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Advanced functional porous materials : from macro to nano scale lengths / / Arya Uthaman [and three others] editors
| Advanced functional porous materials : from macro to nano scale lengths / / Arya Uthaman [and three others] editors |
| Pubbl/distr/stampa | Cham, Switzerland : , : Springer, , [2022] |
| Descrizione fisica | 1 online resource (690 pages) |
| Disciplina | 620.116 |
| Collana | Engineering Materials |
| Soggetto topico | Porous materials |
| ISBN | 3-030-85397-7 |
| Classificazione | UXA |
| Formato | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Intro -- Contents -- Contributors -- Fundamentals of Porous Materials -- 1 Introduction -- 2 Pores -- 2.1 Porosity -- 3 Classification of Porous Materials -- 3.1 Based on Pores Size -- 3.2 Based on Building Framework -- 3.3 Artificial Porous Materials -- 4 Applications of Porous Materials -- 5 Conclusion -- References -- Synthesis of Macro Porous Ceramic Materials -- 1 Introduction -- 2 Structural Characters of Porous Ceramic Materials -- 3 Synthesizing Method -- 3.1 Partial Sintering -- 3.2 Replica Template -- 3.3 Sacrificial Template -- 3.4 Direct Foaming -- 3.5 Advantages and Limitations of Partial Sintering, Replica Template, Sacrificial Template and Direct Foaming -- 4 Future Trends in Producing Porous Ceramics Components -- 5 Conclusion -- References -- Emulsion Templated Hierarchical Macroporous Polymers -- 1 Introduction -- 2 HIPE Formation and Structure of HIPEs -- 2.1 Stabilization of HIPEs -- 3 Polymerization Strategies for HIPEs -- 3.1 Chain-Growth Polymerization -- 3.2 Step-Growth Polymerization -- 3.3 Ring Opening Polymerization (ROP) -- 4 PolyHIPE Properties -- 5 PolyHIPE Applications -- 5.1 Adsorption/Separation/Filtration Processes -- 5.2 Tissue Engineering -- 5.3 Organic Reactions and Catalysis -- 5.4 Energy Storage -- 6 Conclusion -- References -- Characterization of Macroporous Materials -- 1 Introduction -- 2 Computerized X-Ray Tomography -- 3 Magnetic Resonance Imaging -- 4 Electron Microscopy -- 4.1 3D Electron Tomography (3DET) Technique -- 4.2 Dual-Beam Electron Microscope -- 5 Conclusions -- References -- Synthesis of Mesoporous Materials -- 1 Introduction -- 2 Properties of Mesoporous Materials -- 3 Preparation Methods of Mesoporous Materials -- 4 Template-Assisted Synthesis of OMMs -- 4.1 Preparation of OMMs by Soft-Templating Method -- 4.2 Preparation of OMMs by Hard-Templating Method.
5 Template-Free Synthesis of OMMs -- 6 Doping in OMMs -- 7 Advantages and Limitations of Different Preparation Methods -- 8 Conclusion and Future Trends -- References -- Characterization of Mesoporous Materials -- 1 Introduction -- 2 Characterization of Mesoporous Materials -- 2.1 X-ray Diffraction (XRD) -- 2.2 Nitrogen Adsorption-Desorption -- 2.3 Transmission Electron Microscope (TEM) -- 2.4 Fourier Transform Infrared (FTIR) Spectroscopy -- 2.5 Thermogravimetric Analysis (TGA) -- 2.6 Energy Dispersive X-ray (EDX) -- 2.7 Differential Scanning Calorimetry (DSC) -- 2.8 Nuclear Magnetic Resonance (NMR) -- 3 Limitations of Techniques -- 4 Conclusion -- References -- Role of Mesoporous Silica Nanoparticles as Drug Carriers: Evaluation of Diverse Mesoporous Material Nanoparticles as Potential Host for Various Applications -- 1 Introduction -- 2 Chemistry and Synthesis of Mesoporous Material -- 3 Functionalization of Mesoporous Material -- 4 Methods