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Ionic and organometallic-catalyzed organosilane reductions [[electronic resource] /] / Gerald L. Larson and James L. Fry
| Ionic and organometallic-catalyzed organosilane reductions [[electronic resource] /] / Gerald L. Larson and James L. Fry |
| Autore | Larson G. L (Gerald L.) |
| Pubbl/distr/stampa | Hoboken, NJ, : Wiley, c2010 |
| Descrizione fisica | 1 online resource (768 p.) |
| Disciplina | 547.08 |
| Altri autori (Persone) | FryJames L |
| Collana | Organic Reactions |
| Soggetto topico |
Organosilicon compounds
Silicon compounds |
| ISBN |
1-282-45532-X
9786612455322 0-470-09899-6 0-470-57268-X 0-470-57267-1 |
| Formato | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto | Ionic and Organometallic-Catalyzed Organosilane Reductions; CONTENTS; FOREWORD; PREFACE; IONIC AND ORGANOMETALLIC-CATALYZED ORGANOSILANE REDUCTIONS; INDEX |
| Record Nr. | UNINA-9910139984803321 |
Larson G. L (Gerald L.)
|
||
| Hoboken, NJ, : Wiley, c2010 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Ionic and organometallic-catalyzed organosilane reductions [[electronic resource] /] / Gerald L. Larson and James L. Fry
| Ionic and organometallic-catalyzed organosilane reductions [[electronic resource] /] / Gerald L. Larson and James L. Fry |
| Autore | Larson G. L (Gerald L.) |
| Pubbl/distr/stampa | Hoboken, NJ, : Wiley, c2010 |
| Descrizione fisica | 1 online resource (768 p.) |
| Disciplina | 547.08 |
| Altri autori (Persone) | FryJames L |
| Collana | Organic Reactions |
| Soggetto topico |
Organosilicon compounds
Silicon compounds |
| ISBN |
1-282-45532-X
9786612455322 0-470-09899-6 0-470-57268-X 0-470-57267-1 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto | Ionic and Organometallic-Catalyzed Organosilane Reductions; CONTENTS; FOREWORD; PREFACE; IONIC AND ORGANOMETALLIC-CATALYZED ORGANOSILANE REDUCTIONS; INDEX |
| Record Nr. | UNINA-9910816987303321 |
|
Larson G. L (Gerald L.)
|
||
| Hoboken, NJ, : Wiley, c2010 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Organosilanes in radical chemistry [[electronic resource] /] / Chryssostomos Chatgilialoglu
| Organosilanes in radical chemistry [[electronic resource] /] / Chryssostomos Chatgilialoglu |
| Autore | Chatgilialoglu Chryssostomos |
| Pubbl/distr/stampa | West Sussex, England, : Wiley, c2004 |
| Descrizione fisica | 1 online resource (241 p.) |
| Disciplina |
547
547.08 547/.08 |
| Soggetto topico |
Organosilicon compounds
Free radicals (Chemistry) |
| Soggetto genere / forma | Electronic books. |
| ISBN |
1-280-26956-1
9786610269563 0-470-09425-7 0-470-02475-5 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Organosilanes in Radical Chemistry; CONTENTS; Preface; Acknowledgements; 1 Formation and Structures of Silyl Radicals; 1.1 Methods of Generation of Silyl Radicals; 1.2 Structural Properties of Silyl Radicals; 1.2.1 Chemical Studies; 1.2.2 Electron Paramagnetic Resonance (EPR) Spectra; 1.2.3 Crystal Structures; 1.2.4 UV-Visible Spectra; 1.2.5 Theoretical Studies; 1.3 References; 2 Thermochemistry; 2.1 General Considerations; 2.2 Bond Dissociation Enthalpies; 2.2.1 Radical Kinetics; 2.2.2 Photoacoustic Calorimetry; 2.2.3 Theoretical Data; 2.2.4 Derived Bond Dissociation Energies
