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Physical chemistry of macromolecules : basic principles and issues / / S.F. Sun
Physical chemistry of macromolecules : basic principles and issues / / S.F. Sun
Autore Sun S. F.
Edizione [2nd ed]
Pubbl/distr/stampa Hoboken, N.J., : John Wiley & Sons, c2004
Descrizione fisica 1 online resource (583 p.)
Disciplina 547.7
547.7045
Soggetto topico Macromolecules
Chemistry, Physical organic
ISBN 1-280-54192-X
9786610541928
0-471-62356-3
0-471-62357-1
Classificazione 431.9
547/.7045
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione und
Nota di contenuto PHYSICAL CHEMISTRY OF MACROMOLECULES Second Edition; CONTENTS; Preface to the Second Edition; Preface to the First Edition; 1 Introduction; 1.1 Colloids; 1.2 Macromolecules; 1.2.1 Synthetic Polymers; 1.2.2 Biological Polymers; 1.3 Macromolecular Science; References; 2 Syntheses of Macromolecular Compounds; 2.1 Radical Polymerization; 2.1.1 Complications; 2.1.2 Methods of Free-Radical Polymerization; 2.1.3 Some Well-Known Overall Reactions of Addition Polymers; 2.2 Ionic Polymerization; 2.2.1 Anionic Polymerization; 2.2.2 Cationic Polymerization; 2.2.3 Living Polymers
2.3 Coordination Polymerization2.4 Stepwise Polymerization; 2.5 Kinetics of the Syntheses of Polymers; 2.5.1 Condensation Reactions; 2.5.2 Chain Reactions; 2.6 Polypeptide Synthesis; 2.6.1 Synthesis of Insulin; 2.6.2 Synthesis of Ribonucleus; 2.7 DNA Synthesis; References; Problems; 3 Distribution of Molecular Weight; 3.1 Review of Mathematical Statistics; 3.1.1 Binomial Distribution; 3.1.2 Poisson Distribution; 3.1.3 Gaussian Distribution; 3.2 One-Parameter Equation; 3.2.1 Condensation Polymers; 3.2.2 Addition Polymers; 3.3 Two-Parameter Equations; 3.3.1 Normal Distribution
3.3.2 Logarithm Normal Distribution3.4 Types of Molecular Weight; 3.5 Experimental Methods for Determining Molecular Weight and Molecular Weight Distribution; References; Problems; 4 Macromolecular Thermodynamics; 4.1 Review of Thermodynamics; 4.2 DS of Mixing: Flory Theory; 4.3 DH of Mixing; 4.3.1 Cohesive Energy Density; 4.3.2 Contact Energy (First-Neighbor Interaction or Energy Due to Contact); 4.4 DG of Mixing; 4.5 Partial Molar Quantities; 4.5.1 Partial Specific Volume; 4.5.2 Chemical Potential; 4.6 Thermodynamics of Dilute Polymer Solutions; 4.6.1 Vapor Pressure; 4.6.2 Phase Equilibrium
Appendix: Thermodynamics and Critical PhenomenaReferences; Problems; 5 Chain Configurations; 5.1 Preliminary Descriptions of a Polymer Chain; 5.2 Random Walk and the Markov Process; 5.2.1 Random Walk; 5.2.2 Markov Chain; 5.3 Random-Flight Chains; 5.4 Wormlike Chains; 5.5 Flory's Mean-Field Theory; 5.6 Perturbation Theory; 5.6.1 First-Order Perturbation Theory; 5.6.2 Cluster Expansion Method; 5.7 Chain Crossover and Chain Entanglement; 5.7.1 Concentration Effect; 5.7.2 Temperature Effect; 5.7.3 Tube Theory (Reptation Theory); 5.7.4 Images of Individual Polymer Chains
5.8 Scaling and UniversalityAppendix A Scaling Concepts; Appendix B Correlation Function; References; Problems; 6 Liquid Crystals; 6.1 Mesogens; 6.2 Polymeric Liquid Crystals; 6.2.1 Low-Molecular Weight Liquid Crystals; 6.2.2 Main-Chain Liquid-Crystalline Polymers; 6.2.3 Side-Chain Liquid-Crystalline Polymers; 6.2.4 Segmented-Chain Liquid-Crystalline Polymers; 6.3 Shapes of Mesogens; 6.4 Liquid-Crystal Phases; 6.4.1 Mesophases in General; 6.4.2 Nematic Phase; 6.4.3 Smectic Phase; 6.4.3.1 Smectic A and C; 6.4.4 Compounds Representing Some Mesophases; 6.4.5 Shape and Phase
6.4.6 Decreasing Order and DH of Phase Transition
Record Nr. UNINA-9910830788603321
Sun S. F.  
