.1.1 From Acyl Complexes; 2.1.1.1 From Acyl Complexes Generated from Carbonyl Complexes; 2.1.1.2 From Acyl Complexes Generated from Metallates
2.1.1.3 From Acyl Complexes Generated by Other Methods2.1.2 From Isonitrile Complexes; 2.1.3 From a-Haloiminium Salts and Metallates; 2.1.4 From Carboxamides and Metallates; 2.1.5 From Vinylidene Complexes; 2.1.5.1 From Vinylidene Complexes Generated from Alkynes; 2.1.5.2 From Vinylidene Complexes Generated from Alkynyl Complexes; 2.1.6 From Carbenes and Carbenoids; 2.1.7 From Alkyl Complexes by a-Abstraction; 2.1.8 From Carbyne Complexes; 2.1.9 Other Methods; 2.2 Synthetic Applications of Heteroatom-Substituted Carbene Complexes; 2.2.1 General Considerations 2.2.2 Demetallation and Formation of Acyclic Products2.2.3 Photochemical Transformations; 2.2.4 Cyclopropanation; 2.2.5 Thermal Benzannulations; 2.2.5.1 The Dötz Benzannulation Reaction; 2.2.5.2 Other Thermal Benzannulations; 2.2.6 Formation of Five-Membered Rings; 2.2.6.1 Cyclization of (1,3-Butadien-1-yl)carbene Complexes; 2.2.6.2 Cyclization of Functionalized Carbene Complexes; 2.2.6.3 Rearrangement of Ammonium Ylides; 2.2.6.4 Other Methods; 2.2.7 Formation of Six-Membered. Non-Aromatic Carbocycles and Six-Membered Heterocycles; 2.2.8 Formation of Seven-Membered Rings 3 Non-Heteroatom-Substituted Carbene Complexes3.1 Generation of Non-Heteroatom-Substituted Carbene Complexes; 3.1.1 a-Abstraction of Electrophiles (Nucleophilic Abstraction); 3.1.2 a-Abstraction of Nucleophiles (Electrophilic Abstraction); 3.1.2.1 a-Abstraction of Hydride; 3.1.2.2 a-Abstraction of Oxygen-Bound Leaving Groups; 3.1.2.3 a-Abstraction of Thioethers; 3.1.2.4 a-Abstraction of Halides; 3.1.3 From Ylides; 3.1.3.1 From Diazoalkanes; 3.1.3.2 From Other Ylides; 3.1.4 From Carbyne Complexes; 3.1.4.1 Nucleophilic Additions to Carbyne Complexes 3.1.4.2 Electrophilic Additions to Carbyne Complexes3.1.5 From Alkynyl and Alkenyl Complexes; 3.1.6 From Alkyne and Cyclopropene Complexes; 3.1.7 By [2 + 2] Cycloreversion; 3.1.8 Other Methods; 3.2 Synthetic Applications of Non-Heteroatom-Substituted Carbene Complexes; 3.2.1 General Considerations; 3.2.2 Cyclopropanation; 3.2.2.1 Stoichiometric Cyclopropanations; 3.2.2.2 Catalytic Cyclopropanations with Diazoalkanes; 3.2.2.3 Catalytic Cyclopropanations with Other Carbene Precursors; 3.2.3 C-H Insertions; 3.2.3.1 C-H Insertions of Nucleophilic Carbene Complexes 3.2.3.2 C-H Insertions of Electrophilic Carbene Complexes |
| Record Nr. | UNINA-9910144281503321 |
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Dörwald Florencio Zaragoza
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| Weinheim, [Germany] : , : Wiley-VCH, , 1999 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
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Metal carbenes in organic synthesis / / Florencio Zaragoza Dörwald
| Metal carbenes in organic synthesis / / Florencio Zaragoza Dörwald |
| Autore | Dörwald Florencio Zaragoza |
| Pubbl/distr/stampa | Weinheim, [Germany] : , : Wiley-VCH, , 1999 |
| Descrizione fisica | 1 online resource (311 p.) |
| Disciplina |
547.050459
547.2 |
| Soggetto topico |
Carbenes (Methylene compounds)
Organic compounds - Synthesis |
| ISBN |
1-281-84252-4
9786611842529 3-527-61406-0 3-527-61407-9 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Metal Carbenes in Organic Synthesis; Table of Contents; Abbreviations; Experimental Procedures; 1 The Carbon-Metal Double Bond; 1 1 Reactivity of Carbene Complexes; 1.2 Fischer-Type and Schrock-Type Carbene Complexes: Theoretical Treatment; 1.3 Olefin Metathesis and Olefin Cyclopropanation; 1.4 Characteristic NMR Data; 2 Heteroatom-Substituted Carbene Complexes; 2.1 Generation of Heteroatom-Substituted Carbene Complexes; 2.1.1 From Acyl Complexes; 2.1.1.1 From Acyl Complexes Generated from Carbonyl Complexes; 2.1.1.2 From Acyl Complexes Generated from Metallates
