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Carbon materials for catalysis [[electronic resource] /] / edited by Philippe Serp, José Luís Figueiredo
| Carbon materials for catalysis [[electronic resource] /] / edited by Philippe Serp, José Luís Figueiredo |
| Pubbl/distr/stampa | Hoboken, N.J., : John Wiley & Sons, c2009 |
| Descrizione fisica | 1 online resource (603 p.) |
| Disciplina |
660
660.2995 660/.2995 |
| Altri autori (Persone) |
FigueiredoJosé Luís
SerpPhilippe |
| Soggetto topico |
Carbon
Catalysis |
| ISBN |
1-282-00187-6
9786612001871 0-470-40370-5 0-470-40369-1 |
| Classificazione | 35.17 |
| Formato | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
CARBON MATERIALS FOR CATALYSIS; Contents; Contributors; Preface; 1 Physicochemical Properties of Carbon Materials: A Brief Overview; 1.1. Introduction; 1.2. Formation of Carbons; 1.2.1. Gas Phase; 1.2.2. Liquid Phase; 1.2.3. Solid Phase; 1.3. Structure and Properties of Carbons; 1.3.1. Macrostructure; 1.3.2. Microstructure; 1.3.3. Nanostructure; 1.3.4. Bulk Properties; 1.3.5. Surface Properties; 1.4. Reactions of Carbons; 1.4.1. Gas Phase; 1.4.2. Liquid Phase; 1.4.3. Solid Phase; 1.5. Conclusions; References; 2 Surface Chemistry of Carbon Materials; 2.1. Introduction
2.2. Surface Functionalities2.2.1. Oxygen-Containing Functionalities; 2.2.2. Nitrogen-Containing Functionalities; 2.2.3. Hydrogen-Carbon Species; 2.2.4. Sulfur, Phosphorus, and Halogen Functionalities; 2.3. Surface Modifications; 2.3.1. Oxidation; 2.3.2. Introduction of Nitrogen-Containing Species; 2.3.3. Introduction of Sulfur Functionality; 2.3.4. Halogenization; 2.3.5. Impregnation and Dry Mixing; 2.3.6. Heat Treatment; 2.4. Characterization of Surface Chemistry; 2.4.1. Elemental Analysis; 2.4.2. Titration; 2.4.3. pH of Carbons, Point of Zero Charge, and Isoelectric Point 2.4.4. Spectroscopic Methods2.4.5. Calorimetric Techniques; 2.4.6. Inverse Gas Chromatography; 2.4.7. Temperature-Programmed Desorption; 2.4.8. Characterization of Surface Functionalities by Electrochemical Techniques; 2.5. Role of Surface Chemistry in the Reactive Adsorption on Activated Carbons; 2.6. Role of Carbon Surface Chemistry in Catalysis; References; 3 Molecular Simulations Applied to Adsorption on and Reaction with Carbon; 3.1. Introduction; 3.2. Molecular Simulation Methods Applied to Carbon Reactions; 3.2.1. Electronic Structure Methods (or Quantum Mechanics Methods) 3.2.2. Molecular Dynamics Simulations3.2.3. Monte Carlo Simulations; 3.3. Hydrogen Adsorption on and Reaction with Carbon; 3.3.1. Atomic Hydrogen Adsorption on the Basal Plane of Graphite; 3.3.2. Reactivities of Graphite Edge Sites and Hydrogen Reactions on These Sites; 3.3.3. Hydrogen Storage in Carbon Nanotubes; 3.4. Carbon Reactions with Oxygen-Containing Gases; 3.4.1. Carbon Reactions with Oxygen-Containing Gases and the Unified Mechanism; 3.4.2. Catalyzed Gas-Carbon Reactions; 3.4.3. More Specific Studies on NO(x), H(2), CO(2), and O(2)-Carbon Reactions; 3.5. Metal-Carbon Interactions 3.6. ConclusionsReferences; 4 Carbon as Catalyst Support; 4.1. Introduction; 4.2. Properties Affecting Carbon's Role as Catalyst Support; 4.2.1. Surface Area and Porosity; 4.2.2. Surface Chemical Properties; 4.2.3. Inertness; 4.3. Preparation of Carbon-Supported Catalysts; 4.3.1. Impregnation; 4.3.2. Other Methods; 4.4. Applications; 4.4.1. Ammonia Synthesis; 4.4.2. Hydrotreating Reactions; 4.4.3. Hydrogenation Reactions; 4.5. Summary; References; 5 Preparation of Carbon-Supported Metal Catalysts; 5.1. Introduction; 5.2. Impregnation and Adsorption 5.2.1. Interaction Between Support and Precursor |
| Record Nr. | UNINA-9910145965603321 |
| Hoboken, N.J., : John Wiley & Sons, c2009 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Carbon materials for catalysis [[electronic resource] /] / edited by Philippe Serp, José Luís Figueiredo
| Carbon materials for catalysis [[electronic resource] /] / edited by Philippe Serp, José Luís Figueiredo |
| Pubbl/distr/stampa | Hoboken, N.J., : John Wiley & Sons, c2009 |
| Descrizione fisica | 1 online resource (603 p.) |
| Disciplina |
660
660.2995 660/.2995 |
| Altri autori (Persone) |
FigueiredoJosé Luís
SerpPhilippe |
| Soggetto topico |
Carbon
Catalysis |
| ISBN |
1-282-00187-6
9786612001871 0-470-40370-5 0-470-40369-1 |
| Classificazione | 35.17 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
