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Chemical bonding at surfaces and interfaces [[electronic resource] /] / edited by Anders Nilsson, Lars G.M. Pettersson and Jens K. Nıorskov
Chemical bonding at surfaces and interfaces [[electronic resource] /] / edited by Anders Nilsson, Lars G.M. Pettersson and Jens K. Nıorskov
Pubbl/distr/stampa Amsterdam ; ; Oxford, : Elsevier, 2008
Descrizione fisica 1 online resource (533 p.)
Disciplina 541.224
Altri autori (Persone) NilssonAnders
PetterssonLars
NıorskovJ. K (Jens K.)
Soggetto topico Chemical bonds
Surface chemistry
ISBN 1-281-03451-7
9786611034511
0-08-055191-2
Classificazione VE 7000
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Front Cover; Chemical Bonding at Surfaces and Interfaces; Copyright Page; Table of Contents; Preface; Chapter 1 Surface Structure; 1. Why surface structure?; 2. Methods of surface adsorbate structure determination; 2.1. General comments; 2.2. Electron scattering; 2.3. X-ray scattering; 2.4. Ion scattering; 2.5. Spectroscopic methods and scanning probe microscopy; 3. Adsorbate-induced surface reconstruction; 4. Molecular adsorbates - local sites, orientations and intramolecular bondlengths; 4.1. General issues and the case of CO on metals; 4.2. Simple hydrocarbons on metals
4.3. Carboxylates on metals4.4. Other substrates: molecules on Si; 5. Chemisorption bondlengths; 5.1. Metal surfaces; 5.2. Oxide surfaces; 6. Conclusions; Chapter 2 Adsorbate Electronic Structure and Bonding on Metal Surfaces; 1. Introduction; 2. Probing the electronic structure; 3. Adsorbate electronic structure and chemical bonding; 4. Adsorbate systems; 5. Radical atomic adsorption; 5.1. The electronic structure of N on Cu(100); 5.2. Chemical bonding of atomic adsorbates; 6. Diatomic molecules; 6.1. N2 adsorbed on Ni(100); 6.2. CO adsorbed on Ni(100)
6.3. CO adsorbed on Cu(100) and other metals6.4. CO adsorbed in different sites; 6.5. Coadsorption of CO and K on Ni(100); 7. Unsaturated hydrocarbons; 7.1. Ethylene (C2H4) adsorbed on Ni(110) and Cu(110); 7.2. Benzene on Ni and Cu surfaces; 7.3. Bond energetics and rehybridization from spin-uncoupling; 8. Saturated hydrocarbons; 8.1. n-Octane adsorbed on Cu(110); 8.2. Difference between octane on Ni and Cu surfaces; 9. Lone pair interactions; 9.1. Water adsorption on Pt and Cu surfaces; 9.2. Adsorption of ammonia and the amino group in glycine on Cu(110); 10. Summary
Chapter 3 The Dynamics of Making and Breaking Bonds at Surfaces1. Introduction; 2. Theoretical background; 2.1. Adiabatic dynamics (Born-Oppenheimer approximation); 2.2. Generic PES topologies; 2.3. Dynamics vs. kinetics; 2.3.1. Direct dissociation; 2.3.2. Precursor-mediated dissociation; 2.4. Detailed balance; 2.5. Lattice coupling; 2.5.1. Energy transfer in adsorption/scattering; 2.5.2. Lattice coupling in direct molecular dissociation; 2.6. Non-adiabatic dynamics; 2.6.1. Hot electrons from chemistry; 2.6.2. Chemistry from hot electrons; 3. Experimental background
3.1. Experimental techniques3.2. Typical measurements; 3.2.1. Rate measurements; 3.2.2. Adsorption-trapping and sticking; 3.2.3. Desorption; 3.2.4. Scattering; 3.2.5. Initial state preparation; 3.2.6. Photochemistry/femtochemistry; 3.2.7. Single molecule chemistry (STM); 4. Processes; 4.1. Atomic adsorption/desorption/scattering; 4.1.1. Ar/Pt(111); 4.1.2. H/Cu(111); 4.2. Molecular adsorption/desorption/scattering; 4.2.1. NO/Ag(111); 4.2.2. NO/Pt(111); 4.3. Direct dissociation/associative desorption; 4.3.1. Activated dissociation; 4.3.2. Weakly activated dissociation
4.3.3. Non-activated dissociation
Record Nr. UNINA-9910784592603321
Amsterdam ; ; Oxford, : Elsevier, 2008
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Chemical bonding at surfaces and interfaces / / edited by Anders Nilsson, Lars G.M. Pettersson and Jens K. Norskov
Chemical bonding at surfaces and interfaces / / edited by Anders Nilsson, Lars G.M. Pettersson and Jens K. Norskov
Edizione [1st ed.]