2.1.1.3 From Acyl Complexes Generated by Other Methods2.1.2 From Isonitrile Complexes; 2.1.3 From a-Haloiminium Salts and Metallates; 2.1.4 From Carboxamides and Metallates; 2.1.5 From Vinylidene Complexes; 2.1.5.1 From Vinylidene Complexes Generated from Alkynes; 2.1.5.2 From Vinylidene Complexes Generated from Alkynyl Complexes; 2.1.6 From Carbenes and Carbenoids; 2.1.7 From Alkyl Complexes by a-Abstraction; 2.1.8 From Carbyne Complexes; 2.1.9 Other Methods; 2.2 Synthetic Applications of Heteroatom-Substituted Carbene Complexes; 2.2.1 General Considerations 2.2.2 Demetallation and Formation of Acyclic Products2.2.3 Photochemical Transformations; 2.2.4 Cyclopropanation; 2.2.5 Thermal Benzannulations; 2.2.5.1 The Dötz Benzannulation Reaction; 2.2.5.2 Other Thermal Benzannulations; 2.2.6 Formation of Five-Membered Rings; 2.2.6.1 Cyclization of (1,3-Butadien-1-yl)carbene Complexes; 2.2.6.2 Cyclization of Functionalized Carbene Complexes; 2.2.6.3 Rearrangement of Ammonium Ylides; 2.2.6.4 Other Methods; 2.2.7 Formation of Six-Membered. Non-Aromatic Carbocycles and Six-Membered Heterocycles; 2.2.8 Formation of Seven-Membered Rings 3 Non-Heteroatom-Substituted Carbene Complexes3.1 Generation of Non-Heteroatom-Substituted Carbene Complexes; 3.1.1 a-Abstraction of Electrophiles (Nucleophilic Abstraction); 3.1.2 a-Abstraction of Nucleophiles (Electrophilic Abstraction); 3.1.2.1 a-Abstraction of Hydride; 3.1.2.2 a-Abstraction of Oxygen-Bound Leaving Groups; 3.1.2.3 a-Abstraction of Thioethers; 3.1.2.4 a-Abstraction of Halides; 3.1.3 From Ylides; 3.1.3.1 From Diazoalkanes; 3.1.3.2 From Other Ylides; 3.1.4 From Carbyne Complexes; 3.1.4.1 Nucleophilic Additions to Carbyne Complexes 3.1.4.2 Electrophilic Additions to Carbyne Complexes3.1.5 From Alkynyl and Alkenyl Complexes; 3.1.6 From Alkyne and Cyclopropene Complexes; 3.1.7 By [2 + 2] Cycloreversion; 3.1.8 Other Methods; 3.2 Synthetic Applications of Non-Heteroatom-Substituted Carbene Complexes; 3.2.1 General Considerations; 3.2.2 Cyclopropanation; 3.2.2.1 Stoichiometric Cyclopropanations; 3.2.2.2 Catalytic Cyclopropanations with Diazoalkanes; 3.2.2.3 Catalytic Cyclopropanations with Other Carbene Precursors; 3.2.3 C-H Insertions; 3.2.3.1 C-H Insertions of Nucleophilic Carbene Complexes 3.2.3.2 C-H Insertions of Electrophilic Carbene Complexes |
| Record Nr. | UNISA-996201940903316 |
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Dörwald Florencio Zaragoza
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| Weinheim, [Germany] : , : Wiley-VCH, , 1999 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. di Salerno | ||
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Metal carbenes in organic synthesis / / Florencio Zaragoza Dörwald
| Metal carbenes in organic synthesis / / Florencio Zaragoza Dörwald |
| Autore | Dörwald Florencio Zaragoza |
| Pubbl/distr/stampa | Weinheim, [Germany] : , : Wiley-VCH, , 1999 |
| Descrizione fisica | 1 online resource (311 p.) |
| Disciplina |
547.050459
547.2 |
| Soggetto topico |
Carbenes (Methylene compounds)
Organic compounds - Synthesis |
| ISBN |
1-281-84252-4
9786611842529 3-527-61406-0 3-527-61407-9 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Metal Carbenes in Organic Synthesis; Table of Contents; Abbreviations; Experimental Procedures; 1 The Carbon-Metal Double Bond; 1 1 Reactivity of Carbene Complexes; 1.2 Fischer-Type and Schrock-Type Carbene Complexes: Theoretical Treatment; 1.3 Olefin Metathesis and Olefin Cyclopropanation; 1.4 Characteristic NMR Data; 2 Heteroatom-Substituted Carbene Complexes; 2.1 Generation of Heteroatom-Substituted Carbene Complexes; 2.1.1 From Acyl Complexes; 2.1.1.1 From Acyl Complexes Generated from Carbonyl Complexes; 2.1.1.2 From Acyl Complexes Generated from Metallates
