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Advances in metallacrown chemistry / / Curtis M. Zaleski, editor
| Advances in metallacrown chemistry / / Curtis M. Zaleski, editor |
| Pubbl/distr/stampa | Cham, Switzerland : , : Springer, , [2022] |
| Descrizione fisica | 1 online resource (xiv, 381 pages) : illustrations (chiefly color) |
| Disciplina | 547.5 |
| Soggetto topico | Cyclic compounds |
| ISBN |
9783031085765
9783031085758 |
| Formato | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Intro -- Preface -- Acknowledgments -- Contents -- Contributors -- Host-Guest Chemistry of Metallacrowns -- 1 Molecular Recognition in Macrocycles -- 1.1 Organic Recognition Agents -- 1.2 Metallacrowns -- 1.3 Binding Larger Metals -- 2 Building up Systems of Greater Complexity -- 3 15-MC-5 Host-Guest Chemistry -- 3.1 Central Ion as Guest in 15-MC-5 -- 3.2 15-MC-5 Structures -- 3.3 Anion Recognition -- 3.4 Porous Structures -- 3.5 Measuring Guest Affinities -- 4 Conclusion -- References -- Aspects of NMR Characterization of Metallacrowns -- 1 Introduction -- 1.1 Pulsed-Gradient Spin-Echo NMR -- 1.2 1H-NMR of Paramagnetic Complexes -- 1.3 1H-NMR of Lanthanide Complexes -- 2 Interaction of Metallacrowns with Inorganic and Organic Anions -- 2.1 Interaction of Mn(III) Metallacrowns with Anions -- 2.2 Interaction of Copper(II) 15-MC-5 with Monocarboxylates -- 2.3 Formation of Dimeric Capsules -- 3 Metal Exchange Equilibria -- 3.1 Metal Exchange in Manganese(II/III) 12-MC-4 Complexes -- 3.2 Metal Exchange in Copper(II) 12-MC-4 and 15-MC-5 Complexes -- 4 MC Rearrangements and Ligand Exchange -- 4.1 MC Expansion -- 4.2 Ligand Exchange in Copper(II) Metallacrowns -- 5 Ln(III)/Mn(III) and Ln(III)/Cu(II) MCs: Insight on Their Structure in Solution -- 5.1 Ln(III)/Mn(III) 12-MC-4 Complexes -- 5.2 Ln(III)/Cu(II) 15-MC-5 Complexes -- 6 Conclusions -- References -- Influence of the Hydroxamate Ligands' Structure on the Thermodynamic Properties and Structure of Metallacrown Complexes -- 1 Introduction -- 2 Hydroxamate Derivatives as Ligands for MCs -- 2.1 Acid-Base Properties -- 3 Self-assembly of Metallacrown Complexes -- 3.1 Metallacrown Structural Paradigm -- 4 Thermodynamic Properties of Metallacrown Complexes -- 4.1 Cu(II) Complexes -- 4.2 Ni(II) Complexes -- 4.3 Zn(II) Complexes -- 5 Structural Studies.
