Green reaction media in organic synthesis [[electronic resource] /] / edited by Koichi Mikami |
Pubbl/distr/stampa | Ames, Iowa, : Blackwell Pub., 2005 |
Descrizione fisica | 1 online resource (202 p.) |
Disciplina |
547.2
660.2844 660/.2844 |
Altri autori (Persone) | MikamiKoichi |
Soggetto topico |
Solvents - Environmental aspects
Organic compounds - Synthesis - Environmental aspects Green products |
Soggetto genere / forma | Electronic books. |
ISBN |
1-280-74856-7
9786610748563 0-470-98877-0 1-4051-7245-2 |
Formato | Materiale a stampa |
Livello bibliografico | Monografia |
Lingua di pubblicazione | eng |
Nota di contenuto |
Green Reaction Media in Organic Synthesis; Contents; Contributors; Preface; 1 Introduction; 1.1 Green reaction media; 1.2 Ionic liquids; 1.3 Fluorous media; 1.4 Supercritical carbon dioxide; References; 2 Ionic liquids; 2.1 Historical background and synthesis; 2.1.1 Historical background; 2.1.2 Synthesis; 2.1.2.1 Preparation of imidazolium halides; 2.1.2.2 Anion metathesis; 2.1.2.3 Functionalized imidazolium ionic liquids; 2.1.2.4 Other types of ionic liquid; 2.1.2.5 Purification; 2.2 Physical properties; 2.2.1 Melting point; 2.2.2 Thermal stability; 2.2.3 Polarity; 2.2.4 Solubility
2.2.5 Viscosity2.2.6 Acidity; 2.2.7 Chirality; 2.2.8 Toxicity and environmental issues; 2.3 Applications as reaction media; 2.3.1 Hydroformylation; 2.3.2 Hydrogenation; 2.3.3 The Friedel-Crafts reaction; 2.3.4 Epoxidation; 2.3.5 Palladium-catalyzed C-C bond formation; 2.3.5.1 The Mizoroki-Heck reaction; 2.3.5.2 The Suzuki-Miyaura cross-coupling reaction; 2.3.5.3 Other palladium-catalyzed cross-coupling reactions; 2.3.6 The Diels-Alder reaction; 2.3.7 Biocatalysis in ionic liquids; 2.4 The future of ionic liquids; 2.5 Experimental part; 2.5.1 Preparation of [bmim][Cl] 2.5.2 Preparation of [bmim][PF6]2.5.3 Preparation of a chiral imidazolium ionic liquid; 2.5.4 Enantioselective hydrogenation of methyl acetoacetate; 2.5.5 Epoxidation of 2,2-dimethylchromene; 2.5.6 Mizoroki-Heck reaction between butyl acrylate and iodobenzene under microwave irradiation; 2.5.7 Diphenylacetylene by the Sonogashira coupling reaction; References; 3 Fluorous solvents; 3.1 Historical background; 3.2 Physical properties; 3.2.1 Key design elements in fluorous/organic liquid biphasic reactions; 3.2.2 Commercial availability; 3.2.3 Polarity; 3.2.4 Solute solubilities 3.2.5 Fluorous solvent miscibilities3.2.6 Partition coefficients and fluorophilicities; 3.2.7 Toxicity and environmental issues; 3.3 Applications as reaction media; 3.3.1 Fluorous catalysts for fluorous biphasic systems; 3.3.1.1 Hydroformylation; 3.3.1.2 Hydrogenation; 3.3.1.3 Catalytic hydroboration and hydrosilylation; 3.3.1.4 Catalytic oxidation reactions; 3.3.1.5 Coupling reactions; 3.3.1.6 Fluorous acid and base catalysts; 3.3.2 Enantioselective catalysts for fluorous biphasic systems; 3.3.2.1 Reduction; 3.3.2.2 Epoxidation; 3.3.2.3 Protonation 3.3.2.4 Et2Zn or Et3Al addition to aldehydes3.3.3 Heavy fluorous reagents; 3.3.3.1 Fluorous tin hydrides; 3.3.3.2 The Stille coupling reaction; 3.3.3.3 Radical carbonylation