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Carbon-centered free radicals and radical cations [[electronic resource] ] : structure, reactivity, and dynamics / / edited by Malcolm D. Forbes
| Carbon-centered free radicals and radical cations [[electronic resource] ] : structure, reactivity, and dynamics / / edited by Malcolm D. Forbes |
| Pubbl/distr/stampa | Hoboken, NJ, : Wiely, c2010 |
| Descrizione fisica | 1 online resource (395 p.) |
| Disciplina | 547.1224 |
| Altri autori (Persone) | ForbesMalcolm D. E. <1960-> |
| Collana | Wiley Series of Reactive Intermediates in Chemistry and Biology |
| Soggetto topico |
Free radicals (Chemistry)
Carbon, Activated Reactivity (Chemistry) Cations |
| ISBN |
1-282-49088-5
9786612490880 0-470-58411-4 0-470-58410-6 |
| Formato | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
CARBON-CENTERED FREE RADICALS AND RADICAL CATIONS; CONTENTS; About the Volume Editor; Preface to Series; Introduction; Contributors; 1. A Brief History of Carbon Radicals; 2. Intermolecular Radical Additions to Alkynes: Cascade-Type Radical Cyclizations; 2.1 Introduction; 2.2 Cascade Reactions Involving Radicals of Second Row Elements; 2.2.1 Cascade Reactions Initiated by Addition of C-Centered Radicals to Alkynes; 2.2.2 Cascade Reactions Initiated by Addition of O-Centered Radicals to Alkynes (Self-Terminating Radical Oxygenations)
2.2.3 Cascade Reactions Initiated by Addition of N-Centered Radicals to Alkynes 2.3 Cascade Reactions Initiated by Addition of Higher Main Group (VI)-Centered Radicals to Alkynes; 2.3.1 Cascade Reactions Initiated by Addition of Sn-Centered Radicals to Alkynes; 2.4 Cascade Reactions Initiated by Addition of Higher Main Group (VI)-Centered Radicals to Alkynes; 2.4.1 Cascade Reactions Initiated by Addition of S-Centered Radicals to Alkynes; 2.4.2 Cascade Reactions Initiated by Addition of Se-Centered Radicals to Alkynes 2.5 Cascade Reactions Initiated by Addition of Higher Main Group (V)-Centered Radicals to Alkynes 2.5.1 Cascade Reactions Initiated by Addition of P-Centered Radicals to Alkynes; 3. Radical Cation Fragmentation Reactions in Organic Synthesis; 3.1 Introduction; 3.1.1 Oxidative Carbon-Carbon Bond Cleavage; 3.1.2 Thermodynamic and Kinetic Considerations; 3.1.3 Reactive Intermediate Lifetime; 3.2 Electron Transfer-Initiated Cyclization Reactions; 3.2.1 Rate Enhancement and Mechanistic Studies; 3.2.2 Development of a Catalytic Aerobic Protocol; 3.2.3 Oxidative Cascade Reactions 3.3 Oxidative Acyliminium Ion Formation 3.4 Carbon-Carbon Bond Formation; 3.4.1 Chemoselectivity and Reactivity; 3.4.2 Reaction Scope; 3.5 Summary and Outlook; 4. Selectivity in Radical Cation Cycloadditions; 4.1 Introduction; 4.2 Mechanism and the Origin of the Rate Acceleration; 4.3 Selectivity in Radical Cation Cycloadditions; 4.4 Chemoselectivity; 4.4.1 Effect of Dienophile Substituents on Chemoselectivity; 4.4.2 Effect of Sensitizers and Solvents on Chemoselectivity; 4.4.3 Effect of Concentrations on Chemoselectivity; 4.4.4 Effect of Electron-Rich Dienophiles on Chemoselectivity 4.5 Regioselectivity 4.6 Periselectivity; 4.6.1 Effects of Solvent and Concentration on Periselectivity; 4.6.2 Effect of Diene/Dienophile Redox Potentials on Periselectivity; 4.6.3 Substituent and Steric Effects on Periselectivity; 4.6.4 Quantifying Periselectivity Through Ion Pair Association; 4.7 Endo/Exo Selectivity; 4.7.1 Effects of Secondary Orbital Interaction and Solvents on Endo/Exo Selectivity; 4.7.2 Effect of Sensitizer on Endo/Exo Selectivity; 4.7.3 Ion Pairs and Endo/Exo Selectivities; 4.8 Conclusions; 5. The Stability of Carbon-Centered Radicals; 5.1 Introduction 5.1.1 The Consequences of Different Stability Definitions: How Stable Are Ethyl and Fluoromethyl Radicals? |
