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Efficient preparations of fluorine compounds [[electronic resource] /] / edited by Herbert W. Roesky
| Efficient preparations of fluorine compounds [[electronic resource] /] / edited by Herbert W. Roesky |
| Pubbl/distr/stampa | Hoboken, N.J., : Wiley, 2013 |
| Descrizione fisica | 1 online resource (484 p.) |
| Disciplina | 546/.7312 |
| Altri autori (Persone) | RoeskyH. W |
| Soggetto topico | Fluorine compounds |
| ISBN |
1-118-40946-9
1-283-66495-X 1-118-40942-6 |
| Classificazione | SCI013030 |
| Formato | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto | Machine generated contents note: Foreword Preface Contributors 1 Preparation of Elemental Fluorine Karl O. Christe 2 Preparation of Highly Active Caesium Fluoride Konrad Seppelt 3 Preparation of Highly Active Silver Fluoride Konrad Seppelt 4 A Room Temperature, Non-Irradiative Synthesis of Xenon Difluoride (XeF2) Ulf Breddemann, John R. DeBackere, Gary J. Schrobilgen 5 Efficient Perfluorination of K2B12H12 in Neutralizing Acetonitrile Dmitry V. Peryshkov, Steven H. Strauss 6 Efficient Preparation of the Highly Soluble ortho- and para-C60(CF2C6F5)2 Derivatives Igor V. Kuvychko, Bryon W. Larson, Steven H. Strauss, and Olga V. Boltalina 7 Synthesis of Cs[1-H-CB11F11] Josef Michl 8 Synthesis of Zero-Valent Trifluoromethyl Chalcogenato Derivatives, [NMe4]ECF3 (E = S, Se, Te) and Related Compounds Wieland Tyrra, Silke Kremer 9 Synthesis Methods for Exotic Inorganic Fluorides with Varied Applications Dayal T. Meshri, N. C. Mathur, Ritesh R. Jain 10 Tris(pentafluorophenyl)boran, B(C6F5)3, a Powerful, Well-soluble, and Non-oxidizing Lewis Acid and the Weakly Coordinating Tetrakis(pentafluorophenyl)borate Anion, [B(C6F5)4]? Hermann-Josef Frohn 11 Pentafluorophenyldifluoroboran, C6F5BF2, and Pentafluorophenyltrifluorosilane, C6F5SiF3, Versatile Reagents for Fluorine/Pentafluorophenyl Substitution Reactions in Strongly Oxidizing Hypervalent Non-metal Fluorides Hermann-Josef Frohn 12 Iodine(III and V) Fluorides: Interesting Fluorinating Agents Hermann-Josef Frohn 13 Tetramethylammonium Fluoride, [N(CH3)4]F, a Widely Applicable Reagent to Introduce Fluoride Ions and a Suitable Nucleophile to Initiate the Transfer of Perfluoroorganyl Groups to Electrophiles Hermann-Josef Frohn 14 Preparation of Transition Metal Sulfide Fluorides Michael Gerken 15 Transition Metal Carbonyl Sulfur Dioxide and Thiazylfluoride Complexes: Reactions at the Metal Center and at the Ligand Rudiger Mews 16 Cesium-, Mercury- and Silver-Salts with Sulfur-Nitrogen-Fluorine Anions: Useful Transfer-Reagents for NSF-Building Blocks Rudiger Mews 17 Laboratory-Scale Synthesis of Gold Trifluoride and Uranium Hexafluoride Thomas M. Klapotke 18 Preparation of Transition Metal Fluorides using ClF3 Ralf Haiges 19 Preparation of Fluorine Containing Molecular Halides and Hetero polar Salts with Elements of Group 15 and Niobium and Tantalum Halides Lothar Kolditz 20 Fluoro- and Fluorohydroxy Complexes of As, Sb, and Sn Lothar Kolditz 21 Trifluoromethyl Compounds via Electrophilic and Nucleophilic Reactions Jeanne M. Shreeve 22 Introduction of Fluorine into Compounds via Electrophilic and Nucleophilic Reactions Jeanne M. Shreeve 23 The ?Real? Iodine and Bromine Mono-Fluorides Shlomo Rozen 24 The Versatile Chemistry of Acetyl Hypofluorite ? Hypofluorite not Bonded to Polyhaloalkyl group Shlomo Rozen 25 Direct Fluorination of Organic Compounds with Elemental Fluorine Shlomo Rozen 26 The Surprising Chemistry of Bromine Trifluoride Shlomo Rozen 27 Preparation of Silicon- and Sulfur-Based Fluorinated Methane Derivatives as Versatile Fluoromethylation Reagents G. K. Surya Prakash, Fang Wang 28 Pentafluoroethyl Lithium: Reactions with Carbonyl Compounds and Epoxides Gerd-Volker Roschenthaler 29 Synthesis of ?-hydroxy-[alpha],[alpha]-difluoromethylenephosphonates Gerd-Volker Roschenthaler 30 Synthesis of Pentafluoro-?6-sulfanyl Substituted Acetylenes for Liquid Crystals Gerd-Volker Roschenthaler 31 Delocalized Lipophilic Cations as a Source of Naked Fluoride and Phase-transfer Catalysts Gerd-Volker Roschenthaler 32 Methyltrifluoropyruvate Imines Possessing N-oxalyl and N-phosphonoformyl Groups ? Precursors to a Variety of [alpha]-CF3-[alpha]-amino Acid Derivatives Gerd-Volker Roschenthaler 33 Rhodium-mediated Synthesis of (3,3,3-Trifluoropropyl)trimethoxysilane and (3,3,3 trifluoropropyl)triphenylsilane Falk Wehmeier, Thomas Braun 34 Rhodium-mediated Synthesis of a Tetrafluoropyridyl-2-boronate Ester Michael Teltewskoi, Thomas Braun 35 Palladium-mediated Synthesis of 4-Vinyltetrafluoropyridine and 2,3,5,6-Tetrafluoropyridine David Breyer, Thomas Braun 36 Preparation of Polyfluoroaryl-1,2-difluorovinylsilanes Donald J. Burton, Ba V. Nguyen 37Preparation of (Z)-2-iodo-1,2-difluorostyrenes Donald J. Burton, Ling Xue 38 Preparation of 1,4-Bis(Z-2-iodo-1,2-difluoroethenyl)benzene Donald J. Burton, Craig A. Wesolowski 39Stereospecific Carboamidation Route to (Z)-N-Phenyl-2,3-difluoro-3-(triethylsilyl) acrylamide Donald J. Burton, Craig A. Wesolowski 40 Preparation of 2-Trifluoromethyl-3,3,3-trifluoropropanal Donald J. Burton, Donald A. Wiebe 41 Synthesis of Tetrafluorocatechol Sudharsanam Ramanathan, Dayong Sang, Vivek Kumar, David M. Lemal 42 Preparation of an Unsymmetrial Bis((perfluoroalkyl)sulfonyl)imide Darryl D. DesMarteau, Thomas D. Hickman 43 Preparation of Perfluoroalkyl Sulfilimines and Sulfoximines Emmanuel Magnier 44 Preparation of Trifluoromethylsulfonium Salts Emmanuel