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Actinide research quarterly / / Los Alamos National Laboratory [[electronic resource]]
Actinide research quarterly / / Los Alamos National Laboratory [[electronic resource]]
Pubbl/distr/stampa Los Alamos, NM, : Los Alamos National Laboratory
Descrizione fisica 1 online resource
Soggetto topico Actinide elements
Heavy elements
Soggetto genere / forma Periodicals.
Formato Materiale a stampa
Livello bibliografico Periodico
Lingua di pubblicazione eng
Record Nr. UNINA-9910142273103321
Los Alamos, NM, : Los Alamos National Laboratory
Materiale a stampa
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Actinide research quarterly of the nuclear materials technology division [[electronic resource]]
Actinide research quarterly of the nuclear materials technology division [[electronic resource]]
Pubbl/distr/stampa Los Alamos, N.M., : Los Alamos National Laboratory, 1994-
Descrizione fisica electronic text, volumes : HTML, digital, PDF file
Soggetto topico Heavy elements
Nuclear physics
Actinide elements
Formato Materiale a stampa
Livello bibliografico Periodico
Lingua di pubblicazione eng
Altri titoli varianti Actinide research quarterly
Record Nr. UNINA-9910695863803321
Los Alamos, N.M., : Los Alamos National Laboratory, 1994-
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Bias estimates used in lieu of validation of fission products and minor actinides in MCNP Keff calculations for PWR burnup credit casks / / prepared by D.E. Mueller [and three others]
Bias estimates used in lieu of validation of fission products and minor actinides in MCNP Keff calculations for PWR burnup credit casks / / prepared by D.E. Mueller [and three others]
Autore Mueller D. E.
Pubbl/distr/stampa Washington, DC : , : U.S. Nuclear Regulatory Commission, Office of Nuclear Material Safety and Safeguards, , September 2015
Descrizione fisica 1 online resource (73 unnumbered pages) : color illustrations
Soggetto topico Fission products - Handling
Monte Carlo method
Actinide elements
Fuel burnup (Nuclear engineering)
Spent reactor fuels - Storage
Spent reactor fuels - Transportation
Pressurized water reactors
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Record Nr. UNINA-9910698624303321
Mueller D. E.  
Washington, DC : , : U.S. Nuclear Regulatory Commission, Office of Nuclear Material Safety and Safeguards, , September 2015
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Computational methods in lanthanide and actinide chemistry / / edited by Michael Dolg ; contributors, Raymond Atta-Fynn [and forty others]
Computational methods in lanthanide and actinide chemistry / / edited by Michael Dolg ; contributors, Raymond Atta-Fynn [and forty others]
Pubbl/distr/stampa Chichester, England : , : Wiley, , 2015
Descrizione fisica 1 online resource (495 p.)
Disciplina 546.41
Soggetto topico Rare earth metals
Actinide elements
Chemistry, Inorganic
Soggetto genere / forma Electronic books.
