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Additives in polymers [[electronic resource] ] : industrial analysis and applications / / Jan C.J. Bart
| Additives in polymers [[electronic resource] ] : industrial analysis and applications / / Jan C.J. Bart |
| Autore | Bart Jan C. J |
| Pubbl/distr/stampa | Chichester, : John Wiley & Sons, c2005 |
| Descrizione fisica | 1 online resource (837 p.) |
| Disciplina | 668.9 |
| Soggetto topico |
Polymers - Additives
Polymers - Analysis |
| ISBN |
1-280-27461-1
9786610274611 0-470-01206-4 0-470-01205-6 |
| Classificazione | UV 2100 |
| Formato | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
ADDITIVES IN POLYMERS Industrial Analysis and Applications; Contents; FOREWORD; PREFACE; ABOUT THE AUTHOR; ACKNOWLEDGEMENTS; CHAPTER 1 Introduction; 1.1 Additives; 1.1.1 Additive functionality; 1.2 Plastics formulations; 1.2.1 Supply forms; 1.2.2 Additive delivery; 1.3 Economic impact of polymer additives; 1.4 Analysis of plastics; 1.4.1 Regulations and standardisation; 1.4.2 Prior art; 1.4.3 Databases; 1.4.4 Scope; 1.4.5 Chapter overview; 1.5 Bibliography; 1.5.1 Plastics additives; 1.5.2 Processing technologies; 1.5.3 Instrumental analysis; 1.5.4 Polymer analysis
1.5.5 Polymer/additive analysis1.6 References; CHAPTER 2 Deformulation Principles; 2.1 Polymer identification; 2.2 Additive analysis of rubbers: 'Best Practice'; 2.3 Polymer extract analysis; 2.4 In situ polymer/additive analysis; 2.5 Class-specific polymer/additive analysis; 2.6 Bibliography; 2.6.1 Polymer identification; 2.6.2 Deformulation of rubbers; 2.6.3 Deformulation of polymers; 2.7 References; CHAPTER 3 Sample Preparation Perspectives; 3.1 Solvents; 3.1.1 Polymer solubility criteria; 3.1.2 Solubility parameters; 3.1.3 Polymer solutions; 3.2 Extraction strategy 3.3 Conventional extraction technologies3.3.1 Liquid-liquid extraction; 3.3.2 Liquid-solid extraction; 3.3.3 Classical solvent extractions of additives from polymers; 3.3.4 Sonication; 3.4 High-pressure solvent extraction methods; 3.4.1 Supercritical fluid technology; 3.4.2 Analytical SFE; 3.4.3 Subcritical water extraction; 3.4.4 Microwave technology; 3.4.5 Microwave-assisted extractions; 3.4.6 Pressurised fluid extraction; 3.5 Sorbent extraction; 3.5.1 Solid-phase extraction; 3.5.2 Solid-phase microextraction; 3.5.3 Stir bar sorptive extraction 3.6 Methodological comparison of extraction methods3.6.1 Experimental comparisons; 3.6.2 Extraction selectivity; 3.6.3 'Nonextractable' additive analysis; 3.7 Polymer/additive dissolution methods; 3.8 Hydrolysis; 3.9 Bibliography; 3.9.1 Sampling and sample preparation; 3.9.2 Solvents/solubility; 3.9.3 Extraction methods; 3.10 References; CHAPTER 4 Separation Techniques; 4.1 Analytical detectors; 4.2 Gas chromatography; 4.2.1 High-temperature gas chromatography; 4.2.2 Headspace gas chromatography; 4.3 Supercritical fluid chromatography; 4.4 Liquid chromatography techniques 4.4.1 Planar chromatographies4.4.2 Column chromatographies; 4.5 Capillary electrophoretic techniques; 4.6 Bibliography; 4.6.1 General texts; 4.6.2 Detectors; 4.6.3 Gas chromatography; 4.6.4 Supercritical fluid chromatography; 4.6.5 Thin-layer chromatography; 4.6.6 Liquid chromatography; 4.6.7 Size-exclusion chromatography; 4.6.8 Ion chromatography; 4.6.9 Capillary electrophoretic techniques; 4.7 References; CHAPTER 5 Polymer/Additive Analysis: The Spectroscopic Alternative; 5.1 Ultraviolet/visible spectrophotometry; 5.2 Infrared spectroscopy; 5.3 Luminescence spectroscopy 5.4 High-resolution nuclear magnetic resonance spectroscopy |
| Record Nr. | UNINA-9910143745303321 |
Bart Jan C. J
|
||
