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Advances in electrochemical science and engineering . Volume 5 [[electronic resource] /] / edited by Richard C. Alkire ... [et al.]
| Advances in electrochemical science and engineering . Volume 5 [[electronic resource] /] / edited by Richard C. Alkire ... [et al.] |
| Pubbl/distr/stampa | New York, N.Y., : Wiley, c1997 |
| Descrizione fisica | 1 online resource (432 p.) |
| Disciplina |
541.3/7
660.297 |
| Altri autori (Persone) | AlkireR. C. <1941-> |
| Collana | Advances in electrochemical science and engineering |
| Soggetto topico |
Electrochemistry
Chemistry, Physical and theoretical |
| Soggetto genere / forma | Electronic books. |
| ISBN |
1-281-75891-4
9786611758912 3-527-61679-9 3-527-61688-8 |
| Formato | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto | Advances in Electrochemical Science and Engineering; Contents; Marcus Theory in the Qualitative and Quantitative Description of Electrochemiluminescence Phenomena; Electrochemistry of Oxide High-Temperature Superconductors; Flow Rate Dependence of Localized Corrosion in Thermal Power Plant Materials; Polymer Electrolyte Fuel Cells; Graphite, Carbonaceous Materials and Organic Solids as Active Electrodes in Metal-Free Batteries; Index |
| Record Nr. | UNINA-9910144095603321 |
| New York, N.Y., : Wiley, c1997 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Advances in electrochemical science and engineering . Volume 5 [[electronic resource] /] / edited by Richard C. Alkire ... [et al.]
| Advances in electrochemical science and engineering . Volume 5 [[electronic resource] /] / edited by Richard C. Alkire ... [et al.] |
| Pubbl/distr/stampa | New York, N.Y., : Wiley, c1997 |
| Descrizione fisica | 1 online resource (432 p.) |
| Disciplina |
541.3/7
660.297 |
| Altri autori (Persone) | AlkireR. C. <1941-> |
| Collana | Advances in electrochemical science and engineering |
| Soggetto topico |
Electrochemistry
Chemistry, Physical and theoretical |
| ISBN |
1-281-75891-4
9786611758912 3-527-61679-9 3-527-61688-8 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto | Advances in Electrochemical Science and Engineering; Contents; Marcus Theory in the Qualitative and Quantitative Description of Electrochemiluminescence Phenomena; Electrochemistry of Oxide High-Temperature Superconductors; Flow Rate Dependence of Localized Corrosion in Thermal Power Plant Materials; Polymer Electrolyte Fuel Cells; Graphite, Carbonaceous Materials and Organic Solids as Active Electrodes in Metal-Free Batteries; Index |
| Record Nr. | UNINA-9910830094303321 |
| New York, N.Y., : Wiley, c1997 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Advances in electrochemical science and engineering . Volume 5 / / edited by Richard C. Alkire ... [et al.]
| Advances in electrochemical science and engineering . Volume 5 / / edited by Richard C. Alkire ... [et al.] |
| Pubbl/distr/stampa | New York, N.Y., : Wiley, c1997 |
| Descrizione fisica | 1 online resource (432 p.) |
| Disciplina |
541.3/7
660.297 |
| Altri autori (Persone) | AlkireR. C. <1941-> |
| Collana | Advances in electrochemical science and engineering |
| Soggetto topico |
Electrochemistry
Chemistry, Physical and theoretical |
| ISBN |
9786611758912
9781281758910 1281758914 9783527616794 3527616799 9783527616886 3527616888 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto | Advances in Electrochemical Science and Engineering; Contents; Marcus Theory in the Qualitative and Quantitative Description of Electrochemiluminescence Phenomena; Electrochemistry of Oxide High-Temperature Superconductors; Flow Rate Dependence of Localized Corrosion in Thermal Power Plant Materials; Polymer Electrolyte Fuel Cells; Graphite, Carbonaceous Materials and Organic Solids as Active Electrodes in Metal-Free Batteries; Index |
| Record Nr. | UNINA-9911019438203321 |
| New York, N.Y., : Wiley, c1997 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Advances in Electrochemical Sensor Applications Using Nano-Structured Materials
| Advances in Electrochemical Sensor Applications Using Nano-Structured Materials |
| Autore | Rajendrachari Shashanka |
| Edizione | [1st ed.] |
| Pubbl/distr/stampa | Cambridge : , : Royal Society of Chemistry, The, , 2025 |
