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Asymmetric organocatalysis [[electronic resource] ] : from biomimetic concepts to applications in asymmetric synthesis / / Albrecht Berkessel, Harald Gröger
Asymmetric organocatalysis [[electronic resource] ] : from biomimetic concepts to applications in asymmetric synthesis / / Albrecht Berkessel, Harald Gröger
Autore Berkessel Albrecht
Pubbl/distr/stampa Weinheim, : Wiley-VCH, c2005
Descrizione fisica 1 online resource (456 p.)
Disciplina 547.215
Altri autori (Persone) GrögerHarald
Soggetto topico Asymmetric synthesis
Catalysis
Organic compounds - Synthesis
Soggetto genere / forma Electronic books.
ISBN 1-280-51952-5
9786610519521
3-527-60467-7
3-527-60405-7
Classificazione 35.52
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Asymmetric Organocatalysis - From Biomimetic Concepts to Applications in Asymmetric Synthesis; Contents; Preface; Foreword; 1 Introduction: Organocatalysis - From Biomimetic Concepts to Powerful Methods for Asymmetric Synthesis; References; 2 On the Structure of the Book, and a Few General Mechanistic Considerations; 2.1 The Structure of the Book; 2.2 General Mechanistic Considerations; References; 3 Nucleophilic Substitution at Aliphatic Carbon; 3.1 α-Alkylation of Cyclic Ketones and Related Compounds; 3.2 α-Alkylation of α-Amino Acid Derivatives
3.2.1 Development of Highly Efficient Organocatalysts3.2.2 Improving Enantioselectivity During Work-up; 3.2.3 Specific Application in the Synthesis of Non-natural Amino Acids; 3.2.4 Synthesis of α,α-Dialkylated Amino Acids; 3.2.5 Enantio- and Diastereoselective Processes - Synthesis of α-Amino Acid Derivatives with Two Stereogenic Centers; 3.2.6 Solid-phase Syntheses; 3.3 α-Alkylation of Other Acyclic Substrates; 3.4 Fluorination, Chlorination, and Bromination Reactions; 3.4.1 Fluorination Reactions; 3.4.2 Chlorination and Bromination Reactions; References
4 Nucleophilic Addition to Electron-deficient C=C Double Bonds4.1 Intermolecular Michael Addition; 4.1.1 Intermolecular Michael Addition of C-nucleophiles; 4.1.1.1 Chiral Bases and Phase-transfer Catalysis; 4.1.1.2 Activation of Michael Acceptors by Iminium Ion Formation, Activation of Carbonyl Donors by Enamine Formation; 4.1.1.3 Addition of C-nucleophiles to Azodicarboxylates; 4.1.1.4 Cyclopropanation of Enoates with Phenacyl Halides; 4.1.2 Intermolecular Michael Addition of N- and O-nucleophiles; 4.1.3 Intermolecular Michael Addition of S- and Se-nucleophiles
4.2 Intramolecular Michael Addition4.2.1 Intramolecular Michael Addition of C-nucleophiles; 4.2.2 Intramolecular Michael Addition of O-nucleophiles; References; 5 Nucleophilic Addition to C=N Double Bonds; 5.1 Hydrocyanation of Imines (Strecker Reaction); 5.1.1 Chiral Diketopiperazines as Catalysts; 5.1.2 Chiral Guanidines as Catalysts; 5.1.3 Chiral Ureas and Thioureas as Catalysts; 5.1.4 Chiral N-Oxides as ""Catalysts""; 5.2 The Mannich Reaction; 5.2.1 Enantioselective Direct Mannich Reaction: Products with One Stereogenic Center
5.2.2 Enantio- and Diastereoselective Direct Mannich Reaction: Products with Two Stereogenic Centers5.2.3 Proline-catalyzed Mannich Reaction: Process Development and Optimization; 5.2.4 Enantioselective Mannich Reaction using Silyl Ketene Acetals; 5.3 β-Lactam Synthesis; 5.4 Sulfur Ylide-based Aziridination of Imines; 5.5 Hydrophosphonylation of Imines; References; 6 Nucleophilic Addition to C=O Double Bonds; 6.1 Hydrocyanation; 6.1.1 The Mechanism of the Reaction; 6.2 Aldol Reactions; 6.2.1 Intermolecular Aldol Reactions
6.2.1.1 Intermolecular Aldol Reaction With Formation of One Stereogenic Center
Record Nr. UNINA-9910142560503321
Berkessel Albrecht  
Weinheim, : Wiley-VCH, c2005
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Asymmetric organocatalysis [[electronic resource] ] : from biomimetic concepts to applications in asymmetric synthesis / / Albrecht Berkessel, Harald Gröger
Asymmetric organocatalysis [[electronic resource] ] : from biomimetic concepts to applications in asymmetric synthesis / / Albrecht Berkessel, Harald Gröger
Autore Berkessel Albrecht
Pubbl/distr/stampa Weinheim, : Wiley-VCH, c2005
Descrizione fisica 1 online resource (456 p.)
Disciplina 547.215
Altri autori (Persone) GrögerHarald
Soggetto topico Asymmetric synthesis
Catalysis
Organic compounds - Synthesis
ISBN 1-280-51952-5
9786610519521
3-527-60467-7
3-527-60405-7
Classificazione 35.52
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Asymmetric Organocatalysis - From Biomimetic Concepts to Applications in Asymmetric Synthesis; Contents; Preface; Foreword; 1 Introduction: Organocatalysis - From Biomimetic Concepts to Powerful Methods for Asymmetric Synthesis; References; 2 On the Structure of the Book, and a Few General Mechanistic Considerations; 2.1 The Structure of the Book; 2.2 General Mechanistic Considerations; References; 3 Nucleophilic Substitution at Aliphatic Carbon; 3.1 α-Alkylation of Cyclic Ketones and Related Compounds; 3.2 α-Alkylation of α-Amino Acid Derivatives
3.2.1 Development of Highly Efficient Organocatalysts3.2.2 Improving Enantioselectivity During Work-up; 3.2.3 Specific Application in the Synthesis of Non-natural Amino Acids; 3.2.4 Synthesis of α,α-Dialkylated Amino Acids; 3.2.5 Enantio- and Diastereoselective Processes - Synthesis of α-Amino Acid Derivatives with Two Stereogenic Centers; 3.2.6 Solid-phase Syntheses; 3.3 α-Alkylation of Other Acyclic Substrates; 3.4 Fluorination, Chlorination, and Bromination Reactions; 3.4.1 Fluorination Reactions; 3.4.2 Chlorination and Bromination Reactions; References
4 Nucleophilic Addition to Electron-deficient C=C Double Bonds4.1 Intermolecular Michael Addition; 4.1.1 Intermolecular Michael Addition of C-nucleophiles; 4.1.1.1 Chiral Bases and Phase-transfer Catalysis; 4.1.1.2 Activation of Michael Acceptors by Iminium Ion Formation, Activation of Carbonyl Donors by Enamine Formation; 4.1.1.3 Addition of C-nucleophiles to Azodicarboxylates; 4.1.1.4 Cyclopropanation of Enoates with Phenacyl Halides; 4.1.2 Intermolecular Michael Addition of N- and O-nucleophiles; 4.1.3 Intermolecular Michael Addition of S- and Se-nucleophiles
4.2 Intramolecular Michael Addition4.2.1 Intramolecular Michael Addition of C-nucleophiles; 4.2.2 Intramolecular Michael Addition of O-nucleophiles; References; 5 Nucleophilic Addition to C=N Double Bonds; 5.1 Hydrocyanation of Imines (Strecker Reaction); 5.1.1 Chiral Diketopiperazines as Catalysts; 5.1.2 Chiral Guanidines as Catalysts; 5.1.3 Chiral Ureas and Thioureas as Catalysts; 5.1.4 Chiral N-Oxides as ""Catalysts""; 5.2 The Mannich Reaction; 5.2.1 Enantioselective Direct Mannich Reaction: Products with One Stereogenic Center
5.2.2 Enantio- and Diastereoselective Direct Mannich Reaction: Products with Two Stereogenic Centers5.2.3 Proline-catalyzed Mannich Reaction: Process Development and Optimization; 5.2.4 Enantioselective Mannich Reaction using Silyl Ketene Acetals; 5.3 β-Lactam Synthesis; 5.4 Sulfur Ylide-based Aziridination of Imines; 5.5 Hydrophosphonylation of Imines; References; 6 Nucleophilic Addition to C=O Double Bonds; 6.1 Hydrocyanation; 6.1.1 The Mechanism of the Reaction; 6.2 Aldol Reactions; 6.2.1 Intermolecular Aldol Reactions
6.2.1.1 Intermolecular Aldol Reaction With Formation of One Stereogenic Center
Record Nr. UNISA-996203314103316
Berkessel Albrecht  
Weinheim, : Wiley-VCH, c2005
Materiale a stampa
Lo trovi qui: Univ. di Salerno
Opac: Controlla la disponibilità qui
Asymmetric organocatalysis [[electronic resource] ] : from biomimetic concepts to applications in asymmetric synthesis / / Albrecht Berkessel, Harald Gröger
Asymmetric organocatalysis [[electronic resource] ] : from biomimetic concepts to applications in asymmetric synthesis / / Albrecht Berkessel, Harald Gröger
Autore Berkessel Albrecht
Pubbl/distr/stampa Weinheim, : Wiley-VCH, c2005
Descrizione fisica 1 online resource (456 p.)
Disciplina 547.215
Altri autori (Persone) GrögerHarald
Soggetto topico Asymmetric synthesis
Catalysis
Organic compounds - Synthesis
ISBN 1-280-51952-5
9786610519521
3-527-60467-7
3-527-60405-7
Classificazione 35.52
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Asymmetric Organocatalysis - From Biomimetic Concepts to Applications in Asymmetric Synthesis; Contents; Preface; Foreword; 1 Introduction: Organocatalysis - From Biomimetic Concepts to Powerful Methods for Asymmetric Synthesis; References; 2 On the Structure of the Book, and a Few General Mechanistic Considerations; 2.1 The Structure of the Book; 2.2 General Mechanistic Considerations; References; 3 Nucleophilic Substitution at Aliphatic Carbon; 3.1 α-Alkylation of Cyclic Ketones and Related Compounds; 3.2 α-Alkylation of α-Amino Acid Derivatives
3.2.1 Development of Highly Efficient Organocatalysts3.2.2 Improving Enantioselectivity During Work-up; 3.2.3 Specific Application in the Synthesis of Non-natural Amino Acids; 3.2.4 Synthesis of α,α-Dialkylated Amino Acids; 3.2.5 Enantio- and Diastereoselective Processes - Synthesis of α-Amino Acid Derivatives with Two Stereogenic Centers; 3.2.6 Solid-phase Syntheses; 3.3 α-Alkylation of Other Acyclic Substrates; 3.4 Fluorination, Chlorination, and Bromination Reactions; 3.4.1 Fluorination Reactions; 3.4.2 Chlorination and Bromination Reactions; References
4 Nucleophilic Addition to Electron-deficient C=C Double Bonds4.1 Intermolecular Michael Addition; 4.1.1 Intermolecular Michael Addition of C-nucleophiles; 4.1.1.1 Chiral Bases and Phase-transfer Catalysis; 4.1.1.2 Activation of Michael Acceptors by Iminium Ion Formation, Activation of Carbonyl Donors by Enamine Formation; 4.1.1.3 Addition of C-nucleophiles to Azodicarboxylates; 4.1.1.4 Cyclopropanation of Enoates with Phenacyl Halides; 4.1.2 Intermolecular Michael Addition of N- and O-nucleophiles; 4.1.3 Intermolecular Michael Addition of S- and Se-nucleophiles
4.2 Intramolecular Michael Addition4.2.1 Intramolecular Michael Addition of C-nucleophiles; 4.2.2 Intramolecular Michael Addition of O-nucleophiles; References; 5 Nucleophilic Addition to C=N Double Bonds; 5.1 Hydrocyanation of Imines (Strecker Reaction); 5.1.1 Chiral Diketopiperazines as Catalysts; 5.1.2 Chiral Guanidines as Catalysts; 5.1.3 Chiral Ureas and Thioureas as Catalysts; 5.1.4 Chiral N-Oxides as ""Catalysts""; 5.2 The Mannich Reaction; 5.2.1 Enantioselective Direct Mannich Reaction: Products with One Stereogenic Center
5.2.2 Enantio- and Diastereoselective Direct Mannich Reaction: Products with Two Stereogenic Centers5.2.3 Proline-catalyzed Mannich Reaction: Process Development and Optimization; 5.2.4 Enantioselective Mannich Reaction using Silyl Ketene Acetals; 5.3 β-Lactam Synthesis; 5.4 Sulfur Ylide-based Aziridination of Imines; 5.5 Hydrophosphonylation of Imines; References; 6 Nucleophilic Addition to C=O Double Bonds; 6.1 Hydrocyanation; 6.1.1 The Mechanism of the Reaction; 6.2 Aldol Reactions; 6.2.1 Intermolecular Aldol Reactions
6.2.1.1 Intermolecular Aldol Reaction With Formation of One Stereogenic Center
Record Nr. UNINA-9910829871003321
Berkessel Albrecht  
Weinheim, : Wiley-VCH, c2005
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Asymmetric organocatalysis : from biomimetic concepts to applications in asymmetric synthesis / / Albrecht Berkessel, Harald Groger
Asymmetric organocatalysis : from biomimetic concepts to applications in asymmetric synthesis / / Albrecht Berkessel, Harald Groger
Autore Berkessel Albrecht
Pubbl/distr/stampa Weinheim, : Wiley-VCH, c2005
Descrizione fisica 1 online resource (456 p.)
Disciplina 547.215
Altri autori (Persone) GrogerHarald
Soggetto topico Asymmetric synthesis
Catalysis
Organic compounds - Synthesis
ISBN 9786610519521
9781280519529
1280519525
9783527604678
3527604677
9783527604050
3527604057
Classificazione 35.52
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Asymmetric Organocatalysis - From Biomimetic Concepts to Applications in Asymmetric Synthesis; Contents; Preface; Foreword; 1 Introduction: Organocatalysis - From Biomimetic Concepts to Powerful Methods for Asymmetric Synthesis; References; 2 On the Structure of the Book, and a Few General Mechanistic Considerations; 2.1 The Structure of the Book; 2.2 General Mechanistic Considerations; References; 3 Nucleophilic Substitution at Aliphatic Carbon; 3.1 α-Alkylation of Cyclic Ketones and Related Compounds; 3.2 α-Alkylation of α-Amino Acid Derivatives
3.2.1 Development of Highly Efficient Organocatalysts3.2.2 Improving Enantioselectivity During Work-up; 3.2.3 Specific Application in the Synthesis of Non-natural Amino Acids; 3.2.4 Synthesis of α,α-Dialkylated Amino Acids; 3.2.5 Enantio- and Diastereoselective Processes - Synthesis of α-Amino Acid Derivatives with Two Stereogenic Centers; 3.2.6 Solid-phase Syntheses; 3.3 α-Alkylation of Other Acyclic Substrates; 3.4 Fluorination, Chlorination, and Bromination Reactions; 3.4.1 Fluorination Reactions; 3.4.2 Chlorination and Bromination Reactions; References
4 Nucleophilic Addition to Electron-deficient C=C Double Bonds4.1 Intermolecular Michael Addition; 4.1.1 Intermolecular Michael Addition of C-nucleophiles; 4.1.1.1 Chiral Bases and Phase-transfer Catalysis; 4.1.1.2 Activation of Michael Acceptors by Iminium Ion Formation, Activation of Carbonyl Donors by Enamine Formation; 4.1.1.3 Addition of C-nucleophiles to Azodicarboxylates; 4.1.1.4 Cyclopropanation of Enoates with Phenacyl Halides; 4.1.2 Intermolecular Michael Addition of N- and O-nucleophiles; 4.1.3 Intermolecular Michael Addition of S- and Se-nucleophiles
4.2 Intramolecular Michael Addition4.2.1 Intramolecular Michael Addition of C-nucleophiles; 4.2.2 Intramolecular Michael Addition of O-nucleophiles; References; 5 Nucleophilic Addition to C=N Double Bonds; 5.1 Hydrocyanation of Imines (Strecker Reaction); 5.1.1 Chiral Diketopiperazines as Catalysts; 5.1.2 Chiral Guanidines as Catalysts; 5.1.3 Chiral Ureas and Thioureas as Catalysts; 5.1.4 Chiral N-Oxides as ""Catalysts""; 5.2 The Mannich Reaction; 5.2.1 Enantioselective Direct Mannich Reaction: Products with One Stereogenic Center
5.2.2 Enantio- and Diastereoselective Direct Mannich Reaction: Products with Two Stereogenic Centers5.2.3 Proline-catalyzed Mannich Reaction: Process Development and Optimization; 5.2.4 Enantioselective Mannich Reaction using Silyl Ketene Acetals; 5.3 β-Lactam Synthesis; 5.4 Sulfur Ylide-based Aziridination of Imines; 5.5 Hydrophosphonylation of Imines; References; 6 Nucleophilic Addition to C=O Double Bonds; 6.1 Hydrocyanation; 6.1.1 The Mechanism of the Reaction; 6.2 Aldol Reactions; 6.2.1 Intermolecular Aldol Reactions
6.2.1.1 Intermolecular Aldol Reaction With Formation of One Stereogenic Center
Record Nr. UNINA-9911018821203321
Berkessel Albrecht  
Weinheim, : Wiley-VCH, c2005
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Asymmetric phase transfer catalysis / / edited by Keiji Maruoka
Asymmetric phase transfer catalysis / / edited by Keiji Maruoka
Pubbl/distr/stampa Weinheim, [Germany] : , : Wiley-VCH Verlag GmbH & Co. KGaA, , 2008
Descrizione fisica 1 online resource (230 p.)
Disciplina 547.215
Soggetto topico Phase-transfer catalysis
Asymmetry (Chemistry)
ISBN 1-281-94695-8
9786611946951
3-527-62262-4
3-527-62263-2
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Asymmetric Phase Transfer Catalysis; Contents; Preface; List of Contributors; 1 The Basic Principle of Phase-Transfer Catalysis and Some Mechanistic Aspects; 1.1 Introduction; 1.2 Inorganic Base-Promoted Activation of Acidic Organic Compounds; 1.2.1 Generation of Reactive Onium Carbanion Species; 1.2.2 Stability of the Onium Carbanion; 1.2.3 Reactivity of the Onium Carbanion; 1.2.4 Nuclueophilic Substitution Reaction; 1.2.5 Nucleophilic Addition to Electrophilic C=X Double Bonds; 1.3 Phase-Transfer-Catalyzed Addition of Anion Supplied as Metal Salt
1.4 Use of Crown Ether as Phase-Transfer CatalystReferences; 2 Cinchona-Derived Chiral Phase-Transfer Catalysts for Amino Acid Synthesis; 2.1 Introduction; 2.2 α-Amino Acid Synthesis; 2.2.1 Monoalkylation of Schiff Bases Derived from Glycine; 2.2.2 Alkylation of Schiff Bases Derived from α-Alkyl-α-Amino Acids; 2.2.3 Other Alkylations for α-Amino Acid Synthesis; 2.2.4 Michael Reaction of Glycinate Benzophenone Schiff Bases; 2.2.5 Aldol and Related Reactions; 2.2.6 Aza-Henry Reaction; 2.2.7 Strecker Reaction; 2.2.8 Aziridination; 2.2.9 Radical Reaction; 2.3 β-Amino Acid Synthesis
2.3.1 Mannich Reaction2.3.2 Cyclopropanation; 2.4 Conclusions; References; 3 Cinchona-Derived Chiral Phase-Transfer Catalysts for Other Asymmetric Synthesis; 3.1 Introduction; 3.2 Asymmetric Darzens Reaction; 3.3 Asymmetric Conjugated Addition; 3.4 Asymmetric Aldol Reaction; 3.5 Asymmetric Oxygen-Functionalization; 3.6 Asymmetric Alkylation; 3.7 Asymmetric Alkenylation and Alkynylation; 3.8 Asymmetric S(N) Aromatic Reaction; 3.9 Asymmetric Strecker Synthesis; 3.10 Asymmetric Fluorination; References; 4 Cinchona-Derived Chiral Poly(Phase-Transfer Catalysts) for Asymmetric Synthesis
4.1 Cinchona Alkaloids4.1.1 Cinchona Alkaloids in Asymmetric Phase-Transfer Catalysis; 4.1.2 The Origin of Stereoselectivity of Cinchona-PTCs; 4.2 Development of Dimeric Cinchona-PTCs by the Park-Jew Group; 4.2.1 Dimeric Cinchona-PTCs with Phenyl Linker; 4.2.2 1,3-Dimeric Cinchona-PTCs with Electronically Modified Phenyl Linker; 4.2.3 Polymeric Cinchona-PTCs with Other Linkers; 4.2.4 1,3-Phenyl- and 2,7-Naphthyl-Linked Dimeric Cinchona-PTCs; 4.3 Polymeric PTCs Developed by the Najera Group; 4.4 Polymeric PTCs Developed by the Siva Group; 4.5 Polymeric PTCs Developed by the Wang Group
4.6 Asymmetric Epoxidation with Polymeric Cinchona-PTCs4.7 Conclusions; References; 5 Binaphthyl- and Biphenyl-Modified Chiral Phase-Transfer Catalysts for Asymmetric Synthesis; 5.1 Introduction; 5.2 Alkylation; 5.2.1 Asymmetric Synthesis of α-Alkyl α-Amino Acids and Their Derivatives; 5.2.1.1 Asymmetric Monoalkylation of Glycine Ester Schiff Bases; 5.2.1.2 Asymmetric Monoalkylation of Glycine Amide Schiff Bases; 5.2.1.3 Diastereoselective Alkylation of Glycine Schiff Base with Optically Enriched Alkyl Halides; 5.2.1.4 Recyclable Catalysts and Reagents and Solid-Phase Synthesis
5.2.1.5 Application of Asymmetric Synthesis of α-Amino Acids
Record Nr. UNINA-9910144450503321
Weinheim, [Germany] : , : Wiley-VCH Verlag GmbH & Co. KGaA, , 2008
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Asymmetric phase transfer catalysis / / edited by Keiji Maruoka
Asymmetric phase transfer catalysis / / edited by Keiji Maruoka
Pubbl/distr/stampa Weinheim, [Germany] : , : Wiley-VCH Verlag GmbH & Co. KGaA, , 2008
Descrizione fisica 1 online resource (230 p.)
Disciplina 547.215
Soggetto topico Phase-transfer catalysis
Asymmetry (Chemistry)
ISBN 1-281-94695-8
9786611946951
3-527-62262-4
3-527-62263-2
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Asymmetric Phase Transfer Catalysis; Contents; Preface; List of Contributors; 1 The Basic Principle of Phase-Transfer Catalysis and Some Mechanistic Aspects; 1.1 Introduction; 1.2 Inorganic Base-Promoted Activation of Acidic Organic Compounds; 1.2.1 Generation of Reactive Onium Carbanion Species; 1.2.2 Stability of the Onium Carbanion; 1.2.3 Reactivity of the Onium Carbanion; 1.2.4 Nuclueophilic Substitution Reaction; 1.2.5 Nucleophilic Addition to Electrophilic C=X Double Bonds; 1.3 Phase-Transfer-Catalyzed Addition of Anion Supplied as Metal Salt
1.4 Use of Crown Ether as Phase-Transfer CatalystReferences; 2 Cinchona-Derived Chiral Phase-Transfer Catalysts for Amino Acid Synthesis; 2.1 Introduction; 2.2 α-Amino Acid Synthesis; 2.2.1 Monoalkylation of Schiff Bases Derived from Glycine; 2.2.2 Alkylation of Schiff Bases Derived from α-Alkyl-α-Amino Acids; 2.2.3 Other Alkylations for α-Amino Acid Synthesis; 2.2.4 Michael Reaction of Glycinate Benzophenone Schiff Bases; 2.2.5 Aldol and Related Reactions; 2.2.6 Aza-Henry Reaction; 2.2.7 Strecker Reaction; 2.2.8 Aziridination; 2.2.9 Radical Reaction; 2.3 β-Amino Acid Synthesis
2.3.1 Mannich Reaction2.3.2 Cyclopropanation; 2.4 Conclusions; References; 3 Cinchona-Derived Chiral Phase-Transfer Catalysts for Other Asymmetric Synthesis; 3.1 Introduction; 3.2 Asymmetric Darzens Reaction; 3.3 Asymmetric Conjugated Addition; 3.4 Asymmetric Aldol Reaction; 3.5 Asymmetric Oxygen-Functionalization; 3.6 Asymmetric Alkylation; 3.7 Asymmetric Alkenylation and Alkynylation; 3.8 Asymmetric S(N) Aromatic Reaction; 3.9 Asymmetric Strecker Synthesis; 3.10 Asymmetric Fluorination; References; 4 Cinchona-Derived Chiral Poly(Phase-Transfer Catalysts) for Asymmetric Synthesis
4.1 Cinchona Alkaloids4.1.1 Cinchona Alkaloids in Asymmetric Phase-Transfer Catalysis; 4.1.2 The Origin of Stereoselectivity of Cinchona-PTCs; 4.2 Development of Dimeric Cinchona-PTCs by the Park-Jew Group; 4.2.1 Dimeric Cinchona-PTCs with Phenyl Linker; 4.2.2 1,3-Dimeric Cinchona-PTCs with Electronically Modified Phenyl Linker; 4.2.3 Polymeric Cinchona-PTCs with Other Linkers; 4.2.4 1,3-Phenyl- and 2,7-Naphthyl-Linked Dimeric Cinchona-PTCs; 4.3 Polymeric PTCs Developed by the Najera Group; 4.4 Polymeric PTCs Developed by the Siva Group; 4.5 Polymeric PTCs Developed by the Wang Group
4.6 Asymmetric Epoxidation with Polymeric Cinchona-PTCs4.7 Conclusions; References; 5 Binaphthyl- and Biphenyl-Modified Chiral Phase-Transfer Catalysts for Asymmetric Synthesis; 5.1 Introduction; 5.2 Alkylation; 5.2.1 Asymmetric Synthesis of α-Alkyl α-Amino Acids and Their Derivatives; 5.2.1.1 Asymmetric Monoalkylation of Glycine Ester Schiff Bases; 5.2.1.2 Asymmetric Monoalkylation of Glycine Amide Schiff Bases; 5.2.1.3 Diastereoselective Alkylation of Glycine Schiff Base with Optically Enriched Alkyl Halides; 5.2.1.4 Recyclable Catalysts and Reagents and Solid-Phase Synthesis
5.2.1.5 Application of Asymmetric Synthesis of α-Amino Acids
Record Nr. UNINA-9910829867903321
Weinheim, [Germany] : , : Wiley-VCH Verlag GmbH & Co. KGaA, , 2008
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Bioorganic and Enzymatic Catalysis
Bioorganic and Enzymatic Catalysis
Autore Woggon Wolf-D
Edizione [1st ed.]
Pubbl/distr/stampa Newark : , : John Wiley & Sons, Incorporated, , 2023
Descrizione fisica 1 online resource (192 pages)
Disciplina 547.215
ISBN 3-527-67836-0
3-527-67833-6
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Cover -- Title Page -- Contents -- Preface -- 1 Enzymatic CC Bond Formation by Aldol Reactions -- Aldolases -- Class I Aldolases -- Bioorganic Class I Aldolase Reactions -- Class II Aldolases -- Class II Aldolase Mimics -- References -- 2 Fatty Acid- and Polyketide-Synthases - Claisen-Type CC Bond Formation -- Biomimetic Decarboxylative CC Bond Formation -- References -- 3 Carbenium-Ion-Driven CC Bond Formations - Terpenes -- Enzyme-like Cyclisations Involving Carbenium Ions -- References -- 4 Oxidations Catalysed by Heme Complexes -- Monooxygenases -- Cytochromes P450 -- Synthetic P450 Enzyme Models -- Chloroperoxidase (CPO) -- Synthetic Enzyme Mimics of Chloroperoxidase (CPO) -- NO Synthase (NOS) -- References -- 5 Oxidations Catalysed by Non-heme Complexes and Other Co-factors -- Methane Monooxygenase -- Active Site Analogues of Methane Monooxygenase -- Enzyme Mimics of Cu Monooxygenases -- Flavin-dependent Monooxygenases -- Enzyme Mimics of Baeyer-Villiger Monooxygenases -- References -- 6 C-H Activation -- References -- 7 Dioxygenases -- Metal Complexes Displaying Dioxygenase-like Reactivity -- References -- 8 Oxidoreductases -- Cytochrome c Oxidase -- References -- 9 Synthetic Systems That Mimic Certain Aspects of Oxidoreductases -- References -- Index -- EULA.
Record Nr. UNINA-9910830807203321
Woggon Wolf-D  
Newark : , : John Wiley & Sons, Incorporated, , 2023
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Bioorganic and Enzymatic Catalysis
Bioorganic and Enzymatic Catalysis
Autore Woggon Wolf-D
Edizione [1st ed.]
Pubbl/distr/stampa Newark : , : John Wiley & Sons, Incorporated, , 2023
Descrizione fisica 1 online resource (192 pages)
Disciplina 547.215
Soggetto topico Bioorganic chemistry
Catalysis
ISBN 9783527678365
3527678360
9783527678334
3527678336
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Cover -- Title Page -- Contents -- Preface -- 1 Enzymatic CC Bond Formation by Aldol Reactions -- Aldolases -- Class I Aldolases -- Bioorganic Class I Aldolase Reactions -- Class II Aldolases -- Class II Aldolase Mimics -- References -- 2 Fatty Acid- and Polyketide-Synthases - Claisen-Type CC Bond Formation -- Biomimetic Decarboxylative CC Bond Formation -- References -- 3 Carbenium-Ion-Driven CC Bond Formations - Terpenes -- Enzyme-like Cyclisations Involving Carbenium Ions -- References -- 4 Oxidations Catalysed by Heme Complexes -- Monooxygenases -- Cytochromes P450 -- Synthetic P450 Enzyme Models -- Chloroperoxidase (CPO) -- Synthetic Enzyme Mimics of Chloroperoxidase (CPO) -- NO Synthase (NOS) -- References -- 5 Oxidations Catalysed by Non-heme Complexes and Other Co-factors -- Methane Monooxygenase -- Active Site Analogues of Methane Monooxygenase -- Enzyme Mimics of Cu Monooxygenases -- Flavin-dependent Monooxygenases -- Enzyme Mimics of Baeyer-Villiger Monooxygenases -- References -- 6 C-H Activation -- References -- 7 Dioxygenases -- Metal Complexes Displaying Dioxygenase-like Reactivity -- References -- 8 Oxidoreductases -- Cytochrome c Oxidase -- References -- 9 Synthetic Systems That Mimic Certain Aspects of Oxidoreductases -- References -- Index -- EULA.
Record Nr. UNINA-9911020229003321
Woggon Wolf-D  
Newark : , : John Wiley & Sons, Incorporated, , 2023
Materiale a stampa
Lo trovi qui: Univ. Federico II
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Catalysis : concepts and green applications / Gadi Rothenberg
Catalysis : concepts and green applications / Gadi Rothenberg
Autore Rothenberg, Gadi
Pubbl/distr/stampa Weinheim, : Wiley-VCH, c2008
Descrizione fisica XIII, 279 p. : ill. ; 25 cm
Disciplina 547
547.215
Soggetto non controllato Chimica organica
ISBN 978-3-527-31824-7
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Record Nr. UNINA-990008810610403321
Rothenberg, Gadi  
Weinheim, : Wiley-VCH, c2008
Materiale a stampa
Lo trovi qui: Univ. Federico II
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Catalytic asymmetric synthesis / edited by Iwao Ojima
Catalytic asymmetric synthesis / edited by Iwao Ojima
Autore Ojima, Iwao
Edizione [3. ed]
Pubbl/distr/stampa Hoboken : Wiley, 2010
Descrizione fisica XVII, 998 p. ; 24 cm.
Disciplina 547.215
Soggetto topico Catalisi
Reazioni chimiche
ISBN 978-0-470-17577-4
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Record Nr. UNIBAS-000033646
Ojima, Iwao  
Hoboken : Wiley, 2010
Materiale a stampa
Lo trovi qui: Univ. della Basilicata
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