reaction; 3.3.3.4 Fluorous tin azide; 3.3.3.5 Fluorous sulfide and sulfoxide; 3.3.3.6 Other fluorous reagents; 3.3.4 Heavy fluorous protecting groups; 3.3.4.1 Trifluoroalkylsilyl protecting group; 3.3.4.2 Fluorous alcohol protective group; 3.3.4.3 Fluorous carboxylic acid protecting group; 3.4 Light fluorous compounds and fluorous silica gel; 3.4.1 Heavy and light fluorous molecules and separation strategy 3.4.2 Solid-phase extractions with fluorous silica gel |
Record Nr. | UNINA-9910143316403321 |
Ames, Iowa, : Blackwell Pub., 2005 | ||
Materiale a stampa | ||
Lo trovi qui: Univ. Federico II | ||
|
Green reaction media in organic synthesis [[electronic resource] /] / edited by Koichi Mikami |
Pubbl/distr/stampa | Ames, Iowa, : Blackwell Pub., 2005 |
Descrizione fisica | 1 online resource (202 p.) |
Disciplina |
547.2
660.2844 660/.2844 |
Altri autori (Persone) | MikamiKoichi |
Soggetto topico |
Solvents - Environmental aspects
Organic compounds - Synthesis - Environmental aspects Green products |
ISBN |
1-280-74856-7
9786610748563 0-470-98877-0 1-4051-7245-2 |
Formato | Materiale a stampa |
Livello bibliografico | Monografia |
Lingua di pubblicazione | eng |
Nota di contenuto |
Green Reaction Media in Organic Synthesis; Contents; Contributors; Preface; 1 Introduction; 1.1 Green reaction media; 1.2 Ionic liquids; 1.3 Fluorous media; 1.4 Supercritical carbon dioxide; References; 2 Ionic liquids; 2.1 Historical background and synthesis; 2.1.1 Historical background; 2.1.2 Synthesis; 2.1.2.1 Preparation of imidazolium halides; 2.1.2.2 Anion metathesis; 2.1.2.3 Functionalized imidazolium ionic liquids; 2.1.2.4 Other types of ionic liquid; 2.1.2.5 Purification; 2.2 Physical properties; 2.2.1 Melting point; 2.2.2 Thermal stability; 2.2.3 Polarity; 2.2.4 Solubility
2.2.5 Viscosity2.2.6 Acidity; 2.2.7 Chirality; 2.2.8 Toxicity and environmental issues; 2.3 Applications as reaction media; 2.3.1 Hydroformylation; 2.3.2 Hydrogenation; 2.3.3 The Friedel-Crafts reaction; 2.3.4 Epoxidation; 2.3.5 Palladium-catalyzed C-C bond formation; 2.3.5.1 The Mizoroki-Heck reaction; 2.3.5.2 The Suzuki-Miyaura cross-coupling reaction; 2.3.5.3 Other palladium-catalyzed cross-coupling reactions; 2.3.6 The Diels-Alder reaction; 2.3.7 Biocatalysis in ionic liquids; 2.4 The future of ionic liquids; 2.5 Experimental part; 2.5.1 Preparation of [bmim][Cl] 2.5.2 Preparation of [bmim][PF6]2.5.3 Preparation of a chiral imidazolium ionic liquid; 2.5.4 Enantioselective hydrogenation of methyl acetoacetate; 2.5.5 Epoxidation of 2,2-dimethylchromene; 2.5.6 Mizoroki-Heck reaction between butyl acrylate and iodobenzene under microwave irradiation; 2.5.7 Diphenylacetylene by the Sonogashira coupling reaction; References; 3 Fluorous solvents; 3.1 Historical background; 3.2 Physical properties; 3.2.1 Key design elements in fluorous/organic liquid biphasic reactions; 3.2.2 Commercial availability; 3.2.3 Polarity; 3.2.4 Solute solubilities 3.2.5 Fluorous solvent miscibilities3.2.6 Partition coefficients and fluorophilicities; 3.2.7 Toxicity and environmental issues; 3.3 Applications as reaction media; 