CARBON MATERIALS FOR CATALYSIS; Contents; Contributors; Preface; 1 Physicochemical Properties of Carbon Materials: A Brief Overview; 1.1. Introduction; 1.2. Formation of Carbons; 1.2.1. Gas Phase; 1.2.2. Liquid Phase; 1.2.3. Solid Phase; 1.3. Structure and Properties of Carbons; 1.3.1. Macrostructure; 1.3.2. Microstructure; 1.3.3. Nanostructure; 1.3.4. Bulk Properties; 1.3.5. Surface Properties; 1.4. Reactions of Carbons; 1.4.1. Gas Phase; 1.4.2. Liquid Phase; 1.4.3. Solid Phase; 1.5. Conclusions; References; 2 Surface Chemistry of Carbon Materials; 2.1. Introduction
2.2. Surface Functionalities2.2.1. Oxygen-Containing Functionalities; 2.2.2. Nitrogen-Containing Functionalities; 2.2.3. Hydrogen-Carbon Species; 2.2.4. Sulfur, Phosphorus, and Halogen Functionalities; 2.3. Surface Modifications; 2.3.1. Oxidation; 2.3.2. Introduction of Nitrogen-Containing Species; 2.3.3. Introduction of Sulfur Functionality; 2.3.4. Halogenization; 2.3.5. Impregnation and Dry Mixing; 2.3.6. Heat Treatment; 2.4. Characterization of Surface Chemistry; 2.4.1. Elemental Analysis; 2.4.2. Titration; 2.4.3. pH of Carbons, Point of Zero Charge, and Isoelectric Point 2.4.4. Spectroscopic Methods2.4.5. Calorimetric Techniques; 2.4.6. Inverse Gas Chromatography; 2.4.7. Temperature-Programmed Desorption; 2.4.8. Characterization of Surface Functionalities by Electrochemical Techniques; 2.5. Role of Surface Chemistry in the Reactive Adsorption on Activated Carbons; 2.6. Role of Carbon Surface Chemistry in Catalysis; References; 3 Molecular Simulations Applied to Adsorption on and Reaction with Carbon; 3.1. Introduction; 3.2. Molecular Simulation Methods Applied to Carbon Reactions; 3.2.1. Electronic Structure Methods (or Quantum Mechanics Methods) 3.2.2. Molecular Dynamics Simulations3.2.3. Monte Carlo Simulations; 3.3. Hydrogen Adsorption on and Reaction with Carbon; 3.3.1. Atomic Hydrogen Adsorption on the Basal Plane of Graphite; 3.3.2. Reactivities of Graphite Edge Sites and Hydrogen Reactions on These Sites; 3.3.3. Hydrogen Storage in Carbon Nanotubes; 3.4. Carbon Reactions with Oxygen-Containing Gases; 3.4.1. Carbon Reactions with Oxygen-Containing Gases and the Unified Mechanism; 3.4.2. Catalyzed Gas-Carbon Reactions; 3.4.3. More Specific Studies on NO(x), H(2), CO(2), and O(2)-Carbon Reactions; 3.5. Metal-Carbon Interactions 3.6. ConclusionsReferences; 4 Carbon as Catalyst Support; 4.1. Introduction; 4.2. Properties Affecting Carbon's Role as Catalyst Support; 4.2.1. Surface Area and Porosity; 4.2.2. Surface Chemical Properties; 4.2.3. Inertness; 4.3. Preparation of Carbon-Supported Catalysts; 4.3.1. Impregnation; 4.3.2. Other Methods; 4.4. Applications; 4.4.1. Ammonia Synthesis; 4.4.2. Hydrotreating Reactions; 4.4.3. Hydrogenation Reactions; 4.5. Summary; References; 5 Preparation of Carbon-Supported Metal Catalysts; 5.1. Introduction; 5.2. Impregnation and Adsorption 5.2.1. Interaction Between Support and Precursor |
| Record Nr. | UNINA-9910830045603321 |
| Hoboken, N.J., : John Wiley & Sons, c2009 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Carbon materials for catalysis / / edited by Philippe Serp, Jose Luis Figueiredo
| Carbon materials for catalysis / / edited by Philippe Serp, Jose Luis Figueiredo |
| Pubbl/distr/stampa | Hoboken, N.J., : John Wiley & Sons, c2009 |
| Descrizione fisica | 1 online resource (603 p.) |
| Disciplina |
660
660.2995 660/.2995 |
| Altri autori (Persone) |
FigueiredoJose Luis
SerpPhilippe |
| Soggetto topico |
Carbon
Catalysis |
| ISBN |
1-282-00187-6
9786612001871 0-470-40370-5 0-470-40369-1 |
| Classificazione | 35.17 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
CARBON MATERIALS FOR CATALYSIS; Contents; Contributors; Preface; 1 Physicochemical Properties of Carbon Materials: A Brief Overview; 1.1. Introduction; 1.2. Formation of Carbons; 1.2.1. Gas Phase; 1.2.2. Liquid Phase; 1.2.3. Solid Phase; 1.3. Structure and Properties of Carbons; 1.3.1. Macrostructure; 1.3.2. Microstructure; 1.3.3. Nanostructure; 1.3.4. Bulk Properties; 1.3.5. Surface Properties; 1.4. Reactions of Carbons; 1.4.1. Gas Phase; 1.4.2. Liquid Phase; 1.4.3. Solid Phase; 1.5. Conclusions; References; 2 Surface Chemistry of Carbon Materials; 2.1. Introduction