Pubbl/distr/stampa Amsterdam ; ; Oxford, : Elsevier, 2008
Descrizione fisica 1 online resource (533 p.)
Disciplina 541.224
Altri autori (Persone) NilssonAnders
PetterssonLars
NørskovJens K
Soggetto topico Chemical bonds
Surface chemistry
ISBN 1-281-03451-7
9786611034511
0-08-055191-2
Classificazione VE 7000
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Front Cover; Chemical Bonding at Surfaces and Interfaces; Copyright Page; Table of Contents; Preface; Chapter 1 Surface Structure; 1. Why surface structure?; 2. Methods of surface adsorbate structure determination; 2.1. General comments; 2.2. Electron scattering; 2.3. X-ray scattering; 2.4. Ion scattering; 2.5. Spectroscopic methods and scanning probe microscopy; 3. Adsorbate-induced surface reconstruction; 4. Molecular adsorbates - local sites, orientations and intramolecular bondlengths; 4.1. General issues and the case of CO on metals; 4.2. Simple hydrocarbons on metals
4.3. Carboxylates on metals4.4. Other substrates: molecules on Si; 5. Chemisorption bondlengths; 5.1. Metal surfaces; 5.2. Oxide surfaces; 6. Conclusions; Chapter 2 Adsorbate Electronic Structure and Bonding on Metal Surfaces; 1. Introduction; 2. Probing the electronic structure; 3. Adsorbate electronic structure and chemical bonding; 4. Adsorbate systems; 5. Radical atomic adsorption; 5.1. The electronic structure of N on Cu(100); 5.2. Chemical bonding of atomic adsorbates; 6. Diatomic molecules; 6.1. N2 adsorbed on Ni(100); 6.2. CO adsorbed on Ni(100)
6.3. CO adsorbed on Cu(100) and other metals6.4. CO adsorbed in different sites; 6.5. Coadsorption of CO and K on Ni(100); 7. Unsaturated hydrocarbons; 7.1. Ethylene (C2H4) adsorbed on Ni(110) and Cu(110); 7.2. Benzene on Ni and Cu surfaces; 7.3. Bond energetics and rehybridization from spin-uncoupling; 8. Saturated hydrocarbons; 8.1. n-Octane adsorbed on Cu(110); 8.2. Difference between octane on Ni and Cu surfaces; 9. Lone pair interactions; 9.1. Water adsorption on Pt and Cu surfaces; 9.2. Adsorption of ammonia and the amino group in glycine on Cu(110); 10. Summary
Chapter 3 The Dynamics of Making and Breaking Bonds at Surfaces1. Introduction; 2. Theoretical background; 2.1. Adiabatic dynamics (Born-Oppenheimer approximation); 2.2. Generic PES topologies; 2.3. Dynamics vs. kinetics; 2.3.1. Direct dissociation; 2.3.2. Precursor-mediated dissociation; 2.4. Detailed balance; 2.5. Lattice coupling; 2.5.1. Energy transfer in adsorption/scattering; 2.5.2. Lattice coupling in direct molecular dissociation; 2.6. Non-adiabatic dynamics; 2.6.1. Hot electrons from chemistry; 2.6.2. Chemistry from hot electrons; 3. Experimental background
3.1. Experimental techniques3.2. Typical measurements; 3.2.1. Rate measurements; 3.2.2. Adsorption-trapping and sticking; 3.2.3. Desorption; 3.2.4. Scattering; 3.2.5. Initial state preparation; 3.2.6. Photochemistry/femtochemistry; 3.2.7. Single molecule chemistry (STM); 4. Processes; 4.1. Atomic adsorption/desorption/scattering; 4.1.1. Ar/Pt(111); 4.1.2. H/Cu(111); 4.2. Molecular adsorption/desorption/scattering; 4.2.1. NO/Ag(111); 4.2.2. NO/Pt(111); 4.3. Direct dissociation/associative desorption; 4.3.1. Activated dissociation; 4.3.2. Weakly activated dissociation