5.1 MC Complexes Based on Hydroxamates Functionalized with O-Donors in β-Position -- 5.2 MC Complexes Based on α-Functionalized Hydroxamates -- 6 Metallacrowns Building Blocks -- References -- Metallacrowns as DNA Binders -- 1 DNA as a Target for Ligand Binding -- 2 Analytical Techniques for Studying Ligand/DNA Interactions -- 3 Metallacrown Complexes with DNA -- 3.1 Metallacrowns as Double-Stranded DNA Ligands -- 3.2 Metallacrowns as G4 DNA Ligands -- 4 Conclusions -- References -- Magnetic Metallacrowns: From Randomness to Rational Design -- 1 Introduction -- 1.1 Molecular Magnetism -- 1.2 Synthetic Strategies for Preparing Molecular Magnets -- 1.3 Single-Molecule, Single-Ion, and Single-Chain Magnets -- 2 Metallacrowns -- 2.1 Structural Control of Metallacrowns -- 3 Pseudo-Metallacrowns with Single-Molecule Magnetic Properties -- 3.1 28-MC-10: DyIII6MnIII4MnIV2, the First Mn-4f Single-Molecule Magnet -- 3.2 22-MC-8: DyIII4MnIII6Displays Slow Magnetic Relaxation -- 3.3 16-MC-6: DyIII4MnIII4 Displays Slow Magnetic Relaxation -- 3.4 26-MC-8: Lanthanide Choice Leads to Different Magnetic Responses -- 3.5 14-MC-5: The Development of Planar Metallacrowns as SMMs -- 3.6 12-MC-4, 16-MC-6, and 20-MC-7: Using Diamagnetic Ring Metals to Probe Lanthanide Coupling -- 4 Single-Molecule Magnetic Metallacrowns -- 4.1 12-MC-4s -- 4.2 15-MC-5s -- References -- Beyond the Metallacrown: Controlling First- and Second-Order Coordination Spheres Towards Discrete and Extended Architectures -- 1 An Introduction to Discrete Host-guest Assemblies Centred on Metallacrown Host Units -- 2 Fluoro-Centred Host Metallacrowns and Their Guest Enticing Abilities -- 2.1 Hexacopper Fluoro Azametallacrown Cavitands as Hosts for Cationic Guests -- 2.2 Guest Binding Within F-bridged Octametallic 16-MCCr(III)-8 [Cr8] Metallacrowns. 2.3 Heterometallic [Cr(III)7M(II)] (M = Mn, Fe, Co, Ni, Zn, Cd and Mg) Metallacrowns (and Variations on the Theme) -- 3 Organometallic 12-MCM(III)-3 (M = Ru, Rh, Ir) Metallacrown Hosts -- 3.1 Redox Responsive 12-MCM(III)-3 (M = Ru, Rh) Metallacrown Li+ and Na+ Receptors -- 3.2 The Accommodation of F-containing Guests Within 12-MCM(III)-3 (M = Ru, Rh, Ir) Metallacrowns -- 3.3 Selective Li+ Ion Detection in Water and Serum -- 3.4 The Role of a 16-Membered Metallacrown in the Interconversion of Two Nanocages -- 4 Controlling the First Coordination Sphere Towards Selective Binding and Topology Control -- 4.1 Hexametallic 18-MCCu(II)-6 Pertechnetate and Perrhenate Scavengers -- 4.2 Pentanuclear 12-MCCu(II)-4 Metallacrowns as Building Blocks Towards 1- and 2-D Extended Networks -- 4.3 Inverse Metallacrowns and Inverse Crown Ether Complexes -- 4.4 Triple Decker Inverse 12-MCCu(I)-pz-4 Azametallacrowns -- 4.5 An Inverse 9-MCCu(II)-3 Metallacrown as Host to an Anti-Inflammatory -- 4.6 Inverse Crown Ether Complexes and Their Solid-State Hosting Abilities -- 5 Concluding Remarks -- References -- Water-Soluble 15-Metallacrown-5 Complexes: Molecular Structures and Properties -- 1 Introduction -- 2 15-MC-5 Structural Paradigm -- 2.1 Computational Study of the Formation Process -- 3 Synthetic Approaches to Aqua Complexes -- 3.1 Structures of Aminohydroximate Ln(III)-Cu(II) 15-MC-5 Aqua Complexes -- 4 Solution-State Behavior -- 4.1 Toward MRI Applications -- 4.2 Toward Hydrothermal Single-Source Precursors of Nanomaterials -- 5 New Similarities and Analogues: Bi(III) Versus Ln(III) -- References -- Metallacrown-Based Catalysts for Water Oxidation and CO2 Conversion -- 1 Water Oxidation -- 2 CO2 Conversion -- 3 Summary -- References -- A Structural Examination of Metallacrowns with Main Group Elements in the Ring Positions -- 1 Introduction. 2 Gallium-Containing Metallacrown Complexes -- 2.1 Gallium 12-MC-4 Structures -- 2.2 Gallium 12-MC-4 Dimer Structures -- 2.3 Non-standard Gallium-Containing Metallacrowns and Metallacryptates -- 3 Other Main Group Metallacrown Complexes -- 3.1 Aluminum-Containing Metallacrowns and Metallacryptates -- 3.2 Tellurium-Containing Metallacrowns -- 3.3 Tin-Containing Metallacrowns -- 4 Azametallacrown Complexes with Main Group Elements -- 4.1 Gallium and Indium Azametallacrowns -- 4.2 Other p-Block Azametallacrowns-Aluminum, Silicon, and Tin -- 4.3 Alkali Metal Azametallacrowns-Lithium and Sodium -- 5 Conclusion -- References -- Index. |