| Chichester, : John Wiley & Sons, c2005 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Additives in polymers : industrial analysis and applications / / Jan C.J. Bart
| Additives in polymers : industrial analysis and applications / / Jan C.J. Bart |
| Autore | Bart Jan C. J |
| Edizione | [1st ed.] |
| Pubbl/distr/stampa | Chichester, : John Wiley & Sons, c2005 |
| Descrizione fisica | 1 online resource (837 p.) |
| Disciplina | 668.9 |
| Soggetto topico |
Polymers - Additives
Polymers - Analysis |
| ISBN |
1-280-27461-1
9786610274611 0-470-01206-4 0-470-01205-6 |
| Classificazione | UV 2100 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
ADDITIVES IN POLYMERS Industrial Analysis and Applications; Contents; FOREWORD; PREFACE; ABOUT THE AUTHOR; ACKNOWLEDGEMENTS; CHAPTER 1 Introduction; 1.1 Additives; 1.1.1 Additive functionality; 1.2 Plastics formulations; 1.2.1 Supply forms; 1.2.2 Additive delivery; 1.3 Economic impact of polymer additives; 1.4 Analysis of plastics; 1.4.1 Regulations and standardisation; 1.4.2 Prior art; 1.4.3 Databases; 1.4.4 Scope; 1.4.5 Chapter overview; 1.5 Bibliography; 1.5.1 Plastics additives; 1.5.2 Processing technologies; 1.5.3 Instrumental analysis; 1.5.4 Polymer analysis
1.5.5 Polymer/additive analysis1.6 References; CHAPTER 2 Deformulation Principles; 2.1 Polymer identification; 2.2 Additive analysis of rubbers: 'Best Practice'; 2.3 Polymer extract analysis; 2.4 In situ polymer/additive analysis; 2.5 Class-specific polymer/additive analysis; 2.6 Bibliography; 2.6.1 Polymer identification; 2.6.2 Deformulation of rubbers; 2.6.3 Deformulation of polymers; 2.7 References; CHAPTER 3 Sample Preparation Perspectives; 3.1 Solvents; 3.1.1 Polymer solubility criteria; 3.1.2 Solubility parameters; 3.1.3 Polymer solutions; 3.2 Extraction strategy 3.3 Conventional extraction technologies3.3.1 Liquid-liquid extraction; 3.3.2 Liquid-solid extraction; 3.3.3 Classical solvent extractions of additives from polymers; 3.3.4 Sonication; 3.4 High-pressure solvent extraction methods; 3.4.1 Supercritical fluid technology; 3.4.2 Analytical SFE; 3.4.3 Subcritical water extraction; 3.4.4 Microwave technology; 3.4.5 Microwave-assisted extractions; 3.4.6 Pressurised fluid extraction; 3.5 Sorbent extraction; 3.5.1 Solid-phase extraction; 3.5.2 Solid-phase microextraction; 3.5.3 Stir bar sorptive extraction 3.6 Methodological comparison of extraction methods3.6.1 Experimental comparisons; 3.6.2 Extraction selectivity; 3.6.3 'Nonextractable' additive analysis; 3.7 Polymer/additive dissolution methods; 3.8 Hydrolysis; 3.9 Bibliography; 3.9.1 Sampling and sample preparation; 3.9.2 Solvents/solubility; 3.9.3 Extraction methods; 3.10 References; CHAPTER 4 Separation Techniques; 4.1 Analytical detectors; 4.2 Gas chromatography; 4.2.1 High-temperature gas chromatography; 4.2.2 Headspace gas chromatography; 4.3 Supercritical fluid chromatography; 4.4 Liquid chromatography techniques 4.4.1 Planar chromatographies4.4.2 Column chromatographies; 4.5 Capillary electrophoretic techniques; 4.6 Bibliography; 4.6.1 General texts; 4.6.2 Detectors; 4.6.3 Gas chromatography; 4.6.4 Supercritical fluid chromatography; 4.6.5 Thin-layer chromatography; 4.6.6 Liquid chromatography; 4.6.7 Size-exclusion chromatography; 4.6.8 Ion chromatography; 4.6.9 Capillary electrophoretic techniques; 4.7 References; CHAPTER 5 Polymer/Additive Analysis: The Spectroscopic Alternative; 5.1 Ultraviolet/visible spectrophotometry; 5.2 Infrared spectroscopy; 5.3 Luminescence spectroscopy 5.4 High-resolution nuclear magnetic resonance spectroscopy |
| Record Nr. | UNINA-9910810642403321 |
|
Bart Jan C. J
|
||
| Chichester, : John Wiley & Sons, c2005 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Polymer grafting and crosslinking [[electronic resource] /] / edited by Amit Bhattacharya, James W. Rawlins, Paramita Ray