2.1.1.3 From Acyl Complexes Generated by Other Methods2.1.2 From Isonitrile Complexes; 2.1.3 From a-Haloiminium Salts and Metallates; 2.1.4 From Carboxamides and Metallates; 2.1.5 From Vinylidene Complexes; 2.1.5.1 From Vinylidene Complexes Generated from Alkynes; 2.1.5.2 From Vinylidene Complexes Generated from Alkynyl Complexes; 2.1.6 From Carbenes and Carbenoids; 2.1.7 From Alkyl Complexes by a-Abstraction; 2.1.8 From Carbyne Complexes; 2.1.9 Other Methods; 2.2 Synthetic Applications of Heteroatom-Substituted Carbene Complexes; 2.2.1 General Considerations 2.2.2 Demetallation and Formation of Acyclic Products2.2.3 Photochemical Transformations; 2.2.4 Cyclopropanation; 2.2.5 Thermal Benzannulations; 2.2.5.1 The Dötz Benzannulation Reaction; 2.2.5.2 Other Thermal Benzannulations; 2.2.6 Formation of Five-Membered Rings; 2.2.6.1 Cyclization of (1,3-Butadien-1-yl)carbene Complexes; 2.2.6.2 Cyclization of Functionalized Carbene Complexes; 2.2.6.3 Rearrangement of Ammonium Ylides; 2.2.6.4 Other Methods; 2.2.7 Formation of Six-Membered. Non-Aromatic Carbocycles and Six-Membered Heterocycles; 2.2.8 Formation of Seven-Membered Rings 3 Non-Heteroatom-Substituted Carbene Complexes3.1 Generation of Non-Heteroatom-Substituted Carbene Complexes; 3.1.1 a-Abstraction of Electrophiles (Nucleophilic Abstraction); 3.1.2 a-Abstraction of Nucleophiles (Electrophilic Abstraction); 3.1.2.1 a-Abstraction of Hydride; 3.1.2.2 a-Abstraction of Oxygen-Bound Leaving Groups; 3.1.2.3 a-Abstraction of Thioethers; 3.1.2.4 a-Abstraction of Halides; 3.1.3 From Ylides; 3.1.3.1 From Diazoalkanes; 3.1.3.2 From Other Ylides; 3.1.4 From Carbyne Complexes; 3.1.4.1 Nucleophilic Additions to Carbyne Complexes 3.1.4.2 Electrophilic Additions to Carbyne Complexes3.1.5 From Alkynyl and Alkenyl Complexes; 3.1.6 From Alkyne and Cyclopropene Complexes; 3.1.7 By [2 + 2] Cycloreversion; 3.1.8 Other Methods; 3.2 Synthetic Applications of Non-Heteroatom-Substituted Carbene Complexes; 3.2.1 General Considerations; 3.2.2 Cyclopropanation; 3.2.2.1 Stoichiometric Cyclopropanations; 3.2.2.2 Catalytic Cyclopropanations with Diazoalkanes; 3.2.2.3 Catalytic Cyclopropanations with Other Carbene Precursors; 3.2.3 C-H Insertions; 3.2.3.1 C-H Insertions of Nucleophilic Carbene Complexes 3.2.3.2 C-H Insertions of Electrophilic Carbene Complexes |
| Record Nr. | UNINA-9910831161403321 |
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Dörwald Florencio Zaragoza
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| Weinheim, [Germany] : , : Wiley-VCH, , 1999 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
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N-heterocyclic carbenes : from laboratory curiosities to efficient synthetic tools / / edited by Silvia Diez-González, Imperial College London, UK
| N-heterocyclic carbenes : from laboratory curiosities to efficient synthetic tools / / edited by Silvia Diez-González, Imperial College London, UK |
| Autore | Díez-González Silvia |
| Edizione | [Second edition.] |
| Pubbl/distr/stampa | Cambridge : , : Royal Society of Chemistry, , [2017] |
| Descrizione fisica | 1 online resource (637 pages) : illustrations |
| Disciplina | 547.59 |
| Collana | RSC catalysis series |
| Soggetto topico |
Carbenes (Methylene compounds)
Heterocyclic compounds |
| ISBN | 1-78262-681-6 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNINA-9910156199103321 |
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Díez-González Silvia
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| Cambridge : , : Royal Society of Chemistry, , [2017] | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