| Record Nr. | UNINA-9910591042603321 |
| Cham, Switzerland : , : Springer, , [2022] | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
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Calixarenes revisited [[electronic resource] /] / C. David Gutsche
| Calixarenes revisited [[electronic resource] /] / C. David Gutsche |
| Autore | Gutsche C. David (Carl David), <1921-> |
| Pubbl/distr/stampa | Cambridge, : Royal Society of Chemistry, Information Services, 1998 |
| Descrizione fisica | 1 online resource (250 p.) |
| Disciplina | 547.5 |
| Collana | Monographs in supramolecular chemistry |
| Soggetto topico |
Phenols
Calixarenes |
| Soggetto genere / forma | Electronic books. |
| ISBN | 1-84755-029-0 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto | BK9780854045020-FX001; BK9780854045020-FP001; BK9780854045020-FP005; BK9780854045020-FP009; BK9780854045020-00001; BK9780854045020-00010; BK9780854045020-00032; BK9780854045020-00041; BK9780854045020-00079; BK9780854045020-00146; BK9780854045020-00185; BK9780854045020-00209; BK9780854045020-00223 |
| Record Nr. | UNINA-9910455298903321 |
Gutsche C. David (Carl David), <1921->
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| Cambridge, : Royal Society of Chemistry, Information Services, 1998 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Calixarenes revisited [[electronic resource] /] / C. David Gutsche
| Calixarenes revisited [[electronic resource] /] / C. David Gutsche |
| Autore | Gutsche C. David (Carl David), <1921-> |
| Pubbl/distr/stampa | Cambridge, : Royal Society of Chemistry, Information Services, 1998 |
| Descrizione fisica | 1 online resource (250 p.) |
| Disciplina | 547.5 |
| Collana | Monographs in supramolecular chemistry |
| Soggetto topico |
Phenols
Calixarenes |
| ISBN | 1-84755-029-0 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto | BK9780854045020-FX001; BK9780854045020-FP001; BK9780854045020-FP005; BK9780854045020-FP009; BK9780854045020-00001; BK9780854045020-00010; BK9780854045020-00032; BK9780854045020-00041; BK9780854045020-00079; BK9780854045020-00146; BK9780854045020-00185; BK9780854045020-00209; BK9780854045020-00223 |
| Record Nr. | UNINA-9910778545403321 |
|
Gutsche C. David (Carl David), <1921->
|
||
| Cambridge, : Royal Society of Chemistry, Information Services, 1998 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Calixarenes revisited / / C. David Gutsche
| Calixarenes revisited / / C. David Gutsche |
| Autore | Gutsche C. David (Carl David), <1921-> |
| Edizione | [1st ed.] |
| Pubbl/distr/stampa | Cambridge, : Royal Society of Chemistry, Information Services, 1998 |
| Descrizione fisica | 1 online resource (250 p.) |
| Disciplina | 547.5 |
| Collana |
ISSN
Monographs in supramolecular chemistry |
| Soggetto topico |
Phenols
Calixarenes |
| ISBN | 1-84755-029-0 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto | BK9780854045020-FX001; BK9780854045020-FP001; BK9780854045020-FP005; BK9780854045020-FP009; BK9780854045020-00001; BK9780854045020-00010; BK9780854045020-00032; BK9780854045020-00041; BK9780854045020-00079; BK9780854045020-00146; BK9780854045020-00185; BK9780854045020-00209; BK9780854045020-00223 |
| Record Nr. | UNINA-9910816269703321 |
|
Gutsche C. David (Carl David), <1921->
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| Cambridge, : Royal Society of Chemistry, Information Services, 1998 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
