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Biodegradable polyesters / / edited by Stoyko Fakirov
| Biodegradable polyesters / / edited by Stoyko Fakirov |
| Pubbl/distr/stampa | Weinheim, Germany : , : Wiley-VCH, , 2015 |
| Descrizione fisica | 1 online resource (370 p.) |
| Disciplina | 668.4225 |
| Soggetto topico |
Polyesters
Biodegradable plastics |
| ISBN |
1-5231-1008-2
3-527-65697-9 3-527-65695-2 3-527-65698-7 |
| Formato | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | ger |
| Nota di contenuto |
Cover; Contents; List of Contributors; List of Abbreviations and Symbols; Preface; Chapter 1 Biodegradable Polyesters: Synthesis, Properties, Applications; 1.1 Historical Overview on the Origin of Polymer Science and Synthesis of Polyamides and Polyesters; 1.1.1 Synthesis of Polyamides; 1.1.2 Initial Knowledge about Polyesters; 1.2 Publication Trend of Representative Biodegradable and Nonbiodegradable Polyesters in the Past Century; 1.3 Biodegradable Polyesters; 1.3.1 Biodegradable Aliphatic Polyesters and Their Copolymers; 1.3.1.1 Poly(lactic acid)
1.3.1.2 Polyglycolide or Poly(glycolic acid)1.3.1.3 Poly(caprolactone); 1.4 Concluding Remarks; Acknowledgment; References; Chapter 2 Functional (Bio)degradable Polyesters by Radical Ring-Opening Polymerization; 2.1 Introduction; 2.2 Radical Ring-Opening Polymerization (RROP) of Cyclic Ketene Acetals; 2.2.1 Starting Monomers: Cyclic Ketene Acetals; 2.2.2 Radical Ring-Opening Polymerization Mechanism; 2.2.3 Functional Polyesters by Conventional and Controlled Radical Homopolymerization of CKAs; 2.2.4 Functional Polyesters by Copolymerization of CKAs and Vinyl Monomers; 2.3 Conclusions References Chapter 3 Microbial Synthesis of Biodegradable Polyesters: Processes, Products, Applications; 3.1 Introduction; 3.2 Biogenesis of Microbial Polyhydroxyalkanoate Granules; 3.3 The Diversity of Biopolyesters; 3.4 Polyester (PHA) Synthases are the Key Enzymes; 3.5 Catalytic Reaction Mechanism; 3.6 PHA Inclusions: Self-Assembly and Structure; 3.7 Industrial Production of Bacterial Polyhydroxyalkanoates: PHAs via Fermentation; 3.8 Application Opportunities of Bacterial Polyhydroxyalkanoates; 3.8.1 In Energy Industry: Biofuels Based on PHAs 3.8.2 In Material Industry: PHAs as Polymeric Materials 3.8.2.1 PHAs as Biodegradable Plastics and Fiber Materials; 3.8.2.2 PHAs as Medical Implant Materials; 3.8.2.3 PHAs as Drug Delivery Carrier; 3.8.3 Fine Chemical Industry: PHA Chiral Monomers; 3.8.4 Application of PHA Granule Surface Proteins; 3.8.5 Production of Tailor-Made Biopolyester Nanoparticles and Potential Applications; 3.8.6 Future Development of PHA-Based Industry; 3.8.6.1 The Development of Low-Cost PHA Production Technology; 3.8.6.2 Unusual PHAs with Special Properties; 3.8.6.3 High Value Added Applications 3.8.6.4 Other Future Applications 3.8.6.5 Microbial Synthesis of Poly(lactic acid) (PLA); 3.8.7 Applications of PHA Inclusions as Functionalized Biobeads; 3.8.7.1 Bioseparations; 3.8.7.2 Drug Delivery; 3.8.7.3 Protein Purification; 3.8.7.4 Enzyme Immobilization; 3.8.7.5 Diagnostics and Imaging; 3.8.7.6 Vaccine Delivery; 3.9 Conclusions and Outlook; Acknowledgments; References; Chapter 4 Synthesis, Properties, and Mathematical Modeling of Biodegradable Aliphatic Polyesters Based on 1,3-Propanediol and Dicarboxylic Acids; 4.1 Introduction; 4.1.1 Aliphatic Polyesters 4.1.2 Production of 1,3-Propanediol |
