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Cinchona alkaloids in synthesis and catalysis [[electronic resource] ] : ligands, immobilization and organocatalysis / / edited by Choong Eui Song
| Cinchona alkaloids in synthesis and catalysis [[electronic resource] ] : ligands, immobilization and organocatalysis / / edited by Choong Eui Song |
| Pubbl/distr/stampa | Weinheim, : Wiley-VCH, c2009 |
| Descrizione fisica | 1 online resource (547 p.) |
| Disciplina |
547.215
547.7 |
| Altri autori (Persone) | SongChoong Eui |
| Soggetto topico |
Cinchona alkaloids
Chirality Organic compounds - Synthesis Catalysis |
| Soggetto genere / forma | Electronic books. |
| ISBN |
1-282-30251-5
9786612302510 3-527-62817-7 3-527-62818-5 |
| Classificazione |
VK 5500
VK 8620 |
| Formato | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Cinchona Alkaloids in Synthesis and Catalysis: Ligands, Immobilization and Organocatalysis; Contents; Preface; Biography; List of Contributors; 1 An Overview of Cinchona Alkaloids in Chemistry; 1.1 Brief History; 1.2 Active Sites in Cinchona Alkaloids and Their Derivatives; 1.3 Structural Information on Cinchona Alkaloids; 1.4 How This Book Is Organized; References; Part One: Cinchona Alkaloid Derivatives as Chirality Inducers in Metal-Catalyzed Reactions; 2 Cinchona Alkaloids as Chirality Transmitters in Metal-Catalyzed Asymmetric Reductions; 2.1 Introduction
2.2 Homogeneous Systems for Ketone Reductions2.3 Heterogeneous Pt and Pd Catalysts Modified with Cinchona Alkaloids; 2.3.1 Background; 2.3.2 Catalysts; 2.3.3 Modifiers and Solvents; 2.3.4 Substrate Scope for Pt Catalysts; 2.3.4.1 α-Keto Acid Derivatives; 2.3.4.2 α,γ-Diketo Esters; 2.3.4.3 Fluorinated Ketones; 2.3.4.4 α-Keto Acetals; 2.3.4.5 α-Keto Ethers; 2.3.4.6 Miscellaneous Ketones; 2.3.5 Substrate Scope for Pd Catalysts; 2.4 Industrial Applications; 2.5 Conclusions; References; 3 Cinchona Alkaloids as Chiral Ligands in Asymmetric Oxidations; 3.1 Introduction 3.2 Asymmetric Dihydroxylation of Alkenes3.2.1 Early Reactions; 3.2.2 Bisalkaloid Ligands; 3.2.3 Mechanism; 3.2.4 Variations; 3.2.5 Substrates and Selectivity; 3.2.5.1 Simple Alkenes; 3.2.5.2 Functionalized Alkenes; 3.2.5.3 Polyenes; 3.2.5.3.1 Nonconjugate Olefins; 3.2.5.3.2 Conjugated Polyenes; 3.2.5.4 Double Asymmetric Induction; 3.2.5.5 Resolutions; 3.2.6 Some Reactions of 1,2-Diols; 3.2.6.1 Cyclic Sulfates and Sulfites; 3.3 Aminohydroxylation; 3.4 Sulfur Oxidations; 3.5 Summary; References 4 Cinchona Alkaloids and their Derivatives as Chirality Inducers in Metal-Promoted Enantioselective Carbon-Carbon and Carbon-Heteroatom Bond Forming Reactions4.1 Introduction; 4.2 Nucleophilic Addition to Carbonyl or Imine Compounds; 4.2.1 Organozinc Addition; 4.2.1.1 Dialkylzinc Addition to Aldehydes; 4.2.1.2 Dialkylzinc Addition to Imines; 4.2.1.3 Addition of Alkynylzincs to Carbonyls; 4.2.2 Asymmetric Reformatsky Reaction; 4.2.3 Indium-Mediated Addition; 4.2.4 Asymmetric Cyanation; 4.2.4.1 Cyanohydrin Synthesis; 4.2.4.2 Strecker Synthesis 4.2.5 Reactions of Chiral Ammonium Ketene Enolates as Nucleophiles with Different Electrophiles4.2.5.1 Lewis Acid Assisted Nucleophilic Addition of Ketenes (or Sulfenes) to Aldehydes: β-Lactone and β-Sultone Synthesis; 4.2.5.2 Lewis Acid Assisted Nucleophilic Addition of Ketenes to Imines: β-Lactam Synthesis; 4.2.5.3 Applications of Chiral Ketene Enolates to Formal [4 + 2] type Cyclization; 4.2.6 Aza-Henry Reaction; 4.2.7 Enantioselective Hydrophosphonylation; 4.3 Miscellaneous Reactions; 4.3.1 Claisen Rearrangements; 4.3.2 Pd-Catalyzed Asymmetric Allylic Substitutions 4.3.3 Pauson-Khand Reaction |
| Record Nr. | UNINA-9910139907903321 |
