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Advances in hydrogen energy [[electronic resource] /] / edited by Catherine E. Grégoire Padró and Francis Lau
Advances in hydrogen energy [[electronic resource] /] / edited by Catherine E. Grégoire Padró and Francis Lau
Edizione [1st ed. 2002.]
Pubbl/distr/stampa New York, : Kluwer Academic/Plenum Publishers, c2000
Descrizione fisica 1 online resource (201 p.)
Disciplina 665.8/1
Altri autori (Persone) Grégoire PadróCatherine E
LauFrancis <1947->
Soggetto topico Hydrogen as fuel
Soggetto genere / forma Electronic books.
ISBN 1-280-20489-3
9786610204892
0-306-46922-7
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Hydrogen from Fossil Fuels without Co2 Emissions -- Hydrogen Production from Western Coal Including CO2 Sequestration and Coalbed Methane Recovery: Economics, CO2 Emissions, and Energy Balance -- Unmixed Reforming: A Novel Autothermal Cyclic Steam Reforming Process -- Fuel Flexible Reforming of Hydrocarbons for Automotive Applications -- The Production of Hydrogen from Methane Using Tubular Plasma Reactors -- A Novel Catalytic Process for Generating Hydrogen Gas from Aqueous Borohydride Solutions -- Production of Hydrogen from Biomass by Pyrolysis/Steam Reforming -- Evaluation and Modeling of a High-temperature, High-pressure, Hydrogen Separation Membrane for Enhanced Hydrogen Production from the Water-gas Shift Reaction -- A First-principles Study of Hydrogen Dissolution in Various Metals and Palladium-silver Alloys -- Investigation of a Novel Metal Hydride Electrode for Ni-Mh Batteries -- Hydrogen Storage Using Slurries of Chemical Hydrides -- Advances in Low Cost Hydrogen Sensor Technology -- The Application of a Hydrogen Risk Assessment Method to Vented Spaces -- Modeling of Integrated Renewable Hydrogen Energy Systems for Remote Applications.
Record Nr. UNINA-9910454971703321
New York, : Kluwer Academic/Plenum Publishers, c2000
Materiale a stampa
Lo trovi qui: Univ. Federico II
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Advances in hydrogen energy [[electronic resource] /] / edited by Catherine E. Grégoire Padró and Francis Lau
Advances in hydrogen energy [[electronic resource] /] / edited by Catherine E. Grégoire Padró and Francis Lau
Edizione [1st ed. 2002.]
Pubbl/distr/stampa New York, : Kluwer Academic/Plenum Publishers, c2000
Descrizione fisica 1 online resource (201 p.)
Disciplina 665.8/1
Altri autori (Persone) Grégoire PadróCatherine E
LauFrancis <1947->
Soggetto topico Hydrogen as fuel
ISBN 1-280-20489-3
9786610204892
0-306-46922-7
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Hydrogen from Fossil Fuels without Co2 Emissions -- Hydrogen Production from Western Coal Including CO2 Sequestration and Coalbed Methane Recovery: Economics, CO2 Emissions, and Energy Balance -- Unmixed Reforming: A Novel Autothermal Cyclic Steam Reforming Process -- Fuel Flexible Reforming of Hydrocarbons for Automotive Applications -- The Production of Hydrogen from Methane Using Tubular Plasma Reactors -- A Novel Catalytic Process for Generating Hydrogen Gas from Aqueous Borohydride Solutions -- Production of Hydrogen from Biomass by Pyrolysis/Steam Reforming -- Evaluation and Modeling of a High-temperature, High-pressure, Hydrogen Separation Membrane for Enhanced Hydrogen Production from the Water-gas Shift Reaction -- A First-principles Study of Hydrogen Dissolution in Various Metals and Palladium-silver Alloys -- Investigation of a Novel Metal Hydride Electrode for Ni-Mh Batteries -- Hydrogen Storage Using Slurries of Chemical Hydrides -- Advances in Low Cost Hydrogen Sensor Technology -- The Application of a Hydrogen Risk Assessment Method to Vented Spaces -- Modeling of Integrated Renewable Hydrogen Energy Systems for Remote Applications.