4.3.3. Non-activated dissociation
Record Nr. UNINA-9910956913003321
Amsterdam ; ; Oxford, : Elsevier, 2008
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Materials dominated by their interfaces / / by Rolf Hempelmann (ed.)
Materials dominated by their interfaces / / by Rolf Hempelmann (ed.)
Pubbl/distr/stampa München : , : Oldenbourg Verlag München Wien, , [2008]
Descrizione fisica 1 online resource (378 p.)
Disciplina 530.4/1
Collana Progress physical chemistry
Soggetto topico Interfaces (Physical sciences)
Soggetto genere / forma Electronic books.
ISBN 3-486-59867-8
Classificazione VE 7000
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Front Matter -- Magnetic Nanorods: Genesis, Self-Organization and Applications / Birringer, Rainer / Wolf, Helmut / Lang, Christian / Tschöpe, Andreas / Michels, Andreas -- Thermodynamic and Structural Investigations of Condensates of Small Molecules in Mesopores / Knorr, Klaus / Huber, Patrick / Wallacher, Dirk -- Precursorchemistry with Metalalkoxides and their Use for Nano-Scaled Materials / Veith, Michael -- One-Dimensional Semiconductor Nanostructures: Growth, Characterization and Device Applications / Mathur, Sanjay / Barth, Sven -- Nanocrystalline Metals Prepared by Electrodeposition / Natter, H. / Hempelmann, R. -- Investigation of Nanocrystalline Materials Using Radioactive Isotopes / Wichert, Th. / Wolf, H. / Guan, Z. / Li, X. -- Theoretical Studies of Structural, Energetic, and Electronic Properties of Clusters / Springborg, Michael / Dong, Yi / Grigoryan, Valeri G. / Tevekeliyska, Violina / Alamanova, Denitsa / Kasabova, Elisaveta / Roy, Sudip / Joswig, Jan-Ole / Asaduzzaman, Abu Md. -- Photoemission Investigation of the L̄-Gap Surface States on Clean and Rare Gas-Covered Noble Metal (111)-Surfaces / Hüfner, Stefan / Reinert, Friedrich / Schmidt, Stefan / Nicolay, Georg / Forster, Frank -- Computer Simulations of Phase Transitions and Dynamics in Confined Systems / Rieger, Heiko / Paul, Raja / Noh, Jae-Dong / Schehr, Grégory -- Quantitative Evaluation of Elastic Properties of Nano-Crystalline Nickel Using Atomic Force Acoustic Microscopy / Kopycinska-Müller, M. / Caron, A. / Hirsekorn, S. / Rabe, U. / Natter, H. / Hempelmann, R. / Birringer, R. / Arnold, W. -- Mechanical Properties of Nanomaterials Examined with a NI-AFM / Vehoff, H. / Yang, B. / Barnoush, A. / Natter, H. / Hempelmann, R. -- Equilibrium and Nonequilibrium Behaviour of Ferrofluids - Experiments and Theory / Embs, Jan Peter / Huke, Björn / Leschhorn, Andreas / Lücke, Manfred -- Combinatorial Fabrication of Thin Film-Libraries and Evaluation of their Piezoelectricity by Ultrasonic Piezo-Mode Imaging / Rende, Daniela / Schwarz, Kerstin / Rabe, Ute / Maier, Wilhelm F. / Arnold, Walter -- Back Matter
Record Nr. UNINA-9910464674403321
München : , : Oldenbourg Verlag München Wien, , [2008]
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Materials dominated by their interfaces / / by Rolf Hempelmann (ed.)
