Efficiency and sustainability in the energy and chemical industries : scientific principles and case studies / / Krishnan Sankaranarayanan, Hedzer J. van der Kooi, Jakob de Swaan Arons |
Autore | Sankaranarayanan Krishnan |
Edizione | [2nd ed.] |
Pubbl/distr/stampa | Boca Raton : , : CRC Press, , 2010 |
Descrizione fisica | 1 online resource (396 p.) |
Disciplina | 660/.2969 |
Altri autori (Persone) |
Swaan AronsJakob de
KooiHedzer van der |
Collana | Green chemistry and chemical engineering |
Soggetto topico |
Energy dissipation
Energy dissipation - Prevention Electric power-plants - Efficiency Chemical engineering |
Soggetto genere / forma | Electronic books. |
ISBN |
0-429-11065-0
1-4398-7607-X 1-4398-1471-6 |
Formato | Materiale a stampa |
Livello bibliografico | Monografia |
Lingua di pubblicazione | eng |
Nota di contenuto |
Front cover; Contents; Preface; About This Book; Acknowledgments; Authors; Part I: Basics; Chapter 1: Introduction; Chapter 2: Thermodynamics Revisited; Chapter 3: Energy "Consumption" and Lost Work; Chapter 4: Entropy Generation: Cause and Effect; Chapter 5: Reduction of Lost Work; Part II: Thermodynamic Analysis of Processes; Chapter 6: Exergy, a Convenient Concept; Chapter 7: Chemical Exergy; Chapter 8: Simple Applications; Part III Case Studies; Chapter 9: Energy Conversion; Chapter 10: Separations; Chapter 11: Chemical Conversion; Chapter 12: A Note on Life Cycle Analysis
Part IV SustainabilityChapter 13: Sustainable Development; Chapter 14: Efficiency and Sustainability in the Chemical Process Industry; Chapter 15: CO2 Capture and Sequestration; Chapter 16: Sense and Nonsense of Green Chemistry and Biofuels; Chapter 17: Solar Energy Conversion; Chapter 18: Hydrogen: Fuel of the Future?; Chapter 19: Future Trends; Epilogue; Problems; Index; Back cover |
Record Nr. | UNINA-9910459148303321 |
Sankaranarayanan Krishnan | ||
Boca Raton : , : CRC Press, , 2010 | ||
Materiale a stampa | ||
Lo trovi qui: Univ. Federico II | ||
|
Physical and chemical equilibrium for chemical engineers [[electronic resource] /] / Noel de Nevers |
Autore | De Nevers Noel <1932-> |
Edizione | [2nd ed.] |
Pubbl/distr/stampa | Hoboken, N.J., : Wiley, c2012 |
Descrizione fisica | 1 recurso en línea (382 p.) : il |
Disciplina | 660/.2969 |
Soggetto topico |
Thermodynamics
Chemical engineering |
ISBN |
1-299-47547-7
1-118-13531-8 1-118-13533-4 1-118-13534-2 |
Classificazione | TEC009010 |
Formato | Materiale a stampa |
Livello bibliografico | Monografia |
Lingua di pubblicazione | eng |
Record Nr. | UNINA-9910137562403321 |
De Nevers Noel <1932-> | ||
Hoboken, N.J., : Wiley, c2012 | ||
Materiale a stampa | ||
Lo trovi qui: Univ. Federico II | ||
|
Physical and chemical equilibrium for chemical engineers / / Noel de Nevers |
Autore | De Nevers Noel <1932-> |
Edizione | [2nd ed.] |
Pubbl/distr/stampa | Hoboken, N.J., : Wiley, c2012 |
Descrizione fisica | 1 recurso en línea (382 p.) : il |
Disciplina | 660/.2969 |
Soggetto topico |
Thermodynamics
Chemical engineering |
ISBN |
1-299-47547-7
1-118-13531-8 1-118-13533-4 1-118-13534-2 |
Classificazione | TEC009010 |
Formato | Materiale a stampa |
Livello bibliografico | Monografia |
Lingua di pubblicazione | eng |
Nota di contenuto |