| Polymer grafting and crosslinking [[electronic resource] /] / edited by Amit Bhattacharya, James W. Rawlins, Paramita Ray |
| Pubbl/distr/stampa | Hoboken, N.J., : John Wiley, c2009 |
| Descrizione fisica | 1 online resource (353 p.) |
| Disciplina | 668.9 |
| Altri autori (Persone) |
BhattacharyaAmit <1946->
RawlinsJames Wayne RayParamita |
| Soggetto topico |
Crosslinked polymers - Industrial applications
Crosslinking (Polymerization) |
| Soggetto genere / forma | Electronic books. |
| ISBN |
1-282-68918-5
9786612689185 0-470-41481-2 0-470-41480-4 |
| Classificazione | UV 2100 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto | POLYMER GRAFTING AND CROSSLINKING; CONTENTS; Preface; Contributors; 1 Introduction; 2 Basic Features and Techniques; 3 Mechanism and Kinetics; 4 Analytical Evidence; 5 Broader Spectrum: Examples; 6 In the Biomedical Arena; 7 In Textiles; 8 In Automobiles; 9 In Cable Technology; 10 In Separation and Purification; 11 In Coatings, Adhesives, and Laminates; 12 In Commodity Plastics; Future Directions; Index |
| Record Nr. | UNINA-9910144652703321 |
| Hoboken, N.J., : John Wiley, c2009 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Polymer grafting and crosslinking [[electronic resource] /] / edited by Amit Bhattacharya, James W. Rawlins, Paramita Ray
| Polymer grafting and crosslinking [[electronic resource] /] / edited by Amit Bhattacharya, James W. Rawlins, Paramita Ray |
| Pubbl/distr/stampa | Hoboken, N.J., : John Wiley, c2009 |
| Descrizione fisica | 1 online resource (353 p.) |
| Disciplina | 668.9 |
| Altri autori (Persone) |
BhattacharyaAmit <1946->
RawlinsJames Wayne RayParamita |
| Soggetto topico |
Crosslinked polymers - Industrial applications
Crosslinking (Polymerization) |
| ISBN |
1-282-68918-5
9786612689185 0-470-41481-2 0-470-41480-4 |
| Classificazione | UV 2100 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto | POLYMER GRAFTING AND CROSSLINKING; CONTENTS; Preface; Contributors; 1 Introduction; 2 Basic Features and Techniques; 3 Mechanism and Kinetics; 4 Analytical Evidence; 5 Broader Spectrum: Examples; 6 In the Biomedical Arena; 7 In Textiles; 8 In Automobiles; 9 In Cable Technology; 10 In Separation and Purification; 11 In Coatings, Adhesives, and Laminates; 12 In Commodity Plastics; Future Directions; Index |
| Record Nr. | UNINA-9910830518603321 |
| Hoboken, N.J., : John Wiley, c2009 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Polymer grafting and crosslinking / / edited by Amit Bhattacharya, James W. Rawlins, Paramita Ray
| Polymer grafting and crosslinking / / edited by Amit Bhattacharya, James W. Rawlins, Paramita Ray |
| Pubbl/distr/stampa | Hoboken, N.J., : John Wiley, c2009 |
| Descrizione fisica | 1 online resource (353 p.) |
| Disciplina | 668.9 |
| Altri autori (Persone) |
BhattacharyaAmit <1946->
RawlinsJames Wayne RayParamita |
| Soggetto topico |
Crosslinked polymers - Industrial applications
Crosslinking (Polymerization) |
| ISBN |
1-282-68918-5
9786612689185 0-470-41481-2 0-470-41480-4 |
| Classificazione | UV 2100 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto | POLYMER GRAFTING AND CROSSLINKING; CONTENTS; Preface; Contributors; 1 Introduction; 2 Basic Features and Techniques; 3 Mechanism and Kinetics; 4 Analytical Evidence; 5 Broader Spectrum: Examples; 6 In the Biomedical Arena; 7 In Textiles; 8 In Automobiles; 9 In Cable Technology; 10 In Separation and Purification; 11 In Coatings, Adhesives, and Laminates; 12 In Commodity Plastics; Future Directions; Index |
| Record Nr. | UNINA-9910877424803321 |