Record Nr. UNINA-9910779969803321
New York, : Kluwer Academic/Plenum Publishers, c2000
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Advances in hydrogen energy / / edited by Catherine E. Grégoire Padró and Francis Lau
Advances in hydrogen energy / / edited by Catherine E. Grégoire Padró and Francis Lau
Edizione [1st ed. 2002.]
Pubbl/distr/stampa New York, : Kluwer Academic/Plenum Publishers, c2000
Descrizione fisica 1 online resource (201 p.)
Disciplina 665.8/1
Altri autori (Persone) Grégoire PadróCatherine E
LauFrancis <1947->
Soggetto topico Hydrogen as fuel
ISBN 1-280-20489-3
9786610204892
0-306-46922-7
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Hydrogen from Fossil Fuels without Co2 Emissions -- Hydrogen Production from Western Coal Including CO2 Sequestration and Coalbed Methane Recovery: Economics, CO2 Emissions, and Energy Balance -- Unmixed Reforming: A Novel Autothermal Cyclic Steam Reforming Process -- Fuel Flexible Reforming of Hydrocarbons for Automotive Applications -- The Production of Hydrogen from Methane Using Tubular Plasma Reactors -- A Novel Catalytic Process for Generating Hydrogen Gas from Aqueous Borohydride Solutions -- Production of Hydrogen from Biomass by Pyrolysis/Steam Reforming -- Evaluation and Modeling of a High-temperature, High-pressure, Hydrogen Separation Membrane for Enhanced Hydrogen Production from the Water-gas Shift Reaction -- A First-principles Study of Hydrogen Dissolution in Various Metals and Palladium-silver Alloys -- Investigation of a Novel Metal Hydride Electrode for Ni-Mh Batteries -- Hydrogen Storage Using Slurries of Chemical Hydrides -- Advances in Low Cost Hydrogen Sensor Technology -- The Application of a Hydrogen Risk Assessment Method to Vented Spaces -- Modeling of Integrated Renewable Hydrogen Energy Systems for Remote Applications.
Record Nr. UNINA-9910827478403321
New York, : Kluwer Academic/Plenum Publishers, c2000
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Biohydrogen / / edited by Matthias Rögner
Biohydrogen / / edited by Matthias Rögner
Pubbl/distr/stampa Berlin ; ; Boston : , : Walter de Gruyter GmbH & Co. KG, , [2015]
Descrizione fisica 1 online resource (298 p.)
Disciplina 665.8/1
Soggetto topico Hydrogen - Biotechnology
Hydrogen as fuel
Biomass energy
Soggetto genere / forma Electronic books.
ISBN 1-5231-0447-3
3-11-033673-1
3-11-038934-7
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Front matter -- Contents -- List of contributing authors -- Preface -- 1 Cyanobacterial design cell for the production of hydrogen from water -- 2 Analysis and assessment of current photobioreactor systems for photobiological hydrogen production -- 3 Catalytic properties and maturation of [FeFe]-hydrogenases -- 4 Oxygen-tolerant hydrogenases and their biotechnological potential -- 5 Metal centers in hydrogenase enzymes studied by X-ray spectroscopy -- 6 Structure and function of [Fe]-hydrogenase and biosynthesis of the FeGP cofactor -- 7 Hydrogenase evolution and function in eukaryotic algae -- 8 Engineering of cyanobacteria for increased hydrogen production -- 9 Semi-artificial photosynthetic Z-scheme for hydrogen production from water -- 10 Photosynthesis and hydrogen metabolism revisited. On the potential of light-driven hydrogen production in vitro -- 11 Re-routing redox chains for directed photocatalysis -- 12 Energy and entropy engineering on sunlight conversion to hydrogen using photosynthetic bacteria -- Index
Record Nr. UNINA-9910460708603321
Berlin ; ; Boston : , : Walter de Gruyter GmbH & Co. KG, , [2015]
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Biohydrogen / / edited by Matthias Rögner
Biohydrogen / / edited by Matthias Rögner
Pubbl/distr/stampa Berlin ; ; Boston : , : Walter de Gruyter GmbH & Co. KG, , [2015]
Descrizione fisica 1 online resource (298 p.)