Hoboken, N.J., : John Wiley & Sons, c2004
Materiale a stampa
Lo trovi qui: Univ. Federico II
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Physical chemistry of macromolecules : basic principles and issues / / S.F. Sun
Physical chemistry of macromolecules : basic principles and issues / / S.F. Sun
Autore Sun S. F.
Edizione [2nd ed]
Pubbl/distr/stampa Hoboken, N.J., : John Wiley & Sons, c2004
Descrizione fisica 1 online resource (583 p.)
Disciplina 547.7
547.7045
Soggetto topico Macromolecules
Chemistry, Physical organic
ISBN 1-280-54192-X
9786610541928
0-471-62356-3
0-471-62357-1
Classificazione 431.9
547/.7045
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione und
Nota di contenuto PHYSICAL CHEMISTRY OF MACROMOLECULES Second Edition; CONTENTS; Preface to the Second Edition; Preface to the First Edition; 1 Introduction; 1.1 Colloids; 1.2 Macromolecules; 1.2.1 Synthetic Polymers; 1.2.2 Biological Polymers; 1.3 Macromolecular Science; References; 2 Syntheses of Macromolecular Compounds; 2.1 Radical Polymerization; 2.1.1 Complications; 2.1.2 Methods of Free-Radical Polymerization; 2.1.3 Some Well-Known Overall Reactions of Addition Polymers; 2.2 Ionic Polymerization; 2.2.1 Anionic Polymerization; 2.2.2 Cationic Polymerization; 2.2.3 Living Polymers
2.3 Coordination Polymerization2.4 Stepwise Polymerization; 2.5 Kinetics of the Syntheses of Polymers; 2.5.1 Condensation Reactions; 2.5.2 Chain Reactions; 2.6 Polypeptide Synthesis; 2.6.1 Synthesis of Insulin; 2.6.2 Synthesis of Ribonucleus; 2.7 DNA Synthesis; References; Problems; 3 Distribution of Molecular Weight; 3.1 Review of Mathematical Statistics; 3.1.1 Binomial Distribution; 3.1.2 Poisson Distribution; 3.1.3 Gaussian Distribution; 3.2 One-Parameter Equation; 3.2.1 Condensation Polymers; 3.2.2 Addition Polymers; 3.3 Two-Parameter Equations; 3.3.1 Normal Distribution
3.3.2 Logarithm Normal Distribution3.4 Types of Molecular Weight; 3.5 Experimental Methods for Determining Molecular Weight and Molecular Weight Distribution; References; Problems; 4 Macromolecular Thermodynamics; 4.1 Review of Thermodynamics; 4.2 DS of Mixing: Flory Theory; 4.3 DH of Mixing; 4.3.1 Cohesive Energy Density; 4.3.2 Contact Energy (First-Neighbor Interaction or Energy Due to Contact); 4.4 DG of Mixing; 4.5 Partial Molar Quantities; 4.5.1 Partial Specific Volume; 4.5.2 Chemical Potential; 4.6 Thermodynamics of Dilute Polymer Solutions; 4.6.1 Vapor Pressure; 4.6.2 Phase Equilibrium