| Hoboken, N.J., : John Wiley, c2009 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Solid state polymerization [[electronic resource] /] / Constantine D. Papaspyrides, Stamatina N. Vouyiouka
| Solid state polymerization [[electronic resource] /] / Constantine D. Papaspyrides, Stamatina N. Vouyiouka |
| Autore | Papaspyrides Constantine D |
| Pubbl/distr/stampa | Hoboken, NJ, : Wiley, c2009 |
| Descrizione fisica | 1 online resource (314 p.) |
| Disciplina |
660
668.9/2 668.92 |
| Altri autori (Persone) | VouyioukaStamatina N |
| Soggetto topico |
Polymerization
Solid state chemistry |
| ISBN |
1-282-13738-7
9786612137389 0-470-45183-1 0-470-45182-3 |
| Classificazione |
UV 2100
VE 8000 VK 8000 VN 5900 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
SOLID STATE POLYMERIZATION; CONTENTS; Contributors; Preface; 1 Fundamentals of Solid State Polymerization; 1.1 Introduction; 1.1.1 Polymers and Plastics; 1.1.2 Polymerization Processes; 1.1.3 Introduction to Solid State Polymerization; 1.2 Solid State Polymerization of Chain-Growth Polymers (Solid State Polyaddition); 1.3 Solid State Polymerization of Step-Growth Polymers (Solid State Polycondensation); 1.3.1 Monomer Solid State Polymerization (Direct SSP); 1.3.2 Prepolymer Solid State Polymerization (Post-SSP, Solid State Finishing); 1.4 Solid State Polymerization Apparatus and Assemblies
1.5 Solid State Applications in the Polymer Industry1.5.1 Solid State Polymerization Advantages; 1.5.2 Post-Solid State Polymerization Application in Polyamides; 1.6 Conclusions; 2 Solid State Polymerization Chemistry and Mechanisms: Unequal Reactivity of End Groups; 2.1 Introduction; 2.2 Special Characteristics of Solid State Polymerization; 2.3 Classical Kinetic Equations in Solid State Polymerization; 2.4 Model of Molecular Morphology and Chain-End Movement; 2.4.1 Definition of Chain-End Length in the Amorphous Phase; 2.4.2 How End Groups Move During Solid State Polymerization 2.4.3 How Chain-End Length Affects the Movement of End Groups2.5 Reactivity of End Groups; 2.5.1 Principles of Equal Reactivity of End Groups in Melt Polymerization; 2.5.2 Principles of Unequal Reactivity of End Groups in Solid State Polymerization; 2.5.3 Sources of Low Reactivity of End Groups; 2.6 Why Intrinsic Viscosity Levels Off During Solid State Polymerization; 2.6.1 Definition of Residual Average Radius and Residual End-Group Concentration; 2.6.2 Relationship Between (r) and; 2.6.3 Relationship Between C(r), (r), and Ultimate IV 2.6.4 Explanation of Temperature Effect on Solid State Polymerization2.6.5 Explanation of Initial IV Effect on Solid State Polymerization; 2.7 Solid State Polymerization Kinetics; 2.7.1 Kinetic Equation of Ideal Solid State Polymerization; 2.7.2 Empirical Kinetic Equation of Real Solid State Polymerization; 2.8 Conclusions; 3 Kinetic Aspects of Polyester Solid State Polymerization; 3.1 Introduction; 3.2 Phenomena Involved in Solid State Polymerization of Polyesters; 3.2.1 Possible Reactions in Solid State Polymerization of Polyesters 3.2.2 Chain Mobility and Diffusion of Low-Molecular-Weight By-Products3.2.3 Kinetic and Diffusion Equations; 3.3 Modeling Solid State Polymerization of Polyesters; 3.3.1 Effects of Variables and Predictions Based on Kinetic Models; 3.4 Solid State Polymerization of Typical Polyesters; 3.4.1 Poly(ethylene terephthalate); 3.4.2 Poly(butylene terephthalate); 3.4.3 Poly(ethylene naphthalate); 3.4.4 Poly(trimethylene terephthalate); 3.4.5 Poly(L-lactic acid); 3.5 Conclusions; 4 Kinetic Aspects of Polyamide Solid State Polymerization; 4.1 Introduction 4.2 Simple Kinetic Models of Solid State Polyamidation |
| Record Nr. | UNINA-9910146399403321 |
|
Papaspyrides Constantine D
|
||