PHYSICAL AND CHEMICAL EQUILIBRIUM FOR CHEMICAL ENGINEERS -- CONTENTS -- Preface -- Nomenclature -- About the Author -- 1 Introduction to Equilibrium -- 1.1 Why Study Equilibrium? -- 1.2 Stability and Equilibrium -- 1.3 Time Scales and the Approach to Equilibrium -- 1.4 Looking Ahead, Gibbs Energy -- 1.5 Units, Conversion Factors, and Notation -- 1.6 Reality and Equations -- 1.7 Phases and Phase Diagrams -- 1.8 The Plan of this Book -- 1.9 Summary -- References -- 2 Basic Thermodynamics -- 2.1 Conservation and Accounting -- 2.2 Conservation of Mass -- 2.3 Conservation of Energy -- the First Law of Thermodynamics -- 2.4 The Second Law of Thermodynamics -- 2.4.1 Reversibility -- 2.4.2 Entropy -- 2.5 Convenience Properties -- 2.6 Using the First and Second Laws -- 2.7 Datums and Reference States -- 2.8 Measurable and Immeasurable Properties -- 2.9 Work and Heat -- 2.10 The Property Equation -- 2.11 Equations of State (EOS) -- 2.11.1 EOSs Based on Theory -- 2.11.2 EOSs Based on Pure Data Fitting -- 2.12 Corresponding States -- 2.13 Departure Functions -- 2.14 The Properties of Mixtures -- 2.15 The Combined First and Second Law Statement -- Reversible Work -- 2.16 Summary -- References -- 3 The Simplest Phase Equilibrium Examples and Some Simple Estimating Rules -- 3.1 Some General Statements About Equilibrium -- 3.2 The Simplest Example of Phase Equilibrium -- 3.2.1 A Digression, the Distinction between Vapor and Gas -- 3.2.2 Back to the Simplest Equilibrium -- 3.3 The Next Level of Complexity in Phase Equilibrium -- 3.4 Some Simple Estimating Rules: Raoult's and Henry's "Laws" -- 3.5 The General Two-Phase Equilibrium Calculation -- 3.6 Some Simple Applications of Raoult's and Henry's Laws -- 3.7 The Uses and Limits of Raoult's and Henry's Laws -- 3.8 Summary -- References -- 4 Minimization of Gibbs Energy.
4.1 The Fundamental Thermodynamic Criterion of Phase and Chemical Equilibrium -- 4.2 The Criterion of Equilibrium Applied to Two Nonreacting Equilibrium Phases -- 4.3 The Criterion of Equilibrium Applied to Chemical Reactions -- 4.4 Simple Gibbs Energy Diagrams -- 4.4.1 Comparison with Enthalpy and Entropy -- 4.4.2 Gibbs Energy Diagrams for Pressure-Driven Phase Changes -- 4.4.3 Gibbs Energy Diagrams for Chemical Reactions -- 4.5 Le Chatelier's Principle -- 4.6 Summary -- References -- 5 Vapor Pressure, the Clapeyron Equation, and Single Pure Chemical Species Phase Equilibrium -- 5.1 Measurement of Vapor Pressure -- 5.2 Reporting Vapor-Pressure Data -- 5.2.1 Normal Boiling Point (NBP) -- 5.3 The Clapeyron Equation -- 5.4 The Clausius-Clapeyron Equation -- 5.5 The Accentric Factor -- 5.6 The Antoine Equation and Other Data-Fitting Equations -- 5.6.1 Choosing a Vapor-Pressure Equation -- 5.7 Applying the Clapeyron Equation to Other Kinds of Equilibrium -- 5.8 Extrapolating Vapor-Pressure Curves -- 5.9 Vapor Pressure of Solids -- 5.10 Vapor Pressures of Mixtures -- 5.11 Summary -- References -- 6 Partial Molar Properties -- 6.1 Partial Molar Properties -- 6.2 The Partial Molar Equation -- 6.3 Tangent Slopes -- 6.4 Tangent Intercepts -- 6.5 The Two Equations for Partial Molar Properties -- 6.6 Using the Idea of Tangent Intercepts -- 6.7 Partial Mass Properties -- 6.8 Heats of Mixing and Partial Molar Enthalpies -- 6.8.1 Differential Heat of Mixing -- 6.8.2 Integral Heat of Mixing -- 6.9 The Gibbs-Duhem Equation and the Counterintuitive Behavior of the Chemical Potential -- 6.10 Summary -- References -- 7 Fugacity, Ideal Solutions, Activity, Activity Coefficient -- 7.1 Why Fugacity? -- 7.2 Fugacity Defined -- 7.3 The Use of the Fugacity -- 7.4 Pure Substance Fugacities -- 7.4.1 The Fugacity of Pure Gases -- 7.4.2 The Fugacity of Pure Liquids and Solids. 