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Chimica dei composti eterociclici / Donato Sica, Franco Zollo
| Chimica dei composti eterociclici / Donato Sica, Franco Zollo |
| Autore | Sica, Donato |
| Pubbl/distr/stampa | Napoli, : EdiSES, 2001 |
| Descrizione fisica | XII, 302 p. ; 25 cm |
| Disciplina | 547.5 |
| Altri autori (Persone) | Zollo, Franco |
| Soggetto non controllato | Composti eterociclici |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | ita |
| Record Nr. | UNINA-990002231550403321 |
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Sica, Donato
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| Napoli, : EdiSES, 2001 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
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Chimica dei composti eterociclici farmacologicamente attivi / Donato Sica, Franco Zollo
| Chimica dei composti eterociclici farmacologicamente attivi / Donato Sica, Franco Zollo |
| Autore | Sica, Donato |
| Pubbl/distr/stampa | Padova : Piccin, c2008 |
| Descrizione fisica | XXX, 521 p. ; 25 cm |
| Disciplina | 547.5 |
| Altri autori (Persone) | Zollo, Franco |
| Soggetto non controllato | Composti eterociclici |
| ISBN | 978-88-299-1881-2 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | ita |
| Record Nr. | UNINA-990008567180403321 |
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Sica, Donato
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| Padova : Piccin, c2008 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
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Cyclic deformation in oxides, carbides and nitrides : alumina, magnesia, yttria, SiC, B4C and Si3N4 / / Joshua Pelleg
| Cyclic deformation in oxides, carbides and nitrides : alumina, magnesia, yttria, SiC, B4C and Si3N4 / / Joshua Pelleg |
| Autore | Pelleg Joshua |
| Pubbl/distr/stampa | Cham, Switzerland : , : Springer, , [2022] |
| Descrizione fisica | 1 online resource (542 pages) |
| Disciplina | 547.5 |
| Collana | Structural integrity (Series) |
| Soggetto topico | Cyclic compounds |
| ISBN |
9783030861186
9783030861179 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNINA-9910768468603321 |
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Pelleg Joshua
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| Cham, Switzerland : , : Springer, , [2022] | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
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Esistenza, società, ecosistema : pensiero geografico e questione ambientale / Adalberto Vallega
| Esistenza, società, ecosistema : pensiero geografico e questione ambientale / Adalberto Vallega |
| Autore | VALLEGA, Adalberto |
| Pubbl/distr/stampa | Milano, : Mursia, 1990 |
| Descrizione fisica | 287 p. ; 21 cm |
| Disciplina | 547.5 |
| Collana | Strumenti per una nuova cultura |
| Soggetto topico | Ecologia |
| ISBN | 88-425-0832-2 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | ita |
| Record Nr. | UNISA-990000997380203316 |
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VALLEGA, Adalberto
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| Milano, : Mursia, 1990 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. di Salerno | ||
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Macrocycle synthesis : a pratical approach / edited by David Parker
| Macrocycle synthesis : a pratical approach / edited by David Parker |
| Pubbl/distr/stampa | Oxford [etc.] : University Press, copyr. 1996 |
| Descrizione fisica | XIII, 250 p. : ill. ; 24 cm. - (The pratical approach in chemistry series) |
| Disciplina | 547.5 |
| ISBN | 0-19-855840-6 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNISA-990000258440203316 |
| Oxford [etc.] : University Press, copyr. 1996 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. di Salerno | ||