Magnier 45 Preparation of Organometallic Fluorides of Main Group and Transition Elements Herbert W. Roesky 46 Preparation of Pentafluorosulfanyl Carbonyl Compounds John T. Welch 47 Preparation of Power-variable Electrophilic Trifluoromethylating Agents, S-(Trifluoromethyl)dibenzothiophenium Salts Series Teruo Umemoto 48 Synthesis of Fluorine Containing Heterocycles from [alpha],[alpha]-Dihydropolyfluoroalkylsulfides and Fluorinated Thiocarboxylic Acids Vadim M. Timoshemko, Yuriy G.Shermolovich 49 Synthesis of Octafluorocyclooctatetraene John M. Buzby, Aldos C. Barefoot, III, Michael W. Grayston, Evan D. Laganis, Roy F. Waldron, David M. Lemal 50 Preparation of Fluoroolefins Moritz F. Kuhnel, Dieter Lentz 51 Preparation of Ionic Liquids of Fluorocomplex and Oxofluorocomplex Anions by Fluoroacid-base Reactions Kazuhiko Matsumoto, Rika Hagiwara 52 Synthesis of Difluorocyclopropyl Building Blocks: 2,2-Difluorocyclopropylmethanol and 2-(Bromomethyl)-1,1-Difluorocyclopropane Wei Xu, William R. Dolbier, Jr. 53 Preparation of 1,1,2,2,9,9,10,10-Octafluoro[2.2]paracyclophane and Perfluoro[2.2]paracyclophane William R. Dolbier, Jr., Jian-Xi Duan, Alex J. Roche, Lianhao Zhang 54 Efficient Preparation of Bioorganic Fluorine Compounds Xiao-Long Qiu 55 1,3-Dipolar Cycloaddition Reactions to Fluoroalkenes Hanna Wojtowicz-Rajchel, Henryk Koroniak 56 Synthesis of Fluorinated Vinyl Derivatives of Nucleic Acid Bases Hanna Wojtowicz-Rajchel, Donata Pluskota-Karwatka, Henryk Koroniak 57 Synthesis of CF3-substituted Aziridine Ring by the Gabriel Reaction Tomasz Cytlak, Bartosz Marciniak, Henryk Koroniak 58 Preparation of [alpha]-Fluoro Amino and [alpha]-Fluoro Enamino Reagents Henryk Koroniak, Justyna Walkowiak 59 Synthesis of Original Fluoromonomers and Their Radical copolymerization with Vinylidene fluoride Bruno Ameduri 60 Convergent 18F Radiosynthesis V. Gouverneur, O. Lozano 61 Asymmetric Fluorocyclization Reactions V. Gouverneur. O. Lozano 62 Preparation of Allylic Fluorides V. Gouverneur, O. Lozano 63 Dehydroxyfluorinations of Primary or Secondary Alcohols Using Perfluoro n-butylsulfonyl Fluoride (nonaflyl Fluoride, NfF) in Combination with 1,8-Diaza-bicyclo[5.4.0]undec-7-ene (DBU) Orlin Petrov, Matthias Schneider, Rolf Bohlmann, Stephan Vettel, Helmut Vorbruggen 64 Preparation of Rare Earth Fluorosulfides and Oxyfluorosulfides A. Demourgues, A.Tressaud 65 Preparation of Carbon-Fluorine Compounds and Fluoride or Oxide Fluoride-Intercalated Graphites Tsuyoshi Nakajima 66 Safe Synthesis of Superstoichiometric Mesoporous Fluorocarbons Valentin N. Mitkin 67 Preparation of Fluorinated ?-Alumina Erhard Kemnitz, Toma? Skapin, John M. Winfield Index. |
| Record Nr. | UNINA-9910141398103321 |
| Hoboken, N.J., : Wiley, 2013 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Efficient preparations of fluorine compounds / / edited by Herbert W. Roesky
| Efficient preparations of fluorine compounds / / edited by Herbert W. Roesky |
| Edizione | [1st ed.] |
| Pubbl/distr/stampa | Hoboken, N.J., : Wiley, 2013 |
| Descrizione fisica | 1 online resource (484 p.) |
| Disciplina | 546/.7312 |
| Altri autori (Persone) | RoeskyH. W |
| Soggetto topico | Fluorine compounds |
| ISBN |
1-118-40946-9
1-283-66495-X 1-118-40942-6 |
| Classificazione | SCI013030 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto | Machine generated contents note: Foreword Preface Contributors 1 Preparation of Elemental Fluorine Karl O. Christe 2 Preparation of Highly Active Caesium Fluoride Konrad Seppelt 3 Preparation of Highly Active Silver Fluoride Konrad Seppelt 4 A Room Temperature, Non-Irradiative Synthesis of Xenon Difluoride (XeF2) Ulf Breddemann, John R. DeBackere, Gary J. Schrobilgen 5 Efficient Perfluorination of K2B12H12 in Neutralizing Acetonitrile Dmitry V. Peryshkov, Steven H. Strauss 6 Efficient Preparation of the Highly Soluble ortho- and para-C60(CF2C6F5)2 Derivatives Igor V. Kuvychko, Bryon W. Larson, Steven H. Strauss, and Olga V. Boltalina 7 Synthesis of Cs[1-H-CB11F11] Josef Michl 8 Synthesis of Zero-Valent Trifluoromethyl Chalcogenato Derivatives, [NMe4]ECF3 (E = S, Se, Te) and Related Compounds Wieland Tyrra, Silke Kremer 9 Synthesis Methods for Exotic Inorganic Fluorides with Varied Applications Dayal T. Meshri, N. C. Mathur, Ritesh R. Jain 10 Tris(pentafluorophenyl)boran, B(C6F5)3, a Powerful, Well-soluble, and Non-oxidizing Lewis Acid and the Weakly Coordinating Tetrakis(pentafluorophenyl)borate Anion, [B(C6F5)4]? Hermann-Josef Frohn 11 Pentafluorophenyldifluoroboran, C6F5BF2, and Pentafluorophenyltrifluorosilane, C6F5SiF3, Versatile Reagents for Fluorine/Pentafluorophenyl Substitution Reactions in Strongly Oxidizing Hypervalent Non-metal Fluorides Hermann-Josef Frohn 12 Iodine(III and V) Fluorides: Interesting Fluorinating Agents Hermann-Josef Frohn 13 Tetramethylammonium Fluoride, [N(CH3)4]F, a Widely Applicable Reagent to Introduce Fluoride Ions and a Suitable Nucleophile to Initiate the Transfer of Perfluoroorganyl Groups to Electrophiles Hermann-Josef Frohn 14 Preparation of Transition Metal Sulfide Fluorides Michael Gerken 15 Transition Metal Carbonyl Sulfur Dioxide and Thiazylfluoride Complexes: Reactions at the Metal Center and at the Ligand Rudiger Mews 16 Cesium-, Mercury- and Silver-Salts with Sulfur-Nitrogen-Fluorine Anions: Useful Transfer-Reagents for NSF-Building Blocks Rudiger Mews 17 Laboratory-Scale Synthesis of Gold Trifluoride and Uranium Hexafluoride Thomas M. Klapotke 18 Preparation of Transition Metal Fluorides using ClF3 Ralf Haiges 