ISBN 1-118-68828-7
1-118-68830-9
1-118-68829-5
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Title Page; Copyright Page; Contents; Contributors; Preface; Chapter 1 Relativistic Configuration Interaction Calculations for Lanthanide and Actinide Anions; 1.1 Introduction; 1.2 Bound Rare Earth Anion States; 1.3 Lanthanide and Actinide Anion Survey; 1.3.1 Prior Results and Motivation for the Survey; 1.3.2 Techniques for Basis Set Construction and Analysis; 1.3.3 Discussion of Results; 1.4 Resonance and Photodetachment Cross Section of Anions; 1.4.1 The Configuration Interaction in the Continuum Formalism; 1.4.2 Calculation of the Final State Wavefunctions; Acknowledgments; References
Chapter 2 Study of Actinides by Relativistic Coupled Cluster Methods2.1 Introduction; 2.2 Methodology; 2.2.1 The Relativistic Hamiltonian; 2.2.2 Fock-Space Coupled Cluster Approach; 2.2.3 The Intermediate Hamiltonian CC method; 2.3 Applications to Actinides; 2.3.1 Actinium and Its Homologues: Interplay of Relativity and Correlation; 2.3.2 Thorium and Eka-thorium: Different Level Structure; 2.3.3 Rn-like actinide ions; 2.3.4 Electronic Spectrum of Superheavy Elements Nobelium (Z=102) and Lawrencium (Z=103); 2.3.5 The Levels of U4+ and U5+: Dynamic Correlation and Breit Interaction
2.3.6 Relativistic Coupled Cluster Approach to Actinide Molecules2.4 Summary and Conclusion; References; Chapter 3 Relativistic All-Electron Approaches to the Study of f Element Chemistry; 3.1 Introduction; 3.2 Relativistic Hamiltonians; 3.2.1 General Aspects; 3.2.2 Four-Component Hamiltonians; 3.2.3 Two-Component Hamiltonians; 3.2.4 Numerical Example; 3.3 Choice of Basis Sets; 3.4 Electronic Structure Methods; 3.4.1 Coupled Cluster Approaches; 3.4.2 Multi-Reference Perturbation Theory; 3.4.3 (Time-Dependent) Density Functional Theory; 3.5 Conclusions and Outlook; Acknowledgments; References
Chapter 4 Low-Lying Excited States of Lanthanide Diatomics Studied by Four-Component Relativistic Configuration Interaction Methods4.1 Introduction; 4.2 Method of Calculation; 4.2.1 Quaternion Symmetry; 4.2.2 Basis Set and HFR/DC Method; 4.2.3 GOSCI and RASCI Methods; 4.3 Ground State; 4.3.1 CeO Ground State; 4.3.2 CeF Ground State; 4.3.3 Discussion of Bonding in CeO and CeF; 4.3.4 GdF Ground State; 4.3.5 Summary of the Chemical Bonds, of CeO, CeF, GdF; 4.4 Excited States; 4.4.1 CeO Excited States; 4.4.2 CeF Excited States; 4.4.3 GdF Excited States; 4.5 Conclusion; References
Chapter 5 The Complete-Active-Space Self-Consistent-Field Approach and Its Application to Molecular Complexes of the f-Elements5.1 Introduction; 5.1.1 Treatment of Relativistic Effects; 5.1.2 Basis Sets; 5.2 Identifying and Incorporating Electron Correlation; 5.2.1 The Hartree Product Wavefunction; 5.2.2 Slater Determinants and Fermi Correlation; 5.2.3 Coulomb Correlation; 5.3 Configuration Interaction and the Multiconfigurational Wavefunction; 5.3.1 The Configuration Interaction Approach; 5.3.2 CI and the Dissociation of H2; 5.3.3 Static Correlation and Crystal Field Splitting
5.3.4 Size Inconsistency and Coupled Cluster Theory
Record Nr. UNINA-9910132450103321
Chichester, England : , : Wiley, , 2015
Materiale a stampa
Lo trovi qui: Univ. Federico II
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Computational methods in lanthanide and actinide chemistry / / edited by Michael Dolg ; contributors, Raymond Atta-Fynn [and forty others]
Computational methods in lanthanide and actinide chemistry / / edited by Michael Dolg ; contributors, Raymond Atta-Fynn [and forty others]
Pubbl/distr/stampa Chichester, England : , : Wiley, , 2015
Descrizione fisica 1 online resource (495 p.)