| Weinheim, : Wiley-VCH, c2009 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Cinchona alkaloids in synthesis and catalysis [[electronic resource] ] : ligands, immobilization and organocatalysis / / edited by Choong Eui Song
| Cinchona alkaloids in synthesis and catalysis [[electronic resource] ] : ligands, immobilization and organocatalysis / / edited by Choong Eui Song |
| Pubbl/distr/stampa | Weinheim, : Wiley-VCH, c2009 |
| Descrizione fisica | 1 online resource (547 p.) |
| Disciplina |
547.215
547.7 |
| Altri autori (Persone) | SongChoong Eui |
| Soggetto topico |
Cinchona alkaloids
Chirality Organic compounds - Synthesis Catalysis |
| ISBN |
1-282-30251-5
9786612302510 3-527-62817-7 3-527-62818-5 |
| Classificazione |
VK 5500
VK 8620 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Cinchona Alkaloids in Synthesis and Catalysis: Ligands, Immobilization and Organocatalysis; Contents; Preface; Biography; List of Contributors; 1 An Overview of Cinchona Alkaloids in Chemistry; 1.1 Brief History; 1.2 Active Sites in Cinchona Alkaloids and Their Derivatives; 1.3 Structural Information on Cinchona Alkaloids; 1.4 How This Book Is Organized; References; Part One: Cinchona Alkaloid Derivatives as Chirality Inducers in Metal-Catalyzed Reactions; 2 Cinchona Alkaloids as Chirality Transmitters in Metal-Catalyzed Asymmetric Reductions; 2.1 Introduction
2.2 Homogeneous Systems for Ketone Reductions2.3 Heterogeneous Pt and Pd Catalysts Modified with Cinchona Alkaloids; 2.3.1 Background; 2.3.2 Catalysts; 2.3.3 Modifiers and Solvents; 2.3.4 Substrate Scope for Pt Catalysts; 2.3.4.1 α-Keto Acid Derivatives; 2.3.4.2 α,γ-Diketo Esters; 2.3.4.3 Fluorinated Ketones; 2.3.4.4 α-Keto Acetals; 2.3.4.5 α-Keto Ethers; 2.3.4.6 Miscellaneous Ketones; 2.3.5 Substrate Scope for Pd Catalysts; 2.4 Industrial Applications; 2.5 Conclusions; References; 3 Cinchona Alkaloids as Chiral Ligands in Asymmetric Oxidations; 3.1 Introduction 3.2 Asymmetric Dihydroxylation of Alkenes3.2.1 Early Reactions; 3.2.2 Bisalkaloid Ligands; 3.2.3 Mechanism; 3.2.4 Variations; 3.2.5 Substrates and Selectivity; 3.2.5.1 Simple Alkenes; 3.2.5.2 Functionalized Alkenes; 3.2.5.3 Polyenes; 3.2.5.3.1 Nonconjugate Olefins; 3.2.5.3.2 Conjugated Polyenes; 3.2.5.4 Double Asymmetric Induction; 3.2.5.5 Resolutions; 3.2.6 Some Reactions of 1,2-Diols; 3.2.6.1 Cyclic Sulfates and Sulfites; 3.3 Aminohydroxylation; 3.4 Sulfur Oxidations; 3.5 Summary; References 4 Cinchona Alkaloids and their Derivatives as Chirality Inducers in Metal-Promoted Enantioselective Carbon-Carbon and Carbon-Heteroatom Bond Forming Reactions4.1 Introduction; 4.2 Nucleophilic Addition to Carbonyl or Imine Compounds; 4.2.1 Organozinc Addition; 4.2.1.1 Dialkylzinc Addition to Aldehydes; 4.2.1.2 Dialkylzinc Addition to Imines; 4.2.1.3 Addition of Alkynylzincs to Carbonyls; 4.2.2 Asymmetric Reformatsky Reaction; 4.2.3 Indium-Mediated Addition; 4.2.4 Asymmetric Cyanation; 4.2.4.1 Cyanohydrin Synthesis; 4.2.4.2 Strecker Synthesis 4.2.5 Reactions of Chiral Ammonium Ketene Enolates as Nucleophiles with Different Electrophiles4.2.5.1 Lewis Acid Assisted Nucleophilic Addition of Ketenes (or Sulfenes) to Aldehydes: β-Lactone and β-Sultone Synthesis; 4.2.5.2 Lewis Acid Assisted Nucleophilic Addition of Ketenes to Imines: β-Lactam Synthesis; 4.2.5.3 Applications of Chiral Ketene Enolates to Formal [4 + 2] type Cyclization; 4.2.6 Aza-Henry Reaction; 4.2.7 Enantioselective Hydrophosphonylation; 4.3 Miscellaneous Reactions; 4.3.1 Claisen Rearrangements; 4.3.2 Pd-Catalyzed Asymmetric Allylic Substitutions 4.3.3 Pauson-Khand Reaction |
| Record Nr. | UNINA-9910831097003321 |