| Descrizione fisica | 1 online resource (501 pages) |
| Disciplina | 660.297 |
| Collana | Issn Series |
| Soggetto topico |
Nanotechnology
Detectors |
| ISBN |
1-83767-529-5
1-83767-528-7 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Cover -- Copyright -- Preface -- Contents -- Chapter 1 A Brief History of Electrochemical Sensors -- 1.1 Introduction -- 1.2 Classification of Electrochemical Sensors -- 1.2.1 Mechanism of Transduction -- 1.2.2 Measurement Type -- 1.2.3 Analyte Type -- 1.2.4 Materials Used -- 1.2.5 Working Principle -- 1.2.6 Area of Application -- 1.2.7 Response Time -- 1.3 Applications of Electrochemical Sensors -- 1.3.1 Environmental Surveillance -- 1.3.1.1 Monitoring Water Quality -- 1.3.1.2 Monitoring Air Quality -- 1.3.2 Health and Medical Services -- 1.3.2.1 Glucose Monitoring -- 1.3.2.2 Biosensors -- 1.3.3 Industrial Process Management -- 1.3.3.1 pH Measurement -- 1.3.3.2 Gas Detection -- 1.3.4 Food Sector -- 1.3.4.1 Food Safety -- 1.3.4.2 Freshness Monitoring -- 1.3.5 Security and Defence -- 1.3.5.1 Explosive Detection -- 1.3.5.2 Chemical Warfare Agent (CWA) Detection -- 1.3.6 Applications in the Automotive Industry: Exhaust Gas Monitoring -- 1.3.7 Applications in Wearable Devices: Fitness and Health Monitoring -- 1.3.8 Energy Conversion and Storage -- 1.3.9 Consumer Electronics: Breathalysers -- 1.3.10 Water and Wastewater Treatment: Monitoring Electrolytes -- 1.4 Advantages of Electrochemical Sensors -- 1.4.1 Higher Sensitivity -- 1.4.2 Selectivity -- 1.4.3 Fast Response Time -- 1.4.4 Low Detection Limits -- 1.4.5 Wide Range of Applications -- 1.5 Disadvantages of Electrochemical Sensors -- 1.5.1 Selectivity Obstacles -- 1.5.2 Requirement for Regular Calibration -- 1.5.3 Analyte Range Restrictions -- 1.5.4 Conditions of Operation -- 1.5.5 Electrode Fouling -- 1.5.6 Reaction Time -- 1.5.7 Limited Lifespan -- 1.5.8 Cost and Complexity -- 1.5.8.1 Cost -- 1.5.8.2 Complexity -- 1.5.9 Gas Permeability -- 1.6 Conclusion -- 1.7 Future Directions -- References -- Chapter 2 Basic Principles of Electrocatalysts -- 2.1 Introduction -- 2.2 Catalyst Types.
2.2.1 Homogeneous Catalysts -- 2.2.2 Heterogeneous Catalysts: Bridging Energy and Sensing -- 2.2.3 Biocatalysts: Pioneering Sensing Technologies -- 2.3 Reaction Mechanisms: Unlocking the Potential of Electrocatalysts -- 2.3.1 HER -- 2.3.2 OER -- 2.3.3 CO2RR -- 2.3.4 Reaction Mechanisms in Catalysts for Sensing -- 2.3.5 Reaction Mechanisms in Catalysts for Energy Materials -- 2.4 Key Considerations in Catalyst Design -- 2.4.1 Catalyst Activity -- 2.4.2 Selectivity -- 2.4.3 Durability -- 2.4.4 Cost-efficiency -- 2.4.5 Poisoning and Deactivation -- 2.5 Conclusion and Future Perspectives -- Abbreviations -- Acknowledgments -- References -- Chapter 3 Discussion of Various Types of Electrochemical Sensing Technology -- 3.1 Introduction -- 3.1.1 Electrochemical Sensors -- 3.2 Classification of Electrochemical Sensors -- 3.2.1 Potentiometric Sensors -- 3.2.2 Amperometric Sensors -- 3.2.3 Conductometric Sensors -- 3.2.4 Impedimetric Sensors -- 3.2.5 Voltammetric Sensor -- 3.2.6 Coulometric Sensors -- 3.3 Key Components and Design of Electrochemical Sensors -- 3.3.1 Modification of Electrodes -- 3.3.1.1 Modified Carbon Paste Electrodes (CPEs) -- 3.3.1.2 Modified Glassy Carbon Electrodes (GCEs) -- 3.3.1.3 Modified Graphene Oxide Electrodes -- 3.3.1.4 Modified Screen-printed Carbon Electrodes -- 3.3.2 Electrolytes -- 3.3.3 Ion-selective Membranes -- 3.3.3.1 Solid-state Membranes -- 3.3.3.2 Liquid and Polymer Membranes -- 3.4 Recent Advancements and Emerging Trends -- 3.4.1 Nanomaterial Integration -- 3.4.2 Microfluidic Devices -- 3.4.3 Aptamer Integration -- 3.4.4 Machine Learning and Data Analysis -- 3.4.5 Point-of-care Diagnostics -- 3.5 Future Perspectives -- 3.5.1 Nanomaterial Integration -- 3.5.2 Biocompatible Materials -- 3.5.3 Microfluidics and Lab-on-a-chip -- 3.5.4 Wireless Communication -- 3.5.5 Machine Learning and Artificial Intelligence. Abbreviations -- References -- Chapter 4 Recent Advances in Nanomaterial-based Electrochemical Sensing Devices -- 4.1 General Aspects of Nanomaterials (NMs), Classification, and Synthesis -- 4.1.1 Classification of NMs -- 4.1.1.1 Carbon-based NMs -- 4.1.1.1.1 Fullerenes -- 