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N-Heterocyclic carbenes : effective tools for organometallic synthesis / / edited by Steven P. Nolan
| N-Heterocyclic carbenes : effective tools for organometallic synthesis / / edited by Steven P. Nolan |
| Pubbl/distr/stampa | Weinheim an der Bergstrasse, Germany : , : Wiley-VCH, , 2014 |
| Descrizione fisica | 1 online resource (569 p.) |
| Disciplina | 547.412 |
| Soggetto topico |
Carbenes (Methylene compounds)
Heterocyclic chemistry Organometallic compounds - Synthesis |
| ISBN |
3-527-67124-2
3-527-67122-6 3-527-67125-0 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
N-Heterocyclic Carbenes: Effective Tools for Organometallic Synthesis; Contents; List of Contributors; Preface; 1 N-Heterocyclic Carbenes; 1.1 Introduction; 1.2 Structure and Properties of NHCs; 1.3 Abnormal Carbenes; 1.4 Why Are NHCs Stable?; 1.5 Bonding of NHCs to Metal Centers; 1.6 Quantifying the Properties of NHCs; 1.6.1 Steric Impact; 1.6.2 Electronic Properties; 1.7 N-Heterocyclic Carbenes in the Context of Other Stable Carbenes; 1.8 Synthesis of NHCs; 1.9 Salts and Adducts of NHCs; 1.10 Summary; References
2 Tuning and Quantifying Steric and Electronic Effects of N-Heterocyclic Carbenes2.1 Introduction; 2.2 Steric Effects in NHC ligands; 2.3 Electronic Effects in NHC Ligands; 2.4 Conclusions; References; 3 Chiral Monodendate N-Heterocyclic Carbene Ligands in Asymmetric Catalysis; 3.1 Introduction; 3.2 NHC-Ru; 3.2.1 Asymmetric Metathesis; 3.2.2 Asymmetric Hydrogenation; 3.2.3 Asymmetric Hydrosilylation; 3.3 NHC-Rh; 3.3.1 Asymmetric Catalysis Using Boronic Acids as Nucleophiles; 3.3.2 Asymmetric Hydrosilylation; 3.3.3 Asymmetric Hydroformylation; 3.4 NHC-Ir; 3.5 NHC-Ni; 3.6 NHC-Pd 3.6.1 Asymmetric Intramolecular α-Arylation ofAmides3.6.2 Asymmetric Diamination; 3.6.3 Other Asymmetric Catalysis Using NHC-Pd; 3.7 NHC-Cu; 3.7.1 Asymmetric Conjugate Addition; 3.7.2 Asymmetric Allylic Substitution; 3.7.3 Silyl Conjugate Addition; 3.7.4 Enantioselective β-Boration; 3.7.5 Asymmetric Hydrosilylation; 3.7.6 Asymmetric Addition to Imines; 3.8 NHC-Ag; 3.9 NHC-Au; 3.9.1 Enantioselective Cycloisomerizations; 3.9.2 Enantioselective Hydrogenation; 3.9.3 Enantioselective Cycloaddition; 3.10 Conclusion; References; 4 (N-Heterocyclic Carbene)-Palladium Complexes in Catalysis 4.1 Introduction4.2 Cross-Coupling Reactions; 4.2.1 Suzuki-Miyaura Coupling; 4.2.2 Buchwald-Hartwig Aminations; 4.2.3 Negishi Reactions; 4.2.4 Hiyama Coupling; 4.2.5 Kumada Coupling; 4.2.6 Sonogashira Coupling; 4.2.7 Heck Reaction; 4.3 Chelates and Pincer Ligands; 4.4 Asymmetric Catalysis; 4.5 Oxidation Reactions; 4.6 Telomerization, Oligomerization and Polymerization; 4.7 Anticancer NHC-Pd Complexes; References; 5 NHC Platinum(0) Complexes: Unique Catalysts for the Hydrosilylation of Alkenes and Alkynes; 5.1 Introduction; 5.2 Hydrosilylation of Alkenes: The Beginning 5.3 Initial Results with Phosphine Ligands5.4 NHC Platinum(0) Complexes: The Breakthrough; 5.4.1 Synthesis of NHC Platinum(0) Complexes and Kinetic Assays; 5.4.2 Functional Group Tolerance and Substrate Scope; 5.4.3 Mechanistic Studies; 5.4.3.1 Activation Period; 5.4.3.2 Catalyst Deactivation Pathways; 5.4.3.3 Semiquantitative Kinetic Studies; 5.4.3.4 Quantitative Kinetic Modeling; 5.4.3.5 Conclusions; 5.5 Hydrosilylation of Alkynes; 5.5.1 Catalyst Screening and the Impact of NHCs on Regioselectivity; 5.5.2 Influence of Silane on Regioselectivity 5.5.3 Second-Generation Catalyst for the Hydrosilylation of Alkynes |
| Record Nr. | UNINA-9910132165903321 |
| Weinheim an der Bergstrasse, Germany : , : Wiley-VCH, , 2014 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
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