Disciplina 665.8/1
Soggetto topico Hydrogen - Biotechnology
Hydrogen as fuel
Biomass energy
Soggetto non controllato Alternative Energy
Biotechnology
Energy Storage
Sustainability
ISBN 1-5231-0447-3
3-11-033673-1
3-11-038934-7
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Front matter -- Contents -- List of contributing authors -- Preface -- 1 Cyanobacterial design cell for the production of hydrogen from water -- 2 Analysis and assessment of current photobioreactor systems for photobiological hydrogen production -- 3 Catalytic properties and maturation of [FeFe]-hydrogenases -- 4 Oxygen-tolerant hydrogenases and their biotechnological potential -- 5 Metal centers in hydrogenase enzymes studied by X-ray spectroscopy -- 6 Structure and function of [Fe]-hydrogenase and biosynthesis of the FeGP cofactor -- 7 Hydrogenase evolution and function in eukaryotic algae -- 8 Engineering of cyanobacteria for increased hydrogen production -- 9 Semi-artificial photosynthetic Z-scheme for hydrogen production from water -- 10 Photosynthesis and hydrogen metabolism revisited. On the potential of light-driven hydrogen production in vitro -- 11 Re-routing redox chains for directed photocatalysis -- 12 Energy and entropy engineering on sunlight conversion to hydrogen using photosynthetic bacteria -- Index
Record Nr. UNINA-9910797010903321
Berlin ; ; Boston : , : Walter de Gruyter GmbH & Co. KG, , [2015]
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Biohydrogen / / edited by Matthias Rögner
Biohydrogen / / edited by Matthias Rögner
Pubbl/distr/stampa Berlin ; ; Boston : , : Walter de Gruyter GmbH & Co. KG, , [2015]
Descrizione fisica 1 online resource (298 p.)
Disciplina 665.8/1
Soggetto topico Hydrogen - Biotechnology
Hydrogen as fuel
Biomass energy
Soggetto non controllato Alternative Energy
Biotechnology
Energy Storage
Sustainability
ISBN 1-5231-0447-3
3-11-033673-1
3-11-038934-7
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Front matter -- Contents -- List of contributing authors -- Preface -- 1 Cyanobacterial design cell for the production of hydrogen from water -- 2 Analysis and assessment of current photobioreactor systems for photobiological hydrogen production -- 3 Catalytic properties and maturation of [FeFe]-hydrogenases -- 4 Oxygen-tolerant hydrogenases and their biotechnological potential -- 5 Metal centers in hydrogenase enzymes studied by X-ray spectroscopy -- 6 Structure and function of [Fe]-hydrogenase and biosynthesis of the FeGP cofactor -- 7 Hydrogenase evolution and function in eukaryotic algae -- 8 Engineering of cyanobacteria for increased hydrogen production -- 9 Semi-artificial photosynthetic Z-scheme for hydrogen production from water -- 10 Photosynthesis and hydrogen metabolism revisited. On the potential of light-driven hydrogen production in vitro -- 11 Re-routing redox chains for directed photocatalysis -- 12 Energy and entropy engineering on sunlight conversion to hydrogen using photosynthetic bacteria -- Index
Record Nr. UNINA-9910810976003321
Berlin ; ; Boston : , : Walter de Gruyter GmbH & Co. KG, , [2015]
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Boron hydrides, high potential hydrogen storage materials [[electronic resource] /] / Umit B. Demirci and Philippe Miele, editors
Boron hydrides, high potential hydrogen storage materials [[electronic resource] /] / Umit B. Demirci and Philippe Miele, editors
Pubbl/distr/stampa New York, : Nova Science Publishers, c2011
Descrizione fisica 1 online resource (276 p.)