4.1.1.1.2 Graphene -- 4.1.1.1.3 CNTs -- 4.1.1.2 Organic NMs -- 4.1.1.3 Inorganic NMs -- 4.1.1.3.1 Metal-based NMs -- 4.1.1.3.1.1 Gold NPs -- 4.1.1.3.1.2 Silver NPs -- 4.1.1.3.2 Metal Oxides -- 4.1.1.3.2.1 Zinc Oxide (ZnO) NMs -- 4.1.1.3.2.2 Titanium Oxide (TiO2) NMs -- 4.1.1.3.3 Metal-Organic Frameworks (MOFs) -- 4.1.2 Synthesis of NMs -- 4.2 What Are Sensors, Biosensors, and Electrochemical Sensing Devices? -- 4.3 Recent Advances in NM-based Electrochemical Sensing Devices, Their Applications, and Recent Studies -- 4.4 Conclusion -- Abbreviations -- References -- Chapter 5 Nanomaterial-incorporated Electrochemical Sensors to Determine Heavy Metal Ions -- 5.1 Introduction -- 5.2 HMs and Pollution -- 5.3 Electroanalytical Techniques Used in HM Sensing -- 5.4 Nanomaterials for Electrochemical Detection of HMs -- 5.4.1 Carbon-based Nanomaterials -- 5.4.1.1 CNTs -- 5.4.1.2 GR and GO -- 5.4.1.3 Other Carbonaceous Materials -- 5.4.2 Metal-based Nanomaterials -- 5.4.3 Metal Oxide-based Nanomaterials -- 5.5 Conclusion -- Acknowledgments -- References -- Chapter 6 Electro-analysis of Food Additives Using Nanomaterial-based Electrochemical Sensors -- 6.1 Introduction -- 6.2 Analysis Methods for Food Additives -- 6.3 Nanomaterials in Electrochemical Methods for the Determination of Food Additives -- 6.4 Preservatives -- 6.5 Antioxidants -- 6.6 Aroma Enhancers -- 6.7 Food Colorants -- 6.8 Enhancers of Nutritional Value -- 6.9 Illegal Food Additives -- 6.10 Conclusion -- Abbreviations -- References. Chapter 7 Nanomaterial-based Electrochemical Sensing Devices for the Determination of Pesticides -- 7.1 Introduction -- 7.2 Pesticides: Definition, Classification, Types, and Uses -- 7.3 Nanomaterials and the Unique Physical and Chemical Features That Make Them Suitable for Sensing Devices -- 7.4 Nanomaterial-based Electrochemical Sensors for the Determination of Pesticides -- 7.5 Conclusions and Future Outlook -- References -- Chapter 8 Nanomaterial-modified Electrodes for the Detection of Various Dyes -- 8.1 Introduction -- 8.2 Basics of Dye Detection -- 8.2.1 Introduction to Dyes and Their Applications -- 8.2.2 Challenges in Dye Detection -- 8.2.3 Role of Electrochemical Sensors for Dye Detection -- 8.3 Nanomaterials in Electrochemical Sensors -- 8.3.1 Nanomaterials in Sensor Modification -- 8.3.2 Advantages of Nanomaterials -- 8.3.3 Methods of Nanomaterial Synthesis -- 8.4 NMEs -- 8.4.1 Basics of Electrodes -- 8.4.2 Electrode Modification with Nanomaterials -- 8.4.3 Types of NME -- 8.4.3.1 Nanoparticles -- 8.4.3.2 Carbon-based Nanomaterials -- 8.4.3.3 Metal Oxide Nanomaterials -- 8.4.3.4 QDs -- 8.4.3.5 Molecularly Imprinted Polymers (MIPs) -- 8.4.3.6 2D Materials -- 8.5 Dye Detection Techniques -- 8.5.1 Dye Detection -- 8.5.1.1 Spectrophotometry -- 8.5.1.2 HPLC (High-performance Liquid Chromatography) -- 8.5.1.3 Colorimetry -- 8.5.1.4 Capillary Electrophoresis -- 8.5.1.5 Fluorescence Spectroscopy -- 8.5.1.6 Electrochemical Detection -- 8.5.1.7 Colorimetric Paper-based Assays -- 8.5.2 Electrochemical Detection Principles -- 8.5.2.1 CV -- 8.5.2.2 Amperometry -- 8.5.2.3 Chronoamperometry -- 8.5.2.4 Impedance Spectroscopy -- 8.5.2.5 Potentiostatic/Galvanostatic Methods -- 8.5.3 Comparison with Other Detection Methods -- 8.5.3.1 Spectrophotometry -- 8.5.3.2 HPLC -- 8.5.3.3 Mass Spectrometry -- 8.5.3.4 Colorimetry -- 8.5.3.5 Titration Methods. 8.5.3.6 Fluorescence Spectroscopy -- 8.6 Applications of NMEs for Dye Detection -- 8.6.1 NMEs for Textile Dye Detection -- 8.6.1.1 CNT-based Electrodes -- 8.6.1.2 Graphene-based Sensors -- 8.6.1.3 Direct Blue 71 Detection -- 8.6.1.4 Reactive Dye Analysis -- 8.6.1.5 Online Monitoring in the Textile Industry -- 8.6.2 Food Coloring Detection (Food Industry Quality Control) -- 8.6.2.1 AuNP-based Sensors -- 8.6.2.2 Graphene-based Electrodes -- 8.6.2.3 Online Monitoring in Food Production -- 8.6.2.4 Compliance with Food Regulations -- 8.6.2.5 Quality Assurance in Beverages -- 8.6.3 Environmental Monitoring (NMEs for Detecting Environmental Dyes and Pollutants) -- 8.6.3.1 Heavy Metal Detection -- 8.6.3.2 Organic Pollutants -- 8.6.3.3 Water Quality Monitoring -- 8.6.3.4 Soil and Air Quality -- 8.6.3.5 Biosensors for Environmental Monitoring -- 8.7 Challenges and Future Directions -- 8.7.1 Current Challenges in Dye Detection -- 8.7.1.1 Selectivity and Interference -- 8.7.1.2 Sensitivity -- 8.7.1.3 Matrix Effects -- 8.7.1.4 Real-time Monitoring -- 8.7.1.5 Environmental Concerns -- 8.7.1.6 Cost-effectiveness -- 8.7.1.7 Regulatory Compliance -- 8.7.1.8 Data Analysis and Interpretation -- 8.7.2 Emerging Trends and Innovations (NMEs for Dye Detection) -- 8.7.2.1 Advanced Nanomaterials -- 8.7.2.2 Multifunctional Nanomaterials -- 8.7.2.3 Printable and Flexible Sensors -- 8.7.2.4 Internet of Things (IoT) Integration -- 8.7.2.5 Machine Learning and Data Analytics -- 8.7.2.6 Point-of-care and Healthcare Applications -- 8.7.2.7 Green and Sustainable Sensors -- 8.7.2.8 3D Printing of Sensors -- 8.7.2.9 Quantum Sensing -- 8.7.2.10 Cross-disciplinary Collaborations -- 8.7.3 The Significance of NMEs in Advancing Dye Detection Technologies -- References -- Chapter 9 Electrochemical Assessment of DNA-based Nanosensors -- 9.1 Introduction. 9.2 Principles of Electrochemical DNA-based Nanosensors. |
| Record Nr. | UNINA-9911069525303321 |
Rajendrachari Shashanka
|
||
| Cambridge : , : Royal Society of Chemistry, The, , 2025 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Berichte der Bunsengesellschaft fur Physikalische Chemie
| Berichte der Bunsengesellschaft fur Physikalische Chemie |
| Pubbl/distr/stampa | Weinheim; Deerfield Beach, FL, : VCH |
| Disciplina | 660.297 |
| ISSN | 0005-9021 |
| Formato | Materiale a stampa |
| Livello bibliografico | Periodico |
| Lingua di pubblicazione | mul |
| Altri titoli varianti |
International journal of physical chemistry
Berichte der Bunsen-Gesellschaft fur Physikalische Chemie |
| Note periodicità | Mensile |
| Record Nr. | UNINA-990008916610403321 |
| Weinheim; Deerfield Beach, FL, : VCH | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Chemically modified electrodes [[electronic resource] /] / edited by Richard C. Alkire, Dieter M. Kolb, Jacek Lipkowski, and Philip N. Ross
| Chemically modified electrodes [[electronic resource] /] / edited by Richard C. Alkire, Dieter M. Kolb, Jacek Lipkowski, and Philip N. Ross |
| Pubbl/distr/stampa | Weinheim, : Wiley-VCH, c2009 |
| Descrizione fisica | 1 online resource (281 p.) |
| Disciplina |
541.3724
660.297 |
| Altri autori (Persone) |
AlkireR. C. <1941->
KolbDieter M LipkowskiJacek RossP. N (Philip N.) |
| Collana | Advances in electrochemical science and engineering |
| Soggetto topico |
Electrodes
Electrochemistry |
| Soggetto genere / forma | Electronic books. |
| ISBN |
1-282-68358-6
9786612683589 3-527-62705-7 3-527-62706-5 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Advances in Electrochemical Science and Engineering; Contents; Preface; List of Contributors; 1 Nanostructured Electrodes with Unique Properties for Biological and Other Applications; 1.1 Introduction; 1.2 High Surface Area Electrodes; 1.2.1 Attachment of Nanoparticles onto Electrodes; 1.2.2 Templating using Membranes; 1.2.3 Templating using Lyotropic Liquid Crystals; 1.2.4 Colloidal Templates; 1.3 Catalytic Properties; 1.4 Exploiting Nanoscale Control to Interface Electrodes with Biomolecules; 1.4.1 Plugging Nanomaterials into Proteins - Nanoparticles
1.4.2 Plugging Nanomaterials into Proteins - Carbon Nanotubes1.4.3 Plugging Nanomaterials into Proteins - Molecular Wires; 1.4.3.1 Nanostructuring Electrodes to Achieve Intimate Connectivity with Biomolecules; 1.4.3.2 Nanostructuring Electrodes using Rigid Molecules; 1.4.3.3 The use of Molecular Wires in Electrochemistry such that Long-Distance Electron Transfer can be Exploited for a Variety of Applications; 1.5 Switchable Surfaces; 1.5.1 Switching Properties of Monolayer Systems; 1.5.2 Control and Enhancement of Electrochemical Reactions using Magnetic Nanostructures on Electrodes 1.6 ConclusionsReferences; 2 Electrochemically Active Polyelectrolyte-Modified Electrodes; 2.1 Introduction; 2.1.1 Chemically Modified Electrodes; 2.1.2 Redox Hydrogels; 2.1.3 Redox Polyelectrolyte Monolayers; 2.1.4 Redox Polymer Brushes and Grafted DNA; 2.1.5 Layer-by-Layer Polyelectrolyte Multilayers; 2.2 Structure; 2.2.1 Polyelectrolye Interpenetration; 2.2.2 Compensation of Polyelectrolyte Charges; 2.2.3 Film Inner Structure; 2.2.4 Effect of the Assembly pH; 2.2.5 Theoretical