19 Preparation of Fluorine Containing Molecular Halides and Hetero polar Salts with Elements of Group 15 and Niobium and Tantalum Halides Lothar Kolditz 20 Fluoro- and Fluorohydroxy Complexes of As, Sb, and Sn Lothar Kolditz 21 Trifluoromethyl Compounds via Electrophilic and Nucleophilic Reactions Jeanne M. Shreeve 22 Introduction of Fluorine into Compounds via Electrophilic and Nucleophilic Reactions Jeanne M. Shreeve 23 The ?Real? Iodine and Bromine Mono-Fluorides Shlomo Rozen 24 The Versatile Chemistry of Acetyl Hypofluorite ? Hypofluorite not Bonded to Polyhaloalkyl group Shlomo Rozen 25 Direct Fluorination of Organic Compounds with Elemental Fluorine Shlomo Rozen 26 The Surprising Chemistry of Bromine Trifluoride Shlomo Rozen 27 Preparation of Silicon- and Sulfur-Based Fluorinated Methane Derivatives as Versatile Fluoromethylation Reagents G. K. Surya Prakash, Fang Wang 28 Pentafluoroethyl Lithium: Reactions with Carbonyl Compounds and Epoxides Gerd-Volker Roschenthaler 29 Synthesis of ?-hydroxy-[alpha],[alpha]-difluoromethylenephosphonates Gerd-Volker Roschenthaler 30 Synthesis of Pentafluoro-?6-sulfanyl Substituted Acetylenes for Liquid Crystals Gerd-Volker Roschenthaler 31 Delocalized Lipophilic Cations as a Source of Naked Fluoride and Phase-transfer Catalysts Gerd-Volker Roschenthaler 32 Methyltrifluoropyruvate Imines Possessing N-oxalyl and N-phosphonoformyl Groups ? Precursors to a Variety of [alpha]-CF3-[alpha]-amino Acid Derivatives Gerd-Volker Roschenthaler 33 Rhodium-mediated Synthesis of (3,3,3-Trifluoropropyl)trimethoxysilane and (3,3,3 trifluoropropyl)triphenylsilane Falk Wehmeier, Thomas Braun 34 Rhodium-mediated Synthesis of a Tetrafluoropyridyl-2-boronate Ester Michael Teltewskoi, Thomas Braun 35 Palladium-mediated Synthesis of 4-Vinyltetrafluoropyridine and 2,3,5,6-Tetrafluoropyridine David Breyer, Thomas Braun 36 Preparation of Polyfluoroaryl-1,2-difluorovinylsilanes Donald J. Burton, Ba V. Nguyen 37Preparation of (Z)-2-iodo-1,2-difluorostyrenes Donald J. Burton, Ling Xue 38 Preparation of 1,4-Bis(Z-2-iodo-1,2-difluoroethenyl)benzene Donald J. Burton, Craig A. Wesolowski 39Stereospecific Carboamidation Route to (Z)-N-Phenyl-2,3-difluoro-3-(triethylsilyl) acrylamide Donald J. Burton, Craig A. Wesolowski 40 Preparation of 2-Trifluoromethyl-3,3,3-trifluoropropanal Donald J. Burton, Donald A. Wiebe 41 Synthesis of Tetrafluorocatechol Sudharsanam Ramanathan, Dayong Sang, Vivek Kumar, David M. Lemal 42 Preparation of an Unsymmetrial Bis((perfluoroalkyl)sulfonyl)imide Darryl D. DesMarteau, Thomas D. Hickman 43 Preparation of Perfluoroalkyl Sulfilimines and Sulfoximines Emmanuel Magnier 44 Preparation of Trifluoromethylsulfonium Salts Emmanuel Magnier 45 Preparation of Organometallic Fluorides of Main Group and Transition Elements Herbert W. Roesky 46 Preparation of Pentafluorosulfanyl Carbonyl Compounds John T. Welch 47 Preparation of Power-variable Electrophilic Trifluoromethylating Agents, S-(Trifluoromethyl)dibenzothiophenium Salts Series Teruo Umemoto 48 Synthesis of Fluorine Containing Heterocycles from [alpha],[alpha]-Dihydropolyfluoroalkylsulfides and Fluorinated Thiocarboxylic Acids Vadim M. Timoshemko, Yuriy G.Shermolovich 49 Synthesis of Octafluorocyclooctatetraene John M. Buzby, Aldos C. Barefoot, III, Michael W. Grayston, Evan D. Laganis, Roy F. Waldron, David M. Lemal 50 Preparation of Fluoroolefins Moritz F. Kuhnel, Dieter Lentz 51 Preparation of Ionic Liquids of Fluorocomplex and Oxofluorocomplex Anions by Fluoroacid-base Reactions Kazuhiko Matsumoto, Rika Hagiwara 52 Synthesis of Difluorocyclopropyl Building Blocks: 2,2-Difluorocyclopropylmethanol and 2-(Bromomethyl)-1,1-Difluorocyclopropane Wei Xu, William R. Dolbier, Jr. 53 Preparation of 1,1,2,2,9,9,10,10-Octafluoro[2.2]paracyclophane and Perfluoro[2.2]paracyclophane William R. Dolbier, Jr., Jian-Xi Duan, Alex J. Roche, Lianhao Zhang 54 Efficient Preparation of Bioorganic Fluorine Compounds Xiao-Long Qiu 55 1,3-Dipolar Cycloaddition Reactions to Fluoroalkenes Hanna Wojtowicz-Rajchel, Henryk Koroniak 56 Synthesis of Fluorinated Vinyl Derivatives of Nucleic Acid Bases Hanna Wojtowicz-Rajchel, Donata Pluskota-Karwatka, Henryk Koroniak 57 Synthesis of CF3-substituted Aziridine Ring by the Gabriel Reaction Tomasz Cytlak, Bartosz Marciniak, Henryk Koroniak 58 Preparation of [alpha]-Fluoro Amino and [alpha]-Fluoro Enamino Reagents Henryk Koroniak, Justyna Walkowiak 59 Synthesis of Original Fluoromonomers and Their Radical copolymerization with Vinylidene fluoride Bruno Ameduri 60 Convergent 18F Radiosynthesis V. Gouverneur, O. Lozano 61 Asymmetric Fluorocyclization Reactions V. Gouverneur. O. Lozano 62 Preparation of Allylic Fluorides V. Gouverneur, O. Lozano 63 Dehydroxyfluorinations of Primary or Secondary Alcohols Using Perfluoro n-butylsulfonyl Fluoride (nonaflyl Fluoride, NfF) in Combination with 1,8-Diaza-bicyclo[5.4.0]undec-7-ene (DBU) Orlin Petrov, Matthias Schneider, Rolf Bohlmann, Stephan Vettel, Helmut Vorbruggen 64 Preparation of Rare Earth Fluorosulfides and Oxyfluorosulfides A. Demourgues, A.Tressaud 65 Preparation of Carbon-Fluorine Compounds and Fluoride or Oxide Fluoride-Intercalated Graphites Tsuyoshi Nakajima 66 Safe Synthesis of Superstoichiometric Mesoporous Fluorocarbons Valentin N. Mitkin 67 Preparation of Fluorinated ?-Alumina Erhard Kemnitz, Toma? Skapin, John M. Winfield Index. |
| Record Nr. | UNINA-9910816262303321 |
| Hoboken, N.J., : Wiley, 2013 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Inorganic hydrazine derivatives : synthesis, properties, and applications / / edited by K. C. Patil and Tanu Mimani Rattan