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Palladacycles : synthesis, characterization and applications / / edited by Jairton Dupont and Michel Pfeffer
| Palladacycles : synthesis, characterization and applications / / edited by Jairton Dupont and Michel Pfeffer |
| Pubbl/distr/stampa | Weinheim, [Germany] : , : Wiley-VCH Verlag GmbH & Co. KGaA, , 2008 |
| Descrizione fisica | 1 online resource (433 p.) |
| Disciplina | 547.5 |
| Soggetto topico |
Organometallic compounds
Polycyclic compounds Catalysis |
| Soggetto genere / forma | Electronic books. |
| ISBN |
1-281-94716-4
9786611947163 3-527-62321-3 3-527-62322-1 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Palladacycles; Contents; List of Contributors; 1 Introduction; 1.1 Introduction; 1.2 Definition; 1.3 Historical Overview; 1.4 Classification of Palladacycles (Types); 1.5 Final Remarks; References; 2 C-H Bond Activation; 2.1 General Remarks; 2.2 Activation of Aryl C-H Bonds; 2.2.1 Donor Group Coordination; 2.2.2 Metal Precursor; 2.2.3 Electron Density at the Arene C-H Bond; 2.3 Pincer Complexes: A Special Case; 2.4 Transcyclometallation; 2.5 Activation of Heterocyclic C-H Bonds, Formation of Pd-Carbene Bonds; 2.6 Activation of sp(3) C-H Bonds; 2.6.1 Activation of Benzylic C-H Bonds
2.6.2 Activation of Aliphatic C-H Bonds2.7 Conclusions and Perspectives; References; 3 Oxidative Addition and Transmetallation; 3.1 Introduction; 3.2 Oxidative Addition; 3.3 Transmetallation; References; 4 Synthesis via Other Synthetic Solutions; 4.1 Introduction; 4.2 Synthesis of Palladacycles via Nucleophile-Palladation Reaction of Olefins or Alkynes Bearing Electron-Donor Heteroatoms; 4.2.1 Alkoxypalladation Reaction; 4.2.2 Carbopalladation; 4.2.3 Chloropalladation; 4.3 Carbopalladation Reaction via Insertion of Olefins or Alkynes into the Pd-C σ-Bond of Nonpalladacyclic Species 4.3.1 Insertion of Olefins or Alkynes Bearing Electron-Donor Atoms4.3.2 Insertion of Olefins, Allenes or Alkynes into a Pd-C σ-Bond of a Fragment Containing Electron-Donor Atoms; 4.4 Nucleophile Palladation of Olefins or Alkynes Not Bearing Heteroatoms; 4.4.1 Aminopalladation and Aminoformylpalladation; 4.5 Conclusion; References; 5 The Pd-C Building Block of Palladacycles: A Cornerstone for Stoichiometric C-C and C-X Bond Assemblage; 5.1 Introduction; 5.2 Reactions with Carbon Monoxide; 5.3 Reactions with Alkenes; 5.4 Reaction with Alkynes; 5.5 Reaction with Isocyanides 5.6 Reaction with Allenes5.7 Reactions with Acyl Halides; 5.8 Reaction with Halogens; 5.9 Conclusions; References; 6 C-H Activations via Palladacycles; 6.1 Introduction: C-C Bond Formation via Cyclopalladation Reactions; 6.2 Stoichiometric C-H Activation Chemistry; 6.3 Catalytic Chemistry; 6.3.1 Vinylations; 6.4 Arylations; 6.5 Direct C-H C-H Coupling Reactions; 6.6 Alkylations; 6.7 Other Reactions; 6.7.1 Carbonylations; 6.7.2 C-N Bond Formation; 6.8 Conclusion; References; 7 Cyclopalladated Compounds as Resolving Agents for Racemic Mixtures of Ligands; 7.1 Introduction 7.2 Resolution Methods7.3 Chiral Palladacyclic Auxiliaries; 7.4 Monodentate Ligands; 7.4.1 Resolution of Phosphines and Arsines; 7.4.2 Resolution of Air-Sensitive Ligands; 7.4.3 Resolution of Atropoisomeric Phosphines; 7.4.4 Resolution of Halogenophosphines; 7.4.5 Resolution of Stibines; 7.4.6 Resolution of Cluttered Chiral Bidentate Ligands; 7.5 Bidentate Ligands; 7.5.1 Neutral Ligands; 7.5.2 Anionic Ligands; 7.6 Conclusion; References; 8 Application of Cyclopalladated Compounds as Catalysts for Heck and Sonogashira Reactions; 8.1 Heck Reaction; 8.1.1 Introduction; 8.1.2 Mechanism 8.1.3 Catalysts |
| Record Nr. | UNINA-9910144113803321 |
| Weinheim, [Germany] : , : Wiley-VCH Verlag GmbH & Co. KGaA, , 2008 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
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