| Record Nr. | UNISA-996212676503316 |
| Hoboken, NJ, : Wiely, c2010 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. di Salerno | ||
| ||
Carbon-centered free radicals and radical cations [[electronic resource] ] : structure, reactivity, and dynamics / / edited by Malcolm D. Forbes
| Carbon-centered free radicals and radical cations [[electronic resource] ] : structure, reactivity, and dynamics / / edited by Malcolm D. Forbes |
| Pubbl/distr/stampa | Hoboken, NJ, : Wiely, c2010 |
| Descrizione fisica | 1 online resource (395 p.) |
| Disciplina | 547.1224 |
| Altri autori (Persone) | ForbesMalcolm D. E. <1960-> |
| Collana | Wiley Series of Reactive Intermediates in Chemistry and Biology |
| Soggetto topico |
Free radicals (Chemistry)
Carbon, Activated Reactivity (Chemistry) Cations |
| ISBN |
1-282-49088-5
9786612490880 0-470-58411-4 0-470-58410-6 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
CARBON-CENTERED FREE RADICALS AND RADICAL CATIONS; CONTENTS; About the Volume Editor; Preface to Series; Introduction; Contributors; 1. A Brief History of Carbon Radicals; 2. Intermolecular Radical Additions to Alkynes: Cascade-Type Radical Cyclizations; 2.1 Introduction; 2.2 Cascade Reactions Involving Radicals of Second Row Elements; 2.2.1 Cascade Reactions Initiated by Addition of C-Centered Radicals to Alkynes; 2.2.2 Cascade Reactions Initiated by Addition of O-Centered Radicals to Alkynes (Self-Terminating Radical Oxygenations)
2.2.3 Cascade Reactions Initiated by Addition of N-Centered Radicals to Alkynes 2.3 Cascade Reactions Initiated by Addition of Higher Main Group (VI)-Centered Radicals to Alkynes; 2.3.1 Cascade Reactions Initiated by Addition of Sn-Centered Radicals to Alkynes; 2.4 Cascade Reactions Initiated by Addition of Higher Main Group (VI)-Centered Radicals to Alkynes; 2.4.1 Cascade Reactions Initiated by Addition of S-Centered Radicals to Alkynes; 2.4.2 Cascade Reactions Initiated by Addition of Se-Centered Radicals to Alkynes 2.5 Cascade Reactions Initiated by Addition of Higher Main Group (V)-Centered Radicals to Alkynes 2.5.1 Cascade Reactions Initiated by Addition of P-Centered Radicals to Alkynes; 3. Radical Cation Fragmentation Reactions in Organic Synthesis; 3.1 Introduction; 3.1.1 Oxidative Carbon-Carbon Bond Cleavage; 3.1.2 Thermodynamic and Kinetic Considerations; 3.1.3 Reactive Intermediate Lifetime; 3.2 Electron Transfer-Initiated Cyclization Reactions; 3.2.1 Rate Enhancement and Mechanistic Studies; 3.2.2 Development of a Catalytic Aerobic Protocol; 3.2.3 Oxidative Cascade Reactions 3.3 Oxidative Acyliminium Ion Formation 3.4 Carbon-Carbon Bond Formation; 3.4.1 Chemoselectivity and Reactivity; 3.4.2 Reaction Scope; 3.5 Summary and Outlook; 4. Selectivity in Radical Cation Cycloadditions; 4.1 Introduction; 4.2 Mechanism and the Origin of the Rate Acceleration; 4.3 Selectivity in Radical Cation Cycloadditions; 4.4 Chemoselectivity; 4.4.1 Effect of Dienophile Substituents on Chemoselectivity; 4.4.2 Effect of Sensitizers and Solvents on Chemoselectivity; 4.4.3 Effect of Concentrations on Chemoselectivity; 4.4.4 Effect of Electron-Rich Dienophiles on Chemoselectivity 4.5 Regioselectivity 4.6 Periselectivity; 4.6.1 Effects of Solvent and Concentration on Periselectivity; 4.6.2 Effect of Diene/Dienophile Redox Potentials on Periselectivity; 4.6.3 Substituent and Steric Effects on Periselectivity; 4.6.4 Quantifying Periselectivity Through Ion Pair Association; 4.7 Endo/Exo Selectivity; 4.7.1 Effects of Secondary Orbital Interaction and Solvents on Endo/Exo Selectivity; 4.7.2 Effect of Sensitizer on Endo/Exo Selectivity; 4.7.3 Ion Pairs and Endo/Exo Selectivities; 4.8 Conclusions; 5. The Stability of Carbon-Centered Radicals; 5.1 Introduction 5.1.1 The Consequences of Different Stability Definitions: How Stable Are Ethyl and Fluoromethyl Radicals? |