2.2. Surface Functionalities2.2.1. Oxygen-Containing Functionalities; 2.2.2. Nitrogen-Containing Functionalities; 2.2.3. Hydrogen-Carbon Species; 2.2.4. Sulfur, Phosphorus, and Halogen Functionalities; 2.3. Surface Modifications; 2.3.1. Oxidation; 2.3.2. Introduction of Nitrogen-Containing Species; 2.3.3. Introduction of Sulfur Functionality; 2.3.4. Halogenization; 2.3.5. Impregnation and Dry Mixing; 2.3.6. Heat Treatment; 2.4. Characterization of Surface Chemistry; 2.4.1. Elemental Analysis; 2.4.2. Titration; 2.4.3. pH of Carbons, Point of Zero Charge, and Isoelectric Point 2.4.4. Spectroscopic Methods2.4.5. Calorimetric Techniques; 2.4.6. Inverse Gas Chromatography; 2.4.7. Temperature-Programmed Desorption; 2.4.8. Characterization of Surface Functionalities by Electrochemical Techniques; 2.5. Role of Surface Chemistry in the Reactive Adsorption on Activated Carbons; 2.6. Role of Carbon Surface Chemistry in Catalysis; References; 3 Molecular Simulations Applied to Adsorption on and Reaction with Carbon; 3.1. Introduction; 3.2. Molecular Simulation Methods Applied to Carbon Reactions; 3.2.1. Electronic Structure Methods (or Quantum Mechanics Methods) 3.2.2. Molecular Dynamics Simulations3.2.3. Monte Carlo Simulations; 3.3. Hydrogen Adsorption on and Reaction with Carbon; 3.3.1. Atomic Hydrogen Adsorption on the Basal Plane of Graphite; 3.3.2. Reactivities of Graphite Edge Sites and Hydrogen Reactions on These Sites; 3.3.3. Hydrogen Storage in Carbon Nanotubes; 3.4. Carbon Reactions with Oxygen-Containing Gases; 3.4.1. Carbon Reactions with Oxygen-Containing Gases and the Unified Mechanism; 3.4.2. Catalyzed Gas-Carbon Reactions; 3.4.3. More Specific Studies on NO(x), H(2), CO(2), and O(2)-Carbon Reactions; 3.5. Metal-Carbon Interactions 3.6. ConclusionsReferences; 4 Carbon as Catalyst Support; 4.1. Introduction; 4.2. Properties Affecting Carbon's Role as Catalyst Support; 4.2.1. Surface Area and Porosity; 4.2.2. Surface Chemical Properties; 4.2.3. Inertness; 4.3. Preparation of Carbon-Supported Catalysts; 4.3.1. Impregnation; 4.3.2. Other Methods; 4.4. Applications; 4.4.1. Ammonia Synthesis; 4.4.2. Hydrotreating Reactions; 4.4.3. Hydrogenation Reactions; 4.5. Summary; References; 5 Preparation of Carbon-Supported Metal Catalysts; 5.1. Introduction; 5.2. Impregnation and Adsorption 5.2.1. Interaction Between Support and Precursor |
| Record Nr. | UNINA-9910876889803321 |
| Hoboken, N.J., : John Wiley & Sons, c2009 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Microporous and mesoporous solid catalysts [[electronic resource] /] / edited by Eric G. Derouane
| Microporous and mesoporous solid catalysts [[electronic resource] /] / edited by Eric G. Derouane |
| Pubbl/distr/stampa | Chichester, England ; ; Hoboken, NJ, : Wiley, c2006 |
| Descrizione fisica | 1 online resource (259 p.) |
| Disciplina |
660.2995
660/.2995 |
| Altri autori (Persone) | DerouaneE. G |
| Collana | Catalysts for fine chemical synthesis |
| Soggetto topico |
Catalysts
Silica-alumina catalysts Zeolites Mesoporous materials |
| ISBN |
1-280-64945-3
9786610649457 0-470-09421-4 0-470-09420-6 |
| Classificazione | 35.17 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Catalysts for Fine Chemical Synthesis; Contents; Series Preface.; Preface to Volume 4; Abbreviations; 1 An Overview of Zeolite, Zeotype and Mesoporous Solids Chemistry: Design, Synthesis and Catalytic Properties; 1.1 Zeolites, zeotypes and mesoporous solids: synthetic aspects; 1.1.1 Introduction; 1.1.2 Synthetic aspects: template theory for zeolite synthesis; 1.1.3 Synthetic aspects: template theory for mesoporous oxides synthesis.; 1.2 Design of extra-large pore zeolites and other micro- and mesoporous catalysts; 1.2.1 Introduction; 1.2.2 Extra-large pore zeolites
1.2.3 Hierarchical pore architectures: combining micro- and mesoporosity.1.3 Potential of post-synthesis functionalized micro- and mesoporous solids as catalysts for fine chemical synthesis; 1.3.1 Introduction; 1.3.2 Covalent functionalization; 1.3.3 Noncovalent immobilization approaches; 1.3.4 Single-site catalysts inspired by natural systems; References; 2 Problems and Pitfalls in the Applications of Zeolites and other Microporous and Mesoporous Solids to Catalytic Fine Chemical Synthesis; 2.1 Introduction; 2.2 Zeolite catalysed organic reactions 2.2.1 Fundamental and practical differences with homogeneous reactions2.2.2 Batch mode catalysis; 2.2.3 Continuous flow mode catalysis; 2.2.4 Competition for adsorption: influence on reaction rate, stability and selectivity; 2.2.5 Catalyst deactivation; 2.3 General conclusions; References; 3 Aromatic Acetylation; 3.1 Aromatic acetylation; 3.1.1 Acetylation with Acetic Anhydride; 3.1.2 Acetylation with Acetic Acid; 3.2 Procedures and protocols; 3.2.1 Selective synthesis of acetophenones in batch reactors through acetylation with acetic anhydride 3.2.2 Selective synthesis of acetophenones in fixed bed reactors through acetylation with acetic anhydrideReferences; 4 Aromatic Benzoylation; 4.1 Aromatic benzoylation; 4.1.1 Effect of the zeolite; 4.1.2 Effect of the acylating agent; 4.1.3 Effect of the solvent.; 4.1.4 Benzoylation of phenol and the Fries rearrangement; 4.1.5 Kinetic law; 4.1.6 Substituent effect; 4.1.7 Experimental.; 4.2 Acylation of anisole over mesoporous aluminosilicates.; References; 5 Nitration of Aromatic Compounds; 5.1 Introduction.; 5.2 Reaction mechanism. 