of Drug Loading and Release of Drugs from MSNs -- 5 Mesoporous Material as a Potential Drug Carrier -- 6 Applicability of Mesoporous Material for Fast or Immediate Drug Delivery Systems -- 7 Applicability of Mesoporous Material for Sustained or Controlled Drug Delivery Systems -- 8 Mesoporous Nanotechnology Approaches for Infectious Diseases -- 9 Conclusion -- References -- Applications and Future Trends in Mesoporous Materials -- 1 Introduction -- 2 Energy Conversion and Storage -- 2.1 Rechargeable Batteries -- 2.2 Supercapacitors -- 2.3 Fuel Cells -- 2.4 Solar Cells -- 3 Carbon Capture -- 4 Filtration -- 5 Catalysis -- 6 Optics -- 7 Drug Delivery -- 8 Conclusion and Future Scope -- References -- Advanced Ordered Nanoporous Materials -- 1 Introduction -- 2 Zeolites -- 2.1 Structure and Physicochemical Properties -- 2.2 Zeolite Synthesis -- 2.3 Applications of Zeolites -- 3 Ordered Mesoporous Materials. 3.1 Mesoporous Silica -- 3.2 Mesoporous Alumina -- 3.3 Mesoporous Metal/Metal Oxide -- 3.4 Mesoporous Carbon -- 4 Metal-Organic Frameworks (MOFs) -- 4.1 Structure and Physicochemical Properties -- 4.2 Synthesis Techniques -- 4.3 Applications -- 5 Covalent Organic Frameworks -- 5.1 Structure and Physicochemical Properties -- 5.2 Synthesis Techniques -- 5.3 Applications -- 6 Summary and Prospects -- References -- Characterization of Nanoporous Materials -- 1 Introduction -- 2 Crystalline Structure -- 2.1 Single Crystal and Powder XRD -- 2.2 Electron Crystallography -- 3 Oxidation State and Coordination -- 3.1 X-Ray Absorption Spectrum -- 3.2 X-Ray Photoelectron Spectrum -- 3.3 UV-Vis Spectra -- 3.4 Nuclear Magnetic Resonance (NMR) -- 4 Chemical Composition -- 5 Pore Analysis -- 6 Morphology: SEM -- 7 Pore Structure: TEM -- 8 Conclusions -- References -- Emerging Biomedical and Industrial Applications of Nanoporous Materials -- 1 Introduction -- 2 Nanobiomedicine Applications -- 2.1 Drug Delivery Systems (DDS) and Tissue Engineering -- 2.2 Bioseparation, Sorting and Analysis -- 2.3 Antifouling and Antibacterial Coatings -- 2.4 Microfluidic Bioassays and Organ-on-Chip Devices -- 2.5 Biosensors and Theranostic Devices -- 2.6 Flexible Bioelectronics and Biointerfaces -- 2.7 Future Horizon and Challenges -- 3 Industrial Applications -- 3.1 Chromatography and Filtration Applications -- 3.2 Photocatalytic and Adsorption Applications -- 3.3 Nanoreactors -- 3.4 Biosensing and Photonic Applications -- 3.5 Energy Harvesting and Storage Applications -- 3.6 Future Horizons and Challenges -- 4 Conclusion -- References -- Fundamentals of Hierarchically Porous Materials and Its Catalytic Applications -- 1 Introduction -- 2 Catalytic Applications of Hierarchical Porous Materials -- 2.1 Photocatalytic Materials -- 2.2 Fuel Chemistry -- 2.3 Valorisation of Biomass. 2.4 Selective Organic Transformation Process -- 2.5 Pollution Abatement -- 3 Recent Studies in Hierarchical Porous Materials -- 4 Conclusion and Future Aspects on Hierarchical Porous Materials -- References -- Characterization of Hierarchical Porous Materials -- 1 Introduction -- 2 Characterization of Hierarchical Porous Materials by X-Ray Diffraction (XRD) -- 2.1 Oxide -- 2.2 Carbon -- 2.3 Metal -- 3 Characterization of Hierarchical Porous Materials by Scanning Electron Microscope (SEM) -- 3.1 Oxide -- 3.2 Polymer -- 3.3 Metal -- 4 Characterization of Hierarchical Porous Materials by Transmission Electron Microscope (TEM) -- 4.1 Oxide -- 4.2 Carbon -- 4.3 Ceramic -- 4.4 Polymer -- 5 Characterization of Hierarchical Porous Materials by Brunauer-Emmett-Teller (BET) -- 5.1 Oxide -- 5.2 Carbon -- 5.3 Polymer -- 6 Conclusion -- References -- Hierarchical Porous Zeolitic Imidazolate Frameworks: Microporous to Macroporous Regime -- 1 Introduction -- 2 Structure of ZIFs -- 3 Synthesis of ZIFs -- 3.1 Modulation-based Method -- 3.2 Template-based Method -- 3.3 Template-free Synthesis -- 3.4 Defect Formation -- 3.5 Freeze-drying and Supercritical Carbon Dioxide (CO2) -- 3.6 3D Printing Method -- 4 Characterization of Porosity -- 5 Conclusion -- References -- Porous Metals -- 1 Introduction -- 2 Types of Porous Metals -- 3 Fabrication of Porous Metals -- 3.1 Liquid-State Processing Routes -- 3.2 Solid-State Processing Route -- 3.3 Metal Deposition Methods -- 4 Properties of Porous Metals -- 4.1 Microstructure of Porous Metals -- 4.2 Mechanical Properties -- 4.3 Acoustic Properties -- 4.4 Thermal Properties -- 5 Applications of Porous Metals -- 5.1 Structural Applications -- 5.2 Functional Applications -- 6 Conclusion -- References -- Porous Ceramic Properties and Its Different Fabrication Process -- 1 Introduction -- 2 Classification of Porous Ceramics. 2.1 Different Methods for Enhancing the Porosity of Porous Ceramic Materials -- 3 Fabrication of Porous Ceramics -- 3.1 Particle Stacking Sintering -- 3.2 Addition of Pore-Forming Agent -- 3.3 Polymeric Sponge Impregnation Process -- 3.4 Foaming Process -- 3.5 Sol-Gel Process -- 3.6 Other Processing Process of Porous Ceramics -- 4 Porous Ceramic Honeycombs -- 5 Porous Ceramic Composites -- 6 Conclusion -- References -- Application of Porous Ceramics -- 1 Introduction -- 2 Ion Exchange -- 2.1 As, Zn, Cd, Cs -- 2.2 Li+ -- 2.3 Na+ -- 2.4 NH4+ -- 2.5 O2− -- 3 Catalyst Carrier -- 4 Porous Electrodes and Membranes -- 4.1 Battery -- 4.2 Photo-Fenton -- 4.3 Fuel Cell -- 5 Filtration and Separation -- 5.1 Hot-Gas Filtration -- 5.2 Fluid Separation -- 5.3 Filtration of Molten Metals -- 5.4 Microfiltration -- 6 Functional Materials -- 6.1 Flexible Porous Ceramics -- 6.2 Dielectric, Ferroelectric, and Piezoelectric Effect -- 7 Combustion and Fire Retardance -- 7.1 Combustion -- 7.2 Fire Retardance -- 8 Conclusion and Future Trends -- References -- Electrospun Porous Biobased Polymer Mats for Biomedical Applications -- 1 Introduction -- 2 Electrospinning Process -- 2.1 Porous Nanofibers -- 2.2 Polymer Used in Nanofiber Fabrication -- 3 Biomedical Applications of Porous Biobased Polymer Mats -- 3.1 Tissue Engineering Applications -- 3.2 Drug Delivery -- 3.3 Wound Dressings -- 3.4 Cosmeceutical Applications -- 3.5 Other Applications -- 4 Future Insights and Challenges -- 5 Conclusion -- References -- Porous Ionic Liquid Derived Materials for CO2 Emissions Mitigation -- 1 Introduction -- 2 Organic Porous Materials -- 2.1 IL Grafted in Polymeric Supports -- 2.2 IPOP (Ionic Porous Organic Polymers) -- 2.3 Material Trends (MIP and Aerogel) -- 3 Hybrid or Crystalline Frameworks -- 3.1 Metal-Organic Frameworks (MOFs) -- 3.2 Zeolitic Imidazolate Frameworks (ZIFs). 3.3 Material Trends (COF). |
| Record Nr. | UNINA-9910522938603321 |
| Cham, Switzerland : , : Springer, , [2022] | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
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Advances in Microporous and Mesoporous Materials / / edited by Rafael Huirache Acuña