7.5 Fugacities of Species in Mixtures -- 7.6 Mixtures of Ideal Gases -- 7.7 Why Ideal Solutions? -- 7.8 Ideal Solutions Defined -- 7.8.1 The Consequences of the Ideal Solution Definition -- 7.9 Why Activity and Activity Coefficients? -- 7.10 Activity and Activity Coefficients Defined -- 7.11 Fugacity Coefficient for Pure Gases and Gas Mixtures -- 7.12 Estimating Fugacities of Individual Species in Gas Mixtures -- 7.12.1 Fugacities from Gas PvT Data -- 7.12.2 Fugacities from an EOS for Gas Mixtures -- 7.12.3 The Lewis and Randall (L-R) Fugacity Rule -- 7.12.4 Other Mixing Rules -- 7.13 Liquid Fugacities from Vapor-Liquid Equilibrium -- 7.14 Summary -- References -- 8 Vapor-Liquid Equilibrium (VLE) at Low Pressures -- 8.1 Measurement of VLE -- 8.2 Presenting Experimental VLE Data -- 8.3 The Mathematical Treatment of Low-Pressure VLE Data -- 8.3.1 Raoult's Law Again -- 8.4 The Four Most Common Types of Low-Pressure VLE -- 8.4.1 Ideal Solution Behavior (Type I) -- 8.4.2 Positive Deviations from Ideal Solution Behavior (Type II) -- 8.4.3 Negative Deviations from Ideal Solution Behavior (Type III) -- 8.4.4 Azeotropes -- 8.4.5 Two-Liquid Phase or Heteroazeotropes (Type IV) -- 8.4.6 Zero Solubility and Steam Distillation -- 8.4.7 Distillation of the Four Types of Behavior -- 8.5 Gas-Liquid Equilibrium, Henry's Law Again -- 8.6 The Effect of Modest Pressures on VLE -- 8.6.1 Liquids -- 8.6.2 Gases, the L-R Rule -- 8.7 Standard States Again -- 8.8 Low-Pressure VLE Calculations -- 8.8.1 Bubble-Point Calculations -- 8.8.1.1 Temperature-Specified Bubble Point -- 8.8.1.2 Pressure-Specified Bubble Point -- 8.8.2 Dew-Point Calculations -- 8.8.2.1 Temperature-Specified Dew Point -- 8.8.2.2 Pressure-Specified Dew Point -- 8.8.3 Isothermal Flashes (T- and P-Specified Flashes) -- 8.8.4 Adiabatic Flashes -- 8.9 Traditional K-Factor Methods. 8.10 More Uses for Raoult's Law -- 8.10.1 Nonvolatile Solutes, Boiling-Point Elevation -- 8.10.2 Freezing-Point Depression -- 8.10.3 Colligative Properties of Solutions -- 8.11 Summary -- References -- 9 Correlating and Predicting Nonideal VLE -- 9.1 The Most Common Observations of Liquid-Phase Activity Coefficients -- 9.1.1 Why Nonideal Behavior? -- 9.1.2 The Shapes of ln, γ - x Curves -- 9.2 Limits on Activity Coefficient Correlations, the Gibbs-Duhem Equation -- 9.3 Excess Gibbs Energy and Activity Coefficient Equations -- 9.4 Activity Coefficients at Infinite Dilution -- 9.5 Effects of Pressure and Temperature on Liquid-Phase Activity Coefficients -- 9.5.1 Effect of Pressure Changes on Liquid-Phase Activity Coefficients -- 9.5.2 Effect of Temperature Changes on Liquid-Phase Activity Coefficients -- 9.6 Ternary and Multispecies VLE -- 9.6.1 Liquid-Phase Activity Coefficients for Ternary Mixtures -- 9.7 Vapor-Phase Nonideality -- 9.8 VLE from EOS -- 9.9 Solubility Parameter -- 9.10 The Solubility of Gases in Liquids, Henry's Law Again -- 9.11 Summary -- References -- 10 Vapor-Liquid Equilibrium (VLE) at High Pressures -- 10.1 Critical Phenomena of Pure Species -- 10.2 Critical Phenomena of Mixtures -- 10.3 Estimating High-Pressure VLE -- 10.3.1 Empirical K-Value Correlations -- 10.3.2 Estimation Methods for Each