Disciplina 665.8/1
Altri autori (Persone) DemirciUmit B
MielePhilippe
Collana Chemistry research and applications
Soggetto topico Hydrogen - Storage - Materials
Boranes
Soggetto genere / forma Electronic books.
ISBN 1-61470-326-4
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Record Nr. UNINA-9910457672303321
New York, : Nova Science Publishers, c2011
Materiale a stampa
Lo trovi qui: Univ. Federico II
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Boron hydrides, high potential hydrogen storage materials [[electronic resource] /] / Umit B. Demirci and Philippe Miele, editors
Boron hydrides, high potential hydrogen storage materials [[electronic resource] /] / Umit B. Demirci and Philippe Miele, editors
Pubbl/distr/stampa New York, : Nova Science Publishers, c2011
Descrizione fisica 1 online resource (276 p.)
Disciplina 665.8/1
Altri autori (Persone) DemirciUmit B
MielePhilippe
Collana Chemistry research and applications
Soggetto topico Hydrogen - Storage - Materials
Boranes
ISBN 1-61470-326-4
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Record Nr. UNINA-9910781854603321
New York, : Nova Science Publishers, c2011
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Boron hydrides, high potential hydrogen storage materials [[electronic resource] /] / Umit B. Demirci and Philippe Miele, editors
Boron hydrides, high potential hydrogen storage materials [[electronic resource] /] / Umit B. Demirci and Philippe Miele, editors
Edizione [1st ed.]
Pubbl/distr/stampa New York, : Nova Science Publishers, c2011
Descrizione fisica 1 online resource (276 p.)
Disciplina 665.8/1
Altri autori (Persone) DemirciUmit B
MielePhilippe
Collana Chemistry research and applications
Soggetto topico Hydrogen - Storage - Materials
Boranes
ISBN 1-61470-326-4
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Intro -- BORON HYDRIDES, HIGH POTENTIAL HYDROGEN STORAGE MATERIALS -- BORON HYDRIDES, HIGH POTENTIAL HYDROGEN STORAGE MATERIALS -- CONTENTS -- PREFACE -- Chapter 1 SOLID-STATE HYDROGEN STORAGE -- Abstract -- Introduction -- 2. Issues Encountering Hydrogen Economy -- 3. Hydrogen Storage Issue -- 3.1 Technical Targets -- 3.2 Physical Methods for Hydrogen Storage -- 3.2.1 High Pressure Storage -- 3.2.2 Cryogenic Storage -- 3.3 Chemical Methods for Hydrogen Storage -- 4. Solids for Hydrogen Storage or Chemical Storage -- 4.1 Adsorption in Porous Materials -- 4.1.1 Activated Carbons including Carbon Nanostructures -- 4.1.2 Hydrogen Physisorption in other Materials -- 4.2 Storage by Absorption -- 4.2.1 Metal Hydrides -- 4.2.2 Complex Hydrides -- 4.2.3 Storage via Chemical Reactions -- Conclusion -- References -- Chapter 2 BORON HYDRIDES -- Abstract -- 1. Introduction -- 2. Boron Compounds -- 2.1 Borides -- 2.2 Boron Hydrides -- 2.3 Boron Halides -- 2.4 Boron-Oxygen Compounds -- 2.5 Boron-Nitrogen Compounds -- 2.6 Other Boron-Based Compounds -- 2.7 Summary -- 3. Borohydrides -- 3.1 All of the Borohydrides -- 3.2 Thermolysis of Borohydrides -- 3.3 Hydrolysis of Borohydrides -- 3.4 Safety Data -- 3.5 Conclusion -- 4. Ammoniaborane and its Derivatives -- 4.1 Ammoniaborane -- 4.2 Amidoboranes -- 4.3 Safety Data -- Conclusion -- References -- Chapter 3 LITHIUM BOROHYDRIDE: SYNTHESIS, PROPERTIES AND THERMAL DECOMPOSITION -- Abstract -- 1. Introduction -- 2. Synthesis Methods -- 3. Crystal Structures -- 4. Ionic Superconduction -- 5. Thermal Decomposition -- 6. Hydrogen Release Enhancement by Catalysts Addition -- 7. Modification of Hydrogen Release by Confinement into Nanoporous Carbons -- Conclusions -- Acknowledgments -- References -- Chapter 4 HYDROGEN CYCLE WITH SODIUM BOROHYDRIDE -- Abstract -- 1. Importance of Sodium Borohydride in Hydrogen Cycle.