| Advances in Microporous and Mesoporous Materials / / edited by Rafael Huirache Acuña |
| Pubbl/distr/stampa | London : , : IntechOpen, , 2020 |
| Descrizione fisica | 1 online resource (111 pages) : illustrations (color) |
| Disciplina | 620.116 |
| Soggetto topico | Mesoporous materials |
| ISBN | 1-83880-756-X |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNINA-9910417991703321 |
| London : , : IntechOpen, , 2020 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Advances in Microporous and Mesoporous Materials / / edited by Rafael Huirache Acuña
| Advances in Microporous and Mesoporous Materials / / edited by Rafael Huirache Acuña |
| Pubbl/distr/stampa | London : , : IntechOpen, , 2020 |
| Descrizione fisica | 1 online resource (111 pages) : illustrations |
| Disciplina | 620.116 |
| Soggetto topico | Mesoporous materials |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNINA-9910688583303321 |
| London : , : IntechOpen, , 2020 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
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Capillary flows in heterogeneous and random porous media . 1 / / Rachid Ababou
| Capillary flows in heterogeneous and random porous media . 1 / / Rachid Ababou |
| Autore | Ababou R (Rachid) |
| Pubbl/distr/stampa | London, England ; ; Hoboken, New Jersey : , : ISTE : , : Wiley, , 2018 |
| Descrizione fisica | 1 online resource (407 pages) |
| Disciplina | 620.116 |
| Soggetto topico | Porous materials |
| ISBN |
1-118-76210-X
1-118-76205-3 1-118-76199-5 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNINA-9910555079003321 |
Ababou R (Rachid)
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| London, England ; ; Hoboken, New Jersey : , : ISTE : , : Wiley, , 2018 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Capillary flows in heterogeneous and random porous media . 1 / / Rachid Ababou
| Capillary flows in heterogeneous and random porous media . 1 / / Rachid Ababou |
| Autore | Ababou R (Rachid) |
| Pubbl/distr/stampa | London, England ; ; Hoboken, New Jersey : , : ISTE : , : Wiley, , 2018 |
| Descrizione fisica | 1 online resource (407 pages) |
| Disciplina | 620.116 |
| Soggetto topico | Porous materials |
| ISBN |
1-118-76210-X
1-118-76205-3 1-118-76199-5 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNINA-9910830818403321 |
|
Ababou R (Rachid)
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| London, England ; ; Hoboken, New Jersey : , : ISTE : , : Wiley, , 2018 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Computational modelling of multi-scale non-fickian dispersion in porous media : an approach based on stochastic calculus / / Don Kulasiri
| Computational modelling of multi-scale non-fickian dispersion in porous media : an approach based on stochastic calculus / / Don Kulasiri |
| Autore | Kulasiri Don |
| Pubbl/distr/stampa | Rijeka, Crotia : , : IntechOpen, , [2011] |
| Descrizione fisica | 1 online resource (244 pages) : illustrations |
| Disciplina | 620.116 |
| Soggetto topico |
Porous materials - Fluid dynamics
Hydrodynamics - Mathematical models |
| ISBN | 953-51-5702-7 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Altri titoli varianti | Computational modelling of multi-scale non-fickian dispersion in porous media |
| Record Nr. | UNINA-9910138251103321 |
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Kulasiri Don