3.3.1 Fluorous catalysts for fluorous biphasic systems; 3.3.1.1 Hydroformylation; 3.3.1.2 Hydrogenation; 3.3.1.3 Catalytic hydroboration and hydrosilylation; 3.3.1.4 Catalytic oxidation reactions; 3.3.1.5 Coupling reactions; 3.3.1.6 Fluorous acid and base catalysts; 3.3.2 Enantioselective catalysts for fluorous biphasic systems; 3.3.2.1 Reduction; 3.3.2.2 Epoxidation; 3.3.2.3 Protonation 3.3.2.4 Et2Zn or Et3Al addition to aldehydes3.3.3 Heavy fluorous reagents; 3.3.3.1 Fluorous tin hydrides; 3.3.3.2 The Stille coupling reaction; 3.3.3.3 Radical carbonylation reaction; 3.3.3.4 Fluorous tin azide; 3.3.3.5 Fluorous sulfide and sulfoxide; 3.3.3.6 Other fluorous reagents; 3.3.4 Heavy fluorous protecting groups; 3.3.4.1 Trifluoroalkylsilyl protecting group; 3.3.4.2 Fluorous alcohol protective group; 3.3.4.3 Fluorous carboxylic acid protecting group; 3.4 Light fluorous compounds and fluorous silica gel; 3.4.1 Heavy and light fluorous molecules and separation strategy 3.4.2 Solid-phase extractions with fluorous silica gel |
Record Nr. | UNISA-996213064903316 |
Ames, Iowa, : Blackwell Pub., 2005 | ||
Materiale a stampa | ||
Lo trovi qui: Univ. di Salerno | ||
|
Green reaction media in organic synthesis [[electronic resource] /] / edited by Koichi Mikami |
Pubbl/distr/stampa | Ames, Iowa, : Blackwell Pub., 2005 |
Descrizione fisica | 1 online resource (202 p.) |
Disciplina |
547.2
660.2844 660/.2844 |
Altri autori (Persone) | MikamiKoichi |
Soggetto topico |
Solvents - Environmental aspects
Organic compounds - Synthesis - Environmental aspects Green products |
ISBN |
1-280-74856-7
9786610748563 0-470-98877-0 1-4051-7245-2 |
Formato | Materiale a stampa |
Livello bibliografico | Monografia |
Lingua di pubblicazione | eng |
Nota di contenuto |
Green Reaction Media in Organic Synthesis; Contents; Contributors; Preface; 1 Introduction; 1.1 Green reaction media; 1.2 Ionic liquids; 1.3 Fluorous media; 1.4 Supercritical carbon dioxide; References; 2 Ionic liquids; 2.1 Historical background and synthesis; 2.1.1 Historical background; 2.1.2 Synthesis; 2.1.2.1 Preparation of imidazolium halides; 2.1.2.2 Anion metathesis; 2.1.2.3 Functionalized imidazolium ionic liquids; 2.1.2.4 Other types of ionic liquid; 2.1.2.5 Purification; 2.2 Physical properties; 2.2.1 Melting point; 2.2.2 Thermal stability; 2.2.3 Polarity; 2.2.4 Solubility
2.2.5 Viscosity2.2.6 Acidity; 2.2.7 Chirality; 2.2.8 Toxicity and environmental issues; 2.3 Applications as reaction media; 2.3.1 Hydroformylation; 2.3.2 Hydrogenation; 2.3.3 The Friedel-Crafts reaction; 2.3.4 Epoxidation; 2.3.5 Palladium-catalyzed C-C bond formation; 2.3.5.1 The Mizoroki-Heck reaction; 2.3.5.2 The Suzuki-Miyaura cross-coupling reaction; 2.3.5.3 Other palladium-catalyzed cross-coupling reactions; 2.3.6 The Diels-Alder reaction; 2.3.7 Biocatalysis in ionic liquids; 2.4 The future of ionic liquids; 2.5 Experimental part; 2.5.1 Preparation of [bmim][Cl] 2.5.2 Preparation of [bmim][PF6]2.5.3 Preparation of a chiral imidazolium ionic liquid; 2.5.4 Enantioselective hydrogenation of methyl acetoacetate; 2.5.5 Epoxidation of 