5.3 Nitration of aromatic compounds using zeolites as catalysts5.3.1 Nitration in liquid phase.; 5.3.2 Vapour phase nitration; 5.4 Conclusions.; References; 6 Oligomerization of Alkenes.; 6.1 Introduction.; 6.2 Reaction mechanisms; 6.3 Acid zeolites as catalysts for oligomerization of alkenes; 6.3.1 Medium pore zeolites: influence of crystal size and acid site density; 6.3.2 Use of large pore zeolites; 6.3.3 Catalytic membranes for olefin oligomerization.; 6.4 Mesoporous aluminosilicates as oligomerization catalysts; 6.5 Nickel supported aluminosilicates as catalysts; References 7 Microporous and Mesoporous Catalysts for the Transformation of Carbohydrates |
| Record Nr. | UNINA-9910143558303321 |
| Chichester, England ; ; Hoboken, NJ, : Wiley, c2006 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Microporous and mesoporous solid catalysts [[electronic resource] /] / edited by Eric G. Derouane
| Microporous and mesoporous solid catalysts [[electronic resource] /] / edited by Eric G. Derouane |
| Pubbl/distr/stampa | Chichester, England ; ; Hoboken, NJ, : Wiley, c2006 |
| Descrizione fisica | 1 online resource (259 p.) |
| Disciplina |
660.2995
660/.2995 |
| Altri autori (Persone) | DerouaneE. G |
| Collana | Catalysts for fine chemical synthesis |
| Soggetto topico |
Catalysts
Silica-alumina catalysts Zeolites Mesoporous materials |
| ISBN |
1-280-64945-3
9786610649457 0-470-09421-4 0-470-09420-6 |
| Classificazione | 35.17 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Catalysts for Fine Chemical Synthesis; Contents; Series Preface.; Preface to Volume 4; Abbreviations; 1 An Overview of Zeolite, Zeotype and Mesoporous Solids Chemistry: Design, Synthesis and Catalytic Properties; 1.1 Zeolites, zeotypes and mesoporous solids: synthetic aspects; 1.1.1 Introduction; 1.1.2 Synthetic aspects: template theory for zeolite synthesis; 1.1.3 Synthetic aspects: template theory for mesoporous oxides synthesis.; 1.2 Design of extra-large pore zeolites and other micro- and mesoporous catalysts; 1.2.1 Introduction; 1.2.2 Extra-large pore zeolites
1.2.3 Hierarchical pore architectures: combining micro- and mesoporosity.1.3 Potential of post-synthesis functionalized micro- and mesoporous solids as catalysts for fine chemical synthesis; 1.3.1 Introduction; 1.3.2 Covalent functionalization; 1.3.3 Noncovalent immobilization approaches; 1.3.4 Single-site catalysts inspired by natural systems; References; 2 Problems and Pitfalls in the Applications of Zeolites and other Microporous and Mesoporous Solids to Catalytic Fine Chemical Synthesis; 2.1 Introduction; 2.2 Zeolite catalysed organic reactions 2.2.1 Fundamental and practical differences with homogeneous reactions2.2.2 Batch mode catalysis; 2.2.3 Continuous flow mode catalysis; 2.2.4 Competition for adsorption: influence on reaction rate, stability and selectivity; 2.2.5 Catalyst deactivation; 2.3 General conclusions; References; 3 Aromatic Acetylation; 3.1 Aromatic acetylation; 3.1.1 Acetylation with Acetic Anhydride; 3.1.2 Acetylation with Acetic Acid; 3.2 Procedures and protocols; 3.2.1 Selective synthesis of acetophenones in batch reactors through acetylation with acetic anhydride 3.2.2 Selective synthesis of acetophenones in fixed bed reactors through acetylation with acetic anhydrideReferences; 4 Aromatic Benzoylation; 4.1 Aromatic benzoylation; 4.1.1 Effect of the zeolite; 4.1.2 Effect of the acylating agent; 4.1.3 Effect of the solvent.; 4.1.4 Benzoylation of phenol and the Fries rearrangement; 4.1.5 Kinetic law; 4.1.6 Substituent effect; 4.1.7 Experimental.; 4.2 Acylation of anisole over mesoporous aluminosilicates.; References; 5 Nitration of Aromatic Compounds; 5.1 Introduction.; 5.2 Reaction mechanism. 5.3 Nitration of aromatic compounds using zeolites as catalysts5.3.1 Nitration in liquid phase.; 5.3.2 Vapour phase nitration; 5.4 Conclusions.; References; 6 Oligomerization of Alkenes.; 6.1 Introduction.; 6.2 Reaction mechanisms; 6.3 Acid zeolites as catalysts for oligomerization of alkenes; 6.3.1 Medium pore zeolites: influence of crystal size and acid site density; 6.3.2 Use of large pore zeolites; 6.3.3 Catalytic membranes for olefin oligomerization.; 6.4 Mesoporous aluminosilicates as oligomerization catalysts; 6.5 Nickel supported aluminosilicates as catalysts; References 7 Microporous and Mesoporous Catalysts for the Transformation of Carbohydrates |
| Record Nr. | UNINA-9910830583003321 |