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| Rijeka, Crotia : , : IntechOpen, , [2011] | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
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Convection in Porous Media [[electronic resource] /] / by Donald A. Nield, Adrian Bejan
| Convection in Porous Media [[electronic resource] /] / by Donald A. Nield, Adrian Bejan |
| Autore | Nield Donald A |
| Edizione | [5th ed. 2017.] |
| Pubbl/distr/stampa | Cham : , : Springer International Publishing : , : Imprint : Springer, , 2017 |
| Descrizione fisica | XXIX, 988 s : ill |
| Disciplina | 620.116 |
| Soggetto topico |
Fluid mechanics
Amorphous substances Complex fluids Geology—Statistical methods Catalysis Thermodynamics Heat engineering Heat transfer Mass transfer Engineering Fluid Dynamics Soft and Granular Matter, Complex Fluids and Microfluidics Quantitative Geology Engineering Thermodynamics, Heat and Mass Transfer |
| ISBN | 3-319-49562-3 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto | Preface to the Fifth Edition -- Preface to the Fourth Edition -- Preface to the Third Edition -- Preface to the Second Edition -- Preface to the First Edition -- Nomenclature -- 1 Mechanics of Fluid Flow through a Porous Medium -- 2 Heat Transfer through a Porous Medium -- 3 Mass Transfer in a Porous Medium: Multicomponent and Multiphase Flows -- 4 Forced Convection -- 5. External Natural Convection -- 6 Internal Natural Convection: Heating from Below -- 7 Internal Natural Convection: Heating from the Side -- 8 Mixed Convection -- 9 Double-Diffusive Convection -- 10 Convection with Change of Phase -- 11 Geophysical Aspects -- References -- Index. |
| Record Nr. | UNINA-9910254346303321 |
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Nield Donald A
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| Cham : , : Springer International Publishing : , : Imprint : Springer, , 2017 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
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Diffusion in nanoporous materials [[electronic resource] /] / Jörg Kärger, Douglas M. Ruthven, and Doros N. Theodorou
| Diffusion in nanoporous materials [[electronic resource] /] / Jörg Kärger, Douglas M. Ruthven, and Doros N. Theodorou |
| Autore | Kärger Jörg |
| Pubbl/distr/stampa | Weinheim, Germany, : Wiley-VCH, c2012 |
| Descrizione fisica | 1 online resource (904 p.) |
| Disciplina |
541.34
620.1/16 620.116 |
| Altri autori (Persone) |
RuthvenDouglas M <1938-> (Douglas Morris)
TheodorouDoros Nicolas |
| Soggetto topico |
Porous materials - Diffusion rate
Materials science |
| Soggetto genere / forma | Electronic books. |
| ISBN |
1-283-59214-2
9786613904591 3-527-65130-6 3-527-65127-6 3-527-65129-2 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Diffusion in Nanoporous Materials; Contents; Preface; Acknowledgments; Part I: Introduction; 1 Elementary Principles of Diffusion; 1.1 Fundamental Definitions; 1.1.1 Transfer of Matter by Diffusion; 1.1.2 Random Walk; 1.1.3 Transport Diffusion and Self-Diffusion; 1.1.4 Frames of Reference; 1.1.5 Diffusion in Anisotropic Media; 1.2 Driving Force for Diffusion; 1.2.1 Gradient of Chemical Potential; 1.2.2 Experimental Evidence; 1.2.3 Relationship between Transport and Self-diffusivities; 1.3 Diffusional Resistances in Nanoporous Media; 1.3.1 Internal Diffusional Resistances