Phase Separately, Not Based on Raoult's Law -- 10.3.3 Estimation Methods Based on Cubic EOSs -- 10.4 Computer Solutions -- 10.5 Summary -- References -- 11 Liquid-Liquid, Liquid-Solid, and Gas-Solid Equilibrium -- 11.1 Liquid-Liquid Equilibrium (LLE) -- 11.2 The Experimental Determination of LLE -- 11.2.1 Reporting and Presenting LLE Data -- 11.2.2 Practically Insoluble Liquid Pairs at 25ºC -- 11.2.3 Partially Soluble Liquid Pairs at 25ºC -- 11.2.4 Miscible Liquid Pairs at 25ºC -- 11.2.5 Ternary LLE at 25ºC. 11.2.6 LLE at Temperatures Other Than 25ºC -- 11.3 The Elementary Theory of LLE -- 11.4 The Effect of Pressure on LLE -- 11.5 Effect of Temperature on LLE -- 11.6 Distribution Coefficients -- 11.7 Liquid-Solid Equilibrium (LSE) -- 11.7.1 One-Species LSE -- 11.7.2 The Experimental Determination of LSE -- 11.7.3 Presenting LSE Data -- 11.7.4 Eutectics -- 11.7.5 Gas Hydrates (Clathrates) -- 11.8 The Elementary Thermodynamics of LSE -- 11.9 Gas-Solid Equilibrium (GSE) at Low Pressures -- 11.10 GSE at High Pressures -- 11.11 Gas-Solid Adsorption, Vapor-Solid Adsorption -- 11.11.1 Langmuir's Adsorption Theory -- 11.11.2 Vapor-solid Adsorption, BET Theory -- 11.11.3 Adsorption from Mixtures -- 11.11.4 Heat of Adsorption -- 11.11.5 Hysteresis -- 11.12 Summary -- References -- 12 Chemical Equilibrium -- 12.1 Introduction to Chemical Reactions and Chemical Equilibrium -- 12.2 Formal Description of Chemical Reactions -- 12.3 Minimizing Gibbs Energy -- 12.4 Reaction Rates, Energy Barriers, Catalysis, and Equilibrium -- 12.5 The Basic Thermodynamics of Chemical Reactions and Its Convenient Formulations -- 12.5.1 The Law of Mass Action and Equilibrium Constants -- 12.6 Calculating Equilibrium Constants from Gibbs Energy Tables and then Using Equilibrium Constants to Calculate Equilibrium Concentrations -- 12.6.1 Change of Reactant Concentration, Reaction Coordinate -- 12.6.2 Reversible and Irreversible Reactions -- 12.7 More on Standard States -- 12.8 The Effect of Temperature on Chemical Reaction Equilibrium -- 12.9 The Effect of Pressure on Chemical Reaction Equilibrium -- 12.9.1 Ideal Solution of Ideal Gases -- 12.9.2 Nonideal Solution, Nonideal Gases -- 12.9.3 Liquids and Solids -- 12.10 The Effect of Nonideal Solution Behavior -- 12.10.1 Liquid-Phase Nonideality -- 12.11 Other Forms of K -- 12.12 Summary -- References. 13 Equilibrium in Complex Chemical Reactions. |
Record Nr. | UNINA-9910824679103321 |
De Nevers Noel <1932-> | ||
Hoboken, N.J., : Wiley, c2012 | ||
Materiale a stampa | ||
Lo trovi qui: Univ. Federico II | ||
|
Thermodynamics, solubility, and environmental issues [[electronic resource] /] / Trevor M. Letcher |
Autore | Letcher T. M (Trevor M.) |
Edizione | [1st ed.] |
Pubbl/distr/stampa | Amsterdam ; ; Boston, : Elsevier, c2007 |
Descrizione fisica | 1 online resource (493 p.) |
Disciplina | 660/.2969 |
Soggetto topico |
Thermodynamics - Industrial applications - Environmental aspects
Solubility - Environmental aspects |
Soggetto genere / forma | Electronic books. |
ISBN |
1-281-05114-4
9786611051143 0-08-048103-5 |
Formato | Materiale a stampa |
Livello bibliografico | Monografia |
Lingua di pubblicazione | eng |
Nota di contenuto |