| Chichester, England ; ; Hoboken, NJ, : Wiley, c2006 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Microporous and mesoporous solid catalysts / / edited by Eric G. Derouane
| Microporous and mesoporous solid catalysts / / edited by Eric G. Derouane |
| Pubbl/distr/stampa | Chichester, England ; ; Hoboken, NJ, : Wiley, c2006 |
| Descrizione fisica | 1 online resource (259 p.) |
| Disciplina | 660/.2995 |
| Altri autori (Persone) | DerouaneE. G |
| Collana | Catalysts for fine chemical synthesis |
| Soggetto topico |
Catalysts
Silica-alumina catalysts Zeolites Mesoporous materials |
| ISBN |
1-280-64945-3
9786610649457 0-470-09421-4 0-470-09420-6 |
| Classificazione | 35.17 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Catalysts for Fine Chemical Synthesis; Contents; Series Preface.; Preface to Volume 4; Abbreviations; 1 An Overview of Zeolite, Zeotype and Mesoporous Solids Chemistry: Design, Synthesis and Catalytic Properties; 1.1 Zeolites, zeotypes and mesoporous solids: synthetic aspects; 1.1.1 Introduction; 1.1.2 Synthetic aspects: template theory for zeolite synthesis; 1.1.3 Synthetic aspects: template theory for mesoporous oxides synthesis.; 1.2 Design of extra-large pore zeolites and other micro- and mesoporous catalysts; 1.2.1 Introduction; 1.2.2 Extra-large pore zeolites
1.2.3 Hierarchical pore architectures: combining micro- and mesoporosity.1.3 Potential of post-synthesis functionalized micro- and mesoporous solids as catalysts for fine chemical synthesis; 1.3.1 Introduction; 1.3.2 Covalent functionalization; 1.3.3 Noncovalent immobilization approaches; 1.3.4 Single-site catalysts inspired by natural systems; References; 2 Problems and Pitfalls in the Applications of Zeolites and other Microporous and Mesoporous Solids to Catalytic Fine Chemical Synthesis; 2.1 Introduction; 2.2 Zeolite catalysed organic reactions 2.2.1 Fundamental and practical differences with homogeneous reactions2.2.2 Batch mode catalysis; 2.2.3 Continuous flow mode catalysis; 2.2.4 Competition for adsorption: influence on reaction rate, stability and selectivity; 2.2.5 Catalyst deactivation; 2.3 General conclusions; References; 3 Aromatic Acetylation; 3.1 Aromatic acetylation; 3.1.1 Acetylation with Acetic Anhydride; 3.1.2 Acetylation with Acetic Acid; 3.2 Procedures and protocols; 3.2.1 Selective synthesis of acetophenones in batch reactors through acetylation with acetic anhydride 3.2.2 Selective synthesis of acetophenones in fixed bed reactors through acetylation with acetic anhydrideReferences; 4 Aromatic Benzoylation; 4.1 Aromatic benzoylation; 4.1.1 Effect of the zeolite; 4.1.2 Effect of the acylating agent; 4.1.3 Effect of the solvent.; 4.1.4 Benzoylation of phenol and the Fries rearrangement; 4.1.5 Kinetic law; 4.1.6 Substituent effect; 4.1.7 Experimental.; 4.2 Acylation of anisole over mesoporous aluminosilicates.; References; 5 Nitration of Aromatic Compounds; 5.1 Introduction.; 5.2 Reaction mechanism. 5.3 Nitration of aromatic compounds using zeolites as catalysts5.3.1 Nitration in liquid phase.; 5.3.2 Vapour phase nitration; 5.4 Conclusions.; References; 6 Oligomerization of Alkenes.; 6.1 Introduction.; 6.2 Reaction mechanisms; 6.3 Acid zeolites as catalysts for oligomerization of alkenes; 6.3.1 Medium pore zeolites: influence of crystal size and acid site density; 6.3.2 Use of large pore zeolites; 6.3.3 Catalytic membranes for olefin oligomerization.; 6.4 Mesoporous aluminosilicates as oligomerization catalysts; 6.5 Nickel supported aluminosilicates as catalysts; References 7 Microporous and Mesoporous Catalysts for the Transformation of Carbohydrates |
| Record Nr. | UNINA-9910877225103321 |
| Chichester, England ; ; Hoboken, NJ, : Wiley, c2006 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Modern biocatalysis [[electronic resource] ] : stereoselective and environmentally friendly reactions / / edited by Wolf-Dieter Fessner and Thorleif Anthonsen
| Modern biocatalysis [[electronic resource] ] : stereoselective and environmentally friendly reactions / / edited by Wolf-Dieter Fessner and Thorleif Anthonsen |
| Pubbl/distr/stampa | Weinheim, : Wiley-VCH, c2009 |
| Descrizione fisica | 1 online resource (401 p.) |
| Disciplina | 660.634 |
| Altri autori (Persone) |
FessnerW.-D (Wolf-Dieter)
AnthonsenThorleif |
| Soggetto topico |
Enzymes - Biotechnology
Catalysis |
| Soggetto genere / forma | Electronic books. |
| ISBN |
1-282-02547-3
9786612025471 3-527-62383-3 3-527-62384-1 |
| Classificazione |
58.30
