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Hypercarbon chemistry [[electronic resource] /] / George A. Olah ... [et al.]
| Hypercarbon chemistry [[electronic resource] /] / George A. Olah ... [et al.] |
| Autore | Olah George A (George Andrew), <1927-> |
| Edizione | [2nd ed.] |
| Pubbl/distr/stampa | Hoboken, N.J., : J. WIley & Sons, c2011 |
| Descrizione fisica | 1 online resource (476 p.) |
| Disciplina | 547.01 |
| Altri autori (Persone) | OlahGeorge A <1927-2017.> (George Andrew) |
| Soggetto topico |
Carbonium ions
Organometallic chemistry |
| ISBN |
1-118-01645-9
1-118-01646-7 1-283-17562-2 9786613175625 1-118-01644-0 |
| Formato | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
HYPERCARBON CHEMISTRY, Second Edition; CONTENTS; FOREWORD TO THE FIRST EDITION; PREFACE TO THE SECOND EDITION; PREFACE TO THE FIRST EDITION; 1: INTRODUCTION: GENERAL ASPECTS; 1.1. AIMS AND OBJECTIVES; 1.2. SOME DEFINITIONS; 1.3. STRUCTURES OF SOME TYPICAL HYPERCARBON SYSTEMS; 1.4. THE THREE-CENTER BOND CONCEPT: TYPES OF THREE-CENTER BONDS; 1.5. THE BONDING IN MORE HIGHLY DELOCALIZED SYSTEMS; 1.6. REACTIONS INVOLVING HYPERCARBON INTERMEDIATES; REFERENCES; 2: CARBON-BRIDGED (ASSOCIATED) METAL ALKYLS; 2.1. INTRODUCTION; 2.2. BRIDGED ORGANOALUMINUM COMPOUNDS
2.3. BERYLLIUM AND MAGNESIUM COMPOUNDS2.4. ORGANOLITHIUM COMPOUNDS; 2.5. ORGANOCOPPER, SILVER, AND GOLD COMPOUNDS; 2.6. SCANDIUM, YTTRIUM, AND LANTHANIDE COMPOUNDS; 2.7. TITANIUM, ZIRCONIUM, AND HAFNIUM COMPOUNDS; 2.8. MANGANESE COMPOUNDS; 2.9. OTHER METAL COMPOUNDS WITH BRIDGING ALKYL GROUPS; 2.10. AGOSTIC SYSTEMS CONTAINING CARBON-HYDROGEN-METAL 3c-2e BONDS; 2.11. CONCLUSIONS; REFERENCES; 3: CARBORANES AND METALLACARBORANES; 3.1. INTRODUCTION; 3.2. CARBORANE STRUCTURES AND SKELETAL ELECTRON NUMBERS; 3.2.1. Closo Carboranes; 3.2.2. Nido and Arachno Carboranes 3.2.3. Carbon Sites in Carboranes Skeletal Connectivities k; 3.2.4. Skeletal Bond Orders in Boranes and Carboranes; 3.3. LOCALIZED BOND SCHEMES FOR CLOSO BORANES AND CARBORANES; 3.3.1. Lipscomb's Styx Rules and Williams' Stx Rules; 3.3.2. Bond Orders and Skeletal Connectivities; 3.3.3. Bond Networks and Skeletal Connectivities; 3.3.4. Calculated Charge Distributions and Edge Bond Orders; 3.4. MO TREATMENTS OF CLOSO BORANES AND CARBORANES; 3.5. THE BONDING IN NIDO AND ARACHNO CARBORANES; 3.5.1. Localized Bond Schemes; 3.5.2. MO Treatments of Nido and Arachno Boranes and Carboranes 4: MIXED METAL-CARBON CLUSTERS AND METAL CARBIDES4.1. INTRODUCTION; 4.2. COMPLEXES OF CnHn RING SYSTEMS WITH A METAL ATOM: NIDO-SHAPED MCn CLUSTERS; 4.3. METAL COMPLEXES OF ACYCLIC UNSATURATED LIGANDS, CnHn+2; 4.4. COMPLEXES OF UNSATURATED ORGANIC LIGANDS WITH TWO OR MORE METAL ATOMS: MIXED METAL-CARBON CLUSTERS; 4.5. METAL CLUSTERS INCORPORATING CORE HYPERCARBON ATOMS; 4.6. BULK METAL CARBIDES; 4.7. METALLATED CARBOCATIONS; 4.8. CONCLUSIONS; REFERENCES; 5: HYPERCOORDINATE CARBOCATIONS AND THEIR BORANE ANALOGS; 5.1. GENERAL CONCEPT OF CARBOCATIONS: CARBENIUM VERSUS CARBONIUM IONS 5.1.1. Trivalent-Tricoordinate (Classical) Carbenium Ions |
| Record Nr. | UNINA-9910139633703321 |
Olah George A (George Andrew), <1927->
|
||
| Hoboken, N.J., : J. WIley & Sons, c2011 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Hypercarbon chemistry / / George A. Olah ... [et al.]