Front cover; Thermodynamics, Solubility and Environmental Issues; Copyright page; Preface; Foreword; List of Contributors; Table of Contents; Part I: Basic Theory and Modelling; Chapter 1. An Introduction to Modelling of Pollutants in the Environment; 1. Introduction; 2. Partition Coefficients; 3. Model Environments; 4. Equilibrium Partition; 5. Environmental Distribution; 6. Environmental Distribution Using a Flow Model; 7. Accumulation of Chemicals in the Food Chain; Chapter 2. Modeling the Solubility in Water of Environmentally Important Organic Compounds; 1. Introduction
2. Quantum Chemistry Methods 3. Experiment-Based QSPR Modeling; 4. Structure-Based QSPR Modeling; 5. The Quantum-Connectivity Indices; 6. Modeling Solubility with Quantum-Connectivity; 7. Concluding Remarks; Chapter 3. Modeling of Contaminant Leaching; 1. Overview of Significance; 2. Geochemical Modeling; 3. Summary; Part II: Industry and Mining; Chapter 4. Supercritical Fluids and Reductions in Environmental Pollution; 1. Introduction; 2. Supercritical Fluids; 3. References for Thermodynamic Properties of Supercritical Fluids 4. Solubility of Electrolytes and Non-Electrolytes in Supercritical Fluids5. Structure of Supercritical Water; 6. Application of Supercritical Fluids for Reducing Pollutants; 7. Concluding Remarks; Chapter 5. Phase Equilibrium Studies on Ionic Liquid Systems for Industrial Separation Processes of Complex Organic Mixtures; 1. Introduction; 2. Solubility Studies on Ionic Liquid-Organic Mixtures and Application to Liquid-Liquid Extraction; 3. The Determination of Activity Coefficients at Infinite Dilution for the Selection of Entrainers in Extractive Distillation 4. Assessment of the Potential of Ionic Liquids as Solvents in Separation Processes 5. Conclusion; Appendix I: List of Abbreviations for Ionic Liquid Nomenclature; Chapter 6. Environmental and Solubility Issues Related to Novel Corrosion Control; 1. Introduction; 2. Corrosion of Industrially Important Metals; 3. The Layers Protecting the Base Metals; 4. Super primers on Metals; 5. Summary/Conclusions; Chapter 7. The Behavior of Iron and Aluminum in Acid Mine Drainage: Specialization, Mineralogy, and Environmental Significance; 1. Introduction 2. Geochemistry and Mineralogy of Iron and Aluminum in AMD 3. Environmental Significance; 4. Conclusions; Part III: Radioactive Wastes; Chapter 8. An Evaluation of Solubility Limits on Maximum Uranium Concentrations in Groundwater; 1. Introduction; 2. Geologic Setting of the Tono Uranium Deposit; 3. Geochemical Constraints on Uranium Solubility; 4. Evaluation of Uranium Solubility; 5. Conclusions; Chapter 9. Leaching from Cementitious Materials Used in Radioactive Waste Disposal Sites; 1. Introduction; 2. Radioactive Waste Disposal Site and Concrete; 3. Leaching from Cementitious Materials 4. Method for Predicting Durability of Concrete |
Record Nr. | UNINA-9910457221003321 |
Letcher T. M (Trevor M.) | ||
Amsterdam ; ; Boston, : Elsevier, c2007 | ||
Materiale a stampa | ||
Lo trovi qui: Univ. Federico II | ||
|
Thermodynamics, solubility, and environmental issues [[electronic resource] /] / Trevor M. Letcher |
Autore | Letcher T. M (Trevor M.) |
Edizione | [1st ed.] |
Pubbl/distr/stampa | Amsterdam ; ; Boston, : Elsevier, c2007 |
Descrizione fisica | 1 online resource (493 p.) |
Disciplina | 660/.2969 |
Soggetto topico |
Thermodynamics - Industrial applications - Environmental aspects
Solubility - Environmental aspects |
ISBN |
1-281-05114-4
9786611051143 0-08-048103-5 |
Formato | Materiale a stampa |