35.17 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Modern Biocatalysis; Contents; Preface; List of Contributors; 1: Fluorescence Assays for Biotransformations; 1.1 Introduction; 1.2 Alcohol Dehydrogenases (ADHs) and Aldolases; 1.2.1 Chiral Fluorogenic ADH Substrates; 1.2.2 Fluorogenic Aldolase Probes; 1.2.3 Transaldolases and Transketolases; 1.2.4 Enolase Probe; 1.3 Lipases and Esterases; 1.3.1 Assays on Solid Support; 1.3.2 The Clips-O Substrates with Periodate; 1.3.3 Esters of Fluorogenic Cyanohydrins and Hydroxyketones; 1.3.4 Fluorogenic Acyloxymethyl Ethers; 1.3.5 FRET-Lipase Probes; 1.4 Other Hydrolases; 1.4.1 Epoxide Hydrolases
1.4.2 Amidases and Proteases1.4.3 Phosphatases; 1.5 Baeyer-Villigerases; 1.6 Conclusion; Acknowledgment; References; 2: Immobilization as a Tool for Improving Enzymes; 2.1 Introduction; 2.2 Adsorption/Electrostatic Interactions; 2.2.1 Van der Waals Interactions; 2.2.2 Hydrogen Bonds; 2.2.3 Ionic Interactions; 2.3 Encapsulation; 2.4 Covalent Binding/Cross-linking; 2.5 Conclusion; Acknowledgments; References; 3: Continuous-flow Microchannel Reactors with Surface-immobilized Biocatalysts; 3.1 Introduction 3.2 Biocatalytic Synthesis Using Microreaction Technology with Free and Immobilized Enzymes3.3 Novel Microfluidic Immobilized Enzyme Reactors; 3.3.1 Microreactor Design; 3.3.2 Enzyme Immobilization; 3.4 Enzymatic Hydrolysis of Lactose; 3.4.1 Catalytic Effectiveness of Immobilized CelB; 3.4.2 Continuous Conversion of Lactose; 3.5 Biocatalytic Process Intensification Using Microreaction Technology; 3.6 Conclusions and Outlook; Acknowledgements; References; 4: Activity and Stability of Proteases in Hydrophilic Solvents; 4.1 Introduction 4.2 Activity and Selectivity of Proteases in Synthesis of Carbohydrate Fatty Acid Esters4.3 Enzyme Stability and Conformation; 4.4 Solvent Engineering; 4.5 Conclusion; References; 5: Importance of Enzyme Formulation for the Activity and Enantioselectivity of Lipases in Organic Solvents; 5.1 Introduction; 5.2 Lipase Formulations and their Activity and Enantioselectivity in Neat Organic Solvent; 5.3 Why do Additives Affect the Activity and Enantioselectivity of Lipases in Organic Solvent?; 5.4 Conclusions; References 6: Direct Esterification with Dry Mycelia of Molds: a (Stereo)selective, Mild and Efficient Method for Obtaining Structurally Diverse Esters6.1 Mycelia and Biotransformations in Organic Media; 6.2 Screening and Microbiological Aspects; 6.3 Production of Acetates; 6.4 Stereoselective Esterifications of Racemic Alcohols; 6.5 Stereoselective Esterifications of Racemic Carboxylic Acids; 6.6 Partition Phenomena and Equilibrium of Esterification Reactions; 6.7 Conclusions; References; 7: Factors Affecting Enantioselectivity: Allosteric Effects; 7.1 How to Provide Enantiopure Compounds 7.1.1 Kinetic Resolution of Racemic Mixtures Catalyzed by Enzymes |
| Record Nr. | UNINA-9910145260603321 |
| Weinheim, : Wiley-VCH, c2009 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Modern biocatalysis [[electronic resource] ] : stereoselective and environmentally friendly reactions / / edited by Wolf-Dieter Fessner and Thorleif Anthonsen
| Modern biocatalysis [[electronic resource] ] : stereoselective and environmentally friendly reactions / / edited by Wolf-Dieter Fessner and Thorleif Anthonsen |
| Pubbl/distr/stampa | Weinheim, : Wiley-VCH, c2009 |
| Descrizione fisica | 1 online resource (401 p.) |
| Disciplina | 660.634 |
| Altri autori (Persone) |
FessnerW.-D (Wolf-Dieter)
AnthonsenThorleif |
| Soggetto topico |
Enzymes - Biotechnology
Catalysis |
| ISBN |
1-282-02547-3
9786612025471 3-527-62383-3 3-527-62384-1 |
| Classificazione |
58.30
35.17 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Modern Biocatalysis; Contents; Preface; List of Contributors; 1: Fluorescence Assays for Biotransformations; 1.1 Introduction; 1.2 Alcohol Dehydrogenases (ADHs) and Aldolases; 1.2.1 Chiral Fluorogenic ADH Substrates; 1.2.2 Fluorogenic Aldolase Probes; 1.2.3 Transaldolases and Transketolases; 1.2.4 Enolase Probe; 1.3 Lipases and Esterases; 1.3.1 Assays on Solid Support; 1.3.2 The Clips-O Substrates with Periodate; 1.3.3 Esters of Fluorogenic Cyanohydrins and Hydroxyketones; 1.3.4 Fluorogenic Acyloxymethyl Ethers; 1.3.5 FRET-Lipase Probes; 1.4 Other Hydrolases; 1.4.1 Epoxide Hydrolases