| Record Nr. | UNINA-9910132410003321 |
| Weinheim, Germany : , : Wiley-VCH, , 2015 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Biodegradable polyesters / / edited by Stoyko Fakirov
| Biodegradable polyesters / / edited by Stoyko Fakirov |
| Pubbl/distr/stampa | Weinheim, Germany : , : Wiley-VCH, , 2015 |
| Descrizione fisica | 1 online resource (370 p.) |
| Disciplina | 668.4225 |
| Soggetto topico |
Polyesters
Biodegradable plastics |
| ISBN |
9783527656981 (ebook)
3-527-65697-9 3-527-65695-2 3-527-65698-7 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | ger |
| Nota di contenuto |
Cover; Contents; List of Contributors; List of Abbreviations and Symbols; Preface; Chapter 1 Biodegradable Polyesters: Synthesis, Properties, Applications; 1.1 Historical Overview on the Origin of Polymer Science and Synthesis of Polyamides and Polyesters; 1.1.1 Synthesis of Polyamides; 1.1.2 Initial Knowledge about Polyesters; 1.2 Publication Trend of Representative Biodegradable and Nonbiodegradable Polyesters in the Past Century; 1.3 Biodegradable Polyesters; 1.3.1 Biodegradable Aliphatic Polyesters and Their Copolymers; 1.3.1.1 Poly(lactic acid)
1.3.1.2 Polyglycolide or Poly(glycolic acid)1.3.1.3 Poly(caprolactone); 1.4 Concluding Remarks; Acknowledgment; References; Chapter 2 Functional (Bio)degradable Polyesters by Radical Ring-Opening Polymerization; 2.1 Introduction; 2.2 Radical Ring-Opening Polymerization (RROP) of Cyclic Ketene Acetals; 2.2.1 Starting Monomers: Cyclic Ketene Acetals; 2.2.2 Radical Ring-Opening Polymerization Mechanism; 2.2.3 Functional Polyesters by Conventional and Controlled Radical Homopolymerization of CKAs; 2.2.4 Functional Polyesters by Copolymerization of CKAs and Vinyl Monomers; 2.3 Conclusions References Chapter 3 Microbial Synthesis of Biodegradable Polyesters: Processes, Products, Applications; 3.1 Introduction; 3.2 Biogenesis of Microbial Polyhydroxyalkanoate Granules; 3.3 The Diversity of Biopolyesters; 3.4 Polyester (PHA) Synthases are the Key Enzymes; 3.5 Catalytic Reaction Mechanism; 3.6 PHA Inclusions: Self-Assembly and Structure; 3.7 Industrial Production of Bacterial Polyhydroxyalkanoates: PHAs via Fermentation; 3.8 Application Opportunities of Bacterial Polyhydroxyalkanoates; 3.8.1 In Energy Industry: Biofuels Based on PHAs 3.8.2 In Material Industry: PHAs as Polymeric Materials 3.8.2.1 PHAs as Biodegradable Plastics and Fiber Materials; 3.8.2.2 PHAs as Medical Implant Materials; 3.8.2.3 PHAs as Drug Delivery Carrier; 3.8.3 Fine Chemical Industry: PHA Chiral Monomers; 3.8.4 Application of PHA Granule Surface Proteins; 3.8.5 Production of Tailor-Made Biopolyester Nanoparticles and Potential Applications; 3.8.6 Future Development of PHA-Based Industry; 3.8.6.1 The Development of Low-Cost PHA Production Technology; 3.8.6.2 Unusual PHAs with Special Properties; 3.8.6.3 High Value Added Applications 3.8.6.4 Other Future Applications 3.8.6.5 Microbial Synthesis of Poly(lactic acid) (PLA); 3.8.7 Applications of PHA Inclusions as Functionalized Biobeads; 3.8.7.1 Bioseparations; 3.8.7.2 Drug Delivery; 3.8.7.3 Protein Purification; 3.8.7.4 Enzyme Immobilization; 3.8.7.5 Diagnostics and Imaging; 3.8.7.6 Vaccine Delivery; 3.9 Conclusions and Outlook; Acknowledgments; References; Chapter 4 Synthesis, Properties, and Mathematical Modeling of Biodegradable Aliphatic Polyesters Based on 1,3-Propanediol and Dicarboxylic Acids; 4.1 Introduction; 4.1.1 Aliphatic Polyesters 4.1.2 Production of 1,3-Propanediol |