Description; 2.3 Electrochemical Response; 2.3.1 Ideal Response; 2.3.2 Peak Position and Donnan Potential 2.3.3 Coupling Between the Acid-Base and Redox Equilibria2.3.4 Peak Width; 2.3.5 Nonreversible Electrochemistry: Charge Transport; 2.4 Dynamics of Solvent and Ion Exchange; 2.4.1 Ion Exchange; 2.4.2 Solvent Exchange; 2.4.3 Specific Ionic Effects; 2.4.4 Break-In; 2.5 Molecular Description of Redox Polyelectrolyte-Modified Electrodes; 2.5.1 Formulation of the Molecular Theory; 2.5.2 Comparison with Phenomenological Models, Advantages and Limitations; 2.6 Applications; 2.6.1 Amperometric Enzymatic Electrodes; 2.6.2 Electrochromic Devices; 2.7 Conclusions; References 3 Electrochemistry on Carbon-Nanotube-Modified Surfaces3.1 Introduction; 3.2 Structure and Properties of Carbon Nanotubes; 3.2.1 Structure and Electronic Properties; 3.2.2 Chemical Properties; 3.2.3 Electrochemical Properties; 3.3 Towards the Design of CNT-Modified Electrodes; 3.3.1 Synthesis of CNTs; 3.3.2 CNT Purification Methods; 3.3.3 Chemical and Biochemical Functionalization; 3.3.3.1 Covalent Modification; 3.3.3.2 Noncovalent Modification; 3.3.3.3 Chemical Modification for CNT Sorting; 3.3.3.4 Chemical Doping, Intercalation and Artificial Defects 3.3.4 CNT Deposition on Electrode Surfaces |
| Record Nr. | UNINA-9910139754103321 |
| Weinheim, : Wiley-VCH, c2009 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Chemically modified electrodes [[electronic resource] /] / edited by Richard C. Alkire, Dieter M. Kolb, Jacek Lipkowski, and Philip N. Ross
| Chemically modified electrodes [[electronic resource] /] / edited by Richard C. Alkire, Dieter M. Kolb, Jacek Lipkowski, and Philip N. Ross |
| Pubbl/distr/stampa | Weinheim, : Wiley-VCH, c2009 |
| Descrizione fisica | 1 online resource (281 p.) |
| Disciplina |
541.3724
660.297 |
| Altri autori (Persone) |
AlkireR. C. <1941->
KolbDieter M LipkowskiJacek RossP. N (Philip N.) |
| Collana | Advances in electrochemical science and engineering |
| Soggetto topico |
Electrodes
Electrochemistry |
| ISBN |
1-282-68358-6
9786612683589 3-527-62705-7 3-527-62706-5 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Advances in Electrochemical Science and Engineering; Contents; Preface; List of Contributors; 1 Nanostructured Electrodes with Unique Properties for Biological and Other Applications; 1.1 Introduction; 1.2 High Surface Area Electrodes; 1.2.1 Attachment of Nanoparticles onto Electrodes; 1.2.2 Templating using Membranes; 1.2.3 Templating using Lyotropic Liquid Crystals; 1.2.4 Colloidal Templates; 1.3 Catalytic Properties; 1.4 Exploiting Nanoscale Control to Interface Electrodes with Biomolecules; 1.4.1 Plugging Nanomaterials into Proteins - Nanoparticles
1.4.2 Plugging Nanomaterials into Proteins - Carbon Nanotubes1.4.3 Plugging Nanomaterials into Proteins - Molecular Wires; 1.4.3.1 Nanostructuring Electrodes to Achieve Intimate Connectivity with Biomolecules; 1.4.3.2 Nanostructuring Electrodes using Rigid Molecules; 1.4.3.3 The use of Molecular Wires in Electrochemistry such that Long-Distance Electron Transfer can be Exploited for a Variety of Applications; 1.5 Switchable Surfaces; 1.5.1 Switching Properties of Monolayer Systems; 1.5.2 Control and Enhancement of Electrochemical Reactions using Magnetic Nanostructures on Electrodes 1.6 ConclusionsReferences; 2 Electrochemically Active Polyelectrolyte-Modified Electrodes; 2.1 Introduction; 2.1.1 Chemically Modified Electrodes; 2.1.2 Redox Hydrogels; 2.1.3 Redox Polyelectrolyte Monolayers; 2.1.4 Redox Polymer Brushes and Grafted DNA; 2.1.5 Layer-by-Layer Polyelectrolyte Multilayers; 2.2 Structure; 2.2.1 Polyelectrolye Interpenetration; 2.2.2 Compensation of Polyelectrolyte Charges; 2.2.3 Film Inner Structure; 2.2.4 Effect of the Assembly pH; 2.2.5 Theoretical Description; 2.3 Electrochemical Response; 2.3.1 Ideal Response; 2.3.2 Peak Position and Donnan Potential 2.3.3 Coupling Between the Acid-Base and Redox Equilibria2.3.4 Peak Width; 2.3.5 Nonreversible Electrochemistry: Charge Transport; 2.4 Dynamics of Solvent and Ion Exchange; 2.4.1 Ion Exchange; 2.4.2 Solvent Exchange; 2.4.3 Specific Ionic Effects; 2.4.4 Break-In; 2.5 Molecular Description of Redox Polyelectrolyte-Modified Electrodes; 2.5.1 Formulation of the Molecular