2,2-dimethylchromene; 2.5.6 Mizoroki-Heck reaction between butyl acrylate and iodobenzene under microwave irradiation; 2.5.7 Diphenylacetylene by the Sonogashira coupling reaction; References; 3 Fluorous solvents; 3.1 Historical background; 3.2 Physical properties; 3.2.1 Key design elements in fluorous/organic liquid biphasic reactions; 3.2.2 Commercial availability; 3.2.3 Polarity; 3.2.4 Solute solubilities 3.2.5 Fluorous solvent miscibilities3.2.6 Partition coefficients and fluorophilicities; 3.2.7 Toxicity and environmental issues; 3.3 Applications as reaction media; 3.3.1 Fluorous catalysts for fluorous biphasic systems; 3.3.1.1 Hydroformylation; 3.3.1.2 Hydrogenation; 3.3.1.3 Catalytic hydroboration and hydrosilylation; 3.3.1.4 Catalytic oxidation reactions; 3.3.1.5 Coupling reactions; 3.3.1.6 Fluorous acid and base catalysts; 3.3.2 Enantioselective catalysts for fluorous biphasic systems; 3.3.2.1 Reduction; 3.3.2.2 Epoxidation; 3.3.2.3 Protonation 3.3.2.4 Et2Zn or Et3Al addition to aldehydes3.3.3 Heavy fluorous reagents; 3.3.3.1 Fluorous tin hydrides; 3.3.3.2 The Stille coupling reaction; 3.3.3.3 Radical carbonylation reaction; 3.3.3.4 Fluorous tin azide; 3.3.3.5 Fluorous sulfide and sulfoxide; 3.3.3.6 Other fluorous reagents; 3.3.4 Heavy fluorous protecting groups; 3.3.4.1 Trifluoroalkylsilyl protecting group; 3.3.4.2 Fluorous alcohol protective group; 3.3.4.3 Fluorous carboxylic acid protecting group; 3.4 Light fluorous compounds and fluorous silica gel; 3.4.1 Heavy and light fluorous molecules and separation strategy 3.4.2 Solid-phase extractions with fluorous silica gel |
Record Nr. | UNINA-9910830948203321 |
Ames, Iowa, : Blackwell Pub., 2005 | ||
Materiale a stampa | ||
Lo trovi qui: Univ. Federico II | ||
|
Green reaction media in organic synthesis / / edited by Koichi Mikami |
Pubbl/distr/stampa | Ames, Iowa, : Blackwell Pub., 2005 |
Descrizione fisica | 1 online resource (202 p.) |
Disciplina | 660/.2844 |
Altri autori (Persone) | MikamiKoichi |
Soggetto topico |
Solvents - Environmental aspects
Organic compounds - Synthesis - Environmental aspects Green products |
ISBN |
1-280-74856-7
9786610748563 0-470-98877-0 1-4051-7245-2 |
Formato | Materiale a stampa |
Livello bibliografico | Monografia |
Lingua di pubblicazione | eng |
Nota di contenuto |
Green Reaction Media in Organic Synthesis; Contents; Contributors; Preface; 1 Introduction; 1.1 Green reaction media; 1.2 Ionic liquids; 1.3 Fluorous media; 1.4 Supercritical carbon dioxide; References; 2 Ionic liquids; 2.1 Historical background and synthesis; 2.1.1 Historical background; 2.1.2 Synthesis; 2.1.2.1 Preparation of imidazolium halides; 2.1.2.2 Anion metathesis; 2.1.2.3 Functionalized imidazolium ionic liquids; 2.1.2.4 Other types of ionic liquid; 2.1.2.5 Purification; 2.2 Physical properties; 2.2.1 Melting point; 2.2.2 Thermal stability; 2.2.3 Polarity; 2.2.4 Solubility