| Record Nr. | UNINA-9910825637803321 |
| Weinheim, Germany : , : Wiley-VCH, , 2015 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Handbook of thermoplastic polyesters : homopolymers, copolymers, blends, and composites
| Handbook of thermoplastic polyesters : homopolymers, copolymers, blends, and composites |
| Pubbl/distr/stampa | [Place of publication not identified], : Wiley VCH, 2002 |
| Descrizione fisica | 1 online resource (1392 pages) |
| Disciplina | 668.4225 |
| Soggetto topico |
Polyesters
Thermoplastic composites Chemical Engineering Chemical & Materials Engineering Engineering & Applied Sciences |
| Soggetto genere / forma | Electronic books. |
| ISBN |
1-280-56069-X
9786610560691 3-527-60196-1 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNINA-9910146051103321 |
| [Place of publication not identified], : Wiley VCH, 2002 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Handbook of thermoplastic polyesters : homopolymers, copolymers, blends, and composites
| Handbook of thermoplastic polyesters : homopolymers, copolymers, blends, and composites |
| Pubbl/distr/stampa | [Place of publication not identified], : Wiley VCH, 2002 |
| Descrizione fisica | 1 online resource (1392 pages) |
| Disciplina | 668.4225 |
| Soggetto topico |
Polyesters
Thermoplastic composites Chemical Engineering Chemical & Materials Engineering Engineering & Applied Sciences |
| ISBN |
1-280-56069-X
9786610560691 3-527-60196-1 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNINA-9910830672603321 |
| [Place of publication not identified], : Wiley VCH, 2002 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Handbook of thermoplastic polyesters : homopolymers, copolymers, blends, and composites
| Handbook of thermoplastic polyesters : homopolymers, copolymers, blends, and composites |
| Pubbl/distr/stampa | [Place of publication not identified], : Wiley VCH, 2002 |
| Descrizione fisica | 1 online resource (1392 pages) |
| Disciplina | 668.4225 |
| Soggetto topico |
Polyesters
Thermoplastic composites Chemical Engineering Chemical & Materials Engineering Engineering & Applied Sciences |
| ISBN |
1-280-56069-X
9786610560691 3-527-60196-1 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNINA-9910877366003321 |
| [Place of publication not identified], : Wiley VCH, 2002 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Modern polyesters [[electronic resource] ] : chemistry and technology of polyesters and copolyesters / / edited by John Scheirs and Timothy E. Long
| Modern polyesters [[electronic resource] ] : chemistry and technology of polyesters and copolyesters / / edited by John Scheirs and Timothy E. Long |
| Pubbl/distr/stampa | Hoboken, NJ, : John Wiley & Sons, c2003 |
| Descrizione fisica | 1 online resource (786 p.) |
| Disciplina | 668.4225 |
| Altri autori (Persone) |
ScheirsJohn
LongTimothy E. <1969-> |
| Collana | Wiley series in polymer science |
| Soggetto topico | Polyesters |
| Soggetto genere / forma | Electronic books. |
| ISBN |
1-280-23893-3