Theory; 2.5.2 Comparison with Phenomenological Models, Advantages and Limitations; 2.6 Applications; 2.6.1 Amperometric Enzymatic Electrodes; 2.6.2 Electrochromic Devices; 2.7 Conclusions; References 3 Electrochemistry on Carbon-Nanotube-Modified Surfaces3.1 Introduction; 3.2 Structure and Properties of Carbon Nanotubes; 3.2.1 Structure and Electronic Properties; 3.2.2 Chemical Properties; 3.2.3 Electrochemical Properties; 3.3 Towards the Design of CNT-Modified Electrodes; 3.3.1 Synthesis of CNTs; 3.3.2 CNT Purification Methods; 3.3.3 Chemical and Biochemical Functionalization; 3.3.3.1 Covalent Modification; 3.3.3.2 Noncovalent Modification; 3.3.3.3 Chemical Modification for CNT Sorting; 3.3.3.4 Chemical Doping, Intercalation and Artificial Defects 3.3.4 CNT Deposition on Electrode Surfaces |
| Record Nr. | UNINA-9910831027003321 |
| Weinheim, : Wiley-VCH, c2009 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Chemically modified electrodes / / edited by Richard C. Alkire, Dieter M. Kolb, Jacek Lipkowski, and Philip N. Ross
| Chemically modified electrodes / / edited by Richard C. Alkire, Dieter M. Kolb, Jacek Lipkowski, and Philip N. Ross |
| Pubbl/distr/stampa | Weinheim, : Wiley-VCH, c2009 |
| Descrizione fisica | 1 online resource (281 p.) |
| Disciplina |
541.3724
660.297 |
| Altri autori (Persone) |
AlkireR. C. <1941->
KolbDieter M LipkowskiJacek RossP. N (Philip N.) |
| Collana | Advances in electrochemical science and engineering |
| Soggetto topico |
Electrodes
Electrochemistry |
| ISBN |
1-282-68358-6
9786612683589 3-527-62705-7 3-527-62706-5 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Advances in Electrochemical Science and Engineering; Contents; Preface; List of Contributors; 1 Nanostructured Electrodes with Unique Properties for Biological and Other Applications; 1.1 Introduction; 1.2 High Surface Area Electrodes; 1.2.1 Attachment of Nanoparticles onto Electrodes; 1.2.2 Templating using Membranes; 1.2.3 Templating using Lyotropic Liquid Crystals; 1.2.4 Colloidal Templates; 1.3 Catalytic Properties; 1.4 Exploiting Nanoscale Control to Interface Electrodes with Biomolecules; 1.4.1 Plugging Nanomaterials into Proteins - Nanoparticles
1.4.2 Plugging Nanomaterials into Proteins - Carbon Nanotubes1.4.3 Plugging Nanomaterials into Proteins - Molecular Wires; 1.4.3.1 Nanostructuring Electrodes to Achieve Intimate Connectivity with Biomolecules; 1.4.3.2 Nanostructuring Electrodes using Rigid Molecules; 1.4.3.3 The use of Molecular Wires in Electrochemistry such that Long-Distance Electron Transfer can be Exploited for a Variety of Applications; 1.5 Switchable Surfaces; 1.5.1 Switching Properties of Monolayer Systems; 1.5.2 Control and Enhancement of Electrochemical Reactions using Magnetic Nanostructures on Electrodes 1.6 ConclusionsReferences; 2 Electrochemically Active Polyelectrolyte-Modified Electrodes; 2.1 Introduction; 2.1.1 Chemically Modified Electrodes; 2.1.2 Redox Hydrogels; 2.1.3 Redox Polyelectrolyte Monolayers; 2.1.4 Redox Polymer Brushes and Grafted DNA; 2.1.5 Layer-by-Layer Polyelectrolyte Multilayers; 2.2 Structure; 2.2.1 Polyelectrolye Interpenetration; 2.2.2 Compensation of Polyelectrolyte Charges; 2.2.3 Film Inner Structure; 2.2.4 Effect of the Assembly pH; 2.2.5 Theoretical Description; 2.3 Electrochemical Response; 2.3.1 Ideal Response; 2.3.2 Peak Position and Donnan Potential 2.3.3 Coupling Between the Acid-Base and Redox Equilibria2.3.4 Peak Width; 2.3.5 Nonreversible Electrochemistry: Charge Transport; 2.4 Dynamics of Solvent and Ion Exchange; 2.4.1 Ion Exchange; 2.4.2 Solvent Exchange; 2.4.3 Specific Ionic Effects; 2.4.4 Break-In; 2.5 Molecular Description of Redox Polyelectrolyte-Modified Electrodes; 2.5.1 Formulation of the Molecular Theory; 2.5.2 Comparison with Phenomenological Models, Advantages and Limitations; 2.6 Applications; 2.6.1 Amperometric Enzymatic Electrodes; 2.6.2 Electrochromic Devices; 2.7 Conclusions; References 3 Electrochemistry on Carbon-Nanotube-Modified Surfaces3.1 Introduction; 3.2 Structure and Properties of Carbon Nanotubes; 3.2.1 Structure and Electronic Properties; 3.2.2 Chemical Properties; 3.2.3 Electrochemical Properties; 3.3 Towards the Design of CNT-Modified Electrodes; 3.3.1 Synthesis of CNTs; 3.3.2 CNT Purification Methods; 3.3.3 Chemical and Biochemical Functionalization; 3.3.3.1 Covalent Modification; 3.3.3.2 Noncovalent Modification; 3.3.3.3 Chemical Modification for CNT Sorting; 3.3.3.4 Chemical Doping, Intercalation and Artificial Defects 3.3.4 CNT Deposition on Electrode Surfaces |