Materials dominated by their interfaces / / by Rolf Hempelmann (ed.)
Pubbl/distr/stampa München : , : Oldenbourg Verlag München Wien, , [2008]
Descrizione fisica 1 online resource (378 p.)
Disciplina 530.4/1
Collana Progress physical chemistry
Soggetto topico Interfaces (Physical sciences)
ISBN 3-486-59867-8
Classificazione VE 7000
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Front Matter -- Magnetic Nanorods: Genesis, Self-Organization and Applications / Birringer, Rainer / Wolf, Helmut / Lang, Christian / Tschöpe, Andreas / Michels, Andreas -- Thermodynamic and Structural Investigations of Condensates of Small Molecules in Mesopores / Knorr, Klaus / Huber, Patrick / Wallacher, Dirk -- Precursorchemistry with Metalalkoxides and their Use for Nano-Scaled Materials / Veith, Michael -- One-Dimensional Semiconductor Nanostructures: Growth, Characterization and Device Applications / Mathur, Sanjay / Barth, Sven -- Nanocrystalline Metals Prepared by Electrodeposition / Natter, H. / Hempelmann, R. -- Investigation of Nanocrystalline Materials Using Radioactive Isotopes / Wichert, Th. / Wolf, H. / Guan, Z. / Li, X. -- Theoretical Studies of Structural, Energetic, and Electronic Properties of Clusters / Springborg, Michael / Dong, Yi / Grigoryan, Valeri G. / Tevekeliyska, Violina / Alamanova, Denitsa / Kasabova, Elisaveta / Roy, Sudip / Joswig, Jan-Ole / Asaduzzaman, Abu Md. -- Photoemission Investigation of the L̄-Gap Surface States on Clean and Rare Gas-Covered Noble Metal (111)-Surfaces / Hüfner, Stefan / Reinert, Friedrich / Schmidt, Stefan / Nicolay, Georg / Forster, Frank -- Computer Simulations of Phase Transitions and Dynamics in Confined Systems / Rieger, Heiko / Paul, Raja / Noh, Jae-Dong / Schehr, Grégory -- Quantitative Evaluation of Elastic Properties of Nano-Crystalline Nickel Using Atomic Force Acoustic Microscopy / Kopycinska-Müller, M. / Caron, A. / Hirsekorn, S. / Rabe, U. / Natter, H. / Hempelmann, R. / Birringer, R. / Arnold, W. -- Mechanical Properties of Nanomaterials Examined with a NI-AFM / Vehoff, H. / Yang, B. / Barnoush, A. / Natter, H. / Hempelmann, R. -- Equilibrium and Nonequilibrium Behaviour of Ferrofluids - Experiments and Theory / Embs, Jan Peter / Huke, Björn / Leschhorn, Andreas / Lücke, Manfred -- Combinatorial Fabrication of Thin Film-Libraries and Evaluation of their Piezoelectricity by Ultrasonic Piezo-Mode Imaging / Rende, Daniela / Schwarz, Kerstin / Rabe, Ute / Maier, Wilhelm F. / Arnold, Walter -- Back Matter
Record Nr. UNINA-9910789484603321
München : , : Oldenbourg Verlag München Wien, , [2008]
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Materials dominated by their interfaces / / by Rolf Hempelmann (ed.)