| Inorganic hydrazine derivatives : synthesis, properties, and applications / / edited by K. C. Patil and Tanu Mimani Rattan |
| Edizione | [First edition.] |
| Pubbl/distr/stampa | West Sussex, England : , : John Wiley & Sons, , 2014 |
| Descrizione fisica | 1 online resource (286 p.) |
| Disciplina | 661 |
| Altri autori (Persone) |
PatilK. C
RattanTanu Mimani |
| Soggetto topico | Hydrazines - Industrial applications |
| ISBN |
1-118-69356-6
1-118-69359-0 1-118-69358-2 |
| Classificazione | SCI013030 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Inorganic Hydrazine Derivatives: Synthesis, Properties and Applications; Contents; List of Contributors; Foreword; Preface; Acknowledgements; 1 Hydrazine and Its Inorganic Derivatives; 1.1 Introduction; 1.1.1 Properties of Hydrazine; 1.1.1.1 Redox Properties; 1.1.2 Hydrazine versus Hydrazine Hydrate; 1.1.2.1 Reducing Property of Hydrazine Hydrate; 1.2 Inorganic Hydrazine Derivatives; 1.2.1 Hydrazine Salts; 1.2.1.1 Synthesis; 1.2.1.2 Structure - Single-Crystal X-Ray Studies; 1.2.2 Metal Hydrazines; 1.2.2.1 Synthesis; 1.2.2.2 Structure - Single-Crystal X-Ray Studies
1.2.3 Metal Hydrazine Carboxylates 1.2.3.1 Synthesis; 1.2.3.2 Structure - Single-Crystal X-Ray Studies; 1.2.4 Hydrazinium Metal Complexes; 1.2.4.1 Synthesis; 1.2.4.2 Structure - Single-Crystal X-Ray Studies; 1.3 Characterization of Inorganic Hydrazine Derivatives; 1.3.1 Analytical Techniques; 1.3.2 Spectroscopic Methods; 1.3.2.1 Infrared Spectroscopy; 1.3.2.2 X-Ray Methods; 1.3.3 Thermal Methods; 1.4 Applications of Inorganic Hydrazine Derivatives; References; 2 Hydrazine Salts; 2.1 Introduction; 2.2 Salts of the Monovalent Cation (N2H5+) - N2H5A 2.2.1 Simple Hydrazinium Salts (A- = F, Cl, Br, I, NO3, N3, VO3, HF2, HSO4, SCN, SO3NH2, COOCH3)2.2.1.1 Synthesis; 2.2.1.2 Infrared Spectra; 2.2.1.3 Thermal Properties; 2.2.2 Hydrazinium Salts with Oxidizing Anions - N2H5A (A- = N3, NO2, NO3, ClO4, etc.); 2.2.2.1 Synthesis; 2.2.2.2 Thermal Properties; 2.3 Salts of the Divalent Cation [(N2H5) 2+ and N2H6 2+]; 2.3.1 Dihydrazinium Salts (N2H5)2 2+) - [(N2H5)2B, B2-=SO3, SO4, C2O4, CO3, HPO4]; 2.3.1.1 Synthesis, Infrared Spectra, and Thermal Properties; 2.3.2 Hydrazonium Salts (N2H6 2+) - N2H6(A)2 or N2H6B 2.3.2.1 Synthesis, Infrared Spectra, and Thermal Properties 2.4 Salts of Monovalent (N2H5 +) and Divalent [(N2H5)2 2+ , N2H6 2+] Cations; 2.4.1 Hydrazine Fluorides - Hydrazinium Fluoride (N2H5F), Hydrazinium Bifluoride (N2H5HF2), and Hydrazonium Fluoride (N2H6F2); 2.4.1.1 Synthesis; 2.4.1.2 Infrared Spectra; 2.4.1.3 Thermal Properties; 2.4.2 Hydrazine Sulfates - Hydrazinium Bisulfate (N2H5HSO4), Dihydrazinium Sulfate [(N2H5)2SO4], and Hydrazonium Sulfate (N2H6SO4); 2.4.2.1 Synthesis; 2.4.2.2 Infrared Spectra; 2.4.2.3 Thermal Properties 2.4.3 Hydrazine Oxalates - Hydrazinium Hydrogen Oxalate (N2H5HC2O4) and Dihydrazinium Oxalate [(N2H5)2C2O4] 2.4.3.1 Synthesis; 2.4.3.2 Thermal Properties; 2.4.4 Hydrazine Phosphates - Monohydrazinium Phosphate (N2H5H2PO4) and Dihydrazinium Phosphate [(N2H5)2HPO4]; 2.4.4.1 Synthesis; 2.4.4.2 Thermal Properties; 2.4.5 Hydrazine Perchlorates - Hydrazinium Perchlorate (N2H5ClO4), Hydrazinium Perchlorate Monohydrate (N2H5ClO4H2O), Hydrazinium Perchlorate Hemihydrate (N2H5ClO40.5H2O), and Hydrazonium Perchlorate [N2H6(ClO4)2]; 2.4.5.1 Synthesis; 2.4.5.2 Infrared Spectra; 2.4.5.3 Thermal Properties 2.4.5.4 Nature of Water Present in Hydrazinium Perchlorate Hydrates, N2H5ClO40.5H2O and N2H6(ClO4)22H2O |
| Record Nr. | UNINA-9910138961303321 |
| West Sussex, England : , : John Wiley & Sons, , 2014 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Inorganic hydrazine derivatives : synthesis, properties, and applications / / edited by K. C. Patil and Tanu Mimani Rattan
| Inorganic hydrazine derivatives : synthesis, properties, and applications / / edited by K. C. Patil and Tanu Mimani Rattan |
| Edizione | [First edition.] |
| Pubbl/distr/stampa | West Sussex, England : , : John Wiley & Sons, , 2014 |
| Descrizione fisica | 1 online resource (286 p.) |
| Disciplina | 661 |
| Altri autori (Persone) |
PatilK. C
RattanTanu Mimani |
| Soggetto topico | Hydrazines - Industrial applications |
| ISBN |
1-118-69356-6
1-118-69359-0 1-118-69358-2 |
| Classificazione | SCI013030 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Inorganic Hydrazine Derivatives: Synthesis, Properties and Applications; Contents; List of Contributors; Foreword; Preface; Acknowledgements; 1 Hydrazine and Its Inorganic Derivatives; 1.1 Introduction; 1.1.1 Properties of Hydrazine; 1.1.1.1 Redox Properties; 1.1.2 Hydrazine versus Hydrazine Hydrate; 1.1.2.1 Reducing Property of Hydrazine Hydrate; 1.2 Inorganic Hydrazine Derivatives; 1.2.1 Hydrazine Salts; 1.2.1.1 Synthesis; 1.2.1.2 Structure - Single-Crystal X-Ray Studies; 1.2.2 Metal Hydrazines; 1.2.2.1 Synthesis; 1.2.2.2 Structure - Single-Crystal X-Ray Studies
