Modern amination methods [[electronic resource] /] / edited by Alfredo Ricci |
Pubbl/distr/stampa | Weinheim ; ; Cambridge, : Wiley-VCH, c2000 |
Descrizione fisica | 1 online resource (288 p.) |
Disciplina |
547.25
660 |
Altri autori (Persone) | RicciAlfredo <1939-> |
Soggetto topico |
Amination - Methodology
Amines |
Soggetto genere / forma | Electronic books. |
ISBN |
1-281-76409-4
9786611764098 3-527-61318-8 3-527-61319-6 |
Formato | Materiale a stampa |
Livello bibliografico | Monografia |
Lingua di pubblicazione | eng |
Nota di contenuto |
Modern Amination Methods; Preface; Contents; List of Authors; Chapter 1 Modem Allylic Amination Methods; 1.1 Introduction; 1.2 Nucleophilic Amination of Functionalized Alkenes; 1.2.1 Amination of Allyl Alcohols; 1.2.2 Amination of Allyl halides; 1.2.2.1 Amination of Allyl Halides and Acetates Catalyzed by metal Complexes; 1.2.3 Electrophilic Amination of Non-Functionalized Alkenes; 1.2.4 Amination with Nitrene Complexes; 1.2.5 Amination Based on Ene-Reaction-Like Processes; 1.2.5.1 Type 1 Reactions: Ene Reaction Followed by [2,3]-Sigmatropic Rearrangement; 1.2.5.2 Type 2 Ene Reactions
1.2.6 Allylic Amination with Ar-NX and a Metal Catalyst1.3 Summary; Acknowledgments; References; Chapter 2 Eletrophilic Amination Routes from Alkenes; 2.1 Introduction; 2.2 Indirect Stoichiometric Amination; 2.2.1 Amination via Organoboron Compounds; 2.2.1.1 Applications to the Synthesis of Primary Amines; 2.2.1.2 Applications to the Synthesis of Secondary Amines; 2.2.1.3 Applications to the Synthesis of Tertiary Amines; 2.2.2 Amination via Organozirconium Compounds; 2.3 Indirect Catalytic Amination; 2.4 Direct Alkene Amination; References Chapter 3 Stereoselective Electrophilic Amination with Sulfonyloxycarbamates and Azodicarboxylates3.1 Introduction; 3.2 Sulfonyloxycarbamates; 3.2.1 Preparation of N-[(arylsulfonyl)oxy]carbamates; 3.2.2 Stereoselective Synthesis of a-Amino Carboxylic and Phosphonic Acids via Electrophilic Amination with Lithium rerr-Butyl N-(tosyloxy) Carbamate; 3.2.2.1 α-Amino Carboxylic Acids; 3.2.2.2 α-Amino Phosphonic Acids; 3.2.3 Reactions of Ethyl N-((p-nitrobenzenesulfonyl)oxy(carbamate with Chiral Enamines and Enol Ethers; 3.3 Dialkylazodicarboxylates 3.3.1 Electrophilic Amination of Silyl Ketene Acetals3.3.2 Electrophilic Amination of Chiral Amide Enolates; 3.3.3 Electrophilic Amination of Chiral Ester Enolates; 3.3.3.1 β-Hydroxy Esters; 3.3.3.2 β-Amino Esters; 3.3.4 Electrophilic Amination of Ketone Enolates; 3.3.5 Electrophilic Amination of Phosphorous-Stabilized Anions; 3.3.5.1 Oxazaphospholanes; 3.3.5.2 Diazaphospholidines; 3.4 Chiral Electrophilic Aminating Reagents; 3.4.1 Azodicarboxylates and Azodicarboxamides; 3.4.2 Chiral Catalytic Approach; 3.5 Conclusion; References Chapter 4 Glycosylamines as Auxiliaries in Stereoselective Syntheses of Chiral Amino Compounds4.1 Introduction; 4.1.1 Exo Anomeric Effect; 4.1.2 Influence of Coordinating Centers; 4.1.3 Pseudo-Enantiomeric Carbohydrates in Stereoselective Syntheses; 4.2 Syntheses of Amino Acids; 4.2.1 Syntheses of Enantiomerically Pure a-Amino Acids; 4.2.2 Syntheses of Enantiomerically Pure β-Amino Acids; 4.2.3 Rearrangement Reactions; 4.2.4 Stereoselective Multicomponent Reactions; 4.3 Stereoselective Syntheses of Chiral Heterocycles; 4.3.1 Heterocycles Through Cycloaddition Reactions 4.3.2 Stereoselective Syntheses of Chiral Piperidines via Addition Reactions to 4-Pyridones |
Record Nr. | UNINA-9910144283403321 |
Weinheim ; ; Cambridge, : Wiley-VCH, c2000 | ||
Materiale a stampa | ||