Materials dominated by their interfaces / / by Rolf Hempelmann (ed.)
Pubbl/distr/stampa München : , : Oldenbourg Verlag München Wien, , [2008]
Descrizione fisica 1 online resource (378 p.)
Disciplina 530.4/1
Collana Progress physical chemistry
Soggetto topico Interfaces (Physical sciences)
ISBN 3-486-59867-8
Classificazione VE 7000
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Front Matter -- Magnetic Nanorods: Genesis, Self-Organization and Applications / Birringer, Rainer / Wolf, Helmut / Lang, Christian / Tschöpe, Andreas / Michels, Andreas -- Thermodynamic and Structural Investigations of Condensates of Small Molecules in Mesopores / Knorr, Klaus / Huber, Patrick / Wallacher, Dirk -- Precursorchemistry with Metalalkoxides and their Use for Nano-Scaled Materials / Veith, Michael -- One-Dimensional Semiconductor Nanostructures: Growth, Characterization and Device Applications / Mathur, Sanjay / Barth, Sven -- Nanocrystalline Metals Prepared by Electrodeposition / Natter, H. / Hempelmann, R. -- Investigation of Nanocrystalline Materials Using Radioactive Isotopes / Wichert, Th. / Wolf, H. / Guan, Z. / Li, X. -- Theoretical Studies of Structural, Energetic, and Electronic Properties of Clusters / Springborg, Michael / Dong, Yi / Grigoryan, Valeri G. / Tevekeliyska, Violina / Alamanova, Denitsa / Kasabova, Elisaveta / Roy, Sudip / Joswig, Jan-Ole / Asaduzzaman, Abu Md. -- Photoemission Investigation of the L̄-Gap Surface States on Clean and Rare Gas-Covered Noble Metal (111)-Surfaces / Hüfner, Stefan / Reinert, Friedrich / Schmidt, Stefan / Nicolay, Georg / Forster, Frank -- Computer Simulations of Phase Transitions and Dynamics in Confined Systems / Rieger, Heiko / Paul, Raja / Noh, Jae-Dong / Schehr, Grégory -- Quantitative Evaluation of Elastic Properties of Nano-Crystalline Nickel Using Atomic Force Acoustic Microscopy / Kopycinska-Müller, M. / Caron, A. / Hirsekorn, S. / Rabe, U. / Natter, H. / Hempelmann, R. / Birringer, R. / Arnold, W. -- Mechanical Properties of Nanomaterials Examined with a NI-AFM / Vehoff, H. / Yang, B. / Barnoush, A. / Natter, H. / Hempelmann, R. -- Equilibrium and Nonequilibrium Behaviour of Ferrofluids - Experiments and Theory / Embs, Jan Peter / Huke, Björn / Leschhorn, Andreas / Lücke, Manfred -- Combinatorial Fabrication of Thin Film-Libraries and Evaluation of their Piezoelectricity by Ultrasonic Piezo-Mode Imaging / Rende, Daniela / Schwarz, Kerstin / Rabe, Ute / Maier, Wilhelm F. / Arnold, Walter -- Back Matter
Record Nr. UNINA-9910814323803321
München : , : Oldenbourg Verlag München Wien, , [2008]
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Physical chemistry of solid-gas interfaces [[electronic resource] ] : concepts and methodology for gas sensors development / / Rene Lalauze
Physical chemistry of solid-gas interfaces [[electronic resource] ] : concepts and methodology for gas sensors development / / Rene Lalauze
Autore Lalauze René
Pubbl/distr/stampa London, : ISTE
Descrizione fisica 1 online resource (448 p.)
Disciplina 620.1
681/.2
Collana ISTE
Soggetto topico Gas-solid interfaces
Gas detectors
Soggetto genere / forma Electronic books.