| Record Nr. | UNINA-9910139517803321 |
| Hoboken, NJ, : Wiely, c2010 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Carbon-centered free radicals and radical cations : structure, reactivity, and dynamics / / edited by Malcolm D. Forbes
| Carbon-centered free radicals and radical cations : structure, reactivity, and dynamics / / edited by Malcolm D. Forbes |
| Edizione | [1st ed.] |
| Pubbl/distr/stampa | Hoboken, NJ, : Wiely, c2010 |
| Descrizione fisica | 1 online resource (395 p.) |
| Disciplina | 547.1224 |
| Altri autori (Persone) | ForbesMalcolm D. E. <1960-> |
| Collana | Wiley Series of Reactive Intermediates in Chemistry and Biology |
| Soggetto topico |
Free radicals (Chemistry)
Carbon, Activated Reactivity (Chemistry) Cations |
| ISBN |
9786612490880
9781282490888 1282490885 9780470584118 0470584114 9780470584101 0470584106 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
CARBON-CENTERED FREE RADICALS AND RADICAL CATIONS; CONTENTS; About the Volume Editor; Preface to Series; Introduction; Contributors; 1. A Brief History of Carbon Radicals; 2. Intermolecular Radical Additions to Alkynes: Cascade-Type Radical Cyclizations; 2.1 Introduction; 2.2 Cascade Reactions Involving Radicals of Second Row Elements; 2.2.1 Cascade Reactions Initiated by Addition of C-Centered Radicals to Alkynes; 2.2.2 Cascade Reactions Initiated by Addition of O-Centered Radicals to Alkynes (Self-Terminating Radical Oxygenations)
2.2.3 Cascade Reactions Initiated by Addition of N-Centered Radicals to Alkynes 2.3 Cascade Reactions Initiated by Addition of Higher Main Group (VI)-Centered Radicals to Alkynes; 2.3.1 Cascade Reactions Initiated by Addition of Sn-Centered Radicals to Alkynes; 2.4 Cascade Reactions Initiated by Addition of Higher Main Group (VI)-Centered Radicals to Alkynes; 2.4.1 Cascade Reactions Initiated by Addition of S-Centered Radicals to Alkynes; 2.4.2 Cascade Reactions Initiated by Addition of Se-Centered Radicals to Alkynes 2.5 Cascade Reactions Initiated by Addition of Higher Main Group (V)-Centered Radicals to Alkynes 2.5.1 Cascade Reactions Initiated by Addition of P-Centered Radicals to Alkynes; 3. Radical Cation Fragmentation Reactions in Organic Synthesis; 3.1 Introduction; 3.1.1 Oxidative Carbon-Carbon Bond Cleavage; 3.1.2 Thermodynamic and Kinetic Considerations; 3.1.3 Reactive Intermediate Lifetime; 3.2 Electron Transfer-Initiated Cyclization Reactions; 3.2.1 Rate Enhancement and Mechanistic Studies; 3.2.2 Development of a Catalytic Aerobic Protocol; 3.2.3 Oxidative Cascade Reactions 3.3 Oxidative Acyliminium Ion Formation 3.4 Carbon-Carbon Bond Formation; 3.4.1 Chemoselectivity and Reactivity; 3.4.2 Reaction Scope; 3.5 Summary and Outlook; 4. Selectivity in Radical Cation Cycloadditions; 4.1 Introduction; 4.2 Mechanism and the Origin of the Rate Acceleration; 4.3 Selectivity in Radical Cation Cycloadditions; 4.4 Chemoselectivity; 4.4.1 Effect of Dienophile Substituents on Chemoselectivity; 4.4.2 Effect of Sensitizers and Solvents on Chemoselectivity; 4.4.3 Effect of Concentrations on Chemoselectivity; 4.4.4 Effect of Electron-Rich Dienophiles on Chemoselectivity 4.5 Regioselectivity 4.6 Periselectivity; 4.6.1 Effects of Solvent and Concentration on Periselectivity; 4.6.2 Effect of Diene/Dienophile Redox Potentials on Periselectivity; 4.6.3 Substituent and Steric Effects on Periselectivity; 4.6.4 Quantifying Periselectivity Through Ion Pair Association; 4.7 Endo/Exo Selectivity; 4.7.1 Effects of Secondary Orbital Interaction and Solvents on Endo/Exo Selectivity; 4.7.2 Effect of Sensitizer on Endo/Exo Selectivity; 4.7.3 Ion Pairs and Endo/Exo Selectivities; 4.8 Conclusions; 5. The Stability of Carbon-Centered Radicals; 5.1 Introduction 5.1.1 The Consequences of Different Stability Definitions: How Stable Are Ethyl and Fluoromethyl Radicals? |