1.4.2 Amidases and Proteases1.4.3 Phosphatases; 1.5 Baeyer-Villigerases; 1.6 Conclusion; Acknowledgment; References; 2: Immobilization as a Tool for Improving Enzymes; 2.1 Introduction; 2.2 Adsorption/Electrostatic Interactions; 2.2.1 Van der Waals Interactions; 2.2.2 Hydrogen Bonds; 2.2.3 Ionic Interactions; 2.3 Encapsulation; 2.4 Covalent Binding/Cross-linking; 2.5 Conclusion; Acknowledgments; References; 3: Continuous-flow Microchannel Reactors with Surface-immobilized Biocatalysts; 3.1 Introduction 3.2 Biocatalytic Synthesis Using Microreaction Technology with Free and Immobilized Enzymes3.3 Novel Microfluidic Immobilized Enzyme Reactors; 3.3.1 Microreactor Design; 3.3.2 Enzyme Immobilization; 3.4 Enzymatic Hydrolysis of Lactose; 3.4.1 Catalytic Effectiveness of Immobilized CelB; 3.4.2 Continuous Conversion of Lactose; 3.5 Biocatalytic Process Intensification Using Microreaction Technology; 3.6 Conclusions and Outlook; Acknowledgements; References; 4: Activity and Stability of Proteases in Hydrophilic Solvents; 4.1 Introduction 4.2 Activity and Selectivity of Proteases in Synthesis of Carbohydrate Fatty Acid Esters4.3 Enzyme Stability and Conformation; 4.4 Solvent Engineering; 4.5 Conclusion; References; 5: Importance of Enzyme Formulation for the Activity and Enantioselectivity of Lipases in Organic Solvents; 5.1 Introduction; 5.2 Lipase Formulations and their Activity and Enantioselectivity in Neat Organic Solvent; 5.3 Why do Additives Affect the Activity and Enantioselectivity of Lipases in Organic Solvent?; 5.4 Conclusions; References 6: Direct Esterification with Dry Mycelia of Molds: a (Stereo)selective, Mild and Efficient Method for Obtaining Structurally Diverse Esters6.1 Mycelia and Biotransformations in Organic Media; 6.2 Screening and Microbiological Aspects; 6.3 Production of Acetates; 6.4 Stereoselective Esterifications of Racemic Alcohols; 6.5 Stereoselective Esterifications of Racemic Carboxylic Acids; 6.6 Partition Phenomena and Equilibrium of Esterification Reactions; 6.7 Conclusions; References; 7: Factors Affecting Enantioselectivity: Allosteric Effects; 7.1 How to Provide Enantiopure Compounds 7.1.1 Kinetic Resolution of Racemic Mixtures Catalyzed by Enzymes |
| Record Nr. | UNINA-9910830040103321 |
| Weinheim, : Wiley-VCH, c2009 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Modern biocatalysis : stereoselective and environmentally friendly reactions / / edited by Wolf-Dieter Fessner and Thorleif Anthonsen
| Modern biocatalysis : stereoselective and environmentally friendly reactions / / edited by Wolf-Dieter Fessner and Thorleif Anthonsen |
| Pubbl/distr/stampa | Weinheim, : Wiley-VCH, c2009 |
| Descrizione fisica | 1 online resource (401 p.) |
| Disciplina | 660.634 |
| Altri autori (Persone) |
FessnerW.-D (Wolf-Dieter)
AnthonsenThorleif |
| Soggetto topico |
Enzymes - Biotechnology
Catalysis |
| ISBN |
1-282-02547-3
9786612025471 3-527-62383-3 3-527-62384-1 |
| Classificazione |
58.30
35.17 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Modern Biocatalysis; Contents; Preface; List of Contributors; 1: Fluorescence Assays for Biotransformations; 1.1 Introduction; 1.2 Alcohol Dehydrogenases (ADHs) and Aldolases; 1.2.1 Chiral Fluorogenic ADH Substrates; 1.2.2 Fluorogenic Aldolase Probes; 1.2.3 Transaldolases and Transketolases; 1.2.4 Enolase Probe; 1.3 Lipases and Esterases; 1.3.1 Assays on Solid Support; 1.3.2 The Clips-O Substrates with Periodate; 1.3.3 Esters of Fluorogenic Cyanohydrins and Hydroxyketones; 1.3.4 Fluorogenic Acyloxymethyl Ethers; 1.3.5 FRET-Lipase Probes; 1.4 Other Hydrolases; 1.4.1 Epoxide Hydrolases
1.4.2 Amidases and Proteases1.4.3 Phosphatases; 1.5 Baeyer-Villigerases; 1.6 Conclusion; Acknowledgment; References; 2: Immobilization as a Tool for Improving Enzymes; 2.1 Introduction; 2.2 Adsorption/Electrostatic Interactions; 2.2.1 Van der Waals Interactions; 2.2.2 Hydrogen Bonds; 2.2.3 Ionic Interactions; 2.3 Encapsulation; 2.4 Covalent Binding/Cross-linking; 2.5 Conclusion; Acknowledgments; References; 3: Continuous-flow Microchannel Reactors with Surface-immobilized Biocatalysts; 3.1 Introduction 3.2 Biocatalytic Synthesis Using Microreaction Technology with Free and Immobilized Enzymes3.3 Novel Microfluidic Immobilized Enzyme Reactors; 3.3.1 Microreactor Design; 3.3.2 Enzyme Immobilization; 3.4 Enzymatic Hydrolysis of Lactose; 3.4.1 Catalytic Effectiveness of Immobilized CelB; 3.4.2 Continuous Conversion of Lactose; 3.5 Biocatalytic Process Intensification Using Microreaction Technology; 3.6 Conclusions and Outlook; Acknowledgements; References; 4: Activity and Stability of Proteases in Hydrophilic Solvents; 4.1 Introduction 4.2 Activity and Selectivity of Proteases in Synthesis of Carbohydrate Fatty Acid Esters4.3 Enzyme Stability and Conformation; 4.4 Solvent Engineering; 4.5 Conclusion; References; 5: Importance of Enzyme Formulation for the Activity and Enantioselectivity of Lipases in Organic Solvents; 5.1 Introduction; 5.2 Lipase Formulations and their Activity and Enantioselectivity in Neat Organic Solvent; 5.3 Why do Additives Affect the Activity and Enantioselectivity of Lipases in Organic Solvent?; 5.4 Conclusions; References 6: Direct Esterification with Dry Mycelia of Molds: a (Stereo)selective, Mild and Efficient Method for Obtaining Structurally Diverse Esters6.1 Mycelia and Biotransformations in Organic Media; 6.2 Screening and Microbiological Aspects; 6.3 Production of Acetates; 6.4 Stereoselective Esterifications of Racemic Alcohols; 6.5 Stereoselective Esterifications of Racemic Carboxylic Acids; 6.6 Partition Phenomena and Equilibrium of Esterification Reactions; 6.7 Conclusions; References; 7: Factors Affecting Enantioselectivity: Allosteric Effects; 7.1 How to Provide Enantiopure Compounds 7.1.1 Kinetic Resolution of Racemic Mixtures Catalyzed by Enzymes |