Disciplina 546.41
Soggetto topico Rare earth metals
Actinide elements
Chemistry, Inorganic
ISBN 1-118-68828-7
1-118-68830-9
1-118-68829-5
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Title Page; Copyright Page; Contents; Contributors; Preface; Chapter 1 Relativistic Configuration Interaction Calculations for Lanthanide and Actinide Anions; 1.1 Introduction; 1.2 Bound Rare Earth Anion States; 1.3 Lanthanide and Actinide Anion Survey; 1.3.1 Prior Results and Motivation for the Survey; 1.3.2 Techniques for Basis Set Construction and Analysis; 1.3.3 Discussion of Results; 1.4 Resonance and Photodetachment Cross Section of Anions; 1.4.1 The Configuration Interaction in the Continuum Formalism; 1.4.2 Calculation of the Final State Wavefunctions; Acknowledgments; References
Chapter 2 Study of Actinides by Relativistic Coupled Cluster Methods2.1 Introduction; 2.2 Methodology; 2.2.1 The Relativistic Hamiltonian; 2.2.2 Fock-Space Coupled Cluster Approach; 2.2.3 The Intermediate Hamiltonian CC method; 2.3 Applications to Actinides; 2.3.1 Actinium and Its Homologues: Interplay of Relativity and Correlation; 2.3.2 Thorium and Eka-thorium: Different Level Structure; 2.3.3 Rn-like actinide ions; 2.3.4 Electronic Spectrum of Superheavy Elements Nobelium (Z=102) and Lawrencium (Z=103); 2.3.5 The Levels of U4+ and U5+: Dynamic Correlation and Breit Interaction
2.3.6 Relativistic Coupled Cluster Approach to Actinide Molecules2.4 Summary and Conclusion; References; Chapter 3 Relativistic All-Electron Approaches to the Study of f Element Chemistry; 3.1 Introduction; 3.2 Relativistic Hamiltonians; 3.2.1 General Aspects; 3.2.2 Four-Component Hamiltonians; 3.2.3 Two-Component Hamiltonians; 3.2.4 Numerical Example; 3.3 Choice of Basis Sets; 3.4 Electronic Structure Methods; 3.4.1 Coupled Cluster Approaches; 3.4.2 Multi-Reference Perturbation Theory; 3.4.3 (Time-Dependent) Density Functional Theory; 3.5 Conclusions and Outlook; Acknowledgments; References
Chapter 4 Low-Lying Excited States of Lanthanide Diatomics Studied by Four-Component Relativistic Configuration Interaction Methods4.1 Introduction; 4.2 Method of Calculation; 4.2.1 Quaternion Symmetry; 4.2.2 Basis Set and HFR/DC Method; 4.2.3 GOSCI and RASCI Methods; 4.3 Ground State; 4.3.1 CeO Ground State; 4.3.2 CeF Ground State; 4.3.3 Discussion of Bonding in CeO and CeF; 4.3.4 GdF Ground State; 4.3.5 Summary of the Chemical Bonds, of CeO, CeF, GdF; 4.4 Excited States; 4.4.1 CeO Excited States; 4.4.2 CeF Excited States; 4.4.3 GdF Excited States; 4.5 Conclusion; References
Chapter 5 The Complete-Active-Space Self-Consistent-Field Approach and Its Application to Molecular Complexes of the f-Elements5.1 Introduction; 5.1.1 Treatment of Relativistic Effects; 5.1.2 Basis Sets; 5.2 Identifying and Incorporating Electron Correlation; 5.2.1 The Hartree Product Wavefunction; 5.2.2 Slater Determinants and Fermi Correlation; 5.2.3 Coulomb Correlation; 5.3 Configuration Interaction and the Multiconfigurational Wavefunction; 5.3.1 The Configuration Interaction Approach; 5.3.2 CI and the Dissociation of H2; 5.3.3 Static Correlation and Crystal Field Splitting
5.3.4 Size Inconsistency and Coupled Cluster Theory
Record Nr. UNINA-9910678279103321
Chichester, England : , : Wiley, , 2015
Materiale a stampa
Lo trovi qui: Univ. Federico II
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Crystalline materials for actinide immobilisation [[electronic resource] /] / Boris E. Burakov, Michael I. Ojovan, William (Bill) E. Lee
Crystalline materials for actinide immobilisation [[electronic resource] /] / Boris E. Burakov, Michael I. Ojovan, William (Bill) E. Lee
Autore Burakov Boris E
Pubbl/distr/stampa London, : Imperial College Press
Descrizione fisica 1 online resource (216 p.)