1.2.3 Metal Hydrazine Carboxylates 1.2.3.1 Synthesis; 1.2.3.2 Structure - Single-Crystal X-Ray Studies; 1.2.4 Hydrazinium Metal Complexes; 1.2.4.1 Synthesis; 1.2.4.2 Structure - Single-Crystal X-Ray Studies; 1.3 Characterization of Inorganic Hydrazine Derivatives; 1.3.1 Analytical Techniques; 1.3.2 Spectroscopic Methods; 1.3.2.1 Infrared Spectroscopy; 1.3.2.2 X-Ray Methods; 1.3.3 Thermal Methods; 1.4 Applications of Inorganic Hydrazine Derivatives; References; 2 Hydrazine Salts; 2.1 Introduction; 2.2 Salts of the Monovalent Cation (N2H5+) - N2H5A 2.2.1 Simple Hydrazinium Salts (A- = F, Cl, Br, I, NO3, N3, VO3, HF2, HSO4, SCN, SO3NH2, COOCH3)2.2.1.1 Synthesis; 2.2.1.2 Infrared Spectra; 2.2.1.3 Thermal Properties; 2.2.2 Hydrazinium Salts with Oxidizing Anions - N2H5A (A- = N3, NO2, NO3, ClO4, etc.); 2.2.2.1 Synthesis; 2.2.2.2 Thermal Properties; 2.3 Salts of the Divalent Cation [(N2H5) 2+ and N2H6 2+]; 2.3.1 Dihydrazinium Salts (N2H5)2 2+) - [(N2H5)2B, B2-=SO3, SO4, C2O4, CO3, HPO4]; 2.3.1.1 Synthesis, Infrared Spectra, and Thermal Properties; 2.3.2 Hydrazonium Salts (N2H6 2+) - N2H6(A)2 or N2H6B 2.3.2.1 Synthesis, Infrared Spectra, and Thermal Properties 2.4 Salts of Monovalent (N2H5 +) and Divalent [(N2H5)2 2+ , N2H6 2+] Cations; 2.4.1 Hydrazine Fluorides - Hydrazinium Fluoride (N2H5F), Hydrazinium Bifluoride (N2H5HF2), and Hydrazonium Fluoride (N2H6F2); 2.4.1.1 Synthesis; 2.4.1.2 Infrared Spectra; 2.4.1.3 Thermal Properties; 2.4.2 Hydrazine Sulfates - Hydrazinium Bisulfate (N2H5HSO4), Dihydrazinium Sulfate [(N2H5)2SO4], and Hydrazonium Sulfate (N2H6SO4); 2.4.2.1 Synthesis; 2.4.2.2 Infrared Spectra; 2.4.2.3 Thermal Properties 2.4.3 Hydrazine Oxalates - Hydrazinium Hydrogen Oxalate (N2H5HC2O4) and Dihydrazinium Oxalate [(N2H5)2C2O4] 2.4.3.1 Synthesis; 2.4.3.2 Thermal Properties; 2.4.4 Hydrazine Phosphates - Monohydrazinium Phosphate (N2H5H2PO4) and Dihydrazinium Phosphate [(N2H5)2HPO4]; 2.4.4.1 Synthesis; 2.4.4.2 Thermal Properties; 2.4.5 Hydrazine Perchlorates - Hydrazinium Perchlorate (N2H5ClO4), Hydrazinium Perchlorate Monohydrate (N2H5ClO4H2O), Hydrazinium Perchlorate Hemihydrate (N2H5ClO40.5H2O), and Hydrazonium Perchlorate [N2H6(ClO4)2]; 2.4.5.1 Synthesis; 2.4.5.2 Infrared Spectra; 2.4.5.3 Thermal Properties 2.4.5.4 Nature of Water Present in Hydrazinium Perchlorate Hydrates, N2H5ClO40.5H2O and N2H6(ClO4)22H2O |
| Record Nr. | UNINA-9910824657203321 |
| West Sussex, England : , : John Wiley & Sons, , 2014 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Ionic interactions in natural and synthetic macromolecules [[electronic resource] /] / edited by Alberto Ciferri, Angelo Perico
| Ionic interactions in natural and synthetic macromolecules [[electronic resource] /] / edited by Alberto Ciferri, Angelo Perico |
| Pubbl/distr/stampa | Hoboken, NJ, : Wiley, c2012 |
| Descrizione fisica | 1 online resource (872 p.) |
| Disciplina | 547/.7045723 |
| Altri autori (Persone) |
CiferriA
PericoAngelo |
| Soggetto topico |
Macromolecules
Ion-ion collisions Supramolecular chemistry |
| ISBN |
1-283-40963-1
9786613409638 1-118-16584-5 1-118-16585-3 1-118-16586-1 |
| Classificazione | SCI013030 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto | Fundamentals -- Ion properties -- Yizhak Marcus -- Ionic interaction in supramolecular complexes -- Hans-Jörg Schnieder -- Polyelectrolyte fundamentals -- Angelo Perico -- Polyelectrolyte and polyampholyte effects in natural and synthetic macromolecules -- Ngo Minh Toan, Bae-Yeun Ha, and D. Thirumalai -- Modelling the structure and dynamics of polyelectrolyte multilayers -- Juan J. Cerda, Christian Holm, and Baofu Qioa -- Mixed Inteactions -- Ionic-mixed interactions and Hofmeister effects -- Alberto Ciferri -- Hydrophobic Polyelectrolytes -- Andre's F. Olea -- Association of polyelectrolytes to surfactants, and supramolecular assemblies -- Alberto Ciferri and Angelo Perico -- Ion transfer in and through charged membranes. Structure, properties, theory -- V. Nikonenko, A. B. Yaroslavtsev, and G. Pourcelly -- Reversible coordination polymers -- Kim de Lange, Jos M. J. Paulusse, Antonius T. M. Marcelis, and Han Zuilhof -- Structured and functional aspects of metal binding sites in natural and designed metalloproteins -- Ornella Maglio, Flavia Nastri, and Angela Lombardi |
| Record Nr. | UNINA-9910139296703321 |
| Hoboken, NJ, : Wiley, c2012 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Ionic interactions in natural and synthetic macromolecules / / edited by Alberto Ciferri, Angelo Perico
| Ionic interactions in natural and synthetic macromolecules / / edited by Alberto Ciferri, Angelo Perico |
| Edizione | [1st ed.] |
| Pubbl/distr/stampa | Hoboken, NJ, : Wiley, c2012 |
| Descrizione fisica | 1 online resource (872 p.) |
| Disciplina | 547/.7045723 |
| Altri autori (Persone) |
CiferriA
PericoAngelo |
| Soggetto topico |
Macromolecules
Ion-ion collisions Supramolecular chemistry |
| ISBN |
1-283-40963-1
9786613409638 1-118-16584-5 1-118-16585-3 1-118-16586-1 |
| Classificazione | SCI013030 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto | Fundamentals -- Ion properties -- Yizhak Marcus -- Ionic interaction in supramolecular complexes -- Hans-Jörg Schnieder -- Polyelectrolyte fundamentals -- Angelo Perico -- Polyelectrolyte and polyampholyte effects in natural and synthetic macromolecules -- Ngo Minh Toan, Bae-Yeun Ha, and D. Thirumalai -- Modelling the structure and dynamics of polyelectrolyte multilayers -- Juan J. Cerda, Christian Holm, and Baofu Qioa -- Mixed Inteactions -- Ionic-mixed interactions and Hofmeister effects -- Alberto Ciferri -- Hydrophobic Polyelectrolytes -- Andre's F. Olea -- Association of polyelectrolytes to surfactants, and supramolecular assemblies -- Alberto Ciferri and Angelo Perico -- Ion transfer in and through charged membranes. Structure, properties, theory -- V. Nikonenko, A. B. Yaroslavtsev, and G. Pourcelly -- Reversible coordination polymers -- Kim de Lange, Jos M. J. Paulusse, Antonius T. M. Marcelis, and Han Zuilhof -- Structured and functional aspects of metal binding sites in natural and designed metalloproteins -- Ornella Maglio, Flavia Nastri, and Angela Lombardi |