| Record Nr. | UNINA-9911020210003321 |
| Weinheim, : Wiley-VCH, c2009 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Diffraction and spectroscopic methods in electrochemistry [[electronic resource] /] / edited by Richard C. Alkire ... [et al.]
| Diffraction and spectroscopic methods in electrochemistry [[electronic resource] /] / edited by Richard C. Alkire ... [et al.] |
| Pubbl/distr/stampa | Weinheim, : Wiley-VCH |
| Descrizione fisica | 1 online resource (447 p.) |
| Disciplina |
541.3/7
660.297 |
| Altri autori (Persone) | AlkireR. C. <1941-> |
| Collana | Advances in electrochemical science and engineering |
| Soggetto topico |
Chemical engineering
Electrochemistry |
| Soggetto genere / forma | Electronic books. |
| ISBN |
1-282-13984-3
9786612139840 3-527-61681-0 3-527-61691-8 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Advances in Electrochemical Science and Engineering Volume 9 Diffraction and Spectroscopic Methods in Electrochemistry; Series Preface; Contents; Volume Preface; List of Contributors; 1 In-situ X-ray Diffraction Studies of the Electrode/Solution Interface; 1.1 Introduction; 1.2 Experimental; 1.3 Adsorbate-induced Restructuring of Metal Substrates; 1.3.1 Surface Relaxation; 1.3.1.1 Pt Monometallic and Bimetallic Surfaces; 1.3.1.2 Group IB Metals; 1.3.2 Surface Reconstruction; 1.4 Adlayer Structures; 1.4.1 Anion Structures; 1.4.2 CO Ordering on the Pt(111) Surface
1.4.3 Underpotential Deposition (UPD)1.5 Reactive Metals and Oxides; 1.6 Conclusions and Future Directions; Acknowledgments; References; 2 UV-visible Reflectance Spectroscopy of Thin Organic Films at Electrode Surfaces; 2.1 Introduction; 2.2 The Basis of UV-visible Reflection Measurement at an Electrode Surface; 2.3 Absolute Reflection Spectrum versus Modulated Reflection Spectrum; 2.4 Wavelength-modulated UV-visible Reflectance Spectroscopy; 2.5 Potential-modulated UV-visible Reflectance Spectroscopy; 2.6 Instrumentation of the Potential-modulated UV-visible Reflection Measurement 2.7 ER Measurements for Redox-active Thin Organic Films2.8 Interpretation of the Reflection Spectrum; 2.9 Reflection Measurement at Special Electrode Configurations; 2.10 Estimation of the Molecular Orientation on the Electrode Surface; 2.10.1 Estimation of the Molecular Orientation on the Electrode Surface using the Redox ER Signal; 2.10.2 Estimation of the Molecular Orientation on the Electrode Surface using the Stark Effect ER Signal; 2.11 Measurement of Electron Transfer Rate using ER Measurement; 2.11.1 Redox ER Signal in Frequency Domain 2.11.2 Examples of Electron Transfer Rate Measurement using ER Signal2.11.3 Improvement in Data Analysis; 2.11.4 Combined Analysis of Impedance and Modulation Spectroscopic Signals; 2.11.5 Upper Limit of Measurable Rate Constant; 2.11.6 Rate Constant Measurement using an ER Voltammogram; 2.12 ER Signal Originated from Non-Faradaic Processes - a Quick Overview; 2.13 ER Signal with Harmonics Higher than the Fundamental Modulation Frequency; 2.14 Distinguishing between Two Simultaneously Occurring Electrode Processes 2.15 Some Recent Examples of the Application of ER Measurement for a Functional Electrode2.16 Scope for Future Development of UV-visible Reflection Measurements; 2.16.1 New Techniques in UV-visible Reflection Measurements; 2.16.2 Remarks on the Scope for Future Development of UV-visible Reflection Measurements; Acknowledgments; References; 3 Epi-fluorescence Microscopy Studies of Potential Controlled Changes in Adsorbed Thin Organic Films at Electrode Surfaces; 3.1 Introduction; 3.2 Fluorescence Microscopy and Fluorescence Probes; 3.3 Fluorescence near Metal Surfaces 3.4 Description of a Fluorescence Microscope for Electrochemical Studies |
| Record Nr. | UNINA-9910146268803321 |
| Weinheim, : Wiley-VCH | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Diffraction and spectroscopic methods in electrochemistry [[electronic resource] /] / edited by Richard C. Alkire ... [et al.]