| Hoboken, NJ, : Wiley, c2009 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Solid state polymerization [[electronic resource] /] / Constantine D. Papaspyrides, Stamatina N. Vouyiouka
| Solid state polymerization [[electronic resource] /] / Constantine D. Papaspyrides, Stamatina N. Vouyiouka |
| Autore | Papaspyrides Constantine D |
| Pubbl/distr/stampa | Hoboken, NJ, : Wiley, c2009 |
| Descrizione fisica | 1 online resource (314 p.) |
| Disciplina |
660
668.9/2 668.92 |
| Altri autori (Persone) | VouyioukaStamatina N |
| Soggetto topico |
Polymerization
Solid state chemistry |
| ISBN |
1-282-13738-7
9786612137389 0-470-45183-1 0-470-45182-3 |
| Classificazione |
UV 2100
VE 8000 VK 8000 VN 5900 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
SOLID STATE POLYMERIZATION; CONTENTS; Contributors; Preface; 1 Fundamentals of Solid State Polymerization; 1.1 Introduction; 1.1.1 Polymers and Plastics; 1.1.2 Polymerization Processes; 1.1.3 Introduction to Solid State Polymerization; 1.2 Solid State Polymerization of Chain-Growth Polymers (Solid State Polyaddition); 1.3 Solid State Polymerization of Step-Growth Polymers (Solid State Polycondensation); 1.3.1 Monomer Solid State Polymerization (Direct SSP); 1.3.2 Prepolymer Solid State Polymerization (Post-SSP, Solid State Finishing); 1.4 Solid State Polymerization Apparatus and Assemblies
1.5 Solid State Applications in the Polymer Industry1.5.1 Solid State Polymerization Advantages; 1.5.2 Post-Solid State Polymerization Application in Polyamides; 1.6 Conclusions; 2 Solid State Polymerization Chemistry and Mechanisms: Unequal Reactivity of End Groups; 2.1 Introduction; 2.2 Special Characteristics of Solid State Polymerization; 2.3 Classical Kinetic Equations in Solid State Polymerization; 2.4 Model of Molecular Morphology and Chain-End Movement; 2.4.1 Definition of Chain-End Length in the Amorphous Phase; 2.4.2 How End Groups Move During Solid State Polymerization 2.4.3 How Chain-End Length Affects the Movement of End Groups2.5 Reactivity of End Groups; 2.5.1 Principles of Equal Reactivity of End Groups in Melt Polymerization; 2.5.2 Principles of Unequal Reactivity of End Groups in Solid State Polymerization; 2.5.3 Sources of Low Reactivity of End Groups; 2.6 Why Intrinsic Viscosity Levels Off During Solid State Polymerization; 2.6.1 Definition of Residual Average Radius and Residual End-Group Concentration; 2.6.2 Relationship Between (r) and; 2.6.3 Relationship Between C(r), (r), and Ultimate IV 2.6.4 Explanation of Temperature Effect on Solid State Polymerization2.6.5 Explanation of Initial IV Effect on Solid State Polymerization; 2.7 Solid State Polymerization Kinetics; 2.7.1 Kinetic Equation of Ideal Solid State Polymerization; 2.7.2 Empirical Kinetic Equation of Real Solid State Polymerization; 2.8 Conclusions; 3 Kinetic Aspects of Polyester Solid State Polymerization; 3.1 Introduction; 3.2 Phenomena Involved in Solid State Polymerization of Polyesters; 3.2.1 Possible Reactions in Solid State Polymerization of Polyesters 3.2.2 Chain Mobility and Diffusion of Low-Molecular-Weight By-Products3.2.3 Kinetic and Diffusion Equations; 3.3 Modeling Solid State Polymerization of Polyesters; 3.3.1 Effects of Variables and Predictions Based on Kinetic Models; 3.4 Solid State Polymerization of Typical Polyesters; 3.4.1 Poly(ethylene terephthalate); 3.4.2 Poly(butylene terephthalate); 3.4.3 Poly(ethylene naphthalate); 3.4.4 Poly(trimethylene terephthalate); 3.4.5 Poly(L-lactic acid); 3.5 Conclusions; 4 Kinetic Aspects of Polyamide Solid State Polymerization; 4.1 Introduction 4.2 Simple Kinetic Models of Solid State Polyamidation |
| Record Nr. | UNINA-9910830473803321 |
|
Papaspyrides Constantine D
|
||