Disciplina 620.1404228
Altri autori (Persone) OjovanMichael I
LeeW. E
Collana Materials for engineering
Soggetto topico Actinide elements
Alpha-bearing wastes
Ceramic materials
Soggetto genere / forma Electronic books.
ISBN 1-283-14335-6
9786613143358
1-84816-419-X
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Preface; Abbreviations; Acknowledgements; Contents; Chapter 1 Introduction to the Actinides; 1.1. Actinide Series; 1.1.1. History; 1.1.2. Basic physical and chemical properties; 1.1.3. History of using actinide-containing materials; 1.1.4. High toxicity and long-lived radioactivity; 1.1.5. Need for actinide immobilisation; 1.2. Natural Actinides and Minerals; 1.2.1. Uraninite, pitchblende and thorianite; 1.2.2. Coffinite and thorite; 1.2.3. Brannerite; 1.2.4. Miscellaneous; 1.3. Artificial Actinides; 1.3.1. Actinide production in the nuclear fuel cycle; 1.3.2. Weapons-grade plutonium
1.3.3. Minor actinides1.3.3.1. Neptunium-237; 1.3.3.2. Americium; 1.3.3.3. Curium; 1.3.3.4. Berkelium and Californium; 1.4. Actinide Host-Phases; 1.4.1. Natural accessory minerals; 1.4.2. Zircon and hafnon; 1.4.3. Monazite; 1.4.4. Zirconolite; 1.4.5. Baddeleyite (monoclinic zirconia); 1.4.6. Tazheranite (cubic zirconia); 1.4.7. Xenotime; 1.4.8. Apatite; 1.4.9. Pyrochlore; 1.4.10. Perovskite; 1.4.11. Garnet; 1.4.12. Murataite; 1.4.13. Kosnarite; 1.4.14. Natural gels; References; Chapter 2 Current and Potential Actinide Applications; 2.1. Advanced Nuclear Fuel Cycle; 2.1.1. MOX nuclear fuel
2.1.2. Ceramic nuclear fuel2.1.3. Advanced nuclear reactors; 2.2. Inert Pu Ceramic Fuel; 2.3. Sealed Radioactive Sources; 2.4. Self-glowing Materials; 2.5. Transmutation Targets; 2.6. Summary; References; Chapter 3 Waste Actinide Immobilisation; 3.1. Ceramic Nuclear Wasteforms: Historical Overview; 3.1.1. Early work; 3.1.2. Emergence of Pu wasteforms; 3.1.3. Emergence of durability studies; 3.2. Titanate-based Ceramics; 3.2.1. Synroc; 3.2.2. Ti-pyrochlore; 3.3. Phosphate-based Ceramics; 3.3.1. Monazite; 3.3.2. Th-phosphate/diphosphate (TPD); 3.3.3. Kosnarite and NZP; 3.3.4. Apatite
3.4. Ceramics Based on Zirconium and Hafnium Minerals3.4.1. Zircon/zirconia and hafnon/hafnia; 3.4.2. Cubic zirconia (tazheranite) and hafnia; 3.5. Garnet/Perovskite; 3.6. Summary; References; Chapter 4 Synthesis Methods; 4.1. Precursor Fabrication; 4.1.1. Sol-gel; 4.1.2. Co-precipitation; 4.1.3. Oxide powder mix; 4.2. Hot Uniaxial Pressing (HUP); 4.3. Hot Isostatic Pressing (HIP); 4.4. Pressing-sintering; 4.5. Melting-crystallisation; 4.6. Self-sustaining (Self-propagating) High Temperature Reactions; 4.7. Single Crystal Growth; 4.8. Summary; References
Chapter 5 Examination of Highly Radioactive Samples5.1. XRD Analysis; 5.2. SEM and EPMA; 5.3. Cathodoluminescence; 5.4. Optical Microscopy; 5.5. Mechanical Durability; 5.6. Leach and Alteration Tests; References; Chapter 6 Radiation Damage; 6.1. Ion-irradiation; 6.2. Doping with 238Pu and 244Cm; 6.2.1. Zircon/zirconia and hafnon/hafnia ceramics; 6.2.2. Zircon single crystal; 6.2.3. Cubic zirconia ceramic; 6.2.4. Monazite ceramic; 6.2.5. Monazite single crystal; 6.2.6. Ti-pyrochlore ceramic; 6.2.7. Zr-pyrochlore ceramic; 6.2.8. Zirconolite ceramic; 6.2.9. Garnet ceramic
6.2.10. Silicate-apatite ceramic and chlorine-apatite powder
Record Nr. UNINA-9910463921603321
Burakov Boris E  
London, : Imperial College Press
Materiale a stampa
Lo trovi qui: Univ. Federico II
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Crystalline materials for actinide immobilisation [[electronic resource] /] / Boris E. Burakov, Michael I. Ojovan, William (Bill) E. Lee
Crystalline materials for actinide immobilisation [[electronic resource] /] / Boris E. Burakov, Michael I. Ojovan, William (Bill) E. Lee
Autore Burakov Boris E
Pubbl/distr/stampa London, : Imperial College Press
Descrizione fisica 1 online resource (216 p.)