2.3 Ion Thermochemistry2.3.1 Negative-ion Cycles; 2.3.2 Hydride-affinity Cycles; 2.4 References; 3 Hydrogen Donor Abilities of Silicon Hydrides; 3.1 Carbon-centred Radicals; 3.1.1 Primary Alkyl Radicals and Free-Radical Clock Methodology; 3.1.2 Other Types of Carbon-centred Radicals; 3.2 Nitrogen-centred Radicals; 3.3 Oxygen-centred Radicals; 3.3.1 Alkoxyl Radicals; 3.3.2 Peroxyl Radicals; 3.3.3 Aryloxyl and Aroyloxyl Radicals; 3.4 Sulfur-centred Radicals; 3.5 Ketone Triplets; 3.6 Hydrogen Atom: An Example of Gas-phase Kinetics; 3.7 Theoretical Approaches; 3.8 References; 4 Reducing Agents 4.1 General Aspects of Radical Chain Reactions4.1.1 Radical-Radical Reactions; 4.2 Radical Initiators; 4.3 Tris(trimethylsilyl)silane; 4.3.1 Dehalogenations; 4.3.2 Reductive Removal of Chalcogen Groups (RS and RSe); 4.3.3 Deoxygenation of Alcohols (Barton-McCombie Reaction); 4.3.4 Miscellaneous Reactions; 4.3.5 Appendix; 4.4 Other Silicon Hydrides; 4.4.1 Trialkylsilanes; 4.4.2 Phenyl Substituted Silicon Hydrides; 4.4.3 Silyl Substituted Silicon Hydrides; 4.4.4 Alkylthio Substituted Silicon Hydrides; 4.5 Silicon Hydride/Thiol Mixture; 4.6 Silanethiols; 4.7 Silylated Cyclohexadienes 4.8 References5 Addition to Unsaturated Bonds; 5.1 Carbon-Carbon Double Bonds; 5.1.1 Formation of Silyl Radical Adducts; 5.1.2 Hydrosilylation of Alkenes; 5.2 Carbon-Carbon Triple Bonds; 5.2.1 Formation of Silyl Radical Adducts; 5.2.2 Hydrosilylation of Alkynes; 5.3 Carbon-Oxygen Double Bonds; 5.3.1 Formation of Silyl Radical Adducts; 5.3.2 Hydrosilylation of Carbonyl Groups; 5.3.3 Radical Brook Rearrangement; 5.4 Other Carbon-Heteroatom Multiple Bonds; 5.5 Cumulenes and Hetero-Cumulenes; 5.6 Heteroatom-Heteroatom Multiple Bonds; 5.7 References; 6 Unimolecular Reactions 6.1 Cyclization Reactions of Silyl Radicals6.1.1 Five-membered Ring Expansion; 6.2 Aryl Migration; 6.3 Acyloxy Migration; 6.4 Intramolecular Homolytic Substitution at Silicon; 6.5 Homolytic Organosilicon Group Transfer; 6.6 References; 7 Consecutive Radical Reactions; 7.1 Basic Concepts of Carbon-Carbon Bond Formation; 7.2 Intermolecular Formation of Carbon-Carbon Bonds; 7.3 Intramolecular Formation of Carbon-Carbon Bonds (Cyclizations); 7.3.1 Construction of Carbocycles; 7.3.2 Construction of Cyclic Ethers and Lactones; 7.3.3 Construction of Cyclic Amines and Lactames 7.4 Formation of Carbon-Heteroatom Bonds |
| Record Nr. | UNINA-9910146249703321 |
|
Chatgilialoglu Chryssostomos
|
||
| West Sussex, England, : Wiley, c2004 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Organosilanes in radical chemistry [[electronic resource] /] / Chryssostomos Chatgilialoglu
| Organosilanes in radical chemistry [[electronic resource] /] / Chryssostomos Chatgilialoglu |
| Autore | Chatgilialoglu Chryssostomos |
| Pubbl/distr/stampa | West Sussex, England, : Wiley, c2004 |
| Descrizione fisica | 1 online resource (241 p.) |
| Disciplina |
547
547.08 547/.08 |
| Soggetto topico |
Organosilicon compounds
Free radicals (Chemistry) |
| ISBN |
1-280-26956-1
9786610269563 0-470-09425-7 0-470-02475-5 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Organosilanes in Radical Chemistry; CONTENTS; Preface; Acknowledgements; 1 Formation and Structures of Silyl Radicals; 1.1 Methods of Generation of Silyl Radicals; 1.2 Structural Properties of Silyl Radicals; 1.2.1 Chemical Studies; 1.2.2 Electron Paramagnetic Resonance (EPR) Spectra; 1.2.3 Crystal Structures; 1.2.4 UV-Visible Spectra; 1.2.5 Theoretical Studies; 1.3 References; 2 Thermochemistry; 2.1 General Considerations; 2.2 Bond Dissociation Enthalpies; 2.2.1 Radical Kinetics; 2.2.2 Photoacoustic Calorimetry; 2.2.3 Theoretical Data; 2.2.4 Derived Bond Dissociation Energies
2.3 Ion Thermochemistry2.3.1 Negative-ion Cycles; 2.3.2 Hydride-affinity Cycles; 2.4 References; 3 Hydrogen Donor Abilities of Silicon Hydrides; 3.1 Carbon-centred Radicals; 3.1.1 Primary Alkyl Radicals and Free-Radical Clock Methodology; 3.1.2 Other Types of Carbon-centred Radicals; 3.2 Nitrogen-centred Radicals; 3.3 Oxygen-centred Radicals; 3.3.1 Alkoxyl Radicals; 3.3.2 Peroxyl Radicals; 3.3.3 Aryloxyl and Aroyloxyl Radicals; 3.4 Sulfur-centred Radicals; 3.5 Ketone Triplets; 3.6 Hydrogen Atom: An Example of Gas-phase Kinetics; 3.7 Theoretical Approaches; 3.8 References; 4 Reducing Agents 4.1 General Aspects of Radical Chain Reactions4.1.1 Radical-Radical Reactions; 4.2 Radical Initiators; 4.3 Tris(trimethylsilyl)silane; 4.3.1 Dehalogenations; 4.3.2 Reductive Removal of Chalcogen Groups (RS and RSe); 4.3.3 Deoxygenation of Alcohols (Barton-McCombie Reaction); 4.3.4 Miscellaneous Reactions; 4.3.5 Appendix; 4.4 Other Silicon Hydrides; 4.4.1 Trialkylsilanes; 4.4.2 Phenyl Substituted Silicon Hydrides; 4.4.3 Silyl Substituted Silicon Hydrides; 4.4.4 Alkylthio Substituted Silicon Hydrides; 4.5 Silicon Hydride/Thiol Mixture; 4.6 Silanethiols; 4.7 Silylated Cyclohexadienes 4.8 References5 Addition to Unsaturated Bonds; 5.1 Carbon-Carbon Double Bonds; 5.1.1 Formation of Silyl Radical Adducts; 5.1.2 Hydrosilylation of Alkenes; 5.2 Carbon-Carbon Triple Bonds; 5.2.1 Formation of Silyl Radical Adducts; 5.2.2 Hydrosilylation of Alkynes; 5.3 Carbon-Oxygen Double Bonds; 5.3.1 Formation of Silyl Radical Adducts; 5.3.2 Hydrosilylation of Carbonyl Groups; 5.3.3 Radical Brook Rearrangement; 5.4 Other Carbon-Heteroatom Multiple Bonds; 5.5 Cumulenes and Hetero-Cumulenes; 5.6 Heteroatom-Heteroatom Multiple Bonds; 5.7 References; 6 Unimolecular Reactions 6.1 Cyclization Reactions of Silyl Radicals6.1.1 Five-membered Ring Expansion; 6.2 Aryl Migration; 6.3 Acyloxy Migration; 6.4 Intramolecular Homolytic Substitution at Silicon; 6.5 Homolytic Organosilicon Group Transfer; 6.6 References; 7 Consecutive Radical Reactions; 7.1 Basic Concepts of Carbon-Carbon Bond Formation; 7.2 Intermolecular Formation of Carbon-Carbon Bonds; 7.3 Intramolecular Formation of Carbon-Carbon Bonds (Cyclizations); 7.3.1 Construction of Carbocycles; 7.3.2 Construction of Cyclic Ethers and Lactones; 7.3.3 Construction of Cyclic Amines and Lactames 7.4 Formation of Carbon-Heteroatom Bonds |
| Record Nr. | UNINA-9910829802503321 |
|
Chatgilialoglu Chryssostomos
|
||
| West Sussex, England, : Wiley, c2004 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Organosilanes in radical chemistry [[electronic resource] /] / Chryssostomos Chatgilialoglu
| Organosilanes in radical chemistry [[electronic resource] /] / Chryssostomos Chatgilialoglu |
| Autore | Chatgilialoglu Chryssostomos |
| Pubbl/distr/stampa | West Sussex, England, : Wiley, c2004 |
| Descrizione fisica | 1 online resource (241 p.) |
| Disciplina |
547
547.08 547/.08 |
| Soggetto topico |
Organosilicon compounds
Free radicals (Chemistry) |
| ISBN |
1-280-26956-1
9786610269563 0-470-09425-7 0-470-02475-5 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Organosilanes in Radical Chemistry; CONTENTS; Preface; Acknowledgements; 1 Formation and Structures of Silyl Radicals; 1.1 Methods of Generation of Silyl Radicals; 1.2 Structural Properties of Silyl Radicals; 1.2.1 Chemical Studies; 1.2.2 Electron Paramagnetic Resonance (EPR) Spectra; 1.2.3 Crystal Structures; 1.2.4 UV-Visible Spectra; 1.2.5 Theoretical Studies; 1.3 References; 2 Thermochemistry; 2.1 General Considerations; 2.2 Bond Dissociation Enthalpies; 2.2.1 Radical Kinetics; 2.2.2 Photoacoustic Calorimetry; 2.2.3 Theoretical Data; 2.2.4 Derived Bond Dissociation Energies
2.3 Ion Thermochemistry2.3.1 Negative-ion Cycles; 2.3.2 Hydride-affinity Cycles; 2.4 References; 3 Hydrogen Donor Abilities of Silicon Hydrides; 3.1 Carbon-centred Radicals; 3.1.1 Primary Alkyl Radicals and Free-Radical Clock Methodology; 3.1.2 Other Types of Carbon-centred Radicals; 3.2 Nitrogen-centred Radicals; 3.3 Oxygen-centred Radicals; 3.3.1 Alkoxyl Radicals; 3.3.2 Peroxyl Radicals; 3.3.3 Aryloxyl and Aroyloxyl Radicals; 3.4 Sulfur-centred Radicals; 3.5 Ketone Triplets; 3.6 Hydrogen Atom: An Example of Gas-phase Kinetics; 3.7 Theoretical Approaches; 3.8 References; 4 Reducing Agents 4.1 General Aspects of Radical Chain Reactions4.1.1 Radical-Radical Reactions; 4.2 Radical Initiators; 4.3 Tris(trimethylsilyl)silane; 4.3.1 Dehalogenations; 4.3.2 Reductive Removal of Chalcogen Groups (RS and RSe); 4.3.3 Deoxygenation of Alcohols (Barton-McCombie Reaction); 4.3.4 Miscellaneous Reactions; 4.3.5 Appendix; 4.4 Other Silicon Hydrides; 4.4.1 Trialkylsilanes; 4.4.2 Phenyl Substituted Silicon Hydrides; 4.4.3 Silyl Substituted Silicon Hydrides; 4.4.4 Alkylthio Substituted Silicon Hydrides; 4.5 Silicon Hydride/Thiol Mixture; 4.6 Silanethiols; 4.7 Silylated Cyclohexadienes 4.8 References5 Addition to Unsaturated Bonds; 5.1 Carbon-Carbon Double Bonds; 5.1.1 Formation of Silyl Radical Adducts; 5.1.2 Hydrosilylation of Alkenes; 5.2 Carbon-Carbon Triple Bonds; 5.2.1 Formation of Silyl Radical Adducts; 5.2.2 Hydrosilylation of Alkynes; 5.3 Carbon-Oxygen Double Bonds; 5.3.1 Formation of Silyl Radical Adducts; 5.3.2 Hydrosilylation of Carbonyl Groups; 5.3.3 Radical Brook Rearrangement; 5.4 Other Carbon-Heteroatom Multiple Bonds; 5.5 Cumulenes and Hetero-Cumulenes; 5.6 Heteroatom-Heteroatom Multiple Bonds; 5.7 References; 6 Unimolecular Reactions 6.1 Cyclization Reactions of Silyl Radicals6.1.1 Five-membered Ring Expansion; 6.2 Aryl Migration; 6.3 Acyloxy Migration; 6.4 Intramolecular Homolytic Substitution at Silicon; 6.5 Homolytic Organosilicon Group Transfer; 6.6 References; 7 Consecutive Radical Reactions; 7.1 Basic Concepts of Carbon-Carbon Bond Formation; 7.2 Intermolecular Formation of Carbon-Carbon Bonds; 7.3 Intramolecular Formation of Carbon-Carbon Bonds (Cyclizations); 7.3.1 Construction of Carbocycles; 7.3.2 Construction of Cyclic Ethers and Lactones; 7.3.3 Construction of Cyclic Amines and Lactames 7.4 Formation of Carbon-Heteroatom Bonds |
| Record Nr. | UNINA-9910840573903321 |
|
Chatgilialoglu Chryssostomos
|
||
| West Sussex, England, : Wiley, c2004 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Organosilicon chemistry : novel approaches and reactions / / edited by Tamejiro Hiyama, Martin Oestreich
| Organosilicon chemistry : novel approaches and reactions / / edited by Tamejiro Hiyama, Martin Oestreich |
| Autore | Hiyama Tamejiro |
| Pubbl/distr/stampa | Weinheim, Germany : , : Wiley-VCH, , [2019] |
| Descrizione fisica | 1 online resource (569 pages) |
| Disciplina | 547.08 |
| Soggetto topico | Organosilicon compounds |
| Soggetto genere / forma | Electronic books. |
| ISBN |
3-527-81477-9
1-5231-3315-5 3-527-81478-7 3-527-81475-2 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNINA-9910554853503321 |
|
Hiyama Tamejiro
|
||
| Weinheim, Germany : , : Wiley-VCH, , [2019] | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Organosilicon chemistry : novel approaches and reactions / / edited by Tamejiro Hiyama, Martin Oestreich
| Organosilicon chemistry : novel approaches and reactions / / edited by Tamejiro Hiyama, Martin Oestreich |
| Autore | Hiyama Tamejiro |
| Pubbl/distr/stampa | Weinheim, Germany : , : Wiley-VCH, , [2019] |
| Descrizione fisica | 1 online resource (569 pages) |
| Disciplina | 547.08 |
| Soggetto topico | Organosilicon compounds |
| ISBN |
3-527-81477-9
1-5231-3315-5 3-527-81478-7 3-527-81475-2 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNINA-9910830900103321 |
|
Hiyama Tamejiro
|
||
| Weinheim, Germany : , : Wiley-VCH, , [2019] | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Organosilicon chemistry . III : from molecules to materials / / edited by Norbert Auner and Johann Weis
| Organosilicon chemistry . III : from molecules to materials / / edited by Norbert Auner and Johann Weis |
| Pubbl/distr/stampa | Weinheim, [Germany] : , : Wiley-VCH, , 1998 |
| Descrizione fisica | 1 online resource (744 p.) |
| Disciplina | 547.08 |
| Soggetto topico | Organosilicon compounds |
| Soggetto genere / forma | Electronic books. |
| ISBN |
1-281-76470-1
9786611764708 3-527-61990-9 3-527-62074-5 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | ger |
| Nota di contenuto |
Organosilicon Chemistry III, from Molecules to Materials; Contents; I. Fascinating Organosilicon Compounds; Introduction; More Compelling Evidence that Silicon is Better Than Carbon: The Thermal Isomerization of Olefins to Carbenes; NMR and Quantum Chemical Characterization of Silicon-Substituted Carbocations; Matrix Isolation Studies of the Reactions of Silicon Atoms; Cycloaddition Reactions of Dimethylaminomethylsilylene with Dienes and Heterodienes; Do Unsubstituted Silacyclobutadienes Exist?; A Thermally Stable Silylene: Reactivity of the Bis(amino)silylene Si[{N(CH2tBu))2}C6H4-1,2]
Pyrido[b]- 1 ,3,2λ2-diazasilole: The First Stable Unsymmetrical SilyleneA New Route to Silaheterocycles: Heterobutadiene Cycloaddition; Base Coordination: A Way to Nucleophilic Silylenes?; Isoelectronic Replacement of Si by P+: A Comparative Study of the Structures of the Spirocyclic EII Compounds E[C(PMe2)2(X)]2 (E = Si, Ge, Sn; X = PMe2,SiMes) and a Novel Spirocyclic 10 e-Phosphorus Cation(Pm) P[C(PPh2)2(SiMe3)]2+; The Main Group Carbonyls mi-CO and R2Si-CO: An Ab Initio Study Unprecedented Multistep Reactions of Decamethylsilicocene, (Me5Cs)zSi:, with C02, CSZ, COS, RNCS (R = Me, Ph), with CF3CCCF3, and with HMn(C0)5Rearrangement of Bis(hypersilyl)silylene and Related Compounds - An Unusual Way to Three-Membered Rings; Oxidation of Silenes and Silylenes: Matrix Isolation of Unusual Silicon Species; New Silaheterocycles: Formation and Properties; Cycloaddition Reactions of 1,l-Dichloro-2-neopentylsilene with Monoterpenes; Silaspirocycles as Precursors for a 2-Silaallene; Catalytic Carbon-Carbon Hydrogenation of Silicon-Functionalized Olefins Dieno- and Enophilicity of Sila-, Germa-, and StannaethenesIminosilanes and Silaamidides: Synthesis and Reactions; Metastable Compounds Containing Silicon-Phosphorus and Silicon-Arsenic Multiple Bonds: Syntheses, Structures and Reactivity; Silole and Germole Dianions and their Dilithium Derivatives - Are they Aromatic?; Supersilylmetal Compounds; Trialkylsilyl Substituted Homobimetallic Phosphanides of the Alkaline Earth Metals as well as Zinc; The Tris(trimethylsily1)silyl Substituent: An Old Hat With A New Feather Functionalized Trisilylmethanes and Trisilylsilanes as Precursors of a New Class of Tripodal Amido LigandsMethoxy-bis[tris(trimethylsilyl)silyl]methane: The First Geminal Di(hypersily1) Compound; The Use of the Tris(trimethylsily1)silyl Group in Stabilization of Low Valent Gallium Compounds; Synthesis, Structure, and Reactions of Tris(trimethylsi1yl)silyl Gallanes and Gallates; Novel Pathways in the Reactions of Vinylsilanes with Lithium Metal; New Organosilicon Reagents : Synthesis, Structure, and Reactivity of (Lithiomethyl)(aminomethyl)silanes (Phenylthiomethyl)silanes as New Bihnctional Assembling Ligands for the Construction of Heterometallic Complexes |
| Record Nr. | UNINA-9910144133203321 |
| Weinheim, [Germany] : , : Wiley-VCH, , 1998 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Organosilicon chemistry . III : from molecules to materials / / edited by Norbert Auner and Johann Weis
| Organosilicon chemistry . III : from molecules to materials / / edited by Norbert Auner and Johann Weis |
| Pubbl/distr/stampa | Weinheim, [Germany] : , : Wiley-VCH, , 1998 |
| Descrizione fisica | 1 online resource (744 p.) |
| Disciplina | 547.08 |
| Soggetto topico | Organosilicon compounds |
| ISBN |
1-281-76470-1
9786611764708 3-527-61990-9 3-527-62074-5 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | ger |
| Nota di contenuto |
Organosilicon Chemistry III, from Molecules to Materials; Contents; I. Fascinating Organosilicon Compounds; Introduction; More Compelling Evidence that Silicon is Better Than Carbon: The Thermal Isomerization of Olefins to Carbenes; NMR and Quantum Chemical Characterization of Silicon-Substituted Carbocations; Matrix Isolation Studies of the Reactions of Silicon Atoms; Cycloaddition Reactions of Dimethylaminomethylsilylene with Dienes and Heterodienes; Do Unsubstituted Silacyclobutadienes Exist?; A Thermally Stable Silylene: Reactivity of the Bis(amino)silylene Si[{N(CH2tBu))2}C6H4-1,2]
Pyrido[b]- 1 ,3,2λ2-diazasilole: The First Stable Unsymmetrical SilyleneA New Route to Silaheterocycles: Heterobutadiene Cycloaddition; Base Coordination: A Way to Nucleophilic Silylenes?; Isoelectronic Replacement of Si by P+: A Comparative Study of the Structures of the Spirocyclic EII Compounds E[C(PMe2)2(X)]2 (E = Si, Ge, Sn; X = PMe2,SiMes) and a Novel Spirocyclic 10 e-Phosphorus Cation(Pm) P[C(PPh2)2(SiMe3)]2+; The Main Group Carbonyls mi-CO and R2Si-CO: An Ab Initio Study Unprecedented Multistep Reactions of Decamethylsilicocene, (Me5Cs)zSi:, with C02, CSZ, COS, RNCS (R = Me, Ph), with CF3CCCF3, and with HMn(C0)5Rearrangement of Bis(hypersilyl)silylene and Related Compounds - An Unusual Way to Three-Membered Rings; Oxidation of Silenes and Silylenes: Matrix Isolation of Unusual Silicon Species; New Silaheterocycles: Formation and Properties; Cycloaddition Reactions of 1,l-Dichloro-2-neopentylsilene with Monoterpenes; Silaspirocycles as Precursors for a 2-Silaallene; Catalytic Carbon-Carbon Hydrogenation of Silicon-Functionalized Olefins Dieno- and Enophilicity of Sila-, Germa-, and StannaethenesIminosilanes and Silaamidides: Synthesis and Reactions; Metastable Compounds Containing Silicon-Phosphorus and Silicon-Arsenic Multiple Bonds: Syntheses, Structures and Reactivity; Silole and Germole Dianions and their Dilithium Derivatives - Are they Aromatic?; Supersilylmetal Compounds; Trialkylsilyl Substituted Homobimetallic Phosphanides of the Alkaline Earth Metals as well as Zinc; The Tris(trimethylsily1)silyl Substituent: An Old Hat With A New Feather Functionalized Trisilylmethanes and Trisilylsilanes as Precursors of a New Class of Tripodal Amido LigandsMethoxy-bis[tris(trimethylsilyl)silyl]methane: The First Geminal Di(hypersily1) Compound; The Use of the Tris(trimethylsily1)silyl Group in Stabilization of Low Valent Gallium Compounds; Synthesis, Structure, and Reactions of Tris(trimethylsi1yl)silyl Gallanes and Gallates; Novel Pathways in the Reactions of Vinylsilanes with Lithium Metal; New Organosilicon Reagents : Synthesis, Structure, and Reactivity of (Lithiomethyl)(aminomethyl)silanes (Phenylthiomethyl)silanes as New Bihnctional Assembling Ligands for the Construction of Heterometallic Complexes |
| Record Nr. | UNINA-9910830667103321 |
| Weinheim, [Germany] : , : Wiley-VCH, , 1998 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Organosilicon chemistry [[electronic resource] ] : from molecules to materials / / edited by Norbert Auner, Johann Weis
| Organosilicon chemistry [[electronic resource] ] : from molecules to materials / / edited by Norbert Auner, Johann Weis |
| Pubbl/distr/stampa | Weinheim ; ; New York, : VCH, c1994 |
| Descrizione fisica | 1 online resource (374 p.) |
| Disciplina |
547
547.08 547/.08 |
| Altri autori (Persone) |
AunerNorbert
WeisJohann |
| Soggetto topico | Organosilicon compounds |
| Soggetto genere / forma | Electronic books. |
| ISBN |
3-527-62041-9
1-283-83495-2 3-527-62077-X 3-527-61993-3 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Organosilicon Chemistry From Molecules to Materials; Contents; Tetravalent Organosilicon Compounds: Chemistry and Structure; Introduction; Structures of Small Silicon Containing Compounds - Why and How?; Sterically Overcrowded Organosilicon Compounds and their Properties; Synthesis of Functionally Substituted Oligosilanes Based on Silyltriflate Derivatives; Electroreductive Formation of Di- and Polysilanes; Linear Tetrasilanes with Internal Substituents: Oligosilanes with Optical Activity; A New Way to Si-Ge and Si-Sn Bonds: Hexachlorodisilane Cleavage of Organometal Phosphanes
29Si29Si-Coupling Constants of Bromo- and Iododisilanes and -trisilanes XnSi2H6-n and XnSi3H8-n (X = Br, I)Calculation of the 29 Si NMR Chemical Shifts in Molecules with SIN, SiCl, and SiSi Bonds; Reactivity of Very Electron-Rich Organosilyl Amines; Lithiated Aminofluorosilanes as Precursors for Monomeric and Dimeric Iminosilanes; Fluorofunctional Silylamines and -Hydrazines Precursors for (Si-N) Ring Systems; New Approaches to (Fluoromethyl)silanes; Homo- and heterocyclic Si-O-Systems . Rings and Cages Silaheterocycles from Intramolecular Reactions of Silicon-functionalized Diazoacetic EstersSynthesis and Reaction Behavior of Organoalkoxysilylphenols; N-Silylation: New Possibilities for Long-known Amines; On the Acid-catalyzed Reaction of Siloxanes with Alcohols; On the Reactivity of Chlorosiloxanes; Chlorosilanols - more stable than you think - shown with 29Si NMR; Diorganosilyl-bis(O-alkylphosphonates); Subvalent and Unsaturated Organosilicon Compounds: Formation and Reactivity; Introduction; Basic Principles of the Theory of Bonding in Silicon Compounds Expectations from an Unusual Compound: The Chemistry of DecamethylsilicoceneCp*2Si(CO) and CP*2Si(N2): Complexes of Decamethylsilicocene; Silicon and Phosphinomethanides: A Novel Entry to Hypervalent and Low Valent Organosilicon Chemistry; Neopentylsilenes: Laboratory Curiosities or Useful Building Blocks for the Synthesis of Silaheterocycles ?; Synthesis and Thermolysis Reactions of Si-functionalized 2-Silaazetidines; Reactions of Silaethenes in the Gas Phase and in Solution; The Reaction of Vinylsilanes with Lithium Metal; Small Silicon Ring Compounds: Formation and Reactions Matrix Photolysis of Simple AzidosilanesLow-coordinated Si-Compounds: Gas Phase Reactions with Heterosubstituted Silylenes; Unusual Coordination in Phosphorus-Silicon Compounds; Unsaturated Silicon Compounds: Matrix IR Investigations and Quantum Chemical Calculations; Hypervalent Organosilicon Compounds: Formation, Structure and Chemistry; Introduction; Reactivity of Penta- and Hexacoordinated Silicon Species; Compounds with High Coordination Numbers at Silicon: Models for the Investigation of the Nucleophilic Substitution Reaction at Silicon Centers Organosilicon Metal Compounds: Coordination Chemistry and Catalysis |
| Record Nr. | UNINA-9910146030103321 |
| Weinheim ; ; New York, : VCH, c1994 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
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