| Record Nr. | UNINA-9910827600103321 |
| Hoboken, NJ, : Wiley, c2012 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Spin-crossover materials [[electronic resource] ] : properties and applications / / edited by Malcolm A. Halcrow
| Spin-crossover materials [[electronic resource] ] : properties and applications / / edited by Malcolm A. Halcrow |
| Pubbl/distr/stampa | Chichester, : J. Wiley and Sons, Inc., 2013 |
| Descrizione fisica | 1 online resource (574 p.) |
| Disciplina | 621.381 |
| Altri autori (Persone) | HalcrowMalcolm A |
| Soggetto topico |
Spintronics - Materials
Nanostructured materials - Electric properties Nanostructured materials - Magnetic properties Electron paramagnetic resonance |
| ISBN |
1-118-51930-2
1-299-18864-8 1-118-51932-9 1-118-51931-0 |
| Classificazione | SCI013030 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto | Machine generated contents note: List of Contributors xv Preface xvii 1 The Development of Spin-Crossover Research 1 Keith S. Murray 1.1 Introduction 1 1.2 Discrete Clusters of SCO Compounds 4 1.3 1D Chains of FeII SCO Materials 22 1.4 1D Chains of FeIII SCO Materials 28 1.5 2D Sheets of FeII SCO Materials 29 1.6 3D Porous SCO Materials 30 1.7 Some Recent Developments in Mononuclear SCO FeII, FeIII and CoII Compounds 33 1.8 Multifunctional/Hybrid SCO Materials 37 1.9 Developments in Instrumental Methods in Spin-Crossover Measurements 40 1.10 Applications of Molecular Spin-Crossover Compounds 41 1.11 Summary 42 2 Novel Mononuclear Spin-Crossover Complexes 55 Birgit Weber 2.1 Introduction and General Considerations 55 2.2 Novel Coordination Numbers (CN), Coordination Geometries and Metal Centres 57 2.3 Iron Complexes with Novel Ligand Donor Atoms and New Ligand Systems 65 2.4 Other Examples 70 2.5 Conclusion and Outlook 72 3 Spin-Crossover in Discrete Polynuclear Complexes 77 Juan Olguin and Sally Brooker 3.1 Introduction 77 3.2 Dinuclear Iron(II) Complexes 79 3.3 Higher Nuclearity Iron(II) Compounds 98 3.4 Iron(III) 104 3.5 Cobalt(II) 109 3.6 Dinuclear Chromium(II) Complex 111 3.7 Concluding Remarks 112 4 Polymeric Spin-Crossover Materials 121 M. Carmen Munoz and Jose Antonio Real 4.1 Introduction 121 4.2 One-Dimensional SCO-CPs 121 4.3 Two-d = Dimensional SCO-CPs 128 4.4 Three-Dimensional SCO-CPs 133 4.5 Conclusion 138 5 Structure:Function Relationships in Molecular Spin-Crossover Materials 147 Malcolm A. Halcrow 5.1 Introduction 147 5.2 Molecular Shape 150 5.3 Crystal Packing 155 5.4 Cooperativity Mediated by Disorder 158 5.5 Compounds Showing Wide Thermal Hysteresis 158 5.6 Other Noteworthy Compounds 162 5.7 Conclusions 164 6 Charge Transfer-Induced Spin-Transitions in Cyanometallate Materials 171 Kim R. Dunbar, Catalina Achim and Michael Shatruk 6.1 Introduction 171 6.2 Characterization of CTIST Compounds 173 6.3 CTIST in Coordination Polymers 174 6.4 CTIST in Nanoscale Materials 189 6.5 CTIST in Polynuclear Transition Metal Complexes 195 6.6 Summary and Outlook 198 7 Valence Tautomeric Transitions in Cobalt-dioxolene Complexes 203 Colette Boskovic 7.1 Introduction 203 7.2 Induction of Valence Tautomeric Transitions 205 7.3 Other Factors that Contribute to the Valence Tautomeric Transition 210 7.4 Polynuclear Valence Tautomeric Complexes 214 7.5 Bifunctional Valence Tautomeric Complexes 218 7.6 Concluding Remarks 220 8 Reversible Spin Pairing in Crystalline Organic Radicals 225 Jeremy M. Rawson and John J. Hayward 8.1 Introduction 225 8.2 Radical Pairs: Solution and Gas Phase Studies 226 8.3 Dimerisation in the Solid State 229 8.4 Summary and Future Perspectives 234 9 Breathing Crystals from Copper Nitroxyl Complexes 239 Victor Ovcharenko and Elena Bagryanskaya 9.1 Introduction 239 9.2 Structural and Magnetic Anomalies 241 9.3 Relationship Between the Chemical Step and the Physical Property 245 9.4 Relationship Between the Thermally Induced Reorientation of Aromatic Solvate Molecules and the Character of the Magnetic Anomaly 251 9.5 EPR Study of Breathing Crystals 255 9.6 Classification of Spin-Transitions in Breathing Crystals and Correlations with Magnetic Susceptibility 261 9.7 The Detailed Magnetic Structure of Breathing Crystals 266 9.8 EPR-detected LIESST on Breathing Crystals 272 9.9 Conclusion 275 10 Spin-State Switching in Solution 281 Matthew P. Shores, Christina M. Klug and Stephanie R. Fiedler 10.1 Introduction and Scope 281 10.2 Spin-Crossover: Solid State Versus Solution 282 10.3 Practical Considerations 283 10.4 Spin-Crossover in Solution 285 10.5 Ligation Changes Driving Spin-State Switching in Solution 288 10.6 Second Coordination Sphere Triggers for Spin-State Switching 291 10.7 Challenges and Opportunities 294 10.8 Conclusions/Outlook 295 11 Multifunctional Materials Combining Spin-Crossover with Conductivity and Magnetic Ordering 303 Osamu Sato, Zhao-Yang Li, Zi-Shuo Yao, Soonchul Kang and Shinji Kanegawa 11.1 Introduction 303 11.2 Spin-Crossover and Conductivity: Spin-Crossover Conductors 303 11.3 Spin-Crossover and Magnetic Interaction: Spin-Crossover Magnets 308 12 Amphiphilic and Liquid Crystalline Spin-Crossover Complexes 321 Shinya Hayami 12.1 Introduction 321 12.2 Unique Magnetic Properties of SCO Cobalt(II) Compounds with Long Alkyl Chains 322 12.3 Liquid Crystalline SCO Compounds 325 12.4 Langmuir-Blodgett Films and Amphiphilic SCO Compounds 331 12.5 Conclusion and Outlook 339 13 Luminescent Spin-Crossover Materials 347 Helena