Disciplina 620.1404228
Altri autori (Persone) OjovanMichael I
LeeW. E
Collana Materials for engineering
Soggetto topico Actinide elements
Alpha-bearing wastes
Ceramic materials
ISBN 1-283-14335-6
9786613143358
1-84816-419-X
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Preface; Abbreviations; Acknowledgements; Contents; Chapter 1 Introduction to the Actinides; 1.1. Actinide Series; 1.1.1. History; 1.1.2. Basic physical and chemical properties; 1.1.3. History of using actinide-containing materials; 1.1.4. High toxicity and long-lived radioactivity; 1.1.5. Need for actinide immobilisation; 1.2. Natural Actinides and Minerals; 1.2.1. Uraninite, pitchblende and thorianite; 1.2.2. Coffinite and thorite; 1.2.3. Brannerite; 1.2.4. Miscellaneous; 1.3. Artificial Actinides; 1.3.1. Actinide production in the nuclear fuel cycle; 1.3.2. Weapons-grade plutonium
1.3.3. Minor actinides1.3.3.1. Neptunium-237; 1.3.3.2. Americium; 1.3.3.3. Curium; 1.3.3.4. Berkelium and Californium; 1.4. Actinide Host-Phases; 1.4.1. Natural accessory minerals; 1.4.2. Zircon and hafnon; 1.4.3. Monazite; 1.4.4. Zirconolite; 1.4.5. Baddeleyite (monoclinic zirconia); 1.4.6. Tazheranite (cubic zirconia); 1.4.7. Xenotime; 1.4.8. Apatite; 1.4.9. Pyrochlore; 1.4.10. Perovskite; 1.4.11. Garnet; 1.4.12. Murataite; 1.4.13. Kosnarite; 1.4.14. Natural gels; References; Chapter 2 Current and Potential Actinide Applications; 2.1. Advanced Nuclear Fuel Cycle; 2.1.1. MOX nuclear fuel
2.1.2. Ceramic nuclear fuel2.1.3. Advanced nuclear reactors; 2.2. Inert Pu Ceramic Fuel; 2.3. Sealed Radioactive Sources; 2.4. Self-glowing Materials; 2.5. Transmutation Targets; 2.6. Summary; References; Chapter 3 Waste Actinide Immobilisation; 3.1. Ceramic Nuclear Wasteforms: Historical Overview; 3.1.1. Early work; 3.1.2. Emergence of Pu wasteforms; 3.1.3. Emergence of durability studies; 3.2. Titanate-based Ceramics; 3.2.1. Synroc; 3.2.2. Ti-pyrochlore; 3.3. Phosphate-based Ceramics; 3.3.1. Monazite; 3.3.2. Th-phosphate/diphosphate (TPD); 3.3.3. Kosnarite and NZP; 3.3.4. Apatite