Appendix: Thermodynamics and Critical PhenomenaReferences; Problems; 5 Chain Configurations; 5.1 Preliminary Descriptions of a Polymer Chain; 5.2 Random Walk and the Markov Process; 5.2.1 Random Walk; 5.2.2 Markov Chain; 5.3 Random-Flight Chains; 5.4 Wormlike Chains; 5.5 Flory's Mean-Field Theory; 5.6 Perturbation Theory; 5.6.1 First-Order Perturbation Theory; 5.6.2 Cluster Expansion Method; 5.7 Chain Crossover and Chain Entanglement; 5.7.1 Concentration Effect; 5.7.2 Temperature Effect; 5.7.3 Tube Theory (Reptation Theory); 5.7.4 Images of Individual Polymer Chains
5.8 Scaling and UniversalityAppendix A Scaling Concepts; Appendix B Correlation Function; References; Problems; 6 Liquid Crystals; 6.1 Mesogens; 6.2 Polymeric Liquid Crystals; 6.2.1 Low-Molecular Weight Liquid Crystals; 6.2.2 Main-Chain Liquid-Crystalline Polymers; 6.2.3 Side-Chain Liquid-Crystalline Polymers; 6.2.4 Segmented-Chain Liquid-Crystalline Polymers; 6.3 Shapes of Mesogens; 6.4 Liquid-Crystal Phases; 6.4.1 Mesophases in General; 6.4.2 Nematic Phase; 6.4.3 Smectic Phase; 6.4.3.1 Smectic A and C; 6.4.4 Compounds Representing Some Mesophases; 6.4.5 Shape and Phase
6.4.6 Decreasing Order and DH of Phase Transition
Record Nr. UNINA-9910877433203321
Sun S. F.  
Hoboken, N.J., : John Wiley & Sons, c2004
Materiale a stampa
Lo trovi qui: Univ. Federico II
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Principles of polymerization / / George Odian
Principles of polymerization / / George Odian
Autore Odian George
Edizione [4th ed]
Pubbl/distr/stampa Hoboken, N.J., : Wiley, c2004
Descrizione fisica 1 online resource (838 p.)
Disciplina 547.28
Soggetto topico Polymerization
ISBN 1-280-34490-3
9786610344901
0-470-35149-7
0-471-47874-1
0-471-47875-X
Classificazione 431.9
434.5
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione und
Nota di contenuto PRINCIPLES OF POLYMERIZATION Fourth Edition; CONTENTS; PREFACE; 1 INTRODUCTION; 1-1 Types of Polymers and Polymerizations; 1-1a Polymer Composition and Structure; 1-1b Polymerization Mechanism; 1-2 Nomenclature of Polymers; 1-2a Nomenclature Based on Source; 1-2b Nomenclature Based on Structure (Non-IUPAC); 1-2c IUPAC Structure-Based Nomenclature System; 1-2d Trade Names and Nonnames; 1-3 Linear, Branched, and Crosslinked Polymers; 1-4 Molecular Weight; 1-5 Physical State; 1-5a Crystalline and Amorphous Behavior; 1-5b Determinants of Polymer Crystallinity; 1-5c Thermal Transitions
1-6 Applications of Polymers1-6a Mechanical Properties; 1-6b Elastomers, Fibers, and Plastics; References; 2 STEP POLYMERIZATION; 2-1 Reactivity of Functional Groups; 2-1a Basis for Analysis of Polymerization Kinetics; 2-1b Experimental Evidence; 2-1c Theoretical Considerations; 2-1d Equivalence of Groups in Bifunctional Reactants; 2-2 Kinetics of Step Polymerization; 2-2a Self-Catalyzed Polymerization; 2-2a-1 Experimental Observations; 2-2a-2 Reasons for Nonlinearity in Third-Order Plot; 2-2a-3 Molecular Weight of Polymer; 2-2b External Catalysis of Polymerization