9786610238934 0-470-09067-7 0-470-09068-5 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Modern Polyesters: Chemistry and Technology of Polyesters and Copolyesters; Contents; Contributors; Series Preface; Preface; About the Editors; I HISTORICAL OVERVIEW; 1 The Historical Development of Polyesters; 1 Introduction; 2 Alkyd and Related Resins; 3 Fibres from Partially Aromatic Polyesters; 3.1 Early Work Leading to Poly(ethylene Terephthalate); 3.2 Spread of Polyester Fibre Production; 3.3 Intermediates; 3.4 Continuous Polymerisation; 3.5 Solid-phase Polymerisation; 3.6 End-use Development; 3.7 High-speed Spinning; 3.8 Ultra-fine Fibres; 4 Other Uses for Semi-aromatic Polyesters
4.1 Films4.2 Moulding Products; 4.3 Bottles; 5 Liquid-crystalline Polyesters; 6 Polyesters as Components of Elastomers; 7 Surface-active Agents; 8 Absorbable Fibres; 9 Polycarbonates; 10 Natural Polyesters; 10.1 Occurrence; 10.2 Poly(b-hydroxyalkanoate)s; 11 Conclusion; References; II POLYMERIZATION AND POLYCONDENSATION; 2 Poly(ethylene Terephthalate) Polymerization - Mechanism, Catalysis, Kinetics, Mass Transfer and Reactor Design; Notation; 1 Introduction; 2 Chemistry, Reaction Mechanisms, Kinetics and Catalysis; 2.1 Esterification/Hydrolysis; 2.2 Transesterication/Glycolysis 2.3 Reactions with Co-monomers2.4 Formation of Short Chain Oligomers; 2.5 Formation of Diethylene Glycol and Dioxane; 2.6 Thermal Degradation of Diester Groups and Formation of Acetaldehyde; 2.7 Yellowing; 2.8 Chemical Recycling; 2.9 Conclusions; 3 Phase Equilibria, Molecular Diffusion and Mass Transfer; 3.1 Phase Equilibria; 3.2 Diffusion and Mass Transfer in Melt-phase Polycondensation; 3.2.1 Mass-transfer Models; 3.2.2 Diffusion Models; 3.2.3 Specific Surface Area; 3.3 Diffusion and Mass Transfer in Solid-state Polycondensation; 3.4 Conclusions 4 Polycondensation Processes and Polycondensation Plants4.1 Batch Processes; 4.1.1 Esterification; 4.1.2 Polycondensation; 4.2 Continuous Processes; 5 Reactor Design for Continuous Melt-phase Polycondensation; 5.1 Esterification Reactors; 5.2 Polycondensation Reactors for Low Melt Viscosity; 5.3 Polycondensation Reactors for High Melt Viscosity; 6 Future Developments and Scientific Requirements; Acknowledgements; References; 3 Synthesis and Polymerization of Cyclic Polyester Oligomers; 1 Introduction; 2 History; 3 Preparation of Polyester Cyclic Oligomers from Acid Chlorides 4 Polyester Cyclic Oligomers via Ring-Chain Equilibration (Depolymerization)5 Mechanism for Formation of Cyclics via Depolymerization; 6 Polymerization of Oligomeric Ester Cyclics; 7 Conclusions; References; 4 Continuous Solid-state Polycondensation of Polyesters; 1 Introduction; 2 The Chemical Reactions of PET in the Solid State; 2.1 Basic Chemistry; 2.2 Mechanism and Kinetics; 2.3 Parameters Affecting SSP; 2.3.1 Temperature; 2.3.2 Time; 2.3.3 Particle Size; 2.3.4 End Group Concentration; 2.3.5 Crystallinity; 2.3.6 Gas Type; 2.3.7 Gas Purity; 2.3.8 Catalyst; 2.3.9 Molecular Weight 3 Crystallization of PET |
| Record Nr. | UNINA-9910146249903321 |
| Hoboken, NJ, : John Wiley & Sons, c2003 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Modern polyesters [[electronic resource] ] : chemistry and technology of polyesters and copolyesters / / edited by John Scheirs and Timothy E. Long
| Modern polyesters [[electronic resource] ] : chemistry and technology of polyesters and copolyesters / / edited by John Scheirs and Timothy E. Long |
| Pubbl/distr/stampa | Hoboken, NJ, : John Wiley & Sons, c2003 |
| Descrizione fisica | 1 online resource (786 p.) |