3.4. Ceramics Based on Zirconium and Hafnium Minerals3.4.1. Zircon/zirconia and hafnon/hafnia; 3.4.2. Cubic zirconia (tazheranite) and hafnia; 3.5. Garnet/Perovskite; 3.6. Summary; References; Chapter 4 Synthesis Methods; 4.1. Precursor Fabrication; 4.1.1. Sol-gel; 4.1.2. Co-precipitation; 4.1.3. Oxide powder mix; 4.2. Hot Uniaxial Pressing (HUP); 4.3. Hot Isostatic Pressing (HIP); 4.4. Pressing-sintering; 4.5. Melting-crystallisation; 4.6. Self-sustaining (Self-propagating) High Temperature Reactions; 4.7. Single Crystal Growth; 4.8. Summary; References
Chapter 5 Examination of Highly Radioactive Samples5.1. XRD Analysis; 5.2. SEM and EPMA; 5.3. Cathodoluminescence; 5.4. Optical Microscopy; 5.5. Mechanical Durability; 5.6. Leach and Alteration Tests; References; Chapter 6 Radiation Damage; 6.1. Ion-irradiation; 6.2. Doping with 238Pu and 244Cm; 6.2.1. Zircon/zirconia and hafnon/hafnia ceramics; 6.2.2. Zircon single crystal; 6.2.3. Cubic zirconia ceramic; 6.2.4. Monazite ceramic; 6.2.5. Monazite single crystal; 6.2.6. Ti-pyrochlore ceramic; 6.2.7. Zr-pyrochlore ceramic; 6.2.8. Zirconolite ceramic; 6.2.9. Garnet ceramic
6.2.10. Silicate-apatite ceramic and chlorine-apatite powder
Record Nr. UNINA-9910788565903321
Burakov Boris E  
London, : Imperial College Press
Materiale a stampa
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Experimental and theoretical approaches to actinide chemistry / / edited by John K. Gibson and Wibe A. de Jong
Experimental and theoretical approaches to actinide chemistry / / edited by John K. Gibson and Wibe A. de Jong
Pubbl/distr/stampa Hoboken, New Jersey : , : Wiley, , 2018
Descrizione fisica 1 online resource (521 pages) : illustrations (some color)
Disciplina 546/.421
Soggetto topico Actinium compounds
Actinide elements
Heavy elements
ISBN 1-119-11554-X
1-119-11553-1
1-119-11555-8
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Record Nr. UNINA-9910270889703321
Hoboken, New Jersey : , : Wiley, , 2018
Materiale a stampa
Lo trovi qui: Univ. Federico II
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Lanthanides and actinides in molecular magnetism / / edited by Richard A. Layfield and Muralee Murugesu
Lanthanides and actinides in molecular magnetism / / edited by Richard A. Layfield and Muralee Murugesu
Pubbl/distr/stampa Weinheim : , : Wiley-VCH, , [2015]
Descrizione fisica 1 online resource (367 p.)