| Record Nr. | UNINA-9910828353703321 |
| Hoboken, NJ, : Wiely, c2010 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Natural gas processing from midstream to downstream / / edited by Nimir O. Elbashir [and three others]
| Natural gas processing from midstream to downstream / / edited by Nimir O. Elbashir [and three others] |
| Edizione | [1st edition] |
| Pubbl/distr/stampa | Hoboken, New Jersey : , : Wiely, , 2019 |
| Descrizione fisica | 1 online resource (587 pages) : illustrations |
| Disciplina | 665.7 |
| Soggetto topico |
Natural gas
Chemical processes |
| Soggetto genere / forma | Electronic books. |
| ISBN |
1-119-26963-6
1-119-26962-8 1-119-26961-X |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNINA-9910467331403321 |
| Hoboken, New Jersey : , : Wiely, , 2019 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Natural gas processing from midstream to downstream / / edited by Nimir O. Elbashir [and three others]
| Natural gas processing from midstream to downstream / / edited by Nimir O. Elbashir [and three others] |
| Edizione | [1st edition] |
| Pubbl/distr/stampa | Hoboken, New Jersey : , : Wiely, , 2019 |
| Descrizione fisica | 1 online resource (587 pages) : illustrations |
| Disciplina | 665.7 |
| Soggetto topico |
Natural gas
Chemical processes |
| ISBN |
1-119-26963-6
1-119-26962-8 1-119-26961-X |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNINA-9910536689603321 |
| Hoboken, New Jersey : , : Wiely, , 2019 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Natural gas processing from midstream to downstream / / edited by Nimir O. Elbashir [and three others]
| Natural gas processing from midstream to downstream / / edited by Nimir O. Elbashir [and three others] |
| Edizione | [1st edition] |
| Pubbl/distr/stampa | Hoboken, New Jersey : , : Wiely, , 2019 |
| Descrizione fisica | 1 online resource (587 pages) : illustrations |
| Disciplina | 665.7 |
| Soggetto topico |
Natural gas
Chemical processes |
| ISBN |
1-119-26963-6
1-119-26962-8 1-119-26961-X |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNINA-9910828861003321 |
| Hoboken, New Jersey : , : Wiely, , 2019 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Wiley 2017 interpretation and application of IFRS standards / / Erwin Bakker [and nine others]
| Wiley 2017 interpretation and application of IFRS standards / / Erwin Bakker [and nine others] |
| Autore | Bakker Erwin |
| Pubbl/distr/stampa | Hoboken, New Jersey : , : Wiely, , [2017] |
| Descrizione fisica | 1 online resource (1,021 pages) : illustrations |
| Collana | Wiley regulatory reporting series |
| Soggetto topico | Accounting - Standards |
| Soggetto genere / forma | Electronic books. |
| ISBN | 1-119-34025-X |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNINA-9910271028903321 |
Bakker Erwin
|
||
| Hoboken, New Jersey : , : Wiely, , [2017] | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Wiley 2017 interpretation and application of IFRS standards / / Erwin Bakker [and nine others]
| Wiley 2017 interpretation and application of IFRS standards / / Erwin Bakker [and nine others] |
| Autore | Bakker Erwin |
| Pubbl/distr/stampa | Hoboken, New Jersey : , : Wiely, , [2017] |
| Descrizione fisica | 1 online resource (1,021 pages) : illustrations |
| Collana | Wiley regulatory reporting series |
| Soggetto topico | Accounting - Standards |
| ISBN | 1-119-34025-X |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNINA-9910831195503321 |
|
Bakker Erwin
|
||
| Hoboken, New Jersey : , : Wiely, , [2017] | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