1.3.2 Surface Resistance1.3.3 External Resistance to Mass Transfer; 1.4 Experimental Methods; References; Part II: Theory; 2 Diffusion as a Random Walk; 2.1 Random Walk Model; 2.1.1 Mean Square Displacement; 2.1.2 The Propagator; 2.1.3 Correspondence with Fick's Equations; 2.2 Correlation Effects; 2.2.1 Vacancy Correlations; 2.2.2 Correlated Anisotropy; 2.3 Boundary Conditions; 2.3.1 Absorbing and Reflecting Boundaries; 2.3.2 Partially Reflecting Boundary; 2.3.3 Matching Conditions; 2.3.4 Combined Impact of Diffusion and Permeation; 2.4 Macroscopic and Microscopic Diffusivities 2.5 Correlating Self-Diffusion and Diffusion with a Simple Jump Model2.6 Anomalous Diffusion; 2.6.1 Probability Distribution Functions of Residence Time and Jump Length; 2.6.2 Fractal Geometry; 2.6.3 Diffusion in a Fractal System; 2.6.4 Renormalization; 2.6.5 Deviations from Normal Diffusion in Nanoporous Materials: A Retrospective; References; 3 Diffusion and Non-equilibrium Thermodynamics; 3.1 Generalized Forces and Fluxes; 3.1.1 Mechanical Example; 3.1.2 Thermodynamic Forces and Fluxes; 3.1.3 Rate of Generation of Entropy; 3.1.4 Isothermal Approximation 3.1.5 Diffusion in a Binary Adsorbed Phase3.2 Self-Diffusion and Diffusive Transport; 3.3 Generalized Maxwell-Stefan Equations; 3.3.1 General Formulation; 3.3.2 Diffusion in an Adsorbed Phase; 3.3.3 Relation between Self- and Transport Diffusivities; 3.4 Application of the Maxwell-Stefan Model; 3.4.1 Parameter Estimation; 3.4.2 Membrane Permeation; 3.4.3 Diffusion in Macro- and Mesopores; 3.5 Loading Dependence of Self- and Transport Diffusivities; 3.5.1 Self-Diffusivities; 3.5.2 Transport Diffusivities; 3.5.3 Molecular Simulation; 3.5.4 Effect of Structural Defects 3.6 Diffusion at High Loadings and in Liquid-Filled PoresReferences; 4 Diffusion Mechanisms; 4.1 Diffusion Regimes; 4.1.1 Size-Selective Molecular Sieving; 4.2 Diffusion in Macro- and Mesopores; 4.2.1 Diffusion in a Straight Cylindrical Pore; 4.2.1.1 Knudsen Mechanism; 4.2.1.2 Viscous Flow; 4.2.1.3 Molecular Diffusion; 4.2.1.4 Transition Region; 4.2.1.5 Self-Diffusion/Tracer Diffusion; 4.2.1.6 Relative Importance of Different Mechanisms; 4.2.1.7 Surface Diffusion; 4.2.1.8 Combination of Diffusional Resistances; 4.2.2 Diffusion in a Pore Network; 4.2.2.1 Dusty Gas Model 4.2.2.2 Effective Medium Approximation |
| Record Nr. | UNINA-9910141285603321 |
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Kärger Jörg
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| Weinheim, Germany, : Wiley-VCH, c2012 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
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Diffusion in nanoporous materials [[electronic resource] /] / Jörg Kärger, Douglas M. Ruthven, and Doros N. Theodorou
| Diffusion in nanoporous materials [[electronic resource] /] / Jörg Kärger, Douglas M. Ruthven, and Doros N. Theodorou |
| Autore | Kärger Jörg |
| Pubbl/distr/stampa | Weinheim, Germany, : Wiley-VCH, c2012 |
| Descrizione fisica | 1 online resource (904 p.) |
| Disciplina |
541.34
620.1/16 620.116 |
| Altri autori (Persone) |
RuthvenDouglas M <1938-> (Douglas Morris)
TheodorouDoros Nicolas |
| Soggetto topico |
Porous materials - Diffusion rate
Materials science |
| ISBN |
1-283-59214-2