| Diffraction and spectroscopic methods in electrochemistry [[electronic resource] /] / edited by Richard C. Alkire ... [et al.] |
| Pubbl/distr/stampa | Weinheim, : Wiley-VCH |
| Descrizione fisica | 1 online resource (447 p.) |
| Disciplina |
541.3/7
660.297 |
| Altri autori (Persone) | AlkireR. C. <1941-> |
| Collana | Advances in electrochemical science and engineering |
| Soggetto topico |
Chemical engineering
Electrochemistry |
| ISBN |
1-282-13984-3
9786612139840 3-527-61681-0 3-527-61691-8 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Advances in Electrochemical Science and Engineering Volume 9 Diffraction and Spectroscopic Methods in Electrochemistry; Series Preface; Contents; Volume Preface; List of Contributors; 1 In-situ X-ray Diffraction Studies of the Electrode/Solution Interface; 1.1 Introduction; 1.2 Experimental; 1.3 Adsorbate-induced Restructuring of Metal Substrates; 1.3.1 Surface Relaxation; 1.3.1.1 Pt Monometallic and Bimetallic Surfaces; 1.3.1.2 Group IB Metals; 1.3.2 Surface Reconstruction; 1.4 Adlayer Structures; 1.4.1 Anion Structures; 1.4.2 CO Ordering on the Pt(111) Surface
1.4.3 Underpotential Deposition (UPD)1.5 Reactive Metals and Oxides; 1.6 Conclusions and Future Directions; Acknowledgments; References; 2 UV-visible Reflectance Spectroscopy of Thin Organic Films at Electrode Surfaces; 2.1 Introduction; 2.2 The Basis of UV-visible Reflection Measurement at an Electrode Surface; 2.3 Absolute Reflection Spectrum versus Modulated Reflection Spectrum; 2.4 Wavelength-modulated UV-visible Reflectance Spectroscopy; 2.5 Potential-modulated UV-visible Reflectance Spectroscopy; 2.6 Instrumentation of the Potential-modulated UV-visible Reflection Measurement 2.7 ER Measurements for Redox-active Thin Organic Films2.8 Interpretation of the Reflection Spectrum; 2.9 Reflection Measurement at Special Electrode Configurations; 2.10 Estimation of the Molecular Orientation on the Electrode Surface; 2.10.1 Estimation of the Molecular Orientation on the Electrode Surface using the Redox ER Signal; 2.10.2 Estimation of the Molecular Orientation on the Electrode Surface using the Stark Effect ER Signal; 2.11 Measurement of Electron Transfer Rate using ER Measurement; 2.11.1 Redox ER Signal in Frequency Domain 2.11.2 Examples of Electron Transfer Rate Measurement using ER Signal2.11.3 Improvement in Data Analysis; 2.11.4 Combined Analysis of Impedance and Modulation Spectroscopic Signals; 2.11.5 Upper Limit of Measurable Rate Constant; 2.11.6 Rate Constant Measurement using an ER Voltammogram; 2.12 ER Signal Originated from Non-Faradaic Processes - a Quick Overview; 2.13 ER Signal with Harmonics Higher than the Fundamental Modulation Frequency; 2.14 Distinguishing between Two Simultaneously Occurring Electrode Processes 2.15 Some Recent Examples of the Application of ER Measurement for a Functional Electrode2.16 Scope for Future Development of UV-visible Reflection Measurements; 2.16.1 New Techniques in UV-visible Reflection Measurements; 2.16.2 Remarks on the Scope for Future Development of UV-visible Reflection Measurements; Acknowledgments; References; 3 Epi-fluorescence Microscopy Studies of Potential Controlled Changes in Adsorbed Thin Organic Films at Electrode Surfaces; 3.1 Introduction; 3.2 Fluorescence Microscopy and Fluorescence Probes; 3.3 Fluorescence near Metal Surfaces 3.4 Description of a Fluorescence Microscope for Electrochemical Studies |
| Record Nr. | UNINA-9910830518003321 |
| Weinheim, : Wiley-VCH | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