2.2.5 Viscosity2.2.6 Acidity; 2.2.7 Chirality; 2.2.8 Toxicity and environmental issues; 2.3 Applications as reaction media; 2.3.1 Hydroformylation; 2.3.2 Hydrogenation; 2.3.3 The Friedel-Crafts reaction; 2.3.4 Epoxidation; 2.3.5 Palladium-catalyzed C-C bond formation; 2.3.5.1 The Mizoroki-Heck reaction; 2.3.5.2 The Suzuki-Miyaura cross-coupling reaction; 2.3.5.3 Other palladium-catalyzed cross-coupling reactions; 2.3.6 The Diels-Alder reaction; 2.3.7 Biocatalysis in ionic liquids; 2.4 The future of ionic liquids; 2.5 Experimental part; 2.5.1 Preparation of [bmim][Cl] 2.5.2 Preparation of [bmim][PF6]2.5.3 Preparation of a chiral imidazolium ionic liquid; 2.5.4 Enantioselective hydrogenation of methyl acetoacetate; 2.5.5 Epoxidation of 2,2-dimethylchromene; 2.5.6 Mizoroki-Heck reaction between butyl acrylate and iodobenzene under microwave irradiation; 2.5.7 Diphenylacetylene by the Sonogashira coupling reaction; References; 3 Fluorous solvents; 3.1 Historical background; 3.2 Physical properties; 3.2.1 Key design elements in fluorous/organic liquid biphasic reactions; 3.2.2 Commercial availability; 3.2.3 Polarity; 3.2.4 Solute solubilities 3.2.5 Fluorous solvent miscibilities3.2.6 Partition coefficients and fluorophilicities; 3.2.7 Toxicity and environmental issues; 3.3 Applications as reaction media; 3.3.1 Fluorous catalysts for fluorous biphasic systems; 3.3.1.1 Hydroformylation; 3.3.1.2 Hydrogenation; 3.3.1.3 Catalytic hydroboration and hydrosilylation; 3.3.1.4 Catalytic oxidation reactions; 3.3.1.5 Coupling reactions; 3.3.1.6 Fluorous acid and base catalysts; 3.3.2 Enantioselective catalysts for fluorous biphasic systems; 3.3.2.1 Reduction; 3.3.2.2 Epoxidation; 3.3.2.3 Protonation 3.3.2.4 Et2Zn or Et3Al addition to aldehydes3.3.3 Heavy fluorous reagents; 3.3.3.1 Fluorous tin hydrides; 3.3.3.2 The Stille coupling reaction; 3.3.3.3 Radical carbonylation reaction; 3.3.3.4 Fluorous tin azide; 3.3.3.5 Fluorous sulfide and sulfoxide; 3.3.3.6 Other fluorous reagents; 3.3.4 Heavy fluorous protecting groups; 3.3.4.1 Trifluoroalkylsilyl protecting group; 3.3.4.2 Fluorous alcohol protective group; 3.3.4.3 Fluorous carboxylic acid protecting group; 3.4 Light fluorous compounds and fluorous silica gel; 3.4.1 Heavy and light fluorous molecules and separation strategy 3.4.2 Solid-phase extractions with fluorous silica gel |
Record Nr. | UNINA-9910877880603321 |
Ames, Iowa, : Blackwell Pub., 2005 | ||
Materiale a stampa | ||
Lo trovi qui: Univ. Federico II | ||
|
Organic synthesis engineering [[electronic resource] /] / L.K. Doraiswamy |
Autore | Doraiswamy L. K (Laxmangudi Krishnamurthy) |
Pubbl/distr/stampa | New York, : Oxford University Press, 2001 |
Descrizione fisica | 1 online resource (937 p.) |
Disciplina |
660.2995
660/.2844 |
Collana | Topics in chemical engineering |
Soggetto topico |
Chemical engineering
Chemical reactors Catalysis Organic compounds - Synthesis |
Soggetto genere / forma | Electronic books. |
ISBN |
0-19-756082-2
1-280-76073-7 9786610760732 0-19-802569-6 1-60119-443-9 |
Formato | Materiale a stampa |
Livello bibliografico | Monografia |
Lingua di pubblicazione | eng |