2-2c Step Polymerizations Other than Polyesterification: Catalyzed versus Uncatalyzed2-2d Nonequivalence of Functional Groups in Polyfunctional Reagents; 2-2d-1 Examples of Nonequivalence; 2-2d-2 Kinetics; 2-3 Accessibility of Functional Groups; 2-4 Equilibrium Considerations; 2-4a Closed System; 2-4b Open, Driven System; 2-4c Kinetics of Reversible Polymerization; 2-5 Cyclization versus Linear Polymerization; 2-5a Possible Cyclization Reactions; 2-5b Cyclization Tendency versus Ring Size; 2-5c Reaction Conditions; 2-5d Thermodynamic versus Kinetic Control; 2-5e Other Considerations
2-6 Molecular Weight Control in Linear Polymerization2-6a Need for Stoichiometric Control; 2-6b Quantitative Aspects; 2-6c Kinetics of Nonstoichiometric Polymerization; 2-7 Molecular Weight Distribution in Linear Polymerization; 2-7a Derivation of Size Distributions; 2-7b Breadth of Molecular Weight Distribution; 2-7c Interchange Reactions; 2-7d Alternate Approaches for Molecular-Weight Distribution; 2-7e Effect of Reaction Variables on MWD; 2-7e-1 Unequal Reactivity of Functional Groups; 2-7e-2 Change in Reactivity on Reaction; 2-7e-3 Nonstoichiometry of Functional Groups
2-8 Process Conditions2-8a Physical Nature of Polymerization Systems; 2-8b Different Reactant Systems; 2-8c Interfacial Polymerization; 2-8c-1 Description of Process; 2-8c-2 Utility; 2-8d Polyesters; 2-8e Polycarbonates; 2-8f Polyamides; 2-8g Historical Aspects; 2-9 Multichain Polymerization; 2-9a Branching; 2-9b Molecular Weight Distribution; 2-10 Crosslinking; 2-10a Carothers Equation: X(n); 2-10a-1 Stoichiometric Amounts of Reactants; 2-10a-2 Extension to Nonstoichiometric Reactant Mixtures; 2-10b Statistical Approach to Gelation: X(w); 2-10c Experimental Gel Points
2-10d Extensions of Statistical Approach
Record Nr. UNINA-9910830743703321
Odian George  
Hoboken, N.J., : Wiley, c2004
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Principles of polymerization / / George Odian
Principles of polymerization / / George Odian
Autore Odian George
Edizione [4th ed]
Pubbl/distr/stampa Hoboken, N.J., : Wiley, c2004
Descrizione fisica 1 online resource (838 p.)
Disciplina 547.28
Soggetto topico Polymerization
ISBN 1-280-34490-3
9786610344901
0-470-35149-7
0-471-47874-1
0-471-47875-X
Classificazione 431.9
434.5
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto PRINCIPLES OF POLYMERIZATION Fourth Edition; CONTENTS; PREFACE; 1 INTRODUCTION; 1-1 Types of Polymers and Polymerizations; 1-1a Polymer Composition and Structure; 1-1b Polymerization Mechanism; 1-2 Nomenclature of Polymers; 1-2a Nomenclature Based on Source; 1-2b Nomenclature Based on Structure (Non-IUPAC); 1-2c IUPAC Structure-Based Nomenclature System; 1-2d Trade Names and Nonnames; 1-3 Linear, Branched, and Crosslinked Polymers; 1-4 Molecular Weight; 1-5 Physical State; 1-5a Crystalline and Amorphous Behavior; 1-5b Determinants of Polymer Crystallinity; 1-5c Thermal Transitions