| Weinheim, : Wiley-VCH, c2009 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Cinchona alkaloids in synthesis and catalysis : ligands, immobilization and organocatalysis / / edited by Choong Eui Song
| Cinchona alkaloids in synthesis and catalysis : ligands, immobilization and organocatalysis / / edited by Choong Eui Song |
| Pubbl/distr/stampa | Weinheim, : Wiley-VCH, c2009 |
| Descrizione fisica | 1 online resource (547 p.) |
| Disciplina |
547.215
547.7 |
| Altri autori (Persone) | SongChoong Eui |
| Soggetto topico |
Cinchona alkaloids
Chirality Organic compounds - Synthesis Catalysis |
| ISBN |
9786612302510
9781282302518 1282302515 9783527628179 3527628177 9783527628186 3527628185 |
| Classificazione |
VK 5500
VK 8620 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Cinchona Alkaloids in Synthesis and Catalysis: Ligands, Immobilization and Organocatalysis; Contents; Preface; Biography; List of Contributors; 1 An Overview of Cinchona Alkaloids in Chemistry; 1.1 Brief History; 1.2 Active Sites in Cinchona Alkaloids and Their Derivatives; 1.3 Structural Information on Cinchona Alkaloids; 1.4 How This Book Is Organized; References; Part One: Cinchona Alkaloid Derivatives as Chirality Inducers in Metal-Catalyzed Reactions; 2 Cinchona Alkaloids as Chirality Transmitters in Metal-Catalyzed Asymmetric Reductions; 2.1 Introduction
2.2 Homogeneous Systems for Ketone Reductions2.3 Heterogeneous Pt and Pd Catalysts Modified with Cinchona Alkaloids; 2.3.1 Background; 2.3.2 Catalysts; 2.3.3 Modifiers and Solvents; 2.3.4 Substrate Scope for Pt Catalysts; 2.3.4.1 α-Keto Acid Derivatives; 2.3.4.2 α,γ-Diketo Esters; 2.3.4.3 Fluorinated Ketones; 2.3.4.4 α-Keto Acetals; 2.3.4.5 α-Keto Ethers; 2.3.4.6 Miscellaneous Ketones; 2.3.5 Substrate Scope for Pd Catalysts; 2.4 Industrial Applications; 2.5 Conclusions; References; 3 Cinchona Alkaloids as Chiral Ligands in Asymmetric Oxidations; 3.1 Introduction 3.2 Asymmetric Dihydroxylation of Alkenes3.2.1 Early Reactions; 3.2.2 Bisalkaloid Ligands; 3.2.3 Mechanism; 3.2.4 Variations; 3.2.5 Substrates and Selectivity; 3.2.5.1 Simple Alkenes; 3.2.5.2 Functionalized Alkenes; 3.2.5.3 Polyenes; 3.2.5.3.1 Nonconjugate Olefins; 3.2.5.3.2 Conjugated Polyenes; 3.2.5.4 Double Asymmetric Induction; 3.2.5.5 Resolutions; 3.2.6 Some Reactions of 1,2-Diols; 3.2.6.1 Cyclic Sulfates and Sulfites; 3.3 Aminohydroxylation; 3.4 Sulfur Oxidations; 3.5 Summary; References 4 Cinchona Alkaloids and their Derivatives as Chirality Inducers in Metal-Promoted Enantioselective Carbon-Carbon and Carbon-Heteroatom Bond Forming Reactions4.1 Introduction; 4.2 Nucleophilic Addition to Carbonyl or Imine Compounds; 4.2.1 Organozinc Addition; 4.2.1.1 Dialkylzinc Addition to Aldehydes; 4.2.1.2 Dialkylzinc Addition to Imines; 4.2.1.3 Addition of Alkynylzincs to Carbonyls; 4.2.2 Asymmetric Reformatsky Reaction; 4.2.3 Indium-Mediated Addition; 4.2.4 Asymmetric Cyanation; 4.2.4.1 Cyanohydrin Synthesis; 4.2.4.2 Strecker Synthesis 4.2.5 Reactions of Chiral Ammonium Ketene Enolates as Nucleophiles with Different Electrophiles4.2.5.1 Lewis Acid Assisted Nucleophilic Addition of Ketenes (or Sulfenes) to Aldehydes: β-Lactone and β-Sultone Synthesis; 4.2.5.2 Lewis Acid Assisted Nucleophilic Addition of Ketenes to Imines: β-Lactam Synthesis; 4.2.5.3 Applications of Chiral Ketene Enolates to Formal [4 + 2] type Cyclization; 4.2.6 Aza-Henry Reaction; 4.2.7 Enantioselective Hydrophosphonylation; 4.3 Miscellaneous Reactions; 4.3.1 Claisen Rearrangements; 4.3.2 Pd-Catalyzed Asymmetric Allylic Substitutions 4.3.3 Pauson-Khand Reaction |
| Record Nr. | UNINA-9911020371203321 |
| Weinheim, : Wiley-VCH, c2009 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||