ISBN 1-282-68892-8
9786612688928
0-470-61129-4
0-470-39391-2
Classificazione UP 7630
VE 7000
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Physical Chemistry of Solid-Gas Interfaces; Table of Contents; Preface; Chapter 1. Adsorption Phenomena; 1.1. The surface of solids: general points; 1.2. Illustration of adsorption; 1.2.1. The volumetric method or manometry; 1.2.2. The gravimetric method or thermogravimetry; 1.3. Acting forces between a gas molecule and the surface of a solid; 1.3.1. Van der Waals forces; 1.3.2. Expression of the potential between a molecule and a solid; 1.3.3. Chemical forces between a gas species and the surface of a solid; 1.3.4. Distinction between physical and chemical adsorption
1.4. Thermodynamic study of physical adsorption1.4.1. The different models of adsorption; 1.4.2. The Hill model; 1.4.3. The Hill-Everett model; 1.4.4. Thermodynamics of the adsorption equilibrium in Hill's model; 1.4.4.1. Formulating the equilibrium; 1.4.4.2. Isotherm equation; 1.4.5. Thermodynamics of adsorption equilibrium in the Hill-Everett model; 1.5. Physical adsorption isotherms; 1.5.1. General points; 1.5.2. Adsorption isotherms of mobile monolayers; 1.5.3. Adsorption isotherms of localized monolayers; 1.5.3.1. Thermodynamic method; 1.5.3.2. The kinetic model
1.5.4. Multilayer adsorption isotherms1.5.4.1. Isotherm equation; 1.6. Chemical adsorption isotherms; 1.7. Bibliography; Chapter 2. Structure of Solids: Physico-chemical Aspects; 2.1. The concept of phases; 2.2. Solid solutions; 2.3. Point defects in solids; 2.4. Denotation of structural members of a crystal lattice; 2.5. Formation of structural point defects; 2.5.1. Formation of defects in a solid matrix; 2.5.2. Formation of defects involving surface elements; 2.5.3. Concept of elementary hopping step; 2.6. Bibliography; Chapter 3. Gas-Solid Interactions: Electronic Aspects
3.1. Introduction3.2. Electronic properties of gases; 3.3. Electronic properties of solids; 3.3.1. Introduction; 3.3.2. Energy spectrum of a crystal lattice electron; 3.3.2.1. Reminder about quantum mechanics principles; 3.3.2.2. Band diagrams of solids; 3.3.2.3. Effective mass of an electron; 3.4. Electrical conductivity in solids; 3.4.1. Full bands; 3.4.2. Partially occupied bands; 3.5. Influence of temperature on the electric behavior of solids; 3.5.1. Band diagram and Fermi level of conductors; 3.5.2. Case of intrinsic semiconductors; 3.5.3. Case of extrinsic semiconductors
3.5.4. Case of materials with point defects3.5.4.1. Metal oxides with anion defects, denoted by MO1-x; 3.5.4.2. Metal oxides with cation vacancies, denoted by M1-xO; 3.5.4.3. Metal oxides with interstitial cations, denoted by M1+xO; 3.5.4.4. Metal oxides with interstitial anions, denoted by MO1+x; 3.6. Bibliography; Chapter 4. Interfacial Thermodynamic Equilibrium Studies; 4.1. Introduction; 4.2. Interfacial phenomena; 4.3. Solid-gas equilibriums involving electron transfers or electron holes; 4.3.1. Concept of surface states; 4.3.2. Space-charge region (SCR); 4.3.3. Electronic work function
4.3.3.1. Case of a semiconductor in the absence of surface states
Record Nr. UNINA-9910139500603321
Lalauze René  
London, : ISTE
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Physical chemistry of solid-gas interfaces [[electronic resource] ] : concepts and methodology for gas sensors development / / Rene Lalauze
Physical chemistry of solid-gas interfaces [[electronic resource] ] : concepts and methodology for gas sensors development / / Rene Lalauze
Autore Lalauze René
Pubbl/distr/stampa London, : ISTE
Descrizione fisica 1 online resource (448 p.)