Livello bibliografico | Monografia |
Lingua di pubblicazione | eng |
Nota di contenuto |
Front cover; Thermodynamics, Solubility and Environmental Issues; Copyright page; Preface; Foreword; List of Contributors; Table of Contents; Part I: Basic Theory and Modelling; Chapter 1. An Introduction to Modelling of Pollutants in the Environment; 1. Introduction; 2. Partition Coefficients; 3. Model Environments; 4. Equilibrium Partition; 5. Environmental Distribution; 6. Environmental Distribution Using a Flow Model; 7. Accumulation of Chemicals in the Food Chain; Chapter 2. Modeling the Solubility in Water of Environmentally Important Organic Compounds; 1. Introduction
2. Quantum Chemistry Methods 3. Experiment-Based QSPR Modeling; 4. Structure-Based QSPR Modeling; 5. The Quantum-Connectivity Indices; 6. Modeling Solubility with Quantum-Connectivity; 7. Concluding Remarks; Chapter 3. Modeling of Contaminant Leaching; 1. Overview of Significance; 2. Geochemical Modeling; 3. Summary; Part II: Industry and Mining; Chapter 4. Supercritical Fluids and Reductions in Environmental Pollution; 1. Introduction; 2. Supercritical Fluids; 3. References for Thermodynamic Properties of Supercritical Fluids 4. Solubility of Electrolytes and Non-Electrolytes in Supercritical Fluids5. Structure of Supercritical Water; 6. Application of Supercritical Fluids for Reducing Pollutants; 7. Concluding Remarks; Chapter 5. Phase Equilibrium Studies on Ionic Liquid Systems for Industrial Separation Processes of Complex Organic Mixtures; 1. Introduction; 2. Solubility Studies on Ionic Liquid-Organic Mixtures and Application to Liquid-Liquid Extraction; 3. The Determination of Activity Coefficients at Infinite Dilution for the Selection of Entrainers in Extractive Distillation 4. Assessment of the Potential of Ionic Liquids as Solvents in Separation Processes 5. Conclusion; Appendix I: List of Abbreviations for Ionic Liquid Nomenclature; Chapter 6. Environmental and Solubility Issues Related to Novel Corrosion Control; 1. Introduction; 2. Corrosion of Industrially Important Metals; 3. The Layers Protecting the Base Metals; 4. Super primers on Metals; 5. Summary/Conclusions; Chapter 7. The Behavior of Iron and Aluminum in Acid Mine Drainage: Specialization, Mineralogy, and Environmental Significance; 1. Introduction 2. Geochemistry and Mineralogy of Iron and Aluminum in AMD 3. Environmental Significance; 4. Conclusions; Part III: Radioactive Wastes; Chapter 8. An Evaluation of Solubility Limits on Maximum Uranium Concentrations in Groundwater; 1. Introduction; 2. Geologic Setting of the Tono Uranium Deposit; 3. Geochemical Constraints on Uranium Solubility; 4. Evaluation of Uranium Solubility; 5. Conclusions; Chapter 9. Leaching from Cementitious Materials Used in Radioactive Waste Disposal Sites; 1. Introduction; 2. Radioactive Waste Disposal Site and Concrete; 3. Leaching from Cementitious Materials 4. Method for Predicting Durability of Concrete |
Record Nr. | UNINA-9910784598903321 |
Letcher T. M (Trevor M.) | ||
Amsterdam ; ; Boston, : Elsevier, c2007 | ||
Materiale a stampa | ||
Lo trovi qui: Univ. Federico II | ||
|
Thermodynamics, solubility, and environmental issues / / Trevor M. Letcher |
Autore | Letcher T. M (Trevor M.) |
Edizione | [1st ed.] |
Pubbl/distr/stampa | Amsterdam ; ; Boston, : Elsevier, c2007 |
Descrizione fisica | 1 online resource (493 p.) |