2. Sodium Borohydride Production Techniques -- 2.1. Borax Reactions -- 2.2. Trimetyl Borate Reactions -- 2.3. NaBH4 Reactions -- 3. Dehydrogenation of NaBH4 and its usage as Hydrogen Carrier -- 3.1. Thermal Dehydrogenation -- 3.2. Catalytic Dehydrogenation -- 3.2.1. Alkaline Hydrolysis Solution -- 3.2.2. Water Requirement for Hydrolysis -- 3.2.3. Catalyst Preparation and its Effect on Hydrolysis -- 3.2.4. Supported Materials of Heterogeneous Catalysts -- 3.2.5. Processing Magnetic Catalysts -- 3.2.6. Co-Ni Couple Catalysts and Reaction Mechanism -- 3.2.7. Electrochemical Catalysts -- 3.2.8. Fuel Cell Application of Catalytic Hydrolysis -- 4. NaBO2 Recycle -- 5. NaBO2-Borax Conversion -- 6. Characterization of NaBH4 -- Conclusion -- References -- Chapter 5 POTENTIAL AND LIMITATION OF THE DIRECT BOROHYDRIDE FUEL CELL. SPECIAL EMPHASIS ON THE BOROHYDRIDE OXIDATION REACTION (BOR) MECHANISM AND KINETICS ON GOLD ELECTROCATALYSTS -- Abstract -- 1. Introduction -- 2. Experimental -- 2.1 Reagents and Solutions -- 2.2 On-Line Electrochemical Mass Spectroscopy (OLEMSlems) -- 2.3 Ftir FTIR Spectroscopy -- 2.4 CV and EIS -- 3. The Ideal Reactant for DBFC -- 3.1 Fuel Composition for DBFC -- 3.2 Alternative Reactants -- 3.3 Fuel Monitoring -- 4. Principle of Operation of a DBFC -- 4.1 Basics and Performance -- 4.2 Influence of the Electrode Geometry and Reactant Channel Design -- 4.3 Membrane and Electrode Materials -- 5. Survey of the BOR on Gold -- 5.1 Is Gold Inactive Regarding the Heterogeneous Hydrolysis of BH4- Aanion? -- 5.2 Evidencing the BOR Intermediates on Gold by FTIR Spectroscopy -- 5.3 Towards a Simplified BOR Pathway for Gold Electrodes -- Conclusion -- Acknowledgments -- References -- Chapter 6 CRYSTAL CHEMISTRY OF LIGHT METAL BOROHYDRIDES -- Abstract -- Introduction -- Crystal Structures -- LiBH4 -- NaBH4 -- KBH4 -- NH4BH4 -- Be(BH4)2 -- Mg(BH4)2.