Lo trovi qui: Univ. Federico II | ||
|
Modern amination methods [[electronic resource] /] / edited by Alfredo Ricci |
Pubbl/distr/stampa | Weinheim ; ; Cambridge, : Wiley-VCH, c2000 |
Descrizione fisica | 1 online resource (288 p.) |
Disciplina |
547.25
660 |
Altri autori (Persone) | RicciAlfredo <1939-> |
Soggetto topico |
Amination - Methodology
Amines |
ISBN |
1-281-76409-4
9786611764098 3-527-61318-8 3-527-61319-6 |
Formato | Materiale a stampa |
Livello bibliografico | Monografia |
Lingua di pubblicazione | eng |
Nota di contenuto |
Modern Amination Methods; Preface; Contents; List of Authors; Chapter 1 Modem Allylic Amination Methods; 1.1 Introduction; 1.2 Nucleophilic Amination of Functionalized Alkenes; 1.2.1 Amination of Allyl Alcohols; 1.2.2 Amination of Allyl halides; 1.2.2.1 Amination of Allyl Halides and Acetates Catalyzed by metal Complexes; 1.2.3 Electrophilic Amination of Non-Functionalized Alkenes; 1.2.4 Amination with Nitrene Complexes; 1.2.5 Amination Based on Ene-Reaction-Like Processes; 1.2.5.1 Type 1 Reactions: Ene Reaction Followed by [2,3]-Sigmatropic Rearrangement; 1.2.5.2 Type 2 Ene Reactions
1.2.6 Allylic Amination with Ar-NX and a Metal Catalyst1.3 Summary; Acknowledgments; References; Chapter 2 Eletrophilic Amination Routes from Alkenes; 2.1 Introduction; 2.2 Indirect Stoichiometric Amination; 2.2.1 Amination via Organoboron Compounds; 2.2.1.1 Applications to the Synthesis of Primary Amines; 2.2.1.2 Applications to the Synthesis of Secondary Amines; 2.2.1.3 Applications to the Synthesis of Tertiary Amines; 2.2.2 Amination via Organozirconium Compounds; 2.3 Indirect Catalytic Amination; 2.4 Direct Alkene Amination; References Chapter 3 Stereoselective Electrophilic Amination with Sulfonyloxycarbamates and Azodicarboxylates3.1 Introduction; 3.2 Sulfonyloxycarbamates; 3.2.1 Preparation of N-[(arylsulfonyl)oxy]carbamates; 3.2.2 Stereoselective Synthesis of a-Amino Carboxylic and Phosphonic Acids via Electrophilic Amination with Lithium rerr-Butyl N-(tosyloxy) Carbamate; 3.2.2.1 α-Amino Carboxylic Acids; 3.2.2.2 α-Amino Phosphonic Acids; 3.2.3 Reactions of Ethyl N-((p-nitrobenzenesulfonyl)oxy(carbamate with Chiral Enamines and Enol Ethers; 3.3 Dialkylazodicarboxylates 3.3.1 Electrophilic Amination of Silyl Ketene Acetals3.3.2 Electrophilic Amination of Chiral Amide Enolates; 3.3.3 Electrophilic Amination of Chiral Ester Enolates; 3.3.3.1 β-Hydroxy Esters; 3.3.3.2 β-Amino Esters; 3.3.4 Electrophilic Amination of Ketone Enolates; 3.3.5 Electrophilic Amination of Phosphorous-Stabilized Anions; 3.3.5.1 Oxazaphospholanes; 3.3.5.2 Diazaphospholidines; 3.4 Chiral Electrophilic Aminating Reagents; 3.4.1 Azodicarboxylates and Azodicarboxamides; 3.4.2 Chiral Catalytic Approach; 3.5 Conclusion; References Chapter 4 Glycosylamines as Auxiliaries in Stereoselective Syntheses of Chiral Amino Compounds4.1 Introduction; 4.1.1 Exo Anomeric Effect; 4.1.2 Influence of Coordinating Centers; 4.1.3 Pseudo-Enantiomeric Carbohydrates in Stereoselective Syntheses; 4.2 Syntheses of Amino Acids; 4.2.1 Syntheses of Enantiomerically Pure a-Amino Acids; 4.2.2 Syntheses of Enantiomerically Pure β-Amino Acids; 4.2.3 Rearrangement Reactions; 4.2.4 Stereoselective Multicomponent Reactions; 4.3 Stereoselective Syntheses of Chiral Heterocycles; 4.3.1 Heterocycles Through Cycloaddition Reactions 4.3.2 Stereoselective Syntheses of Chiral Piperidines via Addition Reactions to 4-Pyridones |
Record Nr. | UNINA-9910830632103321 |
Weinheim ; ; Cambridge, : Wiley-VCH, c2000 | ||
Materiale a stampa | ||
Lo trovi qui: Univ. Federico II | ||
|
Modern amination methods / / edited by Alfredo Ricci |
Pubbl/distr/stampa | Weinheim ; ; Cambridge, : Wiley-VCH, c2000 |
Descrizione fisica | 1 online resource (288 p.) |
Disciplina |
547.25
660 |
Altri autori (Persone) | RicciAlfredo <1939-> |
Soggetto topico |
Amination - Methodology
Amines |
ISBN |
1-281-76409-4
9786611764098 3-527-61318-8 3-527-61319-6 |
Formato | Materiale a stampa |
Livello bibliografico | Monografia |
Lingua di pubblicazione | eng |
Nota di contenuto |
Modern Amination Methods; Preface; Contents; List of Authors; Chapter 1 Modem Allylic Amination Methods; 1.1 Introduction; 1.2 Nucleophilic Amination of Functionalized Alkenes; 1.2.1 Amination of Allyl Alcohols; 1.2.2 Amination of Allyl halides; 1.2.2.1 Amination of Allyl Halides and Acetates Catalyzed by metal Complexes; 1.2.3 Electrophilic Amination of Non-Functionalized Alkenes; 1.2.4 Amination with Nitrene Complexes; 1.2.5 Amination Based on Ene-Reaction-Like Processes; 1.2.5.1 Type 1 Reactions: Ene Reaction Followed by [2,3]-Sigmatropic Rearrangement; 1.2.5.2 Type 2 Ene Reactions
1.2.6 Allylic Amination with Ar-NX and a Metal Catalyst1.3 Summary; Acknowledgments; References; Chapter 2 Eletrophilic Amination Routes from Alkenes; 2.1 Introduction; 2.2 Indirect Stoichiometric Amination; 2.2.1 Amination via Organoboron Compounds; 2.2.1.1 Applications to the Synthesis of Primary Amines; 2.2.1.2 Applications to the Synthesis of Secondary Amines; 2.2.1.3 Applications to the Synthesis of Tertiary Amines; 2.2.2 Amination via Organozirconium Compounds; 2.3 Indirect Catalytic Amination; 2.4 Direct Alkene Amination; References Chapter 3 Stereoselective Electrophilic Amination with Sulfonyloxycarbamates and Azodicarboxylates3.1 Introduction; 3.2 Sulfonyloxycarbamates; 3.2.1 Preparation of N-[(arylsulfonyl)oxy]carbamates; 3.2.2 Stereoselective Synthesis of a-Amino Carboxylic and Phosphonic Acids via Electrophilic Amination with Lithium rerr-Butyl N-(tosyloxy) Carbamate; 3.2.2.1 α-Amino Carboxylic Acids; 3.2.2.2 α-Amino Phosphonic Acids; 3.2.3 Reactions of Ethyl N-((p-nitrobenzenesulfonyl)oxy(carbamate with Chiral Enamines and Enol Ethers; 3.3 Dialkylazodicarboxylates 3.3.1 Electrophilic Amination of Silyl Ketene Acetals3.3.2 Electrophilic Amination of Chiral Amide Enolates; 3.3.3 Electrophilic Amination of Chiral Ester Enolates; 3.3.3.1 β-Hydroxy Esters; 3.3.3.2 β-Amino Esters; 3.3.4 Electrophilic Amination of Ketone Enolates; 3.3.5 Electrophilic Amination of Phosphorous-Stabilized Anions; 3.3.5.1 Oxazaphospholanes; 3.3.5.2 Diazaphospholidines; 3.4 Chiral Electrophilic Aminating Reagents; 3.4.1 Azodicarboxylates and Azodicarboxamides; 3.4.2 Chiral Catalytic Approach; 3.5 Conclusion; References Chapter 4 Glycosylamines as Auxiliaries in Stereoselective Syntheses of Chiral Amino Compounds4.1 Introduction; 4.1.1 Exo Anomeric Effect; 4.1.2 Influence of Coordinating Centers; 4.1.3 Pseudo-Enantiomeric Carbohydrates in Stereoselective Syntheses; 4.2 Syntheses of Amino Acids; 4.2.1 Syntheses of Enantiomerically Pure a-Amino Acids; 4.2.2 Syntheses of Enantiomerically Pure β-Amino Acids; 4.2.3 Rearrangement Reactions; 4.2.4 Stereoselective Multicomponent Reactions; 4.3 Stereoselective Syntheses of Chiral Heterocycles; 4.3.1 Heterocycles Through Cycloaddition Reactions 4.3.2 Stereoselective Syntheses of Chiral Piperidines via Addition Reactions to 4-Pyridones |
Record Nr. | UNINA-9910877466903321 |
Weinheim ; ; Cambridge, : Wiley-VCH, c2000 | ||
Materiale a stampa | ||
Lo trovi qui: Univ. Federico II | ||
|