Disciplina 620.1
681/.2
Collana ISTE
Soggetto topico Gas-solid interfaces
Gas detectors
ISBN 1-282-68892-8
9786612688928
0-470-61129-4
0-470-39391-2
Classificazione UP 7630
VE 7000
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Physical Chemistry of Solid-Gas Interfaces; Table of Contents; Preface; Chapter 1. Adsorption Phenomena; 1.1. The surface of solids: general points; 1.2. Illustration of adsorption; 1.2.1. The volumetric method or manometry; 1.2.2. The gravimetric method or thermogravimetry; 1.3. Acting forces between a gas molecule and the surface of a solid; 1.3.1. Van der Waals forces; 1.3.2. Expression of the potential between a molecule and a solid; 1.3.3. Chemical forces between a gas species and the surface of a solid; 1.3.4. Distinction between physical and chemical adsorption
1.4. Thermodynamic study of physical adsorption1.4.1. The different models of adsorption; 1.4.2. The Hill model; 1.4.3. The Hill-Everett model; 1.4.4. Thermodynamics of the adsorption equilibrium in Hill's model; 1.4.4.1. Formulating the equilibrium; 1.4.4.2. Isotherm equation; 1.4.5. Thermodynamics of adsorption equilibrium in the Hill-Everett model; 1.5. Physical adsorption isotherms; 1.5.1. General points; 1.5.2. Adsorption isotherms of mobile monolayers; 1.5.3. Adsorption isotherms of localized monolayers; 1.5.3.1. Thermodynamic method; 1.5.3.2. The kinetic model
1.5.4. Multilayer adsorption isotherms1.5.4.1. Isotherm equation; 1.6. Chemical adsorption isotherms; 1.7. Bibliography; Chapter 2. Structure of Solids: Physico-chemical Aspects; 2.1. The concept of phases; 2.2. Solid solutions; 2.3. Point defects in solids; 2.4. Denotation of structural members of a crystal lattice; 2.5. Formation of structural point defects; 2.5.1. Formation of defects in a solid matrix; 2.5.2. Formation of defects involving surface elements; 2.5.3. Concept of elementary hopping step; 2.6. Bibliography; Chapter 3. Gas-Solid Interactions: Electronic Aspects
3.1. Introduction3.2. Electronic properties of gases; 3.3. Electronic properties of solids; 3.3.1. Introduction; 3.3.2. Energy spectrum of a crystal lattice electron; 3.3.2.1. Reminder about quantum mechanics principles; 3.3.2.2. Band diagrams of solids; 3.3.2.3. Effective mass of an electron; 3.4. Electrical conductivity in solids; 3.4.1. Full bands; 3.4.2. Partially occupied bands; 3.5. Influence of temperature on the electric behavior of solids; 3.5.1. Band diagram and Fermi level of conductors; 3.5.2. Case of intrinsic semiconductors; 3.5.3. Case of extrinsic semiconductors
3.5.4. Case of materials with point defects3.5.4.1. Metal oxides with anion defects, denoted by MO1-x; 3.5.4.2. Metal oxides with cation vacancies, denoted by M1-xO; 3.5.4.3. Metal oxides with interstitial cations, denoted by M1+xO; 3.5.4.4. Metal oxides with interstitial anions, denoted by MO1+x; 3.6. Bibliography; Chapter 4. Interfacial Thermodynamic Equilibrium Studies; 4.1. Introduction; 4.2. Interfacial phenomena; 4.3. Solid-gas equilibriums involving electron transfers or electron holes; 4.3.1. Concept of surface states; 4.3.2. Space-charge region (SCR); 4.3.3. Electronic work function
4.3.3.1. Case of a semiconductor in the absence of surface states
Record Nr. UNINA-9910829887603321
Lalauze René  
London, : ISTE
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Physico-chemistry of solid-gas interfaces : concepts and methodology for gas sensors development / / Rene Lalauze
Physico-chemistry of solid-gas interfaces : concepts and methodology for gas sensors development / / Rene Lalauze
Autore Lalauze Rene
Pubbl/distr/stampa London, : ISTE
Descrizione fisica 1 online resource (448 p.)