Ca(BH4)2 -- Mn(BH4)2 -- Al(BH4)3 -- LiK(BH4)2 -- MSc(BH4)4 (M = Li, Na) -- MZn2(BH4)5 (M = Li, Na) -- NaZn(BH4)3 -- Structural Evolution under Non-Ambient Conditions -- Diffraction Studies of the Stability Regions and Structure Evolution under External Stimuli -- Phenomenological and Crystal-Chemical Analysis of the Mechanisms of the Phase Transitions -- Crystal Chemistry -- Geometry of the BH4 Group -- BH4…M and BH4…BH4 Contacts -- Chemical Destabilization: Mixed-Cation and Mixed-Anion Borohydrides -- Chemical Destabilization: Substitution in the BH4 Group -- References -- Chapter 7 AMMONIA BORANE: THERMOLYSIS -- Abstract -- 1. Introduction -- 2. Ammonia Borane -- 3. Solid Neat Ammonia Borane Thermolysis -- 3.1 The Induction Period -- 3.2 The First Reaction Step -- 3.3 The Second Reaction Step -- 3.4 The Third Reaction Step -- 4. Thermolysis of Neat Ammonia Borane in Solution -- 5. Catalyzed Ammonia Borane Thermolysis -- 5.1 Catalyzed Solid State Ammonia Borane -- 5.2 Catalyzed Ammonia Borane in Solution -- 6. Ammonia Borane Compounds Thermolysis -- 6.1 Solid State Ammonia Borane Compounds Thermolysis -- 7. Supported Ammonia Borane Thermolysis -- 8. Regeneration of Ammonia Borane Dehydrogenation Products -- Conclusion -- References -- Chapter 8 AMMONIA BORANE: HYDROLYSIS AND ELECTROOXIDATION -- Abstract -- 1. Introduction -- 2. Ammonia Borane Hydrolysis -- 2.1 Concept -- 2.2 State-of-the-Art -- 2.2.1 Transition Metal Catalyst -- 2.2.2 Effective Gravimetric Hydrogen Storage Capacity -- 2.2.3 Recycling of the Reaction by-Products -- 2.3 Ammonia Borane versus Sodium Borohydride -- 3. Ammonia Borane Electrooxidation -- 3.1 Direct Liquid Fuel Cells -- 3.2 Basics -- 3.3 State-of-the-art and Issues -- 3.4 Direct Ammonia Borane Fuel Cell Vversus Direct Borohydride Ffuel Cell -- Conclusion -- References -- Chapter 9 METAL AMIDOBORANES -- Abstract.
Introduction -- Syntheses -- Structures and Crystal Chemistry -- 1. Metal Amidoboranes -- 2. Other Amidoborane Complexes -- Dehydrogenation Properties -- 1. Lithium Amidoborane -- 2. Sodium Amidoborane -- 3. Calcium Amidoborane -- 4. Structural Characteristics Responsible for the Dehydrogenation Properties -- 5. Other Amidoborane Complexes -- Conclusions -- Acknowledgment -- References -- Chapter 10 CONCLUSION AND OUTLOOK: WHICH FUTURE FOR BORON HYDRIDES? -- Abstract -- 1. Introduction -- 2. Current Potentials of the Boron Hydrides -- 2.1 Borohydrides -- 2.2 Ammonia Borane and Amidoboranes -- 2.3 Summary -- 3. Always the same Challenges -- 3.1 Hydrogen Production and Distribution -- 3.2 Hydrogen Storage -- 3.3 Summary -- 4. The Most Critical Challenges Facing Boron Hydrides -- 4.1 Effective Storage Capacity -- 4.2 Storage Reversibility -- 4.3 Summary -- 5. Greenness Considerations -- 5.1 Green Chemistry -- 5.2 Greenness of the Boron Hydrides -- 5.3 Summary -- Conclusion and Outlook -- References -- INDEX -- Blank Page.
Record Nr. UNINA-9910827129103321
New York, : Nova Science Publishers, c2011
Materiale a stampa
Lo trovi qui: Univ. Federico II
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High temperature electrolysis in large-scale hydrogen production [[electronic resource] /] / Yu Bo and Xu Jingming
High temperature electrolysis in large-scale hydrogen production [[electronic resource] /] / Yu Bo and Xu Jingming
Autore Bo Yu <1975->
Pubbl/distr/stampa New York, : Nova Science Publishers, Inc., c2010
Descrizione fisica 1 online resource (95 p.)
Disciplina 665.8/1
Altri autori (Persone) JingmingXu <1945->
Collana Energy science, engineering and technology
Novinka
Soggetto topico Hydrogen as fuel
High temperature electrolysis
Soggetto genere / forma Electronic books.
ISBN 1-61668-697-9
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Record Nr. UNINA-9910456598403321
Bo Yu <1975->  
New York, : Nova Science Publishers, Inc., c2010
Materiale a stampa
Lo trovi qui: Univ. Federico II
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