Nota di contenuto | Contents; Chapter 1 Introduction and Structure of the Book; PART I: REACTIONS AND REACTORS IN ORGANIC SYNTHESIS: BASIC CONCEPTS; PART II: CATALYSIS IN ORGANIC SYNTHESIS AND TECHNOLOGY; PART III: REACTOR DESIGN FOR HOMOGENEOUS AND FLUID-SOLID (CATALYTIC) REACTIONS; PART IV: FLUID-FLUID AND FLUID-FLUID-SOLID REACTIONS AND REACTORS; PART V: STRATEGIES FOR ENHANCING THE RATES OF ORGANIC REACTIONS; A Process Overview; Epilogue; Acknowledgments for Figures and Tables; Index |
Record Nr. | UNINA-9910451120903321 |
Doraiswamy L. K (Laxmangudi Krishnamurthy) | ||
New York, : Oxford University Press, 2001 | ||
Materiale a stampa | ||
Lo trovi qui: Univ. Federico II | ||
|
Organic synthesis engineering [[electronic resource] /] / L.K. Doraiswamy |
Autore | Doraiswamy L. K (Laxmangudi Krishnamurthy) |
Pubbl/distr/stampa | New York, : Oxford University Press, 2001 |
Descrizione fisica | 1 online resource (937 p.) |
Disciplina |
660.2995
660/.2844 |
Collana | Topics in chemical engineering |
Soggetto topico |
Chemical engineering
Chemical reactors Catalysis Organic compounds - Synthesis |
ISBN |
0-19-756082-2
1-280-76073-7 9786610760732 0-19-802569-6 1-60119-443-9 |
Formato | Materiale a stampa |
Livello bibliografico | Monografia |
Lingua di pubblicazione | eng |
Nota di contenuto | Contents; Chapter 1 Introduction and Structure of the Book; PART I: REACTIONS AND REACTORS IN ORGANIC SYNTHESIS: BASIC CONCEPTS; PART II: CATALYSIS IN ORGANIC SYNTHESIS AND TECHNOLOGY; PART III: REACTOR DESIGN FOR HOMOGENEOUS AND FLUID-SOLID (CATALYTIC) REACTIONS; PART IV: FLUID-FLUID AND FLUID-FLUID-SOLID REACTIONS AND REACTORS; PART V: STRATEGIES FOR ENHANCING THE RATES OF ORGANIC REACTIONS; A Process Overview; Epilogue; Acknowledgments for Figures and Tables; Index |
Record Nr. | UNINA-9910783933103321 |
Doraiswamy L. K (Laxmangudi Krishnamurthy) | ||
New York, : Oxford University Press, 2001 | ||
Materiale a stampa | ||
Lo trovi qui: Univ. Federico II | ||
|
Synthetic natural gas from coal, dry biomass, and power-to-gas applications / / edited by Tilman J. Schildhauer, Serge M. Biollaz |
Pubbl/distr/stampa | Hoboken, New Jersey : , : Wiley, , 2016 |
Descrizione fisica | 1 online resource (328 p.) |
Disciplina | 660/.2844 |
Soggetto topico |
Synthesis gas
Coal gasification Biomass conversion Gas manufacture and works |
ISBN |
1-119-19136-X
1-119-19125-4 1-119-19133-5 |
Formato | Materiale a stampa |
Livello bibliografico | Monografia |
Lingua di pubblicazione | eng |
Record Nr. | UNINA-9910135046603321 |
Hoboken, New Jersey : , : Wiley, , 2016 | ||
Materiale a stampa | ||
Lo trovi qui: Univ. Federico II | ||
|
Synthetic natural gas from coal, dry biomass, and power-to-gas applications / / edited by Tilman J. Schildhauer, Serge M. Biollaz |
Pubbl/distr/stampa | Hoboken, New Jersey : , : Wiley, , 2016 |
Descrizione fisica | 1 online resource (328 p.) |
Disciplina | 660/.2844 |
Soggetto topico |
Synthesis gas
Coal gasification Biomass conversion Gas manufacture and works |
ISBN |
1-119-19136-X
1-119-19125-4 1-119-19133-5 |
Formato | Materiale a stampa |
Livello bibliografico | Monografia |
Lingua di pubblicazione | eng |
Record Nr. | UNINA-9910807946803321 |
Hoboken, New Jersey : , : Wiley, , 2016 | ||
Materiale a stampa | ||
Lo trovi qui: Univ. Federico II | ||
|