Disciplina 551.5
Soggetto topico Rare earth metals
Actinide elements
ISBN 3-527-67349-0
3-527-67347-4
3-527-67350-4
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Lanthanides and Actinides in Molecular Magnetism; Contents; Preface; List of Contributors; Chapter 1 Electronic Structure and Magnetic Properties of Lanthanide Molecular Complexes; 1.1 Introduction; 1.2 Free Ion Electronic Structure; 1.2.1 Free Ion Magnetism; 1.3 Electronic Structure of Lanthanide Ions in a Ligand Field; 1.3.1 Stevens' Formalism; 1.3.2 Wybourne's Formalism; 1.3.3 Standardization; 1.3.4 Calculation of Crystal Field Parameters; 1.4 Magnetic Properties of Isolated Lanthanide Ions; 1.4.1 Effect of a Magnetic Field; 1.4.2 EPR Spectroscopy of Lanthanide Complexes
1.5 Exchange Coupling in Systems Containing Orbitally Degenerate LanthanidesAcknowledgements; References; Chapter 2 Mononuclear Lanthanide Complexes: Use of the Crystal Field Theory to Design Single-Ion Magnets and Spin Qubits; 2.1 Introduction; 2.2 Modelling the Magnetic Properties of Lanthanide Single-Ion Magnets: The Use of the Crystal Field Model; 2.2.1 Theoretical Background; 2.2.2 How to Determine the Crystal-Field Parameters: 1. The Ishikawa Approach; 2.2.3 How to Determine the Crystal-Field Parameters: 2. The Point Charge Electrostatic Model
2.2.4 How to Determine the Crystal-Field Parameters: 3. The Effective Point Charge Model2.3 Magneto-Structural Correlations for Some Typical Symmetries; 2.4 Impact of Lanthanide Complexes in Quantum Computing; 2.4.1 Quantum Computing Paradigms and Design Criteria; 2.4.2 Combining Physical Qubit Implementations with Lanthanide Complexes; 2.4.3 Molecular Spin Qubits; 2.5 Conclusions; Acknowledgements; References; Chapter 3 Polynuclear Lanthanide Single Molecule Magnets; 3.1 Introduction; 3.2 Synthetic Strategies; 3.2.1 Dy3 Triangles and Their Derivatives; 3.2.1.1 Seminal Dy3 Triangle
3.2.1.2 Other Triangular Dy3 Systems3.2.1.3 The Coupling of Dy3 Triangles; 3.2.2 Linear Polynuclear Lanthanide Complexes Showing Robust SMM Behaviour; 3.2.2.1 Linear Dy3 SMMs; 3.2.2.2 Linear Dy4 SMMs; 3.2.3 Planar Dy4 SMMs; 3.2.4 Dyn SMMs Having Multiple μn-O (n>4) Bridges; 3.2.4.1 The Dy4 Grids Fixed by μ4-O Atom; 3.2.4.2 The Dy4 Tetrahedron Fixed by μ4-O Atom; 3.2.4.3 The Dy5 Pyramid Fixed by μ5-O Atom; 3.2.5 Hydrazone-Based Lanthanide SMMs; 3.2.5.1 The Assembly of Dy6 Triangular Prism with Dy2 Units; 3.2.5.2 A Dy3 Molecular Cluster Pair (Dy6)
3.2.6 The Organometallic Synthesis - A New Approach3.3 Conclusion; References; Chapter 4 Lanthanides in Extended Molecular Networks; 4.1 Introduction; 4.2 Extended Networks Based on Gd3+; 4.2.1 Metal-Organic Frameworks; 4.2.1.1 Magneto-Caloric Effect; 4.2.1.2 Slow Magnetic Relaxation and Phonon Bottleneck Effects; 4.2.2 Magnetic Chains; 4.2.2.1 Magnetic Interactions Involving Gd3+ Ions; 4.2.2.2 Gadolinium-Radical Chains; 4.3 Extended Networks Based on Anisotropic Ions; 4.3.1 SCM in a Nutshell; 4.3.2 An Overview of Monodimensional Lanthanide Chains Based on Anisotropic Ions
4.3.2.1 Chains Based on 4f Ions
Record Nr. UNINA-9910132284103321
Weinheim : , : Wiley-VCH, , [2015]
Materiale a stampa
Lo trovi qui: Univ. Federico II
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Rare Earth and actinide complexes / / edited by Stephen Mansell, Steve Liddle
Rare Earth and actinide complexes / / edited by Stephen Mansell, Steve Liddle
Pubbl/distr/stampa Basel, Switzerland : , : MDPI - Multidisciplinary Digital Publishing Institute, , [2017]