| Disciplina | 668.4225 |
| Altri autori (Persone) |
ScheirsJohn
LongTimothy E. <1969-> |
| Collana | Wiley series in polymer science |
| Soggetto topico | Polyesters |
| ISBN |
1-280-23893-3
9786610238934 0-470-09067-7 0-470-09068-5 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Modern Polyesters: Chemistry and Technology of Polyesters and Copolyesters; Contents; Contributors; Series Preface; Preface; About the Editors; I HISTORICAL OVERVIEW; 1 The Historical Development of Polyesters; 1 Introduction; 2 Alkyd and Related Resins; 3 Fibres from Partially Aromatic Polyesters; 3.1 Early Work Leading to Poly(ethylene Terephthalate); 3.2 Spread of Polyester Fibre Production; 3.3 Intermediates; 3.4 Continuous Polymerisation; 3.5 Solid-phase Polymerisation; 3.6 End-use Development; 3.7 High-speed Spinning; 3.8 Ultra-fine Fibres; 4 Other Uses for Semi-aromatic Polyesters
4.1 Films4.2 Moulding Products; 4.3 Bottles; 5 Liquid-crystalline Polyesters; 6 Polyesters as Components of Elastomers; 7 Surface-active Agents; 8 Absorbable Fibres; 9 Polycarbonates; 10 Natural Polyesters; 10.1 Occurrence; 10.2 Poly(b-hydroxyalkanoate)s; 11 Conclusion; References; II POLYMERIZATION AND POLYCONDENSATION; 2 Poly(ethylene Terephthalate) Polymerization - Mechanism, Catalysis, Kinetics, Mass Transfer and Reactor Design; Notation; 1 Introduction; 2 Chemistry, Reaction Mechanisms, Kinetics and Catalysis; 2.1 Esterification/Hydrolysis; 2.2 Transesterication/Glycolysis 2.3 Reactions with Co-monomers2.4 Formation of Short Chain Oligomers; 2.5 Formation of Diethylene Glycol and Dioxane; 2.6 Thermal Degradation of Diester Groups and Formation of Acetaldehyde; 2.7 Yellowing; 2.8 Chemical Recycling; 2.9 Conclusions; 3 Phase Equilibria, Molecular Diffusion and Mass Transfer; 3.1 Phase Equilibria; 3.2 Diffusion and Mass Transfer in Melt-phase Polycondensation; 3.2.1 Mass-transfer Models; 3.2.2 Diffusion Models; 3.2.3 Specific Surface Area; 3.3 Diffusion and Mass Transfer in Solid-state Polycondensation; 3.4 Conclusions 4 Polycondensation Processes and Polycondensation Plants4.1 Batch Processes; 4.1.1 Esterification; 4.1.2 Polycondensation; 4.2 Continuous Processes; 5 Reactor Design for Continuous Melt-phase Polycondensation; 5.1 Esterification Reactors; 5.2 Polycondensation Reactors for Low Melt Viscosity; 5.3 Polycondensation Reactors for High Melt Viscosity; 6 Future Developments and Scientific Requirements; Acknowledgements; References; 3 Synthesis and Polymerization of Cyclic Polyester Oligomers; 1 Introduction; 2 History; 3 Preparation of Polyester Cyclic Oligomers from Acid Chlorides 4 Polyester Cyclic Oligomers via Ring-Chain Equilibration (Depolymerization)5 Mechanism for Formation of Cyclics via Depolymerization; 6 Polymerization of Oligomeric Ester Cyclics; 7 Conclusions; References; 4 Continuous Solid-state Polycondensation of Polyesters; 1 Introduction; 2 The Chemical Reactions of PET in the Solid State; 2.1 Basic Chemistry; 2.2 Mechanism and Kinetics; 2.3 Parameters Affecting SSP; 2.3.1 Temperature; 2.3.2 Time; 2.3.3 Particle Size; 2.3.4 End Group Concentration; 2.3.5 Crystallinity; 2.3.6 Gas Type; 2.3.7 Gas Purity; 2.3.8 Catalyst; 2.3.9 Molecular Weight 3 Crystallization of PET |
| Record Nr. | UNINA-9910830719203321 |
| Hoboken, NJ, : John Wiley & Sons, c2003 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||