| Hoboken, NJ, : Wiley, c2009 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Solid state polymerization / / Constantine D. Papaspyrides, Stamatina N. Vouyiouka
| Solid state polymerization / / Constantine D. Papaspyrides, Stamatina N. Vouyiouka |
| Autore | Papaspyrides Constantine D |
| Pubbl/distr/stampa | Hoboken, NJ, : Wiley, c2009 |
| Descrizione fisica | 1 online resource (314 p.) |
| Disciplina | 668.9/2 |
| Altri autori (Persone) | VouyioukaStamatina N |
| Soggetto topico |
Polymerization
Solid state chemistry |
| ISBN |
1-282-13738-7
9786612137389 0-470-45183-1 0-470-45182-3 |
| Classificazione |
UV 2100
VE 8000 VK 8000 VN 5900 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
SOLID STATE POLYMERIZATION; CONTENTS; Contributors; Preface; 1 Fundamentals of Solid State Polymerization; 1.1 Introduction; 1.1.1 Polymers and Plastics; 1.1.2 Polymerization Processes; 1.1.3 Introduction to Solid State Polymerization; 1.2 Solid State Polymerization of Chain-Growth Polymers (Solid State Polyaddition); 1.3 Solid State Polymerization of Step-Growth Polymers (Solid State Polycondensation); 1.3.1 Monomer Solid State Polymerization (Direct SSP); 1.3.2 Prepolymer Solid State Polymerization (Post-SSP, Solid State Finishing); 1.4 Solid State Polymerization Apparatus and Assemblies
1.5 Solid State Applications in the Polymer Industry1.5.1 Solid State Polymerization Advantages; 1.5.2 Post-Solid State Polymerization Application in Polyamides; 1.6 Conclusions; 2 Solid State Polymerization Chemistry and Mechanisms: Unequal Reactivity of End Groups; 2.1 Introduction; 2.2 Special Characteristics of Solid State Polymerization; 2.3 Classical Kinetic Equations in Solid State Polymerization; 2.4 Model of Molecular Morphology and Chain-End Movement; 2.4.1 Definition of Chain-End Length in the Amorphous Phase; 2.4.2 How End Groups Move During Solid State Polymerization 2.4.3 How Chain-End Length Affects the Movement of End Groups2.5 Reactivity of End Groups; 2.5.1 Principles of Equal Reactivity of End Groups in Melt Polymerization; 2.5.2 Principles of Unequal Reactivity of End Groups in Solid State Polymerization; 2.5.3 Sources of Low Reactivity of End Groups; 2.6 Why Intrinsic Viscosity Levels Off During Solid State Polymerization; 2.6.1 Definition of Residual Average Radius and Residual End-Group Concentration; 2.6.2 Relationship Between (r) and; 2.6.3 Relationship Between C(r), (r), and Ultimate IV 2.6.4 Explanation of Temperature Effect on Solid State Polymerization2.6.5 Explanation of Initial IV Effect on Solid State Polymerization; 2.7 Solid State Polymerization Kinetics; 2.7.1 Kinetic Equation of Ideal Solid State Polymerization; 2.7.2 Empirical Kinetic Equation of Real Solid State Polymerization; 2.8 Conclusions; 3 Kinetic Aspects of Polyester Solid State Polymerization; 3.1 Introduction; 3.2 Phenomena Involved in Solid State Polymerization of Polyesters; 3.2.1 Possible Reactions in Solid State Polymerization of Polyesters 3.2.2 Chain Mobility and Diffusion of Low-Molecular-Weight By-Products3.2.3 Kinetic and Diffusion Equations; 3.3 Modeling Solid State Polymerization of Polyesters; 3.3.1 Effects of Variables and Predictions Based on Kinetic Models; 3.4 Solid State Polymerization of Typical Polyesters; 3.4.1 Poly(ethylene terephthalate); 3.4.2 Poly(butylene terephthalate); 3.4.3 Poly(ethylene naphthalate); 3.4.4 Poly(trimethylene terephthalate); 3.4.5 Poly(L-lactic acid); 3.5 Conclusions; 4 Kinetic Aspects of Polyamide Solid State Polymerization; 4.1 Introduction 4.2 Simple Kinetic Models of Solid State Polyamidation |
| Record Nr. | UNINA-9910877040003321 |
|
Papaspyrides Constantine D
|
||
| Hoboken, NJ, : Wiley, c2009 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||