1-6 Applications of Polymers1-6a Mechanical Properties; 1-6b Elastomers, Fibers, and Plastics; References; 2 STEP POLYMERIZATION; 2-1 Reactivity of Functional Groups; 2-1a Basis for Analysis of Polymerization Kinetics; 2-1b Experimental Evidence; 2-1c Theoretical Considerations; 2-1d Equivalence of Groups in Bifunctional Reactants; 2-2 Kinetics of Step Polymerization; 2-2a Self-Catalyzed Polymerization; 2-2a-1 Experimental Observations; 2-2a-2 Reasons for Nonlinearity in Third-Order Plot; 2-2a-3 Molecular Weight of Polymer; 2-2b External Catalysis of Polymerization
2-2c Step Polymerizations Other than Polyesterification: Catalyzed versus Uncatalyzed2-2d Nonequivalence of Functional Groups in Polyfunctional Reagents; 2-2d-1 Examples of Nonequivalence; 2-2d-2 Kinetics; 2-3 Accessibility of Functional Groups; 2-4 Equilibrium Considerations; 2-4a Closed System; 2-4b Open, Driven System; 2-4c Kinetics of Reversible Polymerization; 2-5 Cyclization versus Linear Polymerization; 2-5a Possible Cyclization Reactions; 2-5b Cyclization Tendency versus Ring Size; 2-5c Reaction Conditions; 2-5d Thermodynamic versus Kinetic Control; 2-5e Other Considerations
2-6 Molecular Weight Control in Linear Polymerization2-6a Need for Stoichiometric Control; 2-6b Quantitative Aspects; 2-6c Kinetics of Nonstoichiometric Polymerization; 2-7 Molecular Weight Distribution in Linear Polymerization; 2-7a Derivation of Size Distributions; 2-7b Breadth of Molecular Weight Distribution; 2-7c Interchange Reactions; 2-7d Alternate Approaches for Molecular-Weight Distribution; 2-7e Effect of Reaction Variables on MWD; 2-7e-1 Unequal Reactivity of Functional Groups; 2-7e-2 Change in Reactivity on Reaction; 2-7e-3 Nonstoichiometry of Functional Groups
2-8 Process Conditions2-8a Physical Nature of Polymerization Systems; 2-8b Different Reactant Systems; 2-8c Interfacial Polymerization; 2-8c-1 Description of Process; 2-8c-2 Utility; 2-8d Polyesters; 2-8e Polycarbonates; 2-8f Polyamides; 2-8g Historical Aspects; 2-9 Multichain Polymerization; 2-9a Branching; 2-9b Molecular Weight Distribution; 2-10 Crosslinking; 2-10a Carothers Equation: X(n); 2-10a-1 Stoichiometric Amounts of Reactants; 2-10a-2 Extension to Nonstoichiometric Reactant Mixtures; 2-10b Statistical Approach to Gelation: X(w); 2-10c Experimental Gel Points
2-10d Extensions of Statistical Approach
Record Nr. UNINA-9910877312603321
Odian George  
Hoboken, N.J., : Wiley, c2004
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
高分子集合体の形成と性質 / / 高分子学会編
高分子集合体の形成と性質 / / 高分子学会編