Disciplina 681/.2
Collana ISTE
Soggetto topico Gas-solid interfaces
Gas detectors
ISBN 1-282-68892-8
9786612688928
0-470-61129-4
0-470-39391-2
Classificazione UP 7630
VE 7000
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Physical Chemistry of Solid-Gas Interfaces; Table of Contents; Preface; Chapter 1. Adsorption Phenomena; 1.1. The surface of solids: general points; 1.2. Illustration of adsorption; 1.2.1. The volumetric method or manometry; 1.2.2. The gravimetric method or thermogravimetry; 1.3. Acting forces between a gas molecule and the surface of a solid; 1.3.1. Van der Waals forces; 1.3.2. Expression of the potential between a molecule and a solid; 1.3.3. Chemical forces between a gas species and the surface of a solid; 1.3.4. Distinction between physical and chemical adsorption
1.4. Thermodynamic study of physical adsorption1.4.1. The different models of adsorption; 1.4.2. The Hill model; 1.4.3. The Hill-Everett model; 1.4.4. Thermodynamics of the adsorption equilibrium in Hill's model; 1.4.4.1. Formulating the equilibrium; 1.4.4.2. Isotherm equation; 1.4.5. Thermodynamics of adsorption equilibrium in the Hill-Everett model; 1.5. Physical adsorption isotherms; 1.5.1. General points; 1.5.2. Adsorption isotherms of mobile monolayers; 1.5.3. Adsorption isotherms of localized monolayers; 1.5.3.1. Thermodynamic method; 1.5.3.2. The kinetic model
1.5.4. Multilayer adsorption isotherms1.5.4.1. Isotherm equation; 1.6. Chemical adsorption isotherms; 1.7. Bibliography; Chapter 2. Structure of Solids: Physico-chemical Aspects; 2.1. The concept of phases; 2.2. Solid solutions; 2.3. Point defects in solids; 2.4. Denotation of structural members of a crystal lattice; 2.5. Formation of structural point defects; 2.5.1. Formation of defects in a solid matrix; 2.5.2. Formation of defects involving surface elements; 2.5.3. Concept of elementary hopping step; 2.6. Bibliography; Chapter 3. Gas-Solid Interactions: Electronic Aspects
3.1. Introduction3.2. Electronic properties of gases; 3.3. Electronic properties of solids; 3.3.1. Introduction; 3.3.2. Energy spectrum of a crystal lattice electron; 3.3.2.1. Reminder about quantum mechanics principles; 3.3.2.2. Band diagrams of solids; 3.3.2.3. Effective mass of an electron; 3.4. Electrical conductivity in solids; 3.4.1. Full bands; 3.4.2. Partially occupied bands; 3.5. Influence of temperature on the electric behavior of solids; 3.5.1. Band diagram and Fermi level of conductors; 3.5.2. Case of intrinsic semiconductors; 3.5.3. Case of extrinsic semiconductors
3.5.4. Case of materials with point defects3.5.4.1. Metal oxides with anion defects, denoted by MO1-x; 3.5.4.2. Metal oxides with cation vacancies, denoted by M1-xO; 3.5.4.3. Metal oxides with interstitial cations, denoted by M1+xO; 3.5.4.4. Metal oxides with interstitial anions, denoted by MO1+x; 3.6. Bibliography; Chapter 4. Interfacial Thermodynamic Equilibrium Studies; 4.1. Introduction; 4.2. Interfacial phenomena; 4.3. Solid-gas equilibriums involving electron transfers or electron holes; 4.3.1. Concept of surface states; 4.3.2. Space-charge region (SCR); 4.3.3. Electronic work function
4.3.3.1. Case of a semiconductor in the absence of surface states
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