Descrizione fisica 1 online resource (264 pages)
Disciplina 546.42
Soggetto topico Actinide elements
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto About the Guest Editors V -- Editorial to "Rare Earth and Actinide Complexes" -- Reprinted from: Inorganics 2016, 4(4), 31; doi:10.3390/inorganics4040031 -- http://www.mdpi.com/2304-6740/4/4/31. VII -- Catalytic Organic Transformations Mediated by Actinide Complexes -- Reprinted from: Inorganics 2015, 3(4), 392-428; doi:10.3390/inorganics3040392 -- http://www.mdpi.com/2304-6740/3/4/392. 1 -- Molecular Pnictogen Activation by Rare Earth and Actinide Complexes -- Reprinted from: Inorganics 2015, 3(4), 597-635; doi:10.3390/inorganics3040597 -- http://www.mdpi.com/2304-6740/3/4/597. 34 -- New Lanthanide Alkynylamidinates and Diiminophosphinates -- Reprinted from: Inorganics 2015, 3(4), 429-447; doi:10.3390/inorganics3040429 -- http://www.mdpi.com/2304-6740/3/4/429 66 -- Dinuclear Lanthanide (III) Coordination Polymers in a Domino Reaction -- Reprinted from: Inorganics 2015, 3(4), 448-466; doi:10.3390/inorganics3040448 -- http://www.mdpi.com/2304-6740/3/4/448 82 -- Luminescent Lanthanide Metal Organic Frameworks for cis-Selective Isoprene Polymerization Catalysis -- Reprinted from: Inorganics 2015, 3(4), 467-481; doi:10.3390/inorganics3040467 -- http://www.mdpi.com/2304-6740/3/4/467 98 -- Assessing Covalency in Cerium and Uranium Hexachlorides: A Correlated Wavefunction and Density Functional Theory Study -- Reprinted from: Inorganics 2015, 3(4), 482-499; doi: 10.3390/inorganics3040482 -- http://www.mdpi.com/2304-6740/3/4/482. 110 -- Holmium(III) Supermesityl-Imide Complexes Bearing Methylaluminato/Gallato Ligands -- Reprinted from: Inorganics 2015, 3(4), 500-510; doi:10.3390/inorganics3040500 -- http://www.mdpi.com/2304-6740/3/4/500 125 -- Gadolinium(III)-DOTA Complex Functionalized with BODIPY as a Potential Bimodal Contrast Agent for MRI and Optical Imaging -- Reprinted from: Inorganics 2015, 3(4), 516-533; doi:10.3390/inorganics3040516 -- http://www.mdpi.com/2304-6740/3/4/516 133 -- Synthesis and Reactivity of a Cerium(III) Scorpionate Complex Containing a Redox Non-Innocent 2,2'-bipyridine Ligand -- Reprinted from: Inorganics 2015, 3(4), 534-553; doi:10.3390/inorganics3040534 -- http://www.mdpi.com/2304-6740/3/4/534. 148 -- Magnetic and Photo-Physical Properties of Lanthanide Dinuclear Complexes Involving the 4,5-Bis(2-Pyridyl-N-Oxidemethylthio)-4',5'-Dicarboxylic Acid-Tetrathiafulvalene-, Dimethyl Ester Ligand -- Reprinted from: Inorganics 2015, 3(4), 554-572; doi:10.3390/inorganics3040554 -- http://www.mdpi.com/2304-6740/3/4/554. 165 -- On the Dehydrocoupling of Alkenylacetylenes Mediated by Various Samarocene Complexes: A Charming Story of Metal Cooperativity Revealing a Novel Dual Metal o-Bond Metathesis Type of Mechanism (DMI-BM) -- Reprinted from: Inorganics 2015, 3(4), 573-588; doi:10.3390/inorganics3040573 -- http://www.mdpi.com/2304-6740/3/4/573 181 -- Synthesis and Characterization of Cerium(IV) Metallocenes -- Reprinted from: Inorganics 2015, 3(4), 589-596; doi:10.3390/inorganics3040589 -- http://www.mdpi.com/2304-6740/3/4/589 194 -- Expanding the Chemistry of Actinide Metallocene Bromides. Synthesis, Properties and Molecular Structures of the Tetravalent and Trivalent Uranium Bromide Complexes: (CsMe
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Basel, Switzerland : , : MDPI - Multidisciplinary Digital Publishing Institute, , [2017]
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