Disciplina | 660/.2969 |
Soggetto topico |
Thermodynamics - Industrial applications - Environmental aspects
Solubility - Environmental aspects |
ISBN |
1-281-05114-4
9786611051143 0-08-048103-5 |
Formato | Materiale a stampa |
Livello bibliografico | Monografia |
Lingua di pubblicazione | eng |
Nota di contenuto |
Front cover; Thermodynamics, Solubility and Environmental Issues; Copyright page; Preface; Foreword; List of Contributors; Table of Contents; Part I: Basic Theory and Modelling; Chapter 1. An Introduction to Modelling of Pollutants in the Environment; 1. Introduction; 2. Partition Coefficients; 3. Model Environments; 4. Equilibrium Partition; 5. Environmental Distribution; 6. Environmental Distribution Using a Flow Model; 7. Accumulation of Chemicals in the Food Chain; Chapter 2. Modeling the Solubility in Water of Environmentally Important Organic Compounds; 1. Introduction
2. Quantum Chemistry Methods 3. Experiment-Based QSPR Modeling; 4. Structure-Based QSPR Modeling; 5. The Quantum-Connectivity Indices; 6. Modeling Solubility with Quantum-Connectivity; 7. Concluding Remarks; Chapter 3. Modeling of Contaminant Leaching; 1. Overview of Significance; 2. Geochemical Modeling; 3. Summary; Part II: Industry and Mining; Chapter 4. Supercritical Fluids and Reductions in Environmental Pollution; 1. Introduction; 2. Supercritical Fluids; 3. References for Thermodynamic Properties of Supercritical Fluids 4. Solubility of Electrolytes and Non-Electrolytes in Supercritical Fluids5. Structure of Supercritical Water; 6. Application of Supercritical Fluids for Reducing Pollutants; 7. Concluding Remarks; Chapter 5. Phase Equilibrium Studies on Ionic Liquid Systems for Industrial Separation Processes of Complex Organic Mixtures; 1. Introduction; 2. Solubility Studies on Ionic Liquid-Organic Mixtures and Application to Liquid-Liquid Extraction; 3. The Determination of Activity Coefficients at Infinite Dilution for the Selection of Entrainers in Extractive Distillation 4. Assessment of the Potential of Ionic Liquids as Solvents in Separation Processes 5. Conclusion; Appendix I: List of Abbreviations for Ionic Liquid Nomenclature; Chapter 6. Environmental and Solubility Issues Related to Novel Corrosion Control; 1. Introduction; 2. Corrosion of Industrially Important Metals; 3. The Layers Protecting the Base Metals; 4. Super primers on Metals; 5. Summary/Conclusions; Chapter 7. The Behavior of Iron and Aluminum in Acid Mine Drainage: Specialization, Mineralogy, and Environmental Significance; 1. Introduction 2. Geochemistry and Mineralogy of Iron and Aluminum in AMD 3. Environmental Significance; 4. Conclusions; Part III: Radioactive Wastes; Chapter 8. An Evaluation of Solubility Limits on Maximum Uranium Concentrations in Groundwater; 1. Introduction; 2. Geologic Setting of the Tono Uranium Deposit; 3. Geochemical Constraints on Uranium Solubility; 4. Evaluation of Uranium Solubility; 5. Conclusions; Chapter 9. Leaching from Cementitious Materials Used in Radioactive Waste Disposal Sites; 1. Introduction; 2. Radioactive Waste Disposal Site and Concrete; 3. Leaching from Cementitious Materials 4. Method for Predicting Durability of Concrete |
Record Nr. | UNINA-9910827123903321 |
Letcher T. M (Trevor M.) | ||
Amsterdam ; ; Boston, : Elsevier, c2007 | ||
Materiale a stampa | ||
Lo trovi qui: Univ. Federico II | ||
|