| Hypercarbon chemistry / / George A. Olah ... [et al.] |
| Autore | Olah George A (George Andrew), <1927-> |
| Edizione | [2nd ed.] |
| Pubbl/distr/stampa | Hoboken, N.J., : J. WIley & Sons, c2011 |
| Descrizione fisica | 1 online resource (476 p.) |
| Disciplina | 547.01 |
| Soggetto topico |
Carbonium ions
Organometallic chemistry |
| ISBN |
9786613175625
9781118016459 1118016459 9781118016466 1118016467 9781283175623 1283175622 9781118016442 1118016440 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
HYPERCARBON CHEMISTRY, Second Edition; CONTENTS; FOREWORD TO THE FIRST EDITION; PREFACE TO THE SECOND EDITION; PREFACE TO THE FIRST EDITION; 1: INTRODUCTION: GENERAL ASPECTS; 1.1. AIMS AND OBJECTIVES; 1.2. SOME DEFINITIONS; 1.3. STRUCTURES OF SOME TYPICAL HYPERCARBON SYSTEMS; 1.4. THE THREE-CENTER BOND CONCEPT: TYPES OF THREE-CENTER BONDS; 1.5. THE BONDING IN MORE HIGHLY DELOCALIZED SYSTEMS; 1.6. REACTIONS INVOLVING HYPERCARBON INTERMEDIATES; REFERENCES; 2: CARBON-BRIDGED (ASSOCIATED) METAL ALKYLS; 2.1. INTRODUCTION; 2.2. BRIDGED ORGANOALUMINUM COMPOUNDS
2.3. BERYLLIUM AND MAGNESIUM COMPOUNDS2.4. ORGANOLITHIUM COMPOUNDS; 2.5. ORGANOCOPPER, SILVER, AND GOLD COMPOUNDS; 2.6. SCANDIUM, YTTRIUM, AND LANTHANIDE COMPOUNDS; 2.7. TITANIUM, ZIRCONIUM, AND HAFNIUM COMPOUNDS; 2.8. MANGANESE COMPOUNDS; 2.9. OTHER METAL COMPOUNDS WITH BRIDGING ALKYL GROUPS; 2.10. AGOSTIC SYSTEMS CONTAINING CARBON-HYDROGEN-METAL 3c-2e BONDS; 2.11. CONCLUSIONS; REFERENCES; 3: CARBORANES AND METALLACARBORANES; 3.1. INTRODUCTION; 3.2. CARBORANE STRUCTURES AND SKELETAL ELECTRON NUMBERS; 3.2.1. Closo Carboranes; 3.2.2. Nido and Arachno Carboranes 3.2.3. Carbon Sites in Carboranes Skeletal Connectivities k; 3.2.4. Skeletal Bond Orders in Boranes and Carboranes; 3.3. LOCALIZED BOND SCHEMES FOR CLOSO BORANES AND CARBORANES; 3.3.1. Lipscomb's Styx Rules and Williams' Stx Rules; 3.3.2. Bond Orders and Skeletal Connectivities; 3.3.3. Bond Networks and Skeletal Connectivities; 3.3.4. Calculated Charge Distributions and Edge Bond Orders; 3.4. MO TREATMENTS OF CLOSO BORANES AND CARBORANES; 3.5. THE BONDING IN NIDO AND ARACHNO CARBORANES; 3.5.1. Localized Bond Schemes; 3.5.2. MO Treatments of Nido and Arachno Boranes and Carboranes 4: MIXED METAL-CARBON CLUSTERS AND METAL CARBIDES4.1. INTRODUCTION; 4.2. COMPLEXES OF CnHn RING SYSTEMS WITH A METAL ATOM: NIDO-SHAPED MCn CLUSTERS; 4.3. METAL COMPLEXES OF ACYCLIC UNSATURATED LIGANDS, CnHn+2; 4.4. COMPLEXES OF UNSATURATED ORGANIC LIGANDS WITH TWO OR MORE METAL ATOMS: MIXED METAL-CARBON CLUSTERS; 4.5. METAL CLUSTERS INCORPORATING CORE HYPERCARBON ATOMS; 4.6. BULK METAL CARBIDES; 4.7. METALLATED CARBOCATIONS; 4.8. CONCLUSIONS; REFERENCES; 5: HYPERCOORDINATE CARBOCATIONS AND THEIR BORANE ANALOGS; 5.1. GENERAL CONCEPT OF CARBOCATIONS: CARBENIUM VERSUS CARBONIUM IONS 5.1.1. Trivalent-Tricoordinate (Classical) Carbenium Ions |
| Record Nr. | UNINA-9910808862703321 |
|
Olah George A (George Andrew), <1927->
|
||
| Hoboken, N.J., : J. WIley & Sons, c2011 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