Autore 高分子学会
Pubbl/distr/stampa 東京, : 共立出版, 1993.5
Descrizione fisica オンライン資料1件
Collana 高分子機能材料シリーズ / 高分子学会編
Soggetto topico 高分子化学
高分子材料
ISBN 4-320-98114-6
Classificazione 431.9
578
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione jpn
Nota di contenuto 表紙 -- 編集委員 -- 「高分子機能材料」シリーズ 発刊にあたって -- まえがき -- 目次 -- 序論 -- 第1章 高分子コンプレックス -- 1.1 コンプレックス形成の基礎 -- A.高分子集合体の特徴 -- B.コンプレックス形成のダイナミックス -- 1.2 合成高分子コンプレックス -- A.高分子間に働く相互作用力 -- B.高分子コンプレックス(Ⅰ)イオン結合系 -- C.高分子コンプレックス(Ⅱ)水素結合系 -- D.高分子コンプレックス(Ⅲ) -- 1.3 天然高分子コンプレックス -- A.集合体形成 -- B.タンパク質間コンプレックス -- C.多糖類とコンプレックス形成 -- D.核とコンプレックス形成 -- 文献 -- 第2章 高分子ゲル -- 2.1 高分子ゲルの形成と性質 -- A.ゲルの分類 -- B.ゲル網目の評価法 -- C.ゲルの動的性質 -- D.ゲルの網目と溶媒の相互作用 -- E.ゲルの機能性 -- 2.2 ゲル化 -- A.ゲル化過程の理論的取り扱い -- B.ゲルの相転移 -- C.ゲル構造のキャラクタリゼーション -- 2.3 天然高分子ゲル -- A.天然高分子試料精製およびゲルの作製法 -- B.天然高分子ゲルの構造と物性 -- 2.4 合成高分子ゲル -- A.高分子ゲルの合成 -- B.合成高分子ゲルの相転移現象 -- C.合成高分子電解質ゲルとpHおよび塩 -- D.熱応答性ゲルの合成とその物性 -- E.両性ゲル -- F.二官能型リン酸ゲルの合成と膨潤特性 -- 文献 -- 第3章 高分子分散系 -- 3.1 分散系の基礎 -- A.表面(界面)エネルギーと分散系の熱力学 -- B.電気二重層と界面動電現象 -- C.D.L.V.O.理論と分散系の安定性 -- D.高分子の吸着と分散・凝集作用 -- E.表面間力の直接測定 -- 3.2 高分子コロイド -- A.高分子ミクロスフェアと高分子コロイド -- B.高分子ミクロスフェア・コロイドの作製法 -- C.高分子ミクロスフェアの構造 -- D.高分子コロイドの特性 -- 3.3 高分子カプセル -- A.高分子カプセルの概念 -- B.作成法 -- C.性質 -- D.他物質との相互作用 -- E.将来展望 -- 3.4 分散系のレオロジー -- A.流動特性 -- B.動的特性 -- C.構造変化を伴う流動 -- D.固体(結晶)構造を持つ分散系 -- 文献 -- 第4章 高分子液晶 -- 4.1 高分子液晶の基礎 -- A.棒状分子液体の等方-異方相転移-その分子的構造- -- B.フランク弾性定数 -- C.コレステリック相 -- D.スメクティック相と柱状相 -- E.屈曲性高分子の液晶相転移 -- 4.2 液晶性を示す高分子 -- A.液晶高分子の合成 -- B.高機能性材料としての液晶高分子 -- 4.3 液晶の高次構造と相転移挙動 -- A.相転移挙動および液晶構造に見られる偶奇効果 -- B.多彩な液晶種とその構造・物性 -- 4.4 液晶のレオロジー -- A.低分子液晶のレオロジー概観 -- B.高分子液晶のレオロジー -- C.高分子液晶の変形機構と流動中の構造 -- D.サーモトロピック液晶高分子とサーモトロピック高分子液晶のレオロジー挙動 -- E.高分子液晶の特異なレオロジー挙動 -- 文献 -- 第5章 有機薄膜 -- 5.1 LB薄膜 -- A.単分子膜の構造 -- B.単分子膜の粘弾的特性 -- C.単分子膜の凝集状態 -- D.LB膜の構築と構造欠陥の評価 -- E.LB膜の重合特性と表面構造の固定化 -- F.高分子/人工脂質複合系の表面状態と機能化 -- 5.2 真空蒸着薄膜 -- A.蒸発特性 -- B.付着特性 -- C.核形成 -- D.分子配列特性 -- E.高分子の蒸着 -- F.蒸着重合による高分子薄膜 -- 5.3 プラズマ重合薄膜 -- A.プラズマ重合膜作成法 -- 文献 -- 第6章 表面,薄膜特性解析 -- 6.1 解析手段の進歩 -- 6.2 X線解析 -- A.X線の性質 -- B.X線回折装置の原理 -- C.薄膜X線回折法 -- D.測定法 -- 6.3 X線光電子分光およびその周辺技術 -- A.X線光電子分光の原理 -- B.表面・界面の測定 -- C.X線光電子分光の周辺技術.
6.4 電子線回折 -- A.電子線回折法の原理 -- B.電子線回折による有機薄膜の構造評価 -- C.有機超薄膜のエピタキシャル成長性の検討 -- D.電子線回折による評価の今後の課題 -- 6.5 トンネル顕微鏡 -- A.STMの原理と高分子への応用 -- B.FI-STMの原理 -- C.AFM原理と高分子への応用 -- 6.6 振動分光法 -- A.赤外スペクトル -- B.ラマンスペクトル -- 6.7 エリプソメトリー -- A.エリプソメトリーの原理 -- B.エリプソメトリーの応用 -- C.エリプソメトリーにおける注意 -- 6.8 超音波顕微鏡 -- A.超音波の性質 -- B.超音波顕微鏡における画像形成 -- C.表面の異方性の評価 -- 6.9 蛍光顕微鏡 -- A.蛍光顕微鏡の原理 -- B.蛍光顕微鏡の構造 -- C.単分子膜の観察 -- 6.10 画像解析 -- A.画像解析システム -- B.モルフォロジー解析用画像処理 -- C.高分子系における空間パターン解析への応用 -- 文献 -- 索引 -- 奥付.
Record Nr. UNINA-9910149143003321
高分子学会  
東京, : 共立出版, 1993.5
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui