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Amino group chemistry : from synthesis to the life sciences / / edited by Alfredo Ricci
| Amino group chemistry : from synthesis to the life sciences / / edited by Alfredo Ricci |
| Pubbl/distr/stampa | Weinheim, [Germany] : , : Wiley-VCH Verlag GmbH & Co. KGaA, , 2008 |
| Descrizione fisica | 1 online resource (410 p.) |
| Disciplina |
547.042
572/.65 |
| Soggetto topico | Amino acids |
| Soggetto genere / forma | Electronic books. |
| ISBN |
1-282-78423-4
9786612784231 3-527-62126-1 3-527-62127-X |
| Classificazione | 35.62 |
| Formato | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | ger |
| Nota di contenuto |
Amino Group Chemistry; Contents; Preface; List of Contributors; 1 Simple Molecules, Highly Efficient Amination; 1.1 Introduction; 1.2 Hydroxylamine Derivatives; 1.2.1 O-Sulfonylhydroxylamine; 1.2.2 O-Phosphinylhydroxylamine; 1.2.3 O-Acylhydroxylamine; 1.2.4 O-Trimethylsilylhydroxylamine; 1.2.5 Experimental Procedures; 1.3 Oxime Derivatives; 1.3.1 Synthesis of Primary Amines by Electrophilic Amination of Carbanions; 1.3.2 Experimental Procedures; 1.4 Azo Compounds; 1.4.1 Azodicarboxylates; 1.4.1.1 Allylic Amination through Ene-Type Reactions; 1.4.1.2 Hydrohydrazination of Alkenes
1.4.2 Arylazo Sulfones1.4.3 Experimental Procedures; 1.5 Oxaziridine Derivatives; 1.5.1 Electrophilic Amination of Carbon Nucleophiles; 1.5.2 Amination of Allylic and Propargylic Sulfides by Use of a Ketomalonate-Derived Oxaziridine; 1.5.3 Experimental Procedures; 1.6 Chloramine-T; 1.6.1 Aminochalcogenation of Alkenes; 1.6.2 Aminohydroxylation of Alkenes; 1.6.3 Aziridination of Alkenes; 1.6.4 Other Applications; 1.6.5 Experimental Procedures; 1.7 N-Sulfonyliminophenyliodinane; 1.7.1 Transition Metal-Catalyzed Amination of Alkenes; 1.7.2 Experimental Procedures 1.8 Transition Metal-Nitride Complexes1.8.1 Nitrogen Atom Transfer Mediated by Transition Metal/Nitride Complexes; 1.8.2 Experimental Procedures; 1.9 Azido Derivatives; 1.9.1 Electrophilic Amination of Organometallic Reagents with Organic Azides; 1.9.2 Radical-Mediated Amination with Sulfonyl Azides; 1.9.3 Hydroazidation of Alkenes with Sulfonyl Azides; 1.9.4 Experimental Procedures; 1.10 Gabriel-Type Reagents; 1.10.1 Nucleophilic Amination Reactions; 1.10.2 Experimental Procedure; 1.11 Conclusion; 2 Catalytic C-H Amination with Nitrenes; 2.1 Introduction; 2.2 Historical Overview 2.3 Hypervalent Iodine-Mediated C-H Amination2.3.1 Intramolecular C-H Amination; 2.3.1.1 From NH(2) Carbamates; 2.3.1.2 From NH(2) Sulfamates; 2.3.1.3 From Other Nitrogen Functionalities; 2.3.2 Intermolecular C-H Amination; 2.3.2.1 General Scope and Limitations; 2.3.2.2 Recent Major Improvements; 2.4 Other Nitrene Precursors for C-H Amination; 2.4.1 Azides; 2.4.2 Haloamines; 2.4.3 Carbamate Derivatives; 2.5 Amination of Aromatic C-H Bonds; 2.6 Applications in Total Synthesis; 2.6.1 Application of Intramolecular C-H Amination with Carbamates 2.6.2 Application of Intramolecular C-H Amination with Sulfamates2.6.3 Application of Intermolecular C-H Amination; 2.7 Conclusions; 3 Nitroalkenes as Amination Tools; 3.1 Introduction; 3.2 General Strategies for the Synthesis of Nitroalkenes; 3.3 Synthesis of Alkylamines; 3.3.1 Monoamines; 3.3.2 Amino Acid Derivatives; 3.3.3 Amino Alcohols; 3.3.4 Diamino Derivatives; 3.4 Pyrrolidine Derivatives; 3.4.1 Pyrrolidinones; 3.4.2 Pyrrolidines; 3.5 Piperidines and Piperazines; 3.6 Pyrrolizidines and Related Derivatives; 3.7 Arene-Fused Nitrogen Heterocycles; 3.7.1 Pyrroloindole Derivatives 3.7.2 Carbolines and their Tryptamine Precursors |
| Record Nr. | UNINA-9910144276703321 |
| Weinheim, [Germany] : , : Wiley-VCH Verlag GmbH & Co. KGaA, , 2008 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Amino group chemistry : from synthesis to the life sciences / / edited by Alfredo Ricci
| Amino group chemistry : from synthesis to the life sciences / / edited by Alfredo Ricci |
| Pubbl/distr/stampa | Weinheim, [Germany] : , : Wiley-VCH Verlag GmbH & Co. KGaA, , 2008 |
| Descrizione fisica | 1 online resource (410 p.) |
| Disciplina |
547.042
572/.65 |
| Soggetto topico | Amino acids |
| ISBN |
1-282-78423-4
9786612784231 3-527-62126-1 3-527-62127-X |
| Classificazione | 35.62 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | ger |
| Nota di contenuto |
Amino Group Chemistry; Contents; Preface; List of Contributors; 1 Simple Molecules, Highly Efficient Amination; 1.1 Introduction; 1.2 Hydroxylamine Derivatives; 1.2.1 O-Sulfonylhydroxylamine; 1.2.2 O-Phosphinylhydroxylamine; 1.2.3 O-Acylhydroxylamine; 1.2.4 O-Trimethylsilylhydroxylamine; 1.2.5 Experimental Procedures; 1.3 Oxime Derivatives; 1.3.1 Synthesis of Primary Amines by Electrophilic Amination of Carbanions; 1.3.2 Experimental Procedures; 1.4 Azo Compounds; 1.4.1 Azodicarboxylates; 1.4.1.1 Allylic Amination through Ene-Type Reactions; 1.4.1.2 Hydrohydrazination of Alkenes
1.4.2 Arylazo Sulfones1.4.3 Experimental Procedures; 1.5 Oxaziridine Derivatives; 1.5.1 Electrophilic Amination of Carbon Nucleophiles; 1.5.2 Amination of Allylic and Propargylic Sulfides by Use of a Ketomalonate-Derived Oxaziridine; 1.5.3 Experimental Procedures; 1.6 Chloramine-T; 1.6.1 Aminochalcogenation of Alkenes; 1.6.2 Aminohydroxylation of Alkenes; 1.6.3 Aziridination of Alkenes; 1.6.4 Other Applications; 1.6.5 Experimental Procedures; 1.7 N-Sulfonyliminophenyliodinane; 1.7.1 Transition Metal-Catalyzed Amination of Alkenes; 1.7.2 Experimental Procedures 1.8 Transition Metal-Nitride Complexes1.8.1 Nitrogen Atom Transfer Mediated by Transition Metal/Nitride Complexes; 1.8.2 Experimental Procedures; 1.9 Azido Derivatives; 1.9.1 Electrophilic Amination of Organometallic Reagents with Organic Azides; 1.9.2 Radical-Mediated Amination with Sulfonyl Azides; 1.9.3 Hydroazidation of Alkenes with Sulfonyl Azides; 1.9.4 Experimental Procedures; 1.10 Gabriel-Type Reagents; 1.10.1 Nucleophilic Amination Reactions; 1.10.2 Experimental Procedure; 1.11 Conclusion; 2 Catalytic C-H Amination with Nitrenes; 2.1 Introduction; 2.2 Historical Overview 2.3 Hypervalent Iodine-Mediated C-H Amination2.3.1 Intramolecular C-H Amination; 2.3.1.1 From NH(2) Carbamates; 2.3.1.2 From NH(2) Sulfamates; 2.3.1.3 From Other Nitrogen Functionalities; 2.3.2 Intermolecular C-H Amination; 2.3.2.1 General Scope and Limitations; 2.3.2.2 Recent Major Improvements; 2.4 Other Nitrene Precursors for C-H Amination; 2.4.1 Azides; 2.4.2 Haloamines; 2.4.3 Carbamate Derivatives; 2.5 Amination of Aromatic C-H Bonds; 2.6 Applications in Total Synthesis; 2.6.1 Application of Intramolecular C-H Amination with Carbamates 2.6.2 Application of Intramolecular C-H Amination with Sulfamates2.6.3 Application of Intermolecular C-H Amination; 2.7 Conclusions; 3 Nitroalkenes as Amination Tools; 3.1 Introduction; 3.2 General Strategies for the Synthesis of Nitroalkenes; 3.3 Synthesis of Alkylamines; 3.3.1 Monoamines; 3.3.2 Amino Acid Derivatives; 3.3.3 Amino Alcohols; 3.3.4 Diamino Derivatives; 3.4 Pyrrolidine Derivatives; 3.4.1 Pyrrolidinones; 3.4.2 Pyrrolidines; 3.5 Piperidines and Piperazines; 3.6 Pyrrolizidines and Related Derivatives; 3.7 Arene-Fused Nitrogen Heterocycles; 3.7.1 Pyrroloindole Derivatives 3.7.2 Carbolines and their Tryptamine Precursors |
| Record Nr. | UNINA-9910830098903321 |
| Weinheim, [Germany] : , : Wiley-VCH Verlag GmbH & Co. KGaA, , 2008 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Protein NMR spectroscopy [[electronic resource] ] : principles and practice / / editors, John Cavanagh ... [et al.]
| Protein NMR spectroscopy [[electronic resource] ] : principles and practice / / editors, John Cavanagh ... [et al.] |
| Edizione | [2nd ed.] |
| Pubbl/distr/stampa | Amsterdam ; ; Boston, : Academic Press, c2007 |
| Descrizione fisica | 1 online resource (915 pages) |
| Disciplina | 572/.636 |
| Altri autori (Persone) | CavanaghJohn <1963-> |
| Soggetto topico |
Proteins - Analysis
Nuclear magnetic resonance spectroscopy |
| ISBN |
1-280-96292-5
9786610962921 0-08-047103-X |
| Classificazione |
35.62
35.71 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Front cover; Title page; Copyright page; Preface; Preface to the First Edition; Acknowledgements; Table of Contents; 1 Classical NMR Spectroscopy; 1.1 Nuclear Magnetism; 1.2 The Bloch Equations; 1.3 The One-Pulse NMR Experiment; 1.4 Linewidth; 1.5 Chemical Shift; 1.6 Scalar Coupling and Limitations of the Bloch Equations; References; 2 Theoretical Description of NMR Spectroscopy; 2.1 Postulates of Quantum Mechanics; 2.2 The Density Matrix; 2.3 Pulses and Rotation Operators; 2.4 Quantum Mechanical NMR Spectroscopy; 2.5 Quantum Mechanics of Multispin Systems; 2.6 Coherence
2.7 Product Operator Formalism2.8 Averaging of the Spin Hamiltonians and Residual Interactions; References; 3 Experimental Aspects of NMR Spectroscopy; 3.1 NMR Instrumentation; 3.2 Data Acquisition; 3.3 Data Processing; 3.4 Pulse Techniques; 3.5 Spin Decoupling; 3.6 B0 Field Gradients; 3.7 Water Suppression Techniques; 3.8 One-Dimensional 1H NMR Spectroscopy; References; 4 Multidimensional NMR Spectroscopy; 4.1 Two-Dimensional NMR Spectroscopy; 4.2 Coherence Transfer and Mixing; 4.3 Coherence Selection, Phase Cycling, and Field Gradients; 4.4 Resolution and Sensitivity 4.5 Three- and Four-Dimensional NMR SpectroscopyReferences; 5 Relaxation and Dynamic Processes; 5.1 Introduction and Survey of Theoretical Approaches; 5.2 The Master Equation; 5.3 Spectral Density Functions; 5.4 Relaxation Mechanisms; 5.5 Nuclear Overhauser Effect; 5.6 Chemical Exchange Effects in NMR Spectroscopy; References; 6 Experimental 1H NMR Methods; 6.1 Assessment of the 1D 1H Spectrum; 6.2 COSY-Type Experiments; 6.3 Multiple-Quantum Filtered COSY; 6.4 Multiple-Quantum Spectroscopy; 6.5 TOCSY; 6.6 Cross-Relaxation NMR Experiments; 6.7 1H 3D Experiments; References 7 Heteronuclear NMR Experiments7.1 Heteronuclear Correlation NMR Spectroscopy; 7.2 Heteronuclear-Edited NMR Spectroscopy; 7.3 13C-13C Correlations: The HCCH-COSY and HCCH-TOCSY Experiments; 7.4 3D Triple-Resonance Experiments; 7.5 Measurement of Scalar Coupling Constants; 7.6 Measurement of Residual Dipolar Coupling Constants; References; 8 Experimental NMR Relaxation Methods; 8.1 Pulse Sequences and Experimental Methods; 8.2 Picosecond-Nanosecond Dynamics; 8.3 Microsecond-Second Dynamics; References; 9 Larger Proteins and Molecular Interactions; 9.1 Larger Proteins 9.2 Intermolecular Interactions9.3 Methods for Rapid Data Acquisition; References; 10 Sequential Assignment, Structure Determination, and Other Applications; 10.1 Resonance Assignment Strategies; 10.2 Three-Dimensional Solution Structures; 10.3 Conclusion; References; Table of Symbols; List of Figures; List of Tables; Suggested Reading; Biomolecular NMR Spectroscopy; NMR Spectroscopy; Quantum Mechanics; Index; Spin-1/2 Product Operator Equations; Table of Constants |
| Record Nr. | UNINA-9910784645003321 |
| Amsterdam ; ; Boston, : Academic Press, c2007 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Protein NMR spectroscopy : principles and practice / / editors, John Cavanagh ... [et al.]
| Protein NMR spectroscopy : principles and practice / / editors, John Cavanagh ... [et al.] |
| Edizione | [2nd ed.] |
| Pubbl/distr/stampa | Amsterdam ; ; Boston, : Academic Press, c2007 |
| Descrizione fisica | 1 online resource (915 pages) |
| Disciplina | 572/.636 |
| Altri autori (Persone) | CavanaghJohn <1963-> |
| Soggetto topico |
Proteins - Analysis
Nuclear magnetic resonance spectroscopy |
| ISBN |
1-280-96292-5
9786610962921 0-08-047103-X |
| Classificazione |
35.62
35.71 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Front cover; Title page; Copyright page; Preface; Preface to the First Edition; Acknowledgements; Table of Contents; 1 Classical NMR Spectroscopy; 1.1 Nuclear Magnetism; 1.2 The Bloch Equations; 1.3 The One-Pulse NMR Experiment; 1.4 Linewidth; 1.5 Chemical Shift; 1.6 Scalar Coupling and Limitations of the Bloch Equations; References; 2 Theoretical Description of NMR Spectroscopy; 2.1 Postulates of Quantum Mechanics; 2.2 The Density Matrix; 2.3 Pulses and Rotation Operators; 2.4 Quantum Mechanical NMR Spectroscopy; 2.5 Quantum Mechanics of Multispin Systems; 2.6 Coherence
2.7 Product Operator Formalism2.8 Averaging of the Spin Hamiltonians and Residual Interactions; References; 3 Experimental Aspects of NMR Spectroscopy; 3.1 NMR Instrumentation; 3.2 Data Acquisition; 3.3 Data Processing; 3.4 Pulse Techniques; 3.5 Spin Decoupling; 3.6 B0 Field Gradients; 3.7 Water Suppression Techniques; 3.8 One-Dimensional 1H NMR Spectroscopy; References; 4 Multidimensional NMR Spectroscopy; 4.1 Two-Dimensional NMR Spectroscopy; 4.2 Coherence Transfer and Mixing; 4.3 Coherence Selection, Phase Cycling, and Field Gradients; 4.4 Resolution and Sensitivity 4.5 Three- and Four-Dimensional NMR SpectroscopyReferences; 5 Relaxation and Dynamic Processes; 5.1 Introduction and Survey of Theoretical Approaches; 5.2 The Master Equation; 5.3 Spectral Density Functions; 5.4 Relaxation Mechanisms; 5.5 Nuclear Overhauser Effect; 5.6 Chemical Exchange Effects in NMR Spectroscopy; References; 6 Experimental 1H NMR Methods; 6.1 Assessment of the 1D 1H Spectrum; 6.2 COSY-Type Experiments; 6.3 Multiple-Quantum Filtered COSY; 6.4 Multiple-Quantum Spectroscopy; 6.5 TOCSY; 6.6 Cross-Relaxation NMR Experiments; 6.7 1H 3D Experiments; References 7 Heteronuclear NMR Experiments7.1 Heteronuclear Correlation NMR Spectroscopy; 7.2 Heteronuclear-Edited NMR Spectroscopy; 7.3 13C-13C Correlations: The HCCH-COSY and HCCH-TOCSY Experiments; 7.4 3D Triple-Resonance Experiments; 7.5 Measurement of Scalar Coupling Constants; 7.6 Measurement of Residual Dipolar Coupling Constants; References; 8 Experimental NMR Relaxation Methods; 8.1 Pulse Sequences and Experimental Methods; 8.2 Picosecond-Nanosecond Dynamics; 8.3 Microsecond-Second Dynamics; References; 9 Larger Proteins and Molecular Interactions; 9.1 Larger Proteins 9.2 Intermolecular Interactions9.3 Methods for Rapid Data Acquisition; References; 10 Sequential Assignment, Structure Determination, and Other Applications; 10.1 Resonance Assignment Strategies; 10.2 Three-Dimensional Solution Structures; 10.3 Conclusion; References; Table of Symbols; List of Figures; List of Tables; Suggested Reading; Biomolecular NMR Spectroscopy; NMR Spectroscopy; Quantum Mechanics; Index; Spin-1/2 Product Operator Equations; Table of Constants |
| Record Nr. | UNINA-9910811454703321 |
| Amsterdam ; ; Boston, : Academic Press, c2007 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||