9786613904591 3-527-65130-6 3-527-65127-6 3-527-65129-2 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Diffusion in Nanoporous Materials; Contents; Preface; Acknowledgments; Part I: Introduction; 1 Elementary Principles of Diffusion; 1.1 Fundamental Definitions; 1.1.1 Transfer of Matter by Diffusion; 1.1.2 Random Walk; 1.1.3 Transport Diffusion and Self-Diffusion; 1.1.4 Frames of Reference; 1.1.5 Diffusion in Anisotropic Media; 1.2 Driving Force for Diffusion; 1.2.1 Gradient of Chemical Potential; 1.2.2 Experimental Evidence; 1.2.3 Relationship between Transport and Self-diffusivities; 1.3 Diffusional Resistances in Nanoporous Media; 1.3.1 Internal Diffusional Resistances
1.3.2 Surface Resistance1.3.3 External Resistance to Mass Transfer; 1.4 Experimental Methods; References; Part II: Theory; 2 Diffusion as a Random Walk; 2.1 Random Walk Model; 2.1.1 Mean Square Displacement; 2.1.2 The Propagator; 2.1.3 Correspondence with Fick's Equations; 2.2 Correlation Effects; 2.2.1 Vacancy Correlations; 2.2.2 Correlated Anisotropy; 2.3 Boundary Conditions; 2.3.1 Absorbing and Reflecting Boundaries; 2.3.2 Partially Reflecting Boundary; 2.3.3 Matching Conditions; 2.3.4 Combined Impact of Diffusion and Permeation; 2.4 Macroscopic and Microscopic Diffusivities 2.5 Correlating Self-Diffusion and Diffusion with a Simple Jump Model2.6 Anomalous Diffusion; 2.6.1 Probability Distribution Functions of Residence Time and Jump Length; 2.6.2 Fractal Geometry; 2.6.3 Diffusion in a Fractal System; 2.6.4 Renormalization; 2.6.5 Deviations from Normal Diffusion in Nanoporous Materials: A Retrospective; References; 3 Diffusion and Non-equilibrium Thermodynamics; 3.1 Generalized Forces and Fluxes; 3.1.1 Mechanical Example; 3.1.2 Thermodynamic Forces and Fluxes; 3.1.3 Rate of Generation of Entropy; 3.1.4 Isothermal Approximation 3.1.5 Diffusion in a Binary Adsorbed Phase3.2 Self-Diffusion and Diffusive Transport; 3.3 Generalized Maxwell-Stefan Equations; 3.3.1 General Formulation; 3.3.2 Diffusion in an Adsorbed Phase; 3.3.3 Relation between Self- and Transport Diffusivities; 3.4 Application of the Maxwell-Stefan Model; 3.4.1 Parameter Estimation; 3.4.2 Membrane Permeation; 3.4.3 Diffusion in Macro- and Mesopores; 3.5 Loading Dependence of Self- and Transport Diffusivities; 3.5.1 Self-Diffusivities; 3.5.2 Transport Diffusivities; 3.5.3 Molecular Simulation; 3.5.4 Effect of Structural Defects 3.6 Diffusion at High Loadings and in Liquid-Filled PoresReferences; 4 Diffusion Mechanisms; 4.1 Diffusion Regimes; 4.1.1 Size-Selective Molecular Sieving; 4.2 Diffusion in Macro- and Mesopores; 4.2.1 Diffusion in a Straight Cylindrical Pore; 4.2.1.1 Knudsen Mechanism; 4.2.1.2 Viscous Flow; 4.2.1.3 Molecular Diffusion; 4.2.1.4 Transition Region; 4.2.1.5 Self-Diffusion/Tracer Diffusion; 4.2.1.6 Relative Importance of Different Mechanisms; 4.2.1.7 Surface Diffusion; 4.2.1.8 Combination of Diffusional Resistances; 4.2.2 Diffusion in a Pore Network; 4.2.2.1 Dusty Gas Model 4.2.2.2 Effective Medium Approximation |
| Record Nr. | UNINA-9910830173303321 |
|
Kärger Jörg
|
||
| Weinheim, Germany, : Wiley-VCH, c2012 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Diffusion in nanoporous materials [[electronic resource] /] / Jörg Kärger, Douglas M. Ruthven, and Doros N. Theodorou
| Diffusion in nanoporous materials [[electronic resource] /] / Jörg Kärger, Douglas M. Ruthven, and Doros N. Theodorou |
| Autore | Kärger Jörg |
| Pubbl/distr/stampa | Weinheim, Germany, : Wiley-VCH, c2012 |
| Descrizione fisica | 1 online resource (904 p.) |
| Disciplina |
541.34
620.1/16 620.116 |
| Altri autori (Persone) |
RuthvenDouglas M <1938-> (Douglas Morris)
TheodorouDoros Nicolas |