| Record Nr. | UNINA-9910876609703321 |
| Weinheim, : Wiley-VCH, c2009 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Multimetallic catalysts in organic synthesis [[electronic resource] /] / edited by Masakatsu Shibasaki and Yoshinori Yamamoto
| Multimetallic catalysts in organic synthesis [[electronic resource] /] / edited by Masakatsu Shibasaki and Yoshinori Yamamoto |
| Pubbl/distr/stampa | Weinheim ; ; [Great Britain], : Wiley-VCH, c2004 |
| Descrizione fisica | 1 online resource (313 p.) |
| Disciplina |
547.1395
547.2 |
| Altri autori (Persone) |
ShibasakiMasakatsu
YamamotoY (Yoshinori) |
| Soggetto topico |
Organic compounds - Synthesis
Metal catalysts |
| Soggetto genere / forma | Electronic books. |
| ISBN |
1-280-51967-3
9786610519675 3-527-60355-7 3-527-60432-4 |
| Classificazione |
35.52
35.17 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Multimetallic Catalysts in Organic Synthesis; Contents; Preface; List of Contributors; 1 Organic Synthesis with Bimetallic Systems; 1.1 Introduction; 1.2 Reactions Promoted by a Combination of Catalytic and Stoichiometric Amounts of Metals; 1.2.1 Transition Metal-Catalyzed Cross-Coupling Reactions; 1.2.2 The Wacker Reaction; 1.2.3 The Heck Reaction; 1.2.4 Reactions Involving π-Allylpalladium Intermediates; 1.2.4.1 Electrophilic Reactions; 1.2.4.2 Nucleophilic Reactions; 1.2.5 Nickel-Catalyzed Three-Component Coupling Reaction; 1.2.6 The Nozaki-Hiyama-Kishi Reaction
1.3 Reactions Promoted by a Combination of Catalytic Amounts of Two Metals1.3.1 Transition Metal Catalyzed Cross-Coupling Reactions; 1.3.1.1 The Stille Reaction; 1.3.1.2 The Hiyama Reaction; 1.3.1.3 The Sonogashira Reaction; 1.3.2 The Wacker Reaction; 1.3.3 Reactions Involving π-Allylpalladium Intermediates; 1.3.4 Transition Metal Catalyzed Cyclization Reactions; 1.3.4.1 [3+2] Cycloaddition Reactions; 1.3.4.2 Intramolecular [n+2] Cyclization Reactions; 1.3.4.3 Intermolecular [n+2+2] Cyclotrimerization Reactions; 1.3.4.4 [2+2+1] Cycloaddition Reactions; The Pauson-Khand Reaction 1.3.4.5 Cycloisomerization Reactions1.3.4.6 Indole-Forming Reaction; 1.3.4.7 Furan- and Pyrrole-Forming Reactions; 1.3.5 Reactions Involving Nucleophilic Addition of Carbonyl Compounds; 1.3.5.1 The Aldol Reaction; 1.3.5.2 Alkynylation Reactions; 1.3.5.3 Conjugate Addition Reactions; 1.3.6 Miscellaneous Reactions; 1.3.6.1 Transition Metal Catalyzed Reactions; 1.3.6.2 Lewis Acid Catalyzed Reactions; 1.3.6.3 Sequential Reactions; References; 2 Zinc Polymetallic Asymmetric Catalysis; 2.1 Introduction; 2.2 Asymmetric Alternating Copolymerization with Dimeric Zn Complexes 2.3 Direct Catalytic Asymmetric Aldol Reaction with Zn Polymetallic Catalysts2.3.1 Introduction; 2.3.2 Direct Catalytic Asymmetric Aldol Reaction with Methyl Ketones; 2.3.3 Direct Catalytic Asymmetric Aldol Reaction with α-Hydroxy Ketones; 2.4 Direct Catalytic Asymmetric Mannich-Type Reactions; 2.5 Direct Catalytic Asymmetric Michael Reaction; 2.6 Nitroaldol (Henry) Reaction; 2.7 Conclusions; References; 3 Group 13-Alkali Metal Heterobimetallic Asymmetric Catalysis; 3.1 Introduction; 3.2 Catalytic Asymmetric Michael Reaction of Stabilized Carbon Nucleophiles 3.2.1 Development of ALB - The First Example of a Group 13-Alkali Metal Heterobimetallic Asymmetric Catalyst3.2.2 Development of the Second-Generation Heterobimetallic Catalysts - Self-Assembly of Heterobimetallic Catalysts and Reactive Nucleophiles; 3.3 Catalytic Asymmetric Ring-Opening Reaction of meso-Epoxides; 3.3.1 Ring-Opening Reaction with Thiols; 3.3.2 Ring-Opening Reaction with Phenolic Oxygen - Development of a Novel Linked-BINOL Complex; 3.4 Catalytic Asymmetric Mannich Reactions; 3.4.1 Direct Catalytic Asymmetric Mannich-Type Reaction of Unmodified Ketones 3.4.2 Enantio- and Diastereoselective Catalytic Nitro-Mannich Reactions |
| Record Nr. | UNINA-9910144298903321 |
| Weinheim ; ; [Great Britain], : Wiley-VCH, c2004 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