J. Shepherd, Carlos M. Quintero, G℗þabor Molnar, Lionel Salmon and Azzedine Bousseksou 13.1 General Introduction 347 13.2 Introduction to Luminescent Materials and Luminescence Energy Transfer 348 13.3 Electronic Transitions and Optical Properties of Spin-Crossover Complexes 358 13.4 Materials with Combined Spin-Crossover and Luminescent Functionalities 361 13.5 Concluding Remarks 371 14 Nanoparticles, Thin Films and Surface Patterns from Spin-Crossover Materials and Electrical Spin State Control 375 Paulo Nuno Martinho, Cyril Rajnak and Mario Ruben 14.1 Introduction 375 14.2 Nanoparticles and Nanocrystals 376 14.3 Thin Films 387 14.4 Surface Patterns 393 14.5 Electrical Spin State Control 396 14.6 Conclusion 399 15 Ultrafast Studies of the Light-Induced Spin Change in Fe(II)-Polypyridine Complexes 405 Majed Chergui 15.1 Introduction 405 15.2 Properties of Fe(II) Complexes 406 15.3 From the Singlet to the Quintet State 408 15.4 Ultrafast X-Ray Studies 415 15.5 Summary and Outlook 417 16 Real-Time Observation of Spin-Transitions by Optical Microscopy 425 Francois Varret, Ahmed Slimani, Damien Garrot, Yann Garcia and Anil D. Naik 16.1 Introduction 425 16.2 Experimental Aspects 426 16.3 Selected Investigations 429 16.4 Conclusions and Prospects 439 17 Theoretical Prediction of Spin-Crossover at the Molecular Level 443 Robert J. Deeth, Christopher M. Handley and Benjamin J. Houghton 17.1 Introduction 443 17.2 Beginnings: Valence Bond and Ligand Field Theories 443 17.3 Quantum Chemistry 446 17.4 Empirical Methods 449 17.5 Conclusions 452 18 Theoretical Descriptions of Spin-Transitions in Bulk Lattices 455 Cristian, Enachescu, Masamichi Nishino and Seiji Miyashita 18.1 Introduction 455 18.2 Elastic Interaction Models for Spin-Crossover Systems 457 18.3 Mechano-Elastic Model 463 18.4 Conclusions 471 19 Optimizing the Stability of Trapped Metastable Spin States 475 Jean-Francois Letard, Guillaume Chastanet, Philippe Guionneau and Cedric Desplanches 19.1 Introduction 475 19.2 Light-Induced Excited Spin-State Trapping (LIESST) Effect 476 19.3 The T(LIESST) Approach: The Case of Mononuclear Compounds 479 19.4 The T(LIESST) Approach: An Extension to Polynuclear Iron(II) Complexes 487 19.5 Simulation and Extrapolation of a T(LIESST) Experiment 495 19.6 Conclusions 500 20 Piezo- and Photo-Crystallography Applied to Spin-Crossover Materials 507 Philippe Guionneau and Eric Collet 20.1 Introduction 507 20.2 Spin-Crossover and Piezo-Crystallography 507 20.3 Crystallography of Photoexcited SCO Materials 512 21 Spin-Transitions in Metal Oxides 527 Jean-Pascal RUEFF 21.1 Introduction 527 21.2 RIXS: A Probe of the 3d Electronic Properties 530 21.3 Experimental Results 533 21.4 Conclusions and Perspectives 538 References 540 Index. |
| Record Nr. | UNINA-9910141486803321 |
| Chichester, : J. Wiley and Sons, Inc., 2013 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Spin-crossover materials : properties and applications / / edited by Malcolm A. Halcrow
| Spin-crossover materials : properties and applications / / edited by Malcolm A. Halcrow |
| Edizione | [1st ed.] |
| Pubbl/distr/stampa | Chichester, : J. Wiley and Sons, Inc., 2013 |
| Descrizione fisica | 1 online resource (574 p.) |
| Disciplina | 621.381 |
| Altri autori (Persone) | HalcrowMalcolm A |
| Soggetto topico |
Spintronics - Materials
Nanostructured materials - Electric properties Nanostructured materials - Magnetic properties Electron paramagnetic resonance |
| ISBN |
1-118-51930-2
1-299-18864-8 1-118-51932-9 1-118-51931-0 |
| Classificazione | SCI013030 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto | Machine generated contents note: List of Contributors xv Preface xvii 1 The Development of Spin-Crossover Research 1 Keith S. Murray 1.1 Introduction 1 1.2 Discrete Clusters of SCO Compounds 4 1.3 1D Chains of FeII SCO Materials 22 1.4 1D Chains of FeIII SCO Materials 28 1.5 2D Sheets of FeII SCO Materials 29 1.6 3D Porous SCO Materials 30 1.7 Some Recent Developments in Mononuclear SCO FeII, FeIII and CoII Compounds 33 1.8 Multifunctional/Hybrid SCO Materials 37 1.9 Developments in Instrumental Methods in Spin-Crossover Measurements 40 1.10 Applications of Molecular Spin-Crossover Compounds 41 1.11 Summary 42 2 Novel Mononuclear Spin-Crossover Complexes 55 Birgit Weber 2.1 Introduction and General Considerations 55 2.2 Novel Coordination Numbers (CN), Coordination Geometries and Metal Centres 57 2.3 Iron Complexes with Novel Ligand Donor Atoms and New Ligand Systems 65 2.4 Other Examples 70 2.5 Conclusion and Outlook 72 3 Spin-Crossover in Discrete Polynuclear Complexes 77 Juan Olguin and Sally Brooker 3.1 Introduction 77 3.2 Dinuclear Iron(II) Complexes 79 3.3 Higher Nuclearity Iron(II) Compounds 98 3.4 Iron(III) 104 3.5 Cobalt(II) 109 3.6 Dinuclear Chromium(II) Complex 111 3.7 Concluding Remarks 112 4 Polymeric Spin-Crossover Materials 121 M. Carmen Munoz and Jose Antonio Real 4.1 Introduction 121 4.2 One-Dimensional SCO-CPs 121 4.3 Two-d = Dimensional SCO-CPs 128 4.4 Three-Dimensional SCO-CPs 133 4.5 Conclusion 138 5 Structure:Function Relationships in Molecular Spin-Crossover Materials 147 Malcolm A. Halcrow 5.1 Introduction 147 5.2 Molecular Shape 150 5.3 Crystal Packing 155 5.4 Cooperativity Mediated by Disorder 158 5.5 Compounds Showing Wide Thermal Hysteresis 158 5.6 Other Noteworthy Compounds 162 5.7 Conclusions 164 6 Charge Transfer-Induced Spin-Transitions in Cyanometallate Materials 171 Kim R. Dunbar, Catalina Achim and Michael Shatruk 6.1 Introduction 171 6.2 Characterization of CTIST Compounds 173 6.3 CTIST in Coordination Polymers 174 6.4 CTIST in Nanoscale Materials 189 6.5 CTIST in Polynuclear Transition Metal Complexes 195 6.6 Summary and Outlook 198 7 Valence Tautomeric Transitions in Cobalt-dioxolene Complexes 203 Colette Boskovic 7.1 Introduction 203 7.2 Induction of Valence Tautomeric Transitions 205 7.3 Other Factors that Contribute to the Valence Tautomeric Transition 210 7.4 Polynuclear Valence Tautomeric Complexes 214 7.5 Bifunctional Valence Tautomeric Complexes 218 7.6 Concluding Remarks 220 8 Reversible Spin Pairing in Crystalline Organic Radicals 225 Jeremy M. Rawson and John J. Hayward 8.1 Introduction 225 8.2 Radical Pairs: Solution and Gas Phase Studies 226 8.3 Dimerisation in the Solid State 229 8.4 Summary and Future Perspectives 234 9 Breathing Crystals from Copper Nitroxyl Complexes 239 Victor Ovcharenko and Elena Bagryanskaya 9.1 Introduction 239 9.2 Structural and Magnetic Anomalies 241 9.3 Relationship Between the Chemical Step and the Physical Property 245 9.4 Relationship Between the Thermally Induced Reorientation of Aromatic Solvate Molecules and the Character of the Magnetic Anomaly 251 9.5 EPR Study of Breathing Crystals 255 9.6 Classification of Spin-Transitions in Breathing Crystals and Correlations with Magnetic Susceptibility 261 9.7 The Detailed Magnetic Structure of Breathing Crystals 266 9.8 EPR-detected LIESST on Breathing Crystals 272 9.9 Conclusion 275 10 Spin-State Switching in Solution 281 Matthew P. Shores, Christina M. Klug and Stephanie R. Fiedler 10.1 Introduction and Scope 281 10.2 Spin-Crossover: Solid State Versus Solution 282 10.3 Practical Considerations 283 10.4 Spin-Crossover in Solution 285 10.5 Ligation Changes Driving Spin-State Switching in Solution 288 10.6 Second Coordination Sphere Triggers for Spin-State Switching 291 10.7 Challenges and Opportunities 294 10.8 Conclusions/Outlook 295 11 Multifunctional Materials Combining Spin-Crossover with Conductivity and Magnetic Ordering 303 Osamu Sato, Zhao-Yang Li, Zi-Shuo Yao, Soonchul Kang and Shinji Kanegawa 11.1 Introduction 303 11.2 Spin-Crossover and Conductivity: Spin-Crossover Conductors 303 11.3 Spin-Crossover and Magnetic Interaction: Spin-Crossover Magnets 308 12 Amphiphilic and Liquid Crystalline Spin-Crossover Complexes 321 Shinya Hayami 12.1 Introduction 321 12.2 Unique Magnetic Properties of SCO Cobalt(II) Compounds with Long Alkyl Chains 322 12.3 Liquid Crystalline SCO Compounds 325 12.4 Langmuir-Blodgett Films and Amphiphilic SCO Compounds 331 12.5 Conclusion and Outlook 339 13 Luminescent Spin-Crossover Materials 347 Helena J. Shepherd, Carlos M. Quintero, G℗þabor Molnar, Lionel Salmon and Azzedine Bousseksou 13.1 General Introduction 347 13.2 Introduction to Luminescent Materials and Luminescence Energy Transfer 348 13.3 Electronic Transitions and Optical Properties of Spin-Crossover Complexes 358 13.4 Materials with Combined Spin-Crossover and Luminescent Functionalities 361 13.5 Concluding Remarks 371 14 Nanoparticles, Thin Films and Surface Patterns from Spin-Crossover Materials and Electrical Spin State Control 375 Paulo Nuno Martinho, Cyril Rajnak and Mario Ruben 14.1 Introduction 375 14.2 Nanoparticles and Nanocrystals 376 14.3 Thin Films 387 14.4 Surface Patterns 393 14.5 Electrical Spin State Control 396 14.6 Conclusion 399 15 Ultrafast Studies of the Light-Induced Spin Change in Fe(II)-Polypyridine Complexes 405 Majed Chergui 15.1 Introduction 405 15.2 Properties of Fe(II) Complexes 406 15.3 From the Singlet to the Quintet State 408 15.4 Ultrafast X-Ray Studies 415 15.5 Summary and Outlook 417 16 Real-Time Observation of Spin-Transitions by Optical Microscopy 425 Francois Varret, Ahmed Slimani, Damien Garrot, Yann Garcia and Anil D. Naik 16.1 Introduction 425 16.2 Experimental Aspects 426 16.3 Selected Investigations 429 16.4 Conclusions and Prospects 439 17 Theoretical Prediction of Spin-Crossover at the Molecular Level 443 Robert J. Deeth, Christopher M. Handley and Benjamin J. Houghton 17.1 Introduction 443 17.2 Beginnings: Valence Bond and Ligand Field Theories 443 17.3 Quantum Chemistry 446 17.4 Empirical Methods 449 17.5 Conclusions 452 18 Theoretical Descriptions of Spin-Transitions in Bulk Lattices 455 Cristian, Enachescu, Masamichi Nishino and Seiji Miyashita 18.1 Introduction 455 18.2 Elastic Interaction Models for Spin-Crossover Systems 457 18.3 Mechano-Elastic Model 463 18.4 Conclusions 471 19 Optimizing the Stability of Trapped Metastable Spin States 475 Jean-Francois Letard, Guillaume Chastanet, Philippe Guionneau and Cedric Desplanches 19.1 Introduction 475 19.2 Light-Induced Excited Spin-State Trapping (LIESST) Effect 476 19.3 The T(LIESST) Approach: The Case of Mononuclear Compounds 479 19.4 The T(LIESST) Approach: An Extension to Polynuclear Iron(II) Complexes 487 19.5 Simulation and Extrapolation of a T(LIESST) Experiment 495 19.6 Conclusions 500 20 Piezo- and Photo-Crystallography Applied to Spin-Crossover Materials 507 Philippe Guionneau and Eric Collet 20.1 Introduction 507 20.2 Spin-Crossover and Piezo-Crystallography 507 20.3 Crystallography of Photoexcited SCO Materials 512 21 Spin-Transitions in Metal Oxides 527 Jean-Pascal RUEFF 21.1 Introduction 527 21.2 RIXS: A Probe of the 3d Electronic Properties 530 21.3 Experimental Results 533 21.4 Conclusions and Perspectives 538 References 540 Index. |
| Record Nr. | UNINA-9910826795203321 |
| Chichester, : J. Wiley and Sons, Inc., 2013 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||