| Soggetto topico |
Porous materials - Diffusion rate
Materials science |
| ISBN |
1-283-59214-2
9786613904591 3-527-65130-6 3-527-65127-6 3-527-65129-2 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Diffusion in Nanoporous Materials; Contents; Preface; Acknowledgments; Part I: Introduction; 1 Elementary Principles of Diffusion; 1.1 Fundamental Definitions; 1.1.1 Transfer of Matter by Diffusion; 1.1.2 Random Walk; 1.1.3 Transport Diffusion and Self-Diffusion; 1.1.4 Frames of Reference; 1.1.5 Diffusion in Anisotropic Media; 1.2 Driving Force for Diffusion; 1.2.1 Gradient of Chemical Potential; 1.2.2 Experimental Evidence; 1.2.3 Relationship between Transport and Self-diffusivities; 1.3 Diffusional Resistances in Nanoporous Media; 1.3.1 Internal Diffusional Resistances
1.3.2 Surface Resistance1.3.3 External Resistance to Mass Transfer; 1.4 Experimental Methods; References; Part II: Theory; 2 Diffusion as a Random Walk; 2.1 Random Walk Model; 2.1.1 Mean Square Displacement; 2.1.2 The Propagator; 2.1.3 Correspondence with Fick's Equations; 2.2 Correlation Effects; 2.2.1 Vacancy Correlations; 2.2.2 Correlated Anisotropy; 2.3 Boundary Conditions; 2.3.1 Absorbing and Reflecting Boundaries; 2.3.2 Partially Reflecting Boundary; 2.3.3 Matching Conditions; 2.3.4 Combined Impact of Diffusion and Permeation; 2.4 Macroscopic and Microscopic Diffusivities 2.5 Correlating Self-Diffusion and Diffusion with a Simple Jump Model2.6 Anomalous Diffusion; 2.6.1 Probability Distribution Functions of Residence Time and Jump Length; 2.6.2 Fractal Geometry; 2.6.3 Diffusion in a Fractal System; 2.6.4 Renormalization; 2.6.5 Deviations from Normal Diffusion in Nanoporous Materials: A Retrospective; References; 3 Diffusion and Non-equilibrium Thermodynamics; 3.1 Generalized Forces and Fluxes; 3.1.1 Mechanical Example; 3.1.2 Thermodynamic Forces and Fluxes; 3.1.3 Rate of Generation of Entropy; 3.1.4 Isothermal Approximation 3.1.5 Diffusion in a Binary Adsorbed Phase3.2 Self-Diffusion and Diffusive Transport; 3.3 Generalized Maxwell-Stefan Equations; 3.3.1 General Formulation; 3.3.2 Diffusion in an Adsorbed Phase; 3.3.3 Relation between Self- and Transport Diffusivities; 3.4 Application of the Maxwell-Stefan Model; 3.4.1 Parameter Estimation; 3.4.2 Membrane Permeation; 3.4.3 Diffusion in Macro- and Mesopores; 3.5 Loading Dependence of Self- and Transport Diffusivities; 3.5.1 Self-Diffusivities; 3.5.2 Transport Diffusivities; 3.5.3 Molecular Simulation; 3.5.4 Effect of Structural Defects 3.6 Diffusion at High Loadings and in Liquid-Filled PoresReferences; 4 Diffusion Mechanisms; 4.1 Diffusion Regimes; 4.1.1 Size-Selective Molecular Sieving; 4.2 Diffusion in Macro- and Mesopores; 4.2.1 Diffusion in a Straight Cylindrical Pore; 4.2.1.1 Knudsen Mechanism; 4.2.1.2 Viscous Flow; 4.2.1.3 Molecular Diffusion; 4.2.1.4 Transition Region; 4.2.1.5 Self-Diffusion/Tracer Diffusion; 4.2.1.6 Relative Importance of Different Mechanisms; 4.2.1.7 Surface Diffusion; 4.2.1.8 Combination of Diffusional Resistances; 4.2.2 Diffusion in a Pore Network; 4.2.2.1 Dusty Gas Model 4.2.2.2 Effective Medium Approximation |
| Record Nr. | UNINA-9910841638203321 |
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Kärger Jörg
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| Weinheim, Germany, : Wiley-VCH, c2012 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
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